FI92837B - Förfarande för framställning av stereoreguljära polymerer med snäv molekylviktsfördelning - Google Patents
Förfarande för framställning av stereoreguljära polymerer med snäv molekylviktsfördelning Download PDFInfo
- Publication number
- FI92837B FI92837B FI882323A FI882323A FI92837B FI 92837 B FI92837 B FI 92837B FI 882323 A FI882323 A FI 882323A FI 882323 A FI882323 A FI 882323A FI 92837 B FI92837 B FI 92837B
- Authority
- FI
- Finland
- Prior art keywords
- carbon atoms
- polycarboxylic acid
- halogenated
- magnesium
- compound
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Polyamides (AREA)
- Polymerisation Methods In General (AREA)
Claims (13)
1. Förfarande för framställning av polymerer med en molekyl-viktsdistribution mellan 3,0 och 4, 5 och ett isotaktiskt index mellan 97 och 99%, kännetecknatav att förfarandet innefattar bringande av en alfa-olefin med 3...8 kolatomer i kontakt med en katalytiskt effektiv mängd av ett katalysator-system i en reaktor med fluidiserad bädd vid ett tryck om högst 7000 kPa och en temperatur om minst 100 ’ C, varvid kata-lysatorsystemet innefattar (a) en fast katalysatorkomponent, som innehäller magnesium, titan, halogenid och en polykarboxylsyraester med tvä ester-grupper i samma pian bundna vid närliggande kolatomer, vilken katalysatorkomponent erhälls genom halogenering av en magne-siumförening med formeln MgR' R", där R' är en alkoxid- eller aryloxidgrupp och R" är en alkoxid- eller aryloxidgrupp eller halogen, med ett överskott av en halogenerad tetravalent titan-förening med minst tvä halogenatomer i närvaro av ett halogen-kolväte och en polykarboxylsyraester med tvä estergrupper i samma pian bundna vid närliggande kolatomer; behandling av den halogenerade produkten med ytterligare halogenerad tetravalent titanförening; tvättning av den behandlade produkten med ett inert kolväte för att avlägsna oreagerad titanförening; och tilivaratagande av den fasta produkten, (b) en organisk aluminiumsamkatalysator, och (c) en elektrondonor innehällande en kisel-syre-kol-bindning, vilken katalysator innehäller ett atomförhällande mellan aluminium i den organiska aluminiumsamkatalysatorn och kisel i elektrondonorn mellan 0,5: 1 och 100: 1, och ett atomförhällande mellan aluminium i den organiska aluminiumsamkatalysatorn och titan i den fasta katalysatorkomponenten mellan 5: 1 och 300: 1.
2. Förfarande enligt patentkravet 1, kännetecknat av att magnesiumföreningen är magnesiumdialkoxid där varje II 37 9 2 8 3 7 alkoxidgrupp innehäller 1...8 kolatomer.
3. Förfarande enligt patentkravet 2, kännetecknat av att magnesiumföreningen är magnesiumdietoxid och den halo-generade tetravalenta titanföreningen är titantetraklorid.
4. Förfarande enligt nägot av patentkraven 1. . . 3, kanne-tecknatav att det halogenerade kolvätet är ett aroma-tiskt halogenerat kolväte son innehäller 6. . . 12 kolatomer och 1. . . 2 halogenatomer.
5. Förfarande enligt patentkravet 4, kännetecknat av att det halogenerade kolvätet är klorbensen.
6. Förfarande enligt nägot av patentkraven 1. . . 5, k ä n n e -tecknatav att den halogenerade produkten behandlas tvä ganger med ytterligare halogenerad tetravalent titanförening och att den andra behandlingen utförs i närvaro av en poly-karboxylsyrahalogenid, som innehäller tvä syrahalogenidgrupper i samma pian bundna vid närliggande kolatomer.
7. Förfarande enligt patentkravet 6, kännetecknat av att polykarboxylsyrahalogeniden är ftaloyldiklorid.
8. Förfarande enligt nägot av patentkraven 1. . . 7, k ä n n e -tecknatav att polykarboxylsyraestern är vald ur gruppen som innefattar (a) karboxylsyraestrar med tvä estergrupper som är bundna vid orto-kolatomerna i en monocyklisk eller polycyklisk aromatisk : ring, varvid vardera estergrupperna ytterligare är bundna vid en koiväteradikal med förgrenad eller oförgrenad ked, (b) polykarboxylsyraestrar med tvä estergrupper som är bundna vid vicinala kolatomer i en icke-aromatisk monocyklisk eller polycyklisk ring och som ligger i syn-konfiguration i för-hällande tili varandra, varvid vardera estergrupperna ytterligare är bundna tili en koiväteradikal med förgrenad eller 92637 oförgrenad ked, och (c) polykarboxylsyraestrar med tvä estergrupper·; som är bundna vid vicinala dubbelbundna kolatomer i en omättad alifatisk förening och som ligger i syn-konfiguration i förhällande tili varandra, varvid vardera estergrupperna är ytterligar bundna vid en koiväteradikal med förgrenad eller oförgrenad ked.
9. Förfarande enligt patentkravet 8, kännetecknat av att polykarboxylsyraestern är härledd ur en monohydrisk alkohol med 1...12 kolatomer och en polykarboxylsyra vald ur gruppen som bestär av (a) monocykliska eller polysykliska aromatiska föreningar med 8... 20 kolatomer och tvä karboxylgrupper som är bundna vid orto-kolatomer i ringstrukturen, (b) monocykliska eller polysykliska icke-aromatiska föreningar med 6. . . 20 kolatomer och tvä karboxylgrupper som är bundna vid vicinala kolatomer i ringstrukturen och som ligger i syn-konfiguration i förhällande tili varandra, (c) omättade alifatiska föreningar med 6...20 kolatomer och tvä karboxylgrupper som är bundna vid vicinala dubbelbundna kolatomer och som ligger i syn-konfiguration i förhällande tili varandra.
10. Förfarande enligt patentkravet 9, kännetecknat av att polykarboxylsyraestern är diisobutylftalat.
11. Förfarande enligt nägot av patentkraven 1... 10, k ä n n -etecknatav att elektrondonorn innehäller en kisel-syre-kol-bindning med formeln R' " ' ' mSiYnXp där: R' ' ' ' ' är en koi väteradikal med 1. . . 20 kolatomer, Y är -OR' ' ' ' ' ' eller -OCOR' ' ' ' ' ' , där R' ' ' ' ' ' är en kolväte- II 92837 radikal med 1. . . 20 kolatomer, X är väte eller halogen, m är ett helt tai med värdet 0. . . 3, n är ett helt tai med värdet 1. . . 4, p är ett helt tai med värdet 0. . . 1, och m + n + p är 4.
12. Förfarande enligt nägot av patentkraven 1. . . 12, k ä n -netecknatav att alfa-olefinen är propylen.
13. Förfarande enligt nägot av patentkraven 1. . . 12, k ä n -netecknatav att en alfa-olefin med 3. . . 8 kolatomer sampolymeriseras med upp tili 20 mol-% etylen i en andra polymerisations reaktor i närvaro av produkten ur den första polymerisations reaktorn.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/051,853 US5093415A (en) | 1987-05-19 | 1987-05-19 | Process for producing stereoregular polymers having a narrow molecular weight distribution |
| US5185387 | 1987-05-19 |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| FI882323A0 FI882323A0 (sv) | 1988-05-18 |
| FI882323A FI882323A (sv) | 1988-11-20 |
| FI92837B true FI92837B (sv) | 1994-09-30 |
| FI92837C FI92837C (sv) | 1995-01-10 |
Family
ID=21973766
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI882323A FI92837C (sv) | 1987-05-19 | 1988-05-18 | Förfarande för framställning av stereoreguljära polymerer med snäv molekylviktsfördelning |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US5093415A (sv) |
| EP (1) | EP0291958B1 (sv) |
| JP (1) | JPH0725836B2 (sv) |
| KR (1) | KR930008452B1 (sv) |
| AT (1) | ATE88193T1 (sv) |
| AU (1) | AU603444B2 (sv) |
| BR (1) | BR8802429A (sv) |
| CA (1) | CA1302640C (sv) |
| CZ (1) | CZ281856B6 (sv) |
| DD (1) | DD274230A5 (sv) |
| DE (1) | DE3880193T2 (sv) |
| ES (1) | ES2039504T3 (sv) |
| FI (1) | FI92837C (sv) |
| GR (1) | GR3008144T3 (sv) |
| IN (1) | IN171145B (sv) |
| MY (1) | MY103526A (sv) |
| NO (1) | NO173142C (sv) |
| NZ (1) | NZ224679A (sv) |
| SK (1) | SK279707B6 (sv) |
| ZA (1) | ZA883535B (sv) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6875721B1 (en) | 1997-12-23 | 2005-04-05 | Borealis Technology Oy | Soluble magnesium dihalide complex, preparation and use |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5883006A (ja) * | 1981-11-13 | 1983-05-18 | Mitsui Petrochem Ind Ltd | オレフインの重合方法 |
| FR2541683B1 (fr) * | 1983-02-28 | 1986-05-09 | Ato Chimie | Procede pour la preparation d'un solide hydrocarbone actif utilisable pour polymeriser des olefines, et procede de synthese d'un polymere ou copolymere olefinique faisant appel audit solide hydrocarbone actif comme systeme |
| GB2143834B (en) * | 1983-07-20 | 1987-06-03 | Toho Titanium Co Ltd | Polymerization catalyst |
| JPS6044507A (ja) * | 1983-08-23 | 1985-03-09 | Toho Titanium Co Ltd | オレフィン類重合用触媒成分 |
| US4535068A (en) * | 1983-09-20 | 1985-08-13 | Shell Oil Company | Olefin polymerization catalyst compositions and polymerization process |
| JPS60139706A (ja) * | 1983-12-27 | 1985-07-24 | Toho Titanium Co Ltd | オレフイン類重合用触媒成分 |
| JPS61126109A (ja) * | 1984-11-22 | 1986-06-13 | Toho Titanium Co Ltd | オレフイン類重合用触媒成分および触媒 |
| ZA882999B (en) * | 1987-05-04 | 1988-11-01 | Shell Oil Company | Preparation of olefin polymerization catalyst component |
-
1987
- 1987-05-19 US US07/051,853 patent/US5093415A/en not_active Expired - Lifetime
-
1988
- 1988-05-16 MY MYPI88000520A patent/MY103526A/en unknown
- 1988-05-17 AU AU16336/88A patent/AU603444B2/en not_active Ceased
- 1988-05-18 BR BR8802429A patent/BR8802429A/pt not_active IP Right Cessation
- 1988-05-18 DE DE8888107969T patent/DE3880193T2/de not_active Expired - Fee Related
- 1988-05-18 KR KR1019880005758A patent/KR930008452B1/ko not_active IP Right Cessation
- 1988-05-18 NO NO882159A patent/NO173142C/no unknown
- 1988-05-18 EP EP88107969A patent/EP0291958B1/en not_active Expired - Lifetime
- 1988-05-18 NZ NZ224679A patent/NZ224679A/xx unknown
- 1988-05-18 CA CA000567103A patent/CA1302640C/en not_active Expired - Lifetime
- 1988-05-18 FI FI882323A patent/FI92837C/sv not_active IP Right Cessation
- 1988-05-18 AT AT88107969T patent/ATE88193T1/de not_active IP Right Cessation
- 1988-05-18 ZA ZA883535A patent/ZA883535B/xx unknown
- 1988-05-18 DD DD88315875A patent/DD274230A5/de not_active IP Right Cessation
- 1988-05-18 ES ES198888107969T patent/ES2039504T3/es not_active Expired - Lifetime
- 1988-05-19 IN IN331/MAS/88A patent/IN171145B/en unknown
- 1988-05-19 JP JP63120798A patent/JPH0725836B2/ja not_active Expired - Fee Related
- 1988-05-19 SK SK3395-88A patent/SK279707B6/sk unknown
- 1988-05-19 CZ CS883395A patent/CZ281856B6/cs unknown
-
1993
- 1993-06-15 GR GR930400026T patent/GR3008144T3/el unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6875721B1 (en) | 1997-12-23 | 2005-04-05 | Borealis Technology Oy | Soluble magnesium dihalide complex, preparation and use |
Also Published As
| Publication number | Publication date |
|---|---|
| NO173142C (no) | 1993-11-03 |
| ATE88193T1 (de) | 1993-04-15 |
| DE3880193T2 (de) | 1993-08-05 |
| CA1302640C (en) | 1992-06-02 |
| NO882159D0 (no) | 1988-05-18 |
| DE3880193D1 (de) | 1993-05-19 |
| KR930008452B1 (ko) | 1993-09-04 |
| CZ281856B6 (cs) | 1997-03-12 |
| DD274230A5 (de) | 1989-12-13 |
| AU1633688A (en) | 1988-11-24 |
| SK339588A3 (en) | 1999-02-11 |
| EP0291958A2 (en) | 1988-11-23 |
| FI882323A0 (sv) | 1988-05-18 |
| NO173142B (no) | 1993-07-26 |
| JPS6454008A (en) | 1989-03-01 |
| MY103526A (en) | 1993-07-31 |
| EP0291958A3 (en) | 1989-11-15 |
| SK279707B6 (sk) | 1999-02-11 |
| KR880013987A (ko) | 1988-12-22 |
| ZA883535B (en) | 1989-01-25 |
| NZ224679A (en) | 1990-05-28 |
| NO882159L (no) | 1988-11-21 |
| FI882323A (sv) | 1988-11-20 |
| JPH0725836B2 (ja) | 1995-03-22 |
| US5093415A (en) | 1992-03-03 |
| FI92837C (sv) | 1995-01-10 |
| CZ339588A3 (en) | 1996-12-11 |
| AU603444B2 (en) | 1990-11-15 |
| BR8802429A (pt) | 1988-12-13 |
| EP0291958B1 (en) | 1993-04-14 |
| IN171145B (sv) | 1992-08-01 |
| GR3008144T3 (sv) | 1993-09-30 |
| ES2039504T3 (es) | 1993-10-01 |
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