JP2008500729A - 安定かつ反復可能なプラズマイオン注入方法及び装置 - Google Patents
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- 238000000034 method Methods 0.000 title claims abstract description 104
- 238000005468 ion implantation Methods 0.000 title claims abstract description 47
- 150000002500 ions Chemical class 0.000 claims abstract description 88
- 239000000758 substrate Substances 0.000 claims abstract description 88
- 238000002513 implantation Methods 0.000 claims abstract description 70
- 230000008569 process Effects 0.000 claims abstract description 53
- 238000012545 processing Methods 0.000 claims abstract description 51
- 230000000694 effects Effects 0.000 claims abstract description 13
- 230000003993 interaction Effects 0.000 claims abstract description 8
- 238000002347 injection Methods 0.000 claims description 38
- 239000007924 injection Substances 0.000 claims description 38
- 239000000463 material Substances 0.000 claims description 10
- 238000010943 off-gassing Methods 0.000 claims description 10
- 230000008859 change Effects 0.000 claims description 6
- 230000005684 electric field Effects 0.000 claims description 4
- 235000012431 wafers Nutrition 0.000 description 30
- 239000007789 gas Substances 0.000 description 20
- 229920002120 photoresistant polymer Polymers 0.000 description 13
- 238000010586 diagram Methods 0.000 description 9
- 239000004065 semiconductor Substances 0.000 description 9
- 238000001802 infusion Methods 0.000 description 8
- 230000006870 function Effects 0.000 description 7
- 239000007943 implant Substances 0.000 description 6
- 241000894007 species Species 0.000 description 6
- 239000004020 conductor Substances 0.000 description 5
- 239000002019 doping agent Substances 0.000 description 5
- 238000013459 approach Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 238000004868 gas analysis Methods 0.000 description 3
- 238000010884 ion-beam technique Methods 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 2
- RBFQJDQYXXHULB-UHFFFAOYSA-N arsane Chemical compound [AsH3] RBFQJDQYXXHULB-UHFFFAOYSA-N 0.000 description 2
- 229910000070 arsenic hydride Inorganic materials 0.000 description 2
- 230000005591 charge neutralization Effects 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 230000001603 reducing effect Effects 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 229910017049 AsF5 Inorganic materials 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 240000005373 Panax quinquefolius Species 0.000 description 1
- YBGKQGSCGDNZIB-UHFFFAOYSA-N arsenic pentafluoride Chemical compound F[As](F)(F)(F)F YBGKQGSCGDNZIB-UHFFFAOYSA-N 0.000 description 1
- 238000005513 bias potential Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000004993 emission spectroscopy Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 238000010849 ion bombardment Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
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- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/26—Bombardment with radiation
- H01L21/263—Bombardment with radiation with high-energy radiation
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32009—Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
- H01J37/32412—Plasma immersion ion implantation
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
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- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/48—Ion implantation
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- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/22—Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities
- H01L21/223—Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities using diffusion into or out of a solid from or into a gaseous phase
- H01L21/2236—Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities using diffusion into or out of a solid from or into a gaseous phase from or into a plasma phase
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Abstract
【選択図】図4
Description
Claims (33)
- 基板のプラズマイオン注入のための方法であって、
処理チャンバ、前記処理チャンバ内にプラズマを生成するためのソース、前記処理チャンバ内で基板を保持するためのプラテン、及びプラズマから基板へイオンを加速するための注入パルスを生成するパルスソースを含むプラズマイオン注入装置を与える工程と、
ドーズ率を有する注入処理に従い基板のプラズマイオン注入を実行する工程と、
注入処理中に、前記ドーズ率を変更する工程と、
から成る方法。 - 請求項1に記載の方法であって、ドーズ率を変更する工程は、注入処理中にドーズ率を増加する工程から成る、ところの方法。
- 請求項1に記載の方法であって、ドーズ率を変更する工程は、注入処理中にひとつまたはそれ以上の工程においてドーズ率を増加する工程から成る、ところの方法。
- 請求項1に記載の方法であって、ドーズ率を変更する工程は、注入処理の少なくとも一部の間に、ドーズ率を連続的に増加する工程から成る、ところの方法。
- 請求項1に記載の方法であって、ドーズ率を変更する工程は、注入パルスのパルス幅を変更する工程から成る、ところの方法。
- 請求項1に記載の方法であって、ドーズ率を変更する工程は、注入パルスのパルス周波数を変更する工程から成る、ところの方法。
- 請求項1に記載の方法であって、ドーズ率を変更する工程は、注入パルスのパルス幅及びパルス周波数を変更する工程から成る、ところの方法。
- 請求項1に記載の方法であって、ドーズ率を変更する工程は、注入処理により特定されるようにドーズ率を調節する工程から成る、ところの方法。
- 請求項1に記載の方法であって、ドーズ率を変更する工程は、プラズマイオン注入装置のパラメータを検知する工程と、検知したパラメータに基づいてドーズ率を制御する工程から成る、ところの方法。
- 請求項9に記載の方法であって、パラメータを検知する工程は、基板からのガス抜けを検知する工程から成る、ところの方法。
- 請求項9に記載の方法であって、パラメータを検知する工程は、基板の帯電を検知する工程から成る、ところの方法。
- 請求項9に記載の方法であって、パラメータを検知する工程は、基板表面条件を検知する工程から成る、ところの方法。
- 請求項9に記載の方法であって、パラメータを検知する工程は、処理チャンバ内の圧力を検知する工程から成る、ところの方法。
- 請求項9に記載の方法であって、パラメータを検知する工程は、残留ガス分析器によりパラメータを検知する工程から成る、ところの方法。
- 請求項9に記載の方法であって、パラメータを検知する工程は、発光分光器によりパラメータを検知する工程から成る、ところの方法。
- 請求項9に記載の方法であって、ドーズ率を制御する工程は、注入パルスの少なくともひとつのパラメータを制御する工程から成る、ところの方法。
- 請求項9に記載の方法であって、ドーズ率を制御する工程は、感知したパラメータの設定ポイントを維持する工程から成る、ところの方法。
- 請求項1に記載の方法であって、注入処理中にドーズ率を変更する工程は、処理チャンバ内のプラズマのプラズマ密度を調節する工程から成る、ところの方法。
- 請求項1に記載の方法であって、ソースはRFソースから成り、注入処理中にドーズ率を変更する工程は、RFソースのRF電力を調節する工程から成る、ところの方法。
- 請求項1に記載の方法であって、注入処理中にドーズ率を変更する工程は、処理チャンバ内の電場を調節する工程から成る、ところの方法。
- 請求項1に記載の方法であって、注入処理中にドーズ率を変更する工程は、処理チャンバ内の磁場を調節する工程から成る、ところの方法。
- 請求項1に記載の方法であって、プラズマイオン注入装置はさらに、プラテンから離隔した陽極を含み、注入処理中にドーズ率を変更する工程は、陽極とプラテンとの間の間隔を調節する工程から成る、ところの方法。
- 基板のプラズマイオン注入のための方法であって、
処理チャンバ、前記処理チャンバ内にプラズマを生成するためのソース、前記処理チャンバ内で基板を保持するためのプラテン、前記プラテンから離隔された陽極、及びプラズマから基板へイオンを加速するための注入パルスを生成するパルスソースを含むプラズマイオン注入装置を与える工程と、
陽極から二次電子を放出させるよう、プラズマから陽極へイオンを加速する工程と、
陽極から基板へ二次電子を加速する工程と、
注入処理に従い基板のプラズマイオン注入を実行する工程と、
から成る方法。 - 請求項23に記載の方法であって、二次電子は約500eVから20keVの範囲のエネルギーを有する、ところの方法。
- 請求項23に記載の方法であって、陽極は電子放出物質で被覆されている、ところの方法。
- 請求項23に記載の方法であって、陽極はプラズマに関して負にバイアスされている、ところの方法。
- 請求項26に記載の方法であって、プラテンは接地されている、ところの方法。
- 請求項26に記載の方法であって、プラテンは正にバイアスされている、ところの方法。
- 請求項26に記載の方法であって、中空陰極が、陽極とプラズマとの間のプラズマ放電領域を包囲し、前記中空陰極が接地されている、ところの方法。
- 基板のプラズマイオン注入のための方法であって、
処理チャンバ、前記処理チャンバ内にプラズマを生成するためのソース、前記処理チャンバ内で基板を保持するためのプラテン、及びプラズマから基板へイオンを加速するための注入パルスを生成するパルスソースを含むプラズマイオン注入装置を与える工程と、
注入処理に従い基板のプラズマイオン注入を実行する工程と、
注入されるイオンと基板との間の不所望な相互作用の効果を少なくとも部分的に補償するよう注入処理中にイオンエネルギーを調節する工程と、
から成る方法。 - プラズマイオン注入装置であって、
処理チャンバと、
前記処理チャンバ内にプラズマを生成するためのソースと、
前記処理チャンバ内で基板を保持するためのプラテンと、
プラズマから基板へイオンを加速するための注入パルスを生成するパルスソースと、
ドーズ率を有する注入処理に従い基板のプラズマイオン注入を実行し、かつ注入処理中にドーズ率を変更するように構成された注入制御器と、
から成る装置。 - プラズマイオン注入装置であって、
処理チャンバと、
前記処理チャンバ内にプラズマを生成するためのソースと、
前記処理チャンバ内で基板を保持するためのプラテンと、
プラテンから離隔された陽極と、
プラズマから基板へイオンを加速するための注入パルスを生成するパルスソースと、
陽極から二次電子を放出させるようプラズマから陽極へイオンを加速するための、及び陽極から基板へ二次電子を加速するための電源と、
から成る装置。 - プラズマイオン注入装置であって、
処理チャンバと、
前記処理チャンバ内にプラズマを生成するためのソースと、
前記処理チャンバ内で基板を保持するためのプラテンと、
プラズマから基板へイオンを加速するための注入パルスを生成するパルスソースと、
注入処理に従い基板のプラズマイオン注入を実行し、注入イオンと基板との間の不所望な相互作用の効果を少なくとも部分的に補償するべく、注入処理中にイオンエネルギーを調節するように構成された注入制御器と、
から成る装置。
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US10/852,643 | 2004-05-24 | ||
US10/852,643 US7396746B2 (en) | 2004-05-24 | 2004-05-24 | Methods for stable and repeatable ion implantation |
PCT/US2005/016219 WO2005115104A2 (en) | 2004-05-24 | 2005-05-09 | Methods for stable and repeatable plasma ion implantation |
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JP2012079462A Pending JP2012178571A (ja) | 2004-05-24 | 2012-03-30 | 安定かつ反復可能なプラズマイオン注入方法及び装置 |
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JP (2) | JP5071976B2 (ja) |
KR (1) | KR101126376B1 (ja) |
CN (2) | CN101892463B (ja) |
TW (1) | TWI345265B (ja) |
WO (1) | WO2005115104A2 (ja) |
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JP5071976B2 (ja) | 2012-11-14 |
KR20070026635A (ko) | 2007-03-08 |
KR101126376B1 (ko) | 2012-03-28 |
US7396746B2 (en) | 2008-07-08 |
WO2005115104A2 (en) | 2005-12-08 |
TWI345265B (en) | 2011-07-11 |
US20050260837A1 (en) | 2005-11-24 |
CN101892463A (zh) | 2010-11-24 |
CN1998062A (zh) | 2007-07-11 |
JP2012178571A (ja) | 2012-09-13 |
TW200539327A (en) | 2005-12-01 |
CN101892463B (zh) | 2012-09-19 |
WO2005115104A3 (en) | 2006-07-06 |
CN1998062B (zh) | 2010-09-01 |
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