EP1268922B1 - Wässrige drucktinten für den einsatz nach dem tintenstrahldruck-verfahren, ihre herstellung und ihre verwendung auf textilen fasermaterialien - Google Patents

Wässrige drucktinten für den einsatz nach dem tintenstrahldruck-verfahren, ihre herstellung und ihre verwendung auf textilen fasermaterialien Download PDF

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Publication number
EP1268922B1
EP1268922B1 EP01909699A EP01909699A EP1268922B1 EP 1268922 B1 EP1268922 B1 EP 1268922B1 EP 01909699 A EP01909699 A EP 01909699A EP 01909699 A EP01909699 A EP 01909699A EP 1268922 B1 EP1268922 B1 EP 1268922B1
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EP
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Prior art keywords
reactive
dried
print
fastness
textile
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EP01909699A
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German (de)
English (en)
French (fr)
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EP1268922A2 (de
Inventor
Karl-Hans Blank
Horst-Roland Mach
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Dystar Textilfarben GmbH and Co Deutschland KG
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Dystar Textilfarben GmbH and Co Deutschland KG
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/30—Ink jet printing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes

Definitions

  • Digital printing techniques will become increasingly important in the textile as well as non-textile fields in the future.
  • the changing market requirements in conventional textile printing require more flexibility in design, color and delivery time.
  • This development is accommodated by digital inkjet technology.
  • the ability of the new technology to print directly from the computer through the printing nozzles to the textiles without the need to produce stencils increases the flexibility, efficiency and environmental compatibility of the printing processes. It allows largely integrated process steps, shortens printing times and meets the demand for rapid reaction to market developments as well as fewer intermediate stages in the production process.
  • aqueous inks are usually used, which are sprayed in small droplets directly onto the substrate.
  • pressure is applied to the ink system either via a piezoelectric crystal or a heated cannula (bubble or thermo-jet method), thus ejecting an ink drop.
  • Such procedures are in text. Chem. Color, Vol. 19 (8), pp. 23 ff and volume 21 pp. 27 ff.
  • dye inks as used for non-textile materials such as paper, wood, plastics, ceramics, etc., give only unsatisfactory results in terms of applicability, as well as color yield and the fastness of the prints on textile material.
  • the present invention thus relates to aqueous printing inks for textile printing by the ink-jet process, which contains one or more reactive dyes, sulfolane, 1 to 20 wt.% Based on the total weight of the ink of a further organic solvent and a buffer system, in which case in that it contains one or more reactive dyestuffs with vinylsulfone series anchor systems, having a pH of less than or equal to 7.0.
  • Dyes which can be used are all reactive dyes which are listed, for example, in European patents EP-B 590397, EP-A 886000 and EP-A 613975.
  • Preferred dyes of the monochlorotriazine series are, for example:
  • Dyes of the vinylsulfone series are, for example:
  • Preferred dyes of the vinylsulfone series are, for example:
  • Double and mixed anchor products are, for example, C.I. Reactive Red 198, C.I. Reactive Red 239, C.I. Reactive Black 5, C.I. Reactive Blue 21.
  • the reactive dyes used are known and can be obtained by conventional diazotization, coupling and condensation reactions.
  • the printing inks according to the invention comprise one or more reactive dyes, for example in amounts of from 0.1 to 50% by weight, preferably in amounts of from 1 to 30% by weight and more preferably in amounts of from 5 to 25% by weight % based on the total weight of the ink.
  • the pH of the printing inks is preferably carried out to a value of 7.0 to 9.0
  • a suitable buffer system set They are used in amounts of from 0.1 to 3% by weight, preferably in 0.5 to 1.5% by weight, based on the total weight of the ink.
  • Suitable buffer systems for printing inks which contain dyes of the monochlorotriazine series are, for example: borax, disodium hydrogenphosphate, modified phosphonates, DEAS.
  • the pH of the printing inks is preferably adjusted to a value of 3.0 to 7.0 by using a suitable buffering system. They are used in amounts of 0.1-3 wt.%, Preferably in 0.5 to 2.5 wt.% Based on the total weight of the ink.
  • Suitable buffer systems for printing inks containing vinylsulfone series dyes include, for example: monosodium phosphate, sodium citrate, modified phosphonates.
  • the dyes used in the inks have a salt content of less than 0.1% by weight, for example from 0.01 to 0.099, by weight Dyes contain. If appropriate, the dyes must be desalted before use in the inks according to the invention, for example by membrane separation processes.
  • a conductivity of 0.5 to 25 mS / m can be set by addition of electrolyte.
  • Suitable electrolytes are, for example: lithium nitrate, potassium nitrate.
  • the inks of the invention contain, for example, 1-30% by weight of sulfolane, preferably 5-25% by weight, and more preferably 10-20% by weight of sulfolane.
  • the dye inks of the invention may contain further organic solvents having a total content of 5 to 20%, preferably of 5 to 15% by weight.
  • Suitable organic solvents are, for example Alcohols, e.g. For example, methanol, ethanol, 1-propanol, isopropanol, 1-butanol, tert. Butanol, pentyl alcohol, polyhydric alcohols e.g.
  • B. Polyethylene glycol, polypropylene glycol, Alkylene glycols having 2 to 8 alkylene groups, e.g. B.: Monoethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, Thioglycol, thiodiglycol, Butyl triglycol, hexylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, lower alkyl ethers of polyhydric alcohols, eg.
  • ethylene glycol monomethyl ether ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, Diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol monohexyl ether, triethylene glycol monomethyl ether, triethylene glycol monobutyl ether, tripropylene glycol monomethyl ether, tetraethylene glycol monomethyl ether, tetraethylene glycol monobutyl ether, tetraethylene glycol dimethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, tripropylene glycol isopropyl ether, polyalkylene glycol ethers such as.
  • polyethylene glycol monomethyl ether polypropylene glycol glycerol ether, polyethylene glycol tridecyl ether, polyethylene glycol nonyl phenyl ether, Amines, such as Example: methylamine, ethylamine, triethylamine, diethylamine, dimethylamine, trimethylamine, dibutylamine, diethanolamine, triethanolamine, N-acetylethanolamine, N-formylethanolamine, ethylenediamine, Urea derivatives, such as.
  • the printing inks according to the invention may contain the customary additives such as viscosity moderators to adjust viscosities in the range of 1.5 to 40.0 mPa * s in a temperature range of 20 to 50 ° C.
  • Preferred inks have a viscosity of from 1.5 to 20 mPa * s and particularly preferred inks have a viscosity of from 1.5 to 15 mPa * s.
  • Suitable viscosity moderators are rheological additives, for example:
  • Polyvinylcaprolactam, polyvinylpyrrolidone and their co-polymers polyether polyol, associative thickener, polyurea, polyurethane, sodium alginates, modified galactomannans, polyether urea, polyurethane, nonionic cellulose ethers.
  • the inks of the invention may be surface-active substances for the adjustment of surface tensions of 20 to 65 mN / m, which may be adjusted depending on the method used (thermal or piezo technology).
  • Suitable surface-active substances are, for example:
  • Nonionic surfactants butyldiglycol, 1,2-hexanediol.
  • the inks may still contain conventional additives such as fungicidal and bacterial growth inhibiting agents in amounts of from 0.01 to 1% by weight based on the total weight of the ink.
  • the inks can be prepared in a conventional manner by mixing the components in water.
  • the dye inks according to the invention are suitable for use in inkjet printing processes for printing a wide variety of preprepared materials, such as silk, leather, wool, polyamide fibers and polyurethanes, and in particular cellulosic fiber materials of all kinds.
  • fiber materials are, for example, the natural cellulose fibers, such as cotton, linen and Hemp, as well as pulp and regenerated cellulose.
  • the printing inks according to the invention are also suitable for printing pretreated hydroxyl-containing or amino-containing fibers which are contained in blend fabrics, for example mixtures of cotton, silk, wool with polyester fibers or polyamide fibers.
  • the auxiliaries In contrast to conventional textile printing, in which the printing ink already contains all fixing chemicals and thickeners for a reactive dye, in ink-jet printing the auxiliaries have to be applied to the textile substrate in a separate pretreatment step.
  • the pretreatment of the textile substrate takes place before printing with an aqueous alkaline liquor.
  • alkali such as sodium carbonate, sodium bicarbonate, sodium acetate, trisodium phosphate, sodium silicate, sodium hydroxide, alkali donors such as sodium trichloroacetate, sodium, hydrotropic substances such as urea, reduction inhibitors, such as sodium nitrobenzenesulfonates, and thickeners, the flow of the to prevent motifs when applying the ink, these are, for example, sodium alginates, modified polyacrylates or highly etherified galactomannans.
  • pre-preparation reagents are applied uniformly to the textile substrate in a defined amount using suitable application devices, for example a 2- or 3-roll padder, with non-contact spray technologies, foam application or appropriately adapted ink-jet technologies, and then dried.
  • suitable application devices for example a 2- or 3-roll padder, with non-contact spray technologies, foam application or appropriately adapted ink-jet technologies, and then dried.
  • the textile fiber material is dried at 120 to 150 ° C and then fixed.
  • the fixation of the inkjet prints prepared with reactive dyes can be carried out at room temperature, or with saturated steam, with superheated steam, with hot air, with microwaves, with infrared radiation, with laser or electron beams or with other suitable types of energy transfer.
  • the post-treatment is carried out, which is the prerequisite for good fastness, high brilliance and a perfect white foundation.
  • the prints produced with the dye inks according to the invention have, in particular on cellulose fiber materials, a high color strength and a high fiber-dye bond stability in both the acidic and in the alkaline range, furthermore good light fastness and very good wet fastness properties, such as washing, water, seawater -, over-dyeing and perspiration, as well as a good pleating, ironing and rubbing fastness.
  • Parts by weight refer to parts by volume such as kilograms to liters.
  • a fabric consisting of leached viscose is padded with a liquor containing 35 g / l of sodium bicarbonate, 150 g / l of urea and 150 g / l of a low-viscosity Na alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 15% CI Reactive Blue 21 10% sulfolane 10% N-methyl-2-pyrrolidone 65% water printed with a drop-on-demand (bubble-jet) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 8 minutes. The pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. This gives a turquoise print with excellent use fastness.
  • a fabric consisting of leached viscose is padded with a liquor containing 35 g / l of sodium bicarbonate, 100 g / l of urea and 150 g / l of a low-viscosity Na alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 8th % CI Reactive Black 14 8th % sulfolane 12% N-methyl-2-pyrrolidone 72% water printed with a drop-on-demand (bubble-jet) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 8 minutes.
  • the pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a fabric consisting of mercerized cotton is padded with a liquor containing 30 g / l of sodium bicarbonate, 150 g / l of urea and 150 g / l of a low viscosity Na alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 6% CI Reactive Blue 21 5% CI Reactive Yellow 37 5% sulfolane 15% N-methyl-2-pyrrolidone 69% water printed with a drop-on-demand (bubble-jet) inkjet print head.
  • the print is completely dried.
  • the fixation takes place by means of saturated steam at 102 ° C for 8 minutes.
  • the pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. This gives a green print with excellent use fastness.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 150 g / l urea and 150 g / l of a low-viscosity Na alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 12% CI Reactive Red 218 5% sulfolane 15% N-methyl-2-pyrrolidone 68% water printed with a drop-on-demand (piezo) inkjet print head.
  • the print is completely dried.
  • the fixation takes place by means of saturated steam at 102 ° C for 8 minutes.
  • the pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. This gives a red print with excellent use fastness.
  • a fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l of sodium bicarbonate, 120 g / l of urea and 150 g / l of a low viscosity Na alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 8th % CI Reactive Orange 13 10% sulfolane 4% N-methyl-2-pyrrolidone 0.5% modified phosphonates 77.5% water printed with a drop-on-demand (piezo) inkjet print head.
  • the print is completely dried.
  • the fixation takes place by means of saturated steam at 102 ° C for 8 minutes.
  • the pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. This gives an orange print with excellent use fastness.
  • a fabric consisting of leached viscose is padded with a liquor containing 35 g / l of sodium bicarbonate, 150 g / l of urea and 150 g / l of a low-viscosity Na alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 10% CI Reactive Red 218 5% sulfolane 15% N-methyl-2-pyrrolidone 0.5% modified phosphonates 69.5% water printed with a drop-on-demand (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 8 minutes. The pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. This gives a red print with excellent use fastness.
  • a fabric comprising viscose viscose is padded with a liquor containing 35 g / l of sodium bicarbonate, 200 g / l of urea and 150 g / l of a low viscosity Na alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 8th % CI Reactive Blue 49 15% sulfolane 5% N-methyl-2-pyrrolidone 0.5% modified phosphonates 71.5% water printed with a drop-on-demand (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 8 minutes. The pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. This gives a blue print with excellent use fastness.
  • a textile fabric consisting of mercerized cotton comes with a Liquor containing 30 g / l sodium carbonate kalz, 100 g / l urea and 150 g / l of a low-viscosity Na alginate solution (6%) padded and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 10% CI Reactive Red 180 15% sulfolane 4% N-methyl-2-pyrrolidone 0.5% modified phosphonates 70.5% water printed with a drop-on-demand (piezo) inkjet print head.
  • the print is completely dried.
  • the fixation takes place by means of saturated steam at 102 ° C for 8 minutes.
  • the pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. This gives a red print with excellent use fastness.
  • a fabric consisting of debranched silk is padded with a liquor containing 50 g / l of sodium acetate, 100 g / l of urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 10% CI Reactive Blue 21 5% sulfolane 15% N-methyl-2-pyrrolidone 70% water printed with a drop-on-demand (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 20 minutes.
  • a fabric consisting of debranched silk is padded with a liquor containing 50 g / l of sodium acetate, 100 g / l of urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 12% CI Reactive Blue 229 7% sulfolane 12% N-methyl-2-pyrrolidone 69% water printed with a drop-on-demand (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 20 minutes.
  • a fabric consisting of debranched silk is padded with a liquor containing 50 g / l of sodium acetate, 100 g / l of urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 8th % CI Reactive Black 14 10% sulfolane 10% N-methyl-2-pyrrolidone 72% water printed with a drop-on-demand (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 20 minutes.
  • a textile fabric consisting of degummed silk is treated with a fleet, containing 50 g / l of sodium acetate, 100 g / l of urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 5% CI Reactive Black 31 8th % sulfolane 12% N-methyl-2-pyrrolidone 75% water printed with a drop-on-demand (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 20 minutes.
  • a fabric consisting of debranched silk is padded with a liquor containing 50 g / l of sodium acetate, 100 g / l of urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 15% CI Reactive Black 5 10% sulfolane 12% N-methyl-2-pyrrolidone 63% water printed with a drop-on-demand (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 20 minutes. Subsequently, the pressure is rinsed with the addition of 1-2 ml of ammonia 25% warm, subjected to a fastness wash with hot water at 70 to 80 ° C, rinsed warm and then dried.
  • a textile fabric consisting of degummed silk is treated with a fleet, containing 50 g / l of sodium acetate, 100 g / l of urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 10% CI Reactive Blue 21 15% sulfolane 3% 1,2-hexanediol 5% polyvinyl caprolactam 67% water printed with a continuous flow (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 20 minutes.
  • a fabric consisting of debranched silk is padded with a liquor containing 50 g / l of sodium acetate, 100 g / l of urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 8th % CI Reactive Black 14 15% sulfolane 5% polyether polyol 3% 1,2-hexanediol 69% water printed with a continuous flow (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 20 minutes.
  • the pressure is then rinsed with the addition of 1-2 ml of ammonia 25% warm, subjected to a fastness wash with hot water at 70 to 80 ° C, rinsed warm and then dried. This gives a gray print with excellent use fastness.
  • a fabric consisting of debranched silk is padded with a liquor containing 50 g / l of sodium acetate, 100 g / l of urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 12% CI Reactive Blue 21 18% sulfolane 7% polyether polyol 3% 1,2-hexanediol 60% water printed with a continuous flow (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 20 minutes.
  • a fabric consisting of debranched silk is padded with a liquor containing 50 g / l of sodium acetate, 100 g / l of urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 10.5% CI Reactive Red 180 15% sulfolane 8th % polyether polyol 6% polypropylene glycol 60.5% water printed with a continuous flow (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 20 minutes.
  • the pressure is rinsed with the addition of 1-2 ml of ammonia 25% warm, subjected to a fastness wash with hot water at 70 to 80 ° C, rinsed warm and then dried. This gives a red print with excellent use fastness.
  • a fabric consisting of debranched silk is padded with a liquor containing 50 g / l of sodium acetate, 100 g / l of urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 10% CI Reactive Yellow 37 15% sulfolane 7% polyether polyol 4% polypropylene glycol 0.3% sodium citrate 63.7% water printed with a continuous flow (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 20 minutes.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l of sodium acetate, 150 g / l of urea and 150 g / l of a low-viscosity Na alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 15% CI Reactive Black 5 10% sulfolane 12% N-methyl-2-pyrrolidone 63% water printed with a drop-on-demand (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 20 minutes.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l of sodium acetate, 150 g / l of urea and 150 g / l of a low-viscosity Na alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 5% CI Reactive Black 31 8th % sulfolane 12% N-methyl-2-pyrrolidone 75% water printed with a drop-on-demand (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 20 minutes.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l of sodium acetate, 150 g / l of urea and 150 g / l of a low-viscosity Na alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 8th % CI Reactive Black 14 10% sulfolane 10% N-methyl-2-pyrrolidone 72% water printed with a drop-on-demand (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 20 minutes.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity Na alginate solution (5%) and then dried.
  • the liquor pick-up is 70%.
  • On the thus pretreated textile is an aqueous ink containing 12% Cl Reactive Blue 229 7% sulfolane 12% N-methyl-2-pyrrolidone 69% water printed with a drop-on-demand (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 20 minutes.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l of sodium acetate, 150 g / l of urea and 150 g / l of a low-viscosity Na alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • aqueous ink containing 10% CI Reactive Blue 21 5% sulfolane 15% N-methyl-2-pyrrolidone 70% water printed with a drop-on-demand (piezo) inkjet print head.
  • the print is completely dried.
  • the fixation takes place by means of saturated steam at 102 ° C for 20 minutes.
  • the pressure is rinsed with the addition of 1-2 ml of ammonia 25% warm, subjected to a fastness wash with hot water at 70 to 80 ° C, rinsed warm and then dried.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l of sodium acetate, 150 g / l of urea and 150 g / l of a low-viscosity Na alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 10% CI Reactive Blue 21 15% sulfolane 3% 1,2-hexanediol 5% polyvinyl caprolactam 67% water printed with a continuous flow (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 20 minutes.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l of sodium acetate, 150 g / l of urea and 150 g / l of a low-viscosity Na alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 10% CI Reactive Yellow 37 15% sulfolane 7% polyether polyol 4% polypropylene glycol 0.3% sodium citrate 63.7% water printed with a continuous flow (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 20 minutes.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l of sodium acetate, 150 g / l of urea and 150 g / l of a low-viscosity Na alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 10.5% CI Reactive Red 180 15% sulfolane 8th % polyether polyol 6% polypropylene glycol 60.5% water printed with a continuous flow (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 20 minutes.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l of sodium acetate, 150 g / l of urea and 150 g / l of a low-viscosity Na alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 12% CI Reactive Blue 21 18% sulfolane 7% polyether polyol 3% 1,2-hexanediol 60% water printed with a continuous flow (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 20 minutes.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l of sodium acetate, 150 g / l of urea and 150 g / l of a low-viscosity Na alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 8th % CI Reactive Black 14 15% sulfolane 5% polyether polyol 3% 1,2-hexanediol 69% water printed with a continuous flow (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 20 minutes.
  • a textile fabric consisting of laugated viscose is padded with a liquor containing 35 g / l sodium carbonate, 200 g / l urea and 150 g / l of a low-viscosity Na alginate solution (6%) and then dried.
  • the Fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 12% Cl Reactive Blue 21 15% sulfolane 5% N-methyl-2-pyrrolidone 7% polyether polyol 61% water printed with a continuous flow (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 8 minutes. The pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. This gives a turquoise print with excellent use fastness.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 50 g / l urea and 150 g / l of a low-viscosity Na alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 8th % CI Reactive Black 14 10% sulfolane 5% N-methyl-2-pyrrolidone 5% polyether polyol 72% water printed with a continuous flow (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 8 minutes. The pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. This gives a gray print with excellent use fastness.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 150 g / l urea and 150 g / l of a low-viscosity Na alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 12% CI Reactive Red 218 10% sulfolane 10% N-methyl-2-pyrrolidone 5% polyvinylpyrrolidone 63% water printed with a continuous flow (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 8 minutes. The pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. This gives a red print with excellent use fastness.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l of sodium carbonate, 100 g / l of urea and 150 g / l of a low-viscosity Na alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 15% CI Reactive Black 5 0.8% CI Reactive Orange 107 0.2% CI Reactive Red 180 20% sulfolane 5% polypropylene glycol 59% water printed with a continuous flow (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 8 minutes.
  • a fabric consisting of mercerized cotton is coated with an aqueous ink 10% CI Reactive Red 180 15% sulfolane 3% N-methyl-2-pyrrolidone 72% water printed with a drop-on-demand (bubble-jet) inkjet print head. The print is completely dried. Fixing takes place according to the technologies known for two-phase fixation. (Flash-firing 20 sec, 125 ° C, short steam 90 sec, 125 ° C, cold pad 20 ° C-40 ° C, 4-12 h) Fixing alkali: Sodium hydroxide / sodium silicate Na 2 0: Si0 2 1: 1.7 to 3 , 3).
  • the pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. This gives a red print with excellent use fastness.
  • a textile fabric consisting of laugated viscose is padded with a liquor containing 150 g / l of a low-viscosity Na alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 8th % CI Reactive Black 8 12% sulfolane 4% 1,2-hexanediol 0.3% modified polyphosphonate 75.7% water printed with a drop-on-demand (piezo) inkjet print head. The print is completely dried. Fixing takes place according to the technologies known for two-phase fixation.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 150 g / l of a low-viscosity Na alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 10% CI Reactive Red 218 10% sulfolane 5% N-methyl-2-pyrrolidone 2% polypropylene glycol 73% water printed with a continuous flow (piezo) inkjet print head. The print is completely dried. Fixing takes place according to the technologies known for two-phase fixation.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 150 g / l of a low-viscosity Na alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 10% CI Reactive Red 239 12% sulfolane 3% 1,2-hexanediol 3% polypropylene glycol 72% water printed with a continuous flow (piezo) inkjet print head. The print is completely dried. Fixing takes place according to the technologies known for two-phase fixation.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 80 g / l of sodium trichloroacetate and 50 g / l of urea and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 8th % CI Reactive Orange 16 12% sulfolane 6% N-methyl-2-pyrrolidone 74% water printed with a drop-on-demand (bubble-jet) inkjet print head.
  • the print is completely dried.
  • the fixation takes place by means of saturated steam at 102 ° C for 10 minutes.
  • the pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. This gives an orange print with excellent use fastness.
  • a fabric consisting of bleached linen is padded with a liquor containing 80 g / l of sodium trichloroacetate, 150 g / l of urea and a liquor containing 150 g / l of a low viscosity Na alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 11% CI Reactive Orange 13 15% sulfolane 5% N-methyl-2-pyrrolidone 0.05% nonionic surfactant 68.95% water printed with a drop-on-demand (piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 10 minutes. The pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. This gives an orange print with excellent use fastness.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 80 g / l Na trichloroacetate, 50 g / l urea and a liquor containing 150 g / l of a low viscosity Na alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 10% CI Reactive Blue 229 12% sulfolane 6% N-methyl-2-pyrrolidone 6% polyether polyol 66% water printed with a Continous Flow (Piezo) inkjet print head.
  • the print is completely dried.
  • the fixation takes place by means of saturated steam at 102 ° C for 10 minutes.
  • the pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. This gives a turquoise print with excellent use fastness.
  • a fabric consisting of bleached linen is padded with a liquor containing 80 g / l of sodium trichloroacetate, 100 g / l of urea and a liquor containing 150 g / l of a low viscosity Na alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 14% CI Reactive Red 187 16% sulfolane 4% 1,2-hexanediol 6% polyvinyl caprolactam 60% water printed with a Continous Flow (Piezo) inkjet print head. The print is completely dried. The fixation takes place by means of saturated steam at 102 ° C for 10 minutes. The pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. This gives a red print with excellent use fastness.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l of sodium carbonate, 100 g / l of urea and 150 g / l of a low-viscosity Na alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 9% CI Reactive Yellow 85 15% sulfolane 5% N-methyl-2-pyrrolidone 71% water printed with a drop-on-demand (bubble-jet) inkjet print head.
  • the print is completely dried.
  • the fixation takes place by means of saturated steam at 102 ° C for 8 minutes.
  • the pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. This gives a yellow print with excellent use fastness.
  • a fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l of sodium bicarbonate and 250 g / l of urea and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 12% CI Reactive Orange 181 15% sulfolane 5% N-methyl-2-pyrrolidone 68% water printed with a drop-on-demand (bubble-jet) inkjet print head.
  • the print is completely dried.
  • the fixation takes place by means of hot air at 150 ° C for 3-5 minutes.
  • the pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. This gives a golden yellow print with excellent use fastness.
  • a fabric consisting of bleached linen is padded with a liquor containing 35 g / l of sodium carbonate and 150 g / l of urea and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 12% CI Reactive Red 245 12% sulfolane 4% 1,2-hexanediol 0.3% borax 71.7% water printed with a drop-on-demand (piezo) inkjet print head.
  • the print is completely dried.
  • the fixation takes place by means of saturated steam at 102 ° C for 8 minutes.
  • the pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. This gives a red print with excellent use fastness.
  • a textile fabric consisting of laugated viscose is padded with a liquor containing 30 g / l of sodium carbonate and 180 g / l of urea and then dried.
  • the fleet intake is 70%.
  • On the thus pretreated textile is an aqueous ink containing 12% CI Reactive Blue 13 15% sulfolane 5% Polypropylendglykol 0.3% borax 67.7% water printed with a Continous Flow (Piezo) inkjet print head.
  • the print is completely dried.
  • the fixation takes place by means of saturated steam at 102 ° C for 8 minutes.
  • the pressure is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. This gives a navy blue print with excellent use fastness.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Coloring (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Ink Jet (AREA)
EP01909699A 2000-02-04 2001-01-27 Wässrige drucktinten für den einsatz nach dem tintenstrahldruck-verfahren, ihre herstellung und ihre verwendung auf textilen fasermaterialien Expired - Lifetime EP1268922B1 (de)

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DE10004954A DE10004954A1 (de) 2000-02-04 2000-02-04 Wässrige Drucktinten für den Einsatz nach dem Tintenstrahldruck-Verfahren, ihre Herstellung und ihre Verwendung auf textilen Fasermaterialien
DE10004954 2000-02-04
PCT/EP2001/000882 WO2001057308A2 (de) 2000-02-04 2001-01-27 Wässrige drucktinten für den einsatz nach dem tintenstrahldruck-verfahren, ihre herstellung und ihre verwendung auf textilen fasermaterialien

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EP1268922B1 true EP1268922B1 (de) 2006-09-27

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EP (1) EP1268922B1 (cs)
JP (1) JP2003521572A (cs)
KR (1) KR100707575B1 (cs)
CN (1) CN1292122C (cs)
AT (1) ATE340893T1 (cs)
BR (1) BR0108097A (cs)
CA (1) CA2399119A1 (cs)
CZ (1) CZ20022661A3 (cs)
DE (2) DE10004954A1 (cs)
ES (1) ES2270983T3 (cs)
HU (1) HUP0204369A2 (cs)
MX (1) MXPA02007555A (cs)
PT (1) PT1268922E (cs)
TW (1) TWI278553B (cs)
WO (1) WO2001057308A2 (cs)
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Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030199611A1 (en) * 2002-03-08 2003-10-23 Chandrasekaran Casey K. Inkjet ink for textiles
GB0222695D0 (en) * 2002-10-01 2002-11-06 Lumenia Technology Ltd Improvements in and relating to methods of colouring materials
US6866378B2 (en) * 2002-10-28 2005-03-15 Hewlett-Packard Development Company, L.P. Conductive additives for use in printing processes employing radiational drying
KR100499312B1 (ko) * 2002-11-22 2005-07-04 세기유화주식회사 수용성 날염 잉크의 제조방법 및 그 방법에 의해 제조된잉크
US20070103529A1 (en) * 2003-06-16 2007-05-10 Kornit Digital Ltd. Process and system for printing images on absorptive surfaces
US11447648B2 (en) 2004-05-30 2022-09-20 Kornit Digital Ltd. Process and system for printing images on absorptive surfaces
US7351277B2 (en) * 2004-09-08 2008-04-01 E. I. Du Pont De Nemours And Company IR transparent cyan inkjet ink
CA2600416A1 (en) 2004-11-01 2006-05-11 Basf Corporation Radiofrequency activated inkjet inks and apparatus for inkjet printing
JP2006199888A (ja) * 2005-01-24 2006-08-03 Seiko Epson Corp 水性インク組成物及びそれを用いたインクジェット記録方法、並びに記録物
US20130153440A9 (en) * 2006-11-13 2013-06-20 Kc Energy, Llc Rf systems and methods for processing salt water
US9550374B1 (en) 2007-06-27 2017-01-24 Cafepress Inc. System and method for improved digital printing on textiles
CN101519551B (zh) * 2008-02-25 2011-07-20 明德国际仓储贸易(上海)有限公司 墨水组成物
CN102076793B (zh) * 2008-07-31 2016-05-18 日本化药株式会社 喷墨印染用油墨组和使用了该油墨组的纤维印染方法
JP2010084058A (ja) * 2008-10-01 2010-04-15 Mimaki Engineering Co Ltd インクジェット捺染用インク組成物
JP2010084289A (ja) * 2008-10-01 2010-04-15 Mimaki Engineering Co Ltd インクジェット捺染方法
CN101952503A (zh) * 2008-10-01 2011-01-19 株式会社御牧工程 喷墨印染用墨水组合物及喷墨印染方法
IT1393671B1 (it) * 2009-02-05 2012-05-08 Everlight Usa Inc Composizione di inchiostro
US8540358B2 (en) 2009-08-10 2013-09-24 Kornit Digital Ltd. Inkjet compositions and processes for stretchable substrates
TWI425055B (zh) * 2009-08-21 2014-02-01 Everlight Chem Ind Corp 反應性印花染料及其液態組成物之應用
US8926080B2 (en) 2010-08-10 2015-01-06 Kornit Digital Ltd. Formaldehyde-free inkjet compositions and processes
WO2012127274A1 (en) * 2011-03-18 2012-09-27 Indian Institute Of Technology Delhi Apparatus and methods for dyeing of fibers
EP2743318B1 (en) * 2011-08-09 2017-11-29 Nippon Kayaku Kabushiki Kaisha Gray ink composition for ink jet printing and method for printing fibers using same
CN104768769B (zh) * 2012-06-04 2017-08-04 惠普发展公司，有限责任合伙企业 织物印刷介质
JP6090320B2 (ja) * 2012-07-23 2017-03-08 コニカミノルタ株式会社 インクジェット捺染インクセット
JP6136577B2 (ja) * 2012-12-10 2017-05-31 セイコーエプソン株式会社 インクジェット捺染用インク組成物およびインクジェット捺染方法
JP6198341B2 (ja) * 2013-09-12 2017-09-20 日本化薬株式会社 インク組成物及び繊維の捺染方法
JP6233579B2 (ja) * 2013-12-17 2017-11-22 セイコーエプソン株式会社 インクジェット捺染用のインク組成物および捺染方法
JP6402980B2 (ja) * 2014-08-01 2018-10-10 セイコーエプソン株式会社 インクジェット捺染用インク組成物及び捺染方法
KR101694726B1 (ko) * 2015-05-29 2017-01-10 주식회사 디지아이 디지털 날염 전처리용 조성물
JP6605765B2 (ja) * 2016-03-16 2019-11-13 富士フイルム株式会社 インク
US10259961B2 (en) * 2016-03-24 2019-04-16 Seiko Epson Corporation Ink jet textile printing ink composition, ink set, and printing method
JP6801305B2 (ja) * 2016-03-24 2020-12-16 セイコーエプソン株式会社 インクジェット捺染用インク組成物、インクセット及び記録方法
CN106320015B (zh) * 2016-08-17 2019-01-11 上海贝通色彩科技有限公司 一种数码印花活性红色墨水及其制备方法
CA3041443A1 (en) 2016-10-31 2018-05-03 Kornit Digital Ltd. Dye-sublimation inkjet printing for textile
WO2018097061A1 (ja) * 2016-11-25 2018-05-31 日本化薬株式会社 インク、インクセット、及び繊維の捺染方法
JP6954053B2 (ja) * 2016-12-28 2021-10-27 セイコーエプソン株式会社 捺染用インクジェットインク組成物、インクセット及び記録方法
EP3342927B1 (en) 2016-12-28 2019-08-14 Seiko Epson Corporation Ink jet ink composition for textile printing, ink set, and recording method
US10894896B2 (en) * 2016-12-28 2021-01-19 Seiko Epson Corporation Ink jet ink composition for textile printing, ink set, and recording method
JP6972741B2 (ja) * 2016-12-28 2021-11-24 セイコーエプソン株式会社 捺染用インクジェットインク組成物、インクセット及び記録方法
JP2019060051A (ja) * 2017-09-27 2019-04-18 セイコーエプソン株式会社 記録方法
JP7017054B2 (ja) 2017-09-29 2022-02-08 セイコーエプソン株式会社 インクジェット捺染インク、インクジェット捺染インクセットおよび捺染方法
EP3701082A4 (en) 2017-10-22 2021-10-13 Kornit Digital Ltd. LOW FRICTION IMAGES BY INKJET PRINTING
EP3868237B1 (en) 2017-10-27 2024-11-13 Nike Innovate C.V. Articles comprising coated fibers and methods of making articles with coated fibers
JP2019137793A (ja) * 2018-02-13 2019-08-22 セイコーエプソン株式会社 捺染インクジェットインク組成物セット及び記録方法
WO2020176081A1 (en) 2019-02-27 2020-09-03 Nike Innovate C.V. Articles, bladders and methods of making articles and bladders
EP3924431B1 (en) * 2019-03-18 2022-07-06 Nike Innovate C.V. Colorant solvent system, methods of use, and articles
JP7639338B2 (ja) * 2020-12-28 2025-03-05 セイコーエプソン株式会社 水系インクジェットインク組成物および記録方法
KR102826397B1 (ko) * 2025-01-03 2025-06-27 주식회사 삼우디티피 디지털 텍스타일 프린팅의 전처리 공정 및 이 공정을 포함하는 디지털 텍스타일 프린팅법

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56161479A (en) * 1980-04-10 1981-12-11 Canon Inc Recording liquid and recording method
US5364462A (en) * 1991-08-14 1994-11-15 Graphic Utilities, Incorporated Waterfast inks
JP3323549B2 (ja) * 1991-09-26 2002-09-09 キヤノン株式会社 インクジェット捺染用インク及びインクジェット捺染方法
US5250121A (en) * 1991-09-26 1993-10-05 Canon Kabushiki Kaisha Ink-jet textile printing ink and ink-jet textile printing process
TW228543B (cs) * 1992-09-26 1994-08-21 Hoechst Ag
US5258064A (en) * 1992-12-17 1993-11-02 Xerox Corporation Ink compositions and preparation processes thereof
JP2895695B2 (ja) * 1992-12-17 1999-05-24 キヤノン株式会社 インクジェット捺染用布帛、インクジェット捺染方法及び捺染物
JP3666895B2 (ja) * 1993-01-13 2005-06-29 キヤノン株式会社 インクジェット捺染インク、かかるインクを用いた捺染方法、機器および得られる捺染物
DE4306433A1 (de) * 1993-03-02 1994-09-08 Hoechst Ag Ink-Jet-Einphasen-Reaktivdruck
JP3376002B2 (ja) * 1993-03-23 2003-02-10 キヤノン株式会社 インクジェット捺染インク、インクジェット捺染方法、記録ユニット、インクカートリッジ、インクジェット記録装置、捺染された布帛および布帛の加工品
US5500023A (en) * 1993-04-21 1996-03-19 Canon Kabushiki Kaisha Ink-jet printing process, ink set for use in such process, and processed article obtained thereby
JP2959692B2 (ja) * 1993-04-21 1999-10-06 キヤノン株式会社 インクジェット捺染方法
JP2959691B2 (ja) * 1993-04-21 1999-10-06 キヤノン株式会社 インクジェット捺染方法
JP3270598B2 (ja) * 1993-11-08 2002-04-02 キヤノン株式会社 インクジェット捺染用布帛並びにインクジェット捺染方法並びに捺染物
DE4417718A1 (de) * 1994-05-20 1995-11-23 Hoechst Ag Reaktivfarbstoffe für den Tintenstrahldruck
US6015454A (en) * 1997-06-17 2000-01-18 Ciba Specialty Chemicals Corporation Process for printing textile fibre materials in accordance with the ink-jet printing process
US5972084A (en) * 1997-06-17 1999-10-26 Ciba Specialty Chemicals Corporation Process for printing textile fiber materials in accordance with the ink-jet printing process
US5958120A (en) * 1998-02-02 1999-09-28 Xerox Corporation Ink compositions with improved waterfastness
US6054505A (en) * 1998-03-24 2000-04-25 Xerox Corporation Ink compositions with improved shelf stability

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DE10004954A1 (de) 2001-08-16
PT1268922E (pt) 2007-01-31
MXPA02007555A (es) 2002-12-13
CZ20022661A3 (cs) 2002-11-13
HUP0204369A2 (en) 2003-04-28
ZA200205628B (en) 2003-11-26
CN1398311A (zh) 2003-02-19
CN1292122C (zh) 2006-12-27
KR100707575B1 (ko) 2007-04-13
WO2001057308A2 (de) 2001-08-09
TWI278553B (en) 2007-04-11
WO2001057308A3 (de) 2002-03-14
JP2003521572A (ja) 2003-07-15
US20030172840A1 (en) 2003-09-18
BR0108097A (pt) 2002-10-29
CA2399119A1 (en) 2001-08-09
DE50111094D1 (de) 2006-11-09
KR20020073199A (ko) 2002-09-19
ATE340893T1 (de) 2006-10-15
EP1268922A2 (de) 2003-01-02
ES2270983T3 (es) 2007-04-16

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