CN1292122C

CN1292122C - Aqueous printing inks for use in ink-jet printing method prodn. and use on textile fibre materials thereof

Info

Publication number: CN1292122C
Application number: CNB01804493XA
Authority: CN
Inventors: K－H·布兰克; H－R·麦克
Original assignee: Dystar Textilfarben GmbH and Co Deutschland KG
Current assignee: Dystar Textilfarben GmbH and Co Deutschland KG
Priority date: 2000-02-04
Filing date: 2001-01-27
Publication date: 2006-12-27
Anticipated expiration: 2021-01-27
Also published as: KR20020073199A; PT1268922E; HUP0204369A2; TWI278553B; JP2003521572A; DE50111094D1; DE10004954A1; WO2001057308A3; ZA200205628B; CA2399119A1; ATE340893T1; BR0108097A; CN1398311A; MXPA02007555A; EP1268922B1; ES2270983T3; KR100707575B1; WO2001057308A2; CZ20022661A3; EP1268922A2

Abstract

An aqueous inkjet printing ink including one or more reactive dyes, sulfolane and a buffer system and having a pH of not more than 7.0 when one or more of said reactive dyes have reactive systems of the vinyl sulfone series is prepared and used on textile fiber materials.

Description

Ink jet printing use printing-ink, its preparation and the application on textile fiber material thereof

In textile field and non-textile field, in the future, it is more and more important that the digital printing technology can become.

For conventional printing in textiles, the market expectations of variation require design, color and time of delivery more flexible.The digital ink-jet technology is its answer.Since can be by computer through the direct printing of stamp nozzle, so do not need to prepare printing screen, this new technology has improved stamp processing flexibility, efficient and environmental-protecting performance.This provides the operation of one basically, has shortened the stamp time, and has satisfied interstage requirement still less in fast reaction and the production process is made in market development.

Ink jet printing usually uses water color ink to finish, and with tiny droplet this printing ink directly is sprayed on the base material.This method is divided into continuity method, wherein, this printing ink is pressed through a nozzle with homogeneous speed piezoelectricity, and the pattern that produces as required, with electric field it is deflected on this base material; Be interrupted ink-jet method or drippage (drop-on-demand) method as required, in these methods, only discharge printing ink in the place that colored spots will occur.In a kind of method in back, adopt piezo-electric crystal or heating muff (bubble or thermojet method) that ink set is exerted pressure, thereby eject ink droplet." textiles chemical stain " be the 19th volume (8) (Text.Chem.Color), the 23rd page and thereafter with the 21st the 27th page of volume and described these technology thereafter.

These highly sensitive microtechnologies require the specially offered dye formulations of exploitation, these preparations (printing ink) for example satisfy, the high request of purity, granularity, viscosity, surface tension, electric conductivity, physical-chemical stability, thermophysics performance, pH value, defoaming, colouring intensity, fastness rank and storage stability aspect.Commercial REACTIVE DYES is its powder, particle or liquid formulation form, and is used in the textile-like stamp as routine, contains a large amount of electrolyte, dust-proofing agent and diluent/standardization agent (standarizer), and they give ink-jet printed a large amount of problems of bringing.On the other hand, non-textile material is used dye inks such as paper, timber, plastics, pottery for example, on textile material, be easy to use and stamp tinctorial yield and fastness aspect only obtained unsafty result.

European patent application EP-A 0886000 and EP-A 0885998, EP-A 0620116, EP-A0606777, DE-A 4417718, DE-A 4417719 have described the dye ink of fibre-bearing with REACTIVE DYES.These dye inks have some weakness of using.For example, because dyestuff is abandoned the interaction deficiency of printing ink parent fiber, cause dye ink stability dissatisfactory or low tinctorial yield.European patent specification EP-A 0602885 has described the water soluble dyestuffs printing ink that contains sulfolane that is used for the non-textile field, and it is unsuitable for textile application.Therefore, need the especially printing inks that is improved of application performance of new, performance, be used for the fibre-reactive dye ink-jetting process.

An object of the present invention is, the printing inks that does not have above-mentioned shortcoming is provided.

Now be surprised to find; following water-based printing inks has obtained chromatic effect, and it contains, and not weaken REACTIVE DYES reactive and prevented simultaneously sulfolane, one or more REACTIVE DYES and a kind of buffer system of guaranteeing the active group function of spray nozzle clogging basically.

Therefore, the invention provides a kind of printing in textiles ink jet inks of water-based, it comprises one or more REACTIVE DYES, sulfolane and a kind of buffer system, and for the situation of the REACTIVE DYES that contains one or more active systems with vinyl sulfone series (fixed system), the pH value is no more than 7.0.

Useful dyestuff comprises, for example all REACTIVE DYES of enumerating among European patent specification EP-B 590397, EP-A 886000 and the EP-A 613975.

The REACTIVE DYES that preferably has monochloro triazine active system and/or vinyl sulfone active system.

The example of monochloro triazine series dyes is:

C.I. reactive yellow 85, C.I. reactive yellow 95, C.I. REACTIVE YELLOW 18 1, C.I. REACTIVE ORANGE 12, C.I. REACTIVE ORANGE 13, C.I. reactive orange 35, C.I. reactive red 3:1, C.I. reactive red 24, C.I. REACTIVE RED 31, C.I. reactive red 45, C.I. reactive red 187, C.I. reactive red 218, C.I. reactive red 245, C.I. REACTIVE VIOLET 1, C.I. reactive blue 13, C.I. reactive blue 49, C.I. reactive blue 71, C.I. reactive blue 72, C.I. reactive blue 162, C.I. reactive blue 234, C.I. active palm fibre 11, the active palm fibre 17 of C.I., the active palm fibre 38 of C.I., C.I. reactive black 8, C.I. reactive black 39.

Preferred monochloro triazine series dyes example is:

C.I. reactive yellow 85, C.I. reactive yellow 95, C.I. REACTIVE ORANGE 12, C.I. REACTIVE ORANGE 13, C.I. reactive red 187, C.I. reactive red 218, C.I. reactive blue 49, C.I. reactive blue 72, C.I. reactive blue 234, C.I. reactive black 8, C.I. reactive black 39.

The example of vinyl sulfone series dyes is:

C.I. reactive yellow 15, C.I. reactive yellow 37, C.I. reactive yellow 42, C.I. reactive orange 16, C.I. reactive orange 74, C.I. reactive orange 107, C.I. reactive red 23, C.I. Reactive Red 35, C.I. reactive red 106, C.I. reactive red 180, C.I. Reactive Violet 5, C.I. active blue 19, C.I. REACTIVE Blue 21, C.I. reactive blue 38, C.I. reactive blue 229, the active palm fibre 18 of C.I., C.I. reactive black 5, C.I. reactive black 14, C.I. reactive black 31.

Preferred vinyl sulfone series dyes example is:

C.I. reactive yellow 37, C.I. reactive orange 16, C.I. reactive orange 74, C.I. Reactive Red 35, C.I. reactive red 180, C.I. active blue 19, C.I. REACTIVE Blue 21, C.I. reactive black 5, C.I. reactive black 14, C.I. reactive black 31.

Two bors d's oeuveres and mixed active dye product are that for example the C.I. reactive red 198, C.I. reactive red 239, C.I. reactive black 5, C.I. REACTIVE Blue 21.

Used REACTIVE DYES is known and can obtains by common diazotization, coupling and condensation reaction.

Printing inks of the present invention comprises, one or more REACTIVE DYES, and its amount for example is 0.1 weight %-50 weight % of this total weight, preferred 1 weight %-30 weight %, preferred especially 5 weight %-25 weight %.

When printing inks of the present invention comprises the dyestuff of a chlorotriazine series, preferably by using suitable buffer system that the pH value of printing inks is adjusted to 7.0-9.0.Their consumption is the 0.1-3 weight % of total weight, preferred 0.5-1.5 weight %.

The printing inks that comprises a chlorotriazine series dyes, the buffer system that it was suitable for comprise, for example borax, sodium hydrogen phosphate, modification phosphonate, DEAS.

When printing inks of the present invention comprises the dyestuff of vinyl sulfone series, preferably by using suitable buffer system that the pH value of printing inks is adjusted to 3.0-7.0.Their consumption is the 0.1-3 weight % of total weight, preferred 0.5-2.5 weight %.

The printing inks that comprises the vinyl sulfone series dyes, the buffer system that it was suitable for comprise, for example sodium dihydrogen phosphate, natrium citricum, modification phosphonate.

Other useful buffer system is described in:

" Chemie der Elemente ", VCH Verlagsgesellschaft mbH, 1988 the 1st edition, 665-666 page or leaf, Holleman-Wiberg, Lehrbuch der anorganischenChemie, WDG ﹠amp; Co.Verlage 47th to 56th version, 109-110 page or leaf, Laborchemikalienverlag der Fa.MERCK, Darmstadt, Ausgabe 1999, the 1128-1133 pages or leaves, " Der Fischer Chemicals Katalog " (FischerScientific UK, 1999), the 409-411 page or leaf, Riedel-de-Ha  n, Laborchemikalien 1996, the 946-951 pages or leaves, Riedel-de-Ha  n, Labor-Hilfstabellen No.6, cushioning liquid.

The dyestuff that uses in these printing ink particularly has the 0.1 weight % that is less than these dyestuff weight, for example the salt content of 0.01-0.099.If desired, in using printing ink of the present invention before, for example by membrane separation process to these dyestuff desalinations.

In order in the continuous-flow operation, to use printing ink,, can be 0.5-25mS/m with conductivity setpoint by adding electrolyte.

Useful electrolyte comprises: for example lithium nitrate and potassium nitrate.

Printing ink of the present invention comprises for example sulfolane of 1-30 weight %, preferred 5-25 weight %, the sulfolane of preferred especially 10-20 weight %.

Dye ink of the present invention not only contains sulfolane, and can further comprise organic solvent, and total content is 5-20%, preferred 5-15 weight %.

The organic solvent that is suitable for comprises, for example alcohols such as methyl alcohol, ethanol, 1-propyl alcohol, isopropyl alcohol, 1-butanols, the tert-butyl alcohol, amylalcohol,

Polyalcohol as: 1,2-ethylene glycol, 1,2,3-glycerol, butanediol, 1,3 butylene glycol, 1,4-butanediol, 1,2-propylene glycol, 2, ammediol, pentanediol, 1,4-pentanediol, 1,5-pentanediol, hexylene glycol, D, L-1,2-hexylene glycol, 1,6-hexylene glycol, 1,2,6-hexylene glycol, 1,2-ethohexadiol, poly alkylene glycol be for example: polyethylene glycol, polypropylene glycol

The alkylene glycol that contains 2-8 alkylidene, for example: ethylene glycol, diethylene glycol (DEG), triethylene glycol, tetraethylene glycol, thioglycol, thiodiglycol,

Butyl triethylene glycol, hexylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol,

The lower alkyl ether of polyalcohol is for example: glycol monoethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diglycol monotertiary butyl ether, diglycol monotertiary hexyl ether, triethylene glycol monomethyl ether, triethylene glycol single-butyl ether, tripropylene glycol monomethyl ether, tetraethylene glycol monomethyl ether, tetraethylene glycol single-butyl ether, tetraethylene glycol dimethyl ether, propylene glycol monomethyl ether, dihydroxypropane single-ether, propylene glycol single-butyl ether, tripropylene glycol isopropyl ether

Polyalkylene glycol ether, for example: poly glycol monomethyl ether, Polypropylene Glycol Glycerin Ether, polyethylene glycol tridecyl ether, polyethylene glycol nonylphenyl ether,

Amine is for example: methylamine, ethamine, triethylamine, diethylamine, dimethylamine, trimethylamine, dibutylamine, diethanol amine, triethanolamine, N-acetylethanolamine, N-formoxyl monoethanolamine, ethylenediamine,

Urea derivative is for example: urea, thiocarbamide, N-methyl urea, N, and N '-dimethyl urea, ethylidene-urea, 1,1,3, the 3-tetramethylurea,

Acid amides is for example: dimethyl formamide, dimethylacetylamide, and acetamide,

Ketone or keto-alcohol be for example: acetone, diacetone alcohol,

Cyclic ethers is for example: oxolane, trimethylolethane, trimethylolpropane, butoxy ethanol, benzylalcohol, butoxy ethanol,

Gamma-butyrolacton, epsilon-caprolactams, and dimethylsulfolane, methyl sulfolane, 2, the 4-dimethylsulfolane, dimethyl sulfone, butadiene sulfone, dimethyl sulfoxide (DMSO), the dibutyl sulfoxide, N-cyclohexyl pyrrolidones, the N-N-methyl-2-2-pyrrolidone N-, the N-ethyl pyrrolidone, 2-Pyrrolidone, 1-(2-ethoxy)-2-Pyrrolidone, 1-(3-hydroxypropyl)-2-Pyrrolidone, 1,3-dimethyl-2-imidazolidinone, 1,3-dimethyl-2-imidazolone (imidazolinone), 1,3-dimethoxy-methyl imidazolidine, 2-(2-methoxy ethoxy) ethanol, 2-(2-ethoxy ethoxy) ethanol, 2-(2-butoxy ethyoxyl) ethanol, 2-(2-propoxyl group ethyoxyl) ethanol, pyridine, piperidines, butyrolactone, trimethylolpropane, 1, the 2-dimethoxy propane, dioxane, ethyl acetate, edetate, ethyl pentyl group ether, 1, the 2-dimethoxy propane, trimethyl propane.

Printing inks of the present invention can further comprise usual additive, and for example the viscosity moderator is used for when 20-50 ℃ of temperature viscosity adjustment being arrived in the 1.5-40.0mPa*s scope.The viscosity of preferred printing ink is 1.5-20mPa*s, and the viscosity of preferred especially printing ink is 1.5-15mPa*s.

The viscosity moderator that is suitable for comprises, rheological additives, for example: Vinylcaprolactam homopolymer, polyvinylpyrrolidone and copolymer thereof, polyether polyol, associate thickeners, polyureas, polyurethane, sodium alginate, modification galactomannans class, polyethers urea, Polyurethane, nonionic cellulose ether.

As further additive, printing ink of the present invention can comprise surface reactive material, and being used for the reconciliation statement surface tension is 20-65mN/m, if necessary, with it according to (heat or the piezoelectricity technology) of method therefor adaptive change in addition.

Used surface reactive material comprises, for example: non-ionic surface active agent, butyldiglycol, 1,2-hexylene glycol.

These printing ink can further comprise, conventional additive for example suppresses the material of fungi and bacterial growth, and consumption is the 0.01-1 weight % of total weight.

This printing ink can prepare in the usual way, and component is mixed in water.

In ink-jet printed technology, dye ink of the present invention can be used for various material previously treated, for example silk, leather, wool, polyamide fiber and polyurethane, and be particularly useful for the stamp of the cellulosic fibre material of any kind of.These fibrous materials are native cellulose fibres for example, as cotton, flax and hemp, and paper pulp and regenerated cellulose.Printing inks of the present invention also can be used for being included in the pretreated hydroxyl in the mixed goods or contains the stamp of amino fibre, for example blend of cotton, silk, wool and polyester fiber or polyamide fiber.

Contrast conventional printing in textiles, wherein printing inks has contained all fixation chemicals and thickeners of REACTIVE DYES, in ink-jet printed, must in the pre-treatment step of separating these auxiliary agents be applied on the textile substrate.

Textile substrate, for example cellulose and regenerated celulose fibre and silk and wool are used the preliminary treatment of aqueous alkaline dye liquor before stamp.In order to make reactive dye color fixing, for example sodium carbonate, sodium bicarbonate, sodium acetate, tertiary sodium phosphate, sodium metasilicate, NaOH, alkali donor be for example to need alkali, sodium trichloroacetate, sodium formate, hydroaropic substance for example, urea (urea), reduction inhibitor agent, for example, the nitrobenzene-sulfonic acid ester, and printing inks prevents the thickener that floral designs flow when applying, for example, the galactomannan of sodium alginate, modified polyacrylate or senior etherificate.

Use suitable bringing device amount in accordance with regulations that these pretreating agents are applied on the textile substrate equably, for example use 2 or 3 rolling cars, contactless spray technique utilizes the technology that foam applies or uses the suitable ink-jet technology that adapts, subsequent drying.

After stamp, textile fiber material is in 120-150 ℃ of drying, fixation then.

With the ink-jet printed goods of REACTIVE DYES preparation, its fixation can be in room temperature, perhaps with saturated vapor, with superheated steam, with hot-air, with microwave, with infra-red radiation, finish with laser or electron beam or with other suitable energy transmission technology.

Fixation is distinguished into a step or two step fixation methods.

In the middle of the one step fixation method, essential fixation chemicals is on textile substrate.

In the middle of the two step fixation methods, do not need this preliminary treatment.Fixation only needs alkali, applies this alkali before the fixation later on ink-jet printed, need not middle drying.Do not need further additive for example urea or thickener.

Then be the post processing of printed articles after the fixation, this is to obtain good fastness, high vivid degree and indefectible in vain prerequisite.

Printed articles with dye ink preparation of the present invention, especially the printed articles that on cellulosic fibre material, prepares, its colouring intensity height, and not only acid range and also in alkaline range the bonding stability of fiber-dyestuff high, color fastness to light is good, and its wet fastness properties for example wash resistant, water-fastly wash, fastness to sea water, be infected with perspiration fastness very goodly, and rivel fastness and ironing fastness and crock fastness are also fine.

Following examples illustrate the present invention.Unless different explanations, umber and percentage are by weight.Weight portion is that kilogram is to rising to parts by volume.

Embodiment 1

Pad the textile fabric of mercerized cotton with the liquid that contains 35 grams per liter natrium carbonicum calcinatums, 100 grams per liter urea and 150 grams per liter low viscosity sodium alginate solutions (6%), dry then.Wet pickup is 70%.

With dripping (drop-on-demand) (bubble jet) ink jet printing head as required, to pretreated like this printing in textiles, this printing ink contains with water color ink

12% C.I. reactive yellow 95

10% sulfolane

78% water.

With this PRINTED FABRIC bone dry.Fixation is 8 minutes in 102 ℃ saturated vapor.

This PRINTED FABRIC of Warm Wash improves the washing of COLOR FASTNESS with 95 ℃ hot water to it then, and Warm Wash is dry then.

The glassy yellow PRINTED FABRIC that is to use the fastness excellence that obtains.

Embodiment 2

Pad the textile fabric of mercerized cotton with the liquid that contains 35 grams per liter natrium carbonicum calcinatums, 150 grams per liter urea and 150 grams per liter low viscosity sodium alginate solutions (6%), dry then.Wet pickup is 70%.

15% C.I. REACTIVE ORANGE 13

12% sulfolane

73% water.

The orange PRINTED FABRIC that is to use the fastness excellence that obtains.

Embodiment 3

Pad the textile fabric of causticization viscose glue with the liquid that contains 35 grams per liter natrium carbonicum calcinatums, 200 grams per liter urea and 150 grams per liter low viscosity sodium alginate solutions (6%), dry then.Wet pickup is 70%.

10% C.I. reactive red 187

15% sulfolane

75% water.

The red PRINTED FABRIC that is to use the COLOR FASTNESS excellence that obtains.

Embodiment 4

Pad the textile fabric of causticization viscose glue with the liquid that contains 30 grams per liter sodium bicarbonates, 200 grams per liter urea and 150 grams per liter low viscosity sodium alginate solutions (6%), dry then.Wet pickup is 70%.

12% C.I. REACTIVE Blue 21

15% sulfolane

73% water.

The turquoise PRINTED FABRIC that is to use the COLOR FASTNESS excellence that obtains.

Embodiment 5

Pad the textile fabric of mercerized cotton with the liquid that contains 35 grams per liter natrium carbonicum calcinatums, 50 grams per liter urea and 150 grams per liter low viscosity sodium alginate solutions (6%), dry then.Wet pickup is 70%.

8% C.I. reactive black 14

10% sulfolane

82% water.

The grey PRINTED FABRIC that is to use the COLOR FASTNESS excellence that obtains.

Embodiment 6

12% C.I. REACTIVE ORANGE 12

8% sulfolane

80% water.

The golden yellow PRINTED FABRIC that is to use the COLOR FASTNESS excellence that obtains.

Embodiment 7

10% C.I. reactive orange 35

6% sulfolane

84% water.

The tenne PRINTED FABRIC that is to use the COLOR FASTNESS excellence that obtains.

Embodiment 8

12% C.I. reactive red 218

10% sulfolane

78% water.

Embodiment 9

15% C.I. reactive blue 49

10% sulfolane

75% water.

The blue look PRINTED FABRIC that is to use the COLOR FASTNESS excellence that obtains.

Embodiment 10

10% C.I. reactive black 39

10% sulfolane

80% water.

The avy blue PRINTED FABRIC that is to use the COLOR FASTNESS excellence that obtains.

Embodiment 11

Pad the textile fabric of mercerized cotton with the liquid that contains 40 grams per liter sodium bicarbonates, 100 grams per liter urea and 150 grams per liter low viscosity sodium alginate solutions (6%), dry then.Wet pickup is 70%.

15% C.I. reactive black 5

20% sulfolane

65% water.

Embodiment 12

6% C.I. REACTIVE Blue 21

5% C.I. reactive yellow 37

15% sulfolane

74% water.

The green PRINTED FABRIC that is to use the COLOR FASTNESS excellence that obtains.

Embodiment 13

With dripping (drop-on-demand) (bubble jet) ink jet printing head as required, with water color ink

To pretreated like this printing in textiles, this printing ink contains

8% C.I. reactive black 8

10% sulfolane

82% water.

Embodiment 14

15.0% C.I. reactive black 5

0.8% C.I. reactive orange 107

0.2% C.I. reactive red 180

20.0% sulfolane

64% water.

The black printed fabric that is to use the COLOR FASTNESS excellence that obtains.

Embodiment 15

Pad the textile fabric of causticization viscose glue with the liquid that contains 35 grams per liter sodium bicarbonates, 150 grams per liter urea and 150 grams per liter low viscosity sodium alginate solutions (6%), dry then.Wet pickup is 70%.

15% C.I. REACTIVE Blue 21

10% sulfolane

10% N-N-methyl-2-2-pyrrolidone N-

65% water.

Embodiment 16

Pad the textile fabric of causticization viscose glue with the liquid that contains 35 grams per liter sodium bicarbonates, 100 grams per liter urea and 150 grams per liter low viscosity sodium alginate solutions (6%), dry then.Wet pickup is 70%.

8% C.I. reactive black 14

8% sulfolane

12% N-N-methyl-2-2-pyrrolidone N-

72% water.

Embodiment 17

Pad the textile fabric of mercerized cotton with the liquid that contains 30 grams per liter sodium bicarbonates, 150 grams per liter urea and 150 grams per liter low viscosity sodium alginate solutions (6%), dry then.Wet pickup is 70%.

6% C.I. REACTIVE Blue 21

5% C.I. reactive yellow 37

5% sulfolane

15% N-N-methyl-2-2-pyrrolidone N-

69% water.

Embodiment 18

With dripping (drop-on-demand) (piezoelectricity) ink jet printing head as required, to pretreated like this printing in textiles, this printing ink contains with water color ink

12% C.I. reactive yellow 95

10% sulfolane

10% butyldiglycol

68% water.

The glassy yellow PRINTED FABRIC that is to use the COLOR FASTNESS excellence that obtains.

Embodiment 19

15% C.I. REACTIVE ORANGE 13

12% sulfolane

4% butyldiglycol

69% water.

The orange PRINTED FABRIC that is to use the COLOR FASTNESS excellence that obtains.

Embodiment 20

10% C.I. reactive red 187

15% sulfolane

10% butyldiglycol

65% water.

Embodiment 21

12% C.I. REACTIVE Blue 21

10% sulfolane

8% butyldiglycol

70% water.

Embodiment 22

8% C.I. reactive black 14

10% sulfolane

5% butyldiglycol

77% water.

Embodiment 23

12% C.I. REACTIVE ORANGE 12

8% sulfolane

10% butyldiglycol

70% water.

Embodiment 24

10% C.I. reactive orange 35

9% sulfolane

5% butyldiglycol

76% water.

Embodiment 25

12% C.I. reactive red 218

5% sulfolane

15% N-N-methyl-2-2-pyrrolidone N-

68% water.

Embodiment 26

15% C.I. reactive blue 49

10% sulfolane

7% butyldiglycol

68% water.

Embodiment 27

15% C.I. reactive black 39

10% sulfolane

5% butyldiglycol

75% water.

The avy blue that is to use the COLOR FASTNESS excellence (navy blue) PRINTED FABRIC that obtains.

Embodiment 28

15% C.I. reactive black 5

20% sulfolane

4% butyldiglycol

61% water.

Embodiment 29

6% C.I. REACTIVE Blue 21

5% C.I. reactive yellow 37

15% sulfolane

5% butyldiglycol

69% water.

Embodiment 30

8% C.I. reactive black 8

10% sulfolane

4% butyldiglycol

78% water.

Embodiment 31

15% C.I. reactive black 5

0.8% C.I. reactive orange 107

0.2% C.I. reactive red 180

20% sulfolane

5% butyldiglycol

59% water.

Embodiment 32

Pad the textile fabric of mercerized cotton with the liquid that contains 35 grams per liter sodium bicarbonates, 120 grams per liter urea and 150 grams per liter low viscosity sodium alginate solutions (6%), dry then.Wet pickup is 70%.

8% C.I. REACTIVE ORANGE 13

10% sulfolane

4% N-N-methyl-2-2-pyrrolidone N-

0.5% modification phosphonate ester

77.5% water.

Embodiment 33

10% C.I. reactive red 218

5% sulfolane

15% N-N-methyl-2-2-pyrrolidone N-

0.5% modification phosphonate ester

69.5% water.

Embodiment 34

Pad the textile fabric of causticization viscose glue with the liquid that contains 35 grams per liter sodium bicarbonates, 200 grams per liter urea and 150 grams per liter low viscosity sodium alginate solutions (6%), dry then.Wet pickup is 70%.

8% C.I. reactive blue 49

15% sulfolane

5% N-N-methyl-2-2-pyrrolidone N-

0.5% modification phosphonate ester

71.5% water.

Embodiment 35

Pad the textile fabric of mercerized cotton with the liquid that contains 30 grams per liter natrium carbonicum calcinatums, 100 grams per liter urea and 150 grams per liter low viscosity sodium alginate solutions (6%), dry then.Wet pickup is 70%.

10% C.I. reactive red 180

15% sulfolane

4% N-N-methyl-2-2-pyrrolidone N-

0.5% modification phosphonate ester

70.5% water.

Embodiment 36

Pad the textile fabric of boiled silk with the liquid of the galactomannans (5%) that contains 50 grams per liter sodium acetates, 100 grams per liter urea and the high degree of etherification falling of 150 grams per liters, dry then.Wet pickup is 70%.

8% C.I. reactive yellow 37

20% sulfolane

72% water.

With this PRINTED FABRIC bone dry.Fixation is 20 minutes in 102 ℃ saturated vapor.

This PRINTED FABRIC of Warm Wash in the presence of 1-2ml 25% ammoniacal liquor improves the washing of COLOR FASTNESS with 70-80 ℃ hot water to it then, and Warm Wash is dry then.

The yellow PRINTED FABRIC that is to use the COLOR FASTNESS excellence that obtains.

Embodiment 37

12% C.I. reactive yellow 42

15% sulfolane

73% water.

Embodiment 38

14% C.I. reactive orange 107

15% sulfolane

71% water.

Embodiment 39

9% C.I. reactive orange 74

15% sulfolane

76% water.

Embodiment 40

8% C.I. reactive orange 16

14% sulfolane

78% water.

Embodiment 41

14% C.I. reactive red 180

16% sulfolane

3% butyldiglycol

0.2% modification galactomannans

66.8% water.

Embodiment 42

9% C.I. reactive red 239

16% sulfolane

5% butyldiglycol

0.2% modification galactomannans

0.5% borax

69.3% water.

Embodiment 43

10% C.I. reactive red 198

12% sulfolane

6% butyldiglycol

0.5% modification phosphonate ester

71.5% water.

Embodiment 44

8% C.I. Reactive Red 35

13% sulfolane

3% butyldiglycol

0.3% natrium citricum

75.7% water.

Embodiment 45

10% C.I. active blue 19

16% sulfolane

3% butyldiglycol

0.5% modification phosphonate ester

70.5% water.

The blue PRINTED FABRIC that is to use the COLOR FASTNESS excellence that obtains.

Embodiment 46

10% C.I. REACTIVE Blue 21

5% sulfolane

15% N-N-methyl-2-2-pyrrolidone N-

70% water.

Embodiment 47

12% C.I. reactive blue 229

7% sulfolane

12% N-N-methyl-2-2-pyrrolidone N-

69% water.

Embodiment 48

8% C.I. reactive black 14

10% sulfolane

10% N-N-methyl-2-2-pyrrolidone N-

72% water.

Embodiment 49

5% C.I. reactive black 31

8% sulfolane

12% N-N-methyl-2-2-pyrrolidone N-

75% water.

Embodiment 50

15% C.I. reactive black 5

10% sulfolane

12% N-N-methyl-2-2-pyrrolidone N-

63% water.

The navy blue PRINTED FABRIC that is to use the COLOR FASTNESS excellence that obtains.

Embodiment 51

With Continuous Flow (piezoelectricity) ink jet printing head, to pretreated like this printing in textiles, this printing ink contains with water color ink

10% C.I. reactive yellow 37

15% sulfolane

7% polyether polyol

68% water.

Embodiment 52

10.5% C.I. reactive red 180

15% sulfolane

8% polyether polyol

66.5% water.

Embodiment 53

12% C.I. REACTIVE Blue 21

18% sulfolane

7% polyether polyol

63% water.

Embodiment 54

8% C.I. reactive black 14

15% sulfolane

5% polyether polyol

72% water.

Embodiment 55

11% C.I. reactive red 180

15% sulfolane

4% Vinylcaprolactam homopolymer

70% water.

Embodiment 56

10% C.I. REACTIVE Blue 21

15% sulfolane

3% 1,2-hexylene glycol

5% Vinylcaprolactam homopolymer

67% water.

Embodiment 57

8% C.I. reactive black 14

15% sulfolane

5% polyether polyol

3% 1,2-hexylene glycol

69% water.

Embodiment 58

12% C.I. REACTIVE Blue 21

18% sulfolane

7% polyether polyol

3% 1,2-hexylene glycol

60% water.

Embodiment 59

10.5% C.I. reactive red 180

15% sulfolane

8% polyether polyol

6% polypropylene glycol

60.5% water.

Embodiment 60

10% C.I. reactive yellow 37

15% sulfolane

7% polyether polyol

4% polypropylene glycol

0.3% natrium citricum

63.7% water.

Embodiment 61

Pad the textile fabric of chlorinated wool with the liquid that contains 50 grams per liter sodium acetates, 150 grams per liter urea and 150 grams per liter low viscosity sodium alginate solutions (5%), dry then.Wet pickup is 70%.

8% C.I. reactive yellow 37

20% sulfolane

72% water.

Embodiment 62

12% C.I. reactive yellow 42

15% sulfolane

73% water.

Embodiment 63

14% C.I. reactive orange 107

15% sulfolane

71% water.

Embodiment 64

9% C.I. reactive orange 74

15% sulfolane

76% water.

Embodiment 65

8% C.I. reactive orange 16

16% sulfolane

78% water.

Embodiment 66

10% C.I. active blue 19

16% sulfolane

3% butyldiglycol

0.5% modification phosphonate ester

70.5% water.

Embodiment 67

8% C.I. Reactive Red 35

13% sulfolane

3% butyldiglycol

0.3% natrium citricum

75.7% water.

Embodiment 68

10% C.I. reactive red 198

12% sulfolane

6% butyldiglycol

0.5% modification phosphonate ester

71.5% water.

Embodiment 69

9% C.I. reactive red 239

16% sulfolane

5% butyldiglycol

0.5% borax

69.5% water.

In the presence of 1-2ml 25% ammoniacal liquor, this PRINTED FABRIC of Warm Wash improves the washing of COLOR FASTNESS with 70-80 ℃ hot water to it then, and Warm Wash is dry then.

Embodiment 70

14% C.I. reactive red 180

16% sulfolane

3% butyldiglycol

67% water.

Embodiment 71

15% C.I. reactive black 5

10% sulfolane

12% N-N-methyl-2-2-pyrrolidone N-

63% water.

The navy blue that is to use the COLOR FASTNESS excellence (navy blue) PRINTED FABRIC that obtains.

Embodiment 72

5% C.I. reactive black 31

8% sulfolane

12% N-N-methyl-2-2-pyrrolidone N-

75% water.

Embodiment 73

8% C.I. reactive black 14

10% sulfolane

10% N-N-methyl-2-2-pyrrolidone N-

72% water.

Embodiment 74

12% C.I. reactive blue 229

7% sulfolane

12% N-N-methyl-2-2-pyrrolidone N-

69% water.

Embodiment 75

10% C.I. REACTIVE Blue 21

5% sulfolane

15% N-N-methyl-2-2-pyrrolidone N-

70% water.

Embodiment 76

8% C.I. reactive black 14

15% sulfolane

5% polyether polyol

72% water.

Embodiment 77

12% C.I. REACTIVE Blue 21

18% sulfolane

7% polyether polyol

63% water.

Embodiment 78

10.5% C.I. reactive red 180

15% sulfolane

8% polyether polyol

66.5% water.

Embodiment 79

10% C.I. reactive yellow 37

15% sulfolane

7% polyether polyol

68% water.

Embodiment 80

10% C.I. REACTIVE Blue 21

15% sulfolane

3% 1,2-hexylene glycol

5% Vinylcaprolactam homopolymer

67% water.

Embodiment 81

11% C.I. reactive red 180

15% sulfolane

4% Vinylcaprolactam homopolymer

70% water.

Embodiment 82

10% C.I. reactive yellow 37

15% sulfolane

7% polyether polyol

4% polypropylene glycol

0.3% natrium citricum

63.7% water.

Embodiment 83

10.5% C.I. reactive red 180

15% sulfolane

8% polyether polyol

6% polypropylene glycol

60.5% water.

Embodiment 84

12% C.I. REACTIVE Blue 21

18% sulfolane

7% polyether polyol

3% 1,2-hexylene glycol

60% water.

Embodiment 85

8% C.I. reactive black 14

15% sulfolane

5% polyether polyol

3% 1,2-hexylene glycol

69% water.

Embodiment 86

12% C.I. reactive yellow 95

10% sulfolane

8% polyether polyol

70% water.

Embodiment 87

9% C.I. REACTIVE ORANGE 13

12% sulfolane

10% polyether polyol

69% water.

Embodiment 88

10% C.I. reactive red 187

15% sulfolane

7% polyether polyol

68% water.

Embodiment 89

12% C.I. REACTIVE Blue 21

15% sulfolane

5% N-N-methyl-2-2-pyrrolidone N-

7% polyether polyol

61% water.

Embodiment 90

8% C.I. reactive black 14

10% sulfolane

5% N-N-methyl-2-2-pyrrolidone N-

5% polyether polyol

72% water.

Embodiment 91

12% C.I. REACTIVE ORANGE 12

20% sulfolane

8% polyether polyol

60% water.

Embodiment 92

Pad the textile fabric of mercerized cotton with the liquid that contains 35 grams per liter natrium carbonicum calcinatums, 200 grams per liter urea and 150 grams per liter low viscosity sodium alginate solutions (6%), dry then.Wet pickup is 70%.

10% C.I. reactive orange 35

16% sulfolane

6% Vinylcaprolactam homopolymer

0.3% borax

67% water.

The orange-brown PRINTED FABRIC that is to use the COLOR FASTNESS excellence that obtains.

Embodiment 93

12% C.I. reactive red 218

10% sulfolane

10% N-N-methyl-2-2-pyrrolidone N-

5% PVP

63% water.

Embodiment 94

15% C.I. reactive blue 49

10% sulfolane

5% polyether polyol

0.5% borax

69.5% water.

Embodiment 95

10% C.I. reactive black 39

18% sulfolane

6% polyether polyol

0.5% phosphoric acid (salt) buffer solution

65.5% water.

Embodiment 96

15% C.I. reactive black 5

20% sulfolane

6% Vinylcaprolactam homopolymer

0.3% modification polyphosphonates

58.7% water.

Embodiment 97

6% C.I. REACTIVE Blue 21

5% C.I. reactive yellow 37

15% sulfolane

8% PVP

0.5% natrium citricum

65.5% water.

Embodiment 98

8% C.I. reactive black 12

10% sulfolane

4% associative thickener

78% water.

Embodiment 99

15% C.I. reactive black 5

0.8% C.I. reactive orange 107

0.2% C.I. reactive red 180

20% sulfolane

5% polypropylene glycol

59% water.

Embodiment 100

Pad the textile fabric of mercerized cotton with the liquid that contains 150 grams per liter low viscosity sodium alginate solutions (6%), dry then.Wet pickup is 70%.

11% C.I. reactive yellow 37

18% sulfolane

71% water.

With this PRINTED FABRIC bone dry.With two known stage fixation methods (125 ℃ of flash distillations 20 seconds; 125 ℃ of short time decatizes 90 seconds; 20 ℃ of-40 ℃ of cold domes were processed 4-12 hour, and fixation alkali is: sodium hydroxide solution/sodium silicate mixture Na ₂O: SiO ₂, its ratio be 1: 1.7 to 3.3 technology to its fixation.

Embodiment 101

With dripping (drop-on-demand) (bubble jet) ink jet printing head as required, with the textile fabric stamp of water color ink to mercerized cotton, this printing ink contains

10% C.I. reactive red 180

15% sulfolane

3% N-N-methyl-2-2-pyrrolidone N-

72% water.

With this PRINTED FABRIC bone dry.With two known stage fixation methods (125 ℃ of flash distillations 20 seconds; 125 ℃ of short time decatizes 90 seconds; 20 ℃ of-40 ℃ of cold domes were processed 4-12 hour, and fixation alkali is: sodium hydroxide solution/sodium silicate mixture Na ₂O: SiO ₂, its ratio be 1: 1.7 to 3.3) technology to its fixation.

This PRINTED FABRIC of Warm Wash improves the water temperature washing of COLOR FASTNESS with 95 ℃ hot water to it then, and is dry then.

Embodiment 102

With dripping (drop-on-demand) (piezoelectricity) ink jet printing head as required, with the textile fabric stamp of water color ink to the causticization viscose glue, this printing ink contains

12% C.I. REACTIVE Blue 21

16% sulfolane

5% butyldiglycol

67% water.

Embodiment 103

Pad the textile fabric of causticization viscose glue with the liquid that contains 150 grams per liter low viscosity sodium alginate solutions (6%), dry then.Wet pickup is 70%.

10% C.I. REACTIVE ORANGE 13

15% sulfolane

0.3% borax

74.7% water.

Embodiment 104

8% C.I. reactive black 8

12% sulfolane

4% 1,2-hexylene glycol

0.3% modification polyphosphonates

75.7% water.

Embodiment 105

10% C.I. reactive red 218

10% sulfolane

5% N-N-methyl-2-2-pyrrolidone N-

2% polypropylene glycol

73% water.

Embodiment 106

15% C.I. reactive black 5

20% sulfolane

10% polyether polyol

0.3% natrium citricum

54.7% water.

Embodiment 107

1% C.I. REACTIVE ORANGE 12

12% C.I. reactive black 39

1% C.I. reactive red 218

20% sulfolane

5% Vinylcaprolactam homopolymer

61% water.

With this PRINTED FABRIC bone dry.With short time decatize 90 seconds, fixation alkali was: sodium hydroxide solution/sodium silicate mixture Na ₂O: SiO ₂, its ratio is that 1: 2.0 technology is to its fixation.

Embodiment 108

10% C.I. reactive red 239

12% sulfolane

3% 1,2-hexylene glycol

3% polypropylene glycol

72% water.

Embodiment 109

Pad the textile fabric of mercerized cotton with the liquid that contains 80 grams per liter Trichloroacetates, 150 grams per liter urea, dry then.Wet pickup is 70%.

11% C.I. reactive yellow 42

12% sulfolane

77% water.

With this PRINTED FABRIC bone dry.Fixation is 10 minutes in 102 ℃ saturated vapor.

Embodiment 110

8% C.I. reactive orange 16

12% sulfolane

6% N-N-methyl-2-2-pyrrolidone N-

74% water.

Embodiment 111

Pad the textile fabric of causticization viscose glue with the liquid that contains 80 grams per liter Trichloroacetates, 150 grams per liter urea, dry then.Wet pickup is 70%.

With dripping (piezoelectricity) ink jet printing head as required, to pretreated like this printing in textiles, this printing ink contains with water color ink

8% C.I. reactive black 14

12% sulfolane

4% butyldiglycol

0.4% modification polyphosphonates

75.5% water.

Embodiment 112

9% C.I. reactive red 198

15% sulfolane

0.3% natrium citricum

75.7% water.

Embodiment 113

Pad the textile fabric of bleaching flax with liquid that contains 80 grams per liter Trichloroacetates, 150 grams per liter urea and the liquid that contains 150 grams per liter low viscosity sodium alginate solutions (5%), dry then.Wet pickup is 70%.

11% C.I. REACTIVE ORANGE 13

15% sulfolane

5% N-N-methyl-2-2-pyrrolidone N-

0.05% non-ionic surface active agent

68.95% water.

Embodiment 114

Pad the textile fabric of causticization viscose glue with liquid that contains 80 grams per liter Trichloroacetates, 150 grams per liter urea and the liquid that contains 150 grams per liter low viscosity sodium alginate solutions (5%), dry then.Wet pickup is 70%.

13% C.I. reactive orange 74

10% sulfolane

5% butyldiglycol

72% water.

Embodiment 115

14% C.I. active blue 19

15% sulfolane

0.05% non-ionic surface active agent

0.15% modification polyphosphonates

70.8% water.

Embodiment 116

Pad the textile fabric of mercerized cotton with liquid that contains 80 grams per liter Trichloroacetates, 50 grams per liter urea and the liquid that contains 150 grams per liter low viscosity sodium alginate solutions (5%), dry then.Wet pickup is 70%.

10% C.I. reactive blue 229

12% sulfolane

6% N-N-methyl-2-2-pyrrolidone N-

6% polyether polyol

66% water.

Embodiment 117

Pad the textile fabric of bleaching flax with liquid that contains 80 grams per liter Trichloroacetates, 100 grams per liter urea and the liquid that contains 150 grams per liter low viscosity sodium alginate solutions (5%), dry then.Wet pickup is 70%.

14% C.I. reactive red 187

16% sulfolane

4% 1,2-hexylene glycol

6% Vinylcaprolactam homopolymer

60% water.

Embodiment 118

9% C.I. reactive yellow 85

15% sulfolane

5% N-N-methyl-2-2-pyrrolidone N-

71% water.

Embodiment 119

Pad the textile fabric of mercerized cotton with the liquid that contains 35 grams per liter sodium bicarbonates, 250 grams per liter urea, dry then.Wet pickup is 70%.

12% C.I. reactive orange 181

15% sulfolane

5% N-N-methyl-2-2-pyrrolidone N-

68% water.

With this PRINTED FABRIC bone dry.Fixation is 3～5 minutes in 150 ℃ hot-air.

Embodiment 120

Pad the textile fabric of causticization viscose glue with the liquid that contains 35 grams per liter natrium carbonicum calcinatums, 100 grams per liter urea and 150 grams per liter low viscosity sodium alginate solutions (6%), dry then.Wet pickup is 70%.

12% C.I. REACTIVE RED 31

12% sulfolane

76% water.

Embodiment 121

Pad the textile fabric of mercerized cotton with the liquid that contains 30 grams per liter natrium carbonicum calcinatums, 100 grams per liter urea, dry then.Wet pickup is 70%.

10% C.I. reactive red 3:1

15% sulfolane

4% butyldiglycol

0.5% borax

70.5% water.

Embodiment 122

Pad the textile fabric of mercerized cotton with the liquid that contains 35 grams per liter natrium carbonicum calcinatums, 150 grams per liter urea, dry then.Wet pickup is 70%.

12% C.I. reactive red 245

12% sulfolane

4% 1,2-hexylene glycol

0.3% borax

71.7% water.

Embodiment 123

Pad the textile fabric of causticization viscose glue with the liquid that contains 35 grams per liter natrium carbonicum calcinatums, 200 grams per liter urea, dry then.Wet pickup is 70%.

10% C.I. reactive blue 72

15% sulfolane

75% water.

Embodiment 124

Pad the textile fabric of causticization viscose glue with the liquid that contains 30 grams per liter natrium carbonicum calcinatums, 180 grams per liter urea, dry then.Wet pickup is 70%.

12% C.I. reactive blue 13

15% sulfolane

5% polypropylene glycol

0.3% borax

67.7% water.

Embodiment 125

Pad the textile fabric of causticization viscose glue with the liquid that contains 30 grams per liter natrium carbonicum calcinatums, 100 grams per liter urea and 150 grams per liter low viscosity sodium alginate solutions (6%), dry then.Wet pickup is 70%.

9% C.I. REACTIVE VIOLET 1

20% sulfolane

0.3% borax

70.7% water.

The purple PRINTED FABRIC that is to use the COLOR FASTNESS excellence that obtains.

Embodiment 126

Pad the textile fabric of causticization viscose glue with the liquid that contains 35 grams per liter sodium carbonate, 250 grams per liter urea, dry then.Wet pickup is 70%.

12% C.I. reactive blue 234

10% sulfolane

8% butyldiglycol

0.3% borax

69.7% water.

Claims

1. the textile inkjet printing-ink of a water-based, it comprises one or more REACTIVE DYES, sulfolane and a kind of buffer system, this buffer system is not dicarboxylic acids and its alkali metal salt, and is no more than 7.0 for the situation pH value of the REACTIVE DYES that contains one or more active systems with vinyl sulfone series.

2. the printing-ink of claim 1 comprises one or more REACTIVE DYES, and based on the gross weight of described printing ink, the amount of this dyestuff is 0.1 weight %-50 weight %.

3. the printing-ink of claim 1 comprises the sulfolane that accounts for described total weight 1-30 weight %.

4. the printing-ink of claim 1 comprises the organic solvent that accounts for described total weight 5-20 weight %, and condition is that this solvent is not a thiodiglycol.

5. each printing-ink in the claim 1 to 4 comprises one or more REACTIVE DYES, and this dyestuff has the active system of a chlorotriazine series.

6. the printing-ink of claim 5 is adjusted into 7.0-9.0 by adding buffer system with the pH value.

7. each printing-ink in the claim 1 to 4 comprises one or more REACTIVE DYES, and this dyestuff has the active system of vinyl sulfone series.

8. the printing-ink of claim 7 is adjusted into 3.0-7.0 by adding buffer system with the pH value.

9. the preparation method of each described printing-ink in the claim 1 to 7 is that these single components are mixed.

10. the purposes of each described printing-ink in the claim 1 to 8 is used for Ink Jet Printing on Textiles.