WO2001057308A2 - Wässrige drucktinten für den einsatz nach dem tintenstrahldruck-verfahren, ihre herstellung und ihre verwendung auf textilen fasermaterialien - Google Patents

Wässrige drucktinten für den einsatz nach dem tintenstrahldruck-verfahren, ihre herstellung und ihre verwendung auf textilen fasermaterialien Download PDF

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Publication number
WO2001057308A2
WO2001057308A2 PCT/EP2001/000882 EP0100882W WO0157308A2 WO 2001057308 A2 WO2001057308 A2 WO 2001057308A2 EP 0100882 W EP0100882 W EP 0100882W WO 0157308 A2 WO0157308 A2 WO 0157308A2
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WIPO (PCT)
Prior art keywords
print
dried
rinsed warm
reactive
padded
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PCT/EP2001/000882
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German (de)
English (en)
French (fr)
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WO2001057308A3 (de
Inventor
Karl-Hans Blank
Horst-Roland Mach
Original Assignee
Dystar Textilfarben Gmbh & Co. Deutschland Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Dystar Textilfarben Gmbh & Co. Deutschland Kg filed Critical Dystar Textilfarben Gmbh & Co. Deutschland Kg
Priority to CA002399119A priority Critical patent/CA2399119A1/en
Priority to DE50111094T priority patent/DE50111094D1/de
Priority to JP2001555930A priority patent/JP2003521572A/ja
Priority to HU0204369A priority patent/HUP0204369A2/hu
Priority to EP01909699A priority patent/EP1268922B1/de
Priority to MXPA02007555A priority patent/MXPA02007555A/es
Priority to BR0108097-0A priority patent/BR0108097A/pt
Publication of WO2001057308A2 publication Critical patent/WO2001057308A2/de
Publication of WO2001057308A3 publication Critical patent/WO2001057308A3/de

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/30—Ink jet printing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes

Definitions

  • the ink-jet process usually uses aqueous inks that are sprayed directly onto the substrate in small droplets.
  • pressure is exerted on the ink system either by means of a piezoelectric crystal or a heated cannula (bubble or thermo-jet method) and an ink drop is thus ejected.
  • Such procedures are in text.
  • dye inks such as those used for non-textile materials, such as paper, wood, plastics, ceramics, etc., only give unsatisfactory results in terms of applicability, as well as the color yield and the fastness of the prints on textile material.
  • Dye inks containing fiber-reactive dyes are described in European patent applications EP-A 0 886 000 and EP-A 0 885 998, EP 0 620 116, EP-A 0 606 777, DE-A 4417718, DE-A 4417719. These dye inks show some weaknesses in application technology, for example unsatisfactory stability of the dye inks or low dye yield due to insufficient interaction of the dyes from the ink with the fiber.
  • European patent specification EP-A 0 602 885 describes aqueous sulfolane-containing dye inks for the non-textile sector which are not suitable for textile use.
  • the object of the present invention was therefore to provide printing inks which do not have the disadvantages mentioned above.
  • the present invention thus relates to aqueous printing inks for textile printing by the ink-jet method, which contains one or more reactive dyes, sulfolane and a buffer system and which, in the event that it contains one or more reactive dyes with anchor systems from the vinylsulfone series, has a pH value less than or equal to 7.0.
  • Reactive dyes with an anchor system from the monochlorotriazine and / or vinyl sulfone series are preferred.
  • Dyes of the monochlorotriazine series are for example:
  • C.I. Reactive Yellow 85 C.I. Reactive Yellow 95, C.I. Yellow 181, C.I. Reactive Orange 12, C.I. Reactive Orange 13, C.I. Reactive Orange 35, C.I. Reactive Red 3: 1, C.I. Reactive Red 24, C.I. Reactive Red 31, C.I. Reactive Red 45, C.I. Reactive Red 187, C.I. Reactive Red 218, C.I. Reactive Red 245, C.I. Reactive Violet 1, C.I. Reactive Blue 13, C.I. Reactive Blue 49, C.I. Reactive Blue 71, C.I. Reactive Blue 72, C.I. Reactive Blue 162, C.I. Reactive Blue 234, C.I. Reactive Brown 11, C.I. Reactive Brown 17, C.I. Reactive Brown 38, C.I. Reactive Black 8, C.I. Reactive Black 39.
  • Preferred dyes of the monochlorotriazine series are, for example:
  • Preferred dyes of the vinyl sulfone series are, for example:
  • Double and mixed anchor products are, for example, C.I. Reactive Red 198, C.I. Reactive Red 239, C.I. Reactive Black 5, C.I. Reactive Blue 21.
  • the reactive dyes used are known and can be obtained by customary diazotization, coupling and condensation reactions.
  • the printing inks according to the invention contain one or more reactive dyes, for example in amounts of 0.1% by weight to 50% by weight, preferably in amounts of 1% by weight to 30% by weight and particularly preferably in amounts of 5% by weight to 25% by weight .% based on the total weight of the ink.
  • the pH of the printing inks is preferably adjusted to a value of 7.0 to 9.0
  • a suitable buffer system are used. They are used in amounts of 0.1-3% by weight, preferably in 0.5-1.5% by weight, based on the total weight of the ink.
  • Suitable buffer systems for printing inks which contain dyes of the monochlorotriazine series are, for example: borax, disodium hydrogen phosphate, modified phosphonates, DEAS.
  • the pH of the printing inks is preferably adjusted to a value of 3.0 to 7.0 by using a suitable buffer system. They are used in amounts of 0.1-3% by weight, preferably in 0.5-2.5% by weight, based on the total weight of the ink.
  • Suitable buffer systems for printing inks which contain dyes of the vinyl sulfone series are, for example: monosodium phosphate, sodium citrate, modified phosphonates.
  • the dyes used in the inks in particular have a salt content of less than 0.1% by weight, for example from 0.01 to 0.099, based on the weight of the Dyes included. If necessary, the dyes must be desalted, for example by membrane separation processes, before use in the inks according to the invention.
  • a conductivity of 0.5 to 25 mS / m can be set by adding electrolyte.
  • Suitable electrolytes are: lithium nitrate, potassium nitrate.
  • the inks according to the invention contain, for example, 1-30% by weight sulfolane, preferably 5-25% by weight, and particularly preferably 10-20% by weight sulfolane.
  • the dye inks according to the invention can contain further organic solvents with a total content of 5-20%, preferably 5-15% by weight.
  • Suitable organic solvents are, for example
  • Alcohols e.g. B. methanol, ethanol, 1-propanol, isopropanol, 1-butanol, tert. butanol,
  • Pentyl alcohol polyhydric alcohols e.g. E.g. 1, 2-ethanediol, 1, 2,3-propanetriol, butanediol, 1, 3-
  • Polyalkylene glycols e.g. E.g .: polyethylene glycol, polypropylene glycol, alkylene glycols with 2 to 8 alkylene groups, e.g. E.g .: monoethylene glycol, diethylene glycol,
  • Amines such as For example: methylamine, ethylamine, triethylamine, diethylamine, dimethylamine, trimethylamine, dibutylamine, diethanolamine, triethanolamine, N-acetylethanolamine, N-formylethanolamine, ethylenediamine, urea derivatives, such as e.g. For example: urea, thiourea, N-methylurea, N, N'- ⁇ dimethylurea, ethyleneurea, 1, 1, 3,3-tetramethylurea, amides, such as, for. For example: dimethylformamide, dimethylacetamide, acetamide, ketones or keto alcohols, such as.
  • acetone, diacetone alcohol, cyclic ethers such as e.g. B .; Tetrahydrofuran, trimethylolethane, trimethylolpropane, 2-butoxyethanol, benzyl alcohol, 2-butoxyethanol, gamma-butyrolactone, ⁇ - caprolactam, also dimethylsulfolane, methylsulfolane, 2,4-dimethylsulfolane, dimethylsulfone, butadienesulfone, dimethylsulfoxide, dibutylrolidone, dibutylrolidone N-methyl-2-pyrrolidone, N-ethyl-pyrrolidone, 2-pyrrolidone, 1- (2-hydroxyethyl) -2-pyrrolidone, 1- (3-hydroxypropyl) -2-pyrrolidone, 1, 3-dimethyl-2- imidazolidinone, 1, 3-dimethyl-2-imidazolinone, 1, 3-bismethoxymethyl
  • the printing inks according to the invention can contain the usual additives contain, such as viscosity moderators to adjust viscosities in the range of 1.5 to 40.0 mPa * s in a temperature range of 20 to 50 ° C.
  • Preferred inks have a viscosity of 1.5 to 20 mPa * s and particularly preferred inks have a viscosity of 1.5 to 15 mPa * s.
  • Suitable viscosity moderators are, for example, rheological additives: polyvinyl caprolactam, polyvinyl pyrrolidone and their copolymers polyether polyol, associative thickener, polyurea, polyurethane, sodium alginates, modified galactomannans, polyether urea, polyurethane, nonionic cellulose ethers.
  • the inks according to the invention can have surface-active substances for setting surface tensions of 20 to 65 mN / m, which may be adapted depending on the method used (thermal or piezo technology).
  • Suitable surface-active substances are: nonionic surfactants, butyl diglycol, 1, 2 hexanediol.
  • the inks can also contain conventional additives, such as substances for inhibiting fungal and bacterial growth, in amounts of from 0.01 to 1% by weight, based on the total weight of the ink.
  • the inks can be prepared in a conventional manner by mixing the components in water.
  • the dye inks according to the invention are suitable for use in ink jet printing processes for printing on a wide variety of prepared materials, such as silk, leather, wool, polyamide fibers and polyurethanes, and in particular cellulose-containing fiber materials of all kinds.
  • Such fiber materials are, for example, the natural cellulose fibers, such as cotton, linen and Hemp, as well as cellulose and regenerated cellulose.
  • the printing inks according to the invention are also for printing pretreated hydroxyl-containing or Suitable fibers containing amino groups, which are contained in blended fabrics, for example mixtures of cotton, silk, wool with polyester fibers or polyamide fibers.
  • the auxiliaries in ink jet printing have to be applied to the textile substrate in a separate pre-treatment step.
  • the pretreatment of the textile substrate such as cellulose and
  • alkali for example sodium carbonate, sodium bicarbonate, sodium acetate, trisodium phosphate, sodium silicate, sodium hydroxide
  • alkali donors such as, for example, sodium trichloroacetate, sodium formate
  • hydrotropic substances such as, for example, urea
  • reduction inhibitors such as, for example, sodium nitrobenzenesulfonate
  • the thickening agent and the thickening agent Prevent motives when applying the printing ink, for example sodium alginates, modified polyacrylates or highly etherified galactomannans.
  • reagents for prepreparation are applied evenly to the textile substrate in a defined amount using suitable applicators, for example with a 2 or 3-roll pad, with contactless spray technologies, by means of foam application or with appropriately adapted inkjet technologies and then dried.
  • the textile fiber material is dried at 120 to 150 ° C and then fixed.
  • the ink-jet prints produced with reactive dyes can be fixed at room temperature, or with saturated steam, with superheated steam, with hot air, with microwaves, with infrared radiation, with laser or electron beams or with other suitable types of energy transmission.
  • This pretreatment can be omitted for two-phase fixation. Only alkali is required for fixation, which is applied after ink-jet printing before the fixation process without intermediate drying. Additional additives such as urea or thickeners can be dispensed with.
  • the print aftertreatment is carried out, which is the prerequisite for good fastness properties, high brilliance and a perfect white background.
  • the prints produced with the dye inks according to the invention in particular on cellulose fiber materials, have a high color strength and high fiber-dye binding stability in both acidic and alkaline ranges, furthermore good light fastness and very good wet fastness properties, such as washing, water and sea water -, over-dyeing and perspiration fastness, as well as good pleating fastness, ironing fastness and rubbing fastness.
  • Parts by weight relate to parts by volume such as kilograms to liters.
  • EXAMPLE 1 A textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 100 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried. The Fleet uptake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • Example 3 A textile fabric consisting of leached viscose is padded with a liquor containing 35 g / l sodium carbonate, 200 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the Fleet uptake is 70%.
  • the print is dried completely. It is fixed with saturated steam at 102 ° C for 8 minutes.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. A red print with excellent fastness properties is obtained.
  • a textile fabric consisting of leached viscose is padded with a liquor containing 30 g / l sodium bicarbonate, 200 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • Example 5 A textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 50 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the Fleet uptake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 100 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • EXAMPLE 7 A textile fabric consisting of leached viscose is padded with a liquor containing 35 g / l sodium carbonate, 200 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried. The Fleet uptake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 150 g / l urea 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • EXAMPLE 9 A textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 150 g / l urea 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried. The Fleet uptake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate and 100 g / l urea 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • Example 11 A textile fabric consisting of mercerized cotton is padded with a liquor containing 40 g / l sodium bicarbonate, 100 g / l urea 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the Fleet uptake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 40 g / l sodium bicarbonate, 100 g / l urea 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • a textile fabric consisting of mercerized cotton is with a liquor containing 35 g / l sodium carbonate, 50 g / l urea 150 g / l low-viscosity Na alginate solution (6%) padded and then dried.
  • the fleet intake is 70%.
  • Example 14 A textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 100 g / l urea 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried. The fleet intake is 70%.
  • Example 15 The print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. A black print with excellent fastness properties is obtained.
  • Example 15 The print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. A black print with excellent fastness properties is obtained.
  • a textile fabric consisting of leached viscose is padded with a liquor containing 35 g / l sodium bicarbonate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of leached viscose is padded with a liquor containing 35 g / l sodium bicarbonate, 100 g / l urea and 150 g / l of a low-viscosity Na alginate solution (6%) and then dried.
  • N-methyl-2-pyrrolidone 72% water printed with a drop-on-demand (bubble jet) inkjet printhead. The print is dried completely. It is fixed with saturated steam at 102 ° C for 8 minutes.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 30 g / l sodium bicarbonate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. A green print with excellent fastness properties is obtained.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 100 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • aqueous ink containing 12% Cl reactive yellow 95 10% sulfolane 10% butyl diglycol 68% water is printed onto the textile pretreated in this way using a drop-on-demand (piezo) inkjet print head.
  • the print is dried completely. It is fixed with saturated steam at 102 ° C for 8 Minutes.
  • a textile fabric consisting of mercerized cotton is combined with a
  • the fleet intake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of leached viscose is padded with a liquor containing 35 g / l sodium carbonate, 200 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • EXAMPLE 21 A textile fabric consisting of leached viscose is padded with a liquor containing 35 g / l sodium carbonate, 200 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the liquor containing 35 g / l sodium carbonate, 200 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) is then dried.
  • a textile fabric consisting of mercerized cotton is combined with a
  • the fleet intake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. You get a gray print with excellent fastness properties.
  • a textile fabric consisting of mercerized cotton is combined with a
  • the fleet intake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of leached viscose is padded with a liquor containing 35 g / l sodium carbonate, 200g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing 10% Cl reactive orange 35 9% sulfolane 5% butyl diglycol 76% water is printed onto the textile pretreated in this way using a drop-on-demand (piezo) inkjet print head. The print is dried completely. It is fixed with saturated steam at 102 ° C for 8 minutes.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • N-methyl-2-pyrrolidone 15% water printed with a drop-on-demand (piezo) inkjet printhead.
  • the print is dried completely. It is fixed with saturated steam at 102 ° C for 8 minutes.
  • a textile fabric consisting of mercerized cotton is with a liquor containing 35 g / l sodium carbonate, 150 g / l urea and 150 g / l low-viscosity Na alginate solution (6%) padded and then dried.
  • the fleet intake is 70%.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 100 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • Example 28 The print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. A navy blue print with excellent fastness properties is obtained.
  • Example 28
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 40 g / l sodium bicarbonate, 100 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 40 g / l sodium bicarbonate, 100 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • Example 30 A textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 50 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried. The uptake of fleets is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. You get a gray print with excellent fastness properties.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 100 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • Example 32 A textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium bicarbonate, 120 g / l urea and 150 g / l of a low-viscosity Na alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. An orange print with excellent fastness properties is obtained.
  • a textile fabric consisting of leached viscose is padded with a liquor containing 35 g / l sodium bicarbonate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing is applied to the textile pretreated in this way 10% Cl reactive red 218 5% sulfolane
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of leached viscose is padded with a liquor containing 35 g / l sodium bicarbonate, 200 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. A blue print with excellent fastness properties is obtained.
  • a textile fabric consisting of mercerized cotton is combined with a Liquor containing 30 g / l sodium carbonate, 100 g / l urea and 150 g / l of a low-viscosity Na alginate solution (6%) padded and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. A red print with excellent fastness properties is obtained.
  • a textile fabric consisting of debossed silk is padded with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a textile fabric consisting of debossed silk is padded with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • Example 38 A textile fabric consisting of debossed silk is padded with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) and then dried. The fleet intake is 70%. An aqueous ink containing 14% C.I. Reactive Orange 107
  • the print is dried completely. It is fixed with saturated steam at 102 ° C for 20 minutes.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C. and rinsed warm and then dried.
  • Example 39 A textile fabric consisting of debossed silk is padded with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a textile fabric consisting of debossed silk is padded with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • aqueous ink containing 8% Cl Reactive Orange 16 14% Sulfolan 78% water is printed on the thus pretreated textile with a drop-on-demand (bubble jet) inkjet print head.
  • the print is dried completely. It is fixed with saturated steam at 102 ° C for 20 minutes.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm, and then dried.
  • a textile fabric consisting of debossed silk is padded with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • a textile fabric consisting of debossed silk is padded with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing is applied to the textile pretreated in this way
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a textile fabric consisting of debossed silk is padded with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • Example 44 The print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried. A red print with excellent fastness properties is obtained.
  • Example 44
  • a textile fabric consisting of debossed silk is padded with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • a textile fabric consisting of debossed silk is padded with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing 10% Cl reactive blue 19 16% sulfolane 3% butyl diglycol 0.5% modified Phoshonate 70.5% water is applied to the textile pretreated in this way printed with a drop-on-demand (Piezo) InkJet printhead. The print is dried completely. It is fixed with saturated steam at 102 ° C for 20 minutes.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a blue print with excellent fastness properties is obtained.
  • Example 46 A textile fabric consisting of debossed silk is mixed with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l highly etherified
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a turquoise-colored print with excellent fastness properties is obtained.
  • a textile fabric consisting of debossed silk is padded with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing is applied to the textile pretreated in this way 12% Cl reactive blue 229 7% sulfolane
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a textile fabric consisting of debossed silk is mixed with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a textile fabric consisting of debossed silk, is combined with a liquor, containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) padded and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried. You get a gray print with excellent fastness properties.
  • a textile fabric consisting of debossed silk is padded with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a navy blue print with excellent fastness properties is obtained.
  • a textile fabric consisting of debossed silk is padded with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a yellow print with excellent fastness properties is obtained.
  • a textile fabric consisting of debossed silk is padded with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried. A red print with excellent fastness properties is obtained.
  • Example 53 A textile fabric consisting of debossed silk is mixed with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified one
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a turquoise blue print with excellent fastness properties is obtained.
  • a textile fabric consisting of debossed silk is padded with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing is applied to the textile pretreated in this way 8% Cl reactive black 14 15% o Sulfolan 5% polyether polyol 72% water printed with a Continuous Flow (Piezo) InkJet printhead. The print is dried completely. It is fixed with saturated steam at 102 ° C for 20 minutes.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a textile fabric consisting of debossed silk is mixed with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a textile fabric consisting of debossed silk, is combined with a liquor, containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) padded and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a textile fabric consisting of debossed silk is padded with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • a textile fabric consisting of debossed silk is padded with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • Example 59 A textile fabric consisting of debossed silk is mixed with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l highly etherified
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried. A red print with excellent fastness properties is obtained.
  • a textile fabric consisting of debossed silk is padded with a liquor containing 50 g / l sodium acetate, 100 g / l urea and 150 g / l of a highly etherified galactomannan (5%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a yellow print with excellent fastness properties is obtained.
  • a textile fabric consisting of chlorinated wool is mixed with a liquor, containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity sodium alginate solution (5%) padded and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a textile fabric consisting of chlorinated wool is mixed with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low viscosity
  • Na alginate solution (5%) padded and then dried.
  • the fleet intake is 70%.
  • a textile fabric consisting of chlorinated wool is mixed with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low viscosity
  • Na alginate solution (5%) padded and then dried.
  • the fleet intake is 70%.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity sodium alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing 10% Cl reactive blue 19 16% sulfolane 3% butyl diglycol 0.5% modified phosphonates 70.5% water is applied to the textile pretreated in this way printed with a drop-on-demand (Piezo) InkJet printhead. The print is dried completely. It is fixed with saturated steam at 102 ° C for 20 minutes.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a blue print with excellent fastness properties is obtained.
  • Example 67 A textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity sodium alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity sodium alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing 10% Cl reactive red 198 12% sulfolane 6% butyl diglycol 0.5% modified phosphonates is applied to the textile pretreated in this way
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing is applied to the textile pretreated in this way
  • Example 70 The print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried. A red print with excellent fastness properties is obtained.
  • Example 70
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing is applied to the textile pretreated in this way
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity sodium alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing 15 > Cl reactive black 5 10% sulfolane 12%) N-methyl-2-pyrrolidone 63%) water is printed onto the textile pretreated in this way using a drop-on-demand (piezo) inkjet print head.
  • the print is dried completely. It is fixed with saturated steam at 102 ° C for 20 minutes.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a textile fabric consisting of chlorinated wool is mixed with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low viscosity
  • Na alginate solution (5%) padded and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • Example 73 A textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity sodium alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing 10% Cl reactive blue 21 5% sulfolane is applied to the textile pretreated in this way
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a turquoise-colored print with excellent fastness properties is obtained.
  • Example 76 A textile fabric consisting of chlorinated wool is mixed with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low viscosity
  • Na alginate solution (5%) padded and then dried.
  • the fleet intake is 70%.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing is applied to the textile pretreated in this way
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity sodium alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing 10.5% Cl reactive red 180 15% sulfolane 8% polyether polyol 66.5% water is printed onto the textile thus pretreated using a continuous flow (piezo) inkjet print head.
  • the print is dried completely. It is fixed with saturated steam at 102 ° C for 20 minutes.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a yellow print with excellent fastness properties is obtained.
  • Example 80 A textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a turquoise-colored print with excellent fastness properties is obtained.
  • a textile fabric consisting of chlorinated wool is mixed with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low viscosity
  • Na alginate solution (5%) padded and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • Example 82 A textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity sodium alginate solution (5%) and then dried. The fleet admission is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a yellow print with excellent fastness properties is obtained.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., warm rinsed and then dried.
  • Example 84 A textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm with the addition of 1-2 ml of ammonia 25%, subjected to a fastness wash with hot water at 70 to 80 ° C., rinsed warm and then dried.
  • a textile fabric consisting of chlorinated wool is padded with a liquor containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing is applied to the textile pretreated in this way
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 100 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. You get a brilliant, yellow print with excellent fastness properties.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing is applied to the textile pretreated in this way 9% Cl Reactive Orange 13 12% Sulfolan 10% Polyetherpolyol 69% Water printed with a Continuous Flow (Piezo) InkJet print head. The print is dried completely. It is fixed with saturated steam at 102 ° C for 8 minutes.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. An orange-colored print with excellent fastness properties is obtained.
  • a textile fabric consisting of leached viscose is padded with a liquor containing 35 g / l sodium carbonate, 200 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • Example 89 A textile fabric consisting of leached viscose is padded with a liquor containing 35 g / l sodium carbonate, 200 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the Fleet uptake is 70%.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 50 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing is applied to the textile pretreated in this way
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 100 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing is applied to the textile pretreated in this way
  • Example 92 A textile fabric consisting of leached viscose is padded with a liquor containing 35 g / l sodium carbonate, 200 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing 12% C.I. Reactive Red 218 10% Sulfolan 10% N-Methyl-2-Pyrrolidone 5% Polyvinylpyrrolidon 63% Water printed with a Continuous Flow (Piezo) InkJet print head. The print is dried completely. It is fixed with saturated steam at 102 ° C for 8 minutes.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 150 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • Example 95 A textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 100 g / l urea and 150 g / l of a low-viscosity Na alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. A navy blue print with excellent fastness properties is obtained.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 40 g / l sodium bicarbonate, 100 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing is applied to the textile pretreated in this way 15% Cl reactive black 5 20% sulfolane 6% polyvinylcaprolactam 0.3% modified polyphosphonate 58.7% water printed with a Continuous Flow (Piezo) InkJet printhead. The print is dried completely. It is fixed with saturated steam at 102 ° C for 8 minutes.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 40 g / l sodium bicarbonate, 100 g / l urea 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • Example 98 The print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. A green print with excellent fastness properties is obtained.
  • Example 98 The print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. A green print with excellent fastness properties is obtained.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 50 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 100 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • Example 100 A textile fabric consisting of mercerized cotton is padded with a liquor containing 150 g / l of a low-viscosity Na alginate solution (6%) and then dried. The fleet intake is 70%. An aqueous ink containing 11% C.I. Reactive Yellow 37 18% Sulfolan
  • a textile fabric consisting of mercerized cotton is containing with an aqueous ink
  • a textile fabric consisting of leached viscose is containing with an aqueous ink
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a turquoise blue print with excellent fastness properties is obtained.
  • a textile fabric consisting of leached viscose is padded with a liquor containing 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing is applied to the textile pretreated in this way
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. An orange-colored print with excellent fastness properties is obtained.
  • a textile fabric consisting of leached viscose is padded with a liquor containing 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing is applied to the textile pretreated in this way
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. You get a gray print with excellent fastness properties.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing 10% Cl Regent Rot 218 10% Sulfolan is applied to the textile pretreated in this way 5% N-methyl-2-pyrrolidone 2% poiypropylene glycol 73% water printed with a Continuous Flow (Piezo) InkJet printhead. The print is dried completely.
  • the fixation takes place according to the technologies known for two-phase fixation.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 150 g / l of a low-viscosity Na alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • Example 107 The print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. A navy blue print with excellent fastness properties is obtained.
  • Example 107 The print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. A navy blue print with excellent fastness properties is obtained.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • Example 108 A textile fabric consisting of mercerized cotton is padded with a liquor containing 150 g / l of a low-viscosity Na alginate solution (6%) and then dried. The fleet intake is 70%. An aqueous ink containing 10% C.I. Reactive red 239 12% sulfolane
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. A red print with excellent fastness properties is obtained.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 80 g / l Na trichloroacetate and 150 g / l urea and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. A yellow print with excellent fastness properties is obtained.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 80 g / l Na trichloroacetate and 50 g / l urea and then dried.
  • the fleet intake is 70%.
  • aqueous ink containing 8% Cl reactive orange 16 12% sulfolane 6% N-methyl-2-pyrrolidone 74% water is applied to the textile pretreated in this way printed with a drop-on-demand (bubble jet) inkjet printhead.
  • the print is dried completely. It is fixed with saturated steam at 102 ° C for 10 minutes.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of leached viscose is padded with a liquor containing 80 g / l sodium trichloroacetate and 150 g / l urea and then dried.
  • the fleet intake is 70%.
  • modified polyphosphonate 75.5% water printed with a drop-on-demand (Piezo) InkJet printhead. The print is dried completely. It is fixed with saturated steam at 102 ° C for 10 minutes.
  • a textile fabric consisting of leached viscose is padded with a liquor containing 80 g / l sodium trichloroacetate and 150 g / l urea and then dried.
  • the fleet intake is 70%.
  • Example 113 A textile fabric consisting of bleached linen is padded with a liquor containing 80 g / l Na trichloroacetate, 150 g / l urea and a liquor containing 150 g / l of a low-viscosity Na alginate solution (5%) and then padded dried.
  • the fleet intake is 70%.
  • Example 114 The print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. An orange-colored print with excellent fastness properties is obtained.
  • Example 114
  • a textile fabric consisting of leached viscose is padded with a liquor containing 80 g / l Na trichloroacetate, 150 g / l urea and a liquor containing 150 g / l of a low-viscosity Na alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. An orange-colored print with excellent fastness properties is obtained.
  • a textile fabric consisting of leached viscose is padded with a liquor containing 80 g / l Na trichloroacetate, 150 g / l urea and a liquor containing 150 g / l of a low-viscosity Na alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • Example 116 A textile fabric consisting of mercerized cotton is padded with a liquor containing 80 g / l Na trichloroacetate, 50 g / l urea and a liquor containing 150 g / l of a low-viscosity Na alginate solution (5%) and then padded dried. The fleet intake is 70%. An aqueous ink containing 10% Cl reactive blue 229 12% sulfolane 6% N-methyl-2-pyrrolidone is applied to the textile pretreated in this way
  • a textile fabric consisting of bleached linen is padded with a liquor containing 80 g / l Na trichloroacetate, 100 g / l urea and a liquor containing 150 g / l of a low-viscosity Na alginate solution (5%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium carbonate, 100 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 35 g / l sodium bicarbonate and 250 g / l urea and then dried.
  • the fleet intake is 70%.
  • a textile fabric consisting of leached viscose is padded with a liquor containing 35 g / l sodium carbonate, 100 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a textile fabric consisting of mercerized cotton is padded with a liquor containing 30 g / l sodium carbonate and 100 g / l urea and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. A red print with excellent fastness properties is obtained.
  • a textile fabric consisting of bleached linen is padded with a liquor containing 35 g / l sodium carbonate and 150 g / l urea and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing is applied to the textile pretreated in this way
  • a textile fabric consisting of leached viscose is padded with a liquor containing 35 g / l sodium carbonate and 200 g / l urea and then dried.
  • the fleet intake is 70%.
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried.
  • a turquoise blue print with excellent fastness properties is obtained.
  • a textile fabric consisting of leached viscose is padded with a liquor containing 30 g / l sodium carbonate and 180 g / l urea and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing is applied to the textile pretreated in this way
  • a textile fabric consisting of leached viscose is padded with a liquor containing 30 g / l sodium carbonate, 100 g / l urea and 150 g / l of a low-viscosity Na-alginate solution (6%) and then dried.
  • the fleet intake is 70%.
  • An aqueous ink containing is applied to the textile pretreated in this way
  • Example 126 A textile fabric consisting of leached viscose is padded with a liquor containing 35 g / l sodium carbonate and 250 g / l urea and then dried. The fleet intake is 70%. An aqueous ink containing 12% C.I. Reactive blue 234 10% sulfolane
  • the print is then rinsed warm, subjected to a fastness wash with hot water at 95 ° C., rinsed warm and then dried. A navy blue print with excellent fastness properties is obtained.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Coloring (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Ink Jet (AREA)
PCT/EP2001/000882 2000-02-04 2001-01-27 Wässrige drucktinten für den einsatz nach dem tintenstrahldruck-verfahren, ihre herstellung und ihre verwendung auf textilen fasermaterialien WO2001057308A2 (de)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CA002399119A CA2399119A1 (en) 2000-02-04 2001-01-27 Aqueous printing inks for use in the inkjet printing, preparation thereof and use thereof on textile fiber materials
DE50111094T DE50111094D1 (de) 2000-02-04 2001-01-27 Wässrige drucktinten für den einsatz nach dem tintenstrahldruck-verfahren, ihre herstellung und ihre verwendung auf textilen fasermaterialien
JP2001555930A JP2003521572A (ja) 2000-02-04 2001-01-27 インクジェット捺染で使用する水性捺染インク、その調製および織物繊維でのその使用
HU0204369A HUP0204369A2 (en) 2000-02-04 2001-01-27 Aqueous printing inks for use in the ink-jet printing method the production and the use on textile fibre materials thereof
EP01909699A EP1268922B1 (de) 2000-02-04 2001-01-27 Wässrige drucktinten für den einsatz nach dem tintenstrahldruck-verfahren, ihre herstellung und ihre verwendung auf textilen fasermaterialien
MXPA02007555A MXPA02007555A (es) 2000-02-04 2001-01-27 Tintas de impresion acuosas para usarse en el metodo de impresion por inyeccion de tinta, la produccion y el uso de las mismas en materiales de fibras textiles.
BR0108097-0A BR0108097A (pt) 2000-02-04 2001-01-27 Tintas de impressão aquosas para uso em impressão por jato de tinta, preparação e uso das mesmas em materiais fibras têxteis

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10004954.0 2000-02-04
DE10004954A DE10004954A1 (de) 2000-02-04 2000-02-04 Wässrige Drucktinten für den Einsatz nach dem Tintenstrahldruck-Verfahren, ihre Herstellung und ihre Verwendung auf textilen Fasermaterialien

Publications (2)

Publication Number Publication Date
WO2001057308A2 true WO2001057308A2 (de) 2001-08-09
WO2001057308A3 WO2001057308A3 (de) 2002-03-14

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US (1) US20030172840A1 (cs)
EP (1) EP1268922B1 (cs)
JP (1) JP2003521572A (cs)
KR (1) KR100707575B1 (cs)
CN (1) CN1292122C (cs)
AT (1) ATE340893T1 (cs)
BR (1) BR0108097A (cs)
CA (1) CA2399119A1 (cs)
CZ (1) CZ20022661A3 (cs)
DE (2) DE10004954A1 (cs)
ES (1) ES2270983T3 (cs)
HU (1) HUP0204369A2 (cs)
MX (1) MXPA02007555A (cs)
PT (1) PT1268922E (cs)
TW (1) TWI278553B (cs)
WO (1) WO2001057308A2 (cs)
ZA (1) ZA200205628B (cs)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004031468A3 (en) * 2002-10-01 2004-09-10 Lumenia Technology Ltd Methods of colouring materials
ITMI20090149A1 (it) * 2009-02-05 2010-08-06 Everlight Usa Inc Composizione di inchiostro

Families Citing this family (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030199611A1 (en) * 2002-03-08 2003-10-23 Chandrasekaran Casey K. Inkjet ink for textiles
US6866378B2 (en) * 2002-10-28 2005-03-15 Hewlett-Packard Development Company, L.P. Conductive additives for use in printing processes employing radiational drying
KR100499312B1 (ko) * 2002-11-22 2005-07-04 세기유화주식회사 수용성 날염 잉크의 제조방법 및 그 방법에 의해 제조된잉크
US20070103529A1 (en) * 2003-06-16 2007-05-10 Kornit Digital Ltd. Process and system for printing images on absorptive surfaces
US11447648B2 (en) 2004-05-30 2022-09-20 Kornit Digital Ltd. Process and system for printing images on absorptive surfaces
US7351277B2 (en) * 2004-09-08 2008-04-01 E. I. Du Pont De Nemours And Company IR transparent cyan inkjet ink
CA2600416A1 (en) 2004-11-01 2006-05-11 Basf Corporation Radiofrequency activated inkjet inks and apparatus for inkjet printing
JP2006199888A (ja) * 2005-01-24 2006-08-03 Seiko Epson Corp 水性インク組成物及びそれを用いたインクジェット記録方法、並びに記録物
US20130153440A9 (en) * 2006-11-13 2013-06-20 Kc Energy, Llc Rf systems and methods for processing salt water
US9550374B1 (en) 2007-06-27 2017-01-24 Cafepress Inc. System and method for improved digital printing on textiles
CN101519551B (zh) * 2008-02-25 2011-07-20 明德国际仓储贸易(上海)有限公司 墨水组成物
CN102076793B (zh) * 2008-07-31 2016-05-18 日本化药株式会社 喷墨印染用油墨组和使用了该油墨组的纤维印染方法
JP2010084058A (ja) * 2008-10-01 2010-04-15 Mimaki Engineering Co Ltd インクジェット捺染用インク組成物
JP2010084289A (ja) * 2008-10-01 2010-04-15 Mimaki Engineering Co Ltd インクジェット捺染方法
CN101952503A (zh) * 2008-10-01 2011-01-19 株式会社御牧工程 喷墨印染用墨水组合物及喷墨印染方法
US8540358B2 (en) 2009-08-10 2013-09-24 Kornit Digital Ltd. Inkjet compositions and processes for stretchable substrates
TWI425055B (zh) * 2009-08-21 2014-02-01 Everlight Chem Ind Corp 反應性印花染料及其液態組成物之應用
US8926080B2 (en) 2010-08-10 2015-01-06 Kornit Digital Ltd. Formaldehyde-free inkjet compositions and processes
WO2012127274A1 (en) * 2011-03-18 2012-09-27 Indian Institute Of Technology Delhi Apparatus and methods for dyeing of fibers
EP2743318B1 (en) * 2011-08-09 2017-11-29 Nippon Kayaku Kabushiki Kaisha Gray ink composition for ink jet printing and method for printing fibers using same
CN104768769B (zh) * 2012-06-04 2017-08-04 惠普发展公司，有限责任合伙企业 织物印刷介质
JP6090320B2 (ja) * 2012-07-23 2017-03-08 コニカミノルタ株式会社 インクジェット捺染インクセット
JP6136577B2 (ja) * 2012-12-10 2017-05-31 セイコーエプソン株式会社 インクジェット捺染用インク組成物およびインクジェット捺染方法
JP6198341B2 (ja) * 2013-09-12 2017-09-20 日本化薬株式会社 インク組成物及び繊維の捺染方法
JP6233579B2 (ja) * 2013-12-17 2017-11-22 セイコーエプソン株式会社 インクジェット捺染用のインク組成物および捺染方法
JP6402980B2 (ja) * 2014-08-01 2018-10-10 セイコーエプソン株式会社 インクジェット捺染用インク組成物及び捺染方法
KR101694726B1 (ko) * 2015-05-29 2017-01-10 주식회사 디지아이 디지털 날염 전처리용 조성물
JP6605765B2 (ja) * 2016-03-16 2019-11-13 富士フイルム株式会社 インク
US10259961B2 (en) * 2016-03-24 2019-04-16 Seiko Epson Corporation Ink jet textile printing ink composition, ink set, and printing method
JP6801305B2 (ja) * 2016-03-24 2020-12-16 セイコーエプソン株式会社 インクジェット捺染用インク組成物、インクセット及び記録方法
CN106320015B (zh) * 2016-08-17 2019-01-11 上海贝通色彩科技有限公司 一种数码印花活性红色墨水及其制备方法
CA3041443A1 (en) 2016-10-31 2018-05-03 Kornit Digital Ltd. Dye-sublimation inkjet printing for textile
WO2018097061A1 (ja) * 2016-11-25 2018-05-31 日本化薬株式会社 インク、インクセット、及び繊維の捺染方法
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EP3342927B1 (en) 2016-12-28 2019-08-14 Seiko Epson Corporation Ink jet ink composition for textile printing, ink set, and recording method
US10894896B2 (en) * 2016-12-28 2021-01-19 Seiko Epson Corporation Ink jet ink composition for textile printing, ink set, and recording method
JP6972741B2 (ja) * 2016-12-28 2021-11-24 セイコーエプソン株式会社 捺染用インクジェットインク組成物、インクセット及び記録方法
JP2019060051A (ja) * 2017-09-27 2019-04-18 セイコーエプソン株式会社 記録方法
JP7017054B2 (ja) 2017-09-29 2022-02-08 セイコーエプソン株式会社 インクジェット捺染インク、インクジェット捺染インクセットおよび捺染方法
EP3701082A4 (en) 2017-10-22 2021-10-13 Kornit Digital Ltd. LOW FRICTION IMAGES BY INKJET PRINTING
EP3868237B1 (en) 2017-10-27 2024-11-13 Nike Innovate C.V. Articles comprising coated fibers and methods of making articles with coated fibers
JP2019137793A (ja) * 2018-02-13 2019-08-22 セイコーエプソン株式会社 捺染インクジェットインク組成物セット及び記録方法
WO2020176081A1 (en) 2019-02-27 2020-09-03 Nike Innovate C.V. Articles, bladders and methods of making articles and bladders
EP3924431B1 (en) * 2019-03-18 2022-07-06 Nike Innovate C.V. Colorant solvent system, methods of use, and articles
JP7639338B2 (ja) * 2020-12-28 2025-03-05 セイコーエプソン株式会社 水系インクジェットインク組成物および記録方法
KR102826397B1 (ko) * 2025-01-03 2025-06-27 주식회사 삼우디티피 디지털 텍스타일 프린팅의 전처리 공정 및 이 공정을 포함하는 디지털 텍스타일 프린팅법

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56161479A (en) * 1980-04-10 1981-12-11 Canon Inc Recording liquid and recording method
US5364462A (en) * 1991-08-14 1994-11-15 Graphic Utilities, Incorporated Waterfast inks
JP3323549B2 (ja) * 1991-09-26 2002-09-09 キヤノン株式会社 インクジェット捺染用インク及びインクジェット捺染方法
US5250121A (en) * 1991-09-26 1993-10-05 Canon Kabushiki Kaisha Ink-jet textile printing ink and ink-jet textile printing process
TW228543B (cs) * 1992-09-26 1994-08-21 Hoechst Ag
US5258064A (en) * 1992-12-17 1993-11-02 Xerox Corporation Ink compositions and preparation processes thereof
JP2895695B2 (ja) * 1992-12-17 1999-05-24 キヤノン株式会社 インクジェット捺染用布帛、インクジェット捺染方法及び捺染物
JP3666895B2 (ja) * 1993-01-13 2005-06-29 キヤノン株式会社 インクジェット捺染インク、かかるインクを用いた捺染方法、機器および得られる捺染物
DE4306433A1 (de) * 1993-03-02 1994-09-08 Hoechst Ag Ink-Jet-Einphasen-Reaktivdruck
JP3376002B2 (ja) * 1993-03-23 2003-02-10 キヤノン株式会社 インクジェット捺染インク、インクジェット捺染方法、記録ユニット、インクカートリッジ、インクジェット記録装置、捺染された布帛および布帛の加工品
US5500023A (en) * 1993-04-21 1996-03-19 Canon Kabushiki Kaisha Ink-jet printing process, ink set for use in such process, and processed article obtained thereby
JP2959692B2 (ja) * 1993-04-21 1999-10-06 キヤノン株式会社 インクジェット捺染方法
JP2959691B2 (ja) * 1993-04-21 1999-10-06 キヤノン株式会社 インクジェット捺染方法
JP3270598B2 (ja) * 1993-11-08 2002-04-02 キヤノン株式会社 インクジェット捺染用布帛並びにインクジェット捺染方法並びに捺染物
DE4417718A1 (de) * 1994-05-20 1995-11-23 Hoechst Ag Reaktivfarbstoffe für den Tintenstrahldruck
US6015454A (en) * 1997-06-17 2000-01-18 Ciba Specialty Chemicals Corporation Process for printing textile fibre materials in accordance with the ink-jet printing process
US5972084A (en) * 1997-06-17 1999-10-26 Ciba Specialty Chemicals Corporation Process for printing textile fiber materials in accordance with the ink-jet printing process
US5958120A (en) * 1998-02-02 1999-09-28 Xerox Corporation Ink compositions with improved waterfastness
US6054505A (en) * 1998-03-24 2000-04-25 Xerox Corporation Ink compositions with improved shelf stability

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004031468A3 (en) * 2002-10-01 2004-09-10 Lumenia Technology Ltd Methods of colouring materials
ITMI20090149A1 (it) * 2009-02-05 2010-08-06 Everlight Usa Inc Composizione di inchiostro

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DE10004954A1 (de) 2001-08-16
PT1268922E (pt) 2007-01-31
MXPA02007555A (es) 2002-12-13
CZ20022661A3 (cs) 2002-11-13
HUP0204369A2 (en) 2003-04-28
ZA200205628B (en) 2003-11-26
CN1398311A (zh) 2003-02-19
CN1292122C (zh) 2006-12-27
KR100707575B1 (ko) 2007-04-13
TWI278553B (en) 2007-04-11
WO2001057308A3 (de) 2002-03-14
JP2003521572A (ja) 2003-07-15
US20030172840A1 (en) 2003-09-18
BR0108097A (pt) 2002-10-29
CA2399119A1 (en) 2001-08-09
DE50111094D1 (de) 2006-11-09
EP1268922B1 (de) 2006-09-27
KR20020073199A (ko) 2002-09-19
ATE340893T1 (de) 2006-10-15
EP1268922A2 (de) 2003-01-02
ES2270983T3 (es) 2007-04-16

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