JP2011505464A - 高温加圧水及び超音波発生予混合器により重質油を品質改良する方法 - Google Patents
高温加圧水及び超音波発生予混合器により重質油を品質改良する方法 Download PDFInfo
- Publication number
- JP2011505464A JP2011505464A JP2010536096A JP2010536096A JP2011505464A JP 2011505464 A JP2011505464 A JP 2011505464A JP 2010536096 A JP2010536096 A JP 2010536096A JP 2010536096 A JP2010536096 A JP 2010536096A JP 2011505464 A JP2011505464 A JP 2011505464A
- Authority
- JP
- Japan
- Prior art keywords
- water
- heavy oil
- oil
- submicron emulsion
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 143
- 239000000295 fuel oil Substances 0.000 title claims abstract description 97
- 238000000034 method Methods 0.000 title claims abstract description 61
- 239000000203 mixture Substances 0.000 claims abstract description 76
- 238000002156 mixing Methods 0.000 claims abstract description 50
- 239000003921 oil Substances 0.000 claims abstract description 36
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 26
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 26
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 17
- 239000011593 sulfur Substances 0.000 claims abstract description 17
- 229910052751 metal Inorganic materials 0.000 claims abstract description 16
- 239000002184 metal Substances 0.000 claims abstract description 16
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 16
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 11
- 239000000839 emulsion Substances 0.000 claims description 58
- 238000006243 chemical reaction Methods 0.000 claims description 40
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 claims description 36
- 239000001257 hydrogen Substances 0.000 claims description 33
- 229910052739 hydrogen Inorganic materials 0.000 claims description 33
- 239000007788 liquid Substances 0.000 claims description 32
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 31
- 239000003054 catalyst Substances 0.000 claims description 19
- 238000002604 ultrasonography Methods 0.000 claims description 18
- 239000007789 gas Substances 0.000 claims description 13
- 238000007254 oxidation reaction Methods 0.000 claims description 13
- 230000003647 oxidation Effects 0.000 claims description 11
- 238000005086 pumping Methods 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 7
- 238000005336 cracking Methods 0.000 claims description 6
- 239000003995 emulsifying agent Substances 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 238000004064 recycling Methods 0.000 claims description 3
- 230000001590 oxidative effect Effects 0.000 claims 2
- 238000011084 recovery Methods 0.000 claims 2
- 239000012535 impurity Substances 0.000 abstract description 17
- 239000012530 fluid Substances 0.000 abstract description 3
- 230000008569 process Effects 0.000 description 21
- 239000000571 coke Substances 0.000 description 19
- 239000003208 petroleum Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 238000007670 refining Methods 0.000 description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 description 5
- 239000010779 crude oil Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 230000033228 biological regulation Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000004517 catalytic hydrocracking Methods 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000003209 petroleum derivative Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000012429 reaction media Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 230000009931 harmful effect Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- -1 radical compounds Chemical class 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000011874 heated mixture Substances 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 238000000194 supercritical-fluid extraction Methods 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 239000008400 supply water Substances 0.000 description 1
- 238000010977 unit operation Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
- B01J3/008—Processes carried out under supercritical conditions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
- C10G31/08—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by treating with water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/24—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with hydrogen-generating compounds
- C10G45/26—Steam or water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/32—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions in the presence of hydrogen-generating compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G75/00—Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH DRILLING; MINING
- E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1033—Oil well production fluids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/205—Metal content
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/205—Metal content
- C10G2300/206—Asphaltenes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4081—Recycling aspects
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/80—Additives
- C10G2300/805—Water
Abstract
Description
表1による性質を有する真空蒸留からの残渣は、本発明の方法により処理される。初めに、供給重質油及び蒸留水をそれぞれ1リットル及び4リットルの量で混合容器に投入する。混合容器は8リットルの容量を有し、30kHzで動作する超音波ホモジナイザーが備えられている。ホモジナイザーは500ワットで1時間操作され、混合容器の温度は50℃に維持される。高圧ポンプを使用して、混合物は次に混合物の温度が250℃に昇温される予備加熱区域に供給される。この加熱された混合物は、次に圧力を25MPaに維持しながら反応区域に導入され、450℃の温度に約60分間加熱される。反応区域からの産生物は、供給物と予備加熱区域で熱交換され、次に圧力調整装置、好ましくは背圧調整器により約0.1MPaに開放される。圧力調整装置からの産生物は、次に気液分離器に供給される。気液分離器からの液体部分は、次に油水分離器に供給される。層分離を促進するために、解乳化剤が液体部分に添加される。油分を集めて分析する。全液体収率は91.5重量%を超える。処理の間に形成されたコークス及び気体の量は、それぞれ原料の2.5及び6.0重量%である。最終油分のAPI比重は12.5であり、全硫黄含有量は2.65重量%である。ニッケル及びバナジウムは、最終油分中のこれらの金属が無視できる含有量であるので、実用上完全に除去されている。
Claims (20)
- 外部供給触媒がなく、外部供給水素源がない環境で重質油を品質改良する方法であって、
重質油を供給水と混合区域で混ぜ合わせて重質油/水混合物を形成するステップであって、重質油/水混合物の温度は150℃を超えない上記ステップと、
重質油/水混合物を超音波に曝してサブミクロン乳化液を生成するステップと、
サブミクロン乳化液を高圧ポンプを用いて予備加熱区域を通じてポンプ輸送するステップであって、高圧ポンプはサブミクロン乳化液の圧力を水の臨界圧以上の目的圧に昇圧する上記ステップと、
サブミクロン乳化液を第1目的温度に加熱して予備加熱サブミクロン乳化液を生成するステップであって、第1目的温度が約150℃から350℃の範囲である上記ステップと、
予備加熱サブミクロン乳化液を反応区域に供給するステップと、
予備加熱サブミクロン乳化液を反応区域で水の臨界温度以上である第2目的温度に加熱して、予備加熱サブミクロン乳化液の少なくとも一部の炭化水素がクラッキングを受けて高温適合混合物を生成し、反応区域は、内側を有する主反応器を含み、主反応器は水の臨界温度及び臨界圧力を超える温度及び圧力に耐えることができ、反応区域には外部供給触媒が本質的になく、外部供給水素源が本質的にないステップと、
高温適合混合物を反応区域から除去し、高温適合混合物を冷却して冷却適合混合物を形成するステップと、
冷却適合混合物を分離して品質改良された石油及び回収水を生成するステップであって、品質改良された石油は重質油と比較してアスファルテン、硫黄、窒素又は金属含有物質の量が少ない品質改良された重質油である上記ステップとを含む上記方法。 - 前記サブミクロン乳化液が化学乳化剤を外部供給せずに生成される、請求項1に記載の方法。
- 前記サブミクロン乳化液が1ミクロン未満の平均直径を有する油滴を含む、請求項1に記載の方法。
- 回収水を超臨界条件下で酸化して処理水流を形成するステップと、
処理水流と供給水を混ぜ合わせることにより処理水流をリサイクルするステップとをさらに含む、請求項1に記載の方法。 - 前記混合区域が超音波発生器を含む、請求項1に記載の方法。
- 重質油と供給水とを混合する前記ステップが、超音波発生器から発生する超音波を使用して混合効果を生成することを含み、超音波はある周波数で作用する、請求項5に記載の方法。
- 超音波発生器から発生する超音波の前記周波数が約10から50kHzの範囲で作用する、請求項6に記載の方法。
- 超音波発生器から発生する超音波の周波数の前記範囲が約20から40kHzである、請求項7に記載の方法。
- 前記サブミクロン乳化液が10から120分の範囲の混合区域内の滞留時間を有する、請求項1に記載の方法。
- 外部供給触媒がなく、外部供給水素源がない環境で重質油を品質改良する方法であって、
重質油を供給水と混合区域内で混合して重質油/水混合物を形成するステップであって、重質油/水混合物はわずかに高い温度で混合され、わずかに高い温度は150℃を超えず、混合区域は超音波発生器を含む上記ステップと、
重質油/水混合物を混合区域内で超音波に曝してサブミクロン乳化液を生成して、サブミクロン乳化液は化学乳化剤を外部供給せずに生成されるステップと、
サブミクロン乳化液を高圧ポンプ輸送手段を用いて予備加熱区域にポンプ輸送するステップであって、高圧ポンプ輸送手段はサブミクロン乳化液の圧力を水の臨界圧を超える目的圧に昇圧する上記ステップと、
サブミクロン乳化液を予備加熱区域で約150℃から350℃の範囲である第1目的温度に加熱して予備加熱サブミクロン乳化液を形成するステップと、
予備加熱サブミクロン乳化液を反応区域に供給するステップと、
反応区域内の温度を水の臨界温度以上である第2目的温度に昇温して、予備加熱サブミクロン乳化液の少なくとも一部の炭化水素がクラッキングを受けて高温適合混合物を形成し、反応区域には外部供給触媒が本質的になく、外部供給水素源が本質的にないステップと、
高温適合混合物を冷却及び減圧して減圧適合混合物を形成するステップと、
少なくとも1台の気液分離器を用いて減圧適合混合物を気体部分及び液体部分に分離するステップと、
少なくとも1台の油水分離器を用いて液体部分を品質改良された石油及び回収水流に分離するステップと、
少なくとも1台の油水分離器から回収される品質改良された石油を集めるステップであって、品質改良された石油は重質油と比較してアスファルテン、硫黄、窒素又は金属含有物質の量が少ない品質改良された石油である上記ステップと、
回収水を超臨界条件下で酸化して処理水流を形成するステップと、
処理水流と供給水を混ぜ合わせることにより処理水流をリサイクルするステップとを含む上記方法。 - 前記サブミクロン乳化液が1ミクロン未満の平均直径を有する油滴を含む、請求項10に記載の方法。
- 重質油と水流とを混合する前記ステップが、超音波発生器から発生する超音波を使用して混合効果を生成することを含み、超音波はある周波数で作用する、請求項10に記載の方法。
- 超音波発生器から発生する超音波の前記周波数が約10から50kHzの範囲である、請求項12に記載の方法。
- 超音波発生器から発生する超音波の周波数の前記範囲が20から40kHzである、請求項13に記載の方法。
- 前記超音波発生器が、スティック型超音波発生器、コイン型超音波発生器、又はそれらの組合せから成る群から選択される、請求項10に記載の方法。
- 前記サブミクロン乳化液が10から120分の範囲の混合区域内の滞留時間を有する、請求項10に記載の方法。
- 外部供給触媒がなく、外部供給水素源がない環境で重質油を品質改良する方法であって、
重質油を供給水と混合区域内で混ぜ合わせて重質油/水混合物を形成するステップであって、重質油/水混合物はわずかに高い温度で混合され、わずかに高い温度は150℃を超えない上記ステップと、
重質油/水混合物を超音波エネルギーに曝すステップと、
水の超臨界圧以上の圧力下の間に、重質油/水混合物中の少なくとも一部の炭化水素がクラッキングを受けるように、重質油/水混合物を水の超臨界温度以上の温度に加熱するステップと、
重質油/水混合物を冷却及び減圧して減圧適合混合物を形成するステップと、
少なくとも1台の気液分離器を用いて減圧適合混合物を気体部分及び液体部分に分離するステップと、
少なくとも1台の油水分離器を用いて液体部分を品質改良された石油及び回収水流に分離するステップと、
少なくとも1台の油水分離器から回収される品質改良された石油を集めるステップであって、品質改良された石油は重質油と比較してアスファルテン、硫黄、窒素又は金属含有物質の量が少ない品質改良された重質油である上記ステップとを含む上記方法。 - 外部供給触媒がなく、外部供給水素源がない環境で重質油を品質改良する装置であって、
重質油を供給水とわずかに高い温度で混ぜ合わせて重質油/水混合物を生成できる混合区域であって、超音波発生器を含む上記混合区域と、
混合区域に流体的に接続される予備加熱区域であって、重質油/水混合物を約350℃までの温度に加熱できる上記予備加熱区域と、
重質油/水混合物の圧力を少なくとも水の臨界圧力に昇圧できる高圧ポンプ輸送手段と、
内側部分を有する主反応器を含み、予備加熱区域と流体的に接続された反応区域であって、主反応器は少なくとも水の臨界温度と同じ高さの温度に耐えることができ、主反応器は水の臨界圧を超える圧力に耐えることができ、反応区域には外部供給触媒が本質的になく、外部供給水素源が本質的にない上記反応区域とを含む上記装置。 - 圧力調整装置と、
圧力調整装置に流体的に接続された気液分離装置であり、液体流及び気体流を生成することができる上記気液分離装置と、
液体流を通じて気液分離装置に流体的に接続された油水分離装置であり、回収水流及び品質改良された炭化水素流を生成できる上記油水分離装置とをさらに含む、請求項18に記載の装置。 - 前記回収水流をリサイクルして供給水と混ぜ合わせることができ、回収水流に流体的に接続される酸化反応器をさらに含み、酸化反応器が酸化を通じて回収水流を清浄化できる、請求項19に記載の装置。
Applications Claiming Priority (11)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US99066207P | 2007-11-28 | 2007-11-28 | |
US99065807P | 2007-11-28 | 2007-11-28 | |
US99064107P | 2007-11-28 | 2007-11-28 | |
US99064807P | 2007-11-28 | 2007-11-28 | |
US99067007P | 2007-11-28 | 2007-11-28 | |
US60/990,670 | 2007-11-28 | ||
US60/990,648 | 2007-11-28 | ||
US60/990,662 | 2007-11-28 | ||
US60/990,658 | 2007-11-28 | ||
US60/990,641 | 2007-11-28 | ||
PCT/US2008/084526 WO2009073440A2 (en) | 2007-11-28 | 2008-11-24 | Process to upgrade heavy oil by hot pressurized water and ultrasonic wave generating pre-mixer |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2011505464A true JP2011505464A (ja) | 2011-02-24 |
JP5202644B2 JP5202644B2 (ja) | 2013-06-05 |
Family
ID=40674560
Family Applications (5)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010536103A Expired - Fee Related JP5346036B2 (ja) | 2007-11-28 | 2008-11-24 | 水素の供給を用いない重質及び高ワックス質原油のアップグレード法 |
JP2010536096A Active JP5202644B2 (ja) | 2007-11-28 | 2008-11-24 | 高温加圧水及び超音波発生予混合器により重質油を品質改良する方法 |
JP2010536099A Expired - Fee Related JP5290317B2 (ja) | 2007-11-28 | 2008-11-24 | 原油の酸性度を低下させる方法 |
JP2010536102A Active JP5269089B2 (ja) | 2007-11-28 | 2008-11-24 | 熱加圧水によって高ワックス質原油をアップグレードする方法 |
JP2010536095A Expired - Fee Related JP5514118B2 (ja) | 2007-11-28 | 2008-11-25 | 高温加圧水及び回収流体により全原油を品質改良する方法 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010536103A Expired - Fee Related JP5346036B2 (ja) | 2007-11-28 | 2008-11-24 | 水素の供給を用いない重質及び高ワックス質原油のアップグレード法 |
Family Applications After (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010536099A Expired - Fee Related JP5290317B2 (ja) | 2007-11-28 | 2008-11-24 | 原油の酸性度を低下させる方法 |
JP2010536102A Active JP5269089B2 (ja) | 2007-11-28 | 2008-11-24 | 熱加圧水によって高ワックス質原油をアップグレードする方法 |
JP2010536095A Expired - Fee Related JP5514118B2 (ja) | 2007-11-28 | 2008-11-25 | 高温加圧水及び回収流体により全原油を品質改良する方法 |
Country Status (10)
Country | Link |
---|---|
US (7) | US8025790B2 (ja) |
EP (5) | EP2231823A2 (ja) |
JP (5) | JP5346036B2 (ja) |
KR (6) | KR101606680B1 (ja) |
CN (5) | CN101970610B (ja) |
BR (5) | BRPI0819687A2 (ja) |
DK (1) | DK2240556T3 (ja) |
ES (1) | ES2582392T3 (ja) |
MX (5) | MX2010005854A (ja) |
WO (5) | WO2009073442A2 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013515141A (ja) * | 2009-12-21 | 2013-05-02 | サウジ アラビアン オイル カンパニー | 水、酸化剤及び重質油を超臨界の温度及び圧力条件下で混合し、最終的にその混合物をマイクロ波処理にかけるプロセス |
Families Citing this family (106)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10310199B4 (de) * | 2003-03-06 | 2007-09-20 | Kronotec Ag | Holzfaserplatte und Verfahren zu deren Herstellung |
US7943036B2 (en) | 2009-07-21 | 2011-05-17 | Chevron U.S.A. Inc. | Systems and methods for producing a crude product |
KR101606680B1 (ko) | 2007-11-28 | 2016-03-25 | 사우디 아라비안 오일 컴퍼니 | 고도로 밀납을 함유하는 원유의 유동점 및 파라핀 함량을 낮추기 위한 연속 공정 |
US20090159498A1 (en) * | 2007-12-20 | 2009-06-25 | Chevron U.S.A. Inc. | Intergrated process for in-field upgrading of hydrocarbons |
US8236169B2 (en) * | 2009-07-21 | 2012-08-07 | Chevron U.S.A. Inc | Systems and methods for producing a crude product |
US7931797B2 (en) | 2009-07-21 | 2011-04-26 | Chevron U.S.A. Inc. | Systems and methods for producing a crude product |
US8759242B2 (en) | 2009-07-21 | 2014-06-24 | Chevron U.S.A. Inc. | Hydroprocessing catalysts and methods for making thereof |
US9068132B2 (en) | 2009-07-21 | 2015-06-30 | Chevron U.S.A. Inc. | Hydroprocessing catalysts and methods for making thereof |
US8927448B2 (en) | 2009-07-21 | 2015-01-06 | Chevron U.S.A. Inc. | Hydroprocessing catalysts and methods for making thereof |
US8551323B2 (en) * | 2009-08-31 | 2013-10-08 | Chevron U.S.A. Inc. | Systems and methods for hydroprocessing a heavy oil feedstock |
US8197670B2 (en) * | 2010-02-23 | 2012-06-12 | Chevron U.S.A. Inc. | Process for upgrading hydrocarbons and device for use therein |
US8444843B2 (en) | 2010-04-15 | 2013-05-21 | Saudi Arabian Oil Company | Electrocatalytic dissociation of water for hydrodesulfurization of hydrocarbon feedstock |
US9005432B2 (en) * | 2010-06-29 | 2015-04-14 | Saudi Arabian Oil Company | Removal of sulfur compounds from petroleum stream |
US9382485B2 (en) * | 2010-09-14 | 2016-07-05 | Saudi Arabian Oil Company | Petroleum upgrading process |
US9039889B2 (en) * | 2010-09-14 | 2015-05-26 | Saudi Arabian Oil Company | Upgrading of hydrocarbons by hydrothermal process |
CN102453513B (zh) * | 2010-10-22 | 2014-03-05 | 中国石油化工股份有限公司 | 降低催化裂化烟气中硫氧化物含量的方法 |
CN102453514B (zh) * | 2010-10-22 | 2014-03-05 | 中国石油化工股份有限公司 | 减少催化裂化烟气中二氧化碳排放量的方法 |
CA2815882C (en) * | 2010-10-27 | 2020-10-27 | 1555771 Alberta Ltd. | Non-aqueous hydrocarbon recovery |
US8894846B2 (en) * | 2010-12-23 | 2014-11-25 | Stephen Lee Yarbro | Using supercritical fluids to refine hydrocarbons |
WO2012091382A2 (ko) * | 2010-12-28 | 2012-07-05 | 에스케이이노베이션 주식회사 | 초임계 용매를 이용한 중질 탄화수소 유분의 수소화 분해 공정 |
KR101759351B1 (ko) | 2010-12-28 | 2017-07-21 | 에스케이이노베이션 주식회사 | 초임계 용매를 이용한 중질 탄화수소 유분의 수소화 분해 공정 |
US9018124B2 (en) | 2010-12-30 | 2015-04-28 | Chevron U.S.A. Inc. | Hydroprocessing catalysts and methods for making thereof |
US8535518B2 (en) * | 2011-01-19 | 2013-09-17 | Saudi Arabian Oil Company | Petroleum upgrading and desulfurizing process |
WO2012143972A1 (ja) * | 2011-04-19 | 2012-10-26 | 日揮株式会社 | 改質油の製造方法、及び改質油製造装置 |
EP2702121B1 (en) * | 2011-04-27 | 2019-04-10 | Saudi Arabian Oil Company | Sulfone cracking using supercritical water |
CN104039434B (zh) * | 2011-10-31 | 2015-11-25 | 沙特阿拉伯石油公司 | 用于改质石油的超临界水工艺 |
CA2757962C (en) | 2011-11-08 | 2013-10-15 | Imperial Oil Resources Limited | Processing a hydrocarbon stream using supercritical water |
KR101515690B1 (ko) | 2011-12-30 | 2015-05-06 | 연세대학교 산학협력단 | 중질 탄화수소 유분 및 목질계 바이오매스의 개질 방법 |
CN103320160B (zh) * | 2012-03-22 | 2016-01-13 | 中国石油化工股份有限公司 | 一种含酸原油的加工方法 |
AU2013280585A1 (en) * | 2012-06-27 | 2014-12-18 | Shell Internationale Research Maatschappij B.V. | Petroleum recovery process and system |
JP2014074111A (ja) * | 2012-10-03 | 2014-04-24 | Jgc Corp | 炭化水素油の処理方法及び炭化水素油の処理装置 |
KR101938171B1 (ko) | 2012-10-31 | 2019-01-14 | 대우조선해양 주식회사 | 백업 기능을 가지는 브라인 및 베이스오일 공급 시스템과 브라인 및 베이스오일의 백업 공급 방법 |
US9687823B2 (en) | 2012-12-14 | 2017-06-27 | Chevron U.S.A. Inc. | Hydroprocessing co-catalyst compositions and methods of introduction thereof into hydroprocessing units |
US9321037B2 (en) | 2012-12-14 | 2016-04-26 | Chevron U.S.A., Inc. | Hydroprocessing co-catalyst compositions and methods of introduction thereof into hydroprocessing units |
KR101898734B1 (ko) * | 2012-12-20 | 2018-09-13 | 에스케이에너지 주식회사 | 원유 탈염 시스템 |
KR101422483B1 (ko) * | 2012-12-21 | 2014-07-23 | 삼성중공업 주식회사 | 고점도의 원유 채굴방법 |
US8715488B1 (en) | 2013-01-07 | 2014-05-06 | Clean Global Energy, Inc. | Method and apparatus for making hybrid crude oils and fuels |
US10907455B2 (en) * | 2013-02-08 | 2021-02-02 | Chevron U.S.A. Inc. | System and process for recovering hydrocarbons using a supercritical fluid |
US11242735B2 (en) * | 2013-02-08 | 2022-02-08 | Chevron U.S.A. Inc. | System and process for recovering hydrocarbons using a supercritical fluid |
CA2843041C (en) | 2013-02-22 | 2017-06-13 | Anschutz Exploration Corporation | Method and system for removing hydrogen sulfide from sour oil and sour water |
US11440815B2 (en) | 2013-02-22 | 2022-09-13 | Anschutz Exploration Corporation | Method and system for removing hydrogen sulfide from sour oil and sour water |
US9708196B2 (en) | 2013-02-22 | 2017-07-18 | Anschutz Exploration Corporation | Method and system for removing hydrogen sulfide from sour oil and sour water |
US9364773B2 (en) | 2013-02-22 | 2016-06-14 | Anschutz Exploration Corporation | Method and system for removing hydrogen sulfide from sour oil and sour water |
US10215399B2 (en) | 2013-03-14 | 2019-02-26 | The Babcock & Wilcox Company | Small supercritical once-thru steam generator |
JP6248253B2 (ja) * | 2013-08-29 | 2017-12-20 | 国立大学法人秋田大学 | 溶液中の重質油回収方法及び回収システム |
CN105518101A (zh) * | 2013-09-13 | 2016-04-20 | 通用电气公司 | 处理用于产生超临界密相流体的采出水和注入地质层用于烃生产 |
US9771527B2 (en) | 2013-12-18 | 2017-09-26 | Saudi Arabian Oil Company | Production of upgraded petroleum by supercritical water |
DK3097165T3 (da) * | 2014-01-20 | 2022-09-12 | Applied Res Associates Inc | Højeffektiv flydepunktsnedsættende fremgangsmåde |
US20170003264A1 (en) * | 2014-01-24 | 2017-01-05 | The University Of Wyoming Research Corporation D/B/A Western Research Institute | Volatile Hydrocarbon Separation and Analysis Apparatus and Methods |
FR3018274B1 (fr) * | 2014-03-10 | 2016-04-08 | Innoveox | Procede de traitement de dechets organiques par oxydation hydrothermale |
US9505678B2 (en) | 2014-05-12 | 2016-11-29 | Saudi Arabian Oil Company | Process to produce aromatics from crude oil |
CN105368487A (zh) * | 2014-08-12 | 2016-03-02 | 罗杰·K·洛特 | 用于加工烃类的超声波处理 |
KR101568615B1 (ko) * | 2014-11-28 | 2015-11-11 | 연세대학교 산학협력단 | 중질 탄화수소 유분의 연속적 처리 방법 |
CN104492412B (zh) * | 2015-01-07 | 2016-08-24 | 苏珂 | 一种石油脱酸催化剂的制备方法 |
JP6556243B2 (ja) * | 2015-01-28 | 2019-08-07 | アプライド リサーチ アソシエーツ, インコーポレイテッド | 水熱浄化プロセス |
US9802176B2 (en) * | 2015-03-24 | 2017-10-31 | Saudi Arabian Oil Company | Method for mixing in a hydrocarbon conversion process |
US10012064B2 (en) | 2015-04-09 | 2018-07-03 | Highlands Natural Resources, Plc | Gas diverter for well and reservoir stimulation |
US10344204B2 (en) | 2015-04-09 | 2019-07-09 | Diversion Technologies, LLC | Gas diverter for well and reservoir stimulation |
US9452434B1 (en) | 2015-04-17 | 2016-09-27 | LLT International (Ireland) Ltd. | Providing wear resistance in a reactor configured to facilitate chemical reactions and/or comminution of solid feed materials using shockwaves created in a supersonic gaseous vortex |
US10427129B2 (en) * | 2015-04-17 | 2019-10-01 | LLT International (Ireland) Ltd. | Systems and methods for facilitating reactions in gases using shockwaves produced in a supersonic gaseous vortex |
US10434488B2 (en) | 2015-08-11 | 2019-10-08 | LLT International (Ireland) Ltd. | Systems and methods for facilitating dissociation of methane utilizing a reactor designed to generate shockwaves in a supersonic gaseous vortex |
KR102250734B1 (ko) * | 2015-09-25 | 2021-05-11 | 에스케이이노베이션 주식회사 | 원유 내의 유기산 및 금속의 제거 방법 |
US9926497B2 (en) * | 2015-10-16 | 2018-03-27 | Saudi Arabian Oil Company | Method to remove metals from petroleum |
CN105403347B (zh) * | 2015-11-27 | 2019-09-06 | 中国石油化工股份有限公司 | Co2驱最小混相压力测定方法及专用装置 |
US10066172B2 (en) * | 2015-12-15 | 2018-09-04 | Saudi Arabian Oil Company | Supercritical water upgrading process to produce paraffinic stream from heavy oil |
EP3370858B1 (en) | 2015-12-15 | 2022-01-26 | Saudi Arabian Oil Company | Supercritical reactor systems and processes for petroleum upgrading |
US10066176B2 (en) | 2015-12-15 | 2018-09-04 | Saudi Arabian Oil Company | Supercritical water upgrading process to produce high grade coke |
US10011790B2 (en) | 2015-12-15 | 2018-07-03 | Saudi Arabian Oil Company | Supercritical water processes for upgrading a petroleum-based composition while decreasing plugging |
KR101696376B1 (ko) | 2016-03-25 | 2017-01-12 | 서울시립대학교 산학협력단 | 촉매를 이용한 바이오 오일의 안정화 방법 |
US10982520B2 (en) | 2016-04-27 | 2021-04-20 | Highland Natural Resources, PLC | Gas diverter for well and reservoir stimulation |
JP6886480B2 (ja) * | 2016-07-08 | 2021-06-16 | アプライド リサーチ アソシエーツ, インコーポレイテッド | 超臨界水分離プロセス |
CN106350101B (zh) * | 2016-09-19 | 2018-01-23 | 华东理工大学 | 基于亚/超临界水中重芳烃自组装效应的重质油预处理的方法及应用 |
US10106748B2 (en) | 2017-01-03 | 2018-10-23 | Saudi Arabian Oil Company | Method to remove sulfur and metals from petroleum |
US10577546B2 (en) | 2017-01-04 | 2020-03-03 | Saudi Arabian Oil Company | Systems and processes for deasphalting oil |
US10815434B2 (en) | 2017-01-04 | 2020-10-27 | Saudi Arabian Oil Company | Systems and processes for power generation |
CN106701161B (zh) * | 2017-02-24 | 2018-05-08 | 哈尔滨工业大学 | 声空化协同供氢剂的重油改质系统与方法 |
US10752847B2 (en) | 2017-03-08 | 2020-08-25 | Saudi Arabian Oil Company | Integrated hydrothermal process to upgrade heavy oil |
US10703999B2 (en) | 2017-03-14 | 2020-07-07 | Saudi Arabian Oil Company | Integrated supercritical water and steam cracking process |
US10689587B2 (en) * | 2017-04-26 | 2020-06-23 | Saudi Arabian Oil Company | Systems and processes for conversion of crude oil |
KR102061960B1 (ko) * | 2017-05-11 | 2020-01-03 | 서울대학교산학협력단 | 초임계 유체를 이용한 아스팔텐 저감 방법 |
RU2655394C1 (ru) * | 2017-05-25 | 2018-05-28 | Государственное унитарное предприятие "Институт нефтехимпереработки Республики Башкортостан" (ГУП "ИНХП РБ") | Способ подготовки высоковязкой нефти |
KR101928204B1 (ko) | 2017-07-19 | 2018-12-11 | 성균관대학교산학협력단 | 중질유분 개질 방법 |
CN108452842B (zh) * | 2017-10-27 | 2020-11-06 | 中国石油天然气股份有限公司 | 催化裂化油浆糠醛抽出油加氢催化剂及其制备方法与应用 |
DE102017127417B4 (de) | 2017-11-21 | 2021-01-21 | Egm-Holding-International Gmbh | Reaktionskammer |
KR102180627B1 (ko) * | 2017-12-04 | 2020-11-18 | 주식회사 엘지화학 | 자동화된 시료 열분해 장치 |
JP2021054873A (ja) * | 2018-01-12 | 2021-04-08 | 独立行政法人石油天然ガス・金属鉱物資源機構 | 高粘度重質油からの炭化水素の生産方法、及び生産システム |
CN108251093A (zh) * | 2018-01-31 | 2018-07-06 | 南京工业大学 | 一种用于稠油热采的超临界流体的制备系统和方法 |
US11286434B2 (en) * | 2018-02-26 | 2022-03-29 | Saudi Arabian Oil Company | Conversion process using supercritical water |
US11021659B2 (en) * | 2018-02-26 | 2021-06-01 | Saudi Arabia Oil Company | Additives for supercritical water process to upgrade heavy oil |
US10927313B2 (en) * | 2018-04-11 | 2021-02-23 | Saudi Arabian Oil Company | Supercritical water process integrated with visbreaker |
WO2019222307A1 (en) * | 2018-05-15 | 2019-11-21 | Worcester Polytechnic Institute | Water-assisted zeolite upgrading of oils |
KR102098148B1 (ko) * | 2018-06-22 | 2020-04-07 | 서울대학교산학협력단 | 아스팔텐 저감 방법 |
US10526552B1 (en) | 2018-10-12 | 2020-01-07 | Saudi Arabian Oil Company | Upgrading of heavy oil for steam cracking process |
CN109650518A (zh) * | 2019-01-30 | 2019-04-19 | 中国原子能科学研究院 | 利用超临界水氧化处理有机废液的方法 |
US11118439B2 (en) | 2019-12-06 | 2021-09-14 | Saudi Arabian Oil Company | Displacing fluid for enhanced oil recovery |
US11384299B2 (en) | 2019-12-19 | 2022-07-12 | Saudi Arabian Oil Company | Systems and processes for upgrading and converting crude oil to petrochemicals through steam cracking |
CN113123740A (zh) * | 2019-12-30 | 2021-07-16 | 四川宏华石油设备有限公司 | 一种钻井液冷却系统 |
US11459511B2 (en) | 2020-04-09 | 2022-10-04 | Saudi Arabian Oil Company | Crude stabilizer bypass |
US11345861B2 (en) | 2020-06-22 | 2022-05-31 | Saudi Arabian Oil Company | Production of linear olefins from heavy oil |
US11845902B2 (en) | 2020-06-23 | 2023-12-19 | Saudi Arabian Oil Company | Online analysis in a gas oil separation plant (GOSP) |
US11781075B2 (en) | 2020-08-11 | 2023-10-10 | Applied Research Associates, Inc. | Hydrothermal purification process |
US11548784B1 (en) | 2021-10-26 | 2023-01-10 | Saudi Arabian Oil Company | Treating sulfur dioxide containing stream by acid aqueous absorption |
US11926799B2 (en) | 2021-12-14 | 2024-03-12 | Saudi Arabian Oil Company | 2-iso-alkyl-2-(4-hydroxyphenyl)propane derivatives used as emulsion breakers for crude oil |
CN114561229A (zh) * | 2022-02-28 | 2022-05-31 | 中海油天津化工研究设计院有限公司 | 一种节能的超临界水改质油品的方法 |
US20240059984A1 (en) * | 2022-08-19 | 2024-02-22 | Uop Llc | Processes and apparatuses for heating a hydrocarbon feed stream for a reactor |
US11898107B1 (en) | 2022-12-16 | 2024-02-13 | Saudi Arabian Oil Company | Systems and methods for processing hydrocarbon feedstocks |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001139960A (ja) * | 1999-11-11 | 2001-05-22 | Mitsubishi Materials Corp | 重質油の軽質化方法及びその装置 |
JP2002155286A (ja) * | 2000-11-20 | 2002-05-28 | Mitsubishi Materials Corp | 重質炭素資源の改質方法 |
JP2004000825A (ja) * | 2002-05-31 | 2004-01-08 | Kurita Water Ind Ltd | 水熱酸化反応方法 |
JP2006169401A (ja) * | 2004-12-16 | 2006-06-29 | Chubu Electric Power Co Inc | 改質プラント及び方法 |
Family Cites Families (108)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US496779A (en) * | 1893-05-02 | Tile or brick machine | ||
US2135332A (en) | 1935-12-31 | 1938-11-01 | Gasoline Prod Co Inc | Conversion of hydrocarbon oil |
US2623596A (en) * | 1950-05-16 | 1952-12-30 | Atlantic Refining Co | Method for producing oil by means of carbon dioxide |
US3325395A (en) * | 1965-04-19 | 1967-06-13 | Mcdowell Wellman Eng Co | Travelling grate method for the recovery of oil from oil bearing minerals |
US4005005A (en) * | 1974-05-31 | 1977-01-25 | Standard Oil Company (Indiana) | Process for recovering and upgrading hydrocarbons from tar sands |
US3989618A (en) | 1974-05-31 | 1976-11-02 | Standard Oil Company (Indiana) | Process for upgrading a hydrocarbon fraction |
US3948755A (en) * | 1974-05-31 | 1976-04-06 | Standard Oil Company | Process for recovering and upgrading hydrocarbons from oil shale and tar sands |
US3960706A (en) * | 1974-05-31 | 1976-06-01 | Standard Oil Company | Process for upgrading a hydrocarbon fraction |
US3983027A (en) * | 1974-07-01 | 1976-09-28 | Standard Oil Company (Indiana) | Process for recovering upgraded products from coal |
US3948754A (en) * | 1974-05-31 | 1976-04-06 | Standard Oil Company | Process for recovering and upgrading hydrocarbons from oil shale and tar sands |
US4113446A (en) * | 1975-07-22 | 1978-09-12 | Massachusetts Institute Of Technology | Gasification process |
JPS5250306A (en) | 1975-10-22 | 1977-04-22 | Kureha Chem Ind Co Ltd | Method and apparatus for decoking |
US4118797A (en) * | 1977-10-25 | 1978-10-03 | Energy And Minerals Research Co. | Ultrasonic emulsifier and method |
US4243514A (en) * | 1979-05-14 | 1981-01-06 | Engelhard Minerals & Chemicals Corporation | Preparation of FCC charge from residual fractions |
US4543190A (en) * | 1980-05-08 | 1985-09-24 | Modar, Inc. | Processing methods for the oxidation of organics in supercritical water |
US4448251A (en) * | 1981-01-08 | 1984-05-15 | Uop Inc. | In situ conversion of hydrocarbonaceous oil |
US4550198A (en) * | 1982-11-04 | 1985-10-29 | Georgia Tech Research Institute | Purification of terephthalic acid by supercritical fluid extraction |
US4446012A (en) * | 1982-12-17 | 1984-05-01 | Allied Corporation | Process for production of light hydrocarbons by treatment of heavy hydrocarbons with water |
US4443325A (en) * | 1982-12-23 | 1984-04-17 | Mobil Oil Corporation | Conversion of residua to premium products via thermal treatment and coking |
US4483761A (en) | 1983-07-05 | 1984-11-20 | The Standard Oil Company | Upgrading heavy hydrocarbons with supercritical water and light olefins |
US4684372A (en) * | 1983-11-02 | 1987-08-04 | Petroleum Fermentations N.V. | Combustion of viscous hydrocarbons |
US4529037A (en) * | 1984-04-16 | 1985-07-16 | Amoco Corporation | Method of forming carbon dioxide mixtures miscible with formation crude oils |
US4543177A (en) * | 1984-06-11 | 1985-09-24 | Allied Corporation | Production of light hydrocarbons by treatment of heavy hydrocarbons with water |
US4839326A (en) | 1985-04-22 | 1989-06-13 | Exxon Research And Engineering Company | Promoted molybdenum and tungsten sulfide catalysts, their preparation and use |
US4818370A (en) * | 1986-07-23 | 1989-04-04 | Cities Service Oil And Gas Corporation | Process for converting heavy crudes, tars, and bitumens to lighter products in the presence of brine at supercritical conditions |
US4753666A (en) * | 1986-07-24 | 1988-06-28 | Chevron Research Company | Distillative processing of CO2 and hydrocarbons for enhanced oil recovery |
US4733724A (en) * | 1986-12-30 | 1988-03-29 | Texaco Inc. | Viscous oil recovery method |
US4840725A (en) * | 1987-06-19 | 1989-06-20 | The Standard Oil Company | Conversion of high boiling liquid organic materials to lower boiling materials |
US4813370A (en) * | 1988-04-21 | 1989-03-21 | Capamaggio Scott A | Bookmarker |
US5110443A (en) * | 1989-02-14 | 1992-05-05 | Canadian Occidental Petroleum Ltd. | Converting heavy hydrocarbons into lighter hydrocarbons using ultrasonic reactor |
US4951561A (en) * | 1989-06-06 | 1990-08-28 | Kraft General Foods, Inc. | Apparatus for fluid-solid bed processing |
US5096567A (en) | 1989-10-16 | 1992-03-17 | The Standard Oil Company | Heavy oil upgrading under dense fluid phase conditions utilizing emulsified feed stocks |
US5851381A (en) * | 1990-12-07 | 1998-12-22 | Idemitsu Kosan Co., Ltd. | Method of refining crude oil |
US5133877A (en) * | 1991-03-29 | 1992-07-28 | The United States Of America As Represented By The United States Department Of Energy | Conversion of hazardous materials using supercritical water oxidation |
EP0721360A1 (en) * | 1992-11-09 | 1996-07-17 | SIPIN, Anatole J. | Controlled fluid transfer system |
US5496464A (en) * | 1993-01-04 | 1996-03-05 | Natural Resources Canada | Hydrotreating of heavy hydrocarbon oils in supercritical fluids |
IT1263961B (it) * | 1993-02-24 | 1996-09-05 | Eniricerche Spa | Procedimento per la deasfaltazione e la demetallazione di residui petroliferi |
US5316659A (en) | 1993-04-02 | 1994-05-31 | Exxon Research & Engineering Co. | Upgrading of bitumen asphaltenes by hot water treatment |
US5389240A (en) * | 1993-08-02 | 1995-02-14 | Uop | Naphthenic acid removal as an adjunct to liquid hydrocarbon sweetening |
CA2200945C (en) * | 1994-10-27 | 2006-06-06 | Minas Robert Apelian | Wax hydroisomerization process |
US5720551A (en) * | 1994-10-28 | 1998-02-24 | Shechter; Tal | Forming emulsions |
FR2727634A1 (fr) * | 1994-12-06 | 1996-06-07 | Electrolyse L | Procede en milieu reducteur de transformation chimique de structures chimiques complexes dans un fluide supercritique |
US5674405A (en) * | 1995-07-28 | 1997-10-07 | Modar, Inc. | Method for hydrothermal oxidation |
US5725054A (en) * | 1995-08-22 | 1998-03-10 | Board Of Supervisors Of Louisiana State University And Agricultural & Mechanical College | Enhancement of residual oil recovery using a mixture of nitrogen or methane diluted with carbon dioxide in a single-well injection process |
DE69631901T2 (de) * | 1995-08-25 | 2005-02-03 | Exxonmobil Research And Engineering Co. | Verfahren zur verminderung der korrosivität und acidität von rohöl |
US5885440A (en) * | 1996-10-01 | 1999-03-23 | Uop Llc | Hydrocracking process with integrated effluent hydrotreating zone |
US5871637A (en) * | 1996-10-21 | 1999-02-16 | Exxon Research And Engineering Company | Process for upgrading heavy oil using alkaline earth metal hydroxide |
US5778977A (en) * | 1997-01-03 | 1998-07-14 | Marathon Oil Company | Gravity concentrated carbon dioxide for process |
US5904839A (en) | 1997-06-06 | 1999-05-18 | Exxon Research And Engineering Co. | Process for upgrading heavy oil using lime |
US6268447B1 (en) * | 1998-12-18 | 2001-07-31 | Univation Technologies, L.L.C. | Olefin polymerization catalyst |
US5928502A (en) * | 1997-08-29 | 1999-07-27 | Exxon Research And Engineering Co. | Process for reducing total acid number of crude oil |
US5871636A (en) * | 1997-08-29 | 1999-02-16 | Exxon Research And Engineering Company | Catalytic reduction of acidity of crude oils in the absence of hydrogen |
JP3572176B2 (ja) * | 1997-09-03 | 2004-09-29 | 三菱重工業株式会社 | コンバインド・サイクル発電方法及び発電装置 |
US6016867A (en) * | 1998-06-24 | 2000-01-25 | World Energy Systems, Incorporated | Upgrading and recovery of heavy crude oils and natural bitumens by in situ hydrovisbreaking |
DE19835479B4 (de) | 1998-08-06 | 2007-06-06 | Kjeld Andersen | Verfahren zum katalytischen Entfernen von Metallverbindungen aus Schwerölen |
JP2000100850A (ja) | 1998-09-24 | 2000-04-07 | Ebara Udylite Kk | 低融点金属バンプの形成方法 |
JP2000104311A (ja) | 1998-09-30 | 2000-04-11 | Matsushita Electric Works Ltd | 衛生洗浄装置 |
JP2000109850A (ja) | 1998-10-07 | 2000-04-18 | Mitsubishi Materials Corp | 重質油の発電設備用流体燃料への転換方法及びその装置 |
JP3489478B2 (ja) | 1999-03-31 | 2004-01-19 | 三菱マテリアル株式会社 | 超臨界水を用いた炭化水素資源の転換方法 |
US6190541B1 (en) | 1999-05-11 | 2001-02-20 | Exxon Research And Engineering Company | Process for treatment of petroleum acids (LAW824) |
JP2001192676A (ja) | 2000-01-11 | 2001-07-17 | Mitsubishi Materials Corp | 炭化水素資源等の高効率転換方法 |
US20010035006A1 (en) * | 2000-02-01 | 2001-11-01 | Danan Dou | Sulfur trap in NOx adsorber systems for enhanced sulfur resistance |
US20020076212A1 (en) * | 2000-04-24 | 2002-06-20 | Etuan Zhang | In situ thermal processing of a hydrocarbon containing formation producing a mixture with oxygenated hydrocarbons |
FR2814967B1 (fr) * | 2000-10-10 | 2003-11-14 | Commissariat Energie Atomique | Procede et dispositif pour l'oxydation en eau supercritique de matieres |
US6547957B1 (en) | 2000-10-17 | 2003-04-15 | Texaco, Inc. | Process for upgrading a hydrocarbon oil |
US6475396B1 (en) * | 2000-11-14 | 2002-11-05 | Hydroprocessing, Llc | Apparatus and method for applying an oxidant in a hydrothermal oxidation process |
US20020086150A1 (en) * | 2000-12-28 | 2002-07-04 | Hazlebeck David A. | System and method for hydrothermal reactions-two layer liner |
US6454936B1 (en) | 2001-03-09 | 2002-09-24 | Exxonmobil Research And Engineering Company | Removal of acids from oils |
CA2348947A1 (en) * | 2001-03-19 | 2002-09-19 | Venanzio Di Tullio | A process for the catalytic reduction of heavy oils, kerogens, plastics, bio-masses, sludges and organic waste to light hydrocarbon liquids, carbon dioxide and amines |
US20020157991A1 (en) * | 2001-03-27 | 2002-10-31 | Mason Thomas G. | Disaggregation of asphaltenes in incompatible petroleum oil mixtures |
US7081196B2 (en) * | 2001-05-10 | 2006-07-25 | Mark Cullen | Treatment of crude oil fractions, fossil fuels, and products thereof with sonic energy |
JP3791363B2 (ja) | 2001-08-07 | 2006-06-28 | 株式会社日立製作所 | 重質油の軽質化方法 |
WO2003025098A2 (en) * | 2001-09-17 | 2003-03-27 | Southwest Research Institute | Pretreatment processes for heavy oil and carbonaceous materials |
JP3724438B2 (ja) * | 2002-03-08 | 2005-12-07 | 株式会社日立製作所 | 超臨界水による重質油の処理方法と処理装置及び重質油処理装置を備えた発電システム |
JP3669340B2 (ja) | 2002-03-27 | 2005-07-06 | 株式会社日立製作所 | 石油の精製方法と精製装置および発電プラント |
NO20033230D0 (no) * | 2003-07-16 | 2003-07-16 | Statoil Asa | Fremgangsmåte for utvinning og oppgradering av olje |
JP4098181B2 (ja) | 2003-08-05 | 2008-06-11 | 株式会社日立製作所 | 重質油の処理方法及び重質油類処理システム |
US7435330B2 (en) * | 2003-10-07 | 2008-10-14 | Hitachi, Ltd. | Heavy oil reforming method, an apparatus therefor, and gas turbine power generation system |
JP4942911B2 (ja) | 2003-11-28 | 2012-05-30 | 東洋エンジニアリング株式会社 | 水素化分解触媒、重質油を水素化分解する方法 |
NL1027766C2 (nl) * | 2003-12-19 | 2006-07-13 | Shell Int Research | Systemen, methoden en katalysatoren voor het produceren van een ruwe-oliehoudend product. |
BRPI0405563A (pt) * | 2003-12-19 | 2005-09-20 | Shell Int Research | Métodos de produzir um produto de petróleo bruto e combustìvel de transporte, combustìvel de aquecimento, lubrificantes ou substâncias quìmicas e produto de petróleo bruto |
US7144498B2 (en) * | 2004-01-30 | 2006-12-05 | Kellogg Brown & Root Llc | Supercritical hydrocarbon conversion process |
US20060016723A1 (en) * | 2004-07-07 | 2006-01-26 | California Institute Of Technology | Process to upgrade oil using metal oxides |
JP4555010B2 (ja) | 2004-07-15 | 2010-09-29 | 株式会社日立製作所 | 改質燃料焚きガスタービン及びその運転方法 |
US7381320B2 (en) * | 2004-08-30 | 2008-06-03 | Kellogg Brown & Root Llc | Heavy oil and bitumen upgrading |
WO2006037368A1 (en) | 2004-10-04 | 2006-04-13 | Petroleo Brasileiro S.A.-Petrobras | Process for reducing the organic acid content of hydrocarbon feedstocks |
JP2006104311A (ja) | 2004-10-05 | 2006-04-20 | Mitsubishi Materials Corp | 未利用重質油の改質方法及びその装置。 |
SE529006C2 (sv) * | 2004-11-15 | 2007-04-03 | Chematur Eng Ab | Förfarande och system för överkritisk vattenoxidation av en ström som innehåller oxiderbart material |
SE528840C2 (sv) * | 2004-11-15 | 2007-02-27 | Chematur Eng Ab | Reaktor och förfarande för överkritisk vattenoxidation |
US20070045881A1 (en) * | 2005-09-01 | 2007-03-01 | Aguirre Everardo L M | Air humidifier |
US7947165B2 (en) * | 2005-09-14 | 2011-05-24 | Yeda Research And Development Co.Ltd | Method for extracting and upgrading of heavy and semi-heavy oils and bitumens |
US7938954B2 (en) * | 2005-12-16 | 2011-05-10 | Chevron U.S.A. Inc. | Systems and methods for producing a crude product |
DE102006008809B4 (de) | 2006-02-25 | 2008-04-24 | Junghans Microtec Gmbh | Mechanischer Raketenzünder |
DE602006019698D1 (de) * | 2006-05-30 | 2011-03-03 | Environmental Consulting Catalysts & Processes For A Sustainable Dev | Verfahren zur Herstellung von leichten Kohlenwasserstoffen aus natürlichen Bitumen oder Schwerölen |
US20070289898A1 (en) * | 2006-06-14 | 2007-12-20 | Conocophillips Company | Supercritical Water Processing of Extra Heavy Crude in a Slurry-Phase Up-Flow Reactor System |
US7730958B2 (en) * | 2006-08-31 | 2010-06-08 | David Randolph Smith | Method and apparatus to enhance hydrocarbon production from wells |
JP2008094829A (ja) * | 2006-10-12 | 2008-04-24 | Kocat Inc | Mc型均一触媒およびo2/co2混合気体を用いた有機酸またはその誘導体の製造方法 |
US20080099378A1 (en) * | 2006-10-31 | 2008-05-01 | Chevron U.S.A. Inc. | Process and reactor for upgrading heavy hydrocarbon oils |
US20080099377A1 (en) * | 2006-10-31 | 2008-05-01 | Chevron U.S.A. Inc. | Process for upgrading heavy hydrocarbon oils |
US20080099376A1 (en) * | 2006-10-31 | 2008-05-01 | Chevron U.S.A. Inc. | Upgrading heavy hydrocarbon oils |
US20080099374A1 (en) * | 2006-10-31 | 2008-05-01 | Chevron U.S.A. Inc. | Reactor and process for upgrading heavy hydrocarbon oils |
EP2099624A1 (en) | 2006-12-01 | 2009-09-16 | The Four Wheeled Motorcycle Company Limited | Suspension system |
WO2008085436A1 (en) | 2006-12-27 | 2008-07-17 | Case Western Reserve University | Situated simulation for training, education, and therapy |
US8052848B2 (en) * | 2007-06-26 | 2011-11-08 | The Penn State Research Foundation | Ultrasonic and microwave methods for enhancing the rate of a chemical reaction and apparatus for such methods |
KR101606680B1 (ko) * | 2007-11-28 | 2016-03-25 | 사우디 아라비안 오일 컴퍼니 | 고도로 밀납을 함유하는 원유의 유동점 및 파라핀 함량을 낮추기 위한 연속 공정 |
US20090166261A1 (en) | 2007-12-28 | 2009-07-02 | Chevron U.S.A. Inc. | Upgrading heavy hydrocarbon oils |
US20090166262A1 (en) | 2007-12-28 | 2009-07-02 | Chevron U.S.A. Inc. | Simultaneous metal, sulfur and nitrogen removal using supercritical water |
US8394260B2 (en) * | 2009-12-21 | 2013-03-12 | Saudi Arabian Oil Company | Petroleum upgrading process |
-
2008
- 2008-11-24 KR KR1020157033396A patent/KR101606680B1/ko active IP Right Grant
- 2008-11-24 BR BRPI0819687A patent/BRPI0819687A2/pt active Search and Examination
- 2008-11-24 MX MX2010005854A patent/MX2010005854A/es unknown
- 2008-11-24 CN CN200880125755.7A patent/CN101970610B/zh not_active Expired - Fee Related
- 2008-11-24 US US12/277,270 patent/US8025790B2/en active Active
- 2008-11-24 WO PCT/US2008/084530 patent/WO2009073442A2/en active Application Filing
- 2008-11-24 CN CN200880125762.7A patent/CN101970609B/zh not_active Expired - Fee Related
- 2008-11-24 WO PCT/US2008/084526 patent/WO2009073440A2/en active Application Filing
- 2008-11-24 US US12/277,268 patent/US9295957B2/en active Active
- 2008-11-24 BR BRPI0820363-6A patent/BRPI0820363B1/pt not_active IP Right Cessation
- 2008-11-24 MX MX2010005855A patent/MX2010005855A/es unknown
- 2008-11-24 EP EP08857382A patent/EP2231823A2/en not_active Ceased
- 2008-11-24 EP EP08855883.8A patent/EP2240556B1/en not_active Not-in-force
- 2008-11-24 WO PCT/US2008/084542 patent/WO2009073446A2/en active Application Filing
- 2008-11-24 US US12/277,275 patent/US7740065B2/en active Active
- 2008-11-24 DK DK08855883.8T patent/DK2240556T3/en active
- 2008-11-24 JP JP2010536103A patent/JP5346036B2/ja not_active Expired - Fee Related
- 2008-11-24 US US12/277,263 patent/US10010839B2/en active Active
- 2008-11-24 JP JP2010536096A patent/JP5202644B2/ja active Active
- 2008-11-24 KR KR1020107014239A patent/KR101419977B1/ko active IP Right Grant
- 2008-11-24 WO PCT/US2008/084543 patent/WO2009073447A2/en active Application Filing
- 2008-11-24 CN CN2008801257542A patent/CN101983227B/zh not_active Expired - Fee Related
- 2008-11-24 KR KR1020107013449A patent/KR20100105611A/ko not_active Application Discontinuation
- 2008-11-24 KR KR1020107014333A patent/KR101504384B1/ko active IP Right Grant
- 2008-11-24 EP EP08858300.0A patent/EP2222819B1/en active Active
- 2008-11-24 CN CN200880125761.2A patent/CN101970611B/zh not_active Expired - Fee Related
- 2008-11-24 MX MX2010005852A patent/MX357637B/es active IP Right Grant
- 2008-11-24 US US12/277,255 patent/US8815081B2/en active Active
- 2008-11-24 JP JP2010536099A patent/JP5290317B2/ja not_active Expired - Fee Related
- 2008-11-24 MX MX2010005851A patent/MX2010005851A/es unknown
- 2008-11-24 KR KR1020107014331A patent/KR101577082B1/ko active IP Right Grant
- 2008-11-24 BR BRPI0820360A patent/BRPI0820360B1/pt not_active IP Right Cessation
- 2008-11-24 JP JP2010536102A patent/JP5269089B2/ja active Active
- 2008-11-24 EP EP08857144A patent/EP2245119A2/en not_active Ceased
- 2008-11-24 BR BRPI0820362 patent/BRPI0820362A2/pt not_active IP Right Cessation
- 2008-11-25 KR KR1020107014334A patent/KR101419978B1/ko active IP Right Grant
- 2008-11-25 EP EP08865032.0A patent/EP2231824B1/en not_active Not-in-force
- 2008-11-25 JP JP2010536095A patent/JP5514118B2/ja not_active Expired - Fee Related
- 2008-11-25 ES ES08865032.0T patent/ES2582392T3/es active Active
- 2008-11-25 MX MX2010005853A patent/MX2010005853A/es active IP Right Grant
- 2008-11-25 CN CN200880125753.8A patent/CN102159675B/zh not_active Expired - Fee Related
- 2008-11-25 BR BRPI0819674A patent/BRPI0819674A2/pt not_active Application Discontinuation
- 2008-11-25 WO PCT/US2008/084520 patent/WO2009082585A2/en active Application Filing
-
2011
- 2011-08-18 US US13/212,509 patent/US8216520B2/en active Active
-
2014
- 2014-07-23 US US14/338,749 patent/US9656230B2/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001139960A (ja) * | 1999-11-11 | 2001-05-22 | Mitsubishi Materials Corp | 重質油の軽質化方法及びその装置 |
JP2002155286A (ja) * | 2000-11-20 | 2002-05-28 | Mitsubishi Materials Corp | 重質炭素資源の改質方法 |
JP2004000825A (ja) * | 2002-05-31 | 2004-01-08 | Kurita Water Ind Ltd | 水熱酸化反応方法 |
JP2006169401A (ja) * | 2004-12-16 | 2006-06-29 | Chubu Electric Power Co Inc | 改質プラント及び方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013515141A (ja) * | 2009-12-21 | 2013-05-02 | サウジ アラビアン オイル カンパニー | 水、酸化剤及び重質油を超臨界の温度及び圧力条件下で混合し、最終的にその混合物をマイクロ波処理にかけるプロセス |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5202644B2 (ja) | 高温加圧水及び超音波発生予混合器により重質油を品質改良する方法 | |
CA2784295C (en) | Process mixing water, oxidant and heavy oil under supercritical temperature and pressure conditions and eventually submitting the mixture to microwave treating | |
JP6080758B2 (ja) | 石油流からの硫黄化合物の除去 | |
WO2009085461A1 (en) | Upgrading heavy hydrocarbon oils |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20111004 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20121228 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20130111 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20130212 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5202644 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20160222 Year of fee payment: 3 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |