JP2013505929A - スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤及び殺菌剤としての使用方法 - Google Patents
スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤及び殺菌剤としての使用方法 Download PDFInfo
- Publication number
- JP2013505929A JP2013505929A JP2012530396A JP2012530396A JP2013505929A JP 2013505929 A JP2013505929 A JP 2013505929A JP 2012530396 A JP2012530396 A JP 2012530396A JP 2012530396 A JP2012530396 A JP 2012530396A JP 2013505929 A JP2013505929 A JP 2013505929A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- acid
- group
- present
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 90
- BJHZMIPASCHBRO-UHFFFAOYSA-N sulfomethaneperoxoic acid Chemical class OOC(=O)S(O)(=O)=O BJHZMIPASCHBRO-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 239000000417 fungicide Substances 0.000 title claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- 150000001875 compounds Chemical class 0.000 claims abstract description 225
- -1 sulfoperoxycarboxylic acid compound Chemical class 0.000 claims abstract description 85
- 239000000203 mixture Substances 0.000 claims description 454
- 239000002253 acid Substances 0.000 claims description 130
- 235000013305 food Nutrition 0.000 claims description 85
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 claims description 79
- 125000000217 alkyl group Chemical group 0.000 claims description 72
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 63
- CVXHBROPWMVEQO-UHFFFAOYSA-N Peroxyoctanoic acid Chemical compound CCCCCCCC(=O)OO CVXHBROPWMVEQO-UHFFFAOYSA-N 0.000 claims description 49
- 239000004094 surface-active agent Substances 0.000 claims description 46
- 239000007800 oxidant agent Substances 0.000 claims description 43
- 238000004140 cleaning Methods 0.000 claims description 41
- SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical compound OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 claims description 38
- 238000004061 bleaching Methods 0.000 claims description 38
- 238000004659 sterilization and disinfection Methods 0.000 claims description 37
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 33
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 32
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 31
- 230000001954 sterilising effect Effects 0.000 claims description 29
- 230000000844 anti-bacterial effect Effects 0.000 claims description 28
- 244000005700 microbiome Species 0.000 claims description 28
- 230000000813 microbial effect Effects 0.000 claims description 26
- 150000003839 salts Chemical class 0.000 claims description 25
- 239000002689 soil Substances 0.000 claims description 23
- 239000003381 stabilizer Substances 0.000 claims description 22
- 235000013372 meat Nutrition 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 20
- 150000002148 esters Chemical class 0.000 claims description 20
- 241000894006 Bacteria Species 0.000 claims description 19
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 19
- 229910052698 phosphorus Inorganic materials 0.000 claims description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
- 229910052739 hydrogen Inorganic materials 0.000 claims description 16
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 15
- 239000011574 phosphorus Substances 0.000 claims description 15
- 241000191967 Staphylococcus aureus Species 0.000 claims description 14
- 239000004753 textile Substances 0.000 claims description 14
- 238000011282 treatment Methods 0.000 claims description 14
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 claims description 13
- WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 claims description 12
- 125000000623 heterocyclic group Chemical group 0.000 claims description 12
- 241000700605 Viruses Species 0.000 claims description 11
- 125000002091 cationic group Chemical group 0.000 claims description 11
- 150000007942 carboxylates Chemical class 0.000 claims description 10
- 150000001735 carboxylic acids Chemical class 0.000 claims description 10
- 235000013601 eggs Nutrition 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- 230000002378 acidificating effect Effects 0.000 claims description 9
- 235000013339 cereals Nutrition 0.000 claims description 8
- 238000004806 packaging method and process Methods 0.000 claims description 7
- 244000144977 poultry Species 0.000 claims description 7
- 235000013594 poultry meat Nutrition 0.000 claims description 7
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 6
- SIOXPEMLGUPBBT-UHFFFAOYSA-N picolinic acid Chemical compound OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 claims description 6
- 241000186781 Listeria Species 0.000 claims description 5
- 241000589517 Pseudomonas aeruginosa Species 0.000 claims description 5
- 230000000855 fungicidal effect Effects 0.000 claims description 5
- 230000001590 oxidative effect Effects 0.000 claims description 5
- 241000991587 Enterovirus C Species 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims description 4
- 240000004808 Saccharomyces cerevisiae Species 0.000 claims description 4
- 241000607142 Salmonella Species 0.000 claims description 4
- 241000293869 Salmonella enterica subsp. enterica serovar Typhimurium Species 0.000 claims description 4
- 235000013311 vegetables Nutrition 0.000 claims description 4
- LXKDYNPYSBDRGE-UHFFFAOYSA-N 10-hydroxyoctadecane-9-sulfonic acid Chemical compound OC(CCCCCCCC)C(CCCCCCCC)S(=O)(=O)O LXKDYNPYSBDRGE-UHFFFAOYSA-N 0.000 claims description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 3
- 241000193755 Bacillus cereus Species 0.000 claims description 3
- 244000063299 Bacillus subtilis Species 0.000 claims description 3
- 235000014469 Bacillus subtilis Nutrition 0.000 claims description 3
- 241000589875 Campylobacter jejuni Species 0.000 claims description 3
- 241000193163 Clostridioides difficile Species 0.000 claims description 3
- RJQXTJLFIWVMTO-TYNCELHUSA-N Methicillin Chemical compound COC1=CC=CC(OC)=C1C(=O)N[C@@H]1C(=O)N2[C@@H](C(O)=O)C(C)(C)S[C@@H]21 RJQXTJLFIWVMTO-TYNCELHUSA-N 0.000 claims description 3
- 241000187479 Mycobacterium tuberculosis Species 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 3
- 235000019253 formic acid Nutrition 0.000 claims description 3
- 229960003085 meticillin Drugs 0.000 claims description 3
- 229940081066 picolinic acid Drugs 0.000 claims description 3
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 claims description 3
- 229910000342 sodium bisulfate Inorganic materials 0.000 claims description 3
- JIRHAGAOHOYLNO-UHFFFAOYSA-N (3-cyclopentyloxy-4-methoxyphenyl)methanol Chemical compound COC1=CC=C(CO)C=C1OC1CCCC1 JIRHAGAOHOYLNO-UHFFFAOYSA-N 0.000 claims description 2
- YDFDTRMRUJXHQL-UHFFFAOYSA-N CCCCCCCCC(S(O)(=O)=O)C(O)C(O)CCCCCCC Chemical compound CCCCCCCCC(S(O)(=O)=O)C(O)C(O)CCCCCCC YDFDTRMRUJXHQL-UHFFFAOYSA-N 0.000 claims description 2
- 239000004278 EU approved seasoning Substances 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- 235000021307 Triticum Nutrition 0.000 claims description 2
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 claims description 2
- 229940092714 benzenesulfonic acid Drugs 0.000 claims description 2
- QDHFHIQKOVNCNC-UHFFFAOYSA-N butane-1-sulfonic acid Chemical compound CCCCS(O)(=O)=O QDHFHIQKOVNCNC-UHFFFAOYSA-N 0.000 claims description 2
- CCIVGXIOQKPBKL-UHFFFAOYSA-M ethanesulfonate Chemical compound CCS([O-])(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-M 0.000 claims description 2
- 235000011194 food seasoning agent Nutrition 0.000 claims description 2
- 244000078673 foodborn pathogen Species 0.000 claims description 2
- 235000013622 meat product Nutrition 0.000 claims description 2
- 229940098779 methanesulfonic acid Drugs 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 150000002431 hydrogen Chemical group 0.000 claims 5
- 241000193403 Clostridium Species 0.000 claims 4
- 239000008139 complexing agent Substances 0.000 claims 4
- 241000193155 Clostridium botulinum Species 0.000 claims 2
- 241000209140 Triticum Species 0.000 claims 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 claims 1
- 150000008052 alkyl sulfonates Chemical class 0.000 claims 1
- 238000007599 discharging Methods 0.000 claims 1
- 150000003977 halocarboxylic acids Chemical class 0.000 claims 1
- QXFVHRPFJIAAOI-UHFFFAOYSA-N octadecane-8,9-diol Chemical compound CCCCCCCCCC(O)C(O)CCCCCCC QXFVHRPFJIAAOI-UHFFFAOYSA-N 0.000 claims 1
- 235000013613 poultry product Nutrition 0.000 claims 1
- KCXFHTAICRTXLI-UHFFFAOYSA-N propane-1-sulfonic acid Chemical compound CCCS(O)(=O)=O KCXFHTAICRTXLI-UHFFFAOYSA-N 0.000 claims 1
- 239000007822 coupling agent Substances 0.000 abstract description 9
- 238000003860 storage Methods 0.000 abstract description 9
- 239000003921 oil Substances 0.000 abstract description 4
- 239000003208 petroleum Substances 0.000 abstract description 4
- 239000000047 product Substances 0.000 description 98
- 239000000243 solution Substances 0.000 description 94
- 150000004965 peroxy acids Chemical class 0.000 description 93
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 82
- 238000012360 testing method Methods 0.000 description 47
- 238000002360 preparation method Methods 0.000 description 42
- 239000000645 desinfectant Substances 0.000 description 41
- 239000000463 material Substances 0.000 description 41
- 238000012545 processing Methods 0.000 description 35
- 239000007844 bleaching agent Substances 0.000 description 34
- 230000009467 reduction Effects 0.000 description 29
- 239000007787 solid Substances 0.000 description 29
- 239000000126 substance Substances 0.000 description 29
- 239000000701 coagulant Substances 0.000 description 25
- 239000004744 fabric Substances 0.000 description 24
- 238000005406 washing Methods 0.000 description 24
- 150000007513 acids Chemical class 0.000 description 23
- 235000019645 odor Nutrition 0.000 description 22
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- 230000000694 effects Effects 0.000 description 20
- 150000002889 oleic acids Chemical class 0.000 description 20
- 239000007921 spray Substances 0.000 description 20
- 235000013361 beverage Nutrition 0.000 description 19
- 239000003599 detergent Substances 0.000 description 19
- 235000014113 dietary fatty acids Nutrition 0.000 description 19
- 239000000194 fatty acid Substances 0.000 description 19
- 229930195729 fatty acid Natural products 0.000 description 19
- 229940006295 sulfonated oleic acid Drugs 0.000 description 19
- 241001465754 Metazoa Species 0.000 description 16
- 230000015572 biosynthetic process Effects 0.000 description 16
- 125000004432 carbon atom Chemical group C* 0.000 description 16
- 150000004665 fatty acids Chemical class 0.000 description 16
- 239000006260 foam Substances 0.000 description 16
- 241000196324 Embryophyta Species 0.000 description 15
- 229910052757 nitrogen Inorganic materials 0.000 description 15
- 239000002562 thickening agent Substances 0.000 description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- 239000004615 ingredient Substances 0.000 description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- 150000001412 amines Chemical class 0.000 description 13
- 239000012085 test solution Substances 0.000 description 13
- 239000002280 amphoteric surfactant Substances 0.000 description 12
- 239000002518 antifoaming agent Substances 0.000 description 12
- 239000002736 nonionic surfactant Substances 0.000 description 12
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 11
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 11
- 229910019142 PO4 Inorganic materials 0.000 description 11
- 229960003237 betaine Drugs 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
- 239000007788 liquid Substances 0.000 description 11
- 241000588724 Escherichia coli Species 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 10
- 239000012141 concentrate Substances 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 10
- 229920001223 polyethylene glycol Polymers 0.000 description 10
- 229920001296 polysiloxane Polymers 0.000 description 10
- 210000001519 tissue Anatomy 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 238000005481 NMR spectroscopy Methods 0.000 description 9
- 235000011054 acetic acid Nutrition 0.000 description 9
- 125000000129 anionic group Chemical group 0.000 description 9
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 9
- 238000005187 foaming Methods 0.000 description 9
- 239000001301 oxygen Substances 0.000 description 9
- 235000021317 phosphate Nutrition 0.000 description 9
- 239000003352 sequestering agent Substances 0.000 description 9
- 239000011734 sodium Substances 0.000 description 9
- 238000005507 spraying Methods 0.000 description 9
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 9
- 239000012224 working solution Substances 0.000 description 9
- 239000002888 zwitterionic surfactant Substances 0.000 description 9
- 229920000742 Cotton Polymers 0.000 description 8
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
- 239000002202 Polyethylene glycol Substances 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 239000003814 drug Substances 0.000 description 8
- 230000002829 reductive effect Effects 0.000 description 8
- 210000003491 skin Anatomy 0.000 description 8
- 230000003330 sporicidal effect Effects 0.000 description 8
- 239000007858 starting material Substances 0.000 description 8
- FSBGUSGSQKUNCC-UHFFFAOYSA-N 2-(1,3-dioxoisoindol-2-yl)hexaneperoxoic acid Chemical compound C1=CC=C2C(=O)N(C(CCCC)C(=O)OO)C(=O)C2=C1 FSBGUSGSQKUNCC-UHFFFAOYSA-N 0.000 description 7
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 7
- 239000003945 anionic surfactant Substances 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 7
- 238000010411 cooking Methods 0.000 description 7
- 238000001816 cooling Methods 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- 238000010790 dilution Methods 0.000 description 7
- 239000012895 dilution Substances 0.000 description 7
- 201000010099 disease Diseases 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 7
- 210000004215 spore Anatomy 0.000 description 7
- 230000000087 stabilizing effect Effects 0.000 description 7
- 125000000547 substituted alkyl group Chemical group 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 244000269722 Thea sinensis Species 0.000 description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
- 230000009471 action Effects 0.000 description 6
- 125000002252 acyl group Chemical group 0.000 description 6
- 150000008051 alkyl sulfates Chemical class 0.000 description 6
- 150000001408 amides Chemical class 0.000 description 6
- 239000003242 anti bacterial agent Substances 0.000 description 6
- 239000002738 chelating agent Substances 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 229940079593 drug Drugs 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000000499 gel Substances 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 6
- 229910052740 iodine Inorganic materials 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 229920003023 plastic Polymers 0.000 description 6
- 239000004033 plastic Substances 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- 235000013616 tea Nutrition 0.000 description 6
- 238000004448 titration Methods 0.000 description 6
- 239000000080 wetting agent Substances 0.000 description 6
- PWKXPXVKNYXHFL-UHFFFAOYSA-N 11-sulfoundecaneperoxoic acid Chemical compound OOC(=O)CCCCCCCCCCS(O)(=O)=O PWKXPXVKNYXHFL-UHFFFAOYSA-N 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 5
- 244000060011 Cocos nucifera Species 0.000 description 5
- 235000013162 Cocos nucifera Nutrition 0.000 description 5
- 102000029797 Prion Human genes 0.000 description 5
- 108091000054 Prion Proteins 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 239000002585 base Substances 0.000 description 5
- 238000010168 coupling process Methods 0.000 description 5
- 238000005859 coupling reaction Methods 0.000 description 5
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- 238000011049 filling Methods 0.000 description 5
- 230000006870 function Effects 0.000 description 5
- 230000036541 health Effects 0.000 description 5
- 239000005457 ice water Substances 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 235000013336 milk Nutrition 0.000 description 5
- 239000008267 milk Substances 0.000 description 5
- 210000004080 milk Anatomy 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 239000000344 soap Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 5
- 150000003512 tertiary amines Chemical class 0.000 description 5
- 238000010998 test method Methods 0.000 description 5
- XINQFOMFQFGGCQ-UHFFFAOYSA-L (2-dodecoxy-2-oxoethyl)-[6-[(2-dodecoxy-2-oxoethyl)-dimethylazaniumyl]hexyl]-dimethylazanium;dichloride Chemical compound [Cl-].[Cl-].CCCCCCCCCCCCOC(=O)C[N+](C)(C)CCCCCC[N+](C)(C)CC(=O)OCCCCCCCCCCCC XINQFOMFQFGGCQ-UHFFFAOYSA-L 0.000 description 4
- HODIOTABVUHCTC-UHFFFAOYSA-N 11-sulfoundecanoic acid Chemical compound OC(=O)CCCCCCCCCCS(O)(=O)=O HODIOTABVUHCTC-UHFFFAOYSA-N 0.000 description 4
- RHMQCFYVEYSOPI-UHFFFAOYSA-N 5-sulfoheptaneperoxoic acid Chemical compound CCC(S(O)(=O)=O)CCCC(=O)OO RHMQCFYVEYSOPI-UHFFFAOYSA-N 0.000 description 4
- YZVZMMPBBOKHNB-UHFFFAOYSA-N 6-sulfohexaneperoxoic acid Chemical compound OOC(=O)CCCCCS(O)(=O)=O YZVZMMPBBOKHNB-UHFFFAOYSA-N 0.000 description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 4
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 4
- 241000233866 Fungi Species 0.000 description 4
- 241000589516 Pseudomonas Species 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000013019 agitation Methods 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 239000003899 bactericide agent Substances 0.000 description 4
- 239000008280 blood Substances 0.000 description 4
- 210000004369 blood Anatomy 0.000 description 4
- 210000000988 bone and bone Anatomy 0.000 description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 125000002843 carboxylic acid group Chemical group 0.000 description 4
- 230000008878 coupling Effects 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- 238000007598 dipping method Methods 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000008233 hard water Substances 0.000 description 4
- 239000011630 iodine Substances 0.000 description 4
- 150000002924 oxiranes Chemical class 0.000 description 4
- 239000000123 paper Substances 0.000 description 4
- 244000052769 pathogen Species 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 229920001983 poloxamer Polymers 0.000 description 4
- 229920005646 polycarboxylate Polymers 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- 229960001922 sodium perborate Drugs 0.000 description 4
- 235000014214 soft drink Nutrition 0.000 description 4
- 241000894007 species Species 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 150000003871 sulfonates Chemical class 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 4
- 239000003981 vehicle Substances 0.000 description 4
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 3
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 3
- KGIFMSXKHQDDAP-UHFFFAOYSA-N 2-sulfoethaneperoxoic acid Chemical compound OOC(=O)CS(O)(=O)=O KGIFMSXKHQDDAP-UHFFFAOYSA-N 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 241000271566 Aves Species 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- 241000283690 Bos taurus Species 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 3
- 241000287828 Gallus gallus Species 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 241000286209 Phasianidae Species 0.000 description 3
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 150000004996 alkyl benzenes Chemical class 0.000 description 3
- 230000029936 alkylation Effects 0.000 description 3
- 238000005804 alkylation reaction Methods 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 235000001014 amino acid Nutrition 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- 239000004599 antimicrobial Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 244000052616 bacterial pathogen Species 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000000872 buffer Substances 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 235000013877 carbamide Nutrition 0.000 description 3
- 210000004027 cell Anatomy 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 235000010980 cellulose Nutrition 0.000 description 3
- 239000013522 chelant Substances 0.000 description 3
- 235000013330 chicken meat Nutrition 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 125000000753 cycloalkyl group Chemical group 0.000 description 3
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 125000001165 hydrophobic group Chemical group 0.000 description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 230000003472 neutralizing effect Effects 0.000 description 3
- 230000009965 odorless effect Effects 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 230000001717 pathogenic effect Effects 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 125000001453 quaternary ammonium group Chemical group 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 3
- 235000014101 wine Nutrition 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- GYSCBCSGKXNZRH-UHFFFAOYSA-N 1-benzothiophene-2-carboxamide Chemical compound C1=CC=C2SC(C(=O)N)=CC2=C1 GYSCBCSGKXNZRH-UHFFFAOYSA-N 0.000 description 2
- LHENQXAPVKABON-UHFFFAOYSA-N 1-methoxypropan-1-ol Chemical compound CCC(O)OC LHENQXAPVKABON-UHFFFAOYSA-N 0.000 description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 2
- YCBKSIKQKZLJTI-UHFFFAOYSA-N 10,11-dihydroxy-9-sulfooctadecaneperoxoic acid Chemical compound CCCCCCCC(O)C(O)C(S(O)(=O)=O)CCCCCCCC(=O)OO YCBKSIKQKZLJTI-UHFFFAOYSA-N 0.000 description 2
- YDTLSRLZPLVLEL-UHFFFAOYSA-N 10-sulfooctadecaneperoxoic acid Chemical compound CCCCCCCCC(S(O)(=O)=O)CCCCCCCCC(=O)OO YDTLSRLZPLVLEL-UHFFFAOYSA-N 0.000 description 2
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 2
- DJCYDDALXPHSHR-UHFFFAOYSA-N 2-(2-propoxyethoxy)ethanol Chemical compound CCCOCCOCCO DJCYDDALXPHSHR-UHFFFAOYSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- IVRXTYCQMSLTPC-UHFFFAOYSA-N 9-hydroxy-10-sulfooctadecaneperoxoic acid Chemical compound CCCCCCCCC(S(O)(=O)=O)C(O)CCCCCCCC(=O)OO IVRXTYCQMSLTPC-UHFFFAOYSA-N 0.000 description 2
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-M Aminoacetate Chemical compound NCC([O-])=O DHMQDGOQFOQNFH-UHFFFAOYSA-M 0.000 description 2
- 241000272517 Anseriformes Species 0.000 description 2
- 241000171738 Arthrinium Species 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 241000221955 Chaetomium Species 0.000 description 2
- 229940126062 Compound A Drugs 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N Decanoic acid Natural products CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 241000238557 Decapoda Species 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 229940120146 EDTMP Drugs 0.000 description 2
- 229920005682 EO-PO block copolymer Polymers 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 241000589248 Legionella Species 0.000 description 2
- 208000007764 Legionnaires' Disease Diseases 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 241001467552 Mycobacterium bovis BCG Species 0.000 description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
- OTGQIQQTPXJQRG-UHFFFAOYSA-N N-(octadecanoyl)ethanolamine Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCO OTGQIQQTPXJQRG-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 241001103617 Pseudomonas aeruginosa ATCC 15442 Species 0.000 description 2
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000004904 UV filter Substances 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- 125000002015 acyclic group Chemical group 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000005233 alkylalcohol group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 210000004666 bacterial spore Anatomy 0.000 description 2
- 235000020279 black tea Nutrition 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 210000001124 body fluid Anatomy 0.000 description 2
- 239000010839 body fluid Substances 0.000 description 2
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 2
- 125000002837 carbocyclic group Chemical group 0.000 description 2
- 235000014171 carbonated beverage Nutrition 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 150000001734 carboxylic acid salts Chemical class 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- JNGZXGGOCLZBFB-IVCQMTBJSA-N compound E Chemical compound N([C@@H](C)C(=O)N[C@@H]1C(N(C)C2=CC=CC=C2C(C=2C=CC=CC=2)=N1)=O)C(=O)CC1=CC(F)=CC(F)=C1 JNGZXGGOCLZBFB-IVCQMTBJSA-N 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 125000006165 cyclic alkyl group Chemical group 0.000 description 2
- 235000013365 dairy product Nutrition 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229940090960 diethylenetriamine pentamethylene phosphonic acid Drugs 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 208000035475 disorder Diseases 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 235000015177 dried meat Nutrition 0.000 description 2
- 239000003651 drinking water Substances 0.000 description 2
- 235000020188 drinking water Nutrition 0.000 description 2
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 2
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000005003 food packaging material Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 2
- 229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 2
- 239000003349 gelling agent Substances 0.000 description 2
- ZTQSADJAYQOCDD-UHFFFAOYSA-N ginsenoside-Rd2 Natural products C1CC(C2(CCC3C(C)(C)C(OC4C(C(O)C(O)C(CO)O4)O)CCC3(C)C2CC2O)C)(C)C2C1C(C)(CCC=C(C)C)OC(C(C(O)C1O)O)OC1COC1OCC(O)C(O)C1O ZTQSADJAYQOCDD-UHFFFAOYSA-N 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000002779 inactivation Effects 0.000 description 2
- 239000003317 industrial substance Substances 0.000 description 2
- 208000015181 infectious disease Diseases 0.000 description 2
- 230000002458 infectious effect Effects 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 235000008960 ketchup Nutrition 0.000 description 2
- 230000002147 killing effect Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000004811 liquid chromatography Methods 0.000 description 2
- 244000144972 livestock Species 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 150000004702 methyl esters Chemical class 0.000 description 2
- 239000000693 micelle Substances 0.000 description 2
- 230000003641 microbiacidal effect Effects 0.000 description 2
- 244000000010 microbial pathogen Species 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 210000003205 muscle Anatomy 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- 235000014571 nuts Nutrition 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 239000004006 olive oil Substances 0.000 description 2
- 235000008390 olive oil Nutrition 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 238000010979 pH adjustment Methods 0.000 description 2
- 238000009928 pasteurization Methods 0.000 description 2
- 229960003330 pentetic acid Drugs 0.000 description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 235000019260 propionic acid Nutrition 0.000 description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 2
- 235000020095 red wine Nutrition 0.000 description 2
- 238000005057 refrigeration Methods 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 238000006798 ring closing metathesis reaction Methods 0.000 description 2
- 229940071089 sarcosinate Drugs 0.000 description 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 210000002374 sebum Anatomy 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229940001584 sodium metabisulfite Drugs 0.000 description 2
- 235000010262 sodium metabisulphite Nutrition 0.000 description 2
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 2
- HRQDCDQDOPSGBR-UHFFFAOYSA-M sodium;octane-1-sulfonate Chemical compound [Na+].CCCCCCCCS([O-])(=O)=O HRQDCDQDOPSGBR-UHFFFAOYSA-M 0.000 description 2
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 2
- 239000008247 solid mixture Substances 0.000 description 2
- 239000012453 solvate Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- 125000001174 sulfone group Chemical group 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 125000004434 sulfur atom Chemical group 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 229960003080 taurine Drugs 0.000 description 2
- 201000008827 tuberculosis Diseases 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- 238000001429 visible spectrum Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- PUNFIBHMZSHFKF-KTKRTIGZSA-N (z)-henicos-12-ene-1,2,3-triol Chemical compound CCCCCCCC\C=C/CCCCCCCCC(O)C(O)CO PUNFIBHMZSHFKF-KTKRTIGZSA-N 0.000 description 1
- YNDGLMYLSGEDHX-UHFFFAOYSA-N 1,2,4,3-trioxathiane 3,3-dioxide Chemical compound O=S1(=O)OCCOO1 YNDGLMYLSGEDHX-UHFFFAOYSA-N 0.000 description 1
- UPNNXUSUOSTIIM-UHFFFAOYSA-N 1,2-dithietane Chemical compound C1CSS1 UPNNXUSUOSTIIM-UHFFFAOYSA-N 0.000 description 1
- WGYZMNBUZFHYRX-UHFFFAOYSA-N 1-(1-methoxypropan-2-yloxy)propan-2-ol Chemical compound COCC(C)OCC(C)O WGYZMNBUZFHYRX-UHFFFAOYSA-N 0.000 description 1
- YNCSEVSDNUYVAY-UHFFFAOYSA-N 1-[1-[(2-methylpropan-2-yl)oxy]propan-2-yloxy]propan-2-ol Chemical compound CC(O)COC(C)COC(C)(C)C YNCSEVSDNUYVAY-UHFFFAOYSA-N 0.000 description 1
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- IBLKWZIFZMJLFL-UHFFFAOYSA-N 1-phenoxypropan-2-ol Chemical compound CC(O)COC1=CC=CC=C1 IBLKWZIFZMJLFL-UHFFFAOYSA-N 0.000 description 1
- FENFUOGYJVOCRY-UHFFFAOYSA-N 1-propoxypropan-2-ol Chemical compound CCCOCC(C)O FENFUOGYJVOCRY-UHFFFAOYSA-N 0.000 description 1
- XBPZFKSXVYBCOW-UHFFFAOYSA-N 10,11-disulfoundecanoic acid Chemical compound OC(=O)CCCCCCCCC(S(O)(=O)=O)CS(O)(=O)=O XBPZFKSXVYBCOW-UHFFFAOYSA-N 0.000 description 1
- ZILCWPAPMSAYJU-UHFFFAOYSA-N 10-hydroxy-9-sulfooctadecaneperoxoic acid Chemical compound CCCCCCCCC(O)C(S(O)(=O)=O)CCCCCCCC(=O)OO ZILCWPAPMSAYJU-UHFFFAOYSA-N 0.000 description 1
- RQDFBKXDHPITFY-UHFFFAOYSA-N 10-hydroxy-9-sulfooctadecanoic acid Chemical compound CCCCCCCCC(O)C(S(O)(=O)=O)CCCCCCCC(O)=O RQDFBKXDHPITFY-UHFFFAOYSA-N 0.000 description 1
- NPWBEGSVYXJUMD-UHFFFAOYSA-N 10-sulfooctadecanoic acid Chemical compound CCCCCCCCC(S(O)(=O)=O)CCCCCCCCC(O)=O NPWBEGSVYXJUMD-UHFFFAOYSA-N 0.000 description 1
- JKTCBAGSMQIFNL-UHFFFAOYSA-N 2,3-dihydrofuran Chemical compound C1CC=CO1 JKTCBAGSMQIFNL-UHFFFAOYSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- WMDZKDKPYCNCDZ-UHFFFAOYSA-N 2-(2-butoxypropoxy)propan-1-ol Chemical compound CCCCOC(C)COC(C)CO WMDZKDKPYCNCDZ-UHFFFAOYSA-N 0.000 description 1
- MTVLEKBQSDTQGO-UHFFFAOYSA-N 2-(2-ethoxypropoxy)propan-1-ol Chemical compound CCOC(C)COC(C)CO MTVLEKBQSDTQGO-UHFFFAOYSA-N 0.000 description 1
- GZMAAYIALGURDQ-UHFFFAOYSA-N 2-(2-hexoxyethoxy)ethanol Chemical compound CCCCCCOCCOCCO GZMAAYIALGURDQ-UHFFFAOYSA-N 0.000 description 1
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 description 1
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 description 1
- AURFNYPOUVLIAV-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]-2-hydroxyacetic acid Chemical compound OC(=O)C(O)N(CC(O)=O)CCN(CC(O)=O)CC(O)=O AURFNYPOUVLIAV-UHFFFAOYSA-N 0.000 description 1
- TYIOVYZMKITKRO-UHFFFAOYSA-N 2-[hexadecyl(dimethyl)azaniumyl]acetate Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)CC([O-])=O TYIOVYZMKITKRO-UHFFFAOYSA-N 0.000 description 1
- UPGSWASWQBLSKZ-UHFFFAOYSA-N 2-hexoxyethanol Chemical compound CCCCCCOCCO UPGSWASWQBLSKZ-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- MUZDXNQOSGWMJJ-UHFFFAOYSA-N 2-methylprop-2-enoic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.CC(=C)C(O)=O MUZDXNQOSGWMJJ-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- 125000006325 2-propenyl amino group Chemical group [H]C([H])=C([H])C([H])([H])N([H])* 0.000 description 1
- YEYKMVJDLWJFOA-UHFFFAOYSA-N 2-propoxyethanol Chemical compound CCCOCCO YEYKMVJDLWJFOA-UHFFFAOYSA-N 0.000 description 1
- HXJOLJWKPKMVDQ-UHFFFAOYSA-N 2-sulfooctadecaneperoxoic acid Chemical compound CCCCCCCCCCCCCCCCC(S(O)(=O)=O)C(=O)OO HXJOLJWKPKMVDQ-UHFFFAOYSA-N 0.000 description 1
- OSPOJLWAJPWJTO-UHFFFAOYSA-N 3-[hexadecyl(dimethyl)azaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)CC(O)CS([O-])(=O)=O OSPOJLWAJPWJTO-UHFFFAOYSA-N 0.000 description 1
- TUBRCQBRKJXJEA-UHFFFAOYSA-N 3-[hexadecyl(dimethyl)azaniumyl]propane-1-sulfonate Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)CCCS([O-])(=O)=O TUBRCQBRKJXJEA-UHFFFAOYSA-N 0.000 description 1
- UXJZLKNQKNMGDH-UHFFFAOYSA-N 3-dodecoxy-1-hydroxy-n,n-bis(2-hydroxyethyl)propan-1-amine oxide Chemical compound CCCCCCCCCCCCOCCC(O)[N+]([O-])(CCO)CCO UXJZLKNQKNMGDH-UHFFFAOYSA-N 0.000 description 1
- VPWLFOOAVIRLEF-UHFFFAOYSA-N 3-hydroperoxy-3-oxopropanoic acid Chemical compound OOC(=O)CC(O)=O VPWLFOOAVIRLEF-UHFFFAOYSA-N 0.000 description 1
- QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 1
- HMMSZUQCCUWXRA-UHFFFAOYSA-N 4,4-dimethyl valeric acid Chemical compound CC(C)(C)CCC(O)=O HMMSZUQCCUWXRA-UHFFFAOYSA-N 0.000 description 1
- ZYLQCUXZBJFNKZ-UHFFFAOYSA-N 4-(2-hydroxyethylamino)-3-oxobutanoic acid Chemical compound OCCNCC(=O)CC(O)=O ZYLQCUXZBJFNKZ-UHFFFAOYSA-N 0.000 description 1
- ZQLDNJKHLQOJGE-UHFFFAOYSA-N 4-octylbenzoic acid Chemical compound CCCCCCCCC1=CC=C(C(O)=O)C=C1 ZQLDNJKHLQOJGE-UHFFFAOYSA-N 0.000 description 1
- JKTORXLUQLQJCM-UHFFFAOYSA-N 4-phosphonobutylphosphonic acid Chemical compound OP(O)(=O)CCCCP(O)(O)=O JKTORXLUQLQJCM-UHFFFAOYSA-N 0.000 description 1
- AWQSAIIDOMEEOD-UHFFFAOYSA-N 5,5-Dimethyl-4-(3-oxobutyl)dihydro-2(3H)-furanone Chemical compound CC(=O)CCC1CC(=O)OC1(C)C AWQSAIIDOMEEOD-UHFFFAOYSA-N 0.000 description 1
- UWQGQQYXWFQSQC-UHFFFAOYSA-N 5-[bis(2-hydroxyethyl)-octadecylazaniumyl]pentanoate Chemical compound CCCCCCCCCCCCCCCCCC[N+](CCO)(CCO)CCCCC([O-])=O UWQGQQYXWFQSQC-UHFFFAOYSA-N 0.000 description 1
- VQAMBJLPYQLDLP-UHFFFAOYSA-N 5-hydroperoxy-5-oxopentanoic acid Chemical compound OOC(=O)CCCC(O)=O VQAMBJLPYQLDLP-UHFFFAOYSA-N 0.000 description 1
- KCAZSAYYICOMMG-UHFFFAOYSA-N 6-hydroperoxy-6-oxohexanoic acid Chemical compound OOC(=O)CCCCC(O)=O KCAZSAYYICOMMG-UHFFFAOYSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 description 1
- KNSYIZORSDDYNB-UHFFFAOYSA-N 7-hydroperoxy-7-oxoheptanoic acid Chemical compound OOC(=O)CCCCCC(O)=O KNSYIZORSDDYNB-UHFFFAOYSA-N 0.000 description 1
- KJNXVXAJAABIBX-UHFFFAOYSA-N 8,9-dihydroxy-10-sulfooctadecaneperoxoic acid Chemical compound CCCCCCCCC(S(O)(=O)=O)C(O)C(O)CCCCCCC(=O)OO KJNXVXAJAABIBX-UHFFFAOYSA-N 0.000 description 1
- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 description 1
- HKPDOIFMZWCYRI-UHFFFAOYSA-N 8-hydroperoxy-8-oxooctanoic acid Chemical compound OOC(=O)CCCCCCC(O)=O HKPDOIFMZWCYRI-UHFFFAOYSA-N 0.000 description 1
- WDJHALXBUFZDSR-UHFFFAOYSA-N Acetoacetic acid Natural products CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000282979 Alces alces Species 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 238000012371 Aseptic Filling Methods 0.000 description 1
- 206010003591 Ataxia Diseases 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- 108091003079 Bovine Serum Albumin Proteins 0.000 description 1
- 208000014644 Brain disease Diseases 0.000 description 1
- 235000014698 Brassica juncea var multisecta Nutrition 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 235000006618 Brassica rapa subsp oleifera Nutrition 0.000 description 1
- 244000188595 Brassica sinapistrum Species 0.000 description 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 1
- HJEFNABTTBSBNG-UHFFFAOYSA-N C(CC)OCC(C)O.C(COCCO)O Chemical compound C(CC)OCC(C)O.C(COCCO)O HJEFNABTTBSBNG-UHFFFAOYSA-N 0.000 description 1
- OKORAVWNQQYVNK-UHFFFAOYSA-N CCCCCCCCCCCC[P+](C)(C)CCCP([O-])(O)=O Chemical compound CCCCCCCCCCCC[P+](C)(C)CCCP([O-])(O)=O OKORAVWNQQYVNK-UHFFFAOYSA-N 0.000 description 1
- 239000004343 Calcium peroxide Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 241000282994 Cervidae Species 0.000 description 1
- 241000288673 Chiroptera Species 0.000 description 1
- 241000273265 Clostridioides difficile ATCC 9689 = DSM 1296 Species 0.000 description 1
- 206010011224 Cough Diseases 0.000 description 1
- 208000020406 Creutzfeldt Jacob disease Diseases 0.000 description 1
- 208000003407 Creutzfeldt-Jakob Syndrome Diseases 0.000 description 1
- 208000010859 Creutzfeldt-Jakob disease Diseases 0.000 description 1
- 241000938605 Crocodylia Species 0.000 description 1
- 241000238424 Crustacea Species 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 241000192700 Cyanobacteria Species 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 206010012289 Dementia Diseases 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- BVTJGGGYKAMDBN-UHFFFAOYSA-N Dioxetane Chemical compound C1COO1 BVTJGGGYKAMDBN-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 241000271571 Dromaius novaehollandiae Species 0.000 description 1
- 208000012661 Dyskinesia Diseases 0.000 description 1
- 241000194029 Enterococcus hirae Species 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 241000192125 Firmicutes Species 0.000 description 1
- 241000237858 Gastropoda Species 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241000282412 Homo Species 0.000 description 1
- CODXQVBTPQLAGA-UHFFFAOYSA-N Hydroxydecanoate Chemical compound CCCCCCCCCC(=O)OO CODXQVBTPQLAGA-UHFFFAOYSA-N 0.000 description 1
- 208000015592 Involuntary movements Diseases 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 241000186779 Listeria monocytogenes Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- SPAGIJMPHSUYSE-UHFFFAOYSA-N Magnesium peroxide Chemical compound [Mg+2].[O-][O-] SPAGIJMPHSUYSE-UHFFFAOYSA-N 0.000 description 1
- 241000124008 Mammalia Species 0.000 description 1
- 229920000715 Mucilage Polymers 0.000 description 1
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 1
- 241000772415 Neovison vison Species 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 241000272458 Numididae Species 0.000 description 1
- 240000007817 Olea europaea Species 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- XEORTEPGCNJPRV-UHFFFAOYSA-N P(O)(O)=O.OC=C Chemical compound P(O)(O)=O.OC=C XEORTEPGCNJPRV-UHFFFAOYSA-N 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002534 Polyethylene Glycol 1450 Polymers 0.000 description 1
- 229920002562 Polyethylene Glycol 3350 Polymers 0.000 description 1
- 229920002571 Polyethylene Glycol 4500 Polymers 0.000 description 1
- 229920002594 Polyethylene Glycol 8000 Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 208000024777 Prion disease Diseases 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- ACCMWECVUUAYCC-UHFFFAOYSA-N S(=O)(=O)(O)C(C(=O)O)(CCCCCCCC)S(=O)(=O)O Chemical compound S(=O)(=O)(O)C(C(=O)O)(CCCCCCCC)S(=O)(=O)O ACCMWECVUUAYCC-UHFFFAOYSA-N 0.000 description 1
- VNZSHSCMYSURMS-UHFFFAOYSA-N S(=O)(=O)(O)C(CCCCCCC(=O)O)CCCCCCCCCC Chemical compound S(=O)(=O)(O)C(CCCCCCC(=O)O)CCCCCCCCCC VNZSHSCMYSURMS-UHFFFAOYSA-N 0.000 description 1
- 108010077895 Sarcosine Proteins 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 208000013738 Sleep Initiation and Maintenance disease Diseases 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 241000256215 Spongomorpha aeruginosa Species 0.000 description 1
- 206010041925 Staphylococcal infections Diseases 0.000 description 1
- 241000271567 Struthioniformes Species 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 235000006468 Thea sinensis Nutrition 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 239000013504 Triton X-100 Substances 0.000 description 1
- 229920004890 Triton X-100 Polymers 0.000 description 1
- 208000018756 Variant Creutzfeldt-Jakob disease Diseases 0.000 description 1
- 241000726445 Viroids Species 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 238000007171 acid catalysis Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 125000004442 acylamino group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 1
- 125000005194 alkoxycarbonyloxy group Chemical group 0.000 description 1
- 125000004457 alkyl amino carbonyl group Chemical group 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 125000004947 alkyl aryl amino group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000003806 alkyl carbonyl amino group Chemical group 0.000 description 1
- 125000004448 alkyl carbonyl group Chemical group 0.000 description 1
- 125000005196 alkyl carbonyloxy group Chemical group 0.000 description 1
- 125000005157 alkyl carboxy group Chemical group 0.000 description 1
- 125000004644 alkyl sulfinyl group Chemical group 0.000 description 1
- 125000004691 alkyl thio carbonyl group Chemical group 0.000 description 1
- 125000004414 alkyl thio group Chemical group 0.000 description 1
- 239000002168 alkylating agent Substances 0.000 description 1
- 229940100198 alkylating agent Drugs 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 229940040526 anhydrous sodium acetate Drugs 0.000 description 1
- 244000037640 animal pathogen Species 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 230000002365 anti-tubercular Effects 0.000 description 1
- 229940064004 antiseptic throat preparations Drugs 0.000 description 1
- 239000003443 antiviral agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000004658 aryl carbonyl amino group Chemical group 0.000 description 1
- 125000005129 aryl carbonyl group Chemical group 0.000 description 1
- 125000005199 aryl carbonyloxy group Chemical group 0.000 description 1
- 125000005110 aryl thio group Chemical group 0.000 description 1
- 125000005200 aryloxy carbonyloxy group Chemical group 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 125000000656 azaniumyl group Chemical group [H][N+]([H])([H])[*] 0.000 description 1
- HONIICLYMWZJFZ-UHFFFAOYSA-N azetidine Chemical compound C1CNC1 HONIICLYMWZJFZ-UHFFFAOYSA-N 0.000 description 1
- 235000008452 baby food Nutrition 0.000 description 1
- 244000000007 bacterial human pathogen Species 0.000 description 1
- ZJRXSAYFZMGQFP-UHFFFAOYSA-N barium peroxide Chemical compound [Ba+2].[O-][O-] ZJRXSAYFZMGQFP-UHFFFAOYSA-N 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 230000003542 behavioural effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- GONOPSZTUGRENK-UHFFFAOYSA-N benzyl(trichloro)silane Chemical compound Cl[Si](Cl)(Cl)CC1=CC=CC=C1 GONOPSZTUGRENK-UHFFFAOYSA-N 0.000 description 1
- 229940000635 beta-alanine Drugs 0.000 description 1
- UCMIRNVEIXFBKS-UHFFFAOYSA-N beta-aminopropionic acid Natural products NCCC(O)=O UCMIRNVEIXFBKS-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- 235000012206 bottled water Nutrition 0.000 description 1
- 208000005881 bovine spongiform encephalopathy Diseases 0.000 description 1
- 210000005013 brain tissue Anatomy 0.000 description 1
- 239000006172 buffering agent Substances 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- ADKBGLXGTKOWIU-UHFFFAOYSA-N butanediperoxoic acid Chemical compound OOC(=O)CCC(=O)OO ADKBGLXGTKOWIU-UHFFFAOYSA-N 0.000 description 1
- LBAYFEDWGHXMSM-UHFFFAOYSA-N butaneperoxoic acid Chemical compound CCCC(=O)OO LBAYFEDWGHXMSM-UHFFFAOYSA-N 0.000 description 1
- 125000006226 butoxyethyl group Chemical group 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- LHJQIRIGXXHNLA-UHFFFAOYSA-N calcium peroxide Chemical compound [Ca+2].[O-][O-] LHJQIRIGXXHNLA-UHFFFAOYSA-N 0.000 description 1
- 235000019402 calcium peroxide Nutrition 0.000 description 1
- 238000009924 canning Methods 0.000 description 1
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- HFNQLYDPNAZRCH-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O.OC(O)=O HFNQLYDPNAZRCH-UHFFFAOYSA-N 0.000 description 1
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical class O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
- KWEDUNSJJZVRKR-UHFFFAOYSA-N carbononitridic azide Chemical compound [N-]=[N+]=NC#N KWEDUNSJJZVRKR-UHFFFAOYSA-N 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 125000004181 carboxyalkyl group Chemical group 0.000 description 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000005779 cell damage Effects 0.000 description 1
- 208000037887 cell injury Diseases 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 235000013351 cheese Nutrition 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 229940106681 chloroacetic acid Drugs 0.000 description 1
- 230000001684 chronic effect Effects 0.000 description 1
- 239000007979 citrate buffer Substances 0.000 description 1
- 229960004106 citric acid Drugs 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 229940011182 cobalt acetate Drugs 0.000 description 1
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- NZNMSOFKMUBTKW-UHFFFAOYSA-N cyclohexanecarboxylic acid Chemical class OC(=O)C1CCCCC1 NZNMSOFKMUBTKW-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- ZRKZFNZPJKEWPC-UHFFFAOYSA-N decylamine-N,N-dimethyl-N-oxide Chemical compound CCCCCCCCCC[N+](C)(C)[O-] ZRKZFNZPJKEWPC-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000002716 delivery method Methods 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- AQEFLFZSWDEAIP-UHFFFAOYSA-N di-tert-butyl ether Chemical compound CC(C)(C)OC(C)(C)C AQEFLFZSWDEAIP-UHFFFAOYSA-N 0.000 description 1
- WOWBFOBYOAGEEA-UHFFFAOYSA-N diafenthiuron Chemical compound CC(C)C1=C(NC(=S)NC(C)(C)C)C(C(C)C)=CC(OC=2C=CC=CC=2)=C1 WOWBFOBYOAGEEA-UHFFFAOYSA-N 0.000 description 1
- 125000004663 dialkyl amino group Chemical group 0.000 description 1
- 125000004473 dialkylaminocarbonyl group Chemical group 0.000 description 1
- 125000004986 diarylamino group Chemical group 0.000 description 1
- 125000001142 dicarboxylic acid group Chemical group 0.000 description 1
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 1
- 238000003113 dilution method Methods 0.000 description 1
- ASQQEOXYFGEFKQ-UHFFFAOYSA-N dioxirane Chemical compound C1OO1 ASQQEOXYFGEFKQ-UHFFFAOYSA-N 0.000 description 1
- 239000001177 diphosphate Substances 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical class [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 description 1
- 229940047642 disodium cocoamphodiacetate Drugs 0.000 description 1
- 229940079857 disodium cocoamphodipropionate Drugs 0.000 description 1
- KJDVLQDNIBGVMR-UHFFFAOYSA-L disodium;3-[2-aminoethyl-[2-(2-carboxylatoethoxy)ethyl]amino]propanoate Chemical compound [Na+].[Na+].[O-]C(=O)CCN(CCN)CCOCCC([O-])=O KJDVLQDNIBGVMR-UHFFFAOYSA-L 0.000 description 1
- DLSFOUQNQPHSQL-UHFFFAOYSA-L disodium;cumene;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CC(C)C1=CC=CC=C1 DLSFOUQNQPHSQL-UHFFFAOYSA-L 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- 238000011067 equilibration Methods 0.000 description 1
- HQPMKSGTIOYHJT-UHFFFAOYSA-N ethane-1,2-diol;propane-1,2-diol Chemical compound OCCO.CC(O)CO HQPMKSGTIOYHJT-UHFFFAOYSA-N 0.000 description 1
- KEUKAQNPUBYCIC-UHFFFAOYSA-N ethaneperoxoic acid;hydrogen peroxide Chemical compound OO.CC(=O)OO KEUKAQNPUBYCIC-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 1
- 208000037957 feline spongiform encephalopathy Diseases 0.000 description 1
- 239000012894 fetal calf serum Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- HKIOYBQGHSTUDB-UHFFFAOYSA-N folpet Chemical group C1=CC=C2C(=O)N(SC(Cl)(Cl)Cl)C(=O)C2=C1 HKIOYBQGHSTUDB-UHFFFAOYSA-N 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 235000019249 food preservative Nutrition 0.000 description 1
- 239000005452 food preservative Substances 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 244000053095 fungal pathogen Species 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 235000014080 ginger ale Nutrition 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 229960004275 glycolic acid Drugs 0.000 description 1
- 230000009036 growth inhibition Effects 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002439 hemostatic effect Effects 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001072 heteroaryl group Chemical group 0.000 description 1
- NQUPKCJGWCPODR-UHFFFAOYSA-N hexaneperoxoic acid Chemical compound CCCCCC(=O)OO NQUPKCJGWCPODR-UHFFFAOYSA-N 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 244000052637 human pathogen Species 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 239000000416 hydrocolloid Substances 0.000 description 1
- DLINORNFHVEIFE-UHFFFAOYSA-N hydrogen peroxide;zinc Chemical compound [Zn].OO DLINORNFHVEIFE-UHFFFAOYSA-N 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 235000015243 ice cream Nutrition 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 125000002636 imidazolinyl group Chemical group 0.000 description 1
- 125000001841 imino group Chemical group [H]N=* 0.000 description 1
- 239000000411 inducer Substances 0.000 description 1
- 238000012994 industrial processing Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910003480 inorganic solid Inorganic materials 0.000 description 1
- 206010022437 insomnia Diseases 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 229940079865 intestinal antiinfectives imidazole derivative Drugs 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229960000448 lactic acid Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 229940031957 lauric acid diethanolamide Drugs 0.000 description 1
- 231100000518 lethal Toxicity 0.000 description 1
- 230000001665 lethal effect Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000012669 liquid formulation Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- HPGPEWYJWRWDTP-UHFFFAOYSA-N lithium peroxide Chemical compound [Li+].[Li+].[O-][O-] HPGPEWYJWRWDTP-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229960004995 magnesium peroxide Drugs 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229940098895 maleic acid Drugs 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 235000021577 malt beverage Nutrition 0.000 description 1
- 208000004396 mastitis Diseases 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 208000015688 methicillin-resistant staphylococcus aureus infectious disease Diseases 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- MGJXBDMLVWIYOQ-UHFFFAOYSA-N methylazanide Chemical compound [NH-]C MGJXBDMLVWIYOQ-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- CQDGTJPVBWZJAZ-UHFFFAOYSA-N monoethyl carbonate Chemical class CCOC(O)=O CQDGTJPVBWZJAZ-UHFFFAOYSA-N 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 230000017311 musculoskeletal movement, spinal reflex action Effects 0.000 description 1
- ONHFWHCMZAJCFB-UHFFFAOYSA-N myristamine oxide Chemical compound CCCCCCCCCCCCCC[N+](C)(C)[O-] ONHFWHCMZAJCFB-UHFFFAOYSA-N 0.000 description 1
- HSZXHHJDZOEAHO-UHFFFAOYSA-N n,n,10-trimethylundecan-1-amine oxide Chemical compound CC(C)CCCCCCCCC[N+](C)(C)[O-] HSZXHHJDZOEAHO-UHFFFAOYSA-N 0.000 description 1
- DZJFABDVWIPEIM-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)dodecan-1-amine oxide Chemical compound CCCCCCCCCCCC[N+]([O-])(CCO)CCO DZJFABDVWIPEIM-UHFFFAOYSA-N 0.000 description 1
- XGZOMURMPLSSKQ-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)N(CCO)CCO XGZOMURMPLSSKQ-UHFFFAOYSA-N 0.000 description 1
- DBPADWNGEAMSFC-UHFFFAOYSA-N n,n-dibutyloctadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCCCC[N+]([O-])(CCCC)CCCC DBPADWNGEAMSFC-UHFFFAOYSA-N 0.000 description 1
- OCKVXAVACGVODF-UHFFFAOYSA-N n,n-dibutyltetradecan-1-amine oxide Chemical compound CCCCCCCCCCCCCC[N+]([O-])(CCCC)CCCC OCKVXAVACGVODF-UHFFFAOYSA-N 0.000 description 1
- GORQZFWSXIRBGQ-UHFFFAOYSA-N n,n-dimethylheptadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCCC[N+](C)(C)[O-] GORQZFWSXIRBGQ-UHFFFAOYSA-N 0.000 description 1
- IBOBFGGLRNWLIL-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)[O-] IBOBFGGLRNWLIL-UHFFFAOYSA-N 0.000 description 1
- XZEZLJBGDNUAQX-UHFFFAOYSA-N n,n-dimethylnonan-1-amine oxide Chemical compound CCCCCCCCC[N+](C)(C)[O-] XZEZLJBGDNUAQX-UHFFFAOYSA-N 0.000 description 1
- UTTVXKGNTWZECK-UHFFFAOYSA-N n,n-dimethyloctadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)[O-] UTTVXKGNTWZECK-UHFFFAOYSA-N 0.000 description 1
- RSVIRMFSJVHWJV-UHFFFAOYSA-N n,n-dimethyloctan-1-amine oxide Chemical compound CCCCCCCC[N+](C)(C)[O-] RSVIRMFSJVHWJV-UHFFFAOYSA-N 0.000 description 1
- DLPZOAYAGDEIHC-UHFFFAOYSA-N n,n-dimethylpentadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCC[N+](C)(C)[O-] DLPZOAYAGDEIHC-UHFFFAOYSA-N 0.000 description 1
- VHXSGTCOHZCUKB-UHFFFAOYSA-N n,n-dimethyltridecan-1-amine oxide Chemical compound CCCCCCCCCCCCC[N+](C)(C)[O-] VHXSGTCOHZCUKB-UHFFFAOYSA-N 0.000 description 1
- KOCNEHDOMLOUNT-UHFFFAOYSA-N n,n-dipropyldodecan-1-amine oxide Chemical compound CCCCCCCCCCCC[N+]([O-])(CCC)CCC KOCNEHDOMLOUNT-UHFFFAOYSA-N 0.000 description 1
- ZLMKHKTZEMXAAJ-UHFFFAOYSA-N n,n-dipropylhexadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCC[N+]([O-])(CCC)CCC ZLMKHKTZEMXAAJ-UHFFFAOYSA-N 0.000 description 1
- FLZHCODKZSZHHW-UHFFFAOYSA-N n,n-dipropyltetradecan-1-amine oxide Chemical compound CCCCCCCCCCCCCC[N+]([O-])(CCC)CCC FLZHCODKZSZHHW-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N n-hexanoic acid Natural products CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 238000001728 nano-filtration Methods 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 210000002445 nipple Anatomy 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- KHIWWQKSHDUIBK-UHFFFAOYSA-N periodic acid Chemical compound OI(=O)(=O)=O KHIWWQKSHDUIBK-UHFFFAOYSA-N 0.000 description 1
- 229940083254 peripheral vasodilators imidazoline derivative Drugs 0.000 description 1
- 238000005502 peroxidation Methods 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-N peroxydisulfuric acid Chemical compound OS(=O)(=O)OOS(O)(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-N 0.000 description 1
- CMFNMSMUKZHDEY-UHFFFAOYSA-M peroxynitrite Chemical compound [O-]ON=O CMFNMSMUKZHDEY-UHFFFAOYSA-M 0.000 description 1
- 125000005342 perphosphate group Chemical group 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 125000001476 phosphono group Chemical group [H]OP(*)(=O)O[H] 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 230000001817 pituitary effect Effects 0.000 description 1
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 description 1
- 229920001993 poloxamer 188 Polymers 0.000 description 1
- 229920003214 poly(methacrylonitrile) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001444 polymaleic acid Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 235000015277 pork Nutrition 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229910001487 potassium perchlorate Inorganic materials 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 235000020991 processed meat Nutrition 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- CZPZWMPYEINMCF-UHFFFAOYSA-N propaneperoxoic acid Chemical compound CCC(=O)OO CZPZWMPYEINMCF-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 230000005180 public health Effects 0.000 description 1
- JKLNROLANBRABU-UHFFFAOYSA-N pyridine-2-carboxylic acid;pyridine-2,6-dicarboxylic acid Chemical compound OC(=O)C1=CC=CC=N1.OC(=O)C1=CC=CC=N1.OC(=O)C1=CC=CC(C(O)=O)=N1 JKLNROLANBRABU-UHFFFAOYSA-N 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 150000004023 quaternary phosphonium compounds Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000020995 raw meat Nutrition 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 235000021572 root beer Nutrition 0.000 description 1
- 229940043230 sarcosine Drugs 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 208000008864 scrapie Diseases 0.000 description 1
- 235000014102 seafood Nutrition 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- QBIHEHITTANFEO-UHFFFAOYSA-N sodium;tetrahydrate Chemical compound O.O.O.O.[Na] QBIHEHITTANFEO-UHFFFAOYSA-N 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 210000000278 spinal cord Anatomy 0.000 description 1
- 239000002422 sporicide Substances 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 239000008223 sterile water Substances 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- UHCGLDSRFKGERO-UHFFFAOYSA-N strontium peroxide Chemical compound [Sr+2].[O-][O-] UHCGLDSRFKGERO-UHFFFAOYSA-N 0.000 description 1
- 125000005346 substituted cycloalkyl group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 235000011044 succinic acid Nutrition 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000004026 tertiary sulfonium compounds Chemical class 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- XSROQCDVUIHRSI-UHFFFAOYSA-N thietane Chemical compound C1CSC1 XSROQCDVUIHRSI-UHFFFAOYSA-N 0.000 description 1
- VOVUARRWDCVURC-UHFFFAOYSA-N thiirane Chemical compound C1CS1 VOVUARRWDCVURC-UHFFFAOYSA-N 0.000 description 1
- 150000003553 thiiranes Chemical class 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical class CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- SJEYEFOHSMBQIX-UHFFFAOYSA-N undecane-1-sulfonic acid Chemical compound CCCCCCCCCCCS(O)(=O)=O SJEYEFOHSMBQIX-UHFFFAOYSA-N 0.000 description 1
- ZNSZAXDZPSIPQV-UHFFFAOYSA-N undecaneperoxoic acid Chemical compound CCCCCCCCCCC(=O)OO ZNSZAXDZPSIPQV-UHFFFAOYSA-N 0.000 description 1
- OZHBUVQCJMARBN-UHFFFAOYSA-N undecylamine-n,n-dimethyl-n-oxide Chemical compound CCCCCCCCCCC[N+](C)(C)[O-] OZHBUVQCJMARBN-UHFFFAOYSA-N 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical class OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 230000003612 virological effect Effects 0.000 description 1
- 210000001835 viscera Anatomy 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 235000013618 yogurt Nutrition 0.000 description 1
- 229940105296 zinc peroxide Drugs 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3945—Organic per-compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/08—Sulfonic acid halides; alpha-Hydroxy-sulfonic acids; Amino-sulfonic acids; Thiosulfonic acids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/20—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom three- or four-membered rings
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B4/00—General methods for preserving meat, sausages, fish or fish products
- A23B4/14—Preserving with chemicals not covered by groups A23B4/02 or A23B4/12
- A23B4/18—Preserving with chemicals not covered by groups A23B4/02 or A23B4/12 in the form of liquids or solids
- A23B4/20—Organic compounds; Microorganisms; Enzymes
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B5/00—Preservation of eggs or egg products
- A23B5/08—Preserving with chemicals
- A23B5/12—Preserving with chemicals in the form of liquids or solids
- A23B5/14—Organic compounds; Microorganisms; Enzymes
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/3463—Organic compounds; Microorganisms; Enzymes
- A23L3/3535—Organic compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
- C07C309/57—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing carboxyl groups bound to the carbon skeleton
- C07C309/58—Carboxylic acid groups or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
- C07C309/57—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing carboxyl groups bound to the carbon skeleton
- C07C309/60—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing carboxyl groups bound to the carbon skeleton the carbon skeleton being further substituted by singly-bound oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/42—Peroxy compounds containing sulfur atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/16—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by esterified hydroxyl radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/34—Compounds containing oxirane rings with hydrocarbon radicals, substituted by sulphur, selenium or tellurium atoms
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3472—Organic compounds containing sulfur additionally containing -COOH groups or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
-
- C11D2111/12—
Abstract
Description
本発明は、新規なスルホペルオキシカルボン酸化合物、組成物、並びにこれらの化合物の製造及び使用の方法に関係する。
本発明は、少なくとも部分的に、スルホペルオキシカルボン酸、その組成物、並びに様々な漂白、殺菌及び洗浄への応用の方法に関係する。本発明のスルホペルオキシカルボン酸はカップリング剤としても活用できる。さらに、本発明の一部の化合物はカスター、トール油、ダイズ、キャノーラ、オリーブ、落花生、獣脂、菜種、ヤシ油など非石油系再生油から抽出されている。
R1は、水素、又は置換若しくは非置換アルキル基であり;
R2は、置換又は非置換アルキル基であり;
Xは、水素、カチオン性基、又はエステル形成部分である}
で表されるスルホペルオキシカルボン酸、又はその塩若しくはエステルに関する。
一部の態様において、本発明は、式Iのスルホン酸ペルオキシカルボン酸化合物、又はその混合物に関する。本発明の組成物は、テキスタイル又は硬質面などの多様な基材及び表面の漂白組成物として使用することができる。本発明の組成物は、消毒又は抗菌組成物としても使用することができる。さらに、本発明の組成物は、食品接触殺菌、硬質面消毒、テキスタイル消毒など、様々な用途の組成物中のカップリング剤としても活用できる。一部の実施形態において、本発明の化合物を含む組成物は多目的に使用できる。つまり、本発明の組成物は、例えば、抗菌剤及び漂白剤、又はカップリング剤、及び漂白剤として機能する。
一部の態様において、本発明の組成物は化学式Iの化合物を含む。一部の実施形態において、本発明の組成物は、さらに少なくとも1種の酸化剤を含む。一部の実施形態において、本発明の組成物は実質的に酸化剤を含まない。酸化剤が存在する場合、本組成物は、例えば過酸化水素といった様々な酸化剤のいずれかを含むことがある。酸化剤は、スルホン化カルボン酸をスルホン化ペルオキシカルボン酸に変換するに足る量が存在することがある。一部の実施形態において、酸化剤は殺菌作用も有している。他の実施形態において、酸化剤の量は殺菌作用を示すのに不十分である。
一部の実施形態において、本発明の組成物は、本発明のスルホペルオキシカルボン酸を少なくとも1種、並びにカルボン酸及び/又はペルカルボン酸を少なくとも1種含む。一部の実施形態において、本発明の組成物は、カルボン酸及び/又はペルカルボン酸を少なくとも2種、少なくとも3種、又は少なくとも4種以上含む。
一部の実施形態において、本発明の組成物は界面活性剤を含む。本発明の組成物と共に使用されるのに適している界面活性剤は、非イオン界面活性剤、陰イオン界面活性剤、両イオン界面活性剤を含むが、これらに限定されるものではない。一部の実施形態において、本発明の組成物は約10重量%〜約50重量%の界面活性剤を含む。他の実施形態において、本発明の組成物は約15重量%〜約30重量%の界面活性剤を含む。さらに他の実施形態において、本発明の組成物は約25重量%の界面活性剤を含む。一部の実施形態において、本発明の組成物は約100ppm〜約1000ppmの界面活性剤を含む。
本発明の組成物との使用に適した適切な非イオン界面活性剤は、アルコキシレート界面活性剤を含む。適切なアルコキシレート界面活性剤は、EO/POコポリマー、キャッピングされたEO/POコポリマー、アルコール・アルコキシレート、キャッピングされたアルコール・アルコキシレート、その混合物などを含む。溶媒としての使用に適したアルコキシレート界面活性剤は、プルロニック及びリバース・プルロニック界面活性剤のようなEO/POブロック・コポリマー、Dehypon LS−54(R−(EO)5(PO)4)及びDehypon LS−36(R−(EO)3(PO)6)のようなアルコール・アルコキシレート、プルラファックLF211及びTegoten EC11のようなキャッピングされたアルコール・アルコキシレート、その混合物などを含む。
半極性タイプの非イオン界面活性剤は、本発明の組成において有用な非イオン界面活性剤の別の種類である。半極非イオン界面活性剤は、アミンオキシド、ホスフィンオキシド、スルホオキシド及びそれらのアルコキシレート誘導体を含む。
に一致する三級アミンオキシドである。一般的に、洗剤分野でのアミンオキシドでは、R1は、約8〜約24個の炭素原子のアルキル基であり、R2及びR3は、1〜3個の炭素原子のアルキル若しくはヒドロキシアルキル、又はその混合物である。R2及びR3は、環構造を形成するために、酸素や窒素原子を介して、互いに結合することができる。R4は、2個〜3個の炭素原子を含むアルキレン又はヒドロキシアルキレン基である。また、nの範囲は0〜約20である。アミンオキシドは対応するアミン、及び過酸化水素のような酸化剤から生成される。
本組成物での使用に適した陰イオン硫酸塩界面活性剤は、アルキルエーテル硫酸塩、アルキル硫酸塩、直鎖及び分岐鎖第一及び第二アルキル硫酸塩、アルキルエトキシ硫酸塩、脂肪族オレイルグリセロール硫酸塩、アルキルフェノールエチレンオキシドエーテル硫酸塩、C5〜C17アシル−N−(C1〜C4アルキル)及び−N−(C1〜C2ヒドロキシアルキル)グルカミン硫酸塩、及びアルキルポリグルコシドの硫酸塩のようなアルキル多糖類の硫酸塩などを含む。さらには、アルキル硫酸塩、アルキルポリ(エチレンオキシ)エーテル硫酸塩、及び硫酸塩又はエチレンオキシドの縮合製品、及びノニルフェノール(通常1分子当たり1〜6個のオキシエチレン基をもつ)のような芳香族ポリ(エチレンオキシ)硫酸塩も含まれる。
R−O−(CH2CH2O)n(CH2)m−CO2X (3)
{式中、Rは、C8〜C22アルキル基、又は
で表されるアルキル又はアルキルアリールエトキシカルボン酸塩を含む一部の実施形態において、nは、4〜10の整数であり、そしてmは1である。一部の実施形態において、Rは、C8〜C16アルキル基である。一部の実施形態において、Rは、C12〜C14アルキル基であり、nは4であり、そしてmは1である。
両性又は両性電解質の界面活性剤は塩基及び酸性親水基と、有機疎水基のいずれも含む。これらのイオン的実体は、本明細書で他のタイプの界面活性剤として記述される、陰イオン又はカチオン性基のいずれかであり得る。塩基窒素及び酸性カルボン酸塩の基は、塩基及び酸性親水基として働く典型的な官能基である。数種の界面活性剤では、スルホン酸塩、硫酸塩、ホスホン酸塩、又はリン酸塩は負電荷を供給する。
をもつ。本組成物で使用され、市販製品の中でも有名なイミダゾリン由来の両性剤には、以下の例:ココアンフォプロピオネート、ココアンフォカルボン酸−プロピオネート、ココアンフォグリシネート、ココアンフォカルボン酸−グリシネート、ココアンフォプロピル−スルホン酸塩、ココアンフォカルボン酸−プロピオン酸が含まれる。アンフォカルボン酸は、アンフォジカルボン酸のジカルボン酸官能基がアセト酢酸及び/又はジプロピオン酸である脂肪族イミダゾリンから生成される。
両イオン界面活性剤は、両性界面活性剤のサブセットと考えられ、陰イオン電荷を含む。両イオン界面活性剤は広義には、二級及び三級アミンの誘導体、ヘテロ環式二級及び三級アミンの誘導体、又は四級アンモニウム、四級ホスホニウム、又は三級スルホニウム化合物として記述できる。典型的には、両イオン界面活性剤は、正電荷の四級アンモニウム、又は一部の事例においては、スルホニウム又はホスホニウムイオン、負電荷のカルボキシル基、及びアルキル基を含む。両イオン剤は一般的に、分子の等電域とほぼ同程度までイオン化し、かつ正・負電荷の中心間で強い「分子内部でできる塩」の引力を作り出せる、カチオン性基及びアニオン基を含む。このような両イオン合成界面活性剤の例は、脂肪族四級アンモニウム、ホスホニウム、及びスルホニウムの化合物の誘導体として記述されるが、その脂肪族基は、直鎖でも分岐鎖でもよく、またその脂肪族置換基の1つは、8〜18個の炭素原子を含み、またそれは、例えば、カルボキシル基、スルホン酸塩、硫酸塩、リン酸塩、ホスホン酸塩などのアニオン性水溶性基を含む。ベタイン及びスルタイン界面活性剤は、本明細書で使用される代表的な両イオン界面活性剤である。
の通りである。
一部の実施形態において、本発明の組成物は、他の追加成分を含む。本発明の組成物との使用に適している追加成分としては、酸味料、キレート剤若しくは金属イオン封鎖剤などの安定化剤、緩衝剤、洗浄剤、湿潤剤、消泡剤、増粘剤、発泡剤、凝固剤、外観改良剤(着色剤、着臭剤、香料など)、その他の洗浄剤が挙げられるが、これらに限定されるものではない。これらの追加成分は、本発明の組成物の追加の前後又は実質的に同時に、本発明の組成物に添加することで、前もって配合することができる。さらに組成物は、一つ又はそれ以上のアルカリ洗剤など従来の洗浄剤と組み合わせて使用できる。
一部の実施形態において、本発明の組成物は酸味料を含む。酸味料はカルボン酸のペルオキシカルボン酸への変換において触媒として作用する。酸味料は、約1又はそれ以下のpHで有効な濃縮組成物を形成する。酸味料は、pHが約5、約5以下、約4、約4以下、約3、約3以下、約2、約2以下で使用組成物を形成させると有効である。一部の実施形態において、酸味料は、アルカリ洗剤溶液のpHを約10、約10以下、約9、約9以下、約8、約8以下、約7、約7以下、約6、約6以下に下げるために使用される。一つの実施形態において、酸味料は無機酸を含む。適切な無機酸は、硫酸、硫酸水素ナトリウム、リン酸、硝酸、塩酸を含むが、これらに限定されるものではない。一部の実施形態において、酸味料は有機酸を含む。適合する有機酸には、メタンスルホン酸、エタンスルホン酸、ブタンスルホン酸、キシレンスルホン酸、ベンゼンスルホン酸、ギ酸、酢酸、モノ、ジ、トリ−ハロゲン化炭化水素酸、ピコリン酸、ジピコリン酸、及びその混合物が含まれるが、これらに限定されるものではない。一部の実施形態において、本発明の組成物は、リンを主成分とする酸を含まないか、又は実質的に含まない。
一部の実施形態において、本発明の組成物は、一つ又はそれ以上の安定化剤を含む。安定化剤は、例えば、過酸及び過酸化水素の安定化、ならびに本発明の組成物中における同成分の早期酸化防止に使用される。
本発明の組成物では、湿潤剤及び消泡剤も有用である。湿潤剤は、本発明の組成物の面接触又は浸透活性を増大させる働きをする。本発明の組成物で使用される湿潤剤は、当業者の間では本発明の組成物の面活性を増大させることが知られている、これら成分のいずれかを含む。
本発明の組成物は、既知の各種増粘剤のいずれかを含むことができる。適切な増粘剤は、キサンタンガム、グアルガム、植物粘質物から形成されるその他のガムをはじめとする天然ガムと、アルギン酸塩、デンプン、セルロースポリマー(例えばカルボキシメチルセルロース)といった多糖類系増粘剤と、ポリアクリラート増粘剤と、ペクチンのようなヒドロコロイド増粘剤などを含む。ある実施形態において、増粘剤は対象物の面上に汚れの原因となる残留物を残さない。例えば、増粘剤又はゲル化剤は、接触部において、食品又は影響を受けやすいその他製品との融和性をもつ。一般的に、本組成物又は本方法で用いられる増粘剤の濃度は、最終組成物で求められる粘度により決定されることになる。しかしながら、一般的なガイドラインでは、本組成物での増粘剤の粘度は約0.1重量%〜約5重量%、約0.1重量%〜約1.0重量%、約0.1重量%〜約0.5重量%と多岐にわたる。
本発明の組成物は、組成物を固体状に保持するために寄与することができる凝固剤を含むことができる。一部の実施形態において、凝固剤は組成物を固体に形成するか、又はその状態を保持することができる。他の実施形態において、スルホン化ペルオキシカルボン酸の最終的な放出に容認し難い減損がなければ、凝固剤は組成物を固体化させることができる。凝固剤は、例えば、中性不活性特性を有するか、又は本組成物の機能性、安定性又は洗浄性に寄与する有機又は無機固形化合物を含むことができる。適合する凝固剤は、固形ポリエチレングリコール(PEG)、固形ポリプロピレングリコール、固形EO/POブロックコポリマー、アミド、尿素(カルバミドとしても知られる)、非イオン界面活性剤(結合剤と共に用いられる)、陰イオン界面活性剤、水溶化デンプン(例えば、酸又はアルカリ処理工程を経たもの)、水溶化セルロース、無機剤、ポリエチレン(無水マレイン酸/メチルビニルエーテル)、ポリメタクリル酸、その他一般的な高融点機能性又は不活性材料、その混合物などを含む。
一部の実施形態において、本発明の組成物は担体を含む。担体は、組成物の他の成分を溶解、懸濁、又は担持する媒体となる。例えば、担体は、スルホン化ペルオキシカルボン酸の溶解、懸濁、生成の媒体に、また平衡混合物の形成の媒体になる。担体は、対象物上に本発明の組成物を送達し、湿潤させるために機能することもできる。この目的のため、担体はこれらの機能を促進できる1種又は複数の成分をいずれも含み得る。
本発明の組成物は、濃縮組成物及び使用組成物を含む。例えば、濃縮組成物は使用組成物にするために水などで希釈することができる。ある実施形態において、濃縮組成物は対象物に適用する前に、使用溶液まで希釈することができる。経済性の観点から、濃縮物は市場性があり、エンドユーザーが濃縮物を水又は水性希釈剤で希釈し、使用溶液を形成することができる。
一部の態様において、本発明は、本発明のスルホペルオキシカルボン酸化合物及び組成物の使用方法を含む。一部の実施形態において、これらの方法は、スルホペルオキシカルボン酸の抗菌及び/又は漂白活性を利用する。例えば、本発明は、病原菌群を減少させる方法、皮膚上の微生物群を減少させる方法、皮膚病を治療する方法、臭気を減らす方法、及び/又は漂白の方法を含む。これらの方法は、物品、面、水域又は気体域などに作用を及ぼすことができるが、それは物品、面、物体、気流に本発明のスルホペルオキシカルボン酸化合物又は組成物が接触することによる。接触には本発明の化合物又は組成物を適用する多くの方法、例えば、化合物又は組成物の噴霧、化合物又は組成物中への物品の浸漬、物品に対する化合物又は組成物の泡又はゲル処理、又はそれらの組み合わせのいずれかが含まれる。
一部の態様において、また、化合物及び組成物は、汚れてしまったテキスタイル製品などの殺菌に利用される。製品は、約4℃〜80℃の範囲の使用温度で、殺菌、消毒、滅菌に充分効果のある時間だけ本発明の化合物と接触させられる。一部の実施形態において、本発明の化合物は、約30℃〜約50℃又は約40℃の温度で製品を漂白及び/又は殺菌するために使用されることができる。例えば、一部の実施形態において、本発明の化合物は、洗濯機の洗浄又はすすぎ水に投入され、汚れのある布帛に殺菌効果をもたらす時間だけ接触させられる。一部の実施形態において、約5〜約30分間、本発明の化合物及び組成物に汚れのある布帛を接触させる。余分な溶液は、その後にすすぎ又は遠心脱水により除去されることができる。
本発明の化合物のための他の硬質面洗浄用途としては、定置洗浄装置(CIP)、分解洗浄装置(COP)、洗浄機−除染機、滅菌器、織物洗濯機、超濾過及びナノ濾過装置、並びに屋内エアフィルターが挙げられる。COP装置には、洗浄槽、浸漬容器、モップバケツ、汚水槽、洗浄シンク、車輌部品洗浄機、間欠洗浄機及び装置などの容易に分解移動ができる装置が含まれる。CIP装置には、飲料、牛乳、ジュースといった主に液体製品の加工工程で使用される槽、ライン、ポンプ、その他の加工設備の内部部品が含まれる。
一部の態様において、本発明は、この化合物又は組成物の利用に適した方法又は器具を用いて、食品とスルホペルオキシカルボン酸化合物又は組成物との接触の方法を提供する。例えば、一部の実施形態において、化合物の噴霧、化合物への浸漬、化合物の泡沫又はゲル処理によって、食品は本発明の化合物と接触する。噴霧、泡沫、ゲル及び浸漬による接触は、食品への殺菌剤利用として当業者間で周知の様々な方法で行われる。耕地、加工場又は加工設備、車輌、倉庫、商店、レストラン、家庭など、食品が存在する場所であればどこでも、食品との接触は起こり得る。同様の方法は、本発明の化合物の対象物への適用に合わせて調整することもできる。
本発明のスルホペルオキシカルボン酸化合物及び組成物は、フルーツジュース、乳製品、麦芽飲料、ダイズを原料とする製品、ヨーグルト、乳児用食品、瓶詰め水製品、紅茶、咳止め、医薬部外品、ソフトドリンクをはじめとする飲料、食品、医薬材料の製造で使用される。本発明の化合物は、殺菌するか、消毒するか、殺胞子剤として機能するか、又はこのような飲料製造で使用される瓶、ポンプ、パイプライン、タンク、混合用機器を滅菌するために使用される。さらに、本発明のスルホペルオキシカルボン酸殺菌化合物は、充填前に殺菌もしくは滅菌される食品、飲料、医薬部外品の容器内への無菌冷却充填操作において使用される。このような操作では、容器は、殺菌スルホペルオキシカルボン酸化合物と接触させられるが、おもに噴霧、浸漬、充填用装置を使用して、微生物を低減させるのに有効な時間に亘って、容器内部に直接スルホペルオキシカルボン酸化合物を接触させる。その後、使用した殺菌剤又は抗菌剤をすべて排出し、容器を空にする。空にした容器は、飲料水又は滅菌水で濯ぎ、再度空にする。濯ぎの後、容器は飲料、食品、医薬部外品を充填される。容器は密閉されてから、最終的な販売に向けた出荷用に包装される。密閉された容器は、追加された菌を殺菌するために、高圧殺菌又は滅菌することもできる。
スルホン化ペルオレイン酸製品を含む本組成物の化合物の安定性を評価するため、高水準滅菌(HLD)条件下、既知の市販消毒剤と比較して、ペルオキシオクタン酸(POOA)の安定性実験を実施した。
漂白剤としての本発明の化合物の使用を評価した。人為的に汚した布帛材料を洗浄することにより、洗浄組成物の汚れ除去能力を測定した。汚れをつけるための布帛材料は、製造者又は供給者(例えば、テスト・ファブリック(Test Fabrics)社、ペンシルバニア州West Pittston)から購入した。オリーブ油、皮脂、化粧品、ワインなどの汚れの種類は、洗濯用途で見られる典型的な自然の汚れである。
SR=((L最終−L初期)/(96−L初期))×100%
1.Y−値はMinolta CM−2610d分光光度計によって計算された反射率値に基づく。Hunter Lab.の分光光度計によって計算されたL−値に非常に近似する。
2.Triplexエマルションはイーコラブ社(欧州)製の界面活性剤を混合乳化させた、市販アルカリ性金属キレートのオールインワンエマルションである。
3.Turbo Usonaはイーコラブ社(欧州)製の界面活性剤を混合乳化させた、市販アルカリ性金属キレートのオールインワンエマルションである。
4.Ozonit Superはイーコラブ社(欧州)製の過酸−過酸化水素漂白消毒剤である。
5.Oxysanはペルオキシオクタン酸も含む、イーコラブ社(欧州)製の過酸−過酸化水素漂白消毒剤である。
CO:綿
PES/CO:ポリエステル・綿混紡
漂白試験は、本発明のスルホペルオキシカルボン酸を含む組成物、つまり11−スルホウンデカンペルオキシ酸(化合物D)と、以下の市販漂白/洗浄組成物を比較しながら行なった。それは、イーコラブ社から発売されているTsunami100(登録商標)、イーコラブ社から発売されているOxonia Active(登録商標)、ソルベイ(Solvay)社から発売されている過酸化水素(35%)及びPAP−70(登録商標)である。これらの薬剤は、重炭酸ナトリウムを使ったpH8へのpH調整と、水酸化ナトリウムの添加によるpH12へのpH調整を除き、5グレインの硬水に対してそのまま使用された。
本発明のスルホペルオキシカルボン酸、つまり11−スルホウンデカンペルオキシ酸(化合物D)の安定性を、フタルイミドペルオキシヘキサノン酸(PAP)の安定性と比較した。PAPサンプルの安定性データは、クラリアント社に付与された米国特許第5,994,284号から得た。本発明の化合物のサンプルを様々な温度で4週間保存した。活性酸素の損失を滴定分析によって測定した。その結果を下表に示す。
本発明の組成物の漂白特性と、以下の市販漂白剤を比較する形で試験を行なった。それは、イーコラブ社から発売されているOzonit(登録商標)、及びクラリアント社から発売されているPAP(登録商標)である。以下の本発明の化合物を使用した:調製物Aは、25重量%のスルホン化ペルオレイン酸製品、約70重量%のH2O2(35%)、及び約5重量%のHEDP60を含む。調製物Bは、スルホン化ペルオレイン酸製品とペルオキシオクタン酸の約24重量%の混合物、約72重量%のH2O2(35%)、及び約4重量%のHEDP60を含む。調製物Cは、スルホン化ペルオレイン酸製品とペルオキシオクタン酸の約20重量%の混合物、約62重量%のH2O2(35%)、約4重量%のHEDP60、及び約13重量%の酢酸を含む。40℃の温度にて、pH7〜8で、これらの調製物を市販の漂白剤と比較した。Ozonit Rも60℃で試験した。
(a)殺微生物効力
本発明に準じた組成の殺微生物効力を測定するため、界面活性剤の有無で、他の市販製品との比較により実験を行った。調製物Aは、約1190ppmのスルホン化ペルオレイン酸製品、同量のペルオキシオクタン酸及び過酢酸を含む。この実施例で使用された界面活性剤は、イーコラブ社から発売されているTurboemulsionR(TE)である。組成物は、クロストリジウム・ディフィシレ(Clostridium difficile)ATCC9689、MRSA ATCC33592、腸内連鎖球菌(Enterococcus hirae)ATCC10541、大腸菌(Escheria coli)ATCC11229、及び緑膿菌(Pseudomonas aeruginosa)ATCC15442に対して、5分及び60分の暴露時間で試験された。市販の組成物、Ozonit(登録商標)、及びPAPも試験した。以下の処方を試験した。
試験を行なって、胞子に対する本発明の組成物の安定性及び殺胞子効力を測定した。試験された組成物には、スルホン化ペルオレイン酸製品、及びかなりの量のペルオキシオクタン酸が含まれていた。使用された試験方法は、欧州規格EN13704:上述の、食品、産業、家庭、施設区域で使用される化学消毒剤及び防腐剤の殺胞子活性評価のための定量浮遊液試験であった。下表はこの研究の結果を示している。
この研究のために、ASME1052−96:浮遊液中のウィルスに対する殺菌剤の有効性標準試験法を使用した。1000ppmのペルオキシ酢酸(POAA)を含む組成物を、単独、及びスルホン化ペルオレイン酸製品との組み合わせにおいて試験した。
この研究のために、MS103:定量抗結核菌試験を使用した。スルホン化ペルオレイン酸製品は、単独及びペルオキシオクタン酸との組み合わせで、様々な濃度において、ウシ型結核菌(Mycobacterium bovis)BCGに対し試験された。pH6.5、室温にて組成物を試験した。その結果を下表に示す。
この試験では、AOAC公式方法955.15−黄色ブドウ球菌(Staphylococcus aureus)に対する消毒剤試験、及びAOAC公式方法964.02−緑膿菌(Pseudomonas aeruginosa)に対する消毒剤試験を使用した。使用された組成物は、様々な濃度で、スルホン化ペルオレイン酸製品、及びペルオキシオクタン酸(POOA)を含んでいた。以下の表に、使用された試験手順及びその結果を要約する。
スルホン化ペルオレイン酸製品を含む本発明の組成物がオクタン酸を結合させる能力について、2種の既知の市販カップリング剤、NAS及び直鎖アルキルベンゼンスルホン酸塩(LAS)を比較した。
過酸の形成において、カルボン酸上のスルホン基の位置が与える影響を測定するため、研究が行われた。具体的には、研究目的は、α位にスルホン基が存在することで、対応するペルオキシカルボン酸を形成するためのカルボン酸基の酸化及び/又は過加水分解が妨げられるかどうかを評価することにあった。
研究を行って、定置洗浄法で用いられる殺菌剤としての、本発明の組成物の有効性を測定した。約5.85重量%のスルホン化ペルオレイン酸製品、約11.6%の過酸化水素、約1重量%のキレート剤、約12.75重量%のH2SO4、約13.6重量%のNAS−FAL(オクタンスルホン酸ナトリウム)、及び約1.5重量%のSXS(ステパン社から発売)を含む組成物を調合した。合成硬水を使用して、求められる過酸濃度まで試験組成物を希釈した。過酸を1000ppm、750ppm、500ppmの濃度で試験した。使用溶液のpHは以下の通りであった。
試験を行って、選ばれた本発明の組成物と、市販の界面活性剤を含む組成物を比較して、発泡特性を測定した。次の組成物:50ppmスルホン化ペルオレイン酸製品を含むpH2.48の調製物Aと、50ppmスルホン化ペルオレイン酸製品を含むpH6.75の調製物Bと、64ppmの市販のスルホン化オレイン酸(SOA)(アクゾノーベル(Akzo Nobel)社から発売されているLankropol OPA(50%))を含むpH2.48の調製物Cと、64ppmの市販のスルホン化オレイン酸(アクゾノーベル社から発売されているLankropol OPA(50%))を含むpH6.56の調製物Dと、128ppmの市販のスルホン化オレイン酸(アクゾノーベル社から発売されているLankropol OPA(50%))を含むpH2.48の調製物Eと、128ppmの市販のスルホン化オレイン酸(アクゾノーベル社から発売されているLankropol OPA(50%))を含むpH7.20の調製物Fと、93ppmのオクタンスルホン酸ナトリウム(NAS)(イーコラブ社から発売)を含むpH2.48の調製物Gを準備した。以下の方法を使用して泡の高さを測定した。まず、3000mlの各調製物を調合して、Glewweシリンダに静かに注いだ。定規をシリンダ側面に取り付け、溶液を定規の一番下に合わせた。ポンプを作動させた。定規と一致した泡の平均レベルを読み取り、泡の高さを評価した。泡の高さの読み取りは、ストップウォッチ又はタイマーを使用して、時間に対して行った。ポンプを停止し、泡の高さをそれぞれの時間で記録した。その結果を下表に示す。
研究を行なって、洗濯物の殺菌に対する本発明の組成物の能力を測定した。スルホン化ペルオレイン酸を含む組成物を、市販の洗浄組成物であるOzonit(登録商標)(イーコラブ社から発売)及びPAP−70(登録商標)(ソルベイ(Solvay)社から発売)に対して試験した。黄色ブドウ球菌(Staphylococcus aureus)ATCC6538及び緑膿菌(Pseudomonas aeruginosa)ATCC15442に対して、組成物を104°Fで6分間試験した。試験方法は以下の通りである。300gの炭酸ナトリウム及び1.5gの非イオン系湿潤剤(例えば、Triton X−100)を含む熱湯で布帛サンプルを濯いだ後、すべての目視できる痕跡が取り除かれるまで冷水で濯いだ。布帛サンプルを完全に乾燥させた。その後、布帛サンプルを滅菌のため高圧消毒した。
水溶液中における種々のスルホン化過酸の安定性を決定するために研究を行った。スルホン化過酸は、選択された過酸の構造的相違がどのように安定性に影響を与えるかを決定するために同じく調節された条件下で比較された。研究されたスルホン化過酸には、中鎖スルホン化過酸及び末端スルホン化過酸の両方が含まれた。
水溶液における種々のスルホン化ペルカルボン酸の漂白特性を測定するために研究を行った。スルホン化過酸は、界面活性剤/ビルダーのみの対照、並びにペルオキシ酢酸と比較された。
水溶液中における種々のスルホン化過酸のカップリング/屈水性を決定するために研究を行った。オクタン酸をカップリングする選択された過酸の能力を測定した。
異なる表面上の個々の溶液の接触角を測定することによって、水溶液中における種々のスルホン化過酸の湿潤性を測定するために研究を行った。
種々のスルホン化過酸の抗菌効果を決定するために研究を行った。以下のペルスルホン化酸:2−スルホペルオキシ酢酸(2−SPOAA);5−スルホペルオキシヘプタン酸(5−SPOHA);6−スルホペルオキシヘキサン酸(6−SPOHXA);11−スルホペルオキシウンデカン酸(11−SPOUA);及びスルホン化ペルオレイン酸製造物(PSOA)の100ppmを含む使用溶液を試験した。
スルホン化ペルオレイン酸製品の調製
417.8gのOA5−R(インタートレイド・オーガニック(Intertrade Organic)社の40%活性スルホン化オレイン酸)を、大きな氷冷槽に浸けられている2リットルビーカーに追加した後、66.4gのDequest2010(モンサント(Monsanto)社の60%活性ヒドロキシエチレンホスホン酸)及び535gの過酸化水素(濃度46%活性、ソルベー−インテロックス(Solvay−Interox)製)をさらに追加した。ビーカーに磁気撹拌子を取り付けて、940gの硫酸(濃度96%活性、マリンクロッド(Mallinkrodt)社製)が加えられている間、強く撹拌した。硫酸追加の割合は制御して、反応溶液中で120°Fの発熱を起こしたところ、この間時々数°F上昇したが、125°Fを超えることはなかった。硫酸の追加が完了してから数分で、氷冷槽は取り除き、この不均一溶液については、温度を環境条件(70°F)と平衡に保ち、72時間撹拌した。
11−スルホペルオキシウンデカン酸:
9又は10−スルホステアリン酸の混合物2.0gへ2.0gの50%H2O2を追加した。室温ですべての固形物が溶けるまで混合物を撹拌した。次いで、2.0gの75%H3PO4を追加して、最終溶液を室温で一晩撹拌した。溶液から純粋な9又は10−スルホペルオキシステアリン酸を単離する試みは行われなかった。溶液の13C NMR(D2O)は174ppmで過酸のピーク(COOOH)を示し、178ppmで元のカルボン酸のピークを示した。ヨウ素滴定(QATM−202)は18.96%のスルホペルオキシステアリン酸を示した。
Claims (85)
- R1が、未置換C9アルキル基である、請求項1に記載の化合物。
- R1が、置換C9アルキル基である、請求項1に記載の化合物。
- R1が、置換C10アルキル基である、請求項1に記載の化合物。
- 置換C9アルキル基が、1以上のヒドロキシル基で置換されている、請求項3に記載の化合物。
- アルキル基の炭素骨格上の少なくとも2つの炭素が複素環式基を形成する、請求項4に記載の化合物。
- R1がC8−C9アルキルであり、R2がC7−C8アルキルである、請求項1に記載の化合物。
- 前記組成物が、10−ヒドロキシ−9−スルホオクタデカンペルオキシ酸、10,11−ジヒドロキシ−9−スルホオクタデカンペルオキシ酸、9−ヒドロキシ−10−スルホオクタデカンペルオキシ酸、及び10−スルホ−8,9−ジヒドロキシオクタデカンペルオキシ酸の少なくとも1つを含む、請求項9に記載の組成物。
- 前記組成物のpHが約9未満である、請求項9に記載の組成物。
- 前記化合物が約10ppm〜約100重量%で存在する、請求項9に記載の組成物。
- 前記化合物が約0.1重量%〜約10重量%で存在する、請求項9に記載の組成物。
- 前記化合物が約0.1重量%〜約5重量%で存在する、請求項9に記載の組成物。
- 前記化合物が有効な殺菌量で存在する、請求項9に記載の組成物。
- 前記化合物が約10ppm〜約100ppmで存在する、請求項16に記載の組成物。
- 前記化合物が、1種以上の食品媒介病原菌又は食品に関連する腐敗菌を殺菌するのに有効な量で存在する、請求項9に記載の組成物。
- 前記食品が、食肉、肉製品、海産物、鳥肉、鳥肉製品、農産物、卵、生卵、卵製品、インスタント食品、小麦、種子、根菜類、塊茎、葉、茎、穀類、花、芽、調味料、又はそれらの組み合わせからなる群から選択される、請求項18に記載の組成物。
- 前記菌が、ネズミチフス菌(Salmonella typhimurium)、サルモネラ・ジャビアナ(Salmonella javiana)、カンピロバクター・ジェジュニ(Campylocater jejun)、リステリア・モノサイトゲネス(Listeria monocytogenes)及び大腸菌(Escherichia coli)O157:H7、酵母菌、カビ及びそれらの混合物からなる群から選択される、請求項18に記載の組成物。
- 前記化合物が、胞子、バクテリア、カビ、酵母菌、ウイルス及びそれらの混合物からなる群から選択される微生物群を低減させるのに有効な量で存在する、請求項9に記載の組成物。
- 前記微生物が、黄色ブドウ球菌(Staphylococcus aureus)、緑膿菌(Pseudomonas aeruginosa)、メチシリン耐性黄色ブドウ球菌(Staphylococcus aureus)、及びそれらの混合物からなる群から選択される、請求項21に記載の組成物。
- 前記微生物が、枯草菌(Bacillus subtilis)、セレウス菌(Bacillus cereus)、スポロゲネス菌(Clostridium sporogenes)、ボツリヌス菌(Clostridium botulinum)、クロストリジウム・ディフィシル(Clostridium difficile)、及びそれらの混合物からなる群から選択される、請求項23に記載の組成物。
- 前記微生物が、ポリオウィルス、マイコバクテリウム結核菌及びそれらの混合物からなる群から選択される、請求項21に記載の組成物。
- さらに酸化剤を含む、請求項9に記載の組成物。
- 前記酸化剤が過酸化水素を含む、請求項25に記載の組成物。
- さらに少なくとも1種のC1〜C22ペルオキシカルボン酸を含む、請求項25に記載の組成物。
- 前記ペルオキシカルボン酸が、少なくとも1種のC5〜C11ペルオキシカルボン酸を含む、請求項27に記載の組成物。
- 前記ペルオキシカルボン酸がペルオキシオクタン酸を含む、請求項28に記載の組成物。
- 前記ペルオキシオクタン酸が、約0.1重量%〜約10重量%で存在する、請求項29に記載の組成物。
- 前記ペルオキシカルボン酸がペルオキシ酢酸を含む、請求項27に記載の組成物。
- 前記ペルオキシ酢酸が、約1重量%〜約10重量%で存在する、請求項31に記載の組成物。
- 少なくとも1種のカルボン酸をさらに含む、請求項27に記載の組成物。
- 前記カルボン酸が、少なくとも1種のC5〜C11カルボン酸を含む、請求項33に記載の組成物。
- 少なくとも1種のC1〜C4ペルオキシカルボン酸及び少なくとも1種のC5〜C11カルボン酸を含む、請求項27に記載の組成物。
- 物品を請求項9に記載の組成物と接触させる工程を含む、物品を殺菌する方法。
- 前記物品が、医療又は外科用機器、テキスタイル、構造面、包装硬質面、食器及びそれらの組み合わせからなる群から選択される、請求項36に記載の方法。
- 物品の表面を請求項9に記載の組成物と接触させる工程を含む、物品から汚れを除去する方法。
- 前記物品が食器から構成されている、請求項38に記載の方法。
- 前記物品が洗濯物から構成されている、請求項38に記載の方法。
- 前記接触の工程が、約4℃〜約80℃の温度で前記洗濯物を前記組成物と接触させる工程を含む、請求項40に記載の方法。
- 面を請求項11に記載の組成物と接触させる工程を含む、面上の微生物群を低減させる方法。
- 前記微生物が、胞子、バクテリア、カビ、酵母菌及びそれらの混合物からなる群から選択される、請求項42に記載の方法。
- 前記微生物が、黄色ブドウ球菌(Staphylococcus aureus)、緑膿菌(Pseudomonas aeruginosa)、メチシリン耐性黄色ブドウ球菌(Staphylococcus aureus)、及びそれらの混合物からなる群から選択される、請求項42に記載の方法。
- 前記組成物が、約40℃、約5分間で前記微生物群を5log低減させるのに有効な量で存在する、請求項42に記載の方法。
- 前記組成物が少なくとも約10ppmで存在する、請求項42に記載の方法。
- 前記組成物が約10ppm〜約2000ppmで存在する、請求項42に記載の方法。
- 前記微生物が、枯草菌(Bacillus subtilis)、セレウス菌(Bacillus cereus)、スポロゲネス菌(Clostridium sporogenes)、ボツリヌス菌(Clostridium botulinum)、クロストリジウム・ディフィシル(Clostridium difficile)、及びそれらの混合物からなる群から選択される、請求項42に記載の方法。
- 前記微生物が、ポリオウィルス、マイコバクテリウム結核菌、及びそれらの混合物からなる群から選択される、請求項42に記載の方法。
- 前記菌が、ネズミチフス菌(Salmonella typhimurium)、サルモネラ・ジャビアナ(Salmonella javiana)、カンピロバクター・ジェジュニ(Campylocater jejun)、リステリア・モノサイトゲネス(Listeria monocytogenes)及び大腸菌(Escherichia coli)O157:H7、酵母菌、カビ及びそれらの混合物からなる群から選択される、請求項45に記載の方法。
- 請求項1に記載の化合物を含む組成物と物品を接触させる工程を含む、物品を漂白する方法。
- 前記物品が硬質面である、請求項51に記載の方法。
- 前記物品がテキスタイルである、請求項51に記載の方法。
- 前記C1〜C4カルボン酸が酢酸である、請求項54に記載の組成物。
- 前記C5〜C11カルボン酸がオクタン酸である、請求項54に記載の組成物。
- 前記式Iで表される化合物が、10−ヒドロキシ−9−スルホオクタデカンペルオキソ酸、10,11−ジヒドロキシ−9−スルホオクタデカンペルオキソ酸、9−ヒドロキシ−10−スルホオクタデカンペルオキソ酸、及び10−スルホ−8,9−ジヒドロキシオクタデカンペルオキソ酸の少なくとも1つを含む、請求項54に記載の組成物。
- 前記組成物が122°Fで少なくとも約4週間安定している、請求項54に記載の組成物。
- 前記酸化剤が過酸化水素を含む、請求項54に記載の組成物。
- さらに安定化剤を含む、請求項54に記載の組成物。
- 前記安定化剤が、有機アミノポリホスホン酸錯化剤、有機ヒドロキシポリホスホン酸錯化剤、及びそれらの混合物からなる群から選択される、請求項61に記載の組成物。
- 前記安定化剤が、カルボン酸、ヒドロキシカルボン酸、アミノカルボン酸、複素環式カルボン酸及びそれらの混合物からなる群から選択される、請求項61に記載の組成物。
- 前記組成物が実質的にリンを含まない、請求項54に記載の組成物。
- (a)約1重量%〜約5重量%の式Iで表される化合物;
(b)約1重量%〜約10重量%のC1〜C4カルボン酸;
(c)約1重量%〜約10重量%のC5〜C11カルボン酸;及び
(d)約10重量%〜約30重量%の酸化剤
を含む、請求項54に記載の組成物。 - (a)請求項54に記載の組成物を洗濯物に適用する工程;及び
(b)該組成物を該洗濯物から排出する工程
を含む、洗濯物を処理する方法。 - 前記洗濯物が約100°Fで処理される、請求項66に記載の方法。
- 前記処理が、洗濯物の殺菌、洗濯物の消毒及びそれらの組み合わせからなる群から選択される、請求項66に記載の方法。
- 前記処理が洗濯物の漂白を含む、請求項66に記載の方法。
- 面を請求項54に記載の組成物と接触させる工程を含む、面上の微生物群を低減する方法。
- 前記微生物が、胞子、バクテリア、カビ、酵母菌、ウイルス、及びそれらの混合物からなる群から選択される、請求項70に記載の方法。
- 前記酸化剤が過酸化水素を含む、請求項72に記載の組成物。
- 前記酸味料が、硫酸、硫酸水素ナトリウム、硝酸、塩酸及びそれらの組み合わせからなる群から選択される、請求項72に記載の組成物。
- 前記酸味料が、メタンスルホン酸、エタンスルホン酸、プロパンスルホン酸、ブタンスルホン酸、キシレンスルホン酸、ベンゼンスルホン酸、ギ酸、酢酸、ハロカルボン酸、ピコリン酸、ジピコリン酸、及びそれらの混合物からなる群から選択される、請求項72に記載の組成物。
- さらに安定化剤を含む、請求項72に記載の組成物。
- 前記安定化剤が、有機アミノポリホスホン酸錯化剤、有機ヒドロキシポリホスホン酸錯化剤、及びそれらの混合物からなる群から選択される、請求項77に記載の組成物。
- 前記安定化剤が、カルボン酸、ヒドロキシカルボン酸、アミノカルボン酸、複素環式カルボン酸、及びそれらの混合物からなる群から選択される、請求項77に記載の組成物。
- 前記組成物が実質的にリンを含まない、請求項72に記載の組成物。
- さらに界面活性剤を含む、請求項72に記載の組成物。
- 前記界面活性剤が、アルキルスルホン酸塩、芳香族スルホン酸塩、及びそれらの混合物からなる群から選択される、請求項82に記載の組成物。
- 面を請求項72に記載の組成物と接触させる工程を含む、定置洗浄法を用いて面を殺菌する方法。
- (a)酸性pH条件下で、非アルファスルホン化カルボン酸を酸化剤と接触させて、スルホペルオキシカルボン酸を製造する工程
を含む、請求項1に記載の化合物を製造する方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/568,493 US8809392B2 (en) | 2008-03-28 | 2009-09-28 | Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents |
US12/568,493 | 2009-09-28 | ||
PCT/IB2010/054270 WO2011036628A2 (en) | 2009-09-28 | 2010-09-21 | Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents |
Related Child Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013208307A Division JP2014024856A (ja) | 2009-09-28 | 2013-10-03 | スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤及び殺菌剤としての使用方法 |
JP2013208332A Division JP2014040455A (ja) | 2009-09-28 | 2013-10-03 | スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤及び殺菌剤としての使用方法 |
JP2013208358A Division JP2014015625A (ja) | 2009-09-28 | 2013-10-03 | スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤及び殺菌剤としての使用方法 |
JP2013208291A Division JP2014040454A (ja) | 2009-09-28 | 2013-10-03 | スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤及び殺菌剤としての使用方法 |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2013505929A true JP2013505929A (ja) | 2013-02-21 |
JP2013505929A5 JP2013505929A5 (ja) | 2013-11-07 |
JP5735515B2 JP5735515B2 (ja) | 2015-06-17 |
Family
ID=43796310
Family Applications (5)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012530396A Active JP5735515B2 (ja) | 2009-09-28 | 2010-09-21 | スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤及び殺菌剤としての使用方法 |
JP2013208291A Pending JP2014040454A (ja) | 2009-09-28 | 2013-10-03 | スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤及び殺菌剤としての使用方法 |
JP2013208332A Pending JP2014040455A (ja) | 2009-09-28 | 2013-10-03 | スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤及び殺菌剤としての使用方法 |
JP2013208307A Pending JP2014024856A (ja) | 2009-09-28 | 2013-10-03 | スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤及び殺菌剤としての使用方法 |
JP2013208358A Pending JP2014015625A (ja) | 2009-09-28 | 2013-10-03 | スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤及び殺菌剤としての使用方法 |
Family Applications After (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013208291A Pending JP2014040454A (ja) | 2009-09-28 | 2013-10-03 | スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤及び殺菌剤としての使用方法 |
JP2013208332A Pending JP2014040455A (ja) | 2009-09-28 | 2013-10-03 | スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤及び殺菌剤としての使用方法 |
JP2013208307A Pending JP2014024856A (ja) | 2009-09-28 | 2013-10-03 | スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤及び殺菌剤としての使用方法 |
JP2013208358A Pending JP2014015625A (ja) | 2009-09-28 | 2013-10-03 | スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤及び殺菌剤としての使用方法 |
Country Status (9)
Country | Link |
---|---|
US (9) | US8809392B2 (ja) |
EP (1) | EP2483241A4 (ja) |
JP (5) | JP5735515B2 (ja) |
CN (1) | CN102834377B (ja) |
BR (1) | BR112012005029A2 (ja) |
CA (1) | CA2771251A1 (ja) |
MX (1) | MX2012003388A (ja) |
WO (1) | WO2011036628A2 (ja) |
ZA (1) | ZA201200841B (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2014522857A (ja) * | 2011-07-14 | 2014-09-08 | エコラボ ユーエスエー インコーポレイティド | 過酸の脱臭 |
KR20210091132A (ko) | 2018-11-12 | 2021-07-21 | 미츠비시 가스 가가쿠 가부시키가이샤 | 살균 및 세정용 조성물, 그 제조 방법, 및 그것을 사용한 살균 및 세정 방법 |
Families Citing this family (67)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BRPI0907918B1 (pt) | 2008-03-28 | 2018-07-24 | Ecolab Inc. | Ácidos sulfoperoxicarboxílicos, sua preparação e métodos de utilizção como agentes alvejantes e antimicrobianos |
US8809392B2 (en) | 2008-03-28 | 2014-08-19 | Ecolab Usa Inc. | Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents |
US8871807B2 (en) | 2008-03-28 | 2014-10-28 | Ecolab Usa Inc. | Detergents capable of cleaning, bleaching, sanitizing and/or disinfecting textiles including sulfoperoxycarboxylic acids |
US20110217204A1 (en) * | 2010-03-05 | 2011-09-08 | Franciskovich Phillip P | Sterilization composition |
US20120252893A1 (en) * | 2010-08-27 | 2012-10-04 | Julio Pimentel | Antimicrobial formulation |
US8906963B2 (en) | 2011-07-14 | 2014-12-09 | Ecolab Usa Inc | Deodorization of peracids |
EP2773648B1 (en) * | 2011-09-29 | 2019-03-13 | ETH Zürich | Pharmaceutical compounds for use in the therapy of clostridium difficile infection |
US9751903B2 (en) | 2011-09-29 | 2017-09-05 | Eth Zurich | Pharmaceutical compounds for use in the therapy of clostridium difficile infection |
JP2014534967A (ja) | 2011-10-20 | 2014-12-25 | アニトックス コーポレーション | ペラルゴン酸を含む抗微生物処方剤 |
WO2013066681A1 (en) * | 2011-11-03 | 2013-05-10 | Amcol International Corporation | Post-added builder composition |
US9321664B2 (en) | 2011-12-20 | 2016-04-26 | Ecolab Usa Inc. | Stable percarboxylic acid compositions and uses thereof |
EP2807244B1 (en) * | 2012-01-27 | 2022-01-26 | Ecolab USA Inc. | Low temperature sulfoperoxycarboxylic acid containing cleaning composition |
ES2566365T3 (es) * | 2012-02-15 | 2016-04-12 | Ecolab Usa Inc. | Método de inactivación de enzimas |
CN106396037B (zh) | 2012-03-30 | 2019-10-15 | 艺康美国股份有限公司 | 过乙酸/过氧化氢和过氧化物还原剂用于处理钻井液、压裂液、回流水和排放水的用途 |
US9462806B2 (en) | 2012-04-16 | 2016-10-11 | Ecolab Usa Inc. | Use of peroxycarboxylic acids for cold aseptic filling |
US20140005273A1 (en) | 2012-06-29 | 2014-01-02 | Ecolab Usa Inc. | Glycerin ether ethoxylate solfactants |
US10844322B2 (en) | 2012-08-07 | 2020-11-24 | Ecolab Usa Inc. | High flashpoint alcohol-based cleaning, sanitizing and disinfecting composition and method of use on food contact surfaces |
US20140308162A1 (en) | 2013-04-15 | 2014-10-16 | Ecolab Usa Inc. | Peroxycarboxylic acid based sanitizing rinse additives for use in ware washing |
US9752105B2 (en) | 2012-09-13 | 2017-09-05 | Ecolab Usa Inc. | Two step method of cleaning, sanitizing, and rinsing a surface |
EP4136973A1 (en) | 2012-10-05 | 2023-02-22 | Ecolab USA Inc. | Use of percarboxylic acid compositions |
US10165774B2 (en) * | 2013-03-05 | 2019-01-01 | Ecolab Usa Inc. | Defoamer useful in a peracid composition with anionic surfactants |
US8822719B1 (en) | 2013-03-05 | 2014-09-02 | Ecolab Usa Inc. | Peroxycarboxylic acid compositions suitable for inline optical or conductivity monitoring |
US20140256811A1 (en) | 2013-03-05 | 2014-09-11 | Ecolab Usa Inc. | Efficient stabilizer in controlling self accelerated decomposition temperature of peroxycarboxylic acid compositions with mineral acids |
US9140648B2 (en) | 2013-03-12 | 2015-09-22 | Ecolab Usa Inc. | Fluorometer with multiple detection channels |
US9618450B2 (en) | 2013-09-27 | 2017-04-11 | Ecolab USA, Inc. | Multi-channel fluorometric sensor and method of using same |
US9578879B1 (en) | 2014-02-07 | 2017-02-28 | Gojo Industries, Inc. | Compositions and methods having improved efficacy against spores and other organisms |
CA2938974C (en) | 2014-02-07 | 2023-08-22 | Gojo Industries, Inc. | Compositions and methods with efficacy against spores and other organisms |
US9677031B2 (en) | 2014-06-20 | 2017-06-13 | Ecolab Usa Inc. | Catalyzed non-staining high alkaline CIP cleaner |
BR122018076176B1 (pt) | 2014-12-18 | 2021-06-01 | Ecolab Usa Inc | Método para formar ácido peroxifórmico, método para tratar uma superfície, método para tratar um biofilme em uma superfície e método para desinfetar uma superfície da pele |
US9845290B2 (en) | 2014-12-18 | 2017-12-19 | Ecolab Usa Inc. | Methods for forming peroxyformic acid and uses thereof |
BR112017016759B1 (pt) * | 2015-02-03 | 2021-01-12 | Merz Pharma Gmbh & Co. Kgaa | seringa de plástico pré-carregada, kit, uso da seringa de plástico pré-carregada e método para o tratamento cosmético da pele |
US9557270B2 (en) | 2015-03-04 | 2017-01-31 | Ecolab Usa Inc. | Multi-channel fluorometric sensor and method of using same |
US9683153B2 (en) | 2015-03-30 | 2017-06-20 | Ecolab Usa Inc. | Freeze conditioning agents utilizing crude glycerin and flowback and produced water |
US10280386B2 (en) | 2015-04-03 | 2019-05-07 | Ecolab Usa Inc. | Enhanced peroxygen stability in multi-dispense TAED-containing peroxygen solid |
US10172351B2 (en) | 2015-09-04 | 2019-01-08 | Ecolab Usa Inc. | Performic acid on-site generator and formulator |
EP3904526A1 (en) | 2015-09-10 | 2021-11-03 | Ecolab USA Inc. | Self indicating antimicrobial chemistry |
US9890350B2 (en) | 2015-10-28 | 2018-02-13 | Ecolab Usa Inc. | Methods of using a soil release polymer in a neutral or low alkaline prewash |
US11707470B2 (en) | 2015-12-11 | 2023-07-25 | Eth Zurich | Inositol derivatives for use in pathological crystallization |
WO2017181005A1 (en) | 2016-04-15 | 2017-10-19 | Ecolab Usa Inc. | Performic acid biofilm prevention for industrial co2 scrubbers |
ES2809023T3 (es) | 2016-05-23 | 2021-03-02 | Ecolab Usa Inc | Composiciones desinfectantes, de higienización, de limpieza ácida con reducción de la formación de neblina a través del uso de polímeros de emulsión de agua en aceite de alto peso molecular |
US10392587B2 (en) | 2016-05-23 | 2019-08-27 | Ecolab Usa Inc. | Reduced misting alkaline and neutral cleaning, sanitizing, and disinfecting compositions via the use of high molecular weight water-in-oil emulsion polymers |
WO2018021110A1 (ja) * | 2016-07-26 | 2018-02-01 | 大日本除蟲菊株式会社 | 消泡効果増強剤およびそれを含有する発泡性洗剤組成物 |
US10866223B2 (en) | 2016-12-15 | 2020-12-15 | Ecolab Usa Inc. | Colorimetric detection and quantitative estimation of peracids using a redox sensitive leuco dye |
EA201991508A1 (ru) * | 2016-12-22 | 2019-11-29 | Способ получения водной композиции, подходящей для физического вспенивания | |
CN106818748A (zh) * | 2017-01-17 | 2017-06-13 | 安徽科技学院 | 一种基于过氧磺化油酸及过氧辛酸的消毒剂及制备方法 |
JP6300055B1 (ja) * | 2017-03-14 | 2018-03-28 | 車工房株式会社 | 樹脂材のクリーニング方法及びクリーニング剤 |
EP4296345A3 (en) | 2017-06-22 | 2024-03-13 | Ecolab USA Inc. | Bleaching using peroxyformic acid and an oxygen catalyst |
CA3067083C (en) | 2017-06-22 | 2024-03-12 | Ecolab Usa Inc. | Chlorine bleaching after peracid treatment |
CN111246835B (zh) * | 2017-10-27 | 2024-01-02 | 联合利华知识产权控股有限公司 | 包含辛酸的非皂液体清洁剂组合物 |
MX2020006903A (es) * | 2017-12-29 | 2021-04-12 | Cms Tech Inc | Sistemas y métodos de tratamiento con ph alto de productos alimentarios y otros sustratos. |
WO2019241635A1 (en) | 2018-06-15 | 2019-12-19 | Ecolab Usa Inc. | On site generated performic acid compositions for teat treatment |
EP3841059A1 (en) | 2018-08-22 | 2021-06-30 | Ecolab USA Inc. | Hydrogen peroxide and peracid stabilization with molecules based on a pyridine carboxylic acid at c-3, -4 or -5 |
EP3918128A1 (en) | 2019-01-31 | 2021-12-08 | Ecolab USA Inc. | Laundry machine kit to enable control of water levels, recirculation, and spray of chemistry |
US20200248383A1 (en) | 2019-01-31 | 2020-08-06 | Ecolab Usa Inc. | Rinse water reuse system and methods of use |
CA3128194A1 (en) | 2019-01-31 | 2020-08-06 | Ecolab Usa Inc. | Controller for a rinse water reuse system and methods of use |
WO2020160425A1 (en) | 2019-01-31 | 2020-08-06 | Ecolab Usa Inc. | Controlling water levels and detergent concentration in a wash cycle |
CN117050817A (zh) | 2019-04-12 | 2023-11-14 | 埃科莱布美国股份有限公司 | 抗微生物多用途清洁剂及其制备和使用方法 |
TR201907343A2 (tr) * | 2019-05-15 | 2020-11-23 | Denge Kimya Ve Tekstil Sanayi Ticaret Anonim Sirketi | Boyalı Tekstiller İçin Bir Ağartma Kompozisyonu ve Bu Kompozisyonun Kullanıldığı Ağartma Yöntemi |
WO2021026410A1 (en) | 2019-08-07 | 2021-02-11 | Ecolab Usa Inc. | Polymeric and solid-supported chelators for stabilization of peracid-containing compositions |
US11820737B2 (en) | 2020-01-31 | 2023-11-21 | Ecolab Usa Inc. | Generation of peroxyhydroxycarboxylic acid and the use thereof |
US20210238505A1 (en) | 2020-01-31 | 2021-08-05 | Ecolab Usa Inc. | Amylase synergy with oxygen bleach in warewash application |
US11905498B2 (en) | 2020-02-12 | 2024-02-20 | Ecolab Usa Inc. | Use of urea or a urea/chelator combination to chemically stabilize peroxycarboxylic acid and peroxide formulations |
EP4103547A1 (en) | 2020-03-31 | 2022-12-21 | Ecolab USA Inc. | Method for quenching peroxycarboxylic acid runaway reactions |
WO2021243120A2 (en) | 2020-05-29 | 2021-12-02 | Ecolab Usa Inc. | Biocidal compositions with hydronium ion sources for biofilm control |
US11939553B2 (en) | 2020-06-03 | 2024-03-26 | Ecolab Usa Inc. | Non-caustic cleaning compositions and uses thereof |
US11932795B2 (en) | 2020-06-03 | 2024-03-19 | Ecolab Usa Inc. | Aromatic amine epoxide adducts for corrosion inhibition |
WO2022165094A1 (en) | 2021-01-29 | 2022-08-04 | Ecolab Usa Inc. | Solid peroxyalphahydroxycarboxylic acid generation compositions and the use thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3414593A (en) * | 1964-08-20 | 1968-12-03 | Procter & Gamble | Alpha-sulfo peroxy fatty acid detergent compounds |
JPS63165364A (ja) * | 1986-11-03 | 1988-07-08 | アクゾ ノベル ナムローゼ ベンノートシャープ | スルホンペルオキシカルボン酸 |
JP2009500415A (ja) * | 2005-07-06 | 2009-01-08 | イーコラブ インコーポレイティド | 界面活性ペルオキシカルボン酸組成物 |
JP2011518775A (ja) * | 2008-03-28 | 2011-06-30 | イーコラブ インコーポレイティド | スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤および殺菌剤としての使用方法。 |
Family Cites Families (362)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2609391A (en) | 1950-09-13 | 1952-09-02 | Buffalo Electro Chem Co | Stabilization of peracids with dipicolinic acid |
DE1024514B (de) | 1953-12-04 | 1958-02-20 | Du Pont | Verfahren zum Oxydieren von organischen Verbindungen mit Wasserstoffperoxyd in fluessigem Zustand |
US3053633A (en) | 1959-12-14 | 1962-09-11 | Shell Oil Co | Peroxide stabilization |
US3156654A (en) | 1961-06-19 | 1964-11-10 | Shell Oil Co | Bleaching |
US3130169A (en) | 1961-06-26 | 1964-04-21 | Fmc Corp | Stabilization of peroxy carboxylic acids |
GB1198734A (en) | 1968-05-01 | 1970-07-15 | Nalco Chemical Co | Prevention of Control of Corrosion in Oil Refining Equipment |
US3929678A (en) | 1974-08-01 | 1975-12-30 | Procter & Gamble | Detergent composition having enhanced particulate soil removal performance |
US3969258A (en) | 1974-10-10 | 1976-07-13 | Pennwalt Corporation | Low foaming acid-anionic surfactant sanitizer compositions |
US3956159A (en) | 1974-11-25 | 1976-05-11 | The Procter & Gamble Company | Stable concentrated liquid peroxygen bleach composition |
NL7608265A (nl) | 1975-08-16 | 1977-02-18 | Henkel & Cie Gmbh | Bij opslag stabiele concentraten van functionele middelen. |
DE2629081A1 (de) | 1976-06-29 | 1978-01-12 | Peroxid Chemie Gmbh | Germizides mittel |
US4100095A (en) | 1976-08-27 | 1978-07-11 | The Procter & Gamble Company | Peroxyacid bleach composition having improved exotherm control |
US4126573A (en) | 1976-08-27 | 1978-11-21 | The Procter & Gamble Company | Peroxyacid bleach compositions having increased solubility |
DE2654164C2 (de) | 1976-11-30 | 1978-08-10 | Schuelke & Mayr Gmbh, 2000 Norderstedt | Wäßrige Perglutarsäurelösung und deren Verwendung |
US4170453A (en) | 1977-06-03 | 1979-10-09 | The Procter & Gamble Company | Peroxyacid bleach composition |
FR2462425A1 (fr) | 1979-08-01 | 1981-02-13 | Air Liquide | Procede de fabrication de solutions diluees stables de peracides carboxyliques aliphatiques |
US4311598A (en) | 1979-09-04 | 1982-01-19 | Interox Chemicals Limited | Disinfection of aqueous media |
US4259201A (en) | 1979-11-09 | 1981-03-31 | The Procter & Gamble Company | Detergent composition containing organic peracids buffered for optimum performance |
FR2502620A1 (fr) | 1981-03-24 | 1982-10-01 | Ugine Kuhlmann | Procede continu de preparation de l'oxyde de propylene |
US4430236A (en) | 1981-06-22 | 1984-02-07 | Texize, Division Of Mortonthiokol | Liquid detergent composition containing bleach |
EP0068547B1 (en) | 1981-06-22 | 1985-09-18 | THE PROCTER & GAMBLE COMPANY | Mixed peroxyacid bleaches having improved bleaching power |
US4374035A (en) | 1981-07-13 | 1983-02-15 | The Procter & Gamble Company | Accelerated release laundry bleach product |
US4391723A (en) | 1981-07-13 | 1983-07-05 | The Procter & Gamble Company | Controlled release laundry bleach product |
EP0075419A3 (en) | 1981-09-15 | 1983-11-02 | THE PROCTER & GAMBLE COMPANY | Laundry bleach product |
US4473507A (en) | 1981-10-21 | 1984-09-25 | The Procter & Gamble Company | Controlled release laundry bleach product |
US4391724A (en) | 1981-10-21 | 1983-07-05 | The Procter & Gamble Company | Controlled release laundry bleach product |
DE3364292D1 (en) | 1982-02-03 | 1986-08-07 | Procter & Gamble | Oxygen-bleach-containing liquid detergent compositions |
FR2521991A1 (fr) | 1982-02-24 | 1983-08-26 | Air Liquide | Solutions commerciales de peracides carboxyliques stables et non corrosives et leurs applications |
US4529534A (en) | 1982-08-19 | 1985-07-16 | The Procter & Gamble Company | Peroxyacid bleach compositions |
US4540721A (en) | 1983-03-10 | 1985-09-10 | The Procter & Gamble Company | Method of providing odor to product container |
JPS59206525A (ja) | 1983-05-10 | 1984-11-22 | Watanabe Tsuguhiko | 電柱の沈下防止装置 |
JPS59206495A (ja) | 1983-05-10 | 1984-11-22 | ライオン株式会社 | 混合界面活性剤組成物 |
JPS59206016A (ja) | 1983-05-11 | 1984-11-21 | Mizusawa Ind Chem Ltd | 自動フイルタプレスにおける濾布支持装置 |
US4786431A (en) | 1984-12-31 | 1988-11-22 | Colgate-Palmolive Company | Liquid laundry detergent-bleach composition and method of use |
US4661280A (en) | 1985-03-01 | 1987-04-28 | Colgate | Built liquid laundry detergent composition containing salt of higher fatty acid stabilizer and method of use |
US4744916A (en) | 1985-07-18 | 1988-05-17 | Colgate-Palmolive Company | Non-gelling non-aqueous liquid detergent composition containing higher fatty dicarboxylic acid and method of use |
US4769168A (en) | 1985-08-05 | 1988-09-06 | Colgate-Palmolive Company | Low phosphate or phosphate free nonaqueous liquid nonionic laundry detergent composition and method of use |
US4846992A (en) | 1987-06-17 | 1989-07-11 | Colgate-Palmolive Company | Built thickened stable non-aqueous cleaning composition and method of use, and package therefor |
IN165978B (ja) | 1985-08-20 | 1990-02-17 | Colgate Palmolive Co | |
NZ216987A (en) | 1985-08-20 | 1988-09-29 | Colgate Palmolive Co | Nonaqueous liquid low phosphate laundry detergent |
GB8531384D0 (en) | 1985-12-20 | 1986-02-05 | Unilever Plc | Sanitizing process |
GB8603961D0 (en) | 1986-02-18 | 1986-03-26 | Interox Chemicals Ltd | Concentrated liquid composition |
IN168163B (ja) | 1986-02-21 | 1991-02-16 | Colgate Palmolive Co | |
US5433881A (en) | 1986-03-19 | 1995-07-18 | Warwick International Group Limited | Granulation process for making granular bleach activator compositions and resulting product |
JPS6316534A (ja) | 1986-07-08 | 1988-01-23 | Mitsui Toatsu Chem Inc | Crtフイルタ− |
FR2601850B1 (fr) | 1986-07-25 | 1990-05-04 | Garcin Francoise | Composition antiseptique incorporant des huiles essentielles. |
ZA876155B (en) | 1986-08-28 | 1989-04-26 | Colgate Palmolive Co | Liquid nonionic laundry detergent composition and method of use |
US4797225A (en) | 1986-09-08 | 1989-01-10 | Colgate-Palmolive Company | Nonaqueous liquid nonionic laundry detergent composition containing an alkali metal dithionite or sulfite reduction bleaching agent and method of use |
NZ221505A (en) | 1986-09-09 | 1989-08-29 | Colgate Palmolive Co | Liquid detergent compositions with peroxygen bleach and calcium cyanamide activator |
US5004558A (en) | 1986-11-03 | 1991-04-02 | Monsanto Company | Sulfone peroxycarboxylic acids |
US4778618A (en) | 1986-11-06 | 1988-10-18 | The Clorox Company | Glycolate ester peracid precursors |
DK690187A (da) | 1986-12-31 | 1988-07-01 | Albright & Wilson | Beskyttet system, som er egnet til anvendelse i rensemidler, samt produkter indeholdende systemet |
DE3709348A1 (de) | 1987-03-21 | 1988-10-06 | Degussa | Peroxycarbonsaeure enthaltende waessrige bleichmittelsuspensionen, verfahren zu ihrer herstellung und ihre verwendung |
US5250212A (en) | 1987-05-27 | 1993-10-05 | The Procter & Gamble Company | Liquid detergent containing solid peroxygen bleach and solvent system comprising water and lower aliphatic monoalcohol |
EP0334427B1 (en) | 1988-03-21 | 1992-06-10 | Akzo N.V. | Alkyl sulphonyl peroxycarboxylic acids and bleaching and detergent compositions containing the same |
FR2630454B1 (fr) | 1988-04-22 | 1990-08-10 | Air Liquide | Lessives liquides aqueuses blanchissantes stables au stockage et procede de lavage |
IT1219689B (it) | 1988-05-04 | 1990-05-24 | Ausimont Spa | Perossiacidi azotati monopersolfati |
US4917815A (en) | 1988-06-10 | 1990-04-17 | Sterling Drug Inc. | Stable aqueous aromatic percarboxylic acid solution |
US4909953A (en) | 1988-06-30 | 1990-03-20 | The Procter & Gamble Company | Phosphate buffer wash for improved amidoperoxyacid storage stability |
DE3823172C2 (de) | 1988-07-08 | 1998-01-22 | Hoechst Ag | omega-Phthalimidoperoxihexansäure, Verfahren zu dessen Herstellung und dessen Verwendung |
US4957063A (en) | 1988-07-25 | 1990-09-18 | The Clorox Company | Odor control animal litter |
GB8830234D0 (en) | 1988-12-24 | 1989-02-22 | Interox Chemicals Ltd | Peroxycarboxylic acids |
GB8830235D0 (en) | 1988-12-24 | 1989-02-22 | Interox Chemicals Ltd | Percarboxylic acids |
CA2010464A1 (en) | 1989-02-21 | 1990-08-21 | Bronislav H. May | Stabilized compositions containing peroxygen compounds |
IT1229564B (it) | 1989-03-09 | 1991-09-04 | Ausimont Srl | Composizioni detergenti e/o sbiancanti prevalentemente liquide contenenti ammine terziarie a basso peso molecolare in forma di n ossido. |
CA2015490A1 (en) | 1989-05-01 | 1990-11-01 | Charles E. Kellner | Agglomerated peroxyacid bleach granule and process for making same |
DE3914827C2 (de) | 1989-05-05 | 1995-06-14 | Schuelke & Mayr Gmbh | Flüssiges Desinfektionsmittelkonzentrat |
US5073285A (en) | 1989-06-12 | 1991-12-17 | Lever Brothers Company, Division Of Conopco, Inc. | Stably suspended organic peroxy bleach in a structured aqueous liquid |
BE1003515A3 (fr) | 1989-10-05 | 1992-04-14 | Interox Sa | Compositions d'acide peracetique et procede pour obtenir ces compositions. |
US5139788A (en) | 1989-10-17 | 1992-08-18 | Ecolab Inc. | Noncontaminating antimicrobial composition |
DK547589D0 (da) | 1989-11-02 | 1989-11-02 | Novo Nordisk As | Fremgangsmaade til fremstilling af organiske forbindelser |
SE8903773L (sv) | 1989-11-10 | 1991-05-11 | Eka Nobel Ab | Peraettiksyrakomposition |
AU7067991A (en) | 1989-12-23 | 1991-07-24 | Interox Chemicals Limited | Peroxycarboxylic acids |
GB9003200D0 (en) | 1990-02-13 | 1990-04-11 | Unilever Plc | Aqueous liquid bleach composition |
GB9004080D0 (en) | 1990-02-23 | 1990-04-18 | Interox Chemicals Ltd | Solutions of peracids |
JP2754928B2 (ja) | 1990-03-16 | 1998-05-20 | 日本電気株式会社 | 無線選択呼出受信機 |
CA2078126A1 (en) | 1990-03-27 | 1991-09-28 | Jerry Leroy Adams | 5-lipoxygenase inhibitors |
GB9007293D0 (en) | 1990-03-31 | 1990-05-30 | Procter & Gamble | Peroxyacid bleach precursors and detergent compositions containing them |
JP2590026B2 (ja) | 1990-04-05 | 1997-03-12 | ミンテック・コーポレーション | 防食性殺菌剤 |
DE4012769A1 (de) | 1990-04-21 | 1991-10-24 | Hoechst Ag | Stabile peroxicarbonsaeuregranulate |
JPH0798816B2 (ja) | 1990-04-25 | 1995-10-25 | 宇部興産株式会社 | ε―カプロラクトンの製造法 |
GB9012876D0 (en) | 1990-06-08 | 1990-08-01 | Interox Chemicals Ltd | Peroxycompounds |
DE4019790A1 (de) | 1990-06-21 | 1992-01-02 | Henkel Kgaa | Fluessige alkylglykosidhaltige tensidmischung |
JPH0823039B2 (ja) | 1990-07-13 | 1996-03-06 | エコラブ・インコーポレイテッド | 食品用銘柄成分からの固体リンス助剤 |
FR2665158B1 (fr) | 1990-07-30 | 1993-12-24 | Air Liquide | Clathrates de peroxyacides. |
AU649761B2 (en) | 1990-11-27 | 1994-06-02 | Croda International Plc | Polymeric materials |
GB9027975D0 (en) | 1990-12-22 | 1991-02-13 | Interox Chemicals Ltd | Peroxycarboxylic acid |
TW291496B (ja) | 1991-02-01 | 1996-11-21 | Hoechst Ag | |
EP0504952A1 (en) | 1991-02-15 | 1992-09-23 | The Procter & Gamble Company | Stable liquid amidoperoxyacid bleach |
US5409629A (en) | 1991-07-19 | 1995-04-25 | Rohm And Haas Company | Use of acrylic acid/ethyl acrylate copolymers for enhanced clay soil removal in liquid laundry detergents |
US5200189A (en) | 1991-07-23 | 1993-04-06 | Ecolab Inc. | Peroxyacid antimicrobial composition |
ATE129492T1 (de) | 1991-10-04 | 1995-11-15 | Akzo Nobel Nv | Suspension und agglomeration von amidoperoxysäuren. |
GB9122048D0 (en) | 1991-10-17 | 1991-11-27 | Interox Chemicals Ltd | Compositions and uses thereof |
JPH05140079A (ja) | 1991-11-14 | 1993-06-08 | Kao Corp | 新規スルホナート及びその製造法 |
US5281351A (en) | 1991-12-06 | 1994-01-25 | Lever Brothers Company, Division Of Conopco, Inc. | Processes for incorporating anti-scalants in powdered detergent compositions |
US5496728A (en) | 1991-12-13 | 1996-03-05 | The Procter & Gamble Company | Encapsulation of liquids in micro-organisms |
US5616281A (en) | 1991-12-13 | 1997-04-01 | The Procter & Gamble Company | Acylated citrate esters as peracid precursors |
JPH06316534A (ja) | 1992-01-10 | 1994-11-15 | Kao Kishinmin | 治療用のプロテインホスファターゼインヒビター |
US5300250A (en) | 1992-01-14 | 1994-04-05 | The Procter & Gamble Company | Granular laundry compositions having improved solubility |
WO1993014832A1 (en) | 1992-01-24 | 1993-08-05 | Patrick Grant | Putting and chipping apparatus |
US5268003A (en) | 1992-03-31 | 1993-12-07 | Lever Brothers Company, Division Of Conopco, Inc. | Stable amido peroxycarboxylic acids for bleaching |
US5264229A (en) | 1992-04-20 | 1993-11-23 | Degussa Corporation | Shelf life extension for commercially processed poultry/fowl and seafood products using a specialized hydrogen peroxide |
AU4777093A (en) | 1992-08-01 | 1994-03-03 | Procter & Gamble Company, The | Peroxyacid bleach precursor compositions |
GB9216454D0 (en) | 1992-08-03 | 1992-09-16 | Ici Plc | Detergent compositions |
DE69324261T2 (de) | 1992-10-23 | 1999-10-14 | Procter & Gamble | Granulare waschmittel mit protease |
GB9225519D0 (en) | 1992-12-07 | 1993-01-27 | Unilever Plc | Improvements to bleaching compositions |
US5288746A (en) | 1992-12-21 | 1994-02-22 | The Procter & Gamble Company | Liquid laundry detergents containing stabilized glucose/glucose oxidase as H2 O2 generation system |
JP3315473B2 (ja) | 1992-12-28 | 2002-08-19 | 花王株式会社 | 新規スルホナート、その製造法及びこれを含有するかび取り剤組成物 |
GB9300243D0 (en) | 1993-01-06 | 1993-03-03 | Solvay Interox Ltd | Disinfection of aqueous solutions |
GB9302442D0 (en) | 1993-02-08 | 1993-03-24 | Warwick Int Group | Oxidising agents |
WO1994019446A1 (en) | 1993-02-26 | 1994-09-01 | Lion Corporation | Bleaching composition |
US5409713A (en) | 1993-03-17 | 1995-04-25 | Ecolab Inc. | Process for inhibition of microbial growth in aqueous transport streams |
GB9305863D0 (en) | 1993-03-22 | 1993-05-12 | Unilever Plc | Peroxyacids |
JP3281445B2 (ja) | 1993-04-28 | 2002-05-13 | 花王株式会社 | 殺菌剤組成物 |
DE4317420C1 (de) | 1993-05-26 | 1994-11-03 | Degussa | Stabilisierte Percarbonsäurelösungen und Verfahren zu deren Herstellung |
DE69320462T2 (de) | 1993-06-09 | 1999-04-22 | Procter & Gamble | Verfahren zur Bleichung von Geweben |
JP3255499B2 (ja) | 1993-06-16 | 2002-02-12 | 花王株式会社 | 新規スルホナート、その製造法及びこれを含有する漂白剤組成物 |
US5415807A (en) | 1993-07-08 | 1995-05-16 | The Procter & Gamble Company | Sulfonated poly-ethoxy/propoxy end-capped ester oligomers suitable as soil release agents in detergent compositions |
WO1995002030A1 (en) | 1993-07-08 | 1995-01-19 | The Procter & Gamble Company | Detergent compositions comprising soil release agents |
NL9301339A (nl) | 1993-07-30 | 1995-02-16 | Tno Instituut Voor Reinigingst | Peroxyzuren of voorlopers daarvan voor de toepassing in het reinigen van textiel, alsmede werkwijzen en inrichtingen voor het reinigen van textiel met behulp van dergelijke peroxyzuren of voorlopers. |
US5435808A (en) | 1993-09-03 | 1995-07-25 | Birko Corporation | Hide raceway treatment and improved method of curing hides |
US5472619A (en) | 1993-09-03 | 1995-12-05 | Birko Corporation | Waste water treatment with peracetic acid compositions |
US5362899A (en) | 1993-09-09 | 1994-11-08 | Affymax Technologies, N.V. | Chiral synthesis of alpha-aminophosponic acids |
US5965785A (en) | 1993-09-28 | 1999-10-12 | Nalco/Exxon Energy Chemicals, L.P. | Amine blend neutralizers for refinery process corrosion |
US5632676A (en) | 1993-10-12 | 1997-05-27 | Fmc Corporation | Use of peracetic acid to sanitize processed fowl |
US5374369A (en) | 1993-10-14 | 1994-12-20 | Lever Brothers Company, Division Of Conopco, Inc. | Silver anti-tarnishing detergent composition |
GB9325558D0 (en) | 1993-12-14 | 1994-02-16 | Solvay Interox Ltd | Percaboxylic acids |
WO1995020030A1 (en) | 1994-01-25 | 1995-07-27 | Unilever N.V. | Co-granules and detergent tablets formed therefrom |
EP0666307A3 (en) | 1994-02-03 | 1996-07-03 | Procter & Gamble | Packaged liquid bleaching composition. |
AU1584295A (en) | 1994-02-07 | 1995-08-21 | Warwick International Group Limited | Pulp bleaching |
WO1995024388A1 (en) | 1994-03-09 | 1995-09-14 | Kemira Chemicals B.V. | A method for the preparation of aqueous solutions containing performic acid as well as their use |
US5578134A (en) | 1994-04-19 | 1996-11-26 | Ecolab Inc. | Method of sanitizing and destaining tableware |
US6257253B1 (en) | 1994-04-19 | 2001-07-10 | Ecolab Inc. | Percarboxylic acid rinse method |
US5437686A (en) | 1994-05-18 | 1995-08-01 | Colgate-Palmolive Co. | Peroxygen bleach composition activated by bi and tricyclic diketones |
GB9411495D0 (en) | 1994-06-08 | 1994-07-27 | Unilever Plc | Aqueous bleaching compositions comprising peroxy carboxylic acids |
EP0765150B1 (en) | 1994-06-16 | 2002-09-11 | Warner-Lambert Company | Process and apparatus for producing closed sealed capsules |
JP3297217B2 (ja) | 1994-09-22 | 2002-07-02 | 花王株式会社 | 漂白洗浄剤組成物 |
JPH10506931A (ja) | 1994-09-26 | 1998-07-07 | ザ、プロクター、エンド、ギャンブル、カンパニー | 非水性漂白剤含有液体洗剤組成物 |
EP0784669A1 (en) | 1994-09-26 | 1997-07-23 | The Procter & Gamble Company | Process for preparing non-aqueous, bleach-containing liquid detergent compositions |
GB2294695A (en) | 1994-11-05 | 1996-05-08 | Procter & Gamble | A method of washing laundry |
GB9423374D0 (en) | 1994-11-19 | 1995-01-11 | Procter & Gamble | Peroxyacid bleach precursor compositions |
JP3297226B2 (ja) | 1994-11-24 | 2002-07-02 | 花王株式会社 | 漂白洗浄剤組成物 |
CA2206852A1 (en) | 1994-12-07 | 1996-06-13 | Novo Nordisk A/S | Polypeptide with reduced allergenicity |
US5691298A (en) | 1994-12-14 | 1997-11-25 | The Procter & Gamble Company | Ester oligomers suitable as soil release agents in detergent compositions |
US5929012A (en) | 1995-02-28 | 1999-07-27 | Procter & Gamble Company | Laundry pretreatment with peroxide bleaches containing chelators for iron, copper or manganese for reduced fabric damage |
US5683977A (en) | 1995-03-06 | 1997-11-04 | Lever Brothers Company, Division Of Conopco, Inc. | Dry cleaning system using densified carbon dioxide and a surfactant adjunct |
JPH08245549A (ja) | 1995-03-13 | 1996-09-24 | Kao Corp | スルホナートの製造法 |
EP0738778A1 (en) | 1995-04-19 | 1996-10-23 | The Procter & Gamble Company | Nonaqueous, particulate-containing liquid detergent compositions |
DE19517465C1 (de) | 1995-05-12 | 1997-01-23 | Degussa | Percarbonsäurelösungen mit verbesserter Stabilität im Kontakt mit Edelstahl |
US5698506A (en) | 1995-05-19 | 1997-12-16 | Lever Brothers Company, Division Of Conopco, Inc. | Automatic dishwashing compositions containing aluminum salts |
CN1192777A (zh) | 1995-06-20 | 1998-09-09 | 普罗格特-甘布尔公司 | 含有烷基苯磺酸盐表面活化剂的非水含颗粒液体洗涤剂组合物 |
EP0751210A1 (en) | 1995-06-27 | 1997-01-02 | The Procter & Gamble Company | Bleaching compositions |
DE19530786A1 (de) | 1995-08-22 | 1997-02-27 | Hoechst Ag | Bleichmittelzusammensetzung enthaltend Polyoxometallate als Bleichkatalysator |
DE19531241A1 (de) | 1995-08-25 | 1997-02-27 | Degussa | Verfahren zur Desinfektion wäßriger Lösungen |
US5576282A (en) | 1995-09-11 | 1996-11-19 | The Procter & Gamble Company | Color-safe bleach boosters, compositions and laundry methods employing same |
JP3471992B2 (ja) | 1995-10-26 | 2003-12-02 | キヤノン株式会社 | トナー補給容器及び画像形成装置 |
US5589507A (en) | 1995-11-17 | 1996-12-31 | Minntech Corporation | Method for sterilizing medical devices utilizing a room temperature sterilant |
US5635195A (en) | 1995-11-17 | 1997-06-03 | Minntech Corporation | Premix for room temperature sterilant |
JPH11504842A (ja) | 1995-12-01 | 1999-05-11 | ミンテック・コーポレーション | 医療装置のための室温滅菌剤 |
JP3488565B2 (ja) | 1996-01-22 | 2004-01-19 | 株式会社東芝 | 光応用測定装置とその製造方法 |
US6310025B1 (en) | 1996-03-04 | 2001-10-30 | The Procter & Gamble Company | Laundry pretreatment process and bleaching compositions |
EP0822183A3 (en) | 1996-07-31 | 1998-07-29 | The Procter & Gamble Company | A process for forming a peracid and a composition comprising said peracid |
EP0823474A1 (en) | 1996-07-24 | 1998-02-11 | The Procter & Gamble Company | Peracids, stable aqueous compositions comprising peracids, and a process for forming said peracids |
ES2175350T5 (es) | 1996-03-08 | 2008-12-16 | Takeda Pharmaceutical Company Limited | Compuestos triciclicos que tienen afinidad de union a receptores de melatonina, su produccion y uso. |
US5968885A (en) | 1996-04-22 | 1999-10-19 | Procter & Gamble Co. | Bleaching compositions |
CZ294120B6 (cs) | 1996-05-03 | 2004-10-13 | Theáprocterá@Ágambleácompany | Prostředky na praní prádla s obsahem kationtových povrchově aktivních činidel a modifikovaných polyaminových dispergátorů špíny |
US5968893A (en) | 1996-05-03 | 1999-10-19 | The Procter & Gamble Company | Laundry detergent compositions and methods for providing soil release to cotton fabric |
EP0901516A1 (en) | 1996-05-03 | 1999-03-17 | The Procter & Gamble Company | Liquid laundry detergent compositions comprising cotton soil release polymers |
MA25183A1 (fr) | 1996-05-17 | 2001-07-02 | Arthur Jacques Kami Christiaan | Compositions detergentes |
US6576602B1 (en) | 1996-06-28 | 2003-06-10 | The Procter & Gamble Company | Nonaqueous, particulate-containing liquid detergent compositions with surfactant-structured liquid phase |
US5814592A (en) | 1996-06-28 | 1998-09-29 | The Procter & Gamble Company | Non-aqueous, particulate-containing liquid detergent compositions with elasticized, surfactant-structured liquid phase |
EP0954570A1 (en) | 1996-06-28 | 1999-11-10 | Novo Nordisk A/S | A recombinant enzyme with mutanase activity |
WO1998000516A1 (en) | 1996-06-28 | 1998-01-08 | The Procter & Gamble Company | Preparation of non-aqueous, particulate-containing liquid detergent compositions with surfactant-structured liquid phase |
US5672739A (en) | 1996-07-12 | 1997-09-30 | Exxon Research & Engineering Company | Class of three tail surfactants law388 |
WO1998005749A1 (en) | 1996-08-07 | 1998-02-12 | The Procter & Gamble Company | Detergent compositions containing dianionic esters |
US5817614A (en) | 1996-08-29 | 1998-10-06 | Procter & Gamble Company | Color-safe bleach boosters, compositions and laundry methods employing same |
EP0925350A1 (en) | 1996-09-13 | 1999-06-30 | The Procter & Gamble Company | Laundry pretreatment process and bleaching compositions |
JP2001506971A (ja) | 1996-09-18 | 2001-05-29 | メトレックス リサーチ コーポレイション | 過酸化水素消毒および滅菌組成物 |
ES2183929T3 (es) | 1996-10-31 | 2003-04-01 | Procter & Gamble | Composiciones liquidas acuosas blanquantes y procedimiento de pretratamiento. |
CN1136311C (zh) | 1996-11-04 | 2004-01-28 | 诺沃奇梅兹有限公司 | 枯草杆菌酶变异体和组合物 |
FI103899B (fi) | 1996-11-06 | 1999-10-15 | Chempolis Oy | Menetelmä erityisen vaalean massan valmistamiseksi |
SE9604413D0 (sv) | 1996-11-29 | 1996-11-29 | Eka Chemicals Ab | Chemical composition |
DE19652769A1 (de) | 1996-12-18 | 1998-06-25 | Voith Sulzer Papiermasch Gmbh | Verfahren und Vorrichtung zur Dämpfung von Kontaktschwingungen |
GB9626637D0 (en) | 1996-12-21 | 1997-02-12 | Solvay Interox Ltd | Percarboxyilic acid solutions |
US6183763B1 (en) | 1997-06-04 | 2001-02-06 | Procter & Gamble Company | Antimicrobial wipes which provide improved immediate germ reduction |
KR20010013377A (ko) | 1997-06-04 | 2001-02-26 | 데이비드 엠 모이어 | 마일드한 잔류성 항균 조성물 |
US5977403A (en) | 1997-08-04 | 1999-11-02 | Fmc Corporation | Method for the production of lower organic peracids |
US6444634B1 (en) | 1997-09-11 | 2002-09-03 | The Procter & Gamble Company | Bleaching compositions |
EP0906950A1 (en) | 1997-10-03 | 1999-04-07 | The Procter & Gamble Company | Peroxygen bleach-containing compositions comprising a particular chelating agent system |
CN1281502A (zh) | 1997-10-14 | 2001-01-24 | 普罗格特-甘布尔公司 | 含有中链支链表面活性剂的非水液体洗涤剂组合物 |
DE19754290A1 (de) | 1997-12-08 | 1999-06-10 | Henkel Kgaa | Enolester als Bleichaktivatoren für Wasch- und Reinigungsmittel |
CA2313475A1 (en) | 1997-12-11 | 1999-06-17 | The Procter & Gamble Company | Non-aqueous liquid detergent compositions containing ethoxylated quaternized amine clay compounds |
GB2332442A (en) | 1997-12-17 | 1999-06-23 | Procter & Gamble | Detergent tablet |
US20030100468A1 (en) | 1997-12-19 | 2003-05-29 | The Procter & Gamble Company | Nonaqueous, particulate-containing liquid detergent compositions with alkyl benzene sulfonate surfactant |
WO1999032598A1 (en) | 1997-12-22 | 1999-07-01 | The Procter & Gamble Company | Improved oxygen bleaching system |
JP2897006B1 (ja) | 1998-03-19 | 1999-05-31 | 株式会社コバード | 横臥棒状食品切断方法とその装置 |
DE19812589A1 (de) | 1998-03-23 | 1999-10-07 | Degussa | Perameisensäure enthaltendes wäßriges Desinfektionsmittel, Verfahren zu dessen Herstellung und deren Verwendung |
US6165483A (en) | 1998-04-06 | 2000-12-26 | Ecolab Inc. | Peroxy acid treatment to control pathogenic organisms on growing plants |
EP0948892A1 (en) | 1998-04-08 | 1999-10-13 | The Procter & Gamble Company | Disinfecting compositions and processes for disinfecting surfaces |
EP1071662B1 (en) | 1998-04-15 | 2004-08-04 | Akzo Nobel N.V. | Peroxides, their preparation process and use |
WO1999064556A1 (en) | 1998-06-05 | 1999-12-16 | The Procter & Gamble Company | Non-aqueous, liquid detergent compositions containing gasified particulate matter |
US6010729A (en) | 1998-08-20 | 2000-01-04 | Ecolab Inc. | Treatment of animal carcasses |
AU758625B2 (en) * | 1998-08-20 | 2003-03-27 | Ecolab Inc. | The treatment of meat products |
GB2341553A (en) | 1998-09-15 | 2000-03-22 | Procter & Gamble | Peroxyacid treatment |
EP1001012A1 (en) | 1998-11-10 | 2000-05-17 | The Procter & Gamble Company | Disinfecting and cleaning compositions |
AU1583699A (en) | 1998-11-10 | 2000-05-29 | Procter & Gamble Company, The | Bleaching compositions |
DE19853845A1 (de) | 1998-11-23 | 2000-05-25 | Henkel Kgaa | Wäßriges Bleichmittelkonzentrat |
DE19856071A1 (de) | 1998-12-04 | 2000-06-15 | Degussa | Verfahren zur Vermeidung einer Gewässerkontamination mit ortsfremden Organismen |
US6548470B1 (en) | 1998-12-14 | 2003-04-15 | The Procter & Gamble Company | Bleaching compositions |
US6346279B1 (en) | 1998-12-14 | 2002-02-12 | Virox Technologies, Inc. | Hydrogen peroxide disinfectant with increased activity |
GB2345701A (en) | 1999-01-12 | 2000-07-19 | Procter & Gamble | Particulate bleaching components |
US6262013B1 (en) * | 1999-01-14 | 2001-07-17 | Ecolab Inc. | Sanitizing laundry sour |
CA2359102A1 (en) | 1999-01-14 | 2000-07-20 | Alfred Busch | Detergent compositions comprising a pectin degrading enzymes system |
US6528471B1 (en) | 1999-01-22 | 2003-03-04 | The Procter & Gamble Company | Process of treating fabrics with a laundry additive |
WO2000047707A1 (en) | 1999-02-10 | 2000-08-17 | The Procter & Gamble Company | Stable non-aqueous liquid laundry detergents comprising low density particles |
JP3551098B2 (ja) | 1999-04-14 | 2004-08-04 | 松下電器産業株式会社 | コンデンサの製造方法 |
US6024986A (en) | 1999-05-24 | 2000-02-15 | Ecolab Inc. | Method of protecting growing plants from the effects of plant pathogens |
EP1061071A1 (en) | 1999-06-14 | 2000-12-20 | SOLVAY (Société Anonyme) | 6-Hydroxypercaproic acid and aqueous compositions thereof |
EP1204735A1 (en) | 1999-06-22 | 2002-05-15 | Deoflor S.p.A. | Cleansing and sanitizing composition for sanitary appliances |
US6699828B1 (en) | 1999-06-28 | 2004-03-02 | The Procter & Gamble Company | Aqueous liquid detergent compositions comprising an effervescent system |
US6192217B1 (en) | 1999-07-01 | 2001-02-20 | Assuresat, Inc. | Universal replacement communications satellite |
US6677289B1 (en) | 1999-07-16 | 2004-01-13 | The Procter & Gamble Company | Laundry detergent compositions comprising polyamines and mid-chain branched surfactants |
US6660711B1 (en) | 1999-07-16 | 2003-12-09 | The Procter & Gamble Company | Laundry detergent compositions comprising zwitterionic polyamines and mid-chain branched surfactants |
AU6935500A (en) | 1999-08-27 | 2001-03-26 | Procter & Gamble Company, The | Stability enhancing formulation components, compositions and laundry methods employing same |
US6548467B2 (en) | 1999-09-02 | 2003-04-15 | The Procter & Gamble Company | Sanitizing compositions and methods |
US6468472B1 (en) | 1999-09-16 | 2002-10-22 | Metrex Research Corporation | Cleaning and decontaminating dialyzers by per-compound solutions |
JP2001114792A (ja) | 1999-10-12 | 2001-04-24 | Nihon Medi Physics Co Ltd | ビスホスホン酸誘導体およびその放射性核種標識体 |
US7012053B1 (en) | 1999-10-22 | 2006-03-14 | The Procter & Gamble Company | Fabric care composition and method comprising a fabric care polysaccharide and wrinkle control agent |
DE19953870A1 (de) | 1999-11-10 | 2001-05-17 | Henkel Kgaa | Verfahren zur Herstellung einer wasserarmen Enzymzubereitung |
US6537958B1 (en) | 1999-11-10 | 2003-03-25 | The Procter & Gamble Company | Bleaching compositions |
US6686324B2 (en) | 1999-11-26 | 2004-02-03 | Virox Technologies, Inc. | Low-foaming hydrogen peroxide cleaning solution for organic soils |
DE19962343A1 (de) | 1999-12-23 | 2001-07-05 | Henkel Ecolab Gmbh & Co Ohg | Desinfizierendes Waschen empfindlicher Textilien mit Persäuren |
US20020172656A1 (en) | 2000-01-20 | 2002-11-21 | Biedermann Kimberly Ann | Cleansing compositions |
CN1221704C (zh) | 2000-02-15 | 2005-10-05 | 斯特赖克投资有限责任公司 | 使用憎水漂白制剂对纺织品组件进行耐久压制整理的方法 |
EP1255888B1 (en) | 2000-02-15 | 2007-08-01 | The Procter & Gamble Company | Method for the one step preparation of textiles |
US6830591B1 (en) | 2000-02-15 | 2004-12-14 | The Procter & Gamble Company | Method for the use of hydrophobic bleaching systems in textile preparation |
DE10011273A1 (de) | 2000-03-08 | 2001-09-20 | Henkel Kgaa | Flüssigwaschmittel mit flüssigen Bleichaktivatoren |
US6627657B1 (en) | 2000-03-22 | 2003-09-30 | Ecolab Inc. | Peroxycarboxylic acid compositions and methods of use against microbial spores |
US6645428B1 (en) | 2000-04-27 | 2003-11-11 | Ondeo Nalco Company | Fluorescent monomers and tagged treatment polymers containing same for use in industrial water systems |
AU2000248557A1 (en) | 2000-05-17 | 2001-11-26 | Raymond C Kralovic | Method of removing microbial contamination |
US20020161258A1 (en) | 2000-06-06 | 2002-10-31 | Miracle Gregory Scot | Mid-chain branched peracids and peracid precursors |
WO2001094692A2 (en) | 2000-06-08 | 2001-12-13 | Lonza Inc. | Aldehyde donors for stabilizing peroxides in papermaking applications |
FR2814180B1 (fr) | 2000-09-18 | 2003-12-05 | Michel Delmas | Procede de blanchiment de pates a papier en milieu organique a hydratation controlee |
JP4422316B2 (ja) | 2000-09-29 | 2010-02-24 | 株式会社リコー | 記録液、記録液カートリッジ、記録装置及び記録方法 |
WO2002040627A2 (en) | 2000-10-27 | 2002-05-23 | The Procter & Gamble Company | Stabilized liquid compositions |
DE10056183A1 (de) | 2000-11-13 | 2002-05-29 | Basf Ag | Hochverzweigte Polymere zur Antiknitterausrüstung von cellulosehaltigen Textilien |
DE10056163A1 (de) | 2000-11-13 | 2002-05-23 | Basf Ag | Hydrophil modifizierte Polyisocyanate und Polyurethane zur Antiknitterausrüstung von cellulosehaltigen Textilien |
DE10060373A1 (de) | 2000-12-05 | 2002-06-06 | Basf Ag | Reaktiv modifizierte, teilchenförmige Polymerisate zur Behandlung der Oberflächen textiler und nicht-textiler Materialien |
US20020107288A1 (en) | 2000-12-08 | 2002-08-08 | Singh Waheguru Pal | Methods of sterilizing with dipercarboxylic acids |
US6569209B2 (en) | 2001-02-27 | 2003-05-27 | The Procter & Gamble Company | Method for the use of hydrophobic bleaching systems in cold batch textile preparation |
US20020128312A1 (en) | 2001-03-09 | 2002-09-12 | Hei Robert D.P. | Stabilized ester peroxycarboxylic acid compositions |
FI111459B (fi) | 2001-04-04 | 2003-07-31 | Kemira Chemicals Oy | Menetelmä stabiilin peretikkahappotuotteen valmistamiseksi |
DE10118478A1 (de) | 2001-04-12 | 2002-10-17 | Basf Ag | Polysiloxanhaltige Polymere zur Antiknitterausrüstung von cellulosehaltigen Textilien |
DE10124387A1 (de) | 2001-05-18 | 2002-11-28 | Basf Ag | Hydrophob modifizierte Polyethylenimine und Polyvinylamine zur Antiknitterausrüstung von cellulosehaltigen Textilien |
US6635286B2 (en) | 2001-06-29 | 2003-10-21 | Ecolab Inc. | Peroxy acid treatment to control pathogenic organisms on growing plants |
US6627593B2 (en) | 2001-07-13 | 2003-09-30 | Ecolab Inc. | High concentration monoester peroxy dicarboxylic acid compositions, use solutions, and methods employing them |
US6593278B2 (en) | 2001-07-13 | 2003-07-15 | Exxonmobil Research And Engineering Company | Method for inhibiting corrosion using certain phosphorus and sulfur-free compounds |
US20030154556A1 (en) | 2001-09-07 | 2003-08-21 | Valerio Del Duca | Bleaching composition comprising a dye maintenance agent |
US20030148909A1 (en) | 2001-09-19 | 2003-08-07 | Valerio Del Duca | Bleaching compositions for dark colored fabric and articles comprising same |
CA2475327C (en) | 2002-02-12 | 2012-01-17 | Virox Technologies Inc. | Enhanced activity hydrogen peroxide disinfectant |
US7169236B2 (en) | 2002-03-28 | 2007-01-30 | Nalco Company | Method of monitoring membrane cleaning processes |
US7060136B1 (en) | 2002-03-28 | 2006-06-13 | Nalco Company | Method of monitoring membrane cleaning processes |
EP1374679A3 (en) | 2002-06-21 | 2004-01-21 | Nippon Peroxide Co., Ltd. | Sterilizing composition and method for sterilizing using the same |
US20030235623A1 (en) | 2002-06-21 | 2003-12-25 | Van Oosterom Piet J.A. | Aqueous disinfecting compositions with rapid bactericidal effect |
US6962714B2 (en) | 2002-08-06 | 2005-11-08 | Ecolab, Inc. | Critical fluid antimicrobial compositions and their use and generation |
EP1558717B1 (en) | 2002-11-04 | 2008-12-24 | Unilever Plc | Laundry detergent composition |
JP3962919B2 (ja) | 2002-11-12 | 2007-08-22 | 栗田工業株式会社 | 金属防食剤、金属防食方法、原油常圧蒸留装置における塩化水素発生防止剤および塩化水素発生防止方法 |
US6755509B2 (en) | 2002-11-23 | 2004-06-29 | Silverbrook Research Pty Ltd | Thermal ink jet printhead with suspended beam heater |
DE10260903A1 (de) | 2002-12-20 | 2004-07-08 | Henkel Kgaa | Neue Perhydrolasen |
JP3857658B2 (ja) | 2003-03-04 | 2006-12-13 | 株式会社東芝 | 磁気ランダムアクセスメモリ |
WO2004089981A2 (en) | 2003-04-02 | 2004-10-21 | Board Of Regents, The University Of Texas System | Antitumor effect of mutant bik |
SE525083C2 (sv) | 2003-04-23 | 2004-11-23 | Kemira Kemi Ab | Sätt att behandla rötslam |
JP2005005136A (ja) | 2003-06-12 | 2005-01-06 | Smk Corp | フレキシブル板状電線接続用コネクタ |
DE10361170A1 (de) | 2003-06-13 | 2005-01-05 | Henkel Kgaa | Lagerstabiles Polyelektrolytkapselsystem auf Basis von Peroxycarbonsäuren |
US7226900B2 (en) | 2003-06-16 | 2007-06-05 | The Proctor & Gamble Company | Liquid laundry detergent composition containing boron-compatible cationic deposition aids |
US7135448B2 (en) | 2003-07-02 | 2006-11-14 | Ecolab Inc. | Warewashing composition for use in automatic dishwashing machines, comprising a mixture of aluminum and zinc ions |
US7601789B2 (en) | 2003-09-09 | 2009-10-13 | Nalco Company | Fluorescent monomers and tagged treatment polymers containing same for use in industrial water systems |
JP2007520479A (ja) | 2004-01-09 | 2007-07-26 | イーコラブ インコーポレイティド | 中鎖ペルオキシカルボン酸組成物 |
AU2005204629B2 (en) | 2004-01-09 | 2010-05-20 | Ecolab Inc. | Methods for washing poultry during processing with medium chain peroxycarboxylic acid compositions |
US7504123B2 (en) | 2004-01-09 | 2009-03-17 | Ecolab Inc. | Methods for washing poultry during processing with medium chain peroxycarboxylic acid compositions |
US7887641B2 (en) | 2004-01-09 | 2011-02-15 | Ecolab Usa Inc. | Neutral or alkaline medium chain peroxycarboxylic acid compositions and methods employing them |
US7771737B2 (en) | 2004-01-09 | 2010-08-10 | Ecolab Inc. | Medium chain peroxycarboxylic acid compositions |
WO2005100529A1 (en) | 2004-04-05 | 2005-10-27 | The Procter & Gamble Company | Liquid bleaching compositions |
WO2006011315A1 (ja) | 2004-07-30 | 2006-02-02 | Katayama Chemical Inc. | 船舶バラスト水の処理方法 |
JP5036962B2 (ja) | 2004-08-06 | 2012-09-26 | 花王株式会社 | 自動洗浄機用殺菌剤組成物 |
US7470655B2 (en) | 2004-08-06 | 2008-12-30 | Ecolab Inc. | Method of inactivating prions |
JP4376727B2 (ja) | 2004-08-06 | 2009-12-02 | 三井化学株式会社 | ビスフェノール類の異性化触媒 |
JP5036963B2 (ja) | 2004-08-06 | 2012-09-26 | 花王株式会社 | 硬質表面用殺菌洗浄剤組成物 |
US7494963B2 (en) | 2004-08-11 | 2009-02-24 | Delaval Holding Ab | Non-chlorinated concentrated all-in-one acid detergent and method for using the same |
JP4038565B2 (ja) | 2004-09-21 | 2008-01-30 | サンノプコ株式会社 | 消泡剤 |
US7910371B2 (en) | 2005-01-20 | 2011-03-22 | Nalco Company | Method of monitoring treating agent residuals in water treatment processes |
DE102005003715A1 (de) | 2005-01-26 | 2006-09-14 | Basf Ag | Verwendung von Polymeren auf Basis modifizierter Polyamine als Zusatz zu Waschmitteln |
JP4699774B2 (ja) | 2005-02-18 | 2011-06-15 | 株式会社片山化学工業研究所 | 船舶バラスト水の処理方法 |
CA2599940C (en) | 2005-03-04 | 2011-11-29 | The Procter & Gamble Company | Automatic dishwashing composition with corrosion inhibitors |
DE102005013780A1 (de) | 2005-03-22 | 2006-09-28 | Basf Ag | Verwendung von kationischen Polykondensationsprodukten als farbfixierender und/oder farbübertragungsinhibierender Zusatz zu Waschmitteln und Wäschenachbehandlungsmitteln |
US8080404B1 (en) | 2005-04-05 | 2011-12-20 | The United States Of America As Represented By The Secretary Of The Army | Enzymatic decontamination |
ATE392465T1 (de) | 2005-04-27 | 2008-05-15 | Mifa Ag Frenkendorf | Flüssigwaschmittel mit bleichmittelzusatz |
WO2006116533A2 (en) | 2005-04-27 | 2006-11-02 | Hw Process Technologies, Inc. | Treating produced waters |
US20060247151A1 (en) | 2005-04-29 | 2006-11-02 | Kaaret Thomas W | Oxidizing compositions and methods thereof |
US20060257964A1 (en) | 2005-05-16 | 2006-11-16 | Biosafe Systems L.L.C. | Method of measuring the concentration of hydrogen peroxide, peroxyacetic acid, chlorinated compounds and other aqueous oxidizer compounds |
US8110603B2 (en) | 2005-07-27 | 2012-02-07 | Mitsubishi Gas Chemical Company, Inc. | Organic peracid polymer composition and process for producing the same |
FI118735B (fi) | 2005-09-13 | 2008-02-29 | Kemira Oyj | Menetelmä peroksihappojen valmistamiseksi |
JP2007084589A (ja) | 2005-09-20 | 2007-04-05 | Nippon Peroxide Co Ltd | 酸性殺菌洗浄剤 |
EP1780260A1 (en) | 2005-10-26 | 2007-05-02 | The Procter & Gamble Company | Process of treating fabrics |
EP1957622A2 (en) | 2005-12-07 | 2008-08-20 | The Procter and Gamble Company | Liquid laundry detergent having improved brightener stability |
US7723083B2 (en) | 2005-12-13 | 2010-05-25 | E.I. Du Pont De Nemours And Company | Production of peracids using an enzyme having perhydrolysis activity |
US20100010856A1 (en) | 2006-02-08 | 2010-01-14 | Kim Huat David Chua | Method and system for constraint-based project scheduling |
DE102006023937A1 (de) | 2006-05-19 | 2007-11-22 | Henkel Kgaa | Verkapselte Bleichmittelteilchen |
US20070281002A1 (en) | 2006-05-31 | 2007-12-06 | Sara Morales | Low irritation antimicrobial cleaning substrate |
NZ573564A (en) | 2006-06-19 | 2012-01-12 | Danisco | PS4 variant polypeptide with amylase activity |
US7448255B2 (en) | 2006-06-29 | 2008-11-11 | Nalco Company | Very high-temperature fluorescent tracer and automation for boiler water applications |
US20080001125A1 (en) | 2006-06-30 | 2008-01-03 | Baker Hughes Incorporated | Method and compositions for inhibition of naphthenic acid induced corrosion |
EP3319251B1 (en) | 2006-08-22 | 2020-01-29 | Juniper Networks, Inc. | Apparatus and method of controlled delay packet forwarding |
US7417017B2 (en) | 2006-09-07 | 2008-08-26 | The Dial Corporation | Detergent compositions with unique builder system for enhanced stain removal |
RU2009113557A (ru) | 2006-09-12 | 2010-10-20 | Космо Текнолоджиз Лтд (Ie) | Фармацевтические композиции для перорального или ректального введения белковых веществ |
TWI354164B (en) | 2006-10-03 | 2011-12-11 | Au Optronics Corp | Liquid crystal display and back light module there |
US20080146482A1 (en) | 2006-12-06 | 2008-06-19 | The Procter & Gamble Company | Liquid laundry detergent having improved brightener stability |
US7949432B2 (en) | 2007-02-16 | 2011-05-24 | Nalco Company | Method of monitoring surface associated microbiological activity in process streams |
US7981679B2 (en) | 2007-02-16 | 2011-07-19 | Nalco Company | Method of monitoring bulk (total) microbiological activity in process streams |
US20080274939A1 (en) | 2007-05-04 | 2008-11-06 | Ecolab Inc. | Water treatment system and downstream cleaning methods |
US7828905B2 (en) | 2007-05-04 | 2010-11-09 | Ecolab Inc. | Cleaning compositions containing water soluble magnesium compounds and methods of using them |
US7985318B2 (en) | 2007-05-10 | 2011-07-26 | Nalco Company | Method of monitoring and inhibiting scale deposition in pulp mill evaporators and concentrators |
US8119412B2 (en) | 2007-06-05 | 2012-02-21 | Ecolab Usa Inc. | Kinetic determination of peracid and/or peroxide concentrations |
US8143070B2 (en) | 2007-06-05 | 2012-03-27 | Ecolab Usa Inc. | Optical cell |
US8512633B2 (en) | 2007-08-16 | 2013-08-20 | American Sterilizer Company | Indicator for monitoring a sterilization process |
US9271494B2 (en) | 2007-08-30 | 2016-03-01 | Ecolab USA, Inc. | Shelf stable, reduced corrosion, ready to use peroxycarboxylic acid antimicrobial compositions |
TW200927915A (en) | 2007-10-25 | 2009-07-01 | Croda Int Plc | Laundry formulations and method of cleaning |
WO2009072156A1 (en) | 2007-12-07 | 2009-06-11 | Emanuela Manna | Deodorizing and sanitizing compositions |
US7666828B2 (en) | 2008-01-22 | 2010-02-23 | Stepan Company | Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them |
US8871807B2 (en) | 2008-03-28 | 2014-10-28 | Ecolab Usa Inc. | Detergents capable of cleaning, bleaching, sanitizing and/or disinfecting textiles including sulfoperoxycarboxylic acids |
US8809392B2 (en) * | 2008-03-28 | 2014-08-19 | Ecolab Usa Inc. | Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents |
US8241624B2 (en) | 2008-04-18 | 2012-08-14 | Ecolab Usa Inc. | Method of disinfecting packages with composition containing peracid and catalase |
US8226939B2 (en) | 2008-04-18 | 2012-07-24 | Ecolab Usa Inc. | Antimicrobial peracid compositions with selected catalase enzymes and methods of use in aseptic packaging |
FR2930732B1 (fr) | 2008-04-30 | 2010-05-14 | Arkema France | Composition et procede pour la destruction de polluants organophosphores et/ou organosoufres |
US7927199B2 (en) | 2008-07-16 | 2011-04-19 | Deere & Company | Grain cleaning assembly support frame movable in two planes |
WO2010011746A2 (en) | 2008-07-24 | 2010-01-28 | Fmc Corporation | Dilute aqueous peracid solutions and stabilization method |
EP2157162A1 (en) | 2008-08-13 | 2010-02-24 | The Procter and Gamble Company | Particulate bleaching composition comprising enzymes |
US9150793B2 (en) | 2008-11-03 | 2015-10-06 | Nalco Company | Method of reducing corrosion and corrosion byproduct deposition in a crude unit |
WO2010077570A2 (en) | 2008-12-09 | 2010-07-08 | Fmc Corporation | Acrylamide removal from aqueous fluid bodies |
CN102256484B (zh) | 2008-12-18 | 2014-12-17 | Fmc有限公司 | 过乙酸油田生物杀灭剂和方法 |
WO2010086832A2 (en) | 2009-01-30 | 2010-08-05 | Ecolab Inc. | Development of an aluminum hydroxycarboxylate builder |
US8575075B2 (en) | 2009-02-27 | 2013-11-05 | Fmc Corporation | Oil-field viscosity breaker method utilizing a peracid |
US8017409B2 (en) | 2009-05-29 | 2011-09-13 | Ecolab Usa Inc. | Microflow analytical system |
US20110177145A1 (en) | 2009-07-27 | 2011-07-21 | E.I. Du Pont De Nemours And Company | In situ preparation of peracid-based removable antimicrobial coating compositions and methods of use |
GB201000122D0 (en) | 2010-01-06 | 2010-02-17 | Reckitt & Colman Overseas | Antimicrobial hand soap composition |
FI125089B (fi) | 2010-01-21 | 2015-05-29 | Kemira Oyj | Annostelulaitekokoonpano reaktiivisille kemikaaleille |
US9254400B2 (en) | 2010-03-02 | 2016-02-09 | Ecolab Usa Inc. | Method for processing peroxygen solutions |
WO2011112886A1 (en) | 2010-03-12 | 2011-09-15 | The Procter & Gamble Company | Fluid detergent compositions comprising a di-amido gellant, and processes for making |
WO2011119950A2 (en) | 2010-03-26 | 2011-09-29 | Aquionics, Inc. | Ultraviolet disinfection of oil field process water |
EP2571972A1 (en) | 2010-05-20 | 2013-03-27 | Arkema Inc. | Activated peroxide cleaning compositions |
US8726989B2 (en) | 2010-07-14 | 2014-05-20 | Donald Nevin | Method for removing contaminants from wastewater in hydraulic fracturing process |
AR082347A1 (es) | 2010-07-28 | 2012-11-28 | Chevron Usa Inc | Sistema y metodo de reutilizacion de agua de fluido de fractura |
US8518159B2 (en) | 2010-10-07 | 2013-08-27 | Encana Corporation | Treatment of water for use in hydraulic fracture stimulation |
RU2584282C2 (ru) | 2010-10-08 | 2016-05-20 | ЭКОЛАБ ЮЭсЭй ИНК. | Составы флуоресцирующего геля и их применение |
US8889010B2 (en) | 2010-10-22 | 2014-11-18 | General Electric Company | Norm removal from frac water |
US8846107B2 (en) | 2010-12-29 | 2014-09-30 | Ecolab Usa Inc. | In situ generation of peroxycarboxylic acids at alkaline pH, and methods of use thereof |
EP2522714A1 (en) | 2011-05-13 | 2012-11-14 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Aqueous concentrated laundry detergent compositions |
EP2522715A1 (en) | 2011-05-13 | 2012-11-14 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Aqueous concentrated laundry detergent compositions |
US8883848B2 (en) | 2011-07-14 | 2014-11-11 | Ecolab Usa Inc. | Enhanced microbial peracid compositions and methods of use at reduced temperatures in aseptic cleaning |
US9321664B2 (en) | 2011-12-20 | 2016-04-26 | Ecolab Usa Inc. | Stable percarboxylic acid compositions and uses thereof |
JP6316534B2 (ja) | 2012-09-25 | 2018-04-25 | シャープ株式会社 | 撮像装置および撮像装置制御方法 |
US20140096971A1 (en) | 2012-10-05 | 2014-04-10 | Timothy S. Keizer | New method and arrangement for feeding chemicals into a hydrofracturing process and oil and gas applications |
-
2009
- 2009-09-28 US US12/568,493 patent/US8809392B2/en active Active
-
2010
- 2010-09-21 CA CA2771251A patent/CA2771251A1/en not_active Abandoned
- 2010-09-21 EP EP10818491.2A patent/EP2483241A4/en not_active Withdrawn
- 2010-09-21 JP JP2012530396A patent/JP5735515B2/ja active Active
- 2010-09-21 WO PCT/IB2010/054270 patent/WO2011036628A2/en active Application Filing
- 2010-09-21 CN CN201080041717.0A patent/CN102834377B/zh active Active
- 2010-09-21 MX MX2012003388A patent/MX2012003388A/es unknown
- 2010-09-21 BR BR112012005029A patent/BR112012005029A2/pt not_active Application Discontinuation
-
2011
- 2011-11-07 US US13/290,355 patent/US9359295B2/en active Active
-
2012
- 2012-02-03 ZA ZA2012/00841A patent/ZA201200841B/en unknown
-
2013
- 2013-10-03 JP JP2013208291A patent/JP2014040454A/ja active Pending
- 2013-10-03 JP JP2013208332A patent/JP2014040455A/ja active Pending
- 2013-10-03 JP JP2013208307A patent/JP2014024856A/ja active Pending
- 2013-10-03 JP JP2013208358A patent/JP2014015625A/ja active Pending
-
2014
- 2014-06-27 US US14/317,128 patent/US9290448B2/en active Active
-
2016
- 2016-02-19 US US15/048,684 patent/US9676711B2/en active Active
-
2017
- 2017-05-11 US US15/592,776 patent/US10017720B2/en active Active
-
2018
- 2018-06-04 US US15/997,392 patent/US10323218B2/en active Active
-
2019
- 2019-03-29 US US16/370,412 patent/US10669512B2/en active Active
-
2020
- 2020-04-27 US US16/858,873 patent/US11015151B2/en active Active
-
2021
- 2021-04-14 US US17/301,792 patent/US11827867B2/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3414593A (en) * | 1964-08-20 | 1968-12-03 | Procter & Gamble | Alpha-sulfo peroxy fatty acid detergent compounds |
JPS63165364A (ja) * | 1986-11-03 | 1988-07-08 | アクゾ ノベル ナムローゼ ベンノートシャープ | スルホンペルオキシカルボン酸 |
JP2009500415A (ja) * | 2005-07-06 | 2009-01-08 | イーコラブ インコーポレイティド | 界面活性ペルオキシカルボン酸組成物 |
JP2011518775A (ja) * | 2008-03-28 | 2011-06-30 | イーコラブ インコーポレイティド | スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤および殺菌剤としての使用方法。 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2014522857A (ja) * | 2011-07-14 | 2014-09-08 | エコラボ ユーエスエー インコーポレイティド | 過酸の脱臭 |
JP2014525909A (ja) * | 2011-07-14 | 2014-10-02 | エコラボ ユーエスエー インコーポレイティド | 改善された抗微生物性過酸組成物および無菌浄化における低下した温度での使用方法 |
KR20210091132A (ko) | 2018-11-12 | 2021-07-21 | 미츠비시 가스 가가쿠 가부시키가이샤 | 살균 및 세정용 조성물, 그 제조 방법, 및 그것을 사용한 살균 및 세정 방법 |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5735515B2 (ja) | スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤及び殺菌剤としての使用方法 | |
JP5524994B2 (ja) | スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤および殺菌剤としての使用方法 | |
US20240158723A1 (en) | Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents | |
AU2010299464B2 (en) | Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents | |
AU2012201801C1 (en) | Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130920 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20130920 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20140814 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A132 Effective date: 20140826 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20141126 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20150317 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20150416 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5735515 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |