JP2010537005A5 - - Google Patents
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- Publication number
- JP2010537005A5 JP2010537005A5 JP2010522032A JP2010522032A JP2010537005A5 JP 2010537005 A5 JP2010537005 A5 JP 2010537005A5 JP 2010522032 A JP2010522032 A JP 2010522032A JP 2010522032 A JP2010522032 A JP 2010522032A JP 2010537005 A5 JP2010537005 A5 JP 2010537005A5
- Authority
- JP
- Japan
- Prior art keywords
- aluminum
- sca
- poly
- dicarboxylic acid
- acid ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 claims 14
- -1 aromatic dicarboxylic acid ester Chemical class 0.000 claims 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 5
- 229910052782 aluminium Inorganic materials 0.000 claims 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 5
- 239000003054 catalyst Substances 0.000 claims 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 3
- 239000003795 chemical substances by application Substances 0.000 claims 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 3
- 229910000077 silane Inorganic materials 0.000 claims 3
- 150000003623 transition metal compounds Chemical class 0.000 claims 3
- 239000003112 inhibitor Substances 0.000 claims 2
- HRAQMGWTPNOILP-UHFFFAOYSA-N 4-Ethoxy ethylbenzoate Chemical compound CCOC(=O)C1=CC=C(OCC)C=C1 HRAQMGWTPNOILP-UHFFFAOYSA-N 0.000 claims 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 claims 1
- 125000005907 alkyl ester group Chemical group 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 150000001983 dialkylethers Chemical class 0.000 claims 1
- 235000014113 dietary fatty acids Nutrition 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 229930195729 fatty acid Natural products 0.000 claims 1
- 239000000194 fatty acid Substances 0.000 claims 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 claims 1
- 229920005646 polycarboxylate Polymers 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US95788807P | 2007-08-24 | 2007-08-24 | |
| US60/957,888 | 2007-08-24 | ||
| PCT/US2008/073882 WO2009029487A1 (en) | 2007-08-24 | 2008-08-21 | Self-limiting catalyst system with controlled aluminum rto sca ratio and method |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010537005A JP2010537005A (ja) | 2010-12-02 |
| JP2010537005A5 true JP2010537005A5 (enExample) | 2011-10-06 |
| JP5576281B2 JP5576281B2 (ja) | 2014-08-20 |
Family
ID=39768748
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010522032A Active JP5576281B2 (ja) | 2007-08-24 | 2008-08-21 | 制御されたアルミニウム対ｓｃａ比を有する自己制御触媒系および方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (3) | US10647788B2 (enExample) |
| EP (2) | EP2185599B1 (enExample) |
| JP (1) | JP5576281B2 (enExample) |
| KR (2) | KR101716609B1 (enExample) |
| CN (3) | CN101848946B (enExample) |
| BR (2) | BRPI0815290A2 (enExample) |
| ES (1) | ES2711342T3 (enExample) |
| MX (3) | MX2010002118A (enExample) |
| PL (2) | PL2185609T3 (enExample) |
| RU (1) | RU2470947C2 (enExample) |
| WO (2) | WO2009029487A1 (enExample) |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101716609B1 (ko) | 2007-08-24 | 2017-03-14 | 더블유.알. 그레이스 앤드 캄파니-콘. | 조절된 알루미늄 대 ｓｃａ 비를 갖는 자기-제한성 촉매 시스템 및 방법 |
| WO2009141831A2 (en) * | 2008-05-21 | 2009-11-26 | Reliance Industries Limited | A catalyst system for polymerization of olefins |
| CN102186889B (zh) * | 2008-08-21 | 2013-11-06 | 陶氏环球技术有限责任公司 | 具有混合的选择性控制剂的催化剂组合物和使用它的聚合反应方法 |
| BRPI0912920B1 (pt) | 2008-08-21 | 2019-07-09 | W. R. Grace & Co. -Conn | Processo de polimerização e copolímero de impacto de propileno |
| US8507717B2 (en) | 2008-12-31 | 2013-08-13 | Dow Global Technologies Llc | Production of substituted phenylene aromatic diesters |
| CN102325808B (zh) | 2008-12-31 | 2014-03-12 | 陶氏环球技术有限责任公司 | 包含取代的1,2-亚苯基芳族二酯内给体的前催化剂组合物及方法 |
| CN101554595B (zh) | 2009-05-18 | 2011-02-02 | 中国石油化工股份有限公司 | 一种烯烃聚合用催化剂载体及其制备方法和应用 |
| KR101784537B1 (ko) | 2009-12-02 | 2017-10-11 | 더블유.알. 그레이스 앤드 캄파니-콘. | 폴리프로필렌 제조를 위한 촉매 중 내부 공여체로서 2개의 원자로 브릿지된 디카르보네이트 화합물 |
| MY158466A (en) | 2009-12-02 | 2016-10-14 | Grace W R & Co | Three and four atom bridged dicarbonate compounds as internal donors in catalysts for polypropylene manufacture |
| MY156361A (en) * | 2009-12-21 | 2016-02-15 | Grace W R & Co | Gas-phase polymerization process having multiple flow regimes |
| US20120116029A1 (en) * | 2010-11-08 | 2012-05-10 | Van Egmond Jan W | Method for polymerizing polypropylene |
| US20120157295A1 (en) | 2010-12-21 | 2012-06-21 | Linfeng Chen | Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product |
| US9382342B2 (en) | 2010-12-21 | 2016-07-05 | W. R. Grace & Co.-Conn. | Procatalyst composition with alkoxyalkyl 2-propenoate internal electron donor and polymer from same |
| US9382343B2 (en) | 2010-12-21 | 2016-07-05 | W. R. Grace & Co.-Conn. | Procatalyst composition with alkoxypropyl ester internal electron donor and polymer from same |
| US20120157645A1 (en) * | 2010-12-21 | 2012-06-21 | Linfeng Chen | Procatalyst Composition with Alkoxypropyl Ester Internal Electron Donor and Polymer From Same |
| CN102174134B (zh) * | 2011-01-27 | 2013-07-24 | 大唐国际化工技术研究院有限公司 | 制备高熔融指数聚丙烯的催化剂组合物、制备方法和用途 |
| US10647790B2 (en) | 2011-06-30 | 2020-05-12 | W. R. Grace & Co.-Conn. | Process for gas-phase polymerization having high bed bulk density |
| CN103044583B (zh) * | 2011-10-13 | 2015-10-28 | 中国石油化工股份有限公司 | 烯烃聚合物及其制备方法 |
| CN104066755B (zh) * | 2011-11-15 | 2017-07-14 | 格雷斯公司 | 用于聚合聚丙烯的方法 |
| EP2607384A1 (en) | 2011-12-21 | 2013-06-26 | Basell Poliolefine Italia S.r.l. | Catalyst system for the polymerization of olefins |
| JP6466395B2 (ja) * | 2013-03-14 | 2019-02-06 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | プロピレン／ブテンインターポリマー生成システム及び方法 |
| ES2963034T3 (es) * | 2013-08-19 | 2024-03-25 | Dow Global Technologies Llc | Método para producir un polímero a base de etileno en un procedimiento de polimerización usando un agente de autolimitación |
| TWI639626B (zh) * | 2013-09-30 | 2018-11-01 | 中國石油化工科技開發有限公司 | Catalyst composition for olefin polymerization and application thereof |
| WO2015073221A1 (en) * | 2013-11-15 | 2015-05-21 | Dow Global Technologies Llc | A polyolefin composition and method of producing the same |
| RU2702633C1 (ru) * | 2013-11-15 | 2019-10-09 | У.Р. Грейс Энд Ко.-Конн | Полимер на основе пропилена с уменьшенной высокомолекулярной частью |
| RU2731442C2 (ru) | 2013-11-21 | 2020-09-02 | У.Р. Грейс Энд Ко.-Конн | Получение полимеров на основе пропилена с высоким содержанием сомономера |
| EP3074429B1 (en) | 2013-11-26 | 2024-01-24 | W.R. Grace & CO. - CONN. | Producing propylene impact copolymers and products |
| CN104774281A (zh) * | 2014-01-09 | 2015-07-15 | 金成豪 | 用于烯烃聚合的催化剂组合物及其应用 |
| US11236222B2 (en) * | 2016-08-30 | 2022-02-01 | W.R. Grace & Co.-Conn. | Catalyst system for the production of polyolefins and method of making and using same |
| RU2692246C1 (ru) * | 2017-06-15 | 2019-06-24 | Индийская Нефтяная Корпорация Лимитэд | Внешний донор для полимеризации олефинов |
| CN109096420B (zh) * | 2017-06-21 | 2021-05-11 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂和烯烃聚合方法 |
| CN109096424A (zh) * | 2017-06-21 | 2018-12-28 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂和烯烃聚合方法 |
| CN109096421A (zh) * | 2017-06-21 | 2018-12-28 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂和烯烃聚合方法 |
| CN109096418A (zh) * | 2017-06-21 | 2018-12-28 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂和烯烃聚合方法 |
| CN109096417A (zh) * | 2017-06-21 | 2018-12-28 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂和烯烃聚合方法 |
| US11613592B2 (en) | 2018-02-07 | 2023-03-28 | Reliance Industries Limited | Ziegler-Natta catalyst system with self-extinguishing properties suitable for olefin polymerization |
| CN108409896B (zh) * | 2018-04-04 | 2021-02-05 | 朴蓝聚烯烃科技发展（上海）有限公司 | 齐格勒-纳塔催化剂组合物及其应用 |
| US11990859B2 (en) | 2018-05-28 | 2024-05-21 | Borealis Ag | Devices for a photovoltaic (PV) module |
| WO2020064190A1 (en) | 2018-09-26 | 2020-04-02 | Borealis Ag | Propylene copolymer composition with excellent optical and mechanical properties |
| CN109517099B (zh) * | 2018-11-27 | 2021-07-30 | 山东鲁晶化工科技有限公司 | 一种外给电子体、烯烃聚合催化剂体系及其应用 |
| WO2020190681A1 (en) * | 2019-03-15 | 2020-09-24 | W.R. Grace & Co.-Conn. | Catalyst system for producing olefin polymers with no fines |
| US20230312782A1 (en) | 2020-06-29 | 2023-10-05 | W.R. Grace & Co.-Conn. | Phthalate-free polypropylene homopolymer having high stiffness properties |
| EP4384556A4 (en) * | 2021-08-09 | 2025-07-09 | Grace W R & Co | METHOD FOR PRODUCING A GRANULAR POLYOLEFIN RESIN HAVING AN INCREASED CONTROLLED APPARENT DENSITY |
| CN118339199A (zh) * | 2021-10-06 | 2024-07-12 | 格雷斯公司 | 用于制备聚丙烯无规共聚物的气相方法 |
| CN116228676A (zh) * | 2023-01-09 | 2023-06-06 | 上海烟草集团有限责任公司 | 一种烟草检测用流化床内气体流速的调整方法 |
| WO2025124978A1 (en) * | 2023-12-11 | 2025-06-19 | Sabic Global Technologies B.V. | Self-extinguishing catalyst system for propylene polymerization |
Family Cites Families (71)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1209255B (it) * | 1980-08-13 | 1989-07-16 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine. |
| DE3247919A1 (de) * | 1982-12-24 | 1984-06-28 | Basf Ag, 6700 Ludwigshafen | Verfahren zum herstellen von homo- und copolymerisaten von (alpha)-monoolefinen mittels einer ziegler-natta-katalysatorsystems |
| US4746762A (en) | 1985-01-17 | 1988-05-24 | Mobil Oil Corporation | Upgrading light olefins in a turbulent fluidized catalyst bed reactor |
| IN168393B (enExample) | 1986-02-28 | 1991-03-23 | Shell Oil Co | |
| EP0284005B1 (en) * | 1987-03-23 | 1991-12-18 | Idemitsu Petrochemical Co. Ltd. | Method of production of polyolefins |
| JPH0796573B2 (ja) | 1987-03-31 | 1995-10-18 | 出光石油化学株式会社 | プロピレン重合体の製造方法 |
| US5093415A (en) | 1987-05-19 | 1992-03-03 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing stereoregular polymers having a narrow molecular weight distribution |
| US4882380A (en) | 1987-07-07 | 1989-11-21 | Union Carbide Chemicals And Plastics Company Inc. | Process for the production of impact polypropylene copolymers |
| DE69019046T2 (de) | 1989-03-02 | 1995-09-07 | Mitsui Petrochemical Ind | Verfahren zur Polymerisation von Olefinen und Katalysator für Olefinpolymerisation. |
| JPH07119290B2 (ja) | 1989-11-28 | 1995-12-20 | 出光石油化学株式会社 | 軟質ポリプロピレンフィルム及びその製造方法 |
| FR2669639A1 (fr) | 1990-11-27 | 1992-05-29 | Atochem | Cocatalyseur de polymerisation du propylene a base de silane et de monoether. |
| US5432244A (en) | 1990-12-12 | 1995-07-11 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the production of polypropylene |
| US5218052A (en) | 1991-02-04 | 1993-06-08 | Amoco Corporation | Olefin polymerization and copolymerization process |
| JP3443848B2 (ja) | 1992-11-04 | 2003-09-08 | 東ソー株式会社 | プロピレンブロック共重合体の製造方法 |
| TW300235B (enExample) * | 1992-12-04 | 1997-03-11 | Mitsui Petroleum Chemicals Ind | |
| GB9300318D0 (en) | 1993-01-08 | 1993-03-03 | Oxford Analytical Instr Ltd | Improvements relating to sample monitoring |
| US5462999A (en) * | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| TW354792B (en) | 1993-08-13 | 1999-03-21 | Mitsui Petrochemical Ind | Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer |
| IT1271420B (it) | 1993-08-30 | 1997-05-28 | Himont Inc | Composizioni poliolefiniche aventi un elevato bilancio di rigidita' e resilienza |
| JP3508187B2 (ja) | 1993-11-10 | 2004-03-22 | チッソ株式会社 | プロピレン・エチレンブロック共重合体の連続製造法 |
| JPH07149812A (ja) | 1993-12-02 | 1995-06-13 | Tonen Corp | α−オレフィン重合用触媒 |
| US6133385A (en) | 1994-04-06 | 2000-10-17 | Fina Technology, Inc. | Catalyst systems for improved stereoselectivity and broader molecular weight distribution in polymerization of olefins |
| JPH0812717A (ja) * | 1994-07-01 | 1996-01-16 | Mitsubishi Chem Corp | プロピレン−エチレン系ブロック共重合体の製造方法 |
| US5529850A (en) | 1994-07-05 | 1996-06-25 | Montell North America Inc. | Fibers produced from crystalline propylene polymers having high melt flow rate values and a narrow molecular weight distribution |
| JP3354729B2 (ja) * | 1994-11-28 | 2002-12-09 | サンアロマー株式会社 | オレフィン重合用触媒およびオレフィン重合体の製造方法 |
| IL117114A (en) | 1995-02-21 | 2000-02-17 | Montell North America Inc | Components and catalysts for the polymerization ofolefins |
| IT1275573B (it) | 1995-07-20 | 1997-08-07 | Spherilene Spa | Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine |
| CN1119364C (zh) | 1995-08-31 | 2003-08-27 | 智索公司 | 丙烯－乙烯共聚物组合物及其制备方法 |
| US6087459A (en) | 1998-05-14 | 2000-07-11 | Exxon Chemical Patents Inc. | Polymeric materials formed using blends of electron donors |
| WO1999058585A1 (en) | 1998-05-14 | 1999-11-18 | Exxon Chemical Patents Inc. | Polymeric materials formed using blends of electron donors |
| US6576697B1 (en) | 1998-09-02 | 2003-06-10 | Thayer A. Brown, Jr. | Malleable high density polymer material |
| JP3182130B2 (ja) | 1999-01-25 | 2001-07-03 | 出光石油化学株式会社 | オレフィン重合体の製造方法 |
| ES2267504T3 (es) | 1999-03-15 | 2007-03-16 | Basell Poliolefine Italia S.R.L. | Componentes y catalizadores para la polimerizacion de olefinas. |
| WO2000063261A1 (en) * | 1999-04-15 | 2000-10-26 | Basell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
| AU6512100A (en) | 1999-08-03 | 2001-02-19 | Union Carbide Chemicals & Plastics Technology Corporation | Method of detecting and correcting local defluidization and channeling in fluidized-bed reactors for polymerization |
| US6391985B1 (en) | 1999-10-21 | 2002-05-21 | Union Carbide Chemicals & Plastics Technology Corporation | High condensing mode polyolefin production under turbulent conditions in a fluidized bed |
| ES2214070T5 (es) | 1999-11-12 | 2010-09-06 | Borealis Technology Oy | Copolimeros heterofasicos. |
| US6815512B2 (en) | 2000-02-28 | 2004-11-09 | Union Carbide Chemicals & Plastics Technology Corporation | Polyolefin production using condensing mode in fluidized beds, with liquid phase enrichment and bed injection |
| US6460412B1 (en) | 2000-10-27 | 2002-10-08 | Union Carbide Chemicals & Plastics Technology Corporation | Detection of dynamic fluidized bed level in a fluidized bed polymerization reactor using ultrasonic waves or microwaves |
| US6825146B2 (en) | 2001-05-29 | 2004-11-30 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization catalyst compositions and method of preparation |
| EP1444276A1 (en) | 2001-11-06 | 2004-08-11 | Dow Global Technologies, Inc. | Isotactic propylene copolymers, their preparation and use |
| US6906160B2 (en) | 2001-11-06 | 2005-06-14 | Dow Global Technologies Inc. | Isotactic propylene copolymer fibers, their preparation and use |
| AU2002358255A1 (en) | 2002-01-03 | 2003-07-30 | Bp Corporation North America Inc. | Gas phase olefin polymerizations using dual donor catalyst systems |
| CN1169845C (zh) | 2002-02-07 | 2004-10-06 | 中国石油化工股份有限公司 | 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用 |
| EP1515996A2 (en) * | 2002-06-14 | 2005-03-23 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition and polymerization process using mixtures of electron donors |
| BRPI0313639B1 (pt) | 2002-08-19 | 2016-03-15 | Toho Titanium Co Ltd | constituinte de catalisador, seu catalisador para polimerização ou copolimerização de alfa-olefina, método para polimerizar alfa-olefina, e método para produzir copolímeros em blocos ou aleatórios da alfa-olefina |
| US6753390B2 (en) | 2002-09-04 | 2004-06-22 | Univation Technologies, Llc | Gas phase polymerization process |
| US6818711B2 (en) | 2003-01-01 | 2004-11-16 | Fina Technology, Inc. | Polymerization of olefins using a ziegler-natta catalyst system having an external electron donor |
| US6759489B1 (en) | 2003-05-20 | 2004-07-06 | Eastern Petrochemical Co. | Fluidized bed methods for making polymers |
| RU2345094C2 (ru) | 2003-09-23 | 2009-01-27 | Дау Глобал Текнолоджиз Инк. | Композиция катализатора с самоограничением реакции, включающая внутренний донор в виде сложного эфира дикарбоновой кислоты, и способ полимеризации пропилена |
| KR101146472B1 (ko) | 2003-09-23 | 2012-05-21 | 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 엘엘씨 | 모노카르복실산 에스테르 내부 공여체를 갖는 자가-소멸촉매 조성물 및 프로필렌 중합 방법 |
| KR101114748B1 (ko) * | 2003-09-23 | 2012-03-05 | 다우 글로벌 테크놀로지스 엘엘씨 | 자가 제한 촉매 조성물 및 프로필렌 중합 방법 |
| EP1548054B1 (en) | 2003-12-26 | 2016-03-23 | Japan Polypropylene Corporation | Polypropylene-based resin composition and molded article thereof |
| JP3953466B2 (ja) | 2004-02-23 | 2007-08-08 | 日本ポリプロ株式会社 | ポリプロピレン系樹脂組成物及びその成形体 |
| JP2005232395A (ja) * | 2004-02-23 | 2005-09-02 | Toho Catalyst Co Ltd | オレフィン類重合用触媒およびこれを用いたオレフィン類重合体の製造方法 |
| WO2005103094A1 (en) | 2004-04-07 | 2005-11-03 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization procatalyst compositions and method of preparation |
| US7226977B2 (en) | 2004-04-19 | 2007-06-05 | Sunoco, Inc. ( R&M) | High melt flow rate thermoplastic polyolefins produced in-reactor |
| US20070224641A1 (en) | 2004-06-16 | 2007-09-27 | Campbell Richard E | Apparatus and method for ziegler-natta research |
| EP1827673B1 (en) | 2004-12-20 | 2012-02-01 | Basell Poliolefine Italia S.r.l. | Process and apparatus for the polymerization of propylene |
| WO2007035885A2 (en) | 2005-09-20 | 2007-03-29 | Emerge Medsystems, Llc | Embolic filter device and related systems and methods |
| JP2007254671A (ja) | 2006-03-24 | 2007-10-04 | Japan Polypropylene Corp | ポリプロピレンの製造方法 |
| CN102351966B (zh) | 2006-02-03 | 2014-04-09 | 日本聚丙烯公司 | 丙烯类聚合物及其制备方法、丙烯类聚合物组合物以及由该组合物制成的成型制品 |
| US20070270558A1 (en) * | 2006-05-16 | 2007-11-22 | Paul Keith Scherrer | Pulsing olefin polymerization fluidized-bed reactors |
| MX2008015361A (es) | 2006-06-01 | 2008-12-16 | Sunoco Inc R&M | Polipropileno de alta cristalinidad de indice de flujo de fusion alto. |
| EP1935938A1 (en) | 2006-12-18 | 2008-06-25 | Borealis Technology Oy | Improved high melt flow heterophasic polypropylene copolymers |
| KR101716609B1 (ko) | 2007-08-24 | 2017-03-14 | 더블유.알. 그레이스 앤드 캄파니-콘. | 조절된 알루미늄 대 ｓｃａ 비를 갖는 자기-제한성 촉매 시스템 및 방법 |
| BRPI0912920B1 (pt) | 2008-08-21 | 2019-07-09 | W. R. Grace & Co. -Conn | Processo de polimerização e copolímero de impacto de propileno |
| KR101510775B1 (ko) | 2008-11-24 | 2015-04-10 | 삼성전자주식회사 | 동기식 펄스 플라즈마 에칭 장비 |
| US8507717B2 (en) | 2008-12-31 | 2013-08-13 | Dow Global Technologies Llc | Production of substituted phenylene aromatic diesters |
| CN102325808B (zh) * | 2008-12-31 | 2014-03-12 | 陶氏环球技术有限责任公司 | 包含取代的1,2-亚苯基芳族二酯内给体的前催化剂组合物及方法 |
| KR101906621B1 (ko) * | 2010-12-21 | 2018-10-10 | 더블유.알. 그레이스 앤드 캄파니-콘. | 고 용융 유동 프로필렌-기재 중합체의 생산 공정 및 이로부터의 생산물 |
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