EP0478799B1 - Dispositif a semiconducteur avec materiau ferro-electrique et procede de production de ce dispositif - Google Patents

Dispositif a semiconducteur avec materiau ferro-electrique et procede de production de ce dispositif Download PDF

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Publication number
EP0478799B1
EP0478799B1 EP91908469A EP91908469A EP0478799B1 EP 0478799 B1 EP0478799 B1 EP 0478799B1 EP 91908469 A EP91908469 A EP 91908469A EP 91908469 A EP91908469 A EP 91908469A EP 0478799 B1 EP0478799 B1 EP 0478799B1
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EP
European Patent Office
Prior art keywords
film
ferroelectric
oxide film
conductive
capacitor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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EP91908469A
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German (de)
English (en)
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EP0478799A1 (fr
EP0478799A4 (en
Inventor
Kazuhiro Takenaka
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Ramtron International Corp
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Ramtron International Corp
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Publication of EP0478799A4 publication Critical patent/EP0478799A4/en
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Publication of EP0478799B1 publication Critical patent/EP0478799B1/fr
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/792Field effect transistors with field effect produced by an insulated gate with charge trapping gate insulator, e.g. MNOS-memory transistors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L28/00Passive two-terminal components without a potential-jump or surface barrier for integrated circuits; Details thereof; Multistep manufacturing processes therefor
    • H01L28/40Capacitors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/43Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/43Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/45Ohmic electrodes
    • H01L29/456Ohmic electrodes on silicon
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/43Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/49Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
    • H01L29/51Insulating materials associated therewith
    • H01L29/516Insulating materials associated therewith with at least one ferroelectric layer
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B12/00Dynamic random access memory [DRAM] devices
    • H10B12/30DRAM devices comprising one-transistor - one-capacitor [1T-1C] memory cells
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B53/00Ferroelectric RAM [FeRAM] devices comprising ferroelectric memory capacitors

Abstract

La structure d'un condensateur ferro-électrique (C) se forme sur une région source (23) entre une électrode de porte (22) et un film d'oxyde local (26). La structure présente une électrode supérieure (30) et une électrode inférieure (31) entre lesquelles un film ferro-électrique (29) est pris en sandwich, et comporte un film d'oxyde électroconducteur (32) entre l'électrode inférieure (31) et la région source (23). Le film d'oxyde électroconducteur (32) se compose de ITO, ReO2, RuO2, MoO3. Afin d'améliorer la cristallinité du film ferro-électrique (29), celui-ci est recuit à l'oxygène. Bien que l'oxygène pénètre par infiltration dans le film d'oxyde conducteur (32) jusqu'à un certain degré, cela n'entraîne aucun effet négatif, à l'exception d'une oxydation ultérieure du film d'oxyde conducteur (32). C'est-à-dire que le film d'oxyde sert de barrière à l'oxydation ou de couche borgne, pour que le silicium à l'interface avec la source soit essentiellement protégée contre l'oxydation. Ainsi, la diminution de la résistance de contact et le développement de capacitances parasites en série sont évités, ce qui accroît la liberté de formation de la région de condensateur (C) et augmente le degré d'intégration.

Claims (8)

  1. Condensateur ferro-électrique (C) à utiliser dans un dispositif à semiconducteur, ledit condensateur comprenant :
    un substrat semiconducteur (20) ;
    un film de siliciure métallique (40 ; 50 ; 60) disposé sur ledit substrat (20) ;
    un film métallique conducteur (41) disposé sur ledit film de siliciure métallique (40 ; 50 ; 60) ;
    un film d'oxyde conducteur (42 ; 52) disposé sur ledit film métallique conducteur (41) ;
    une électrode inférieure (31) disposée sur ledit film d'oxyde conducteur (42 ; 52), ladite électrode inférieure (31) étant constituée d'un matériau choisi dans le groupe constitué par le platine et le palladium ;
    une couche (29) de matériau ferro-électrique disposée sur ladite électrode inférieure (31) ; et
    une électrode supérieure (30) disposée sur ladite couche (29) de matériau ferro-électrique.
  2. Condensateur selon la revendication 1, dans lequel ledit film de siliciure métallique (40 ; 50 ; 60) contient un métal choisi dans le groupe comprenant le titane, le platine, le ruthénium, le rhénium, le molybdène, le tungstène, le tantale et le palladium.
  3. Condensateur selon la revendication 1, dans lequel ledit film métallique conducteur (41) contient un métal choisi dans le groupe comprenant le ruthénium, le rhénium et le molybdène.
  4. Condensateur selon la revendication 1, dans lequel ledit film d'oxyde conducteur (42 ; 52) contient un composé choisi dans le groupe comprenant l'oxyde de ruthénium, l'oxyde de rhénium, l'oxyde de molybdène et l'oxyde d'étain et d'indium.
  5. Condensateur selon la revendication 1, dans lequel ledit film d'oxyde conducteur (42 ; 52) contient plus de deux des composés choisis dans le groupe comprenant l'oxyde de ruthénium, l'oxyde de rhénium, l'oxyde de molybdène et l'oxyde d'étain et d'indium.
  6. Condensateur selon la revendication 1, dans lequel ledit film de siliciure métallique (40 ; 50 ; 60) est disposé sur une région source (23) dans ledit substrat (20).
  7. Procédé de fabrication d'un condensateur ferro-électrique (C) à utiliser dans un dispositif à semiconducteur, ledit procédé comprenant les opérations consistant à :
    fabriquer un substrat semiconducteur (20) ;
    disposer un film métallique conducteur (41) sur ledit substrat (20) ;
    former une électrode inférieure (31) sur ledit film métallique conducteur (41), ladite électrode inférieure (31) comprenant un matériau choisi dans le groupe constitué par le platine et le palladium ;
    disposer une couche (29) de matériau ferro-électrique sur ladite électrode inférieure (31) ;
    effectuer ensuite un recuit dans de l'oxygène, ledit recuit entraînant la formation par ledit film métallique conducteur d'un film de silicium métallique (40 ; 50 ; 60) entre ledit film métallique conducteur (41) et ledit substrat (20) et d'un film d'oxyde conducteur (42 ; 52) entre ledit film métallique conducteur (41) et ladite électrode inférieure (31) ; et
    disposer une électrode supérieure (30) sur ladite couche (29) de matériau ferro-électrique.
  8. Procédé selon la revendication 7, dans lequel ledit film métallique conducteur (41) est disposé sur une région source (23) dans ledit substrat (20).
EP91908469A 1990-04-24 1991-04-23 Dispositif a semiconducteur avec materiau ferro-electrique et procede de production de ce dispositif Expired - Lifetime EP0478799B1 (fr)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
JP10801190 1990-04-24
JP10801390 1990-04-24
JP108011/90 1990-04-24
JP108012/90 1990-04-24
JP10801290 1990-04-24
JP108013/90 1990-04-24
PCT/JP1991/000539 WO1991016731A1 (fr) 1990-04-24 1991-04-23 Dispositif a semiconducteur avec materiau ferro-electrique et procede de production de ce dispositif

Publications (3)

Publication Number Publication Date
EP0478799A1 EP0478799A1 (fr) 1992-04-08
EP0478799A4 EP0478799A4 (en) 1992-10-21
EP0478799B1 true EP0478799B1 (fr) 1996-12-04

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EP91908469A Expired - Lifetime EP0478799B1 (fr) 1990-04-24 1991-04-23 Dispositif a semiconducteur avec materiau ferro-electrique et procede de production de ce dispositif

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Country Link
US (1) US5293510A (fr)
EP (1) EP0478799B1 (fr)
KR (1) KR100349999B1 (fr)
DE (1) DE69123422T2 (fr)
WO (1) WO1991016731A1 (fr)

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Also Published As

Publication number Publication date
EP0478799A1 (fr) 1992-04-08
WO1991016731A1 (fr) 1991-10-31
KR100349999B1 (ko) 2002-12-11
DE69123422T2 (de) 1997-06-05
KR920702797A (ko) 1992-10-06
EP0478799A4 (en) 1992-10-21
US5293510A (en) 1994-03-08
DE69123422D1 (de) 1997-01-16

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