DE69906814T2 - Elektrochemische zellen mit hoher dichte von elektroaktiven schwefel-enthaltenden materialien in kathodisch aktiven schichten - Google Patents
Elektrochemische zellen mit hoher dichte von elektroaktiven schwefel-enthaltenden materialien in kathodisch aktiven schichten Download PDFInfo
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- DE69906814T2 DE69906814T2 DE69906814T DE69906814T DE69906814T2 DE 69906814 T2 DE69906814 T2 DE 69906814T2 DE 69906814 T DE69906814 T DE 69906814T DE 69906814 T DE69906814 T DE 69906814T DE 69906814 T2 DE69906814 T2 DE 69906814T2
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- cathode active
- active layer
- sulfur
- containing material
- electroactive sulfur
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Classifications
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- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M2010/4292—Aspects relating to capacity ratio of electrodes/electrolyte or anode/cathode
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/40—Alloys based on alkali metals
- H01M4/405—Alloys based on lithium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/215,057 US6302928B1 (en) | 1998-12-17 | 1998-12-17 | Electrochemical cells with high volumetric density of electroactive sulfur-containing materials in cathode active layers |
| US215057 | 1998-12-17 | ||
| PCT/US1999/030117 WO2000036674A2 (en) | 1998-12-17 | 1999-12-16 | Electrochemical cells with high volumetric density of electroactive sulfur-containing materials in cathode active layers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69906814D1 DE69906814D1 (de) | 2003-05-15 |
| DE69906814T2 true DE69906814T2 (de) | 2004-03-11 |
Family
ID=22801463
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69906814T Expired - Lifetime DE69906814T2 (de) | 1998-12-17 | 1999-12-16 | Elektrochemische zellen mit hoher dichte von elektroaktiven schwefel-enthaltenden materialien in kathodisch aktiven schichten |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US6302928B1 (enExample) |
| EP (1) | EP1151487B1 (enExample) |
| JP (1) | JP2002532854A (enExample) |
| KR (1) | KR100652926B1 (enExample) |
| CN (1) | CN1168163C (enExample) |
| AU (1) | AU2481300A (enExample) |
| DE (1) | DE69906814T2 (enExample) |
| WO (1) | WO2000036674A2 (enExample) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102010027950A1 (de) | 2010-04-20 | 2011-10-20 | Robert Bosch Gmbh | Kathodenzusammensetzung für Lithium-Schwefel-Zellen |
| WO2012059262A1 (de) | 2010-11-04 | 2012-05-10 | Robert Bosch Gmbh | Kathodenmaterial für lithium-schwefel-zelle |
| WO2013171023A1 (de) | 2012-05-18 | 2013-11-21 | Robert Bosch Gmbh | Verfahren zum herstellen einer elektrode für einen elektrochemischen energiespeicher und elektrochemischer energiespeicher |
| DE102014003128A1 (de) | 2014-03-03 | 2015-09-03 | Hochschule Aalen | Verbundmaterial |
| DE102021214966A1 (de) | 2021-12-22 | 2023-06-22 | Volkswagen Aktiengesellschaft | Verfahren zur Herstellung einer Kathode für eine Lithium-Ionen-Batteriezelle |
Families Citing this family (53)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6544688B1 (en) | 2000-09-20 | 2003-04-08 | Moltech Corporation | Cathode current collector for electrochemical cells |
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| US6566006B1 (en) * | 2000-09-20 | 2003-05-20 | Moltech Corporation | Sulfur-containing cathode |
| JP4080335B2 (ja) | 2000-12-21 | 2008-04-23 | シオン・パワー・コーポレーション | 電気化学電池のためのリチウム負極 |
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| JP2017515277A (ja) | 2014-05-01 | 2017-06-08 | ビーエイエスエフ・ソシエタス・エウロパエアBasf Se | 電極製造方法および関連システムおよび物品 |
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| JP2016033929A (ja) * | 2015-12-08 | 2016-03-10 | ソニー株式会社 | 二次電池、二次電池の製造方法、二次電池用正極、二次電池用正極の製造方法、電池パック、電子機器および電動車両 |
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| US11038239B2 (en) * | 2018-04-20 | 2021-06-15 | Massachusetts Institute Of Technology | Electrochemically active multifunctional interlayer for a Li-S battery |
| KR102579019B1 (ko) * | 2018-07-18 | 2023-09-18 | 재단법인대구경북과학기술원 | 다공성 실리카-황 복합체 및 이를 포함하는 리튬-황 전지 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3639174A (en) | 1970-04-22 | 1972-02-01 | Du Pont | Voltaic cells with lithium-aluminum alloy anode and nonaqueous solvent electrolyte system |
| US4152491A (en) | 1978-06-26 | 1979-05-01 | Exxon Research & Engineering Co. | Cells having cathodes containing carbon monosulfide polymer cathode-active materials |
| US4143214A (en) | 1978-06-26 | 1979-03-06 | Exxon Research & Engineering Co. | Cells having cathodes containing Cs S cathode-active materials |
| FR2442512A1 (fr) | 1978-11-22 | 1980-06-20 | Anvar | Nouveaux materiaux elastomeres a conduction ionique |
| US4192913A (en) * | 1978-11-27 | 1980-03-11 | Magnavox Government And Industrial Electronics Company | Deferred action battery having an improved depolarizer |
| US4409168A (en) | 1981-05-22 | 1983-10-11 | Mrazek Franklin C | Method of forming components for a high-temperature secondary electrochemical cell |
| US4739018A (en) | 1983-09-20 | 1988-04-19 | Societe Nationale Elf Aquitaine | Polycarbon sulphide polymers |
| FR2570882B1 (fr) | 1984-09-21 | 1986-12-05 | Comp Generale Electricite | Matiere active positive a base d'un polymere conducteur electronique pour generateur electrochimique |
| FR2591605B1 (fr) | 1985-12-13 | 1988-10-07 | Commissariat Energie Atomique | Polymeres conducteurs electroniques azotes a base de polyanilines et de soufre ou de polysulfures, leurs procedes de preparation et generateur electrochimique utilisant ces polymeres. |
| US4833048A (en) | 1988-03-31 | 1989-05-23 | The United States Of America As Represented By The United States Department Of Energy | Metal-sulfur type cell having improved positive electrode |
| US4917974A (en) | 1989-04-14 | 1990-04-17 | The United States Of America As Represented By The Department Of Energy | Lithium/organosulfur redox cell having protective solid electrolyte barrier formed on anode and method of making same |
| US5162175A (en) | 1989-10-13 | 1992-11-10 | Visco Steven J | Cell for making secondary batteries |
| US5324599A (en) | 1991-01-29 | 1994-06-28 | Matsushita Electric Industrial Co., Ltd. | Reversible electrode material |
| US5441831A (en) | 1992-12-17 | 1995-08-15 | Associated Universities, Inc. | Cells having cathodes containing polycarbon disulfide materials |
| US5518841A (en) * | 1993-02-12 | 1996-05-21 | Matsushita Electric Industrial Co., Ltd. | Composite cathode |
| US5460905A (en) | 1993-06-16 | 1995-10-24 | Moltech Corporation | High capacity cathodes for secondary cells |
| US5538812A (en) | 1994-02-04 | 1996-07-23 | Moltech Corporation | Electrolyte materials containing highly dissociated metal ion salts |
| JPH0831449A (ja) * | 1994-07-12 | 1996-02-02 | Moltec Corp | 二次電池用高容量電池 |
| US5424147A (en) * | 1994-07-15 | 1995-06-13 | Electric Fuel (E.F.L.) Ltd. | Water-activated battery |
| US5516598A (en) | 1994-07-28 | 1996-05-14 | Polyplus Battery Company, Inc. | Secondary cell using organosulfur/metal charge transfer materials as positive electrode |
| US5478676A (en) | 1994-08-02 | 1995-12-26 | Rexam Graphics | Current collector having a conductive primer layer |
| US5814420A (en) | 1994-11-23 | 1998-09-29 | Polyplus Battery Company, Inc. | Rechargeable positive electrodes |
| US5523179A (en) | 1994-11-23 | 1996-06-04 | Polyplus Battery Company | Rechargeable positive electrode |
| US5582623A (en) | 1994-11-23 | 1996-12-10 | Polyplus Battery Company, Inc. | Methods of fabricating rechargeable positive electrodes |
| US5686201A (en) | 1994-11-23 | 1997-11-11 | Polyplus Battery Company, Inc. | Rechargeable positive electrodes |
| US5601947A (en) | 1995-06-07 | 1997-02-11 | Moltech Corporation | Electroactive high storage capacity polycarbon-sulfide materials and electrolytic cells containing same |
| JPH11506799A (ja) * | 1995-06-07 | 1999-06-15 | モルテック コーポレイション | 電気活性な高蓄容量ポリアセチレン−コ−ポリイオウ物質およびそれを含む電解セル |
| US5529860A (en) | 1995-06-07 | 1996-06-25 | Moltech Corporation | Electroactive high storage capacity polyacetylene-co-polysulfur materials and electrolytic cells containing same |
| WO1997044840A1 (en) * | 1996-05-22 | 1997-11-27 | Moltech Corporation | Composite cathodes, electrochemical cells comprising novel composite cathodes, and processes for fabricating same |
| US6210831B1 (en) * | 1997-12-19 | 2001-04-03 | Moltech Corporation | Cathodes comprising electroactive sulfur materials and secondary batteries using same |
| US6110619A (en) * | 1997-12-19 | 2000-08-29 | Moltech Corporation | Electrochemical cells with cationic polymers and electroactive sulfur compounds |
| JP3333130B2 (ja) * | 1998-01-28 | 2002-10-07 | 松下電器産業株式会社 | 複合電極、その製造方法、およびリチウム二次電池 |
-
1998
- 1998-12-17 US US09/215,057 patent/US6302928B1/en not_active Expired - Lifetime
-
1999
- 1999-12-16 CN CNB998158666A patent/CN1168163C/zh not_active Expired - Fee Related
- 1999-12-16 WO PCT/US1999/030117 patent/WO2000036674A2/en not_active Ceased
- 1999-12-16 EP EP99968135A patent/EP1151487B1/en not_active Expired - Lifetime
- 1999-12-16 DE DE69906814T patent/DE69906814T2/de not_active Expired - Lifetime
- 1999-12-16 KR KR1020017007698A patent/KR100652926B1/ko not_active Expired - Fee Related
- 1999-12-16 JP JP2000588829A patent/JP2002532854A/ja active Pending
- 1999-12-16 AU AU24813/00A patent/AU2481300A/en not_active Abandoned
-
2001
- 2001-05-23 US US09/864,771 patent/US20010034934A1/en not_active Abandoned
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102010027950A1 (de) | 2010-04-20 | 2011-10-20 | Robert Bosch Gmbh | Kathodenzusammensetzung für Lithium-Schwefel-Zellen |
| WO2011131584A1 (de) | 2010-04-20 | 2011-10-27 | Robert Bosch Gmbh | Kathodenzusammensetzung für lithium-schwefel-zellen |
| WO2012059262A1 (de) | 2010-11-04 | 2012-05-10 | Robert Bosch Gmbh | Kathodenmaterial für lithium-schwefel-zelle |
| DE102010043400A1 (de) | 2010-11-04 | 2012-05-10 | Robert Bosch Gmbh | Kathodenmaterial für Lithium-Schwefel-Zelle |
| WO2013171023A1 (de) | 2012-05-18 | 2013-11-21 | Robert Bosch Gmbh | Verfahren zum herstellen einer elektrode für einen elektrochemischen energiespeicher und elektrochemischer energiespeicher |
| DE102012208311A1 (de) | 2012-05-18 | 2013-11-21 | Robert Bosch Gmbh | Verfahren zum Herstellen einer Elektrode für einen elektrochemischen Energiespeicher und elektrochemischer Energiespeicher |
| US9935311B2 (en) | 2012-05-18 | 2018-04-03 | Robert Bosch Gmbh | Method for manufacturing an electrode for an electrochemical energy store and electrochemical energy store |
| DE102014003128A1 (de) | 2014-03-03 | 2015-09-03 | Hochschule Aalen | Verbundmaterial |
| WO2015131977A1 (de) | 2014-03-03 | 2015-09-11 | Hochschule Aalen Technik Und Wirtschaft | Folienverbundmaterial |
| DE102021214966A1 (de) | 2021-12-22 | 2023-06-22 | Volkswagen Aktiengesellschaft | Verfahren zur Herstellung einer Kathode für eine Lithium-Ionen-Batteriezelle |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1334971A (zh) | 2002-02-06 |
| EP1151487A2 (en) | 2001-11-07 |
| DE69906814D1 (de) | 2003-05-15 |
| WO2000036674A2 (en) | 2000-06-22 |
| EP1151487B1 (en) | 2003-04-09 |
| CN1168163C (zh) | 2004-09-22 |
| US6302928B1 (en) | 2001-10-16 |
| US20010034934A1 (en) | 2001-11-01 |
| KR20010110410A (ko) | 2001-12-13 |
| KR100652926B1 (ko) | 2006-12-01 |
| AU2481300A (en) | 2000-07-03 |
| JP2002532854A (ja) | 2002-10-02 |
| WO2000036674A3 (en) | 2000-09-14 |
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