US2071250A - Linear condensation polymers - Google Patents

Linear condensation polymers Download PDF

Info

Publication number
US2071250A
US2071250A US548701A US54870131A US2071250A US 2071250 A US2071250 A US 2071250A US 548701 A US548701 A US 548701A US 54870131 A US54870131 A US 54870131A US 2071250 A US2071250 A US 2071250A
Authority
US
United States
Prior art keywords
fibres
product
polymer
volatile
condensation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US548701A
Inventor
Wallace H Carothers
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EI Du Pont de Nemours and Co
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority to US548701A priority Critical patent/US2071250A/en
Priority claimed from US660778A external-priority patent/US2071251A/en
Application granted granted Critical
Publication of US2071250A publication Critical patent/US2071250A/en
Anticipated expiration legal-status Critical
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=24190030&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=US2071250(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/12Molecular distillation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/21Nylon

Description

Feb. 16, 1937. w. H. CAROTHERS 2,071,250

LINEAR CONDENSATION POLYMERS Filed July 3, 1951 h/a/lace H. Carat/lens. 3mm

Patented Feb. 16', 1937 TUNIT-EDITSTATES i PATENT OFFICE 2,071,250 LINEAR. CONDENSATION POLYMERS Wallace H. Carothers, Pennsbury Township, Chester County, Pa., assignor to E. I. du Pont de Nemours & Company, Wilmington, Del., a

corporation of Delaware Application July 3, 1931, Serial No. 548,70

2:; Claims. (01. 260 -106) This invention relates to the preparationof high molecular weight linear superpolymers having unusual. and valuable properties, and more particularly it relates to the production of fibres.

from synthetic materials, and to a new method of propagating chemical reactions; v

Linear condensation polymers of various types, particularly linear polyesters, have been described in the scientific and patent literature (Carothers m and Arvin, J.[Am. Chem; Soc. 51, 2560 (1929);

Carothers and Van Natta, ibid 52, 314. (1930);

Lycan and Adams, ibid., 51, 3450 (1929), and in the applications of Wallace H. Carothers, Serial vNumbers 382,843 now Patent No.2,012,267 and 406,721 now Patent No. 1,995,291 filed August 1, 1929 and November I, 12,. 1929, respectively).

Through thev application of the, principles set forth in these citations, linear polyesters of moderately high molecular weight have been obtained. Thus, if ethylene glycol and succinic acid in equivalent amounts are heated together in a 3 molecular weight together with water, unchanged succinic acid, and unchanged glycol. If the same an apparent limit has been reached, and so far I 253-281 (1920).) So far as I am aware,-no synclosed container one obtains a mixture in the form of a liquid or pasty mass which is partly composed of polymeric ethylene succinate of low reactants are heated in a distilling flask arranged so that the water can distill out of the re-. action mixture as fast as it is formed, practically all the succinic acid and glycol are finally used up and the product consists of polymeric ethylene succinate having a molecular. weight of about 1500. If the heating of this product. is continued.

' in the distilling flask under vacuum its molecular weight finally rises to about 3000. At. this stage as I am aware no linear condensation polymers having the same unique properties and having an average molecular weight as high as my new compounds have ever been prepared hitherto.

The synthetic linearcondensation superpoly mers produced in accordance with the present invention are suitable for the production of artificial fibres which are pliable,strong, and elastic and which show a high degree of orientation along the fibre axis.

searches have proved, are also linearsuperpoly mers. (Meyer, Biochemische Zeitschrift, 214:,

thctic material has hitherto been prepared which is capable/of being formed'into fibres showing appreciable strength and pliability, definite orientation along the fibre axis, and high elastic re- 55 covery in the manner characteristic of the pres- In this respect they resemblc cellulose and silk which, as recent. re-

ent invention. It is true that Staudinger has frequently emphasized the probable structural analogy between polyoxymethylene and cellulose, and he has shown (Z. Krist. 70, 193 (1929)) that it is possible to obtain polyoxymethylene in the form of oriented fibres, but these fibres are only a few millimetres in length andthey are very fragile- It is true also that threads or filaments can be drawn from any tough thermoplastic resin, and BritishPatent'303,867 (French equivalent 667,077) disclosesa process for making artificial silk in which a condensation product of a polyhydric alcohol and a polybasic acid or its anhydride is employed as a raw material. British' Patent 305,468 discloses a process for making synthetic fibres from a urea-formaldehyde resin. But there is nothing in the disclosures of these references to indicate that the filaments or fibres are sufilciently strong or pliable to have any utility, and insofar as I am able to ascertain, filaments or fibres'produced in accordance with the disclosures of these patents do not have any useful degree of pliability, strength, or elasticity.

Before considering in detail the objects of the -etc.). Examples are: esterification, I

ether formation,

R, OH+HO-R' R0-R' +1120; anhydride formation,

2RVCOOH- (R-CO) 2O +H20.

Condensation polymers arecompounds formed by the mutual condensation of a number of (functionally) similar molecules to form a single molecule.

cules are long chains builtup from repeating Linear polymers are compounds whose moleunits. This type of structure may be symbolized by the general formula (a) Polyesters formed by the intermolecular selfesterification of hydroxy acids, I-IORCOOH+HORCOOH (b) Polyesters formed by the action of dibasic acids on dihydric alcohols, n HOOC-R-COOH+ (n +1) HO-R'--- OH HO-R'O-(COR--COO R'-O)nH+H20, etc.;

(0) Polyamides derived from esters of amino It may be observed that each of these starting compounds contains two (and only two) functional groups capable of participating in the condensation. I call such compounds bifunctional compounds, and their reactions bifunctional reactions. My invention is concerned not with polyfunctional condensations generally, but only with bifunctional condensations. This restriction is necessary since the presence of more than two functional groups in any of the reacting compounds introduces the possibility of developing a three-dimensional polymeric structure; and this involves a. complication with which my invention is not concerned.

It is a characteristic feature of .bifunctional condensations, such as those exemplified in the general equations (a), (b), c), (d) and (e), that they present the formal possibility of producing molecules of infinite length. Thus the self-esterification of ten molecules of hydroxy acid, HO-R-CO-OH would lead to the formation of the polyester,

be expected to interrupt this progressive coupling before the molecules have grown to' any very great length. The following may be mentioned:

(1) Reaction may be intramolecular at some stage (i. e., it may lead to the formation of a ring).

(2) The terminal functional groups responsible for the progressive coupling may be lostor mutilated through side reactions LAW (3) Mechanical factors such as solubility and kinetic effects may come into play.

I have devoted considerable study, to reactions of the type defined above as bifunctional condensations and have discovered the following facts: Such reactions are usually exclusively intermolecular at every stage, and the terminal groups responsible for the initial reaction are still present at the ends of the product molecule. Interruption of the progressive coupling through intramolecular reaction (ring formation) occurs generally only through the formation of 5-atom rings, less frequently through the formation of rings of Gatoms, and rarely through the formation ofrings of '7 or 3 atoms. The loss or mutilation of terminal groups'through side reaction occurs only when patently inappropriate experimental conditions are adopted. Thus in most cases there is nothing theoretically 'to' preclude the possibility of producing exceedingly long molecules in bifunctional condensations.

It is well known that reactions such as esterification, ester interchange, amide formation, etherification, anhydride formation or acetal formation are reversible reactions, and that such reactions can be forced to completion by the separation' of the reaction products as they are formed. But from the facts outlined above it follows that if the reversible reaction isa bifunctional condensation, the degree of completeness of the reaction will regulate the size of the molecule in the polymeric product; the more nearly complete the reaction, the longer the molecule; and the reaction can be absolutely complete only'when the product molecule is infinitely long. According to the present invention reacactions of this type are brought to a degree of completeness heretofore unknown.

Ihis invention has as an object the preparation of linear condensation superpolymers, and

by this I mean linear condensation polymers capable of being formed into useful fibres. A second object is the manufacture of synthetic fibres. A third object resides in a method of propagating reversible chemical reactions involving the simultaneous formation of volatile and non-volatile products.

The first of these objects, briefly expressed, is accomplished by subjecting the linear polymers resulting from reversible bifunctional condensations to the action of heat under conditions which particularly facilitate the removal of any possible volatile reaction products. The second of these objects is accomplished by spinning or drawing filaments from a synthetic linear condensation superpolymer. The third object is accomplished by utilizing a molecular still, for removing the volatile product or products of a reaction where their effective vapor pressure is too low to be removed'by the usual distillation technique and where the non-volatile product is substantially completely non-volatile.

It may be observed that the results described herein furnish a very satisfactory verification of my theory. It is to be understood, however, that I do not desire the claims to be limited thereby inasmuch as the theory has been presented in detailmerely to make clear the nature of the invention and especially to explain the terminology used in describing it.

.For a more complete understanding of the .na

ture of theinvention and the method of carrying ii out reference may be had to the following cmuparison of the properties and methods of production of a known linear condensation polymer with my new linear condensation superpolymer made from thesame materials.

It has already been mentioned that the polyester. ethylene succinate, can be obtained by heating together succinic acid and ethylene glycol. and if the heating is finally carried out in a. good vacuum the polyester finally obtained has a molecular weight of about 3000. This material is a brittle, opaque solid which melts at about 100 C. to a very viscous liquid; it dissolves readily in certain solvents (e. g., chloroform) and can be precipitated or crystallized in the form of a dusty, white powder (microcrystalline). This material has very little utility as such. In the massive form it is rather fragile, weak, and brittle.

But now according to the present invention 1 further reaction (esterification or ester interchange) and at the same time cause a very complete and effective removal of any possible volatile products. For example, I heat this polyester at 200 C. in a molecular still, more specifically referred to hereinafter, for several days. A small amount of volatile material is removed, and the polyester which remains as a residue is found to have a much higher molecular weight (considerably higher than 10,000). It is my theory that this effect is due to a continuation of the initial bifunctional coupling, i. e., the terminal groups of the initial polyester molecules react with each other to produce still longer molecules. In any event it is a fact that the new product although it closely resembles the initial polyester in its analytical composition and chemical behavior, nevertheless differs profoundly from the initial polyester in its physical properties.

The new superpolyester is an exceedingly strong, tough, and flexible mass. It is opaque and on being heated to about 100 C. it melts, i. e., it becomes transparent, but the molten mass at this temperature is so viscous that it shows no tendency to flow. When brought into contact with solvents this material imbibes solvent and swells before dissolving, and finally yields highly viscous solutions. But the most remarkable property of the new superpolymer is its' capacity to be drawn out into fibres or threads which are pliable and strong and which have a high elastic recovery and which show evidence of a high degree of orientation along the fibre axis.

The molecular still which is referred to above, and is more fully described below, consists essentially in a highly evacuated vessel provided 'with a condenser placed at a. distance from the evaporating surface less than the mean free path of the evaporating molecules. It is to be observed that in molecular distillation, where arrangements are made for the capture of most of the escaping molecules in their first free paths, which in the specific instance above has been carried out by means of a molecular still for the production of the ethylene succinate superpolymer, the situation is radically different from ordinary distillation where the removal of the escaping molecules depends upon an appreciable vapor pressure, (as in the preparation of the known polyester ethylene succinate referred to ouent stream of vapor from the distilling surface sufficient to prevent return. Ordinary distillation thus fails as a means of displacing equilibria when the vapor pressure of the distilling substance falls to a value below that necessary to maintain a continuous stream of vapor. When this condition obtains the situation is that of a dynamic equilibrium where as many molecules are reflected back by collision and reenter the evaporating surface as escape from it. Under these conditions equilibrium will be displaced only by the relatively slow process of diifusion of the volatile product or products to a part of the apparatus from which return is impossible. When molecular distillation is carried out with a molecular still, the distillation is conducted under very low pressure with a condenser so arranged that the distance from the distilling surface to the condenser is less than the mean free path of the distilling molecules at the pressure and. temperature used. Under these conditions any molecule escaping from the distilling surface enjoys a very high probability of reaching the condenser without collision with another molecule. The condenser is maintained at such a temperature that the escaping tendency of the molecules of the distillate is negligible. A convenient form of molecular still consists of a tube or vessel in the bottom of which the distilling substance is heated, and a second tube fitting tightly into the neck of the first tube and extending therein so that the bottom of the second tube which forms the condensing surface is within the required distance from the distilling surface, provision being had for the presence of a cooling medium in the second tube and for the application of vacuum to the chamber formed by the internal walls of the first tube and the external walls of the second tube.

Apparatus useful in carrying out my invention'is illustrated in the accompanying drawing in which the single figure illustrates a form of molecular still.

In the drawing, the numeral lindicatesa spherical glass vessel closed with a stopper. 6 through which passes the neck 3 of \the condenser element 2. The condenser element 2 is provided with outlet and inlet tubes 4 and 5 for circulation of water or other cooling fluid. Leading into the spherical glass vessel 1 through the tubular portion H is a glass supporting member which carries lead wires from a suitable source of electric current to the heating element 8. The numeral 1 indicates a dish which is heated by the element 8 and which is used for holding materials from which volatile products are to be removed. The tubular portion H is provided with a tube 12 for application to a source of vacuum and with a stopper ll fitting snugly around the lower end of the member 9.

For the successful operation of molecular distillation the following conditions -must be fulfilled:

(l) The reaction mixture must be maintained at a temperature at which the rate of reaction is appreciable and the volatile product to be removed has a significant vapor pressure (10- mm. or above).

(2) The condenser must be maintained at a temperature at which the volatile product will have a negligible-vapor pressure.

(3) The pressure must be sufliciently low to render the mean free path of the distilling molethe evaporating surface to the condenser. r

The methodis or course veryflexible. temperature of both the reacting mixture and the condenser may be varied over a very wide range. The expressiorrifmean free path used herein is employed in the usual sense and may be defined as th'mean distance traveled by a molecule between successive collisions with other molecules. The value of the mean free path (L) in centimeters is given by the following formula:

r: T L 1235M? where n is the viscosity in c. g. s. units, 9 the pressure in mm; T the absolute temperature, and M the molecular weight. The following table gives values of the mean free path of mercury at various pressures at 0 C.

Pressure M. F. P.

em. 0. 75X10- mm. 0! Hg 3. 24 0. 75x10" 32. 4 0. 75x10 324.

The values for other substances will, in general, be different but of the same order of magnitude. It is advantageous to arrange the condenser at a shorter distance from the evaporating surface than the higher values of the mean free path of mercury given above, ordinarily less than 10 centimeters. The maximum distance that the condensing surface may be placed from the distilling substance depends upon the pressure used. The permissible distance is greater at very low pressures and in some instances may be as high as 20 centimeters.

While molecular distillation is not new per se as disclosed by the following references: Washburn, Bureau of Standards Journal of Research 2, 4'76, (1929); Burch, Proc. Roy. Soc. (London) 123, 271, (1929); Bronsted and Hevesy, Phil. Mag. 43, 31 (1922); and Synthetic Organic Chemicals, Eastman Kodak Co., Bulletin, Vol. II, No. 3, Feb. 1929, molecular distillation has heretofore been applied to processes involving nothing more than the separation of substances by distillation, as the separation of the isotopes of mercury, and not for the purpose of propagating chemical reactions and more particularly reversible reactions involving the simultaneous formation of volatile and non-volatile products. The principle of mass action, i. e., that when two reactants A and B react to form C and D in such a way that an equilibrium mixture of A, B, C and D is formed, the reaction may be forced to completion by constantly displacing the equilibrium by continuous removal of either C or D or both, is of course well known. This principle applies equally to reactions where only one or more than two reactants distillation technique and where the non-volatile product is substantially completely non-volatile,

tribution to chemical science. "Ihe is, however, believed to be a new and valuable con- By. conducting such a reaction under the conditions of molecular distillation, any molecules escaping from the reacting mixture are removed with a negligible probability of return, and the equilibrium consequently is irreversibly displaced. By means of the application of these principles in the present invention reversible reactions may be carried to a degree of completion hitherto unknown for the production of various new and valuable products of which the linear condensation superpolymers herein described are examples. I

The following is a more or less typical example of the method of carrying out the invention by means of a molecular still:

Example I Hexadecamethylene dicarboxylic acid and trimethylene glycol (molecular ratio 1:1.2) were heated together first at atmospheric pressure for 3 hours at C. to C. and then under 1 mm. pressure, for 7 hours at 220 C. The brittle, waxy product was crystallized from hot ethyl acetate from which it separated as a microcrystalline powder. A sample of polyester prepared in this manner (average molecular weight ca. 3500) was heated at 200 C. for '7 days in an apparatus arranged with a condenser cooled by circulating tap water 2 cm. above the distilling surface. The pressure was maintained at 10- mm. or below. The reaction proceeded with the accumulation of a small amount of low molecular weight material on the condenser. The polyester before this treatment was a microcrystalline powder; in the mass it was brittle, opaque, and very weak meconsists in heating the polymer in a molecular.

still. It is to be understood, however, that irrespective of the method of preparation my invention includes the entire class of compounds designated by the term synthetic linear condensation superpolymer, since no members of this class have been described or produced hitherto. Among the suitable methods, in addition to the use of the molecular still, by means of which the reaction may be carried out there may be mentioned the passage of an inert gas or an organic vapor through or over the molten polymer with or without the use of reduced pressure to carry away the volatile products. The reaction may also be carried out in a solvent with or without the addition of catalysts with arrangements for distilling and returning the solvent after separating the volatile products of the reaction distilling with it. The purpose may likewise sometimes be effected simply by prolonged heating in a good vacuum, and it is advantageous when using this method to have the material spread out in a thin layer. In certain cases also this purpose may be effected by using powerfully adsorbent materials such as silica gel, absorbent carbon, activated alumina, etc., to bring about the irreversible absorption of the volatile reaction products. The reaction must be carried out at a temperature high enough to make the rate of reaction appreciable but low enough to avoid 2,071,250 I anyfthermal decomposition. The use or tern-Y compounds used should be capableot forming a I peratures over 300 "C. s'is-.notvadvisable'. The

range ISO-259 C. is particularly suitable. Various types of linear polymers can be brought into the superpolymerlc state and the transformation, as in the examples mentioned, is

accompanied by a similarly remarkable change in physical properties. ,I may use, for example, compoundsselected from the following seven classes:

(1) Polyethers derived from dihydrlc alcohols such as ethylene glycol, propylene glycol, trimethylene glycol, hexamethylene glycol, etc., and

prepared either directly from these glycols or from appropriate derivatives of the glycols.

(2) Polyesters derived from hydroxy acids such as lactic acid, ---hydroxydecanoic acid, hydroxycaprolc acid, etc., and prepared either directly from the hydroxy acids or from appropriate derivatives of the hydroxy acids.

(3) Polyesters derived from dibasic acids plus glycols. As acids may be mentioned carbonic,

oxalic, succinic, glutario, adipic, pimelic, sebacic,

hexadecamethylene dicarboxylic phthalic, etc.;

as -glycols)'ethylene glycol, propylene glycol, trimethylene glycol, hexamethylene glycol, decamethylene glycol, etc. The polyesters may be prepared either directly from the acids and the glycols, or they may be prepared from some suitable derivatives of the acid and the glycols.

(4) Polyamides derived from amino acids such as S-aminocaproic acid (NH2(CH2)5COOH), 10- aminoundecanoic acid (NH2(CH2)10COOH), etc. The naming of the amino acids mentioned herein is in accordance with the system of numbering given in Organic Chemistry by Holleman, 7th Edition (1930). By amino acids I mean not only the acids themselves but also derivatives thereof inasmuch as these polyamides may be prepared either directly from the amino acids or from some suitable derivatives of the amino acids.

(5) Polyamides derived from dibasic acids plus diamines. As acids may be mentioned those referred to under (3) above, and as diamines ethylene diamine, trimethylene diamine, propylene diamine, pentamethylene diamine, benzidine, phenylene diamine, etc. By dibasic acids and diamines as used in this classification I mean not only the dibasic acids and diamines themselves but also derivatives thereof inasmuch as the polyamides maybe prepared either directly from the acids plus the diamines or from some suitable derivatives of the acids and the diamines.

(6) Polyanhydrides derived from dibasic acids, such as adlpic acid, pimelic acid, suberic acid, sebacic acid, hexadecamethylene dicarboxylic acid, etc.

(7) Polyacetals derived from hydroxy aldehydes or hydroxy ketones or from aldehydes plus glycols. As aldehydes may be mentioned acetaldehyde, propionaldehyde, butyraldehyde, benzaldehyde, etc.

I may also use mixed polymers such as mixed polyester-polyamides prepared by heating together a mixture containing a dibasic acid, a glycol, and a diamine; or a mixture containing both an hydroxy acid and an amino acid, etc. And in general I may use any polymers which result from reversible bifunctional condensations. I may of course also use any of the simple bifunctional compounds from which initial polymers are prepared, since the formation of the superpolymer involves the initial polymer as a necessary intermediate step. The only limitation necessary here is that the simple bifunctional polymer. -Thus,it is" not possible to-prepare a superpolymer from ethylene glycol and diethyl carbonate because, although these are bifunctional compounds, the ester product, ethylene carbonate, is a 5-membered monomeric ring. No polymeric product is formed, and hence no superpolymer can be obtained. On the other hand the higher glycols (tetramethylene, hexamethylene, decamethylene) do react with diethyl carbonate to form polymers (Cf. Carothers application No. 406,721) and superpolymers can be prepared either starting with these polymers or starting directly with the diethyl carbonate and the glycol.

In addition to the examples previously mentioned, the nature of the invention may be further illustrated by the following specific examples:

Example II A sample of the initial ester used in the previous example was heated at 200-250? C. for 32 hours with a current of dry nitrogen bubbling through the molten mass. The viscosity of the molten polymer increased very greatly and the product exhibited the phenomenon of colddrawing.

Eazample III Succinic acid and ethylene glycol (molecular ratio 1: 1.05) were heated together first at atmos-' pheric pressure for 3 hours at 175 C. to 185 C. and then under a good vacuum (less than 1 mm.) for about 3 hours at 200 to 250 C. The product was polymeric ethylene succinate in the form of a hard, brittle wax melting at 103 C. (See Carothers and Arvin, J; Am. Chem. Soc. 51, 2560 (1929); Carothers and Dorough, ibid., 52, 711 (1930) A sample of this polyester was heated for 7 days at 200 C. in a molecular still. The product was a tough, flexible, elastic mass which could be drawn out into elastic, strong, highly oriented fibres- Example IV w-hydroxydecanoic acid was heated at 100 for 10 hours under a moderate vacuum. The product was a non-volatile polyester in the form of a brittle wax. This material was transferred to a molecular still and heated to 200 C. for 7 days. The product was a tough, flexible, elastic polyester. Its apparent average molecular weight was about 25,000, It possessed-the property of cold-drawing", and yielded fibres which were pliable, strong, and elastic.

Example V Sebacic acid was heated under reflux for 5 hours with three times its weight of acetic anhydride. The excess acetic anhydride and the acetic acid formed in the reaction were then removed by distillation under vacuum. The brittle, waxy residue was dissolved in hot, dry benzene and precipitated with petroleum ether. The precipitate was dried in a. vacuum over potassium hydroxide. The product was polymeric sebacic anhydride in the form of adusty powder melting at 79 C. (See Voerman, Rec. trav. chim., 23, 265 (1904) A sample of the product was heated at 200 C. for several days in a molecular still. The product, unlike the initial anhydride, was a strong very tough mass which could readily be drawn into strong, pliable, highly oriented filaments. Since the chemical properties of this final product were identical with those of the initial anhydride, the profound change in physical properties must ,be ascribed to an increase in the degree of polymerization.

Example VI A polymeric amide (molecular weight ca. 1000) obtained by heating 5-aminocaproic acid was heated at 200 C. for 2 days in a molecular still. The product was a hard mass much tougher and more flexible than the initial polymer;

Example VII Example VIII Ethyl sebacate, ethylene diamine, and ethylene glycol (molecular ratio 2:1:1) were heated in a sealed tube. The powdery product from this reaction was heated at 250-300 C. in a molecular still for 5 days. The product was a very hard, tough, opaque mass whichsoftened at 290 C.

Example IX A mixture of w-hydroxydecanoic acid and 5- amino caproic acid (molecular ratio 1:1) was heated first at atmospheric pressure and then at reduced pressure. This material was converted by heating in a moleculaf still for 6 days at 200 C. into a fairly tough, elastic product which yielded fibres on cold-drawing.

Example X Trimethylene glycol, hexadecamethylene dicarboxylic acid, and 5-aminocaproic acid (molecular ratio 1:1:1) were heated together at 200-220 C. in a current of dry nitrogen until no more water was evolved. The mixture was then heated for several hours at 250-260 C. at 1 mm. pressure. The product was heated for 4 days at 200 C. in a molecular still. The product was tough and elastic and yielded strong oriented fibres. It started to soften at about 75 C.

In the following two examples the superpolymers are made by prolonged heating at reduced pressure:

Example XI Trimethylene glycol, hexadecamethylene dicarboxylic acid, and 5-aminocaproic acid (molecular ratio 121:3), were heated first at atmospheric pressure and then at reduced pressure at 200-250 C. for 6 hours. The product was very tough, fiexible, and elastic and yielded oriented fibres. It started to soften at about C.

Example XII One-half mole of sebacic acid and 0.525 mole of ethylene glycol were heated for 4 hours at 1'75200. The mixture was then subjected to heating at 250 for 5 hours at 2 mm. pressure. The product was a hard, brittle wax which was obtained in the form of a powder after crystallization from ethyl acetate. Both the wax and the powder yielded threads which could be drawn when slightly warm into fairly strong, pliable, elastic, highly oriented lustrous fibres.

Linear condensation superpolymers generally difier from ordinary linear condensation polymers in the following respects: they are more viscous when molten; they dissolve more slowly and solution is preceded by swelling; their solutions are more viscous in the massive state they are stronger, tougher, and more pliable; usually they can be drawn out into oriented threads or filaments which are very strong and pliable. The properties of linear condensation superpolymers are determined in part by the nature of the units of which their molecules are composed. The superpolyamides have high melting points and are insoluble in most of the common solvents. On the other hand, superpolyesters are less brittle, they are more readily soluble, and they usually become thermoplastic at temperatures below C.

Mixed polyester-polyamides lie between polyes ters and polyamides in their properties.

The properties which characterize the linear condensation polymers which constitute this invention adapt them to a variety of useful purposes. As mentioned above, those which have the capacity to be drawninto strong, oriented fibres are adapted to be used as artificial silk,

artificial hair bristles, threads, filaments, yarns,

strips, films, bands, and the like. Further, the

polymers of tough and elastic character may be used in plastic and elastic compositions or molding compositions, or as film forming materials. They may also be used as modifying agents for cellulose acetate or other cellulose derivatives.

The compounds covered in this invention may also be used with considerable advantage in paints, varnishes, lacquers and enamels in a number of ways. They may be used as substitutes for the resin constituent, as substitutes for the softener constituent, as substitutes for the total resin plus softener constituents, or as partial substitutes for either the resin constituent or the softener constituent in clear or pigmented lacquer compositions. They may also be used by themselves for the preparation of lacquers along with pigments in the formulation of enamel compositions. They may also be used with other resins, e. g., in mixtures with bakelite, phenol-formaldehyde, and rosin or oil modified polyhydric alcohol-polybasic acid condensation products. These latter condensation products are made, as understood by those skilled in the art, by reacting together with heat treatment a polyhydric alcohol suc h as glycerol; a polybasic acid, such as plithalic acidi"rosin; and/or a fatty oil, such as linseed oil, or the corresponding amount of oil acids. Use of the compounds disclosed in this invention in lacquer and enamel compositions imparts marked improvements in toughness, adhesion and flexibility characteristics without any appreciable sacrifice in other characteristics such as drying qualities, hardness, water resistance, thermoplasticity, and solids content. Since these compounds function as toughening and fiexibillzing agents, and since there is no chemical change in these compositions on aging, they contribute to systems in which they are used considerably improved retention of flexibility and consequentthe composition disclosed in this invention may be used either alone, in combination with cellulose derivatives such as cellulose acetate, cellulose nitrate, ethyl cellulose and benzyl cellulose; in combination with natural resins such as rosin, damar, Congo, Pontianac and Manila gums; along with synthetic-resins such-phenol-formaldehyde, urea-formaldehyde, acetone-formaldehyde, and polyhydric alcohol-polybasic acid condensation products; and in combinations with softeners such as triacetin, triphenyl phosphate, dibutyl phthalate, tricresyl phosphate, cellosolve stearate, acetyllaurin, as well as castor oil, cottonseed oil, and other vegetable oils. I

- An especially valuable and remarkable property of the synthetic compounds of the present invention resides in their capacity to be drawn into strong, flexible fibres which are in some respects, especially in their elastic properties and high ratio of wet strength to dry strength, superior to any artificial fibres that have been prepared hitherto. This capacity appears to depend upon the extraordinary facility with which the polymers of this invention accept a very highdegree of permanent orientation under. the action of mechanical stress. In the massive state at ordinary temperatures these condensation polymers are generally tough, opaque masses. The opacity is associated with a certain degree of microscopic or sub-microscopic crystallinity since the materials when examined by the usual X-ray methods furnish powder diffraction patterns and since on being heated the opacity completely dis,- appears at a definite temperature. Except in those instances in which the melting point of the polymers lies so high that melting is accompanied by decomposition threadsof these polymers are readily obtained by touching a molten specimen ability and are somewhat fragile.

with a rod and drawing the rod away. When this drawing is done very slowing the threads closely resemble the mass from which they were drawn, that is, they are opaque and show the same melting point as before. Very fine threads prepared in this way are frequently lacking in pli- However, if such threads are subjected to stretching at ordinary or slightly elevated temperatures they are profoundly changed in their physical properties. The stretching results in a permanent elongation; the original thread first separates into two sections joined by a thinner transparent section, and as the stretching continues this transparent section grows until the opaque sections are completely exhausted. The fibre produced in this way is very muchstronger than the thread from which it was drawn. It is also more pliable and elastic. Its melting point is changed and its transparency and luster increased. It exhibits a high degree of birefringence and parallel extinction between crossed Nicols prisms and furnishes a typical oriented fibre diagram when examined by X-ray methods in the usual way. This method of imparting new properties to the polymers is or spinnerette. Thus, I may prepare a solution of I the polymer either alone or together with another grams per denier and probably higher. tenacity is at least equal to the dry tenacity. The

fibreforming material such as cellulose derivatives,e. g., cellulose nitrate, cellulose acetate, ethyl cellulose, etc. in a solvent such as chloroform and extrude the solution through a fine nozzle or spinnerette into a chamber maintained at elevated temperature to accelerate the evaporation of the Such-a solution instead of being spun solvent. into a chamber containing air may also be spun directly into a liquid capable of dissolving the I solvent but not the polymer. In a similar manner many of the polymers of this invention can be spun directly in the molten state from a spinneret maintained at a suitably elevated temperature. In this case, no arrangements are necessary to provide for the. removal of solvent. Whatever method is used for spinning the fibres, it is necessary to finally submit the threads to the" action of, mechanical stress or stretching to produce the high orientation which is associated with a high degree of strength, pliability and elasticity.

series of staggered pins in a zig-zag fashion; or

it can be passed around a series of rollers where it is made to do work progressively on these rollers; or one can use any other means which are ordinarily associated with what is known in the spinning industry as methods for producing tension-spun threads or filaments. In a similar manner films, bands, strips, and the like can be formed and subjected to mechanical stretching toproduce the orientation, strength and other desirable properties already indicated.

It has already been mentioned that the fibres prepared from the materials of this invention not only have a high degree of strength, pliability and luster but they are superior to any artificial fibres known hitherto in the fact that their wet strength is substantially equal to their dry strength and in the fact that their elastic recovery resembles that of natural silk and in certain instances is even better than natural silk. A further unique property of the polymers of the present invention lies in the fact that it is possible to spin them in the form of exceedingly fine filaments. Thus it is easily possible to spin filaments as fine as V;

denier or even less and these fibres have very good properties.

The fibres produced in accordance with the following example are typical of those which can be made from the polymers disclosed in this-invention:

Example XIII The superpolymer prepared from the polyester of trimethylene glycol and hexadecamethylene dicarboxylic acid as described injExample I was dissolved in chloroform to form a solution containing 23% by weight of the polymer. The solution was extruded through a spinnerette with 0.0045 inch holes into a chamber heated to about C. The resulting fibres, after stretching or cold-drawing to the fullest extent were subjected to physical tests which yielded the following information. The dry tenacity is at least 1.1 The wet luster is good, resembling silk. The pliability is also very remarkable. It ispossible to tie hard knots in the fibre'without producing any noticeable diminution in tenacity. The fibres show very remarkable elastic recovery (true elasticity) both wet and dry, being in this respect vastly superior to rayon and, in certain instances, equal to or even better thannatural silk.

The remarkable elastic recovery characteristics of this product may be seen by a comparison of it with samples of viscose rayon and natural silk. A sample of ordinary viscose rayon was stretched 4% and held there for 1 minute after which the load was removed. In one minute it had recovered 28% of the extension. Fibres of the superpolymer submitted to the same test recovered89% in the same time. The values for wet fibres in the same test were 59% for the viscose rayon and 99% for the artificial fibre. A sample of natural silk recovered 56 dry and 50% wet.

Examples of other superpolymers which have been observed'to exhibit the property of colddrawing and the capacity to be formed into oriented fibres are those derived from: (1) polyesters derived from dibasic acids plus glycols, as ethylene succinate and ethylene sebacate in Examples III and XII; (2) polyesters derived from hydroxyacids, as w-hydroxydecanoic acid in Example IV; (3) polyanhydrides derived from dibasic acids, as polymeric sebacic anhydride in Example V; (4) mixed polymers, as w-hydroxydecanoic acid plus .5-aminocaproic acid in Example IX and trimethylene glycol plus hexadecamethylene dicarboxylic acid plus 5-aminocaproic acid in Examples IX and XI.

When selecting superpolymers for fibreformation those superpolymers should be chosen which are sufficiently soluble in some solvent to give a solution which can be spun or sufficiently thermoplastic at some temperature below their decom position temperatures to be drawn into fibres. In this connection it should be mentioned that polyamides are very much less soluble than polyesters, but they can usually be dissolved in hot phenol or hot forma'mide.

From the foregoing it will be seen that I have produced new compounds having unique properties not possessed bythe compounds from which they are prepared. The production of artificial fibres as disclosed herein through the actual synthesis of the materials from which the fibres are made is to be sharply distinguished from the manufacture of fibres (as for instance artificial silk from cellulose) from materials in which the fibre-forming molecules simply serve as the initial raw material and are not produced by synthesis. The present invention may, therefore, be regarded as the first step in the art of preparing synthetic materials suitable for making useful artificial fibres, an art, which in the sense of the present invention, has hitherto been non-existent.

As many apparently widely different embodiments of this invention may be made without departing from the spirit and scope thereof, it is to be understood that I do not limit myself to the specific embodiments thereof except as defined in functional compounds and having an average molecular weight not less than 10,000.

3. A synthetic linear condensation polymer capable of being drawn into fibres showing by characteristic X-ray patterns orientation along the fibre axis, said polymer being obtainable by condensation reaction between bifunctional compounds.

'4. A synthetic linear condensation polymer which is crystalline and fusible without decomposition and having an average molecular weight not less than 10,000.

5. A synthetic linear condensation polymer capable of being drawn from a melt thereof into fibres showing by characteristic X-ray patterns orientation along the fibre axis.

6. A synthetic linear condensation polymer which is fusible without decomposition and which is capable of being drawn into long, tough, flexible fibres showing permanent orientation along the fibre axis, said polymer in its massive state exhibiting a crystalline structure under X-ray examination.

'7. A synthetic linear condensation polymer capable of being cold drawn into oriented fibres exhibiting birefringence. with parallel extinction between crossed Nicols prisms and exhibiting characteristic fibre X-ray patterns.

8. A synthetic linear condensation polymer capable of being formed into fibres showing by characteristic X-ray patterns orientation along the fibre axis, the material comprising said polymer being selected from polymerized materials of the following classes: polyethers, polyesters, poly- Y molecular weight of said polymer is at least 10. A process which comprises carrying out bifunctional condensations under conditions which particularly facilitate the removal of volatile product from said condensation and continuing such removal of volatile product while maintaining the condensation reaction conditions until the condensation product is capable of being drawn into a continuous filament which is further capable of being cold drawn with simultaneous increase in strength and elasticity.

11. A process of producing linear condensation superpolymers which comprises maintaining a linear condensation polymer under reduced pressure and at a temperature at which the volatile product evolved from said polymer has a vapor pressure of at least 10- mm., placing a condenser within the mean free-path of the molecules of said evolved volatile product and maintaining said condenser at a temperature at which said volatile product has a negligible vapor pressure, and continuing the removal of said volatile product by said condenser until the molecular weight of the polymer is at least 10,000.

12. A process of producing linear condensation superpolymers which comprises maintaining a linear condensation polymer under a pressure of less than 0.1 mm. of mercury and at a temperature at which the volatile pr'oduct evolved from said polymer has a vapor pressure of at least 10* mm. of mercury, placing a condenser within 20 centimeters from said polymer and maintaining said condenser at a temperature at which said volatile product has a negligible vapor pressure, and continuing the removalof said volatile product by said condenser until the molecular weight of the polymer is at'l'eas 5 10,000.

13. A process for producing' linear condensation superpolyme'rs which" comprises heating a .linear condensation polymer under reduced pressure, and absorbing the volatile reaction products with an absorbent within themean free path of the molecules or the evolved volatile reaction products until the molecular weight of said polymer is at least 10,000.

14. A process of producing linear condensation superpolymers which comprises maintaining a linear condensation polymer under'a pressure of less than 0.1 mm. of mercury'and at a temperature between 150 C. and 300 C., placing a condenser within 20 centimeters from said polymer and vmaintaining said condenser at a temperature at which saidvolatile product has a negligible vapor pressure, and continuing the removal of said volatile product by said condenser until the molecular weight of the polymer is at least 10,000.

15. A process of producing linear condensation superpolymers which comprises maintaining a linear. condensation polymer under reduced pressure and at a temperature at which the volatile product evolved from said polymer has a vapor pressure of at least 10- mm., and removing the volatile product from said polymer until its molecular weight is at least 10,000 by passing a gas over said polymer.

16. A process of producing linear condensation superpolymers which comprises maintaining a linear condensation polymer under reduced pressure and atva temperature at which the volatile product evolved from said polymer has a vapor pressure of at least 10- mm., and removing the volatile product from said polymer until its molecularweight is at least 10,000 by passing a gas through said polymer.

17. A method of propagating reversible chemical reactions involving the simultaneous formation oi a volatile and, a non-volatile product which comprises placing a condenser within the mean free path of the molecules of said volatile product and maintaining said condenser under reduced pressure and at a temperature at which said volatile product has a negligible vapor pressure.

18. A method of propagating reversible chemical reactions involving the simultaneous formation of a volatile and a non-volatile product which comprises maintaining the reacting material at a temperature at which the volatile product evolved from said reacting material has a vapor pressure of at least 10- mm. of mercury, placing a condenser within 20 centimeters from the reacting material and maintaining said condenser at a temperature at which said volatile product has a negligible vapor pressure.

19. A synthetic linear condensation polymer capable of being drawn from the polymer in liquid form into filaments which are further capable oi being cold drawn at ordinary temperatures with simultaneous increase in strength, pliability, and elasticity.

20. A process for producing linear condensation superpolymers which comprises subjecting a linear condensation polymer to condensation reaction conditions at a temperature high enough to make the rate of reaction appreciable but low enough to avoid thermal decomposition while continuously removing from said polymer the volatile reaction product and continuing to maintain said conditions until the molecular weight of said polymer is at least 10,000.

21. A process of carrying out bifunctional condensationswh'ich comprises heating a linear condensation polymer under conditions that facilitate iurther condensation and maintaining such conditions until the condensation product can be drawn into fibres which are further capable of being cold drawn with simultaneous increase in strength, pliability, and elasticity.

22. A synthetic linear poly-ether having an average molecular weight not less than 10,000.

23. A synthetic linear polyester having an average molecular weight not less than 10,000.

24. A synthetic linear polyanhydride of a dibasic acid having an average molecular weight not less than 10,000.

25. A synthetic linear condensation polymer capable of being drawn into fibres which can be tied into hard knots, said polymer being obtainable by a condensation reaction between bifunctional compounds.

26. A synthetic material capable of being drawn into useful pliable fibres,said material being a synthetic linear condensation polymer obtained from bifunctional condensations.

2'7. A process for producing linear condensa tion polymers which comprises heating under condensation reaction conditions bifunctional re-. actants capable of yielding a volatile and a nonvolatile product until a polymer is formed which can be-drawn into useful pliable fibres.

28. A process for preparingflinear condensation polymers which comprises heating under condensation reaction conditions in the presence of an inert solvent bifunctional reactants capable of yielding a volatile and a non-volatile product until a polymer is formed which can be drawn into useful pliable fibres.

WALLACE H. CAROTHERS.

US548701A 1931-07-03 1931-07-03 Linear condensation polymers Expired - Lifetime US2071250A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US548701A US2071250A (en) 1931-07-03 1931-07-03 Linear condensation polymers

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US548701A US2071250A (en) 1931-07-03 1931-07-03 Linear condensation polymers
US660778A US2071251A (en) 1931-07-03 1933-03-14 Fiber and method of producing it

Publications (1)

Publication Number Publication Date
US2071250A true US2071250A (en) 1937-02-16

Family

ID=24190030

Family Applications (1)

Application Number Title Priority Date Filing Date
US548701A Expired - Lifetime US2071250A (en) 1931-07-03 1931-07-03 Linear condensation polymers

Country Status (1)

Country Link
US (1) US2071250A (en)

Cited By (300)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE739938C (en) * 1938-11-01 1943-10-11 I G Farbenindustire Ag Verstaerkungseinlagen for rubber tires
DE743825C (en) * 1940-01-03 1944-01-03 Deutsche Celluloid Fabrik A process for the production of leather substitutes, artificial leather, leather cloths, covering materials, balloon materials or flooring materials of polyamides
DE740903C (en) * 1940-09-28 1944-02-24 Ig Farbenindustrie Ag A process for the preparation of impregnations and UEberzuegen
DE743775C (en) * 1940-10-20 1944-03-31 Deutsche Celluloid Fabrik Wundpflaster
US2416041A (en) * 1940-10-21 1947-02-18 Du Pont Manufacture of coated fabric
US2423093A (en) * 1943-01-08 1947-07-01 Bell Telephone Labor Inc Ethylene glycol-isopropylene glycol-sebacic acid-aconitic acid polyester
US2423823A (en) * 1943-06-26 1947-07-15 Bell Telephone Labor Inc Cellulose ester-polyester compositions and methods of preparing them
US2430933A (en) * 1944-04-06 1947-11-18 Du Pont Thermosetting adhesives
US2430923A (en) * 1943-09-20 1947-11-18 Du Pont N-alkoxymethyl polyamides and method for obtaining same
US2433357A (en) * 1943-11-09 1947-12-30 Bell Telephone Labor Inc Vulcanizing polyester synthetic rubbers to metal bases by means of an intermediate layer of a glycerol phthalate composition
US2440965A (en) * 1943-03-19 1948-05-04 Wingfoot Corp Improved tank for hydrocarbon fuels
US2443450A (en) * 1943-07-01 1948-06-15 Du Pont Article coated with nu-alkoxymethyl polyamide and process of making same
US2448585A (en) * 1943-04-30 1948-09-07 Bell Telephone Labor Inc Organic peroxide-curable and organic peroxide-cured synthetic polyester rubbers
US2465319A (en) * 1941-07-29 1949-03-22 Du Pont Polymeric linear terephthalic esters
US2471023A (en) * 1945-12-11 1949-05-24 Ici Ltd Highly polymeric linear esters
US2475002A (en) * 1943-04-30 1949-07-05 Bell Telephone Labor Inc Stabilization of cured polymers
US2492955A (en) * 1946-08-31 1950-01-03 Shell Dev Polyoxyalkylene compounds
US2500222A (en) * 1946-10-17 1950-03-14 Armstrong Cork Co Curable alkyd resins
US2503209A (en) * 1948-01-30 1950-04-04 American Cyanamid Co Unsaturated alkyd reacted with unsaturated isocyanate
US2503251A (en) * 1945-02-16 1950-04-11 Ici Ltd Production of filaments, fibers, and the like
US2531134A (en) * 1946-03-12 1950-11-21 American Cyanamid Co Dimethyl phthalate solution of acetyl peroxide as catalyst for trifluorochloroethylene polymerization
US2533455A (en) * 1947-09-10 1950-12-12 Eastman Kodak Co Process for preparing linear condensation polymers from bis-diazodiketo alkanes
US2550650A (en) * 1945-09-19 1951-04-24 Orlan M Arnold Process of producing a plastic composition from waste nylon fibers
US2550744A (en) * 1945-07-17 1951-05-01 Publicker Ind Inc Halogen derivatives of tetrahydrophthalic acid and processes for producing same
US2551702A (en) * 1943-07-28 1951-05-08 Bata Narodni Podnik Process for the production of polyamides by polymerization of lactams
US2555062A (en) * 1948-03-24 1951-05-29 Ici Ltd Vinyl chloride polymers plasticized with plyesters
US2596272A (en) * 1947-03-27 1952-05-13 Bata Narodni Podnik Method and device for an automatic supply of low molecular raw material for continuous production and spinning of polyamides
US2617813A (en) * 1944-05-13 1952-11-11 Armour & Co Polyamides
US2628219A (en) * 1949-01-25 1953-02-10 Du Pont Process for preparing polyamides from dinitrile and ditertiary diolefin
US2628218A (en) * 1949-01-25 1953-02-10 Du Pont Process for preparing polyamides from a dinitrile and a ditertiary alcohol or ester of the last
US2628216A (en) * 1949-01-25 1953-02-10 Du Pont Process for preparing polyamides from dinitriles and disecondary alcohols or their esters
US2646413A (en) * 1946-06-24 1953-07-21 Wingfoot Corp Polyamide interpolymer plasticized with diacetin
DE897241C (en) * 1942-11-11 1953-11-19 Hans Roser Dr A process for producing artificial leather
DE766083C (en) * 1940-01-26 1954-02-01 Ig Farbenindustrie Ag Means for finishing fibrous materials
DE902967C (en) * 1942-05-27 1954-02-01 Lissmann Alkor Werk A process for the production of leather or parchment-like materials of non-woven webs
DE905066C (en) * 1946-03-29 1954-02-25 Ici Ltd u with fibers, yarns, Gewseben. like. Reinforced plastic masses
DE907129C (en) * 1940-07-20 1954-03-22 Draegerwerk Ag The production of transparent places in a murky polyamide films, especially for the production of gas masks and similar devices
US2683100A (en) * 1949-07-15 1954-07-06 Ici Ltd Copolyesters and their use for electrical insulation
US2687673A (en) * 1949-04-04 1954-08-31 Boone Philip Textile material having oriented fibers
US2695908A (en) * 1951-04-09 1954-11-30 Gen Mills Inc Polyamide composition
US2703798A (en) * 1950-05-25 1955-03-08 Commercial Solvents Corp Detergents from nu-monoalkyl-glucamines
DE767933C (en) * 1938-09-29 1955-03-10 Du Pont Od method for the production of strongly adherent metal surfaces on UEberzuegen. Like.
DE926935C (en) * 1938-09-27 1955-04-25 Du Pont A process for the production of linear polyester-polyamides
US2722524A (en) * 1951-09-24 1955-11-01 Du Pont Synthetic linear condensation polymers containing silicon
DE936522C (en) * 1940-05-02 1955-12-15 Aeg A process for the production of flexible and adherent to UEberzuegen Metallflaechen, in particular electric wires made of super polyamides
US2749329A (en) * 1951-03-30 1956-06-05 Du Pont Compositions comprising polyester plasticizers
US2786045A (en)