TWI278553B - Aqueous printing inks for use in ink-jet printing, preparation thereof and use thereof, on textile fiber materials - Google Patents

Aqueous printing inks for use in ink-jet printing, preparation thereof and use thereof, on textile fiber materials Download PDF

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TWI278553B
TWI278553B TW090102072A TW90102072A TWI278553B TW I278553 B TWI278553 B TW I278553B TW 090102072 A TW090102072 A TW 090102072A TW 90102072 A TW90102072 A TW 90102072A TW I278553 B TWI278553 B TW I278553B
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dried
reactive
printed
printing
water
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TW090102072A
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Chinese (zh)
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Karl-Hans Blank
Horst Roland Mach
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Dystar Textilfarben Gmbh & Co
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/30Ink jet printing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Coloring (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Ink Jet (AREA)

Abstract

An aqueous inkjet printing ink including one or more reactive dyes, sulfolane and a buffer system and having a pH of not more than 7.0 when one or more of said reactive dyes have reactive systems of the vinyl sulfone series is prepared and used on textile fiber materials.

Description

I278553 A7 五、發明說明(彳) 數位印刷技術在未來的紡織和非紡織領域將愈趨重要 〇 傳統紡織印刷中已改變的市場期待需求在設計,彩色 和輸料時間上的更高可撓性。數位噴墨技術恰可合乎所求 。藉由毋須製備印刷篩而可直接從電腦經由印刷噴嘴印刷 ’此一新穎技術改善了印刷方法之可撓性,效率與環保性 能。它實際提供整體操作,縮短印刷時間且符合市場發展 之迅速反應需求與製程中中間步驟較少的需求。 噴墨印刷方法經常水性墨水進行,其係以小水滴型態 直接噴灑至基材上。有一種連續型態的方法係在均勻速率 下,將墨水經由噴嘴以壓電方式壓製並依製備型態,藉由 電場偏轉至基材上,還有一種非間歇是噴墨或drop-on-demand的方法,其中,墨水僅在上色點出現處被逐出。後 一種方法採用壓電結晶或經加熱之cannula (氣泡或熱噴射 方法)施壓於墨水系統上以噴射出墨水滴粒。這些技術揭 示於 Text.Chem.Color,19(8)卷 2 3ff 頁和 21 卷 27ff 頁中。 此一高敏感性顯微技術需要發展符合,例如,純度、 顆粒大小、黏度、表面張力、導電性、物化安定性、熱物 理性質、p Η値、不起泡、顏色強度、堅牢度與貯存安定 性等高度要求的適合染料組成构。傳統類似紡織印刷上使 用之粉末、顆粒或液態組成物型態的商售反應性染料包含 顯著Μ量電解質,防塵劑和標準化劑(standanzer)而在噴墨 印刷上產生大量問題。另一方面,如非紡織材料(例如, 紙、木材、塑膠、陶瓷,等)所用的染色墨水在使用容易 本紙張尺度適用中國國家標準(CNS)A4規格(2】0 X 297公釐) (請先閱讀背面之注意事項再填寫本頁)I278553 A7 V. INSTRUCTIONS (彳) Digital printing technology will become increasingly important in the future of textiles and nonwovens. The market that has changed in traditional textile printing expects higher flexibility in design, color and delivery time. . Digital inkjet technology is exactly what you want. This novel technology improves the flexibility, efficiency and environmental performance of the printing process by eliminating the need to prepare a printing screen that can be printed directly from a computer via a printing nozzle. It actually provides overall operation, reduces printing time and meets the rapid response needs of the market and the need for fewer intermediate steps in the process. Ink jet printing processes are often carried out with aqueous inks which are sprayed directly onto the substrate in the form of small water droplets. There is a continuous type of method in which the ink is piezoelectrically pressed through a nozzle at a uniform rate and, depending on the preparation, deflected onto the substrate by an electric field, and a non-intermittent inkjet or drop-on- A method of demand in which ink is ejected only at the point where the color point appears. The latter method applies piezoelectric crystals or heated cannula (bubble or thermal spray method) to the ink system to eject ink droplets. These techniques are disclosed in Text. Chem. Color, 19(8), Vol. 2, 3ff, and 21, Vol. This highly sensitive microscopy technology needs to be developed to meet, for example, purity, particle size, viscosity, surface tension, electrical conductivity, physical and chemical stability, thermophysical properties, p Η値, non-foaming, color strength, fastness and storage. Stable and other highly desirable dye compositions. Commercially available reactive dyes, which are conventionally used in the form of powders, granules or liquid compositions used in textile printing, contain significant amounts of electrolytes, dusting agents and standardizers, which create a number of problems in ink jet printing. On the other hand, dyed inks used in non-woven materials (eg, paper, wood, plastics, ceramics, etc.) are easily applied to the Chinese National Standard (CNS) A4 specification (2] 0 X 297 mm). Please read the notes on the back and fill out this page.)

-4 1278553 A7 ____B7^__ 五、發明說明(2 ) 性及在紡織材料上之印刷顏色得率與堅牢度方面僅獲致不 令人滿意的結果。 (請先閱讀背面之注意事項再填寫本頁) 歐洲專利申請案E P — A 0 8 8 6 〇 〇 〇和 EP — A 0 885998 ,EP 0 62 0 116 , EP — A 0606777,DE — A4417718, D E - A 4 4 1 7 7 1 9揭示包含纖維反應性染料之染料 墨水。這些染料墨水具有某些使用缺點,例如,不令人滿 意的染料墨水安定性或因墨水中之染料和纖維間的不充分 交互作用而致低染料得率。歐洲專利申請案 EP — A0 6 0 2 8 8 5揭示非織物用之含四亞甲基碾烷 的染料墨水,其不適用於織物用途。因此,亟需一種具有 改良性質(尤其是使用性質)之纖維反應性染料的噴墨印 刷法用新穎印刷染料。 本發明的目的在於提供不具有前述缺點的印刷墨水。 令人驚訝的,現已發現包含四亞甲基硕烷(其不破壞 反應性染料之反應性且同時可避免噴嘴阻塞),一或多種 反應性染料和確保反應性基團功能之緩衝系統的水性印刷 墨水可提供優良結果。 因此,本發明係提供一種水性織物噴墨印刷墨水,其 包含一或多種反應性染料,四亞甲基砸烷和一緩衝系統且 當一或多種前述反應性染料具有乙烯基碼系之反應系統時 ,其PH値不大於7 .〇。 有用的染料包括所有在,例如,歐洲專利申請案( EP — B590397 , EP — A8860〇〇和 EP — 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 1278553 A7 B7 五、發明說明(3 ) A 6 1 3 9 7 5 )中提及的反應性染料。 參見具有單氯三嗪和/或乙烯基四亞甲基砸烷系反應 (請先閱讀背面之注意事項再填寫本頁) 系統之反應性染料。 單氯三嗪系染料之實例爲: C. I. Reactive Yellow 85, C. I. Reactive Yellow 95, C. I. Yellow 181, C. I. Reactive Orange 12, C. I. Reactive Orange 13, C. I. Reactive Orange 35, C. I. Reactive Red 3:1, C. I. Reactive Red 24, C. I. Reactive Red 31 ,C. I. Reactive Red 45, C. I. Reactive Red 187, C. I. Reactive Red 218, C. I. Reactive Red 245, C. I. Reactive Violet 1, C. I. Reactive Blue 13, C. I. Reactive Blue 49, C. I. Reactive Blue 71, C. I. Reactive Blue 72, C. I. Reactive 巳lue 162, C. I. Reactive Blue 234, C. I. Reactive Brown 11, C. I. Reactive Brown 17, C. I. Reactive Brown 38, C. I. Reactive Black 8, C. I. Reactive Black 39. 單氯三嗪系之較佳染料實例爲: C. I. Reactive Yellow 85, C. I. Reactive Yellow 95, C. I. Reactive Orange 12, C. I. Reactive Orange 13, C. I. Reactive Red 187, C. I. Reactive Red 218, C. I. Reactive Blue 49, C. I. Reactive Blue 72, C. I. Reactive Blue 234, C. I. Reactive Black 8, C. I. Reactive Black 39. 乙烯基四亞甲基砸烷染料之實例爲 C. I· Reactive 丫ellow 15, C. I. Reactive Yellow 37, C. I. Reactive Yellow 42, C. I. Reactive Orange 16, C. I. Reactive Orange 74, C. I. Reactive Orange 107, C. I. Reactive Red 23, C. I. Reactive Red 35, C. I. Reactive Red 106, C. I. Reactive Red 180, C. I. Reactive Violet 5, C. I. Reactive Blue 19, C. I. Reactive Blue 21, C. I. Reactive Blue 38, C. I. Reactive Blue 229, C. I_ Reactive Brown 18, C. I. Reactive Black 5, C. I. Reactive Black 14, C. I. Reactive Black 31. 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -6 - 1278553 A7 ____ B7 _ 五、發明說明(4 ) 乙燒基四亞甲基砸院染料之較佳實例爲: C. I. Reactive Yellow 37, C. I. Reactive Orange 16, C. I. Reactive Orange 74, C. I. Reactive Red 35, C. I. Reactive Red 180, C. I. Reactive Blue 19, C. I. Reactive Blue 21, C. I. Reactive Black 5, C. I. Reactive Black 14, C. I. Reactive Black 31. 雙重及混合的反應性產物係如C.I.ReacUve Red 1 98,C.I.Reactive Red 239,C.I.Reactive Black 5,C.I.Reactive B1 ue 21 o 所用之反應性染料係屬已知且由傳統之重氮化反應, 偶合反應和縮合反應製得。 本發明之印刷墨水包含數量爲,例如,0.1-50,宜爲 1 - 3 0,尤宜爲5 - 2 5重量百分比(以墨水總重量爲基準)的 一或多種反應性染料。 當本發明之印刷墨水包含單氯三嗪系之染料時,印刷 墨水之P Η値宜使用適當緩衝系統調節至7.0-9.0。他們之 使用數量爲0.1-3,宜爲0.5-1.5重量百分比(以墨水總重量 爲基準)。 供包含單氯三嗪系染料之印刷墨水用的有用緩衝系統 包括,例如,硼砂,磷酸氫二鈉,改良之磷酸酯, D E A S。 ,· 當本發明之印刷墨水包含乙烯基四亞甲基碼院系染料_ 時,印刷墨水之P Η値宜使用適當緩衝系統調節至3 . 〇_7 .〇 。他們之使用數量爲0.1-3,宜爲0.5-2.5重量百分比(以墨 水總重量爲基準)。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁) 裝 · 1278553 A7 ____B7__ 五、發明說明(5 ) -1 Γ I II ^1 I I I 1 I —^^^1 · I I (請先閱讀背面之注意事項再填寫本頁) 供包含乙烯基四亞甲基硕烷系染料之印刷墨水用的有 用緩衝系統包括,例如,磷酸鈉,檸檬酸鈉,改良之磷酸 酯。 其他有用之緩衝系統揭示於: "Chemie der 曰emente'VCH Verlagsgesellschaft mbH, 1st edition 1988, pages 665 to 666, Holleman-Wiberg, Lehrbuch der anorganischen Chemie, WDG & Co.-4 1278553 A7 ____B7^__ V. INSTRUCTIONS (2) Sexuality and print color yield and fastness on textile materials have only resulted in unsatisfactory results. (Please read the note on the back and then fill out this page.) European Patent Application EP - A 0 8 8 6 〇〇〇 and EP - A 0 885998, EP 0 62 0 116 , EP - A 0606777, DE - A4417718, DE - A 4 4 1 7 7 1 9 discloses a dye ink comprising a fiber-reactive dye. These dye inks have certain disadvantages of use, such as unsatisfactory dye ink stability or low dye yield due to insufficient interaction between dyes and fibers in the ink. European Patent Application EP-A0 6 0 2 8 8 5 discloses a dye ink containing tetramethylene-millane for non-woven fabrics which is not suitable for use in fabrics. Accordingly, there is a need for a novel printing dye for ink jet printing having a fiber reactive dye having improved properties, particularly in the nature of use. It is an object of the present invention to provide a printing ink that does not have the aforementioned disadvantages. Surprisingly, it has now been found to include tetramethylene alkane (which does not destroy the reactivity of the reactive dye while avoiding nozzle clogging), one or more reactive dyes and a buffer system that ensures the functionality of the reactive groups. Aqueous printing inks provide excellent results. Accordingly, the present invention provides an aqueous fabric inkjet printing ink comprising one or more reactive dyes, tetramethylene decane and a buffer system and when one or more of the foregoing reactive dyes have a vinyl code system reaction system When the PH値 is not greater than 7. 〇. Useful dyes include all, for example, European Patent Application (EP-B590397, EP-A8860〇〇 and EP). This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1278553 A7 B7 V. DESCRIPTION OF THE INVENTION (3) Reactive dyes mentioned in A 6 1 3 9 7 5 ). See reactive dyes for systems with monochlorotriazine and/or vinyl tetramethylene decane (please read the notes on the back and fill out this page). Examples of monochlorotriazine dyes are: CI Reactive Yellow 85, CI Reactive Yellow 95, CI Yellow 181, CI Reactive Orange 12, CI Reactive Orange 13, CI Reactive Orange 35, CI Reactive Red 3:1, CI Reactive Red 24 , CI Reactive Red 31, CI Reactive Red 187, CI Reactive Red 218, CI Reactive Red 245, CI Reactive Violet 1, CI Reactive Blue 13, CI Reactive Blue 49, CI Reactive Blue 71, CI Reactive Blue 72 , CI Reactive 巳lue 162, CI Reactive Blue 234, CI Reactive Brown 11, CI Reactive Brown 17, CI Reactive Brown 38, CI Reactive Black 8, CI Reactive Black 39. Examples of preferred dyes for monochlorotriazines are: CI Reactive Yellow 85, CI Reactive Yellow 95, CI Reactive Orange 13, CI Reactive Red 187, CI Reactive Red 218, CI Reactive Blue 49, CI Reactive Blue 72, CI Reactive Blue 234, CI Reactive Black 8, CI Reactive Black 39. Vinyltetramethylene decane dye Examples are C. I. Reactive 丫ellow 15, CI Reactive Yellow 37, CI Reactive Yellow 42, CI Reactive Orange 16, CI Reactive Orange 74, CI Reactive Orange 107, CI Reactive Red 23, CI Reactive Red 35, CI Reactive Red 106 , CI Reactive Red 180, CI Reactive Violet 5, CI Reactive Blue 19, CI Reactive Blue 21, CI Reactive Blue 38, CI Reactive Blue 229, C. I_ Reactive Brown 18, CI Reactive Black 5, CI Reactive Black 14, CI Reactive Black 31. This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) -6 - 1278553 A7 ____ B7 _ V. Description of invention (4) Ethylene-based tetramethylene brothel dyes are preferred Examples are: CI Reactive Yellow 37, CI Reactive Orange 16, CI Reactive Orange 74, CI Reactive Red 35, CI Reactive Red 180, CI Reactive Blue 19, CI Reactive Blue 21, CI Reactive Black 5, CI Reactive Black 14, CI Reactive Black 31. Dual and mixed reactive products such as CIReacUve Red 1 98, CIReactive Red 239, CI .Reactive Black 5, C.I. Reactive B1 ue 21 o The reactive dyes used are known and are prepared by conventional diazotization, coupling and condensation reactions. The printing ink of the present invention comprises one or more reactive dyes in an amount of, for example, 0.1 to 50, preferably 1 to 30, particularly preferably 5 to 25% by weight based on the total weight of the ink. When the printing ink of the present invention contains a monochlorotriazine-based dye, the P of the printing ink should be adjusted to 7.0-9.0 using a suitable buffer system. They are used in an amount of 0.1-3, preferably 0.5-1.5 weight percent based on the total weight of the ink. Useful buffer systems for printing inks containing monochlorotriazine-based dyes include, for example, borax, disodium hydrogen phosphate, modified phosphates, D E A S. When the printing ink of the present invention contains a vinyltetramethylene yard dye _, the printing ink P should be adjusted to 3 using a suitable buffer system. 〇_7 . They are used in an amount of 0.1-3, preferably 0.5-2.5 weight percent based on the total weight of the ink. This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill out this page). · 1278553 A7 ____B7__ V. Invention description (5 ) -1 Γ I II ^ 1 III 1 I —^^^1 · II (Please read the notes on the back and fill out this page.) Useful buffering systems for printing inks containing vinyl tetramethylene-based dyes include, for example, sodium phosphate. , sodium citrate, modified phosphate. Other useful buffering systems are disclosed in: "Chemie der 曰emente'VCH Verlagsgesellschaft mbH, 1st edition 1988, pages 665 to 666, Holleman-Wiberg, Lehrbuch der anorganischen Chemie, WDG & Co.

Verlage 47th to 56th edition, pages 109 to 110, Laborchemikaiienverlag der Fa. MERCK, Darmstadt, Ausgabe 1999, pages 1128 to 1133, uDer Fischer Chemicals Katalog" (Fischer Scientific UK, 1999) page 409 to 411, Riedel-de Haen, Laborchemikalien 1996, page 946 to 951, Riedel-de Haen, Labor-Hilfstabellen No. 6, buffer solutions. 墨水中所用之染料特別含有小於0.1重量% ,例如, 0.0卜0.099 (以染料重量爲基準)的鹽含量。若必要的話, 在用於本發明墨水中前,染料必須經脫鹽處理,例如,利 用薄膜分離方法。 爲使染料用於連續流動方法中,可藉由加入電解質而 將導電性固定於〇. 5 - 2 5 m S / m。 有用之電解質包括,例如,硝酸鋰和硝酸鉀。 % 本發明之墨水包含,例如,、.1-30,宜爲5-25,尤宜爲 10-20重量%的四亞甲基硕烷。 本發明之染料墨水以及四亞甲基砸烷可包含其他有機 溶劑至總含量5-20重量% ,宜爲5-15重量% 。有用之有機 溶劑包括,例如,醇類,如,甲醇,乙醇,1 -丙醇,異丙 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -R - 1278553 Α7 Β7 五、發明說明(6 ) 醇,1-丁醇,特丁醇,戊醇;多元醇,如,丨.2_乙二醇, 1.2.3-丙三醇,1.3-丁二醇,1.4-丁二醇 ’ 1.2-丙二醇,2.3 醇 醇 1.4' 醇 1. 5 -戊二醇 醇,D,L·Verlage 47th to 56th edition, pages 109 to 110, Laborchemikaiienverlag der Fa. MERCK, Darmstadt, Ausgabe 1999, pages 1128 to 1133, uDer Fischer Chemicals Katalog" (Fischer Scientific UK, 1999) page 409 to 411, Riedel-de Haen, Laborchemikalien 1996, page 946 to 951, Riedel-de Haen, Labor-Hilfstabellen No. 6, buffer solutions. The dye used in the ink contains, in particular, a salt content of less than 0.1% by weight, for example, 0.0, 0.099 (based on the weight of the dye). If necessary, the dye must be desalted prior to use in the ink of the present invention, for example, by a film separation method. In order to use the dye in the continuous flow method, the conductivity can be fixed to 〇. 5 - 2 5 m S / m by adding an electrolyte. Useful electrolytes include, for example, lithium nitrate and potassium nitrate. % The ink of the present invention contains, for example, .1 to 30, preferably 5 to 25, particularly preferably 10 to 20% by weight of tetramethylene alkane. The dye ink of the present invention and tetramethylene decane may contain other organic solvents to a total content of 5 to 20% by weight, preferably 5 to 15% by weight. Useful organic solvents include, for example, alcohols such as methanol, ethanol, 1-propanol, isopropyl paper scales applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -R - 1278553 Α7 Β7 5 , invention description (6) alcohol, 1-butanol, tert-butanol, pentanol; polyol, such as 丨.2_ethylene glycol, 1.2.3-glycerol, 1.3-butanediol, 1.4-butyl Diol '1.2-propanediol, 2.3 alcohol 1.4' alcohol 1.5-pentanediol, D, L·

L 1.2-己二醇,1.6-己二醇,1·2·6-己二醇,1.2-辛二醇;聚 (烷撐)二醇,如,聚乙二醇,聚丙二醇;具有2-8個烷撐 基之烷撐二醇,如,單乙撐二醇,二乙撐二醇’三乙撐二 醇,四乙撐二醇,硫甘醇,硫二甘醇,丁基三甘醇,己二 醇,丙二醇,二丙二醇,三丙二醇;多元醇之低烷醚,如 ,乙二醇單甲醚,乙二醇單乙醚,乙二醇單丁醚,二乙二 醇單甲醚,二乙二醇單乙醚,二乙二醇單丁醚,二乙二醇 單己醚,三乙二醇單甲醚,三乙二醇單丁醚,三丙二醇單 甲醚,四乙二醇單甲醚,四乙二醇單丁醚,四乙二醇二甲 醚,丙二醇單甲醚,丙二醇單乙醚,丙二醇單丁醚,三丙 二醇異丙醚;聚烷撐二醇醚,如,聚乙二醇單甲醚,聚丙 二醇甘油醚,聚乙二醇三癸醚,聚乙二醇壬苯基醚;胺類 ,如,甲胺,乙胺,三乙胺,二乙胺,二甲胺,三甲胺, 二丁胺,二乙醇胺,三乙醇胺,Ν-乙醯基乙醇胺,Ν-甲醯 基乙醇胺,乙撐二胺;脲,硫脲,Ν-甲基脲,Ν,Ν-二甲基 脲,乙撐脲,1,1,3,3-四甲基脲;醯胺類,如,二甲基甲醯 胺,二甲基乙醯胺,乙醯胺;酮.類或酮醇類,如,丙酮, 二乙酮醇;環醚類,如,四氫呋喃,三羥甲基乙烷,三羥— 甲基丙烷,2-丁氧基乙醇,苯甲醇,2-丁氧基乙醇,r -丁 內酯,ε-己內醯胺,以及二甲基四亞甲基砸烷,甲基四亞 甲基硕烷,2,4-二甲基四亞甲基硕烷,二甲基碾,丁二烯 (請先閱讀背面之注意事項再填寫本頁) 訂:L 1.2-hexanediol, 1.6-hexanediol, 1·2·6-hexanediol, 1.2-octanediol; poly(alkylene) glycol, such as polyethylene glycol, polypropylene glycol; 8 alkylene glycol diols, such as monoethylene glycol, diethylene glycol 'triethylene glycol, tetraethylene glycol, thioglycol, thiodiglycol, butyl triglyceride Alcohol, hexanediol, propylene glycol, dipropylene glycol, tripropylene glycol; low alkyl ethers of polyols, such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether , diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol monohexyl ether, triethylene glycol monomethyl ether, triethylene glycol monobutyl ether, tripropylene glycol monomethyl ether, tetraethylene glycol Monomethyl ether, tetraethylene glycol monobutyl ether, tetraethylene glycol dimethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, tripropylene glycol isopropyl ether; polyalkylene glycol ether, such as poly Ethylene glycol monomethyl ether, polypropylene glycol glyceryl ether, polyethylene glycol triterpene ether, polyethylene glycol phenyl ether; amines, such as methylamine, ethylamine, triethylamine, diethylamine, dimethyl Amine, trimethylamine, dibutylamine, two Alcoholamine, triethanolamine, hydrazine-acetamidoethanolamine, hydrazine-mercaptoethanolamine, ethylenediamine; urea, thiourea, hydrazine-methylurea, hydrazine, hydrazine-dimethylurea, ethylene urea, 1 , 1,3,3-tetramethylurea; guanamines, such as dimethylformamide, dimethylacetamide, acetamide; ketones or ketones, such as acetone, diethyl Keto alcohols; cyclic ethers such as tetrahydrofuran, trimethylolethane, tris-methylpropane, 2-butoxyethanol, benzyl alcohol, 2-butoxyethanol, r-butyrolactone, ε- Caprolactam, and dimethyltetramethylene decane, methyltetramethylene sulane, 2,4-dimethyltetramethylene sulane, dimethyl milling, butadiene (please Read the notes on the back and fill out this page)

本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -9- 澄齊STto曰慧讨轰苟SL肖Mk-ivn乍土 1278553 A7 ___ B7_ 五、發明說明(7 ) 硕,二甲基亞碾,二丁基亞砸,二甲基亞碩,N_環己基吡 略烷酮,N-甲基-2-吡咯烷酮,N-乙基-2』比咯烷酮,2-吡略 烷酮,1- ( 2-羥乙基)-2-吡咯烷酮,1- ( 3-羥丙基)-2-吡 咯烷酮,1,3-二甲基-2-咪唑烷酮,1,3-二甲基-2-咪唑啉酮 ,1,3-雙甲氧基甲基咪唑烷,2- ( 2-甲氧基乙氧基)乙醇 ,2-( 2-乙氧基乙氧基)乙醇,2-( 2-丁氧基乙氧基)乙 醇’ 2- ( 2-丙氧基乙氧基)乙醇,卩比卩定,π辰卩定,丁內酯, 三羥甲基丙烷,1,2-二甲氧基丙烷,二噁烷,乙酸乙酯, 乙撐二胺四乙酸酯,乙基戊基醚,丨,2-二甲氧基丙烷,三· 羥甲基丙烷。 本發明之印刷墨水可再包含傳統添加物,例如,黏度 調節劑以固定黏度在1.5-40.OmPa*s範圍內(在20-50 °C溫 度範圍內)。較佳之墨水黏度爲1.5-20mPa*s且更理想之墨 水具有1.5-15mPa*s的黏度。 有用的黏度調節劑包括流變添加劑,例如,聚乙烯基 己內醯胺,聚乙烯基吡咯烷酮及其供劇務聚醚多元醇,組 合稠化劑,聚脲,聚胺基甲烷,藻朊酸鈉,甘露半乳聚糖 ,聚醚脲,聚氨基甲酸酯,非離子性纖維素醚。本發明墨 水之其他添加劑可包括表面活性物質以固定表面張力於2 0 -65mN/m,其視需要經調整爲所用方法(熱或壓力技術)的函 數。 有用之表面活性物質包括,例如: 非離子性表面活性物質,丁基二甘醇,1,2 -己二醇。 此墨水還可包含傳統添加劑,例如,抑制黴菌和細菌 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁)This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) -9- Cheng Qi STto曰慧讨轰苟SL 肖 Mk-ivn乍土1278553 A7 ___ B7_ V. Invention description (7) Master, Dimethyl argon, dibutyl sulfoxide, dimethyl arsenic, N-cyclohexyl pyrrolidone, N-methyl-2-pyrrolidone, N-ethyl-2" pyrrolidone, 2- Pyrrolidone, 1-(2-hydroxyethyl)-2-pyrrolidone, 1-(3-hydroxypropyl)-2-pyrrolidone, 1,3-dimethyl-2-imidazolidinone, 1,3 - dimethyl-2-imidazolidinone, 1,3-bismethoxymethylimidazolidine, 2-(2-methoxyethoxy)ethanol, 2-(2-ethoxyethoxy) Ethanol, 2-(2-butoxyethoxy)ethanol '2-(2-propoxyethoxy)ethanol, anthraquinone, π chenidine, butyrolactone, trimethylolpropane, 1,2-dimethoxypropane, dioxane, ethyl acetate, ethylenediaminetetraacetate, ethylpentyl ether, hydrazine, 2-dimethoxypropane, trimethylolpropane. The printing ink of the present invention may further comprise a conventional additive, for example, a viscosity modifier having a fixed viscosity in the range of 1.5 to 40.OmPa*s (in the range of 20 to 50 °C). Preferably, the ink has a viscosity of 1.5 to 20 mPa*s and more preferably the ink has a viscosity of 1.5 to 15 mPa*s. Useful viscosity modifiers include rheological additives such as polyvinyl caprolactam, polyvinylpyrrolidone and its functional polyether polyols, combination thickeners, polyureas, polyaminomethane, sodium alginate , mannose galactan, polyether urea, polyurethane, nonionic cellulose ether. Other additives to the ink of the present invention may include a surface active material at a fixed surface tension of from 20 to 65 mN/m, which is adjusted as a function of the method used (thermal or pressure technique) as needed. Useful surface active materials include, for example, nonionic surface active materials, butyl diglycol, 1,2-hexanediol. This ink can also contain traditional additives such as mold and bacteria. This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill out this page)

-10 - 1278553 A7 __ B7___ 五、發明說明(8 ) 成長的物質,其數量佔墨水總重量之0 · 0 1 -1重量% 。本墨 水可依傳統方法,由混合各成分於水中而製得。 本發明之染料墨水可用於噴墨印刷方法中以供印刷多 種預經處理之材料,諸如,絲製品,皮革,羊毛,聚醯胺 纖維和聚氨基甲酸乙酯纖維,特別是任何種類之纖維素纖 維材料。前述纖維材料係如天然纖維中之纖維素纖維,諸 如,棉花,亞麻和大麻,以及紙獎和再生纖維素。本發明 之印刷墨水亦可用於印刷以摻合纖維(例如,棉花,絲, 羊毛與聚酯纖維或聚醯胺纖維之摻合物)存在的預經處理 含羥基或含胺基纖維。 和傳統織物印刷(其印刷墨水已包含所有固定化學品 和反應性染料之稠化劑)相反地,在此噴墨印刷中,輔助 劑必須在個別之預處理步驟中施加至織物基材。 織物基材(例如,纖維素與再生纖維素纖維以及絲和 羊毛)之預處理係在印刷前用含水鹼液進行。爲了固定反 應性染料必須用鹼,其如碳酸鈉,碳酸氫鈉,乙酸鈉,磷 酸三鈉,矽酸鈉,氫氧化鈉,鹼給予體,諸如,三氯乙酸 鈉,甲酸鈉,水溶性物質,諸如,脲,還原抑制劑,例如 ,硝酸苯磺酸鈉以及避免施用印刷墨水時流體流動的稠化 劑,例如,藻朊酸鈉,改良聚丙烯酸酯或高度醚化甘露半 乳聚糖。 這些預處理試劑係使用適當塗布器(例如,使用2-或 3-輥墊),無接觸噴灑技術,利用泡沫塗布或使用適當經 改良噴墨技術,定量地均勻塗布至織物基材上,隨後加以 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -—W — W------.— (請先閱讀背面之注意事項再填寫本頁) 訂· 經濟部智慧財產局員工消費合作杜印製 -11 - 1278553 A7 B7 經濟部智慧財產局員工消費合作fi印製 五、發明說明(9 ) 乾燥。 印刷後,紡織纖維材料於1 20-1 50 °C乾燥且隨之予以 固定。 用反應性染料製得之噴墨印刷的固定可於室溫下或使 用過熱蒸氣,熱空氣,微波,紅外線,雷射或電子束或使 用其他適當能量轉移技術進行。 在單-與雙相固定方法之間有所不同: 在單-相固定中,必要之固定化學品已在織物基材上。 在雙··相固定中,此一預處理是不必要的。固定僅需鹼 ,其在噴墨印刷後,在固定前施加而毋須中間乾燥。其亦 不需要其他添加劑,諸如,脲或稠化劑。 固定後隨之進行印刷後處理,此係獲致優異堅牢度, 高鮮豔度與無缺點白底之要件。 用本發明染料墨水製得之印刷(尤其是在纖維素纖維 材料上)具有高度彩色強度和高度纖維-染料結合安定性( 不僅在酸性範圍,在鹼性範圍亦然)優異耐光性及非常優 異之耐濕性(諸如,洗滌,水,海水),交染與耐汗堅牢 度,以及對熱固定和電鍍之優異堅牢性與甕堅牢度。 以下實例說明本發明。除非另外指明,否則份數與百 分比均按重量計。重量份數與體積份數之關聯恰如千克與 升之關聯。 ^ 實例一 商售棉花之紡織織物塡塞以含有35g/l無水碳酸鈉, --m--rm---I I I ___ (請先閱讀背面之注意事項再填寫本頁) 訂· ^_ 鲁 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -12- 1278553 A7 B7 五、發明說明(1Q ) 100g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是7 0 % 。如此製得之預處理織物使用 (請先閱讀背面之注意事項再填寫本頁) d r 〇 p - ◦ η - d e m a n d (泡沬噴射)噴墨印刷頭,用包含以下成分 之水性墨水印刷: 1 2 % C.I. Reactive Yellow 95 10 % 四亞甲基硕烷 7 8 °/〇 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之鮮黃色印刷。 商售棉花之紡織織物塡塞以含有35g/l無水碳酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 d r ο p - ο η - d e m a n d (泡沫噴射)噴墨印刷頭,用包含以下成分 之水性墨水印刷: 經濟部智慧財產局員工消費合作社印製 1 5 % C.I. Reactive Orange 13 12 °/〇 四亞甲基碾烷 、 7 3 °/〇 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -13- 1278553 A7 __B7 _._ 五、發明說明(11 ) 結果獲得具有優異使用堅牢性之橙色印刷。 實例三 商售棉花之紡織織物塡塞以含有35g/l無水碳酸鈉’ 200g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 d r ο ρ - ο η - d e m a n d (泡沫噴射)噴墨印刷頭,用包含以下成分 之水性墨水印刷: 12 % C.I. Reactive Yellow 95 10 % 四亞甲基砸烷 7 8 °/〇 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗’用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例四 經鹼化黏膠絲之紡織織物塡塞以含有30g/l無水碳酸鈉 ,200g/l脲和150g/l低黏度藻阮酸鈉溶液(6 % )的液體後 加以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使 用drop-on-demand (泡沫噴射)、噴墨印刷頭,用包含以]、 成分之水性墨水印刷: 12 % C.I. Reactive Blue 21 15 % 四亞甲基碾烷 7 3 % 水 _ Ί/1 _ (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 1278553 A7 B7 五、發明說明(12 ) (請先閱讀背面之注意事項再填寫本頁) 印刷物經完全乾燥。在於1 02 t下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之藍綠色印刷。 實例五 商售棉花之紡織織物塡塞以含有3 5 g /1無水碳酸鈉’ 50g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是7 0 % 。如此製得之預處理織物使用 drop-on-demand (泡沫噴射)噴墨印刷頭,用包含以下成分 之水性墨水印刷: 8 % C.I. Reactive Black 1 4 10 % 四亞甲基砸烷 8 2% 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之灰色印刷。 經齊郎知曰慧时轰局員1.消費^咋:±1中製 實例六 、 商售棉花之紡織織物塡塞以含有35g/l無水碳酸鈉, lOOg/ί脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (泡沫噴射)噴墨印刷頭’用包含以下成分 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -15 - 1278553 A7 _B7______ 五、發明說明(13 ) 之水性墨水印刷: 12% C .1. Reactive Orange 12 (請先閱讀背面之注意事項再填寫本頁) 8 % 四亞甲基砸院 8 0 % 水 印刷物經完全乾燥。在於1 〇2 °C下’利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗’用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之金黃色印刷。 實例七 經鹼化黏膠絲之肪織織物塡基以含有3 5 g /1無水碳酸納 ,200g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後 加以乾燥。潮濕收獲物是7 0 % 。如此製得之預處理織物使 用drop-on-demand (泡沫噴射)噴墨印刷頭’用包含以下 成分之水性墨水印刷: 10% C.I. Reactive Orange35 6 °/〇 四亞甲基硕烷 8 4 % 水 經齊郎智慧时轰咼員X.消費合阼fi中製 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經、加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之褐紅色印刷。 實例八 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -16- 1278553 A7 B7 五、發明說明(14 ) (請先閱讀背面之注意事項再填寫本頁) 商售棉花之紡織織物塡塞以含有35g/l無水碳酸鈉’ 150g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (泡沫噴射)噴墨印刷頭’用包含以下成分 之水性墨水印刷: 12 °/〇 C.I. Reactive Red 218 10 % 四亞甲基砸烷 7 8 °/〇 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在9 5 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例九 商售棉花之紡織織物塡塞以含有35g/l無水碳酸鈉’ 150g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (泡沫噴射)噴墨印刷頭’用包含以下成分 經濟部智慧財產局員工消費合作杜印製 之水性墨水印刷: 1 5 % C.I. Reactive Blue 49,. 10 % 四亞甲基硕烷 7 5 % 水-10 - 1278553 A7 __ B7___ V. INSTRUCTIONS (8) The amount of the substance growing is 0. 0 1 -1% by weight based on the total weight of the ink. The ink can be prepared by mixing the ingredients in water according to a conventional method. The dye inks of the present invention can be used in ink jet printing processes for printing a variety of pretreated materials such as silk products, leather, wool, polyamide fibers and polyurethane fibers, particularly any type of cellulose. Fiber material. The aforementioned fibrous materials are such as cellulose fibers in natural fibers, such as cotton, linen and hemp, as well as paper and regenerated cellulose. The printing inks of the present invention can also be used to print pre-treated hydroxyl- or amin-containing fibers in the presence of fibers (e.g., cotton, silk, blends of wool and polyester fibers or polyamide fibers). In contrast to conventional fabric printing, which has all of the fixing chemicals and thickeners for reactive dyes, in this ink jet printing, the adjuvant must be applied to the textile substrate in a separate pretreatment step. Pretreatment of the fabric substrate (e.g., cellulose and regenerated cellulose fibers, as well as silk and wool) is carried out with an aqueous lye prior to printing. In order to fix the reactive dye, it is necessary to use a base such as sodium carbonate, sodium hydrogencarbonate, sodium acetate, trisodium phosphate, sodium citrate, sodium hydroxide, an alkali donor such as sodium trichloroacetate, sodium formate, a water-soluble substance, For example, urea, a reduction inhibitor, for example, sodium benzene sulfonate, and a thickening agent that avoids fluid flow when applying printing ink, for example, sodium alginate, modified polyacrylate or highly etherified mannan galactan. These pretreatment reagents are quantitatively uniformly applied to the textile substrate using a suitable applicator (for example, using a 2- or 3-roll pad), contactless spraying technique, using foam coating or using suitable modified inkjet techniques, followed by Apply this paper scale to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -—W — W------.— (Please read the notes on the back and fill out this page) Intellectual Property Bureau employee consumption cooperation Du printing system -11 - 1278553 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau staff consumption cooperation fi printing five, invention description (9) dry. After printing, the textile fiber material is dried at 1 20-1 50 °C and then fixed. The fixing of the ink jet printing made with the reactive dye can be carried out at room temperature or using superheated steam, hot air, microwave, infrared, laser or electron beam or using other suitable energy transfer techniques. There is a difference between the single- and two-phase fixation methods: In single-phase fixation, the necessary fixing chemicals are already on the textile substrate. In the double phase fixation, this preprocessing is unnecessary. Fixation requires only alkali, which is applied prior to fixation after inkjet printing without the need for intermediate drying. It also does not require other additives such as urea or thickeners. After the fixation, the post-printing treatment is followed, which results in excellent fastness, high vividness and impeccable white background. Printing made with the dye ink of the invention (especially on cellulosic fiber materials) has high color strength and high fiber-dye binding stability (not only in the acidic range, but also in the alkaline range) excellent light fastness and excellent Moisture resistance (such as washing, water, sea water), cross-dyeing and perspiration fastness, and excellent fastness and fastness to heat setting and plating. The following examples illustrate the invention. Parts and percentages are by weight unless otherwise indicated. The association between parts by weight and parts by volume is just like the association between kilograms and liters. ^ Example 1 Commercial textile woven cotton fabric with 35g / l anhydrous sodium carbonate, --m--rm---III ___ (please read the back of the note before you fill out this page) Book · ^_ Ruben Paper scale applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -12- 1278553 A7 B7 V. Invention description (1Q) 100g/l urea and 150g/l low viscosity sodium alginate solution (6%) The liquid is then dried. The wet harvest is 70%. The pretreated fabric thus obtained is used (please read the note on the back and fill out this page) dr 〇p - ◦ η - demand (injection jet) inkjet print head, printed with water-based ink containing the following ingredients: 1 2 % CI Reactive Yellow 95 10% tetramethylene sulphate 7 8 ° / hydrazine print was completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a bright yellow printing having excellent use fastness was obtained. Commercially available cotton woven fabrics were smeared with a liquid containing 35 g/l of anhydrous sodium carbonate, 150 g/l of urea and 150 g/l of low viscosity sodium alginate solution (6%) and dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a dr ο p - ο η - demand (foam jet) inkjet print head with an aqueous ink containing the following ingredients: Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed 1 5 % CI Reactive Orange The 13 12 ° / 〇 tetramethylene hexane, 7 3 ° / 〇 water print was completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -13- 1278553 A7 __B7 _._ V. Invention Description (11) The result is an orange print with excellent use fastness. Example 3 A woven fabric of cotton was smeared with a liquid containing 35 g/l of anhydrous sodium carbonate '200 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a dr ο ρ - ο η - demand (foam jet) inkjet print head with an aqueous ink containing the following ingredients: 12 % CI Reactive Yellow 95 10 % tetramethylene decane 7 8 The °/hydrophobic print is completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further subjected to warm rinsing and washing with hot water at 95 ° C, rinsing with heating, and then drying. As a result, red printing with excellent use fastness was obtained. Example 4 A woven fabric of alkalized viscose wadding was dried with a liquid containing 30 g/l of anhydrous sodium carbonate, 200 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand, ink jet print head with an aqueous ink containing the ingredients: 12% CI Reactive Blue 21 15 % tetramethylene milling 7 3 %水_ Ί/1 _ (Please read the notes on the back and fill out this page) This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1278553 A7 B7 V. Invention Description (12) ( Please read the notes on the back and fill out this page.) The printed matter is completely dry. At 10 2 t, it was fixed with saturated steam for 8 minutes. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a blue-green printing having excellent use fastness was obtained. Example 5 A woven fabric of cotton for sale was dried with a liquid containing 35 g / 1 anhydrous sodium carbonate '50 g / l urea and 150 g / l low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet printhead with an aqueous ink containing the following ingredients: 8 % CI Reactive Black 1 4 10 % tetramethylene decane 8 2% water The print was completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, gray printing with excellent use fastness is obtained.齐齐知知曰慧时轰员 1. Consumption ^咋: ±1 in the middle of the example six, commercial cotton textile fabric chops to contain 35g / l anhydrous sodium carbonate, lOOg / 脲 urea and 150g / l low viscosity algae The sodium citrate solution (6%) was then dried. The wet harvest is 70%. The pretreated fabric thus obtained uses a drop-on-demand inkjet print head' with the following ingredients. The paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -15 - 1278553 A7 _B7______ V. Inventive Note (13) Water-based ink printing: 12% C.1. Reactive Orange 12 (Please read the back note first and then fill out this page) 8 % Tetramethyl brothel 80% Water print completely dry. It was fixed at 1 〇 2 °C for 8 minutes using saturated steam. Then, the printed matter was further subjected to warm rinsing and washing with hot water at 95 ° C, rinsing with heating, and then drying. As a result, golden yellow printing with excellent use fastness was obtained. Example 7 The woven base of the woven fabric of the alkalized viscose was dried with a liquid containing 35 g / 1 anhydrous sodium carbonate, 200 g / l urea and 150 g / l low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus prepared was printed using a drop-on-demand inkjet print head with an aqueous ink containing the following ingredients: 10% CI Reactive Orange 35 6 ° / 〇 tetramethylene olefin 8 4 % water When the Qilang wisdom is used, the smasher X. The printed matter in the consumer 阼fi is completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter is further subjected to warming and rinsing, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a maroon printing with excellent use fastness was obtained. Example Eight Paper Size Applicable to China National Standard (CNS) A4 Specification (210 X 297 mm) -16- 1278553 A7 B7 V. Invention Description (14) (Please read the note on the back and fill out this page) Commercial Cotton The woven fabric was dried with a liquid containing 35 g/l of anhydrous sodium carbonate '150 g/l urea and 150 g/l of low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with an aqueous ink containing the following ingredients: 12 ° / 〇 CI Reactive Red 218 10 % tetramethylene decane 7 8 ° /Water-repellent prints are completely dry. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. Example 9 Commercially available cotton woven fabrics were dried with a liquid containing 35 g/l of anhydrous sodium carbonate '150 g/l of urea and 150 g/l of low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained uses a drop-on-demand inkjet printhead to print with water-based inks containing the following components of the Ministry of Economic Affairs' Intellectual Property Office's consumer collaboration: 1 5 % CI Reactive Blue 49, . 10 % tetramethylene alkane 7 5 % water

印刷物經完全乾燥。在於1 〇2 °C下’利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗’用熱水在95 °C -17- 本紙張尺度適用中國國家標準(cns)a4規格(210 x 297公爱) 1278553 A7 _______Β7___ 五、發明說明(15 ) 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之藍色印刷。 (請先閱讀背面之注意事項再填寫本頁) 實例十 商售棉花之紡織織物塡塞以含有3 5 g/Ι無水碳酸鈉’ l〇〇g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是7 0 % 。如此製得之預處理織物使用 drop-on-demand (泡沫噴射)噴墨印刷頭’用包含以下成分 之水性墨水印刷: 1 〇 % C.I. Reactive Black 39 10 °/〇 四亞甲基硕烷 8 0 °/〇 水 印刷物經完全乾燥。在於1 02 °C下’利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗’用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之海軍藍色印刷。 實例·The print was completely dried. It was fixed at 1 〇 2 °C for 8 minutes using saturated steam. Then, the printed matter is then tempered by heating. 'With hot water at 95 °C -17- This paper scale applies Chinese national standard (cns) a4 specification (210 x 297 public) 1278553 A7 _______Β7___ V. Invention description (15) Fast wash treatment, warm rinse, then dry. As a result, a blue print having excellent use fastness was obtained. (Please read the notes on the back and then fill out this page.) Example 10 Commercially available cotton textile fabrics with 3 5 g / Ι anhydrous sodium carbonate ' l〇〇g / l urea and 150 g / l low viscosity alginic acid The sodium solution (6%) of the liquid is then dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with an aqueous ink containing the following ingredients: 1 〇% CI Reactive Black 39 10 °/〇tetramethylene sulane 8 0 The °/hydrophobic print is completely dried. It was fixed at 1 02 °C for 8 minutes using saturated steam. Then, the printed matter was further subjected to warm rinsing and washing with hot water at 95 ° C, rinsing with heating, and then drying. As a result, a navy blue print with excellent use fastness is obtained. Example·

經濟部智慧財產局員工消費合泎社印W 商售棉花之紡織織物塡塞以含有40g/l無水碳酸鈉’ 100g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是7 0 % 。如此製得之預處理織物使用 drop-on-demand (泡沫噴射)噴墨印刷頭’用包含以下成分 之水性墨水印刷: 1 5 % C.I. Reactive Black 5 -1ft - 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 1278553 A7 B7 五、發明說明(16) 20 % 四亞甲基砸烷 6 5 °/〇 水 (請先閱讀背面之注意事項再填寫本頁) 印刷物經完全乾燥。在於1 〇2 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之海軍藍色印刷。 實例十二 商售棉花之紡織織物塡塞以含有40g/l無水碳酸鈉, 100g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 d r ο ρ - ο η - d e m a n d (泡沫噴射)噴墨印刷頭,用包含以下成分 之水性墨水印刷: 6 % C.I. Reactive Blue 21 5 % C.I. Reactive Yellow 37 15 °/〇 四亞甲基硕烷 74 % 水 陘齊郎智慧时產苟員二消費合阼社印製 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之綠色印刷。 實例十三 商售棉花之紡織織物塡塞以含有35g/l無水碳酸鈉, 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -1P - 1278553 A7 _ B7______ 五、發明說明(17 ) 50g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 (請先閱讀背面之注意事項再填寫本頁) drop-on-demand (泡沫噴射)噴墨印刷頭,用包含以下成分 之水性墨水印刷: 8 % C.I. Reactive Black 8 10 °/〇 四亞甲基砸烷 8 2 % 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之灰色印刷。 實例十四 商售棉花之紡織織物塡塞以含有35g/Ι無水碳酸鈉, 100g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (泡沬噴射)噴墨印刷頭,用包含以下成分 之水性墨水印刷: 經濟郎智慧財產局員工消費合阼fi印製 15.0% C.I. Reactive Black 5 8 % C.I. Reactive Orange 1,0 7 0.2% C.I. Reactive Red 180 20.0 % 四亞甲基砸烷 64% 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -20- 1278553 A7 _____Β7___ 五、發明說明(18 ) 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 t 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 (請先閱讀背面之注意事項再填寫本頁) 結果獲得具有優異使用堅牢性之黑色印刷。 實例十五 經鹼化黏膠絲之紡織織物塡塞以含有35g/Ι無水碳酸鈉 ,150g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後 加以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使 用drop-on-demand (泡沫噴射)噴墨印刷頭,用包含以下 成分之水性墨水印刷: 1 5 % C.I. Reactive Blue 2 1 10 % 四亞甲基硕烷 10% N-甲基-2-吡咯烷酮 65% 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之藍綠色印刷。 經濟部智慧財產局員工消費合作社印製 實例十六 、 經鹼化黏膠絲之紡織織物塡塞以含有35g/l無水碳酸鈉 ,100g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後 加以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使 用drop-on-demand (泡沫噴射)噴墨印刷頭’用包含以下 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -21 - 1278553 A7 _B7_ 五、發明說明(19 ) 成分之水性墨水印刷: (請先閱讀背面之注意事項再填寫本頁) 8 % C.I. Reactive Black 14 8 % 四亞甲基砸烷 12 % N-甲基-2-吡咯烷酮 72 % 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之灰色印刷。 實例十七 商售棉花之紡織織物塡塞以含有30g/l無水碳酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (泡沫噴射)噴墨印刷頭,用包含以下成分 之水性墨水印刷: 經濟部智慧財產局員工消費合作社印製 6 % C.I. Reactive Blue 21 5 % C.I. Reactive Yellow 37 5 °/〇 四亞甲基硕烷 15 % N-甲基-2-吡咯烷酮、 69% 水 έρ刷物經完全乾燥。在於1 02 t下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 1278553 A7 __B7_ 五、發明說明(2〇 ) 結果獲得具有優異使用堅牢性之綠色印刷。 (請先閱讀背面之注意事項再填寫本頁) 實例十八 商售棉花之紡織織物塡塞以含有35g/Ι無水碳酸鈉, 100g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 1 2 % C.I. Reactive Yellow 95 10 °/〇 四亞甲基硕烷 1 0 % 丁基二甘醇 6 8 °/〇 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗’用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之鮮黃色印刷。 實例十九 瘦齊卽扣曰慧时轰苟員31肖費όνα咋pi中製 商售棉花之紡織織物塡塞以含有35g/l無水碳酸鈉, 150g/l脲和150g/l低黏度藻朊酸、鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 1 2 % C.I. Reactive Orange 1 3 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -23- 1278553 A7 _B7_______ 五、發明說明(21 ) 10 °/〇 四亞甲基砸烷 (請先閱讀背面之注咅心事項再填寫本頁) 1 0 % 丁基二甘醇 6 8 % 水 印刷物經完全乾燥。在於1 02 t下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之橙色印刷。 實例二十 經鹼化黏膠絲之紡織織物塡塞以含有35g/l無水碳酸鈉 ,200g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後 加以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使 用drop-on-demand (壓力)噴墨印刷頭,用包含以下成分 之水性墨水印刷: 1 0 % C.I. Reactive Red 1 87 15 °/〇 四亞甲基硕烷 10 % 丁基二甘醇 65% 水 澄齊印皆慧讨轰笱員1.肖費^阼^^-& 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經、加溫漂洗,用熱水在95 t 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例二十一 本紙張尺度適用中國國家標準(CNS)A4規格(2〗0 X 297公釐) -24- 1278553 A7 _B7___ 五、發明說明(22 ) (請先閱讀背面之注意事項再填寫本頁) 經鹼化黏膠絲之紡織織物塡塞以含有35g/l無水碳酸鈉 ,200g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後 加以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使 用drop-on-demand (壓力)噴墨印刷頭’用包含以下成分 之水性墨水印刷: 1 2 % C.I. Reactive Blue 21 10 % 四亞甲基硕烷 8 % 丁基二甘醇 70 % 水 印刷物經完全乾燥。在於1 02 t下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之藍綠色印刷。 實例二十二 商售棉花之紡織織物塡塞以含有35g/l無水碳酸鈉, 50g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 經齊郎智慧財產局員X消費合作杜印製 drop-on-demand (壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 、 8 °/〇 C.I. Reactive Black 14 1 0 % 四亞甲基砸烷 5 % 丁基二甘醇 77 % 水 本紙張尺度適用中國國家標準(CNS)A4規格(2】0 X 297公釐) -25- 1278553 A7 ____B7___ 五、發明說明(23 ) (請先閱讀背面之注意事項再填寫本頁) 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之灰色印刷。 實例二十三 商售棉花之紡織織物塡塞以含有35g/l無水碳酸鈉’ 100g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 1 2 % C.I. Reactive Orange 12 8 % 四亞甲基硕烷 10 % 丁基二甘醇 70 % 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在9 5 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之金黃色印刷。 實例二十四 經鹼化黏膠絲之紡織織物塡塞以含有35g/l無水碳酸鈉 ,200g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後 加以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -26- 1278553 A7 B7 五、發明說明(24) 用drop-on-demand (壓力)噴墨印刷頭’用包含以下成分 之水性墨水印刷: (請先閱讀背面之注意事項再填寫本頁) 1 〇 % C.I. Reactive Orange 35 9 % 四亞甲基砸烷 5 % 丁基二甘醇 7 6 % 水 印刷物經完全乾燥。在於1 02 t下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之褐黃色印刷。 實例二十五 商售棉花之紡織織物塡塞以含有35g/l無水碳酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 1 2 % C.I. Reactive Red 2 1 8 經濟部智慧財產局員工消費合作社印製 5 % 四亞甲基碾烷 15 % 丁基二甘醇 、 6 8 % 水 ' 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -27- 1278553 A7 ____B7_ 五、發明說明(25 ) 結果獲得具有優異使用堅牢性之紅色印刷。 (請先閱讀背面之注意事項再填寫本頁) 實例二十六 商售棉花之紡織織物塡塞以含有35g/l無水碳酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-〇n-demand (壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 1 5 % C.I. Reactive Blue 49 1 0 % 四亞甲基硕烷 7 % 丁基二甘醇 6 8 °/〇 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之藍色印刷。 實例二十七 經濟部智慧財產局員工消費合阼Fi印製 商售棉花之紡織織物塡塞以含有35g/l無水碳酸鈉, 100g/l脲和150g/l低黏度藻朊酸、_溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (壓力)噴墨印刷頭’用包含以下成分之水 性墨水印刷: 1 0 % C.I. Reactive Black 39 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐〉 -28- 1278553 A7 B7 五、發明說明(26 ) 1 0 % 四亞甲基砸院 5 % 丁基二甘醇 7 5 % 水 印刷物經完全乾燥。在於102 t下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之海軍藍色印刷。 實例二十八 商售棉花之紡織織物塡塞以含有40g/l無水碳酸鈉, 100g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷= 1 5 % C.I. Reactive Black 5 20 % 四亞甲基硕烷 4 % 丁基二甘醇 6 1 % 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經、加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 ' ί吉果獲得具有優異使用堅牢性之海軍藍色印刷。 實例二十九 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) --*---,--------裝--- (請先閱讀背面之注意事項再填寫本頁) 訂-· •線丨· 經濟部智慧財產局員工消費合作社印製 -29- 1278553 A7 __ B7___ 五、發明說明(27 ) -ϋ ϋ» i n i ϋ ϋ n ϋ · i n (請先閱讀背面之注意事項再填寫本頁) 商售棉花之紡織織物塡塞以含有40g/l無水碳酸鈉’ 100g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 6 % C.I. Reactive Blue 21 5 % C.I. Reactive Yellow 37 15 °/〇 四亞甲基硕烷 5 % 丁基二甘醇 69% 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之綠色印刷。 實例三十 商售棉花之紡織織物塡塞以含有35g/Ι無水碳酸鈉, 經濟部智慧財產局員工消費合作钍印製 5 0g/l脲和1 50g/l低黏度藻阮酸鈉溶液(6 % )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (壓力)噴墨印厕頭,用包含以下成分之水 性墨水印刷: 8 % C.I. Reactive Black 8 1 0 % 四亞甲基碩烷 4 % 丁基二甘醇 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -30- 1278553 A7 B7 五、發明說明(28 ) 7 8 °/〇 水 -I J I I |\| I I I I I * I I (請先閱讀背面之注意事項再填寫本頁) 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗’用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之灰色印刷。 實例三十一 商售棉花之紡織織物塡塞以含有35g/l無水碳酸鈉’ 200g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: # 1 5 % C.I. Reactive Black 5 0.8% C.I. Reactive Orange 107 0.2 % C.I. Reactive Red 180 20 % 四亞甲基碼烷 5 °/。丁基二甘醇 5 9 °/〇 水 經濟部智慧財產局員工消費合作社印製 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經、加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之黑色印刷。 實例三十二 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -31 - 1278553 A7 B7___ 五、發明說明(29 ) (請先閱讀背面之注意事項再填寫本頁) 商售棉花之紡織織物塡塞以含有35g/Ι無水碳酸氫鈉, 200g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 8 % C.I. Reactive Orange 1 3 10 °/〇 四亞甲基砸烷 4 °/〇 N-甲基-2-吡咯烷酮 0.5 % 經改良磷酸鹽 77.5 % 水 印刷物經完全乾燥。在於1 02 t下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之橙色印刷。 實例三十三 經濟部智慧財產局員工消費合作社印製 經鹼化黏膠絲之紡織織物塡塞以含有35g/Ι無水碳酸氫 鈉,150g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體 後加以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物 使用drop-on-demand (壓力)噴、墨印刷頭,用包含以下成 分之水性墨水印刷= 1 0 % C . I. Reactive Red 218 5 °/〇 四亞甲基碾烷 15 % N-甲基-2-吡咯烷酮 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) - 32- 1278553 A7 _______B7____ 五、發明說明(30 ) 0.5%經改良磷酸鹽 69.5% 水 (請先閱讀背面之注意事項再填寫本頁) 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後’此印刷物再經加溫漂洗’用熱水在95 °c 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例三十四 經鹼化黏膠絲之紡織織物塡塞以含有35g/l無水碳酸氫 鈉,200g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體 後加以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物 使用drop-on-demand (壓力)噴墨印刷頭’用包含以下成 分之水性墨水印刷: 8 % C.I. Reactive Blue 49 15% 四亞甲基硕院 5 % N-甲基-2-吡咯烷酮 5 %經改良磷酸鹽 71.5% 水 經濟邹智慧財產局員工消費合阼:ώ印製 印刷物經完全乾燥。在於1 02 °c下’利用飽和蒸氣固 定8分鐘。然後,此印刷物再經、加溫漂洗’用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之藍色印刷。 實例三十五 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 1278553 A7 B7 五、發明說明(31 ) (請先閱讀背面之注意事項再填寫本頁) 商售棉花之紡織織物塡塞以含有30g/l無水碳酸鈉, 100g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 1 〇 % C.I. Reactive Red 1 80 15 °/〇 四亞甲基硕烷 4 °/〇 N-甲基-2-吡咯烷酮 0.5 %經改良磷酸鹽 7 0.5 % 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再經加溫漂洗,用熱水在95 °C 下堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例三十六 痤齊郎智慧財4¾員工消費合作社印製 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉,150gH脲 和1 50g/l高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用drop- on-demand (泡沬噴射) 噴墨印 刷頭, 用包含以下成分之水 性墨水印刷: 8 % C.I. Reactive Yellow 37 20 % 四亞甲基硕烷 7 2 °/〇 水 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) _ ^/1 _ 1278553 A7 __B7___ 五、發明說明(32 ) (請先閱讀背面之注意事項再填寫本頁) 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於1-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢性之黃色印刷。 實例三十七 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉,100g/l脲 和1 50g/l高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用drop- on-demand (泡沬噴射)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 1 2 % C.I. Reactive Yellow 42 15 % 四亞甲基砸烷 7 3 °/〇 水 經濟部智慧財產局員工消費合作杜印製 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l_2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理’加溫漂洗’然 後加以乾燥。 結果獲得具有優異使用堅牢性之黃色印刷。 實例兰十八 脫膠絲之紡織織物塡塞以含有5〇g/l乙酸鈉’ l〇〇g/l脲 和150g/l高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -35- 1278553 A7 ______ B7__ 五、發明說明(33 ) 。潮濕收獲物是70 % 。如此製得之預處理織物使用drop- (請先閱讀背面之注意事項再填寫本頁) on-demand (泡沫噴射) 噴墨印 刷頭’ 用包含以下成分之水 性墨水印刷: 1 4 % C.I. Reactive Orange 107 2 1 5四亞甲基硕烷 71 % 水 印刷物經完全乾燥。在於1 〇2 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理’加溫漂洗’然 後加以乾燥。 結果獲得具有優異使用堅牢性之金黃色印刷。 實例三十九 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉,100g/l脲 和150g/l高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用drop- on-demand (泡沬噴射) 噴墨印 刷頭, 用包含以下成分之水 性墨水印刷: 逐齊印皆慧讨ini?, U乍i .Ρ-ΞΓ1Χ 9 % C.I. Reactive Orange 74 15 °/〇 四亞甲基硕烷 、 776 % 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗’然 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -36- 1278553 A7 __B7_ 五、發明說明(34 ) 後加以乾燥。 結果獲得具有優異使用堅牢性之橙色印刷。 (請先閱讀背面之注意事項再填寫本頁) 實例四十 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉’ 100g/l脲 和1 50g/l高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用drop- on-demand (泡沬噴射)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 8 % C.I. Reactive Orange 16 14 % 四亞甲基硕烷 7 8 °/〇 水 印刷物經完全乾燥。在於1 〇 2 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢性之橙色印刷。 經濟部智慧財產局員工消費合作社印製 實例四十一 脫膠絲之紡織織物塡塞以贪.有50g/l乙酸鈉,100g/l脲 和1 50gM高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮-收獲物是70 % 。如此製得之預處理織物使用drop- on-demand (壓力 ) 噴墨 印刷頭 ,用包 含以下 成分之 水性墨 水印刷: 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -37- 1278553 A7 B7 五、發明說明(35) 1 4 % C.I. Reactive Red 1 80 16 °/〇 四亞甲基硕烷 3 % 丁基二甘醇 (請先閱讀背面之注意事項再填寫本頁) 2 % 經改良甘露半乳聚糖 66.8¾ 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例四十二 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉,l〇〇g/l脲 和1 50g/l高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用drop- on-demand (壓力 ) 噴墨 印刷頭 ,用包含以下成分之水性墨 水印刷: 經齊郎智慧时產笱員1-¾費όνη乍fi-中裂 9 % C.I. Reactive Red 239 16 % 四亞甲基碾烷 5 % 丁基二甘醇 、 0.2 % 經改良甘露半乳聚糖 0.5 %硼烷 69.3 % 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 本纸張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -38 - 1278553 A7 __ B7 ___ 五、發明說明(36 ) (請先閱讀背面之注意事項再填寫本頁) 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例四十三 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉,100g/l脲 和1 50g/l高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用drop- on-demand (壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 10 % C.I. Reactive Red 198 12% 四亞甲基砸院 6 % 丁基二甘醇 0.5 %經改良磷酸鹽 7 1.5% 水 瘦齊郎智慧財轰笱員!-肖費乂α乍Fi^-沒 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 、 結果獲得具有優異使用堅牢性之紅色印刷。 實例四十四 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉’ l〇〇g/l脲 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -39- 經濟部智慧財產局員工消費合作社印製 1278553 A7 ________B7_五、發明說明(37 ) 和1 5Og/Ι高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用drop- on - d e m a n d (泡沬 噴射) 噴墨印 刷頭, 用包含 以下成 分之水 性墨水印刷: 8 % C.I. Reactive Red 35 13 % 四亞甲基硕烷 3 °/◦丁基二甘醇 0.3 %檸檬酸鈉 7 5.7% 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例四十五 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉,100g/l脲 和1 50g/l高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用drop- on-demand (壓力 ) 噴墨印 刷頭、,用包 含以下 成分之 水性墨 水印刷: 10 % C.I. Reactive Blue 19 16 % 四亞甲基硕烷 3 °/〇 Ί 一基二 :甘醇 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁) 裝 -l·, -40- 1278553 A7 _B7____ 五、發明說明(38 ) 0.5 %經改良磷酸鹽 70.5% 水 (請先閱讀背面之注意事項再填寫本頁) 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗’然 後加以乾燥。 結果獲得具有優異使用堅牢性之藍色印刷。 實例四十六 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉,l〇〇g/l脲 和150g/l高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用心〇?- on-demand (壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 10 °/〇 C.I. Reactive Blue 21 5 % 四亞甲基碼烷 15 % N-甲基-2-吡咯烷酮 7 0 °/〇 水 經濟邹智慧財產咼員工消費合阼fi印製 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再玲l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢性之藍綠色印刷。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -41 - 1278553 A7 ____B7 _ 五、發明說明(39 ) 實例四十七 (請先閱讀背面之注意事項再填寫本頁) 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉,100g/l脲 和1 50g/l高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用drop- on-demand (壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 1 2 % C.I. Reactive Blue 229 Ί % 四亞甲基硕烷 12 % Ν-甲基-2-吡咯烷酮 69% 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢性之藍綠色印刷。 實例四十八 經濟部智慧財產局員工消費合作杜印製 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉,100g/l脲 和1 5Og/Ι高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用drop- on-demand (壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 1 0 % C.I. Reactive Black 14 10 °/〇 四亞甲基碾烷 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -42 - 1278553 A7 __B7__ 五、發明說明(4〇 ) 10 % N·甲基-2-吡咯烷酮 7 2 °/〇 水 (請先閱讀背面之注意事項再填寫本頁) 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗’然 後加以乾燥。 結果獲得具有優異使用堅牢性之灰色印刷。 實例四十九 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉,100g/l脲 和1 50g/l高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用drop- on-demand (壓力 ) 噴墨 印刷頭 ,用包 含以下 成分之 水性墨 水印刷: 5 % C.I. Reactive Black 3 1 8 % 四亞甲基硕烷 12 % N-甲基-2-吡咯烷酮 7 5 °/〇 水 經濟部智慧財產局員工消費合作社印製 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再玲l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢性之灰色印刷。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -43- 1278553 A7 ____B7 _ 五、發明說明(41 ) 實例五十 (請先閱讀背面之注意事項再填寫本頁) 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉,100g/l脲 和1 50g/l高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用drop- on-demand (壓力 ) 噴墨 印刷頭 ,用包 含以下 成分之 水性墨 水印刷: 1 5 % C.I. Reactive Black 5 10 % 四亞甲基砸烷 12 % N-甲基-2-吡咯烷酮 63 % 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定2 0分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70_80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢性之海軍藍色印刷。 實例五十一 經濟部智慧財產局員工消費合作社印製 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉,l〇〇g/l脲 和1 50g/l高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用連續流 動(壓力)噴墨印刷頭,用包含以下成分之水性墨水印刷_ 1 0 % C.I. Reactive Yellow 37 1 5 % 四亞甲基硕院 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -44- 1278553 A7 B7 五、發明說明(42 ) 7 % 聚醚多元醇 6 8 % 水 (請先閱讀背面之注意事項再填寫本頁) 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢性之黃色印刷。 實例五十二 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉,100g/l脲 和1 50g/l高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用連續流 動(壓力)噴墨印刷頭,用包含以下成分之水性墨水印刷 10.5% C.I. Reactive Red 180 15 % 四亞甲基硕烷 8 % 聚醚多元醇 66.5 % 水 經濟邹智慧財產局員工消費合阼;ώ印製 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 t下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -45- 1278553 A7 B7 五、發明說明(43) 實例五十三 (請先閱讀背面之注意事項再填寫本頁) 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉,100g/l脲 和150g/l高度醚化甘露半乳聚糖(5% )的液體後加以乾燥 。潮濕收獲物是7 0 % 。如此製得之預處理織物使用連續流 動(壓力)噴墨印刷頭,用包含以下成分之水性墨水印刷 1 2 % C.I. Reactive Blue 21 18 % 四亞甲基硕烷 7 °/〇 聚醚多元醇 63 % 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25%氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗’然 後加以乾燥。 結果獲得具有優異使用堅牢性之藍綠色印刷。 實例五十四 經齊邨智慧时產局員x-消費合阼达中綠 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉,l〇〇g/l脲 和1 50g/l高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用連續流 動(壓力)噴墨印刷頭,用包含以下成分之水性墨水印刷 8 % C . I. Reactive Black 14 15 % 四亞甲基碾烷 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -46- 1278553 A7 ___B7____ 五、發明說明(44 ) 5 °/〇 聚醚多元醇 72 % 水 (請先閱讀背面之注意事項再填寫本頁) 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在7 0 - 8 0 °C下堅牢性洗滌處理’加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢性之灰色印刷。 實例五十五 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉,l〇〇g/l脲 和150g/l高度醚化甘露半乳聚糖(5% )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用連續流 動(壓力)噴墨印刷頭,用包含以下成分之水性墨水印刷 1 1 % C.I. Reactive Red 1 80 • 15 % 四亞甲基硕烷 4 % 聚乙烯基己內醯胺 7 0 % 水 經濟部智慧財產局員工消費合作杜印製 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再玲l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-8(TC下堅牢性洗滌處理,加溫漂洗’然 後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -47- 1278553 A7 一 —___B7 __ 五、發明說明(45 ) 實例五十六 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉’ 100g/l脲 (請先閱讀背面之注意事項再填寫本頁) 和1 50g/l高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 ^潮濕收獲物是7 0 % 。如此製得之預處理織物使用連續流 動(壓力)噴墨印刷頭,用包含以下成分之水性墨水印刷 1 0 % C.I. Reactive Blue 21 15 °/〇 四亞甲基硕烷 3 °/〇 1,2-己二醇 5 °/〇 聚乙烯基己內醯胺 67 °/〇 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗’然 後加以乾燥。 結果獲得具有優異使用堅牢性之藍綠色印刷。 實例五十七 經齊郎fel曰慧时轰笱員二肖費& 口阼Fi中製 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉,l〇〇g/l脲 和1 50g/l高度醚化甘露半乳聚糖、(5 % )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用連續流 動(壓力)噴墨印刷頭,用包含以下成分之水性墨水印刷 8 % C.I. Reactive Black 1 4 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -48- 1278553 A7 ____B7_ 五、發明說明(46 ) 1 5 % 四亞甲基碾院 (請先閱讀背面之注意事項再填寫本頁) 5 % 聚醚多元醇 3 % 1,2 -己二醇 69% 水 印刷物經完全乾燥。在於1 〇 2 c下’利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理’加溫漂洗’然 後加以乾燥。 結果獲得具有優異使用堅牢性之灰色印刷。 實例五十八 脫膠絲之紡織織物塡塞以含有50g/l乙酸鈉,100g/l脲 和1 50g/l高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮濕收獲物是7 0 % 。如此製得之預處理織物使用連續流 動(壓力)噴墨印刷頭,用包含以下成分之水性墨水印刷 經濟部智慧財產局員工消費合作社印製 1 2 % C.I. Reactive Blue 2 1 18 °/〇 四亞甲基硕烷 7 % 聚醚多元醇 3 % 1,2-己二醇 、 60 % 水 却刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗’然 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -49- 1278553 A7 B7 五、發明說明(47 ) 後加以乾燥。 結果獲得具有優異使用堅牢性之藍綠色印刷。 (請先閱讀背面之注意事項再填寫本頁) 實例五十九 脫膠絲之紡織織物塡塞以含有5〇g/l乙酸鈉,100g/l脲 和1 5Og/Ι高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用連續流 動(壓力)噴墨印刷頭,用包含以下成分之水性墨水印刷 10.5C.I. Reactive Red 180 15 % 四亞甲基硕烷 8 % 聚醚多元醇 6 % 聚丙二醇 60.5 °/〇 水 印刷物經完全乾燥◦在於1 02 °C下,利用飽和蒸氣固 定2 0分鐘。然後,此印刷物再於i_2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例六十 ίΐ兌膠絲之紡織織物塡塞以含有50g/l乙酸鈉,100g/l脲 和1 50g/l高度醚化甘露半乳聚糖(5 % )的液體後加以乾燥 。潮濕收獲物是70 % 。如此製得之預處理織物使用連續流 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -50- 1278553 A7 B7 五、發明說明(48 ) 動(壓力)噴墨印刷頭’用包含以下成分之水性墨水印刷 (請先閱讀背面之注意事項再填寫本頁) 1 0 % C.I. Reactive Yellow 37 15 °/〇 四亞甲基砸烷 7 % 聚醚多元醇 4 % 聚丙二醇 0.3% 檸檬酸鈉 63.7 % 水 印刷物經完全乾燥。在於1 〇 2 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l_2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理’加溫漂洗’然 後加以乾燥。 結果獲得具有優異使用堅牢性之黃色印刷。 實例六Η— 經氯化羊毛之紡織織物塡塞以含有50gn乙酸鈉’ 暖齊郎智慧时產苟員11消費^阼^印製 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (泡沫噴射)噴墨印刷頭’用包含以下成分 之水性墨水印刷: 、 8 % C.I. Reactive Yellow 37 20% 四亞甲基碾烷 7 2 °/〇 水 印刷物經完全乾燥。在於1 〇2 °C下’利用飽和蒸氣固 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 1278553 A7 B7___ 五、發明說明(49 ) 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 (請先閱讀背面之注意事項再填寫本頁) 結果獲得具有優異使用堅牢性之黃色印刷。 實例六十二 經氯化羊毛之紡織織物塡塞以含有50g/l乙酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (泡沫噴射)噴墨印刷頭,用包含以下成分 之水性墨水印刷: 1 2 % C.I. Reactive Yellow 42 15 % 四亞甲基硕烷 7 3 % 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理’加溫漂洗,然 後加以乾燥。 經濟部智慧財產局員工消費合作社印製 結果獲得具有優異使用堅牢性之黃色印刷。 實例六十三 氯化羊毛之紡織織物塡塞以含有SOW1乙酸鈉’ 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -52- 1278553 A7 B7 五、發明說明(50) drop-on-demand (泡沬噴射)噴墨印刷頭’用包含以下成分 之水性墨水印刷: (請先閱讀背面之注意事項再填寫本頁) 1 4 % C.I. Reactive Orange 107 15 % 四亞甲基砸烷 71 °/〇 水 印刷物經完全乾燥。在於1 〇2 °C下’利用飽和蒸氣固 定20分鐘。然後,此印刷物再於I-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理’加溫漂洗’然 後加以乾燥。 結果獲得具有優異使用堅牢性之金黃色印刷。 實例六十四 經氯化羊毛之紡織織物塡塞以含有50g/l乙酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (泡沫噴射)噴墨印刷頭,用包含以下成分 之水性墨水印刷: 經濟部智慧財產局員工消費合作杜印製 9 % C.I. Reactive Orange 74 15 % 四亞甲基硕烷 7 6 % 水 、 印刷物經完全乾燥。在於1 〇 2 °C下,利用飽和蒸氣固 定20’分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -53- 1278553 A7 B7 五、發明說明(51 ) 結果獲得具有優異使用堅牢性之橙色印刷。 實例六十五 經氯化羊毛之紡織織物塡塞以含有50g/l乙酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (泡沫噴射)噴墨印刷頭,用包含以下成分 之水性墨水印刷: 8 % C.I. Reactive Orange 16 16% 四亞甲基硕院 78 % 水 印刷物經完全乾燥。在於1 02 °C下’利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25%氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理’加溫漂洗’然 後加以乾燥。 結果獲得具有優異使用堅牢性之橙色印刷。 實例六十六 齊 皆 i 讨 ί % 經氯化羊毛之紡織織物塡塞以含有502/1乙酸鈉’ 150g/l脲和150g/l低黏度藻朊酸雜溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 1 0 % C.I. Reactive Blue 19 -54 - (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 1278553 A7 ___B7_ 五、發明說明(52 ) 16% 四亞甲基硕垸 3 % 丁基二丁醇 (請先閱讀背面之注意事項再填寫本頁) 0.5%經改良磷酸鹽 7 0.5% 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理’加溫漂洗’然 後加以乾燥。 結果獲得具有優異使用堅牢性之藍色印刷。 實例六十七 經氯化羊毛之紡織織物塡塞以含有50g/l乙酸鈉’ 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 8 % C.I. Reactive Red 35 13 % 四亞甲基砸烷 ;3 % 丁基二甘醇 0.3%檸檬酸鈉 、 7 5.7% 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -55 - 1278553 A7 B7 五、發明說明(53 ) 後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例六十八 經氯化羊毛之紡織織物塡塞以含有50g/l乙酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 1 0 % C.I. Reactive Red 1 98 12 °/〇 四亞甲基砚烷 6% 丁基二甘醇 0.5 %經改良磷酸鹽 71.5% 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-8(TC下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例六十九 ί至氯化羊毛之紡織織物塡塞以含有50g/l乙酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) ---?------------裝--- (請先閱讀背面之注意事項再填寫本頁) - ¼. 經濟部智慧財產局員X消費合作fi印製 -56- 1278553 A7 B7 五、發明說明(54 ) drop-on-demand (壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: (請先閱讀背面之注意事項再填寫本頁) 9 % C.I. Reactive Red 239 16 % 四亞甲基硕烷 5 % 丁基二丁醇 0.5 % 硼烷 69.5 °/〇 水 印刷物經完全乾燥。在於102 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於25%氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗’然 後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例七十 經氯化羊毛之紡織織物塡塞以含有50g/l乙酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 1 4 % C.I. Reactive Red 18Q. 16 % 四亞甲基硕烷 3 % 丁基二丁醇 67 °/〇 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -57- 1278553 A7 ___B7___ 五、發明說明(55 ) 定20分鐘。然後,此印刷物再於丨-21^1 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理’加溫漂洗’然 (請先閱讀背面之注意事項再填寫本頁) 後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例七十一 經氯化羊毛之紡織織物塡塞以含有5〇g/l乙酸鈉’ 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (壓力)噴墨印刷頭’用包含以下成分之水 性墨水印刷: 1 5 % C.I. Reactive Black 5 10 % 四亞甲基硕烷 12 % N-甲基-2-吡咯烷酮 6 3 % 水 經濟部智慧財產局員工消費合作杜印製 印刷物經完全乾燥。在於1 02 t下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗’然 後加以乾燥。 結果獲得具有優異使用堅牢.性之藍綠色印刷。 實例七十二 經氯化羊毛之紡織織物塡塞以含有50g/l乙酸鈉’ 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -58- 1278553 A7 _____B7___ 五、發明說明(56 ) 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 (請先閱讀背面之注意事項再填寫本頁) drop-on-demand (壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 5 % C.I. Reactive Black 3 1 8 % 四亞甲基砸烷 12 % N-甲基-2-吡咯烷酮 7 5 % 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗’然 後加以乾燥。 結果獲得具有優異使用堅牢性之灰色印刷。 實例七十三 經氯化羊毛之紡織織物塡塞以含有50g/l乙酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 經濟部智慧財產局員工消費合作社印製 drop-on-demand (壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 8 % C.I. Reactive Black 14.. 10 °/〇 四亞甲基硕烷 10 % N-甲基-2-吡咯烷酮 7 2 % 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -59- 1278553 A7 B7 五、發明說明(57 ) (請先閱讀背面之注意事項再填寫本頁) 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 , 結果獲得具有優異使用堅牢性之灰色印刷。 實例七十四 經氯化羊毛之紡織織物塡塞以含有50g/l乙酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-on-demand (壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 1 2 % C.I. Reactive Black 229 Ί % 四亞甲基硕烷 12% Ν-甲基-2-吡咯烷酮 69 % 水 經濟部智慧財產局員工消費合作社印製 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢、性之藍綠色印刷。 實例七十五 經氯化羊毛之紡織織物塡塞以含有50g/l乙酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -60- 1278553 A7 B7 五、發明說明(58) (請先閱讀背面之注意事項再填寫本頁) 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 drop-〇n-demand (壓力)噴墨印刷頭’用包含以下成分Z水 性墨水印刷: 1 0 % C.I. Reactive Blue 21 5 % 四亞甲基砸烷 15 % N-甲基-2-吡略烷酮 70 % 水 印刷物經完全乾燥。在於102 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理’加溫漂洗’然 後加以乾燥。 結果獲得具有優異使用堅牢性之藍綠色印刷。 實例七十六 經氯化羊毛之紡織織物塡塞以含有50g/l乙酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 連續流動(壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 8 % C.I. Reactive Black 14、 1 5 % 四亞甲基硕烷 5 % 聚醚多元醇 7 2 °/〇 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -61 - 1278553 A7 ____B7_ 五、發明說明(59 ) (請先閱讀背面之注意事項再填寫本頁) 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢性之灰色印刷。 實例七十七 經氯化羊毛之紡織織物塡塞以含有50g/l乙酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 連續流動(壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 1 2 % C.I. Reactive Blue 21 18 °/〇 四亞甲基砸烷 7 °/〇 聚醚多元醇 63 % 水 經濟邹智慧財產局員X.消費&口阼fi印製 印刷物經完全乾燥。在於1 〇 2 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅竿.性之藍綠色印刷。 實例七十八 經氯化羊毛之紡織織物塡塞以含有50g/l乙酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5 % )的液體後加 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -62- 1278553 A7 _B7___ 五、發明說明(6〇 ) 以乾燥。潮濕收獲物是70 % °如此製得之預處理織物使用 (請先閱讀背面之注意事項再填寫本頁) 連續流動(壓力)噴墨印刷頭’用包含以下成分之水性墨 水印刷: 10.5% C.I. Reactive Red 180 15 % 四亞甲基砸烷 8 °/〇 聚醚多元醇 66.5 % 水 印刷物經完全乾燥。在於1 02 °C下’利用飽和蒸氣固 定20分鐘。然後,此印刷物再於1 _2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理’加溫漂洗’然 後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例七十九 經氯化羊毛之紡織織物塡塞以含有50g/l乙酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 連續流動(壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 10 % C.I. Reactive Yellow 3 7 15 % 四亞甲基硕烷 7 °/〇 聚醚多元醇 6 8 °/〇 水 印刷物經完全乾燥。在於102 °C下,利用飽和蒸氣固 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -63- 1278553 A7 ___B7__ 五、發明說明(61 ) 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 T:下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 (請先閱讀背面之注意事項再填寫本頁) 結果獲得具有優異使用堅牢性之灰色印刷。 實例八十 經氯化羊毛之紡織織物塡塞以含有50g/l乙酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 連續流動(壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 1 0 % C.I. Reactive Blue 21 15 % 四亞甲基硕烷 3 % 1,2-己二醇 5 %聚乙烯基己內醯胺 67 % 水 經濟部智慧財產局員X.消費合阼:ώ印製 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於1 -2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗’然 後加以乾燥。 、 結果獲得具有優異使用堅牢性之藍綠色印刷° 實例八十一 經氯化羊毛之紡織織物塡塞以含有50g/l乙酸鈉’ 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -64 - 1278553 A7 B7 五、發明說明(62 ) (請先閱讀背面之注意事項再填寫本頁) 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 連續流動(壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 1 1 % C.I. Reactive Red 1 80 15 % 四亞甲基硕烷 4 °/〇 聚乙烯基己內醯胺 70% 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25%氨存在下加溫 漂洗,用熱水在70-80 t下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例八十二 經氯化羊毛之紡織織物塡塞以含有50g/l乙酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 連續流動(壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 、 1 0 % C.I. Reactive Yellow 37 15 % 四亞甲基硕烷 Ί % 聚醚多元醇 4 % 聚丙二醇 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -65- 1278553 A7 B7 五、發明說明(63 ) 6 3.7% 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢性之黃色印刷。 實例八十三 經氯化羊毛之紡織織物塡塞以含有5Og/Ι乙酸鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是7 0 % 。如此製得之預處理織物使用 連續流動(壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 10.5% C.I. Reactive Red 180 15 °/〇 四亞甲基硕烷 8 % 聚醚多元醇 6 % 聚丙二醇 60.5% 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再妗1 -2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) ----1 -----------裝--- (請先閱讀背面之注意事項再填寫本頁) 訂· -66 - 1278553 A7 _B7____ 五、發明說明(64 ) 實例八十四 經氯化羊毛之紡織織物塡塞以含有5〇g/1乙酸鈉’ 150g/l脲和150g/l低黏度藻朊酸鈉溶液(5% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 連續流動(壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 10.5% C.I. Reactive Red 180 15 % 四亞甲基硕烷 8 % 聚醚多元醇 6 °/〇 聚丙二醇 60.5 % 水 印刷物經完全乾燥。在於1 〇 2 °C下’利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理,加溫漂洗’然 後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例八十五 經氯化羊毛之紡織織物塡塞以含有5Og/Ι乙酸鈉, 15 0g/l脲和150g/l低黏度藻朊酸鈉溶液(5 % )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 連續兔動(壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 8 °/〇 C.I. Reactive Black 14 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -------.------_裝—— (請先閱讀背面之注意事項再填寫本頁) “ %· 經濟部智慧財產局員工消費合作杜印製 -67- 1278553 A7 ___B7__ 五、發明說明(65 ) 5 % 四亞甲基硕烷 5 % 聚醚多元醇 3 % 1,2 -己二醇 69% 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定20分鐘。然後,此印刷物再於l-2ml 25 %氨存在下加溫 漂洗,用熱水在70-80 °C下堅牢性洗滌處理’加溫漂洗,然 後加以乾燥。 結果獲得具有優異使用堅牢性之灰色印刷。 實例八十六 商售棉花之紡織織物塡塞以含有35g/無水碳酸氫鈉, 100g/l脲和1.50g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 連續流動(壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 1 2 % C.I. Reactive Yellow 95 10 % 四亞甲基碾烷 8 % 聚醚多元醇 70 % 水 、 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再加溫漂洗,用熱水在95 °C下 堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之鮮黃色印刷。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) ----I------------裝--- (請先閱讀背面之注意事項再填寫本頁) 訂· ¼. - 68- 1278553 A7 _____B7_ _ 五、發明說明(66 ) 實例八十七 (請先閱讀背面之注意事項再填寫本頁) 商售棉花之紡織織物塡塞以含有35g/l無水碳酸氫鈉, 150g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 連續流動(壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 9 % C .I. Reactive Orange 13 1 2 % 四亞甲基碩院 10 % 聚醚多元醇 69% 水 印刷物經完全乾燥。在於1 02 °C下,·利用飽和蒸氣固 定8分鐘。然後,此印刷物再加溫漂洗,用熱水在95 °C下 堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之橙色印刷。 實例八十八 經齊郎智慧时4局員工消費合阼;ώ印製 經鹼化黏膠絲之紡織織物塡塞以含有35g/l無水碳酸鈉 ,200g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後 加以乾燥。潮濕收獲物是70 % :如此製得之預處理織物使 用連續流動(壓力)噴墨印刷頭,用包含以下成分之水性 墨水έ卩刷: 1 〇 % C.I. Reactive Red 1 87 15 % 四亞甲基砸烷 -69- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 1278553 A7 ____B7__ 五、發明說明(67 ) Ί % 聚醚多元醇 6 8 °/〇 水 (請先閱讀背面之注意事項再填寫本頁) 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再加溫漂洗,用熱水在9 5 °C下 堅牢性洗滌處理,加溫漂洗’然後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例八十九 經鹼化黏膠絲之紡織織物塡塞以含有35g/Ι無水碳酸氫 鈉,200g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體 後加以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物 使用連續流動(壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 1 2 % C.I. Reactive Blue 2 1 15 °/〇 四亞甲基硕烷 5 °/〇 N-甲基-2-吡咯烷酮 17% 聚醚多元醇 61 % 水 經濟部智慧財產局員工消費合作社印製 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再加、,溫漂洗,用熱水在9 5 °C下 堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之藍綠色印刷。 實例九十 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 1278553 A7 ___B7____ 五、發明說明(68 ) (請先閱讀背面之注意事項再填寫本頁) 商售棉花之紡織織物塡塞以含有35g/l無水碳酸氫鈉, 50g/l脲和150g/l低黏度藻朊酸鈉溶液(6°/。)的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 連續流動(壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 8 % C.I. Reactive Black 14 1 0 % 四亞甲基硕院 5 % N-甲基-2-吡咯烷酮 5 % 聚醚多元醇 7 2 °/〇 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再加溫漂洗,用熱水在95 °C下 堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之灰色印刷。 實例九十一 經濟部智慧財產局員工消費合作社印制农 商售棉花之紡織織物塡塞以含有35 g/Ι無水碳酸氫鈉, 100g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後力口 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 連續流動(壓力)噴墨印刷頭,、用包含以下成分之水性墨 水印刷: 1 2 % C.I. Reactive Orange 12 20 % 四亞甲基碼烷 8 °/〇 聚醚多元醇 本紙張尺度適用中國國家標準(CNS)A4規格(2]0 X 297公釐) -71 - 1278553 A7 B7 五、發明說明(69) 60% 水 (請先閱讀背面之注意事項再填寫本頁) 印刷物經完全乾燥。在於1 〇2 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再加溫漂洗’用熱水在95 °C下 堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之金黃色印刷。 實例九十二 經鹼化黏膠絲之紡織織物塡塞以含有35g/l無水碳酸氫 鈉,200g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體 後加以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物 使用連續流動(壓力)噴墨印刷頭’用包含以下成分之水 性墨水印刷: 1 0 % C.I. Reactive Orange 35 16 °/〇 四亞甲基硕烷 6 % 聚乙烯基己內醯胺 0.3 % 硼烷 67.7 % 水 經齊郎智慧財產咼員x消費合阼fi印製 印刷物經完全乾燥。在於1 02 t下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再加溫漂洗,用熱水在95 °C下 堅牢性洗滌處理,加溫漂洗,然.後加以乾燥。 結果獲得具有優異使用堅牢性之褐橙色印刷。 實例九十三 商售棉花之紡織織物塡塞以含有35g/l無水碳酸氫鈉, 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -72- 1278553 A7 ____B7 五、發明說明(7〇 ) 150g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後力口 (請先閱讀背面之注意事項再填寫本頁) 以乾燥。潮濕收獲物是7 0 % 。如此製得之預處理織物使用 連續流動(壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 12 % C.I. Reactive Red 218 10 % 四亞甲基碾烷 10 % N-甲基-2-吡咯烷酮 5 °/〇 聚乙烯基吡咯烷酮 6 3 % 水 印刷物經完全乾燥。在於1 〇2 °C下’利用飽和蒸氣固 定8分鐘。然後,此印刷物再加溫漂洗’用熱水在9 5 °C下 堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例九十四 經濟部智慧財產局員工消費合作社印製 商售棉花之紡織織物塡塞以含有35g/l無水碳酸氫鈉, 150g/l脈和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 連續流動(壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 、 15% C.I. Reactive Blue 49 1 0 % 四亞甲基砸烷 5 % 聚醚多元醇 0.5 %硼烷 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -73- 1278553 A7 -----_ 五、發明說明(71 ) 69.5% 水 (請先閱讀背面之注意事項再填寫本頁) 印刷物經τα全乾燥。在於1 0 2 C下,利用飽和蒸氣固 定8分鐘。然後’此印刷物再加溫漂洗,用熱水在95 °C下 堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之藍色印刷。 實例九十五 商售棉花之紡織織物塡塞以含有35g/l無水碳酸氫鈉, l〇〇g/l脲和150g/l低黏度藻脫酸鈉溶液(6 % )的液體後加 以乾燥。潮濕收獲物是7 0 % 。如此製得之預處理織物使用 連續流動(壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 1 0 % C.I. Reactive Black 39 18 % 四亞甲基硕烷 6 % 聚醚多元醇 0.5 %磷酸鹽緩衝劑 65.5 % 水 經濟部智慧財產局員工消費合阼Fi印製 印刷物經完全乾燥。在於1 02 t下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再加溫漂洗,用熱水在95 °C下 堅牢性洗滌處理,加溫漂洗,然、後加以乾燥。 結果獲得具有優異使用堅牢性之海軍藍色印刷。 實例九十六 商售棉花之紡織織物塡塞以含有40g/l碳酸氫鈉, 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 1278553 A7 _____B7 五、發明說明(72 ) ---------------裝--- (請先閱讀背面之注意事項再填寫本頁) 100g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後力口 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 連續流動(壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 1 5 % C.I. Reactive Black 5 20 % 四亞甲基砸院 6 % 聚乙烯基己內醯胺 0.3 % 經改良磷酸鹽 5 8.7% 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再加溫漂洗,用熱水在95 °C下 堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之海軍藍色印刷。 實例九十七 商售棉花之紡織織物塡塞以含有40g/l碳酸氫鈉, 100g/l脲和150g/l·低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 經齊郎智慧財產咼員X.消費合阼fi-印製 連續流動(壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 、 6 % C.I. Reactive Blue 21 5 % C.I. Reactive Yellow 37 15 °/〇 四亞甲基硕烷 8 % 聚乙烯基吡略烷酮 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -75· 1278553 A7 __B7_ 五、發明說明(73 ) 0.5% 檸檬酸鈉 65.5 % 水 (請先閱讀背面之注意事項再填寫本頁) 印刷物經完全乾燥。在於102 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再加溫漂洗’用熱水在95 °C下 堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之綠色印刷。 實例九十八 商售棉花之紡織織物塡塞以含有35g/l無水碳酸鈉’ 50g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 連續流動(壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 8 % C .1. Reactive Black 1 2 10 % 四亞甲基硕烷 4 % 組合稠化劑 7 8 °/〇 水 經濟部智慧財產局員工消費合作杜印製 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再加溫漂洗,用熱水在95 °C下 堅牢性洗滌處理,加溫漂洗,然.後加以乾燥。 結果獲得具有優異使用堅牢性之灰色印刷。 實例九十九 商售棉花之紡織織物塡塞以含有35g/l無水碳酸鈉’ 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -76- 1278553 A7 B7 五、發明說明(74 ) 100g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後加 以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用 (請先閱讀背面之注意事項再填寫本頁) 連續流動(壓力)噴墨印刷頭,用包含以下成分之水性墨 水印刷: 1 5 % C.I. Reactive Black 5 0.8 % C.I. Reactive Orange 107 0.2 % C.I. Reactive Red 1 80 20 % 四亞甲基碾烷 5 °/〇 聚丙二醇 5 9% 水 印刷物經完全乾燥。在於1 02 °C下,利用飽和蒸氣固 定8分鐘。然後,此印刷物再加溫漂洗,用熱水在95 °C下 堅牢性洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之黑色印刷。 實例一〇〇 商售棉花之紡織織物塡塞以含有150g/l低黏度藻朊酸 鈉溶液(6 % )的液體後加以乾燥。潮濕收獲物是70 % 。 經濟部智慧財產局員工消費合作社印製 如此製得之預處理織物使用drop-on-demand (泡沫噴射) 噴墨印刷頭,用包含以下成分之.水性墨水印刷: 1 1 % C.I. Reactive Yellow 37 1 8 °/〇 四亞甲基硕烷 7 1 °/〇 水 印刷物經完全乾燥。根據已知技術,利用二相固定法 -77- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 1278553 A7 --- -B7_ 五、發明說明(75 ) (請先閱讀背面之注意事項再填寫本頁) 固定(閃蒸蒸熱20秒,125 °C ;短時間蒸熱90秒,125 °C ;冷批處理20 °C -40 °C,4-12小時)固定鹼:氫氧化鈉溶 液/砂酸鈉混合物Na2〇:Si〇2 1 : 1.7-3.3 )。此印刷物再 加溫漂洗,用熱水在95 t下堅牢性洗滌處理,加溫漂洗, 然後加以乾燥。 結果獲得具有優異使用堅牢性之黃色印刷。 實例一〇一 商售棉花之紡織織物使用d r ο ρ - ο η - d e m a n d (泡沬噴射 )噴墨印刷頭,用包含以下成分之水性墨水印刷: 1 0 % C.I. Reactive Red 1 80 15 % 四亞甲基.碩烷 3 % N-甲基-2-吡咯烷酮 72 % 水 印刷物經完全乾燥。根據已知技術,利用二相固定法 ‘固定(閃蒸蒸熱20秒,125 °C ;短時間蒸熱90秒,125 °C ;冷批處理20 °C -40 °C,4-12小時)固定鹼:氫氧化鈉溶 液/矽酸鈉混合物Na2〇:Si〇2 1 : 1.7-3.3 )。此印刷物再 經濟部智慧財產局員工消費合作杜印製 加溫漂洗,用熱水在95 °C下堅牢性洗滌處理,加溫漂洗’ 然後加以乾燥。 、 結果獲得具有優異使用堅牢性之紅色印刷。 實例一〇二 商售棉花之紡織織物使用drop-on-demand (泡沫噴射 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -78- 1278553 A7 ----- B7__ 五、發明說明(76 ) )噴墨印刷頭,用包含以下成分之水性墨水印刷: 1 2 % C.I. Reactive Blue 2 1 16% 四亞甲基硕院 (請先閱讀背面之注意事項再填寫本頁) 5 % 丁基二甘醇 67% 水 印刷物經完全乾燥。根據已知技術,利用二相固定法 固定(閃蒸蒸熱20秒,125 °C ;短時間蒸熱90秒,125 °C ;冷批處理20 °C -40 ΐ:,4-12小時)固定鹼:氫氧化鈉溶 液/矽酸鈉混合物Na2〇 : Si〇2 1 : 1.7-3.3 )。此印刷物再 加溫漂洗,用熱水在95 °C下堅牢性洗滌處理,加溫漂洗, 然後加以乾燥。 結果獲得具有優異使用堅牢性之藍綠色印刷。 實例一〇三 經鹼化黏膠絲之紡織織物塡塞以含有1 50g/l低黏度藻 朊酸鈉溶液(6 % )的液體後加以乾燥。潮濕收獲物是7〇 % 。如此製得之預處理織物使用drop-on-demand (壓力) 噴墨印刷頭,用包含以下成分之水性墨水印刷: 經濟部智慧財產局員工消費合作社印製 1 0 % C.I. Reactive Orange 1 3 15 °/〇 四亞甲基硕烷 、 0.3% 硼烷 7 4.7 °/〇 水Ministry of Economic Affairs, Intellectual Property Office, Employees, Consumers, Employees, Printing, Textiles, Cotton, Textiles, Cloths, Liquids containing 40g/l anhydrous sodium carbonate '100g/l urea and 150g/l low viscosity sodium alginate solution (6%) Then dry it. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand ink jet print head with an aqueous ink containing the following ingredients: 1 5 % C. I.  Reactive Black 5 -1ft - This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1278553 A7 B7 V. Description of invention (16) 20 % Tetramethyl decane 6 5 ° / 〇水 ( Please read the notes on the back and fill out this page.) The printed matter is completely dry. It was fixed at 1 〇 2 °C for 8 minutes with saturated steam. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a navy blue print with excellent use fastness is obtained. Example 12 Commercially available cotton woven fabrics were dried with a liquid containing 40 g/l of anhydrous sodium carbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a d r ο ρ - ο η - d e m a n d (foam jet) ink jet print head with an aqueous ink containing the following ingredients: 6 % C. I.  Reactive Blue 21 5 % C. I.  Reactive Yellow 37 15 ° / 〇 tetramethylene sulane 74 % water 陉 郎 智慧 智慧 时 时 苟 消费 消费 消费 消费 消费 消费 消费 消费 消费 印刷 印刷 印刷 印刷 印刷 印刷 印刷It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, green printing with excellent use fastness is obtained. Example 13 Commercial textile woven cotton fabric with 35g/l anhydrous sodium carbonate, this paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -1P - 1278553 A7 _ B7______ V. Description of invention (17) A liquid of 50 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) was dried. The wet harvest is 70%. The pretreated fabric thus obtained (please read the back note before filling out this page) drop-on-demand inkjet print head, printed with water-based ink containing the following ingredients: 8 % C. I.  Reactive Black 8 10 ° / 〇 tetramethylene decane 8 2 % water The print is completely dry. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, gray printing with excellent use fastness is obtained. Example 14 Commercially available cotton woven fabrics were smeared with a liquid containing 35 g/t anhydrous sodium carbonate, 100 g/l urea and 150 g/l low viscosity sodium alginate solution (6%), followed by drying. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet printhead and printed with an aqueous ink containing the following ingredients: Economic Lang Intellectual Property Bureau employee consumption combined with fi printing 15. 0% C. I.  Reactive Black 5 8 % C. I.  Reactive Orange 1,0 7 0. 2% C. I.  Reactive Red 180 20. 0 % tetramethylene decane 64% water The print was completely dried. At 1 02 °C, use the saturated steam solid paper scale to apply the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -20- 1278553 A7 _____Β7___ V. Invention description (18) for 8 minutes. Then, the printed matter was further tempered by heating, washed with hot water at 95 t, heated and rinsed, and then dried. (Please read the notes on the back and fill out this page.) The result is a black print with excellent fastness. Example 15 A woven fabric of alkalized viscose was smeared with a liquid containing 35 g/t anhydrous sodium carbonate, 150 g/l urea and 150 g/l low viscosity sodium alginate solution (6%) and dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with an aqueous ink containing the following ingredients: 1 5 % C. I.  Reactive Blue 2 1 10 % Tetramethylene alkane 10% N-methyl-2-pyrrolidone 65% Water The print was completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a blue-green printing having excellent use fastness was obtained. Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing example 16. Textile fabric woven with alkalized viscose silk containing 35g / l anhydrous sodium carbonate, 100g / l urea and 150g / l low viscosity sodium alginate solution ( 6%) of the liquid is then dried. The wet harvest is 70%. The pretreated fabric thus obtained uses a drop-on-demand inkjet printhead' with the following Chinese paper standard (CNS) A4 specification (210 X 297 mm) -21 - 1278553 A7 _B7_ V. INSTRUCTIONS (19) Water-based ink printing of ingredients: (Please read the notes on the back and fill out this page) 8 % C. I.  Reactive Black 14 8 % Tetramethyl decane 12 % N-methyl-2-pyrrolidone 72 % Water The print was completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, gray printing with excellent use fastness is obtained. Example 17 Commercially available cotton woven fabrics were smeared with a liquid containing 30 g/l of anhydrous sodium carbonate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%), followed by drying. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with an aqueous ink containing the following ingredients: Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperative, Printed 6 % C. I.  Reactive Blue 21 5 % C. I.  Reactive Yellow 37 5 ° / 〇 tetramethylene alkane 15 % N-methyl-2-pyrrolidone, 69% water έ brush is completely dried. At 10 2 t, it was fixed with saturated steam for 8 minutes. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm). 1278553 A7 __B7_ V. Description of invention (2〇) The result is a green print with excellent use fastness. (Please read the note on the back and then fill out this page.) Example 18 Commercially woven cotton fabric with 35g/Ι anhydrous sodium carbonate, 100g/l urea and 150g/l low viscosity sodium alginate solution (6 %) of the liquid is then dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with a water-based ink containing the following ingredients: 1 2 % C. I.  Reactive Yellow 95 10 ° / 〇 tetramethylene sulane 1 0 % butyl diglycol 6 8 ° / 〇 water The print was completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further subjected to warm rinsing and washing with hot water at 95 ° C, rinsing with heating, and then drying. As a result, a bright yellow printing having excellent use fastness was obtained. Example 19: Thin and thin 卽 曰 时 时 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 The acid, sodium solution (6%) of the liquid is then dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with a water-based ink containing the following ingredients: 1 2 % C. I.  Reactive Orange 1 3 This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) -23- 1278553 A7 _B7_______ V. Description of invention (21 ) 10 ° / 〇 tetramethylene decane (please read first On the back of the note, please fill out this page) 10% butyl diglycol 6 8 % Water print is completely dried. At 10 2 t, it was fixed with saturated steam for 8 minutes. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, an orange print having excellent use fastness was obtained. Example 20 A woven fabric of alkalized viscose wadding was dried with a liquid containing 35 g/l of anhydrous sodium carbonate, 200 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with an aqueous ink containing the following ingredients: 10% C. I.  Reactive Red 1 87 15 ° / 〇 tetramethylene sulane 10 % butyl diglycol 65% water Cheng Qi Yin Hui Hui smasher 1. Xiao Fei ^阼^^-& The print is completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter is further rinsed by heating, heated, washed with hot water at 95 t, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. Example 21 Paper scale applies to China National Standard (CNS) A4 specification (2 〗 0 X 297 mm) -24- 1278553 A7 _B7___ V. Invention description (22) (Please read the note on the back and fill out this page. The woven fabric of the alkalized viscose filament was dried with a liquid containing 35 g/l of anhydrous sodium carbonate, 200 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand ink jet print head with an aqueous ink containing the following ingredients: 1 2 % C. I.  Reactive Blue 21 10% tetramethylene sulane 8 % butyl diglycol 70 % water The print was completely dried. At 10 2 t, it was fixed with saturated steam for 8 minutes. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a blue-green printing having excellent use fastness was obtained. Example 22 A woven fabric of cotton for sale was dried with a liquid containing 35 g/l of anhydrous sodium carbonate, 50 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a water-based ink containing the following components: a water-based ink containing the following ingredients: ° 8 °/〇 C. I.  Reactive Black 14 1 0 % Tetramethyl decane 5% butyl diglycol 77 % Water on paper scale applicable to China National Standard (CNS) A4 specification (2) 0 X 297 mm) -25- 1278553 A7 ____B7___ , invention instructions (23) (please read the notes on the back and then fill out this page) The printed matter is completely dry. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, gray printing with excellent use fastness is obtained. Example Twenty-three Commercially available cotton woven fabrics were dried with a liquid containing 35 g/l of anhydrous sodium carbonate '100 g/l urea and 150 g/l of low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with a water-based ink containing the following ingredients: 1 2 % C. I.  Reactive Orange 12 8 % Tetramethylene alkane 10 % Butyldiethylene glycol 70 % Water The print was completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, golden yellow printing with excellent use fastness was obtained. Example 24 A woven fabric of alkalized viscose mash was dried with a liquid containing 35 g/l of anhydrous sodium carbonate, 200 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained makes the paper scale applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -26- 1278553 A7 B7 V. Description of the invention (24) Spray with drop-on-demand Ink print heads are printed with water-based inks containing the following ingredients: (Please read the notes on the back and fill out this page) 1 〇% C. I.  Reactive Orange 35 9 % Tetramethyl decane 5 % Butyl diglycol 7 6 % Water The print was completely dried. At 10 2 t, it was fixed with saturated steam for 8 minutes. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, brownish yellow printing with excellent use fastness was obtained. Example 25 A woven fabric of cotton for sale was dried with a liquid containing 35 g/l of anhydrous sodium carbonate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with a water-based ink containing the following ingredients: 1 2 % C. I.  Reactive Red 2 1 8 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 5 % Tetramethyl Cyclohexane 15 % Butyl Diethylene Glycol, 6 8 % Water ' The print was completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -27- 1278553 A7 ____B7_ V. Invention Description (25) The result is a red print with excellent use fastness. (Please read the precautions on the back and fill out this page.) Example Twenty-six cotton fabrics for commercial cotton are packed with 35g/l anhydrous sodium carbonate, 150g/l urea and 150g/l low viscosity sodium alginate solution ( 6%) of the liquid is then dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-〇n-demand (pressure) inkjet print head with a water-based ink containing the following ingredients: 1 5 % C. I.  Reactive Blue 49 1 0 % Tetramethylene sulane 7 % Butyl diglycol 6 8 ° / 〇 Water The print was completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a blue print having excellent use fastness was obtained. Example 27: Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption, 阼Fi printing, commercial cotton woven fabric, containing 35g/l anhydrous sodium carbonate, 100g/l urea and 150g/l low viscosity alginic acid, _ solution ( 6%) of the liquid is then dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand ink jet print head with a water-based ink containing the following composition: 10% C. I.  Reactive Black 39 This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -28- 1278553 A7 B7 V. Description of invention (26 ) 1 0 % Tetramethyl brothel 5% butyl bis Alcohol 7 5 % water print was completely dried. It was fixed at 102 t with saturated steam for 8 minutes. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, then Drying. The result is a navy blue printing with excellent fastness of use. Example 28 Commercially woven cotton fabric tampon with 40 g/l anhydrous sodium carbonate, 100 g/l urea and 150 g/l low viscosity alginic acid The sodium solution (6%) of the liquid is then dried. The wet harvest is 70%. The pretreated fabric thus prepared is printed using a drop-on-demand inkjet printhead with an aqueous ink containing the following ingredients = 1 5 % C. I.  Reactive Black 5 20% Tetramethylene 2% Butyl Diethylene Glycol 6 1 % Water The print was completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter is further subjected to warming and rinsing, washed with hot water at 95 ° C, heated and rinsed, and then dried. ' 吉 果 fruit gets a navy blue print with excellent use of fastness. Example 29 The paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) --*---,--------Install--- (Please read the notes on the back first) Fill in this page) Order-··Line丨· Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Print -29- 1278553 A7 __ B7___ V. Inventions (27) -ϋ ϋ»ini ϋ ϋ n ϋ · in (please Read the notes on the back and fill out this page. The cotton fabric of the commercial cotton is smeared with a liquid containing 40g/l anhydrous sodium carbonate '100g/l urea and 150g/l low viscosity sodium alginate solution (6%). dry. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with a water-based ink containing the following ingredients: 6 % C. I.  Reactive Blue 21 5 % C. I.  Reactive Yellow 37 15 ° / 〇 tetramethylene olefin 5 % butyl diglycol 69% water The print was completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, green printing with excellent use fastness is obtained. Example 30 Commercially-selling cotton textile fabrics with 35g/Ι anhydrous sodium carbonate, Ministry of Economic Affairs, Intellectual Property Office staff consumption cooperation, printing 50g/l urea and 1 50g/l low viscosity sodium alginate solution (6 %) of the liquid is then dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with a water-based ink containing the following ingredients: 8 % C. I.  Reactive Black 8 1 0 % Tetramethylene 4% Butyl Glycol This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) -30- 1278553 A7 B7 V. Description of invention (28 7 8 °/〇水-IJII |\| IIIII * II (Please read the note on the back and fill out this page) The print is completely dry. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further subjected to warm rinsing and washing with hot water at 95 ° C, rinsing with heating, and then drying. As a result, gray printing with excellent use fastness is obtained. Example 31 A woven fabric of cotton for sale was dried with a liquid containing 35 g/l of anhydrous sodium carbonate '200 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with a water-based ink containing the following ingredients: # 1 5 % C. I.  Reactive Black 5 0. 8% C. I.  Reactive Orange 107 0. 2 % C. I.  Reactive Red 180 20 % Tetramethylmethane 5 °/. Butyl diglycol 5 9 ° / 〇 Water Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed The printed matter was completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter is further subjected to warming and rinsing, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, black printing having excellent use fastness is obtained. Example 32 paper size applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -31 - 1278553 A7 B7___ V. Invention description (29) (Please read the note on the back and fill out this page) The woven fabric of cotton sold was dried with a liquid containing 35 g/d anhydrous sodium hydrogencarbonate, 200 g/l urea and 150 g/l low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with a water-based ink containing the following ingredients: 8 % C. I.  Reactive Orange 1 3 10 ° / 〇 tetramethylene decane 4 ° / 〇 N-methyl-2-pyrrolidone 0. 5 % modified phosphate 77. 5 % water The print was completely dried. At 10 2 t, it was fixed with saturated steam for 8 minutes. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, an orange print having excellent use fastness was obtained. Example Thirty-three Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed the woven fabric of alkalized viscose to contain 35g/Ι anhydrous sodium bicarbonate, 150g/l urea and 150g/l low viscosity sodium alginate solution (6%) of the liquid is then dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand spray ink head with an aqueous ink containing the following components = 10% C.  I.  Reactive Red 218 5 ° / 〇 tetramethylene hexane 15 % N-methyl-2-pyrrolidone This paper scale applies to China National Standard (CNS) A4 specifications (210 X 297 mm) - 32- 1278553 A7 _______B7____ Description of the invention (30) 0. 5% modified phosphate 69. 5% water (please read the notes on the back and fill out this page) The print is completely dry. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was subjected to warming and rinsing, and the mixture was washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. Example 34 A woven fabric of alkalized viscose wadding was dried with a liquid containing 35 g/l of anhydrous sodium hydrogencarbonate, 200 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand ink jet print head with an aqueous ink containing the following components: 8 % C. I.  Reactive Blue 49 15% Tetramethylendron 5 % N-methyl-2-pyrrolidone 5 % modified phosphate 71. 5% Water Economy Zou Intellectual Property Bureau employee consumption contract: ώ Printing The printed matter is completely dry. It was fixed at 1 02 °c for 8 minutes using saturated steam. Then, the printed matter was again subjected to warming and rinsing, washed rapidly with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a blue print having excellent use fastness was obtained. Example 35 Paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1278553 A7 B7 V. Invention description (31) (Please read the note on the back and fill out this page) Commercial cotton The woven fabric was dried with a liquid containing 30 g/l of anhydrous sodium carbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with a water-based ink containing the following ingredients: 1 〇 % C. I.  Reactive Red 1 80 15 ° / 〇 tetramethylene olefin 4 ° / 〇 N-methyl-2-pyrrolidone 0. 5 % modified phosphate 7 0. 5 % water The print was completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further tempered by heating, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. Example 36 痤 郎 智慧 智 智 智 43⁄4 staff consumption cooperative printed woven silk fabric woven with 50g / l sodium acetate, 150g H urea and 150g / l highly etherified mannan galactan (5 %) The liquid is then dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet printing head with a water-based ink containing the following ingredients: 8 % C. I.  Reactive Yellow 37 20 % Tetramethylene alkane 7 2 °/〇水 This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) _ ^/1 _ 1278553 A7 __B7___ V. Description of invention (32 (Please read the notes on the back and fill out this page) The print is completely dry. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1-2 ml of 25 % ammonia, washed rapidly with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, a yellow print having excellent use fastness is obtained. Example 37 A woven fabric of degummed silk was dried with a liquid containing 50 g/l sodium acetate, 100 g/l urea and 150 g/l highly etherified mannan galactan (5 %). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with a water-based ink containing the following ingredients: 1 2 % C. I.  Reactive Yellow 42 15 % Tetramethyl decane 7 3 °/〇 Water Ministry of Economic Affairs Intellectual Property Bureau employees consumption cooperation du printing The printed matter is completely dry. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1 - 2 ml of 25 % ammonia, and washed with hot water at 70 - 80 ° C for 'warm rinsing' and then dried. As a result, a yellow print having excellent use fastness is obtained. The woven fabric of the Example 18 degummed silk was dried and dried with a liquid containing 5 g/l sodium acetate 'l〇〇g/l urea and 150 g/l highly etherified mannan galactan (5 %). The paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -35- 1278553 A7 ______ B7__ V. Description of invention (33). The wet harvest is 70%. The pretreated fabric thus prepared uses drop- (please read the back note first and then fill out this page) on-demand (foam jet) inkjet print head ' Printed with water-based ink containing the following ingredients: 1 4 % C. I.  Reactive Orange 107 2 1 5 tetramethylene sulphate 71 % Water The print was completely dried. It was fixed at 1 〇 2 °C for 8 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1 - 2 ml of 25 % ammonia, and washed with hot water at 70 - 80 ° C for 'warm rinsing' and then dried. As a result, golden yellow printing with excellent use fastness was obtained. Example 39 A woven fabric of degummed silk was dried with a liquid containing 50 g/l sodium acetate, 100 g/l urea and 150 g/l highly etherified mannan galactan (5 %). The wet harvest is 70%. The pretreated fabric thus obtained is printed using a drop-on-demand inkjet printing head, and is printed with a water-based ink containing the following components: Ρ-ΞΓ1Χ 9 % C. I.  Reactive Orange 74 15 ° / 〇 tetramethylene sulane , 776 % water The print is completely dry. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter is further heated and rinsed in the presence of l-2ml of 25% ammonia, and is rapidly washed with hot water at 70-80 °C, and heated and rinsed. The paper size is applicable to the Chinese National Standard (CNS) A4 specification. (210 X 297 mm) -36- 1278553 A7 __B7_ V. Inventive Note (34) and then dried. As a result, an orange print having excellent use fastness was obtained. (Please read the note on the back and then fill out this page.) Example 40 Degaussed textile fabric with 50g/l sodium acetate '100g/l urea and 1 50g/l highly etherified mannan galactan (5 %) of the liquid is then dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with a water-based ink containing the following ingredients: 8 % C. I.  Reactive Orange 16 14 % Tetramethylene alkane 7 8 °/〇 Water The print is completely dry. It was fixed at 1 〇 2 °C for 8 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1-2 ml of 25 % ammonia, washed rapidly with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, an orange print having excellent use fastness was obtained. Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption cooperatives, printing, example, forty-one, the textile fabric of degummed silk is smashed with greed. A liquid of 50 g/l sodium acetate, 100 g/l urea and 150 g of highly etherified mannan galactan (5 %) was dried and dried. The tide-harvest is 70%. The pretreated fabric thus obtained is printed using a drop-on-demand inkjet printhead with an aqueous ink containing the following ingredients: This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) - 37- 1278553 A7 B7 V. Description of invention (35) 1 4 % C. I.  Reactive Red 1 80 16 ° / 〇 tetramethylene sulane 3 % butyl diglycol (please read the back note before filling this page) 2 % modified mannose galactan 66. 83⁄4 Water The print is completely dry. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1-2 ml of 25 % ammonia, washed rapidly with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. Example 42 A woven fabric of degummed silk was dried with a liquid containing 50 g/l sodium acetate, 10 g/l urea and 150 g/l highly etherified mannan galactan (5 %). The wet harvest is 70%. The pretreated fabric thus obtained is printed using a drop-on-demand inkjet print head with an aqueous ink containing the following ingredients: 齐 郎 智慧 智慧 1-3 1-3 1-3 1-3 1-3 1-3 1-3 1-3 1-3 1-3 1-3 - - - - 9 9 C. I.  Reactive Red 239 16 % tetramethylene sulphate 5 % butyl diglycol, 0. 2% modified mannose galactan 0. 5 % borane 69. 3 % water The print was completely dried. At 1 02 °C, use the saturated steam to fix the paper scale to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -38 - 1278553 A7 __ B7 ___ V. Invention description (36) (Read first Note on the back side of this page.) Set 20 minutes. Then, the printed matter was further tempered in the presence of 1-2 ml of 25 % ammonia, washed rapidly with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. Example 43 A woven fabric of degummed silk was dried with a liquid containing 50 g/l sodium acetate, 100 g/l urea and 150 g/l highly etherified mannan galactan (5 %). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with aqueous ink containing the following ingredients: 10% C. I.  Reactive Red 198 12% tetramethylene brothel 6 % butyl diglycol 0. 5 % modified phosphate 7 1. 5% Water Thin Qilang wisdom financial smasher! - Xiao Fei 乂 α 乍 Fi ^ - no prints are completely dry. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1-2 ml of 25 % ammonia, washed rapidly with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. Example forty-four degummed silk fabric choking to contain 50g / l sodium acetate 'l〇〇g / l urea paper size applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) -39- Ministry of Economic Affairs The Intellectual Property Office Staff Consumer Cooperative printed 1275553 A7 ________B7_5, invention instructions (37) and 1 5Og / Ι highly etherified mannose galactan (5%) liquid and dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-d e a n d ink jet printing head with an aqueous ink containing the following components: 8 % C. I.  Reactive Red 35 13 % tetramethylene olefin 3 ° / ◦ butyl diglycol 0. 3 % sodium citrate 7 5. 7% water The print was completely dried. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1-2 ml of 25 % ammonia, washed rapidly with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. Example 45 A woven fabric of degummed silk was dried with a liquid containing 50 g/l sodium acetate, 100 g/l urea and 150 g/l highly etherified mannan galactan (5 %). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet printing head with aqueous ink containing the following ingredients: 10% C. I.  Reactive Blue 19 16 % Tetramethylene alkane 3 ° / 〇Ί One base 2: Glycol This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back first) Fill in this page) Loading -l·, -40- 1278553 A7 _B7____ V. Description of invention (38) 0. 5 % modified phosphate 70. 5% water (please read the notes on the back and fill out this page) The print is completely dry. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1 - 2 ml of 25 % ammonia, washed with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, a blue print having excellent use fastness was obtained. Example 46 A woven fabric of degummed silk was dried with a liquid containing 50 g/l sodium acetate, 10 g/l urea and 150 g/l highly etherified mannan galactan (5 %). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a enamel-on-demand inkjet print head with aqueous ink containing the following ingredients: 10 ° / 〇 C. I.  Reactive Blue 21 5 % Tetramethylmethane 15 % N-methyl-2-pyrrolidone 7 0 °/〇 Water Economy Zou Wisdom property 咼 Employees' consumption 阼fi Printed The print is completely dry. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter is tempered by tempering l-2 ml of 25 % ammonia, washed with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, a blue-green printing having excellent use fastness was obtained. This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) -41 - 1278553 A7 ____B7 _ V. Invention description (39) Example forty-seven (please read the note on the back and fill out this page) The woven fabric of degummed silk was dried with a liquid containing 50 g/l sodium acetate, 100 g/l urea and 150 g/l highly etherified mannan galactan (5 %). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with aqueous ink containing the following ingredients: 1 2 % C. I.  Reactive Blue 229 Ί % Tetramethylene alkane 12 % Ν-methyl-2-pyrrolidone 69% Water The print was completely dried. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1-2 ml of 25 % ammonia, washed rapidly with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, a blue-green printing having excellent use fastness was obtained. Example 48: Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption cooperation, Du-printed debonded silk fabric, with 50g/l sodium acetate, 100g/l urea and 150g/Ι highly etherified mannan galactan (5 %) The liquid is then dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with aqueous ink containing the following ingredients: 10% C. I.  Reactive Black 14 10 ° / 〇 tetra methylene chloride This paper scale applies to China National Standard (CNS) A4 specifications (210 X 297 mm) -42 - 1278553 A7 __B7__ V. Description of invention (4〇) 10 % N· Methyl-2-pyrrolidone 7 2 ° / 〇水 (please read the notes on the back and fill out this page) The print is completely dry. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1 - 2 ml of 25 % ammonia, washed with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, gray printing with excellent use fastness is obtained. Example 49 A woven fabric of degummed silk was dried with a liquid containing 50 g/l sodium acetate, 100 g/l urea and 150 g/l highly etherified mannan galactan (5 %). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet printhead with aqueous ink containing the following ingredients: 5 % C. I.  Reactive Black 3 1 8 % Tetramethylene alkane 12 % N-methyl-2-pyrrolidone 7 5 °/〇 Water Printed by the Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs The printed matter was completely dried. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter is tempered by tempering l-2 ml of 25 % ammonia, washed with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, gray printing with excellent use fastness is obtained. This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -43- 1278553 A7 ____B7 _ V. Invention description (41) Example 50 (please read the note on the back and fill in this page) Degumming The silk fabric was smeared with a liquid containing 50 g/l sodium acetate, 100 g/l urea and 150 g/l highly etherified mannan galactan (5 %) and dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet printhead with aqueous ink containing the following ingredients: 1 5 % C. I.  Reactive Black 5 10% tetramethylene decane 12 % N-methyl-2-pyrrolidone 63 % Water The print was completely dried. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1 - 2 ml of 25 % ammonia, washed rapidly with hot water at 70 - 80 ° C, warmed and rinsed, and then dried. As a result, a navy blue print with excellent use fastness is obtained. Example 51. Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative, printed textile fabric with degummed silk, containing 50g/l sodium acetate, l〇〇g/l urea and 150 g/l highly etherified mannan galactan ( 5%) of the liquid is then dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with an aqueous ink containing the following ingredients: _ 10 % C. I.  Reactive Yellow 37 1 5 % Tetramethyl syllabus This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) -44- 1278553 A7 B7 V. Description of invention (42) 7 % Polyether polyol 6 8 % water (please read the notes on the back and fill out this page) The print is completely dry. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 25% ammonia, washed rapidly with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, a yellow print having excellent use fastness is obtained. Example 52 A woven fabric of degummed silk was dried with a liquid containing 50 g/l sodium acetate, 100 g/l urea and 150 g/l highly etherified mannan galactan (5 %). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with an aqueous ink containing the following ingredients. 5% C. I.  Reactive Red 180 15 % tetramethylene olefin 8 % polyether polyol 66. 5 % Water Economic Zou Intellectual Property Bureau employees consume a combination; ώ printed The printed matter is completely dry. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1-2 ml of 25 % ammonia, washed rapidly with hot water at 70-80 t, warmed and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -45- 1278553 A7 B7 V. Description of invention (43) Example 53 (please read the notes on the back and fill out this page) The silk fabric was smeared with a liquid containing 50 g/l sodium acetate, 100 g/l urea and 150 g/l highly etherified mannan galactan (5%) and dried. The wet harvest is 70%. The pretreated fabric thus obtained was subjected to a continuous flow (pressure) ink jet print head, and printed with an aqueous ink containing the following components, 1 2 % C. I.  Reactive Blue 21 18 % Tetramethylene alkane 7 ° / 聚醚 Polyether polyol 63 % Water The print is completely dried. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1 - 2 ml of 25% ammonia, washed with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, a blue-green printing having excellent use fastness was obtained. Example fifty-four by Qi Village wisdom, the production bureau member x-consumer 阼 中 中 中 脱 脱 脱 woven fabric woven with 50g / l sodium acetate, l 〇〇 g / l urea and 1 50g / l highly etherified nectar The galactan (5%) liquid is then dried. The wet harvest is 70%. The pretreated fabric thus obtained was subjected to a continuous flow (pressure) ink jet print head, and 8 % C was printed with an aqueous ink containing the following ingredients.  I.  Reactive Black 14 15 % Tetramethyl ruthenium paper size applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -46- 1278553 A7 ___B7____ V. Description of invention (44) 5 ° / 〇 polyether Alcohol 72% water (please read the notes on the back and fill out this page) The print is completely dry. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1 - 2 ml of 25 % ammonia, and subjected to a rapid washing treatment with hot water at 70 - 80 ° C, followed by rinsing and drying. As a result, gray printing with excellent use fastness is obtained. Example 55 A woven fabric of degummed silk was dried with a liquid containing 50 g/l of sodium acetate, 10 g/l of urea and 150 g/l of highly etherified mannan galactan (5%). The wet harvest is 70%. The pretreated fabric thus obtained was subjected to a continuous flow (pressure) ink jet print head, and printed with an aqueous ink containing the following components, 1 1 % C. I.  Reactive Red 1 80 • 15 % Tetramethylene olefin 4 % Polyvinyl caprolactam 7 0 % Water Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperation Du printed The printed matter is completely dried. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter is heated and rinsed in the presence of 1 - 2 ml of 25 % ammonia, washed with hot water at 70-8 (fast washing under TC, heated and rinsed) and then dried. The result is a red color with excellent use fastness. Printing. This paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -47- 1278553 A7 I-___B7 __ V. Description of invention (45) Example 56 Textile fabric entangled with degummed silk to contain 50g / l sodium acetate '100g / l urea (please read the back of the note before filling this page) and 1 50g / l highly etherified mannose galactan (5 %) liquid and then dry ^ wet harvest is 70%. The pretreated fabric thus obtained uses a continuous flow (pressure) inkjet print head and is printed with 10% C. using an aqueous ink containing the following ingredients. I.  Reactive Blue 21 15 ° / 〇 tetramethylene olefin 3 ° / 〇 1,2-hexanediol 5 ° / 聚乙烯 polyvinyl caprolactam 67 ° / 〇 water The print was completely dried. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1 - 2 ml of 25 % ammonia, washed with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, a blue-green printing having excellent use fastness was obtained. Example 57: Qi Lang fel 曰 时 笱 笱 二 肖 肖 肖 肖 肖 & & & & 纺织 阼 阼 阼 Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi Fi l Highly etherified mannose galactan, (5%) liquid and dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with an aqueous ink containing the following ingredients: 8 % C. I.  Reactive Black 1 4 This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -48- 1278553 A7 ____B7_ V. Invention description (46) 1 5 % Tetramethyl mesh (please read the back first) Note on this page.) 5 % Polyether Polyol 3 % 1,2-Hexanediol 69% Water prints are completely dried. It is fixed at 1 〇 2 c for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1 - 2 ml of 25 % ammonia, and washed with hot water at 70 - 80 ° C for 'warm rinsing' and then dried. As a result, gray printing with excellent use fastness is obtained. Example 58 A woven fabric of degummed silk was dried with a liquid containing 50 g/l sodium acetate, 100 g/l urea and 150 g/l highly etherified mannan galactan (5 %). The wet harvest is 70%. The pretreated fabric thus obtained uses a continuous flow (pressure) inkjet print head, and is printed with an aqueous ink containing the following components. The Ministry of Commerce, Intellectual Property Office, Staff Consumer Cooperative, printed 1 2 % C. I.  Reactive Blue 2 1 18 ° / 〇 tetramethylene alkane 7 % polyether polyol 3 % 1,2-hexanediol, 60 % water The brush is completely dried. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter is further heated and rinsed in the presence of l-2ml of 25% ammonia, and is rapidly washed with hot water at 70-80 °C, and heated and rinsed. The paper size is applicable to the Chinese National Standard (CNS) A4 specification. (210 X 297 mm) -49- 1278553 A7 B7 V. Inventive Note (47) and then dried. As a result, a blue-green printing having excellent use fastness was obtained. (Please read the precautions on the back and fill out this page.) Example 59. The fabric of the degummed silk fabric is packed with 5〇g/l sodium acetate, 100g/l urea and 150g/Ι highly etherified nectar semi-emulsion. The sugar (5 %) of the liquid is then dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with an aqueous ink containing the following ingredients. 5C. I.  Reactive Red 180 15 % tetramethylene olefin 8 % polyether polyol 6 % polypropylene glycol 60. 5 ° / 〇 Water The print is completely dried and fixed at 10 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of i_2 ml of 25 % ammonia, washed rapidly with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. An example of a sixteenth velvet woven fabric was dried with a liquid containing 50 g/l sodium acetate, 100 g/l urea and 150 g/l highly etherified mannan galactan (5 %). The wet harvest is 70%. The pretreated fabric thus obtained is of continuous flow paper size and is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -50-1278553 A7 B7 5. Inventive Note (48) Dynamic (Pressure) Inkjet Print Head 'Print with water-based inks containing the following ingredients (please read the notes on the back and fill out this page) 1 0 % C. I.  Reactive Yellow 37 15 ° / 〇 tetramethylene decane 7 % polyether polyol 4 % polypropylene glycol 0. 3% sodium citrate 63. 7 % water The print was completely dried. It was fixed at 1 〇 2 °C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1 - 2 ml of 25 % ammonia, and washed with hot water at 70 - 80 ° C for 'warm rinsing' and then dried. As a result, a yellow print having excellent use fastness is obtained. Example Six Η 经 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 纺织 Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η 5%) of the liquid is then dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand ink jet print head with an aqueous ink containing the following ingredients: 8 % C. I.  Reactive Yellow 37 20% Tetramethyl methoxide 7 2 °/〇 Water The print is completely dry. At 1 〇 2 °C, use the saturated steam solid paper scale for the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1278553 A7 B7___ V. Invention description (49) for 20 minutes. Then, the printed matter was further tempered in the presence of 1-2 ml of 25 % ammonia, washed rapidly with hot water at 70-80 ° C, heated and rinsed, and then dried. (Please read the notes on the back and fill out this page.) The result is a yellow print with excellent fastness. Example Sixty-two A woven fabric of chlorinated wool was smeared with a liquid containing 50 g/l sodium acetate, 150 g/l urea and 150 g/l low viscosity sodium alginate solution (5%), followed by drying. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with an aqueous ink containing the following ingredients: 1 2 % C. I.  Reactive Yellow 42 15 % Tetramethylene alkane 7 3 % Water The print was completely dried. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1-2 ml of 25 % ammonia, and washed with hot water at 70-80 ° C for rapid washing, followed by drying. The Ministry of Economic Affairs, the Intellectual Property Bureau, the employee consumption cooperative, printed the result, and obtained yellow printing with excellent use of fastness. Example 63 A woven fabric of chlorinated wool was smeared with a liquid containing SOW1 sodium acetate '150 g/l urea and 150 g/l low viscosity sodium alginate solution (5%) and dried. The wet harvest is 70%. The pretreated fabric thus obtained is of the Chinese National Standard (CNS) A4 specification (210 X 297 mm) using the paper scale. -52-1283753 A7 B7 V. Invention Description (50) drop-on-demand (bubble jet) The inkjet print head 'prints with water-based inks containing the following ingredients: (Please read the notes on the back and fill out this page) 1 4 % C. I.  Reactive Orange 107 15 % Tetramethyl decane 71 ° / 〇 Water The print is completely dry. It was fixed at 1 〇 2 °C for 20 minutes using saturated steam. Then, the printed matter was further tempered in the presence of 1 - 2 ml of 25 % ammonia, and washed with hot water at 70 - 80 ° C for 'warm rinsing' and then dried. As a result, golden yellow printing with excellent use fastness was obtained. Example Sixty-four woven fabrics of chlorinated wool were smeared with a liquid containing 50 g/l sodium acetate, 150 g/l urea and 150 g/l low viscosity sodium alginate solution (5%) and dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with an aqueous ink containing the following components: Ministry of Economic Affairs, Intellectual Property Office, employee consumption cooperation, printing 9% C. I.  Reactive Orange 74 15 % Tetramethylene alkane 7 6 % Water, printed material completely dried. It was fixed at 20 °C with saturated steam at 1 〇 2 °C. Then, the printed matter was further tempered in the presence of 1-2 ml of 25 % ammonia, washed rapidly with hot water at 70-80 ° C, heated and rinsed, and then dried. This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -53- 1278553 A7 B7 V. Inventive Note (51) The result is an orange print with excellent fastness of use. Example Sixty-five A woven fabric of chlorinated wool was stoppered and dried with a liquid containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with an aqueous ink containing the following ingredients: 8 % C. I.  Reactive Orange 16 16% Tetramethyl ketone 78 % Water The print is completely dry. It was fixed at 12 ° C for 20 minutes using saturated steam. Then, the printed matter was further tempered in the presence of 1 - 2 ml of 25% ammonia, and subjected to a fast washing treatment with a hot water at 70 to 80 ° C, and then dried. As a result, an orange print having excellent use fastness was obtained. Example Sixty-six are all %% woven fabric of chlorinated wool is smeared with liquid containing 502/1 sodium acetate '150g/l urea and 150g/l low viscosity alginic acid mixed solution (5%) dry. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with a water-based ink containing the following ingredients: 10% C. I.  Reactive Blue 19 -54 - (Please read the note on the back and fill out this page) This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1278553 A7 ___B7_ V. Invention description (52 ) 16% Tetramethylidene 垸 3 % butyl dibutanol (please read the notes on the back and fill out this page) 0. 5% modified phosphate 7 0. 5% water The print was completely dried. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1 - 2 ml of 25 % ammonia, and washed with hot water at 70 - 80 ° C for 'warm rinsing' and then dried. As a result, a blue print having excellent use fastness was obtained. Example 67 A textile fabric of chlorinated wool was smeared with a liquid containing 50 g/l sodium acetate '150 g/l urea and 150 g/l low viscosity sodium alginate solution (5%) and dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with a water-based ink containing the following ingredients: 8 % C. I.  Reactive Red 35 13 % tetramethylene decane; 3 % butyl diglycol 0. 3% sodium citrate, 7 5. 7% water The print was completely dried. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter is heated and rinsed in the presence of l-2ml of 25 % ammonia, and is washed with hot water at 70-80 ° C for rapid washing, and the paper is scaled according to the Chinese National Standard (CNS) A4 specification. (210 X 297 mm) -55 - 1278553 A7 B7 5. Inventive Note (53) and then dried. As a result, red printing with excellent use fastness was obtained. Example 68 A woven fabric of chlorinated wool was smeared with a liquid containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%), followed by drying. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with a water-based ink containing the following ingredients: 10% C. I.  Reactive Red 1 98 12 ° / 〇 tetramethylene decane 6% butyl diglycol 0. 5 % modified phosphate 71. 5% water The print was completely dried. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter is further tempered in the presence of 1 - 2 ml of 25 % ammonia, washed with hot water at 70-8 (TC under strong washing, heated and rinsed, and then dried. The result is a red color with excellent use fastness. Printing. Example 69 woven fabric of chlorinated wool is dried with a liquid containing 50 g / l sodium acetate, 150 g / l urea and 150 g / l low viscosity sodium alginate solution (5%). The harvest is 70%. The pretreated fabric thus obtained is of this paper size and is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ---?------------ --- (Please read the notes on the back and fill out this page) - 1⁄4.  Ministry of Economic Affairs Intellectual Property Officer X Consumer Cooperation fi printing -56-1285553 A7 B7 V. Invention Description (54) drop-on-demand (pressure) inkjet print head, printed with water-based ink containing the following ingredients: (Read first Note on the back page again) 9 % C. I.  Reactive Red 239 16 % tetramethylene alkane 5 % butyl dibutanol 0. 5 % borane 69. 5 ° / 〇 Water The print is completely dry. It was fixed at 102 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 25% ammonia, washed rapidly with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. Example 70 A woven fabric of chlorinated wool was stoppered and dried with a liquid containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with a water-based ink containing the following ingredients: 1 4 % C. I.  Reactive Red 18Q.  16 % tetramethylene sulane 3 % butyl dibutanol 67 ° / 〇 Water The print was completely dried. At 1 02 °C, use the saturated steam solid paper scale to apply the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -57- 1278553 A7 ___B7___ V. Inventive Note (55) for 20 minutes. Then, the printed matter is heated and rinsed in the presence of 丨-21^1 25 % ammonia, and washed with hot water at 70-80 ° C. 'Warming and rinsing' (please read the notes on the back and fill in the form) This page) is dried. As a result, red printing with excellent use fastness was obtained. Example 71 A woven fabric of chlorinated wool was stoppered and dried with a liquid containing 5 g/l sodium acetate '150 g/l urea and 150 g/l low viscosity sodium alginate solution (5%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand ink jet print head with a water-based ink containing the following ingredients: 1 5 % C. I.  Reactive Black 5 10 % Tetramethylene alkane 12 % N-methyl-2-pyrrolidone 6 3 % Water Ministry of Economic Affairs Intellectual Property Bureau employees consumption cooperation Du printing The printed matter is completely dried. It was fixed at 20 t for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1 - 2 ml of 25 % ammonia, washed with hot water at 70-80 ° C, heated and rinsed, and then dried. The result is obtained with excellent use of firmness. Sexual blue-green printing. Example Seventy-two woven fabrics of chlorinated wool are smeared with liquid containing 50g/l sodium acetate '150g/l urea and 150g/l low viscosity sodium alginate solution (5%). Standard (CNS) A4 size (210 X 297 mm) -58- 1278553 A7 _____B7___ V. Description of invention (56) to dry. The wet harvest is 70%. The pretreated fabric thus obtained (please read the back note before filling out this page) drop-on-demand (pressure) inkjet print head, printed with water-based ink containing the following ingredients: 5 % C. I.  Reactive Black 3 1 8 % Tetramethyl decane 12 % N-methyl-2-pyrrolidone 7 5 % Water The print was completely dried. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1 - 2 ml of 25 % ammonia, washed with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, gray printing with excellent use fastness is obtained. Example 73 A woven fabric of chlorinated wool was stoppered and dried with a liquid containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head printed by the Ministry of Economic Affairs' Intellectual Property Office Staff Consumer Cooperative, using a water-based ink containing the following ingredients: 8 % C. I.  Reactive Black 14. .  10 ° / 〇 tetramethylene alkane 10 % N-methyl-2-pyrrolidone 7 2 % water The print was completely dried. At 12 ° ° C, using saturated steam to solidify the paper scale applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) -59- 1278553 A7 B7 V. Invention description (57) (Please read the back of the note first Please fill in this page again) 20 minutes. Then, the printed matter was further tempered in the presence of 1-2 ml of 25 % ammonia, washed rapidly with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, gray printing with excellent use fastness is obtained. Example 74 A woven fabric of chlorinated wool was stoppered and dried with a liquid containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with a water-based ink containing the following ingredients: 1 2 % C. I.  Reactive Black 229 Ί % Tetramethylidene 12% Ν-methyl-2-pyrrolidone 69 % Water Printed by the Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs The printed matter was completely dried. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1-2 ml of 25 % ammonia, washed rapidly with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, a blue-green print with excellent use and firmness is obtained. Example Seventy-five woven fabrics of chlorinated wool are smeared with liquid containing 50g/l sodium acetate, 150g/l urea and 150g/l low viscosity sodium alginate solution (5%). Standard (CNS) A4 size (210 X 297 mm) -60- 1278553 A7 B7 V. Description of invention (58) (Please read the note on the back and fill out this page) to dry. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-〇n-demand (pressure) inkjet print head with a water-based ink containing the following composition: 10% C. I.  Reactive Blue 21 5 % Tetramethyl decane 15 % N-methyl-2-pyrrolidone 70 % Water The print was completely dried. It was fixed at 102 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1 - 2 ml of 25 % ammonia, and washed with hot water at 70 - 80 ° C for 'warm rinsing' and then dried. As a result, a blue-green printing having excellent use fastness was obtained. Example 76 A woven fabric of chlorinated wool was stoppered and dried with a liquid containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with aqueous ink containing the following ingredients: 8 % C. I.  Reactive Black 14, 1 5 % Tetramethylene olefin 5 % Polyether polyol 7 2 ° / 〇 Water The print is completely dried. At 1 02 °C, use the saturated steam to fix the paper size. Applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -61 - 1278553 A7 ____B7_ V. Invention description (59) (Please read the back note first) Please fill in this page again) 20 minutes. Then, the printed matter was further tempered in the presence of 1-2 ml of 25 % ammonia, washed rapidly with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, gray printing with excellent use fastness is obtained. Example 77 A woven fabric of chlorinated wool was stoppered and dried with a liquid containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with aqueous ink containing the following ingredients: 1 2 % C. I.  Reactive Blue 21 18 ° / 〇 tetramethylene decane 7 ° / 聚醚 polyether polyol 63 % water economic Zou wisdom property board X. Consumption & 阼fi printing The print is completely dry. It was fixed at 1 〇 2 °C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1-2 ml of 25 % ammonia, washed rapidly with hot water at 70-80 ° C, heated and rinsed, and then dried. The result is obtained with excellent use of firmness. Sexual blue-green printing. Example 78 woven fabric of chlorinated wool is smeared with liquid containing 50g/l sodium acetate, 150g/l urea and 150g/l low viscosity sodium alginate solution (5%). Standard (CNS) A4 size (210 X 297 mm) -62- 1278553 A7 _B7___ V. Description of invention (6〇) to dry. The wet harvest is 70% ° used in the pre-treated fabric (please read the back note first and then fill out this page). Continuous flow (pressure) inkjet print heads are printed with aqueous ink containing the following ingredients: 5% C. I.  Reactive Red 180 15 % Tetramethyl decane 8 ° / 聚醚 Polyether polyol 66. 5 % water The print was completely dried. It was fixed at 12 ° C for 20 minutes using saturated steam. Then, the printed matter was further tempered in the presence of 1 _2 ml of 25 % ammonia, and washed with hot water at 70-80 ° C for 'warm rinsing' and then dried. As a result, red printing with excellent use fastness was obtained. Example 79 A woven fabric of chlorinated wool was stoppered and dried with a liquid containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with aqueous ink containing the following ingredients: 10% C. I.  Reactive Yellow 3 7 15 % Tetramethylene alkane 7 ° / 聚醚 Polyether polyol 6 8 ° / 〇 Water The print is completely dried. At 102 °C, use the saturated steam solid paper scale to apply the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -63-1283753 A7 ___B7__ V. Invention description (61) for 20 minutes. Then, the printed matter was further tempered in the presence of 1-2 ml of 25 % ammonia, washed rapidly with hot water at 70-80 T:, rinsed with temperature, and then dried. (Please read the notes on the back and fill out this page.) The result is a gray print with excellent fastness. Example 80 A woven fabric of chlorinated wool was stoppered and dried with a liquid containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with aqueous ink containing the following ingredients: 10% C. I.  Reactive Blue 21 15 % Tetramethylene alkane 3 % 1,2-hexanediol 5 % polyvinyl caprolactam 67 % Water Ministry of Economic Affairs Intellectual Property Officer X. Consumer Consolidation: ώ Printed The print is completely dry. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1-2 ml of 25 % ammonia, washed with hot water at 70-80 ° C, heated and rinsed, and then dried. The result is a blue-green printing with excellent fastness of use. Example 81 woven fabric of chlorinated wool with 50g/l sodium acetate' This paper scale applies to China National Standard (CNS) A4 specification (210 X 297) PCT) -64 - 1278553 A7 B7 V. INSTRUCTIONS (62) (Please read the note on the back and fill out this page) 150g/l urea and 150g/l low viscosity sodium alginate solution (5%) Then dry it. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with aqueous ink containing the following ingredients: 1 1 % C. I.  Reactive Red 1 80 15 % Tetramethylene 2 °/〇 Polyvinylcaprolamine 70% Water The print is completely dried. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1-2 ml of 25% ammonia, washed rapidly with hot water at 70-80 t, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. Example 88 A woven fabric of chlorinated wool was stoppered and dried with a liquid containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with aqueous ink containing the following ingredients:, 10% C. I.  Reactive Yellow 37 15 % Tetramethylene oxime Ί % Polyether polyol 4 % Polypropylene glycol This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) -65- 1278553 A7 B7 V. Description of invention (63) 6 3. 7% water The print was completely dried. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered in the presence of 1-2 ml of 25 % ammonia, washed rapidly with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, a yellow print having excellent use fastness is obtained. Example 83 A woven fabric of chlorinated wool was smeared with a liquid containing 50 g/sodium acetate, 150 g/l urea and 150 g/l low viscosity sodium alginate solution (5%), followed by drying. The wet harvest is 70%. The pretreated fabric thus obtained is printed using a continuous flow (pressure) ink jet print head with aqueous ink containing the following ingredients: 5% C. I.  Reactive Red 180 15 ° / 〇 tetramethylene alkane 8 % polyether polyol 6 % polypropylene glycol 60. 5% water The print was completely dried. It was fixed at 20 ° C for 20 minutes with saturated steam. Then, the printed matter was further tempered by 1-2 ml of 25 % ammonia, washed with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. This paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) ----1 -----------Installation--- (Please read the notes on the back and fill in the form) Page) Order · -66 - 1278553 A7 _B7____ V. INSTRUCTIONS (64) Example Eighty-four woven fabrics of chlorinated wool are packed with 5〇g/1 sodium acetate '150g/l urea and 150g/l low viscosity The liquid of the sodium alginate solution (5%) was dried. The wet harvest is 70%. The pretreated fabric thus obtained is printed using a continuous flow (pressure) ink jet print head with aqueous ink containing the following ingredients: 5% C. I.  Reactive Red 180 15 % Tetramethylene alkane 8 % Polyether polyol 6 ° / 聚 Polypropylene glycol 60. 5 % water The print was completely dried. It was fixed at 1 〇 2 °C for 20 minutes using saturated steam. Then, the printed matter was further tempered in the presence of 1 - 2 ml of 25 % ammonia, washed with hot water at 70-80 ° C, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. Example 85 A woven fabric of chlorinated wool was stoppered and dried with a liquid containing 50 g/sodium acetate, 150 g/l urea and 150 g/l low viscosity sodium alginate solution (5%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous rabbit (pressure) inkjet print head with aqueous ink containing the following ingredients: 8 ° / 〇 C. I.  Reactive Black 14 This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -------. ------_装—— (Please read the notes on the back and fill out this page) “%· Ministry of Economic Affairs Intellectual Property Bureau employees cooperation cooperation du printing system-67- 1278553 A7 ___B7__ V. Invention description (65) 5 % tetramethylene olefin 5% polyether polyol 3% 1,2- hexane diol 69% The water print was completely dried. It was fixed at 12 ° C for 20 minutes with saturated steam. Then, the printed matter was again It is heated and rinsed in the presence of 1 - 2 ml of 25 % ammonia, and is rapidly washed with hot water at 70-80 ° C. 'Warming and rinsing, and then dried. The result is gray printing with excellent fastness of use. Example 80 Six commercial cotton fabrics are tamped to contain 35g / anhydrous sodium bicarbonate, 100g / l urea and 1. A liquid of 50 g/l of low viscosity sodium alginate solution (6%) was added and dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with aqueous ink containing the following ingredients: 1 2 % C. I.  Reactive Yellow 95 10% tetramethylene sulphate 8 % polyether polyol 70% water, printed matter completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a bright yellow printing having excellent use fastness was obtained. This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) ----I------------Installation--- (Please read the notes on the back and fill in This page) order · 1⁄4.  - 68- 1278553 A7 _____B7_ _ V. INSTRUCTIONS (66) EXAMPLE VIII (Please read the note on the back and fill out this page) Commercially woven cotton fabric with 35g/l anhydrous sodium bicarbonate, 150g / l urea and 150 g / l low viscosity sodium alginate solution (6%) of the liquid and then dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with aqueous ink containing the following ingredients: 9 % C . I.  Reactive Orange 13 1 2 % Tetramethyl Group 10% Polyether Polyol 69% Water The print is completely dry. It was fixed at 10 ° C for 8 minutes using saturated steam. Then, the printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, an orange print having excellent use fastness was obtained. Example 88: When the Qilang wisdom is used, the employees of the 4th Bureau of Labor consume the 阼; the woven fabric of the alkalized viscose ruthenium is smashed to contain 35g/l anhydrous sodium carbonate, 200g/l urea and 150g/l low viscosity algae The sodium citrate solution (6%) was then dried. The wet harvest is 70%: The pretreated fabric thus prepared uses a continuous flow (pressure) inkjet print head and is brushed with an aqueous ink containing the following ingredients: 1 〇 % C. I.  Reactive Red 1 87 15 % Tetramethyl decane-69- This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1278553 A7 ____B7__ V. Description of invention (67 ) Ί % Polyether polyol 6 8 °/〇水 (please read the notes on the back and fill out this page) The print is completely dry. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. Example 89 A woven fabric of an alkalized viscose mash was dried with a liquid containing 35 g/d of anhydrous sodium hydrogencarbonate, 200 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with a water-based ink containing the following ingredients: 1 2 % C. I.  Reactive Blue 2 1 15 °/〇 Tetramethylene alkane 5 °/〇 N-methyl-2-pyrrolidone 17% Polyether polyol 61 % Water Printed by the Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative The printed matter was completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter is further added, warmed and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a blue-green printing having excellent use fastness was obtained. Example Ninety paper scales apply to China National Standard (CNS) A4 specification (210 X 297 mm) 1278553 A7 ___B7____ V. Description of invention (68) (Please read the note on the back and then fill out this page) Commercially available cotton textile The fabric was smeared with a liquid containing 35 g/l of anhydrous sodium hydrogencarbonate, 50 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6 °/.) and dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with aqueous ink containing the following ingredients: 8 % C. I.  Reactive Black 14 1 0 % Tetramethyl ketone 5 % N-methyl-2-pyrrolidone 5 % Polyether polyol 7 2 ° / 〇 Water The print is completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, gray printing with excellent use fastness is obtained. Example 91 Eleventh Department of Economic Affairs Intellectual Property Bureau Employees Consumption Cooperatives Printed cotton fabrics of agricultural and commercial cotton smashed with 35 g / Ι anhydrous sodium bicarbonate, 100 g / l urea and 150 g / l low viscosity sodium alginate solution ( 6%) of the liquid after the mouth to dry. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with aqueous ink containing the following ingredients: 1 2 % C. I.  Reactive Orange 12 20% tetramethylene alkane 8 ° / 〇 polyether polyol This paper scale applies to China National Standard (CNS) A4 specifications (2] 0 X 297 mm) -71 - 1278553 A7 B7 V. Invention Description (69) 60% water (please read the notes on the back and fill out this page) The print is completely dry. It was fixed at 1 〇 2 °C for 8 minutes with saturated steam. Then, the printed matter was further heated and rinsed & washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, golden yellow printing with excellent use fastness was obtained. Example 92 A woven fabric of alkalized viscose yarn was dried with a liquid containing 35 g/l of anhydrous sodium hydrogencarbonate, 200 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with a water-based ink containing the following ingredients: 10% C. I.  Reactive Orange 35 16 ° / 〇 tetramethylene alkane 6 % polyvinyl caprolactam 0. 3 % borane 67. 7 % Water Printed by Qilang Intellectual Property Employee x Consumer Consumed Printed printing is completely dry. At 10 2 t, it was fixed with saturated steam for 8 minutes. Then, the printed matter is further heated and rinsed, and washed with hot water at 95 ° C, and rinsed with warmth. Then dry it. As a result, a brown-orange print having excellent use fastness was obtained. Example 93 Commercial textile fabrics of cotton are smashed to contain 35g/l anhydrous sodium bicarbonate. This paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -72- 1278553 A7 ____B7 V. Invention Description (7〇) 150g / l urea and 150g / l low viscosity sodium alginate solution (6%) of the liquid after the mouth (please read the back of the note before filling this page) to dry. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with aqueous ink containing the following ingredients: 12% C. I.  Reactive Red 218 10% tetramethylene sulphate 10% N-methyl-2-pyrrolidone 5 ° / 聚乙烯 polyvinylpyrrolidone 6 3 % water The print was completely dried. It was fixed at 1 〇 2 °C for 8 minutes using saturated steam. Then, the printed matter was heated and rinsed again. It was subjected to a fast washing treatment with hot water at 95 ° C, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. Example 94 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperatives Printed cotton fabrics for commercial use to contain 35g / l anhydrous sodium bicarbonate, 150g / l pulse and 150g / l low viscosity sodium alginate solution (6% The liquid is then dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with aqueous ink containing the following ingredients: 15% C. I.  Reactive Blue 49 1 0 % Tetramethylnonane 5 % Polyether Polyol 0. 5 % borane This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) -73- 1278553 A7 -----_ V. Invention description (71) 69. 5% water (please read the notes on the back and fill out this page) The printed matter is fully dried by τα. At 10 ° C, it was fixed with saturated steam for 8 minutes. Then, the printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a blue print having excellent use fastness was obtained. Example 95 A woven fabric of cotton for sale was dried with a liquid containing 35 g/l of anhydrous sodium hydrogencarbonate, l〇〇g/l of urea and 150 g/l of a low-viscosity sodium alginate solution (6 %). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with aqueous ink containing the following ingredients: 10% C. I.  Reactive Black 39 18 % tetramethylene alkane 6 % polyether polyol 0. 5 % phosphate buffer 65. 5 % Water Ministry of Economic Affairs Intellectual Property Bureau staff consumption combined with Fi printing The printed matter is completely dry. At 10 2 t, it was fixed with saturated steam for 8 minutes. Then, the printed matter is further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a navy blue print with excellent use fastness is obtained. Example 96 Textile fabrics for commercial cotton are packed to contain 40g/l sodium bicarbonate. This paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 mm). 1278553 A7 _____B7 V. Description of invention (72) --------------- Pack--- (Please read the notes on the back and fill out this page) 100g / l urea and 150g / l low viscosity sodium alginate solution (6% The liquid is then forced to dry. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with aqueous ink containing the following ingredients: 1 5 % C. I.  Reactive Black 5 20 % tetramethylene brothel 6 % polyvinyl caprolactam 0. 3 % modified phosphate 5 8. 7% water The print was completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a navy blue print with excellent use fastness is obtained. Example 97 A woven fabric of cotton for sale was dried with a liquid containing 40 g/l of sodium hydrogencarbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained is used by Qi Qilang Intellectual Property Employee X. Consumables fi-printed Continuous flow (pressure) inkjet printheads, printed with aqueous ink containing the following ingredients: , 6 % C. I.  Reactive Blue 21 5 % C. I.  Reactive Yellow 37 15 ° / 〇 tetramethylene alkane 8 % polyvinylpyrrolidone This paper scale applies to China National Standard (CNS) A4 specifications (210 X 297 mm) -75· 1278553 A7 __B7_ V. Invention Description (73) 0. 5% sodium citrate 65. 5 % water (please read the notes on the back and fill out this page) The print is completely dry. It was fixed at 102 ° C for 8 minutes with saturated steam. Then, the printed matter was further heated and rinsed & washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, green printing with excellent use fastness is obtained. Example 98 A woven fabric of cotton for sale was dried with a liquid containing 35 g/l of anhydrous sodium carbonate '50 g/l of urea and 150 g of 1 of low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) ink jet print head with aqueous ink containing the following ingredients: 8 % C . 1.  Reactive Black 1 2 10 % Tetramethylene alkane 4 % Combined thickener 7 8 °/〇 Water Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperation Du printing The printed matter is completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter is further heated and rinsed, and washed with hot water at 95 ° C, and rinsed with warmth. Then dry it. As a result, gray printing with excellent use fastness is obtained. Example 99 Commercial textile woven cotton fabric with 35g/l anhydrous sodium carbonate' This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) -76- 1278553 A7 B7 V. Description of invention (74) A liquid of 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) was dried. The wet harvest is 70%. The pre-treated fabric thus obtained (please read the note on the back and fill out this page) Continuous flow (pressure) inkjet print head, printed with water-based ink containing the following ingredients: 1 5 % C. I.  Reactive Black 5 0. 8 % C. I.  Reactive Orange 107 0. 2 % C. I.  Reactive Red 1 80 20 % Tetramethyl methoxide 5 ° / 聚 Polypropylene glycol 5 9% Water The print was completely dried. It was fixed at 10 ° C for 8 minutes with saturated steam. Then, the printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, black printing having excellent use fastness is obtained. EXAMPLES A commercial textile woven fabric of cotton was dried with a liquid containing 150 g/l of a low viscosity sodium alginate solution (6%). The wet harvest is 70%. Printed by the Ministry of Economic Affairs, the Intellectual Property Office, and the Consumer Cooperative. The pretreated fabric thus produced uses a drop-on-demand inkjet printhead with the following ingredients. Water-based ink printing: 1 1 % C. I.  Reactive Yellow 37 1 8 °/〇 Tetramethylene alkane 7 1 °/〇 Water The print is completely dry. According to the known technology, the two-phase fixed method-77- paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm). 1278553 A7 --- -B7_ V. Invention description (75 ) (Read first Precautions on the back side Fill in this page) Fix (flash steaming for 20 seconds, 125 °C; short steaming for 90 seconds, 125 °C; cold batch treatment 20 °C -40 °C, 4-12 hours) fixed base: Sodium hydroxide solution / sodium silicate mixture Na2 〇: Si 〇 2 1 : 1. 7-3. 3). The printed matter was further heated and rinsed, washed with hot water at 95 t, heated and rinsed, and then dried. As a result, a yellow print having excellent use fastness is obtained. EXAMPLES ONE A commercial textile fabric of cotton uses d r ο ρ - ο η - d e m a n d (bubble jet) inkjet print head, printed with an aqueous ink containing the following components: 10% C. I.  Reactive Red 1 80 15 % tetramethylene. Styrene 3 % N-methyl-2-pyrrolidone 72 % water The print was completely dried. According to the known technique, it is fixed by two-phase fixation method (flash steaming for 20 seconds, 125 °C; short-time steaming for 90 seconds, 125 °C; cold batch treatment at 20 °C -40 °C, 4-12 hours). Alkali: sodium hydroxide solution / sodium citrate mixture Na2 〇: Si 〇 2 1 : 1. 7-3. 3). This printed matter will be printed by the Intellectual Property Office of the Ministry of Economic Affairs. The employees will cooperate with the printing and heating and rinsing. They will be washed with hot water at 95 °C, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. Example 1-2 Commercially used cotton textile fabrics using drop-on-demand (foam jet paper size applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -78- 1278553 A7 ----- B7__ five , invention description (76)) inkjet print head, printed with an aqueous ink containing the following components: 1 2 % C. I.  Reactive Blue 2 1 16% Tetramethyl Resin (Please read the note on the back and fill out this page) 5 % Butyl Glycol 67% Water The print is completely dry. According to the known technique, fixed by a two-phase fixation method (flash heat for 20 seconds, 125 ° C; short-time steaming for 90 seconds, 125 ° C; cold batch treatment 20 ° C -40 ΐ:, 4-12 hours) : sodium hydroxide solution / sodium citrate mixture Na2 〇: Si〇2 1 : 1. 7-3. 3). The printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a blue-green printing having excellent use fastness was obtained. Example 1-3 A woven fabric of alkalized viscose wadding was dried with a liquid containing 150 g/l of a low viscosity sodium citrate solution (6%). The wet harvest is 7〇%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with an aqueous ink containing the following ingredients: Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative, printed 10% C. I.  Reactive Orange 1 3 15 °/〇 Tetramethylene, 0. 3% borane 7 4. 7 ° / 〇 water

印刷物經完全乾燥。根據已知技術,利用二相固定法 固定(閃蒸蒸熱20秒,125 °C ;短時間蒸熱90秒’ 125 °C 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) ~ 1278553 A7 一 _______B7_ 五、發明說明(77 ) ;冷批處理20 t -4(TC,4-12小時)固定鹼:氫氧化鈉溶 液/矽酸鈉混合物Na2〇:Si〇2 1 : 1.7-3.3 )。此印刷物再 (請先閱讀背面之注意事項再填寫本頁) 加溫漂洗,用熱水在95 °C下堅牢性洗滌處理,加溫漂洗, 然後加以乾燥。 結果獲得具有優異使用堅牢性之橙色印刷。 實例一〇四 經鹼化黏膠絲之紡織織物塡塞以含有1 50g/l低黏度藻 朊酸鈉溶液(6 % )的液體後加以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使用drop-on-demand (壓力) 噴墨印刷頭,用包含以下成分之水性墨水印刷: 8 % C.I. Reactive Black 8 12% 四亞甲基硕烷 4 % 1,2-己二醇 0.3 %經改良磷酸鹽 72 % 水 經濟部智慧財產局員工消費合作社印製 印刷物經完全乾燥。根據已知技術,利用二相固定法 固定(閃蒸蒸熱20秒,125 °C ;短時間蒸熱90秒,125 °C ;冷批處理20Ό -40 °C,4-12小時)固定鹼:氫氧化鈉溶 液/矽酸鈉混合物Na2〇:Si〇2 1、: 1.7-3.3 )。此印刷物再 加溫漂洗,用熱水在95 °C下堅牢性洗滌處理,加溫漂洗, 然後加以乾燥。 結果獲得具有優異使用堅牢性之灰色印刷。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -80- 1278553 A7 ____B7___ 五、發明說明(78 ) 實例一〇五 商售棉花之紡織織物塡塞以含有150g/l低黏度藻朊酸 鈉溶液(6 % )的液體後加以乾燥。潮濕收獲物是70 % 。 (請先閱讀背面之注意事項再填寫本頁) 如此製得之預處理織物使用連續流動(壓力)噴墨印刷頭 ,用包含以下成分之水性墨水印刷: 1 〇 % C.I. Reactive Red 2 1 8 1 0 % 四亞甲基砸烷 5 °/〇 N-甲基-2-吡咯烷酮 2 % 聚丙二醇 7 3 % 水 印刷物經完全乾燥。根據已知技術,利用二相固定法 固定(閃蒸蒸熱20秒,125 °C ;短時間蒸熱90秒,125 °C ;冷批處理20 °C -40 °C,4-12小時)固定鹼:氫氧化鈉溶 液/矽酸鈉混合物Na2〇:Si〇2 1 : 1.7-3.3 )。此印刷物再 加溫漂洗,用熱水在95 °C下堅牢性洗滌處理’加溫漂洗, 然後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 經濟部智慧財產局員X.消費合阼杜印製 實例一◦六 、 商售棉花之紡織織物塡塞以含有1 5Og/Ι低黏度藻朊酸 鈉溶液(6 % )的液體後加以乾燥。潮濕收獲物是70 % 。 如此製得之預處理織物使用連續流動(壓力)噴墨印刷頭 ,用包含以下成分之水性墨水印刷: 1 5 % C.I. Reactive Black 5 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -81 - 1278553 A7 B7 五、發明說明(79 ) 20 % 四亞甲基砸烷 1 0 % 聚醚多元醇 0.3% 檸檬酸鈉 5 4.7% 水 印刷物經完全乾燥。根據已知技術,利用二相固定法 固定(閃蒸蒸熱20秒,125 °C ;短時間蒸熱90秒,125 °C ;冷批處理20 °C -40 °C,4-12小時)固定鹼:氫氧化鈉溶 液/矽酸鈉混合物Na2〇:SiCh 1 : 1.7-3.3 )。此印刷物再 加溫漂洗,用熱水在95 °C下堅牢性洗滌處理,加溫漂洗, 然後加以乾燥。 結果獲得具有優異使用堅牢性之海軍藍色印刷。 實例一〇七 商售棉花之紡織織物塡塞以含有150g/l低黏度藻朊酸 鈉溶液(6 % )的液體後加以乾燥。潮濕收獲物是70 % 。 如此製得之預處理織物使用連續流動(壓力)噴墨印刷頭 ,用包含以下成分之水性墨水印刷: 1 % C.I. Reactive Orange 12 12 % C.I. Reactive Black 39 1 °/〇 C.I. Reactive Red 21S. 20 % 四亞甲基硕烷 5 % 聚乙烯基己內醯胺 61 % 水 印刷物經完全乾燥。根據已知技術,利用二相固定法 -ft?- (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 1278553 A7 B7 五、發明說明(8G)The print was completely dried. According to the known technology, it is fixed by two-phase fixation method (flash steaming for 20 seconds, 125 °C; short-time steaming for 90 seconds' 125 °C. This paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 mm). ~ 1278553 A7 A _______B7_ V. Description of invention (77); cold batch treatment 20 t -4 (TC, 4-12 hours) fixed base: sodium hydroxide solution / sodium citrate mixture Na2 〇: Si 〇 2 1 : 1.7 -3.3). This printed matter (please read the note on the back and fill out this page). Rinse with warm water, wash it with hot water at 95 °C, rinse with warmth, and then dry. As a result, an orange print having excellent use fastness was obtained. Example 1-4 A woven fabric of alkalized viscose wadding was dried with a liquid containing 150 g/l of a low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with an aqueous ink containing the following ingredients: 8 % CI Reactive Black 8 12% tetramethylene olefin 4 % 1,2- Hexanediol 0.3% modified phosphate 72% Water Ministry of Economics Intellectual Property Bureau employee consumption cooperative printed printed matter was completely dried. According to the known technique, it is fixed by two-phase fixation method (flash steaming for 20 seconds, 125 ° C; short-time steaming for 90 seconds, 125 ° C; cold batch treatment 20 Ό -40 ° C, 4-12 hours) to fix the base: hydrogen Sodium oxide solution / sodium citrate mixture Na2 〇: Si 〇 2 1 :: 1.7-3.3 ). The printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, gray printing with excellent use fastness is obtained. This paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -80- 1278553 A7 ____B7___ V. Invention description (78) Example 1-5 Commercial textile fabric woven with 150g/l low The liquid of the viscosity sodium alginate solution (6%) was dried. The wet harvest is 70%. (Please read the note on the back and fill out this page.) The pretreated fabric thus prepared uses a continuous flow (pressure) inkjet printhead and is printed with an aqueous ink containing the following ingredients: 1 〇% CI Reactive Red 2 1 8 1 0% tetramethylene decane 5 ° / 〇 N-methyl-2-pyrrolidone 2 % polypropylene glycol 7 3 % water prints were completely dried. According to the known technique, fixed by a two-phase fixation method (flash heat for 20 seconds, 125 ° C; short-time steaming for 90 seconds, 125 ° C; cold batch treatment at 20 ° C -40 ° C, 4-12 hours) : sodium hydroxide solution / sodium citrate mixture Na2 〇: Si 〇 2 1 : 1.7-3.3 ). The print was further tempered and rinsed with hot water at 95 ° C for 'fast rinsing' and then dried. As a result, red printing with excellent use fastness was obtained. Ministry of Economic Affairs Intellectual Property Officer X. Consumption of Du Fu Printing Example 1-6. Commercial textile fabrics of cotton are smeared with a liquid containing 150 g/s low viscosity sodium alginate solution (6%) and dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) inkjet printhead with an aqueous ink containing the following ingredients: 1 5 % CI Reactive Black 5 This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297) -81 - 1278553 A7 B7 V. INSTRUCTIONS (79) 20 % Tetramethyl decane 10% Polyether polyol 0.3% Sodium citrate 5 4.7% The water print is completely dried. According to the known technique, fixed by a two-phase fixation method (flash heat for 20 seconds, 125 ° C; short-time steaming for 90 seconds, 125 ° C; cold batch treatment at 20 ° C -40 ° C, 4-12 hours) : sodium hydroxide solution / sodium citrate mixture Na2 〇: SiCh 1 : 1.7-3.3 ). The printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a navy blue print with excellent use fastness is obtained. Example 177 A woven fabric of cotton for sale was dried with a liquid containing 150 g/l of a low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus prepared was printed using a continuous flow (pressure) inkjet printhead with an aqueous ink containing the following ingredients: 1% CI Reactive Orange 12 12 % CI Reactive Black 39 1 °/〇CI Reactive Red 21S. 20 % Tetramethylidene 5% 5% polyvinyl caprolactam 61% water prints were completely dried. According to the known technology, the two-phase fixed method - ft?- (please read the back note first and then fill out this page) This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1278553 A7 B7 , invention description (8G)

固定(閃蒸蒸熱20秒,125 °C ;短時間蒸熱90秒’ 125 °C (請先閱讀背面之注意事項再填寫本頁) ;冷批處理20 °C -40 °C,4-12小時)固定鹼:氫氧化鈉溶 液/矽酸鈉混合物Na2〇:Si〇2 1 : 1.7-3.3 )。此印刷物再 加溫漂洗,用熱水在95 °C下堅牢性洗滌處理’加溫漂洗’ 然後加以乾燥。 結果獲得具有優異使用堅牢性之黑色印刷。 實例一〇八 商售棉花之紡織織物塡塞以含有150g/l低黏度藻朊酸 鈉溶液(6 % )的液體後加以乾燥。潮濕收獲物是70 % 。 如此製得之預處理織物使用連續流動(壓力)噴墨印刷頭 ,用包含以下成分之水性墨水印刷: 10 % C.I. Reactive Red 239 12 °/〇 四亞甲基砸烷 3 % 1,2-己二醇 0.3 % 檸檬酸鈉 5 4.7% 水 經濟部智慧財產局員工消費合作杜印製 印刷物經完全乾燥。根據已知技術,利用二相固定法 固定(閃蒸蒸熱20秒,125 °C ;短時間蒸熱90秒,125 °C ;冷批處理20 °C -40 °C,4-12小.時)固定鹼:氫氧化鈉溶 液/矽酸鈉混合物Na2〇:Si〇2 1 : 1.7-3.3 )。此印刷物再 加溫漂洗,用熱水在95 °C下堅牢性洗滌處理,加溫漂洗, 然後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -83- 1278553 A7 B7 五、發明說明(81 ) 實例一〇九 商售棉花之紡織織物塡塞以含有80g/l三氯乙酸鈉和 150g/l脲的液體後加以乾燥。潮濕收獲物是70 % 。如此製 得之預處理織物使用drop-on-demand (泡沫噴射)噴墨印 刷頭,用包含以下成分之水性墨水印刷: 1 1 % C.I. Reactive Yellow 42 1 2 % 四亞甲基硕烷 7 7 °/〇 水 印刷物經完全乾燥。利用飽和蒸氣,在1 02 °C下固定 1 0分鐘。此印刷物再加溫漂洗,用熱水在95 °C下堅牢性洗 滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之黃色印刷。 實例——〇 商售棉花之紡織織物塡塞以含有80g/l三氯乙酸鈉和 150g/l脲的液體後加以乾燥。潮濕收獲物是70 % 。如此製 得之預處理織物使用drop-on·demand (泡沫噴射)噴墨印 刷頭,用包含以下成分之水性墨水印刷: 8 % C.I. Reactive Orange 16 12 % 四亞甲基硕烷 6 °/〇 N-甲基-2-吼咯烷酮 74 % 水 印刷物經完全乾燥。利用飽和蒸氣,在1 02 °C下固定 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) II---------lt·II (請先閱讀背面之注意事項再填寫本頁) . · 陘齊邨智慧时產局員工消費^阼达印製 -84- 經齊即智慧时i局員1.消費^阼^印製 1278553 A7 ___B7_____ 五、發明說明(82 ) 1 0分鐘。此印刷物再加溫漂洗’用熱水在9 5 °c下堅牢性洗 滌處理’加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之橙色印刷。 實例---- 商售棉花之紡織織物塡塞以含有80g/l三氯乙酸鈉和 150g/l脲的液體後加以乾燥。潮濕收獲物是70 % 。如此製 得之預處理織物使用dr〇P-〇n-demand (壓力)噴墨印刷頭 ,用包含以下成分之水性墨水印刷: 8 % C.I. Reactive Black 14 12 °/〇 四亞甲基砸烷 4 °/〇 丁基二丁醇 0.5 %經改良磷酸鹽 7 5.5 % 水 印刷物經完全乾燥。利用飽和蒸氣,在1 02 °c下固定 1 0分鐘。此印刷物再加溫漂洗,用熱水在95 °C下堅牢性洗 滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之灰色印刷。 實例一一二 、 經鹼化黏膠絲之紡織織物塡塞以含有8〇g/l三氯乙酸鈉 和1 50g/l脲的液體後加以乾燥。潮濕收獲物是70 % 。如此 製得之預處理織物使用ckop-on-demand (壓力)噴墨印刷 頭,用包含以下成分之水性墨水印刷: (請先閱讀背面之注意事項再填寫本頁) 裝 訂: 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -RFi - 1278553 A7 B7 五、發明說明(83) 9 % C.I. Reactive Red 198 15 % 四亞甲基硕烷 0.3% 檸檬酸鈉 7 5.7% 水 印刷物經完全乾燥。利用飽和蒸氣,在1 02 °C下固定 1 0分鐘。此印刷物再加溫漂洗,用熱水在95 °C下堅牢性洗 滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例——三 經漂白亞麻之紡織織物塡塞以含有80g/l三氯乙酸鈉, 150g/l脲的液體以及含150g/l低黏度藻朊酸鈉溶液(5% ) 的液體後加以乾燥。潮濕收獲物是70 % 。如此製得之預處 理織物使用d r ο ρ - ο η - d e m a n d (壓力)噴墨印刷頭,用包含 以下成分之水性墨水印刷: 1 1 % C.I. Reactive Orange 13 15 % 四亞甲基硕烷 5 °/〇 N-甲基-2-吼咯烷酮 0.05 % 非離子性界面活性劑 6 8.9 5 % 水 ' 印刷物經完全乾燥。利用飽和蒸氣,在1 02 t下固定 1 0分-。此印刷物再加溫漂洗,用熱水在95 °C下堅牢性洗 滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之橙色印刷。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) ---------------裝--- (請先閱讀背面之注意事項再填寫本頁) 訂·Fixed (flash steaming for 20 seconds, 125 °C; short steaming for 90 seconds '125 °C (please read the back note before filling this page); cold batch 20 °C -40 °C, 4-12 hours ) Fixed base: sodium hydroxide solution / sodium citrate mixture Na2 〇: Si 〇 2 1 : 1.7-3.3 ). The print was further tempered and rinsed with hot water at 95 ° C for 'warm rinse' followed by drying. As a result, black printing having excellent use fastness is obtained. Example 138 A woven fabric of cotton for sale was dried with a liquid containing 150 g/l of a low viscosity sodium alginate solution (6%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) inkjet printhead with an aqueous ink containing the following ingredients: 10% CI Reactive Red 239 12 ° / 〇 tetramethylene decane 3 % 1,2-hex Glycol 0.3% Sodium citrate 5 4.7% The Department of Water Economics Intellectual Property Bureau employees collaborate with the printed printed matter completely dried. According to the known technique, it is fixed by two-phase fixation method (flash steaming for 20 seconds, 125 °C; short-time steaming for 90 seconds, 125 °C; cold batch treatment of 20 °C -40 °C, 4-12 hours.) Fixing base: sodium hydroxide solution / sodium citrate mixture Na2 〇: Si 〇 2 1 : 1.7-3.3 ). The printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) -83- 1278553 A7 B7 V. Description of invention (81) Example 〇 商 Commercial cotton fabric woven with 80g/l A liquid of sodium chloroacetate and 150 g/l of urea is dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with an aqueous ink containing the following ingredients: 1 1 % CI Reactive Yellow 42 1 2 % tetramethylene sulane 7 7 ° /Water-repellent prints are completely dry. It was fixed at 10 ° C for 10 minutes using saturated steam. The printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a yellow print having excellent use fastness is obtained. Example - 纺织 Commercially available cotton woven fabric was dried with a liquid containing 80 g/l of sodium trichloroacetate and 150 g/l of urea. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on·demand ink jet print head with an aqueous ink containing the following ingredients: 8 % CI Reactive Orange 16 12 % tetramethylene olefin 6 ° / 〇 N -Methyl-2-pyrrolidone 74% water print was completely dried. Use saturated steam to fix the paper at 10 ° C. Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) II---------lt·II (Please read the back of the note first) Please fill in this page again. · 陉Qi Village Wisdom Bureau of Production Bureau staff consumption ^阼达印-84- Jing Qi is wisdom when i board member 1. Consumption ^阼^Printed 1278553 A7 ___B7_____ V. Description of invention (82) 10 minutes. The print was then warmed and rinsed & 'removed by hot water at 95 ° C.', heated and rinsed, and then dried. As a result, an orange print having excellent use fastness was obtained. EXAMPLES - A woven fabric of cotton for sale was dried with a liquid containing 80 g/l of sodium trichloroacetate and 150 g/l of urea. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a dr〇P-〇n-demand (pressure) inkjet print head with an aqueous ink containing the following ingredients: 8 % CI Reactive Black 14 12 ° / 〇 tetramethylene decane 4 ° / 〇 butyl dibutanol 0.5 % modified phosphate 7 5.5 % water prints were completely dried. Using a saturated vapor, it was fixed at 10 ° C for 10 minutes. The printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, gray printing with excellent use fastness is obtained. Example 1-2. A woven fabric of alkalized viscose wadding was dried with a liquid containing 8 g/l of sodium trichloroacetate and 1 50 g/l of urea. The wet harvest is 70%. The pretreated fabric thus obtained is printed using a ckop-on-demand inkjet printhead with an aqueous ink containing the following ingredients: (Please read the note on the back and fill out this page) Binding: This paper size applies to China National Standard (CNS) A4 Specification (210 X 297 mm) -RFi - 1278553 A7 B7 V. Description of Invention (83) 9 % CI Reactive Red 198 15 % Tetramethylidene 0.3% Sodium Citrate 7 5.7% Water The print was completely dried. It was fixed at 10 ° C for 10 minutes using saturated steam. The printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. EXAMPLES - Three woven fabrics of bleached linen were dried with a liquid containing 80 g/l sodium trichloroacetate, 150 g/l urea and a liquid containing 150 g/l low viscosity sodium alginate solution (5%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a dr ο ρ - ο η - demand (pressure) inkjet print head with an aqueous ink containing the following ingredients: 1 1 % CI Reactive Orange 13 15 % tetramethylene olefin 5 ° /〇N-Methyl-2-pyrrolidone 0.05% Nonionic surfactant 6 8.9 5 % Water' The print was completely dried. With saturated steam, fixed at 10 ° - at 10 2 t. The printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, an orange print having excellent use fastness was obtained. This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) --------------- Pack--- (Please read the notes on the back and fill out this page. ) Booking ·

.P -86- 經濟部智慧財產局員工消費合作杜印製 1278553 A7 _B7__ 五、發明說明(84 ) 實例一^ 一*四 經鹼化黏膠絲之紡織織物塡塞以含有80g/l三氯乙酸鈉 ,150g/l脲的液體以及含150g/l低黏度藻朊酸鈉溶液(5% )後加以乾燥。潮濕收獲物是7〇 % 。如此製得之預處理織 物使用連續流動(壓力)噴墨印刷頭,用包含以下成分之 水性墨水印刷: 1 3 % C.I. Reactive Orange 74 10% 四亞甲基®烷 5 °/〇 丁基二甘醇 7 2 °/〇 水 印刷物經完全乾燥。利用飽和蒸氣,在1 02 t下固定 1 0分鐘。此印刷物再加溫漂洗,用熱水在95 °C下堅牢性洗 滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之橙色印刷。 實例一一五 經鹼化黏膠絲之紡織織物塡塞以含有80g/l三氯乙酸鈉 ,150g/l脲的液體以及含150g/l低黏度藻朊酸鈉溶液(5 % )後加以乾燥。潮濕收獲物是70 % 。如此製得之預處理織 物使用連續流動(壓力)噴墨印刷頭,用包含以下成分之 水性墨水印刷: 1 4 % C.I. Reactive Blue 1 9 1 5 % 四亞甲基硕院 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁) 裝 -87- 經濟部智慧財產局員工消費合作社印製 1278553 A7 ___B7____ 五、發明說明(85 ) 0.05% 非離子性界面活性劑 0.15 % 經改良磷酸鹽 7 0.8% 水 印刷物經完全乾燥。利用飽和蒸氣’在1 02 °c下固定 1 0分鐘。此印刷物再加溫漂洗’用熱水在95 °c下堅牢性洗 滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之藍色印刷。 實例--六 市售棉花之紡織織物塡塞以含有80g/l三氯乙酸鈉, 50g/l脲的液體以及含150g/l低黏度藻朊酸鈉溶液(5% ) 後加以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物 使用連續流動(壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 1 0 % C.I. Reactive Blue 229 12 % 四亞甲基硕烷 6 % N-甲基-2-吡咯烷酮 6 % 聚醚多元醇 66 % 水 印刷物經完全乾燥。利用飽、.和蒸氣,在102 °C下固定 1 0分鐘。此印刷物再加溫漂洗,用熱水在95 °C下堅牢性洗 滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之海軍藍色印刷。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) •--------I I I I I --- (請先閱讀背面之注咅?事項再填寫本頁) · 1278553 A7 B7 五、發明說明(86) 實例——七 經漂白亞麻之紡織織物塡塞以含有80g/l三氯乙酸鈉, 100g/l脲的液體以及含150g/l低黏度藻朊酸鈉溶液(5% ) 後加以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物 使用連續流動(壓力)噴墨印刷頭,用包含以下成分之水 性墨水印刷: 1 4 % C.I. Reactive Red 1 87 16 °/〇 四亞甲基碾烷 4 °/〇 1,2-己二醇 6 °/〇 聚乙烯基己內醯胺 60% 水 印刷物經完全乾燥。利用飽和蒸氣,在1 02 °C下固定 1 〇分鐘。此印刷物再加溫漂洗,用熱水在95 °C下堅牢性洗 滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例——八 商售棉花之紡織織物塡塞以含有3 5 g /1無水碳酸鈉’ 100g/l脲的液體以及含150g/l低黏度藻朊酸鈉溶液(6% ) 後加以乾燥。潮濕收獲物是70 。如此製得之預處理織物 使用drop-on-demand (泡沫噴射)噴墨印刷頭,用包含以 下成分之水性墨水印刷: 9 % C.I. Reactive Yellow 85 15 % 四亞甲基砸烷 -RQ - (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 1278553 A7 _____B7__ 五、發明說明(87 ) 5 % N-甲基-2-吡咯烷酮 7 1 % 水 (請先閱讀背面之注咅?事項再填寫本頁} 印刷物經完全乾燥。利用飽和蒸氣,在1 02 t下固定 1 0分鐘。此印刷物再加溫漂洗,用熱水在95 °C下堅牢性洗 滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之黃色印刷。 實例一一九 商售棉花之紡織織物塡塞以含有35g/l碳酸氫鈉和 25Og/Ι脲的液體後加以乾燥。潮濕收獲物是70 % 。如此製 得之預處理織物使用drop-on-demand (泡沬噴射)噴墨印 刷頭,用包含以下成分之水性墨水印刷: 1 2 % C.I. Reactive Orange 1 8 1 15 % 四亞甲基硕烷.P -86- Ministry of Economic Affairs Intellectual Property Bureau Staff Consumption Cooperation Du Printing 1278553 A7 _B7__ V. Invention Description (84) Example 1 ^ 1 * Four alkalized viscose woven fabric woven with 80g / l trichloro Sodium acetate, 150 g/l urea liquid and 150 g/l low viscosity sodium alginate solution (5%) were dried. The wet harvest is 7〇%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) inkjet printhead with an aqueous ink containing the following ingredients: 1 3 % CI Reactive Orange 74 10% tetramethylene® alkane 5 ° / butyl butyl gan The alcohol 7 2 °/hydrophobic print was completely dried. It was fixed at 10 2 ° for 10 minutes using saturated steam. The printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, an orange print having excellent use fastness was obtained. Example 1-5. The woven fabric of the alkalized viscose tampon is dried with a liquid containing 80 g/l of sodium trichloroacetate, 150 g/l of urea and a solution of 150 g/l of low viscosity sodium alginate (5 %). . The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) inkjet print head with an aqueous ink containing the following ingredients: 1 4 % CI Reactive Blue 1 9 1 5 % Tetramethyl syllabus This paper scale applies to China Standard (CNS) A4 specification (210 X 297 mm) (Please read the note on the back and fill out this page) Pack-87- Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed 1278553 A7 ___B7____ V. Invention Description (85) 0.05% nonionic surfactant 0.15 % modified phosphate 7 0.8% water print was completely dried. It was fixed at 10 ° C for 10 minutes using saturated vapor'. The print was then re-warmed and washed with hot water at 95 ° C, rinsed with warmth, and then dried. As a result, a blue print having excellent use fastness was obtained. EXAMPLES - Six commercially available cotton woven fabrics were dried with a liquid containing 80 g/l sodium trichloroacetate, 50 g/l urea and a solution of 150 g/l low viscosity sodium alginate solution (5%). The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) inkjet print head with an aqueous ink containing the following ingredients: 10% CI Reactive Blue 229 12% tetramethylene olefin 6 % N-methyl-2 - Pyrrolidone 6% Polyether polyol 66% Water prints are completely dried. The mixture was fixed at 102 ° C for 10 minutes using satiety, and steam. The printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a navy blue print with excellent use fastness is obtained. This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) •--------IIIII --- (Please read the back note? Please fill out this page) · 1278553 A7 B7 V. INSTRUCTIONS (86) EXAMPLES - Seven bleached linen textile fabrics are plugged with a liquid containing 80 g/l sodium trichloroacetate, 100 g/l urea and a solution containing 150 g/l low viscosity sodium alginate (5) %) and then dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) inkjet printhead with an aqueous ink containing the following ingredients: 1 4 % CI Reactive Red 1 87 16 ° / 〇 tetramethylene milling 4 ° / 〇 1 , 2-hexanediol 6 ° / 〇 polyvinyl caprolactam 60% water prints were completely dried. Use saturated steam and fix at 1 02 °C for 1 〇 minutes. The printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. EXAMPLES - Eight Commercially woven cotton fabrics were smeared with a liquid containing 35 g / 1 anhydrous sodium carbonate '100 g / l urea and 150 g / l low viscosity sodium alginate solution (6%) and dried. The wet harvest is 70. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet printhead with an aqueous ink containing the following ingredients: 9 % CI Reactive Yellow 85 15 % tetramethylene decane-RQ - (please Read the notes on the back and fill out this page.) The paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm). 1278553 A7 _____B7__ V. Description of the invention (87) 5 % N-methyl-2-pyrrolidone 7 1 % water (please read the note on the back first? Then fill out this page) The print is completely dried. Use saturated steam and fix it at 10 2 for 10 minutes. This print is then warmed and rinsed with hot water at 95. Fast washing at °C, rinsing with warming, and then drying. The result is a yellow printing with excellent fastness of use. Example 119 Commercial textile woven fabric of cotton with 35g / l sodium bicarbonate and 25Og / The urea vapor was dried and the wet harvest was 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with an aqueous ink containing the following ingredients: 1 2 % CI Reactiv e Orange 1 8 1 15 % tetramethylene alkane

5 % N -甲基· 2 -卩比略院酮I 6 8 % 水 睡齊郎智慧时產咼員X-消費合阼Fi印製 印刷物經完全乾燥。利用飽和蒸氣,在1 50.°C下固定 3-5分鐘。此印刷物再加溫漂洗,用熱水在95 °C下堅牢性 洗滌處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅韦性之金黃色印刷。 實例一二〇 經鹼化黏膠絲之紡織織物塡塞以含有35g/l無水碳酸鈉 ,100g/l脲的液體以及含150g/l低黏度藻朊酸鈉溶液(6 % 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -90- 1278553 A7 ___B7___ 五、發明說明(88 ) )後加以乾燥。潮濕收獲物是70 % 。如此製得之預處理織 物使用drop-on-demand (泡沬噴射)噴墨印刷頭,用包含 以下成分之水性墨水印刷: 1 2 % C.I. Reactive Red 31 12 % 四亞甲基砸烷 7 6 % 水 印刷物經完全乾燥。利用飽和蒸氣,在1 02 t下固定8 分鐘。此印刷物再加溫漂洗,用熱水在95 °C下堅牢性洗滌 處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例一二一 商售棉花之紡織織物塡塞以含有30g/l無水碳酸鈉和 100g/l脲的液體後加以乾燥。潮濕收獲物是70 % 。如此製 得之預處理織物使用drop-on-demand (壓力)噴墨印刷頭 ,用包含以下成分之水性墨水印刷: 10 % C.I. Reactive Red 3 ·· 1 15 % 四亞甲基碾烷 4 % 丁基二甘醇 0.5 °/〇 硼烷 70.5 % ;水 印刷物經完全乾燥。利用飽和蒸氣,在1 02 °C下固定8 分鐘。此印刷物再加溫漂洗,用熱水在9 5 °C下堅牢性洗滌 處理,加溫漂洗,然後加以乾燥。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) ---------------裝--- (請先閱讀背面之注意事項再填寫本頁) -91 - 1278553 A7 B7 五、發明說明(89) 4結果獲得具有優異使用堅牢性之紅色印刷。 經漂白亞麻之紡織織物塡塞以含有35g/Ι無水碳酸鈉和 1 5Og/Ι脲的液體後加以乾燥。潮濕收獲物是70 % 。如此製 得之預處理織物使用drop-on-demand (壓力)噴墨印刷頭 ,用包含以下成分之水性墨水印刷: 1 2 % C.I. Reactive Red 245 12 % 四亞甲基砸烷 4 °/〇 1,2 -己二醇 0.3°/。 硼烷 7 1.7% 水 印刷物經完全乾燥。利用飽和蒸氣,在1 02 t下固定8 分鐘。此印刷物再加溫漂洗,用熱水在95 °C下堅牢性洗滌 處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之紅色印刷。 實例一二三 經鹼化黏膠絲之紡織織物塡塞以含有35g/l無水碳酸鈉 和200g/l脲的液體後加以乾燥。潮濕收獲物是70 % 。如此 製得之預處理織物使用連續流動(壓力)噴墨印刷頭,用 包含以下成分之水性墨水印刷: 10 % C.I. Reactive Red 3 : 1 15 % 四亞甲基硕烷 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) ---r-----------裝--- (請先閱讀背面之注音心事項再填寫本頁) · -92- 齊 ί § 五 1278553 A7 一 —___B7 _ 五、發明說明(9〇 ) 4 % 丁基二甘醇 0.5% 棚院 7 0.5% 水 印刷物經完全乾燥。利用飽和蒸氣,在1 02 °C下固定8 分鐘。此印刷物再加溫漂洗,用熱水在9 5 °C下堅牢性洗滌 處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之藍綠色印刷。 實例一二四 經鹼化黏膠絲之紡織織物塡塞以含有3Og/l無水碳酸鈉 和1 80g/l脲的液體後加以乾燥。潮濕收獲物是70 % 。如此 製得之預處理織物使用連續流動(壓力)噴墨印刷頭,用 包含以下成分之水性墨水印刷: 1 2 % C.I. Reactive Blue 13 15 % 四亞甲基硕烷 5 °/〇 聚丙二醇 0.3 % 硼烷 61.1 % 水 印刷物經完全乾燥。利用飽和蒸氣,在1 02 °C下固定8 分鐘。此印刷物再加溫漂洗,甩熱水在95 t下堅牢性洗滌 處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之海軍藍色印刷。 實 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) --------------裝--- (請先閱讀背面之注意事項再填寫本頁) 訂: -93- 1278553 A7 ___Β7___ 五、發明說明(91 ) (請先閱讀背面之注意事項再填寫本頁) 經鹼化黏膠絲之紡織織物塡塞以含有30g/l無水碳酸鈉 ,100g/l脲和150g/l低黏度藻朊酸鈉溶液(6% )的液體後 加以乾燥。潮濕收獲物是70 % 。如此製得之預處理織物使 用drop-on-demand (壓力)噴墨印刷頭,用包含以下成分 之水性墨水印刷: 9 % C.I. Reactive Violet 1 20 °/〇 四亞甲基砸烷 035 % 硼烷 7 0.7% 水 印刷物經完全乾燥。利用飽和蒸氣,在1 02 °C下固定8 分鐘。此印刷物再加溫漂洗,用熱水在95 °C下堅牢性洗滌 處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之紫色印刷。 實例一二六 經鹼化黏膠絲之紡織織物塡塞以含有35g/Ι碳酸鈉和 25 0g/l脲的液體後加以乾燥。潮濕收獲物是70 % 。如此製 經濟部智慧財產局員工消費合作fi印製 得之預處理織物使用連續流動(壓力)噴墨印刷頭,用包 含以下成分之水性墨水印刷: 1 2 % C.I. Reactive Blue 23,4 10 °/〇 四亞甲基砸烷 8 % 丁基二甘醇 0.3 % 硼烷 69.7 °/〇 水 -Qd - 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 1278553 A7 B7五、發明說明(92 ) 印刷物經完全乾燥。利用飽和蒸氣,在1 02 °C下固定8 分鐘。此印刷物再加溫漂洗,用熱水在95 °C下堅牢性洗滌 處理,加溫漂洗,然後加以乾燥。 結果獲得具有優異使用堅牢性之海軍藍色印刷。 (請先閱讀背面之注意事項再填寫本頁) !· 裝 訂. 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -95-5 % N-methyl· 2 -indole ketone I 6 8 % water Sleeping Qilang Wisdom 咼X-consumer 阼Fi printing The print is completely dry. It is fixed at 1 50 ° C for 3-5 minutes using saturated steam. The printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a golden yellow printing having excellent use of the firmness was obtained. Example 1 〇 woven fabric of alkalized viscose crepe with a liquid containing 35g / l anhydrous sodium carbonate, 100g / l urea and 150g / l low viscosity sodium alginate solution (6 % of this paper scale for China) National Standard (CNS) A4 specification (210 X 297 mm) -90- 1278553 A7 ___B7___ V. Invention description (88)) and then dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with an aqueous ink containing the following ingredients: 1 2 % CI Reactive Red 31 12 % tetramethylene decane 7 6 % The water print is completely dried. With saturated steam, fix at 8 02 t for 8 minutes. The printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. Example 1-2 A woven fabric of cotton for sale was dried with a liquid containing 30 g/l of anhydrous sodium carbonate and 100 g/l of urea. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with an aqueous ink containing the following ingredients: 10% CI Reactive Red 3 ·· 1 15 % tetramethylene-millane 4 % The bisglycol 0.5 ° / borane borane 70.5 %; the water print was completely dried. With saturated steam, fix at 8 ° C for 8 minutes. The printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) --------------- Pack--- (Please read the notes on the back and fill out this page. ) -91 - 1278553 A7 B7 V. INSTRUCTIONS (89) 4 The result is red printing with excellent use fastness. The bleached linen woven fabric was dried with a liquid containing 35 g/t anhydrous sodium carbonate and 150 g/niobium urea. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with an aqueous ink containing the following ingredients: 1 2 % CI Reactive Red 245 12 % tetramethylene decane 4 ° / 〇 1 , 2 - hexanediol 0.3 ° /. Borane 7 1.7% Water The print was completely dried. With saturated steam, fix at 8 02 t for 8 minutes. The printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, red printing with excellent use fastness was obtained. Example 138 The woven fabric of the alkalized viscose mash was dried with a liquid containing 35 g/l of anhydrous sodium carbonate and 200 g/l of urea. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) inkjet print head with an aqueous ink containing the following ingredients: 10 % CI Reactive Red 3 : 1 15 % Tetramethyl sulane This paper scale applies to Chinese national standards. (CNS) A4 size (210 X 297 mm) ---r----------- Pack--- (Please read the note on the back of the note and fill out this page) · -92- Qi ί § 51275853 A7 I—___B7 _ V. Description of invention (9〇) 4% Butyl diglycol 0.5% shed 7 0.5% Water prints are completely dried. With saturated steam, fix at 8 ° C for 8 minutes. The printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a blue-green printing having excellent use fastness was obtained. Example 142 A woven fabric of alkalized viscose wadding was dried with a liquid containing 3Og/l of anhydrous sodium carbonate and 1800 g/l of urea. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a continuous flow (pressure) inkjet printhead with an aqueous ink containing the following ingredients: 1 2 % CI Reactive Blue 13 15 % tetramethylene olefin 5 ° / 〇 polypropylene glycol 0.3 % The borane 61.1% water print was completely dried. With saturated steam, fix at 8 ° C for 8 minutes. The printed matter was further heated and rinsed, and the hot water was washed in a strong manner at 95 t, heated and rinsed, and then dried. As a result, a navy blue print with excellent use fastness is obtained. The actual paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) --------------Installation --- (Please read the notes on the back and fill out this page. ) Order: -93- 1278553 A7 ___Β7___ V. Description of invention (91) (Please read the note on the back and fill out this page) The woven fabric of alkalized viscose is smeared with 30g/l anhydrous sodium carbonate, 100g / l urea and 150 g / l low viscosity sodium alginate solution (6%) of the liquid and then dried. The wet harvest is 70%. The pretreated fabric thus obtained was printed using a drop-on-demand inkjet print head with an aqueous ink containing the following ingredients: 9 % CI Reactive Violet 1 20 ° / 〇 tetramethylene decane 05% borane 7 0.7% water prints are completely dried. With saturated steam, fix at 8 ° C for 8 minutes. The printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a purple print having excellent use fastness is obtained. Example 126 A woven fabric of alkalized viscose wadding was dried with a liquid containing 35 g/Ι sodium carbonate and 25 0 g/l urea. The wet harvest is 70%. The pre-processed fabric printed by the Ministry of Economic Affairs' Intellectual Property Office employee consumption cooperation uses a continuous flow (pressure) inkjet print head printed with an aqueous ink containing the following components: 1 2 % CI Reactive Blue 23,4 10 °/ 〇tetramethylene decane 8% butyl diglycol 0.3% borane 69.7 ° / hydrazine - Qd - This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1278553 A7 B7 V. Description of the invention (92) The print is completely dried. With saturated steam, fix at 8 ° C for 8 minutes. The printed matter was further heated and rinsed, washed with hot water at 95 ° C, heated and rinsed, and then dried. As a result, a navy blue print with excellent use fastness is obtained. (Please read the notes on the back and fill out this page) !· Binding. This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) -95-

Claims (1)

經濟部智慧財產局員工消費合作社印製 六、申請專利範圍 —一險.,3 A :第9 〇 1 0 2 0 7 2號專利申請案 ·:;- 中文申請專利範圍替換本 —..民國92年6月12日修正 1 · 一種水性之織物用噴墨印刷墨水,其包含一或多種 反應性染料,一種非爲硫二甘醇之有機溶劑,不含羥基醯胺 之四亞甲基硕烷,和一緩衝系統,且當一或多種該反應性染 料具有乙烯基硕系之反應系統時,其pH値不大於7 · 0。 2 ·如申請專利範圍第1項之印刷墨水,其包含_數量爲 0 . 0 1 - 4 0重量百分比〔以前述墨水總重量爲基準〕的一 或多種反應性染料。 3 ·如申請專利範圍第1項之印刷墨水,其包含數量爲 1 - 3 0重量百分比〔以前述墨水總重量爲基準〕的四亞甲 基硕院。 4 ·如申請專利範圍第1項之印刷墨水,其包含數量爲 1 - 2 0重量百分比〔以前述墨水總重量爲基準〕的有機溶 劑。 5 ·如申請專利範圍第1項之印刷墨水,其包含具有單 氛二嗪系反應系統之·~或多種反應性染料。 6 ·如申請專利範圍第5項之印刷墨水,其藉由加入緩 衝系統以調整至ρ Η値爲7 . 〇 — 9 ·〇。 7 ·如申請專利範圍第1項之印刷墨水,其包含具有乙 烯基硕系反應系統之〜或多種反應性染料。 8 ·如申請專利範圍第7項之印刷墨水,其藉由加入緩 本紙張尺度適用中國國家標準(CNS ) Α4規格(21〇><297公嫠 (請先閱讀背面之注意事項再填寫本頁)Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperatives, Printing VI, Applying for Patent Scope - One Insurance., 3 A: No. 9 〇1 0 2 0 7 2 Patent Application·:;- Chinese Patent Application Scope Replacement -.. Republic of China Amendment June 12, 1992 1 · An aqueous inkjet printing ink comprising one or more reactive dyes, an organic solvent other than thiodiglycol, and no tetramethylene hydroxyguanamine An alkane, and a buffer system, and when one or more of the reactive dyes have a vinyl system, the pH is not more than 7.5. 2) The printing ink of claim 1, which comprises one or more reactive dyes in an amount of from 0.01 to 40% by weight based on the total weight of the ink. 3. A printing ink according to item 1 of the patent application, which comprises a quantity of 1 - 30% by weight based on the total weight of the ink described above. 4. The printing ink according to claim 1 of the patent application, which comprises an organic solvent in an amount of from 1 to 20% by weight based on the total weight of the ink. 5. The printing ink according to the first aspect of the patent application, which comprises a reactive dye having a mono-diazine-based reaction system. 6 · As in the printing ink of claim 5, it is adjusted to ρ Η値 by adding a buffer system to 7. 〇 — 9 · 〇. 7. The printing ink of claim 1, which comprises ~ or more reactive dyes having a vinyl system. 8 · If you apply for the printing ink of item 7 of the patent scope, it is applicable to the Chinese National Standard (CNS) Α4 specification by adding the paper size. (21〇><297 嫠 (please read the notes on the back and fill in the form) This page) 1278553 A8 B8 C8 D8 六、申請專利範圍 衝系統以調整至Ρ Η値爲3 . 0 — 7 ·〇。 9 . 一種用以製造如申請專利範圍第1至8項中任一項 之印刷墨水的方法,其係藉由混合各成分而得。. 1 〇 .如申請專利範圍第1至8項中任一項之印刷墨7jC ,可用於對織物印刷之噴墨方法中。 (請先閱讀背面之注意事項再填寫本頁) 、τ 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -2 -1278553 A8 B8 C8 D8 VI. Patent application scope The system is adjusted to Ρ 3 to 3. 0 — 7 · 〇. A method for producing a printing ink according to any one of claims 1 to 8, which is obtained by mixing the components. The printing ink 7jC of any one of claims 1 to 8 can be used in an ink jet method for printing a fabric. (Please read the note on the back and then fill out this page), τ Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative Printed This paper scale applies to China National Standard (CNS) A4 specification (210X297 mm) -2 -
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