DE60034151T2 - Klebstoffe auf der basis von alpha-olefinpolymeren - Google Patents
Klebstoffe auf der basis von alpha-olefinpolymeren Download PDFInfo
- Publication number
- DE60034151T2 DE60034151T2 DE60034151T DE60034151T DE60034151T2 DE 60034151 T2 DE60034151 T2 DE 60034151T2 DE 60034151 T DE60034151 T DE 60034151T DE 60034151 T DE60034151 T DE 60034151T DE 60034151 T2 DE60034151 T2 DE 60034151T2
- Authority
- DE
- Germany
- Prior art keywords
- interpolymer
- determined
- polymer
- mol
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 52
- 239000004711 α-olefin Substances 0.000 title description 15
- 229920000098 polyolefin Polymers 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 103
- 229920000642 polymer Polymers 0.000 claims abstract description 64
- 230000001070 adhesive effect Effects 0.000 claims abstract description 52
- 238000000034 method Methods 0.000 claims abstract description 24
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000005977 Ethylene Substances 0.000 claims abstract description 8
- 238000006116 polymerization reaction Methods 0.000 claims description 33
- 239000003054 catalyst Substances 0.000 claims description 30
- 238000009472 formulation Methods 0.000 claims description 30
- 238000009826 distribution Methods 0.000 claims description 22
- 239000002904 solvent Substances 0.000 claims description 21
- 238000005481 NMR spectroscopy Methods 0.000 claims description 17
- 239000000758 substrate Substances 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 9
- 238000003860 storage Methods 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 7
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 229920013639 polyalphaolefin Polymers 0.000 claims description 6
- 229910052796 boron Inorganic materials 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 230000009257 reactivity Effects 0.000 claims description 4
- 150000005673 monoalkenes Chemical class 0.000 claims description 3
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 3
- 230000004927 fusion Effects 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 239000005022 packaging material Substances 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000003999 initiator Substances 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- 229920002959 polymer blend Polymers 0.000 abstract 1
- 229920005606 polypropylene copolymer Polymers 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 96
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 57
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 39
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 38
- 238000002844 melting Methods 0.000 description 33
- 230000008018 melting Effects 0.000 description 33
- 150000001875 compounds Chemical class 0.000 description 28
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 24
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 24
- 239000000243 solution Substances 0.000 description 23
- 239000000178 monomer Substances 0.000 description 22
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 20
- 239000003446 ligand Substances 0.000 description 19
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 18
- -1 polypropylene Polymers 0.000 description 18
- 239000004831 Hot glue Substances 0.000 description 16
- 238000005227 gel permeation chromatography Methods 0.000 description 13
- 150000001450 anions Chemical class 0.000 description 11
- 230000006399 behavior Effects 0.000 description 11
- 239000010935 stainless steel Substances 0.000 description 9
- 229910001220 stainless steel Inorganic materials 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 239000004743 Polypropylene Substances 0.000 description 8
- 238000002425 crystallisation Methods 0.000 description 8
- 230000008025 crystallization Effects 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000002243 precursor Substances 0.000 description 8
- 229910052723 transition metal Inorganic materials 0.000 description 8
- 239000012300 argon atmosphere Substances 0.000 description 7
- 229920001155 polypropylene Polymers 0.000 description 7
- 150000003624 transition metals Chemical class 0.000 description 7
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 6
- 239000012298 atmosphere Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- NDJMNNSJDIFFTH-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr+2]([SiH](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 Chemical compound [Cl-].[Cl-].CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr+2]([SiH](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 NDJMNNSJDIFFTH-UHFFFAOYSA-L 0.000 description 5
- LEOYKWIXWJXYQJ-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1C Chemical compound [Cl-].[Cl-].CC1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1C LEOYKWIXWJXYQJ-UHFFFAOYSA-L 0.000 description 5
- 239000012190 activator Substances 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 150000002902 organometallic compounds Chemical class 0.000 description 5
- 229920005604 random copolymer Polymers 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- 229920013640 amorphous poly alpha olefin Polymers 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 239000003085 diluting agent Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical compound C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000012943 hotmelt Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 125000002524 organometallic group Chemical group 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000002516 radical scavenger Substances 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000012718 coordination polymerization Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 229910052752 metalloid Inorganic materials 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 230000002000 scavenging effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 150000003623 transition metal compounds Chemical class 0.000 description 2
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 1
- SRHKOOPBMSDMED-UHFFFAOYSA-N CC1=C(C(=C(C(=C1C[Ti](CC1=CC=CC=C1)(CC1=CC=CC=C1)C1C=CC=C1)C)C)C)C Chemical compound CC1=C(C(=C(C(=C1C[Ti](CC1=CC=CC=C1)(CC1=CC=CC=C1)C1C=CC=C1)C)C)C)C SRHKOOPBMSDMED-UHFFFAOYSA-N 0.000 description 1
- GJDDRFCPFHFDNU-UHFFFAOYSA-N C[Si](C)(C)C[V] Chemical compound C[Si](C)(C)C[V] GJDDRFCPFHFDNU-UHFFFAOYSA-N 0.000 description 1
- AWRSKMDJAJASLT-UHFFFAOYSA-N C[Si](C)(C)C[Zr] Chemical compound C[Si](C)(C)C[Zr] AWRSKMDJAJASLT-UHFFFAOYSA-N 0.000 description 1
- COOXAWDWHWRVRD-UHFFFAOYSA-N C[Ti]C Chemical compound C[Ti]C COOXAWDWHWRVRD-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- 229910000799 K alloy Inorganic materials 0.000 description 1
- QAZMUCGKMKAGKA-UHFFFAOYSA-N N-(4-dimethylsilyl-2,2,3-trimethylpentan-3-yl)cyclopenta-2,4-dien-1-amine Chemical compound CC(C(C)(C(C)(C)C)NC1C=CC=C1)[SiH](C)C QAZMUCGKMKAGKA-UHFFFAOYSA-N 0.000 description 1
- 229920000034 Plastomer Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- FJMJPZLXUXRLLD-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1 FJMJPZLXUXRLLD-UHFFFAOYSA-L 0.000 description 1
- RLEZACANRPOGPQ-UHFFFAOYSA-L [Cl-].[Cl-].C1CC2CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CCC2CC1 Chemical compound [Cl-].[Cl-].C1CC2CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CCC2CC1 RLEZACANRPOGPQ-UHFFFAOYSA-L 0.000 description 1
- BQZTYWHJXFLPTA-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC2=CC=C3C=CC=CC3=C2C1[Zr+2]([SiH](C)C)C1C2=C3C=CC=CC3=CC=C2C=C1C Chemical compound [Cl-].[Cl-].CC1=CC2=CC=C3C=CC=CC3=C2C1[Zr+2]([SiH](C)C)C1C2=C3C=CC=CC3=CC=C2C=C1C BQZTYWHJXFLPTA-UHFFFAOYSA-L 0.000 description 1
- UNWKBZUIWISZEL-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](C)(C)C[Nb+2](C[Si](C)(C)C)C[Si](C)(C)C Chemical compound [Cl-].[Cl-].C[Si](C)(C)C[Nb+2](C[Si](C)(C)C)C[Si](C)(C)C UNWKBZUIWISZEL-UHFFFAOYSA-L 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000006664 bond formation reaction Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910052800 carbon group element Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- UHOVQNZJYSORNB-MICDWDOJSA-N deuteriobenzene Chemical compound [2H]C1=CC=CC=C1 UHOVQNZJYSORNB-MICDWDOJSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- RAABOESOVLLHRU-UHFFFAOYSA-N diazene Chemical compound N=N RAABOESOVLLHRU-UHFFFAOYSA-N 0.000 description 1
- 229910000071 diazene Inorganic materials 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012632 extractable Substances 0.000 description 1
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 230000008570 general process Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000003936 heterocyclopentadienyl group Chemical group 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 150000002602 lanthanoids Chemical group 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- 238000004811 liquid chromatography Methods 0.000 description 1
- 239000013627 low molecular weight specie Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000003863 metallic catalyst Substances 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- QSLMQGXOMLSFAW-UHFFFAOYSA-N methanidylbenzene;zirconium(4+) Chemical compound [Zr+4].[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1 QSLMQGXOMLSFAW-UHFFFAOYSA-N 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 229920001384 propylene homopolymer Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000003335 steric effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229920000428 triblock copolymer Polymers 0.000 description 1
- XBEXIHMRFRFRAM-UHFFFAOYSA-N tridodecylalumane Chemical compound CCCCCCCCCCCC[Al](CCCCCCCCCCCC)CCCCCCCCCCCC XBEXIHMRFRFRAM-UHFFFAOYSA-N 0.000 description 1
- LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical compound CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- 238000000214 vapour pressure osmometry Methods 0.000 description 1
- 125000002348 vinylic group Chemical group 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910001868 water Inorganic materials 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/10—Homopolymers or copolymers of propene
- C09J123/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US171715P | 1999-12-21 | ||
| US17171599P | 1999-12-22 | 1999-12-22 | |
| US19909300P | 2000-04-21 | 2000-04-21 | |
| US199093P | 2000-04-21 | ||
| PCT/US2000/035016 WO2001046278A2 (en) | 1999-12-21 | 2000-12-21 | Adhesive alpha-olefin inter-polymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60034151D1 DE60034151D1 (de) | 2007-05-10 |
| DE60034151T2 true DE60034151T2 (de) | 2008-01-10 |
Family
ID=26867350
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60034151T Expired - Lifetime DE60034151T2 (de) | 1999-12-21 | 2000-12-21 | Klebstoffe auf der basis von alpha-olefinpolymeren |
Country Status (13)
| Country | Link |
|---|---|
| US (4) | US6747114B2 (enExample) |
| EP (3) | EP1263815B1 (enExample) |
| JP (1) | JP4966463B2 (enExample) |
| KR (1) | KR100718424B1 (enExample) |
| CN (1) | CN1333032C (enExample) |
| AT (1) | ATE358144T1 (enExample) |
| AU (2) | AU777944B2 (enExample) |
| BR (1) | BR0016618B1 (enExample) |
| CA (2) | CA2414498C (enExample) |
| DE (1) | DE60034151T2 (enExample) |
| ES (1) | ES2282158T3 (enExample) |
| MX (1) | MXPA02006199A (enExample) |
| WO (2) | WO2001046277A2 (enExample) |
Families Citing this family (189)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7232871B2 (en) * | 1997-08-12 | 2007-06-19 | Exxonmobil Chemical Patents Inc. | Propylene ethylene polymers and production process |
| US6635715B1 (en) * | 1997-08-12 | 2003-10-21 | Sudhin Datta | Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers |
| US6921794B2 (en) * | 1997-08-12 | 2005-07-26 | Exxonmobil Chemical Patents Inc. | Blends made from propylene ethylene polymers |
| AU4962399A (en) | 1998-07-01 | 2000-01-24 | Exxon Chemical Patents Inc. | Elastic blends comprising crystalline polymer and crystallizable polymers of propylene |
| WO2001019866A1 (en) * | 1999-09-10 | 2001-03-22 | The University Of Sydney | Dipeptidyl peptidases |
| WO2001046277A2 (en) * | 1999-12-22 | 2001-06-28 | Exxonmobil Chemical Patents, Inc. | Polypropylene-based adhesive compositions |
| US6657009B2 (en) * | 2000-12-29 | 2003-12-02 | Kimberly-Clark Worldwide, Inc. | Hot-melt adhesive having improved bonding strength |
| US6872784B2 (en) * | 2000-12-29 | 2005-03-29 | Kimberly-Clark Worldwide, Inc. | Modified rubber-based adhesives |
| US20020123538A1 (en) * | 2000-12-29 | 2002-09-05 | Peiguang Zhou | Hot-melt adhesive based on blend of amorphous and crystalline polymers for multilayer bonding |
| US6627623B2 (en) * | 2001-02-21 | 2003-09-30 | Rutgers, The State University | Inducing cell apoptosis and treating cancer using 1-O-acetylbritannilactone or 1,6-O,O-diacetylbritannilactone |
| JP5156167B2 (ja) | 2001-04-12 | 2013-03-06 | エクソンモービル・ケミカル・パテンツ・インク | プロピレン−エチレンポリマー及び製造法 |
| GB0111020D0 (en) * | 2001-05-04 | 2001-06-27 | Borealis Tech Oy | Process |
| CN1276018C (zh) * | 2001-06-22 | 2006-09-20 | 埃克森美孚化学专利公司 | 作为抗冲改性剂的茂金属生产的极低密聚乙烯或线型低密度聚乙烯 |
| US6943215B2 (en) * | 2001-11-06 | 2005-09-13 | Dow Global Technologies Inc. | Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers |
| US6927256B2 (en) * | 2001-11-06 | 2005-08-09 | Dow Global Technologies Inc. | Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent |
| EP1444276A1 (en) * | 2001-11-06 | 2004-08-11 | Dow Global Technologies, Inc. | Isotactic propylene copolymers, their preparation and use |
| US6906160B2 (en) * | 2001-11-06 | 2005-06-14 | Dow Global Technologies Inc. | Isotactic propylene copolymer fibers, their preparation and use |
| US6960635B2 (en) * | 2001-11-06 | 2005-11-01 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
| US6992131B2 (en) | 2002-03-22 | 2006-01-31 | Exxonmobil Chemical Patents Inc. | Adhesives |
| US8003725B2 (en) | 2002-08-12 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Plasticized hetero-phase polyolefin blends |
| US7998579B2 (en) | 2002-08-12 | 2011-08-16 | Exxonmobil Chemical Patents Inc. | Polypropylene based fibers and nonwovens |
| US7271209B2 (en) | 2002-08-12 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Fibers and nonwovens from plasticized polyolefin compositions |
| WO2004014997A2 (en) | 2002-08-12 | 2004-02-19 | Exxonmobil Chemical Patents Inc. | Plasticized polyolefin compositions |
| US7531594B2 (en) | 2002-08-12 | 2009-05-12 | Exxonmobil Chemical Patents Inc. | Articles from plasticized polyolefin compositions |
| US7541402B2 (en) * | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US7700707B2 (en) * | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US8653169B2 (en) | 2002-10-15 | 2014-02-18 | Exxonmobil Chemical Patents Inc. | Propylene copolymers for adhesive applications |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| EP2261292B1 (en) * | 2002-10-15 | 2014-07-23 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions |
| US8618219B2 (en) * | 2002-10-15 | 2013-12-31 | Exxonmobil Chemical Patents Inc. | Propylene copolymers for adhesive applications |
| US7067585B2 (en) * | 2002-10-28 | 2006-06-27 | Bostik, Inc. | Hot melt adhesive composition based on a random copolymer of isotactic polypropylene |
| US7579407B2 (en) | 2002-11-05 | 2009-08-25 | Dow Global Technologies Inc. | Thermoplastic elastomer compositions |
| US7459500B2 (en) * | 2002-11-05 | 2008-12-02 | Dow Global Technologies Inc. | Thermoplastic elastomer compositions |
| US20040086621A1 (en) * | 2002-11-06 | 2004-05-06 | Kraft Foods Holdings, Inc. | Reduced calorie fat |
| US7314901B2 (en) * | 2003-01-30 | 2008-01-01 | Exxonmobil Chemical Patents Inc. | Polypropylene films |
| US7265193B2 (en) | 2003-01-31 | 2007-09-04 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| US6780936B1 (en) * | 2003-02-11 | 2004-08-24 | Exxonmobil Chemical Patents Inc. | Diene-modified propylene polymer nucleating agents |
| US6984696B2 (en) * | 2003-03-28 | 2006-01-10 | Exxonmobil Chemical Patents Inc. | Elastic blends of semicrystalline propylene polymers and high glass transition temperature materials |
| US8192813B2 (en) | 2003-08-12 | 2012-06-05 | Exxonmobil Chemical Patents, Inc. | Crosslinked polyethylene articles and processes to produce same |
| US7763676B2 (en) | 2003-08-25 | 2010-07-27 | Dow Global Technologies Inc. | Aqueous polymer dispersions and products from those dispersions |
| TW200517426A (en) * | 2003-08-25 | 2005-06-01 | Dow Global Technologies Inc | Aqueous dispersion, its production method, and its use |
| US7270889B2 (en) * | 2003-11-04 | 2007-09-18 | Kimberly-Clark Worldwide, Inc. | Tackified amorphous-poly-alpha-olefin-bonded structures |
| US7955710B2 (en) * | 2003-12-22 | 2011-06-07 | Kimberly-Clark Worldwide, Inc. | Ultrasonic bonding of dissimilar materials |
| US20050133145A1 (en) * | 2003-12-22 | 2005-06-23 | Kimberly-Clark Worldwide, Inc. | Laminated absorbent product with ultrasonic bond |
| US20050136224A1 (en) * | 2003-12-22 | 2005-06-23 | Kimberly-Clark Worldwide, Inc. | Ultrasonic bonding and embossing of an absorbent product |
| WO2005095473A1 (en) | 2004-03-12 | 2005-10-13 | Basell Polyolefine Gmbh | Process for polymerizing 1-hexene or higher alpha-olefins |
| WO2005095474A1 (en) | 2004-03-12 | 2005-10-13 | Basell Polyolefine Gmbh | Process for polymerizing 1-hexene or higher alpha-olefins |
| CN1961053A (zh) * | 2004-03-19 | 2007-05-09 | 三井化学株式会社 | 粘着材、粘着薄膜及其使用方法 |
| US7589145B2 (en) * | 2004-04-15 | 2009-09-15 | Exxonmobil Chemical Patents Inc. | Syndiotactic rich polyolefins |
| US7645829B2 (en) * | 2004-04-15 | 2010-01-12 | Exxonmobil Chemical Patents Inc. | Plasticized functionalized propylene copolymer adhesive composition |
| CA2566132A1 (en) * | 2004-05-11 | 2005-11-24 | Huntsman Polymers Corporation | Hot-melt adhesive compositions based on olefin co-polymers |
| EP1745094A4 (en) * | 2004-05-11 | 2009-02-25 | Huntsman Polymers Corp | MELT ADHESIVE COMPOSITIONS BASED ON OLEFIN COPOLYMERS |
| KR101197933B1 (ko) * | 2004-06-28 | 2012-11-05 | 다우 글로벌 테크놀로지스 엘엘씨 | 다중 구조 적층체용 접착 촉진제 |
| CN100351304C (zh) * | 2004-08-25 | 2007-11-28 | 三井化学株式会社 | 树脂组合物及由此获得的薄膜 |
| US20060069209A1 (en) * | 2004-09-29 | 2006-03-30 | Klosiewicz Daniel W | Heat stable functionalized polyolefin emulsions |
| WO2006044149A1 (en) * | 2004-10-13 | 2006-04-27 | Exxonmobil Chemical Patents Inc. | Elastomeric reactor blend compositions |
| ES2370503T3 (es) * | 2004-10-13 | 2011-12-19 | Exxonmobil Chemical Patents Inc. | Composiciones de mezclas de reactor elastoméricas. |
| GB2420348B (en) * | 2004-10-28 | 2009-11-18 | Exxonmobil Chem Patents Inc | Syndiotactic rich polyolefins |
| ATE435887T1 (de) * | 2004-12-17 | 2009-07-15 | Exxonmobil Chem Patents Inc | Folien aus polymerblends |
| CN104963085A (zh) * | 2004-12-17 | 2015-10-07 | 埃克森美孚化学专利公司 | 聚合物共混物和由其获得的无纺制品 |
| ES2331741T3 (es) * | 2004-12-17 | 2010-01-14 | Exxonmobil Chemical Patents Inc. | Mezclas polimericas heterogeneas y articulos moldeados a partir de las mismas. |
| JP4782800B2 (ja) * | 2004-12-17 | 2011-09-28 | エクソンモービル・ケミカル・パテンツ・インク | 均一ポリマー・ブレンドおよび該ブレンドからの製品 |
| US8389615B2 (en) | 2004-12-17 | 2013-03-05 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin |
| ES2471381T3 (es) * | 2004-12-21 | 2014-06-26 | Dow Global Technologies Llc | Compuestos adhesivos a base de poli(propileno) |
| JP5590517B2 (ja) * | 2005-04-14 | 2014-09-17 | エクソンモービル・ケミカル・パテンツ・インク | 透明ポリオレフィン組成物 |
| DE102005020205A1 (de) † | 2005-04-28 | 2006-11-09 | Jowat Ag | Nichtreaktive thermoplastische Schmelzklebstoffe auf Basis von metallocenkatalytisch hergestellten Polyolefinen |
| US7812085B2 (en) * | 2005-06-24 | 2010-10-12 | Exxonmobil Chemical Patents Inc. | Functionalized propylene copolymer adhesive composition |
| WO2007002177A1 (en) | 2005-06-24 | 2007-01-04 | Exxonmobil Chemical Patents Inc. | Plasticized functionalized propylene copolymer adhesive composition |
| US8513347B2 (en) | 2005-07-15 | 2013-08-20 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions |
| WO2007013185A1 (ja) * | 2005-07-29 | 2007-02-01 | Matsumura Oil Research Corp. | 接着剤組成物 |
| TW200713336A (en) * | 2005-08-05 | 2007-04-01 | Dow Global Technologies Inc | Polypropylene-based wire and cable insulation or jacket |
| WO2007022372A2 (en) * | 2005-08-17 | 2007-02-22 | Bostik, Inc. | Polyolefin based hot melt adhesive having improved heat resistance |
| WO2007047657A1 (en) | 2005-10-20 | 2007-04-26 | Exxonmobil Chemical Patents Inc. | Hydrocarbon resid processing |
| US20070142801A1 (en) * | 2005-12-15 | 2007-06-21 | Peiguang Zhou | Oil-resistant elastic attachment adhesive and laminates containing it |
| CA2641818C (en) * | 2006-02-02 | 2012-04-10 | Basell Polyolefine Gmbh | Propylene homopolymer melt blown resins |
| DE102006049089A1 (de) * | 2006-10-18 | 2008-04-30 | Clariant International Limited | Heißschmelzklebemasse |
| US9096747B2 (en) * | 2007-04-09 | 2015-08-04 | Exxonmobil Chemical Patents Inc. | Isotactic polypropylene nucleation |
| US8263707B2 (en) * | 2007-04-09 | 2012-09-11 | Exxonmobil Chemical Patents Inc. | Soft heterogeneous isotactic polypropylene compositions |
| ATE547469T1 (de) | 2007-04-09 | 2012-03-15 | Exxonmobil Chem Patents Inc | Weiche heterogene isotaktische polypropylenzusammensetzungen |
| US9232808B2 (en) | 2007-06-29 | 2016-01-12 | Kraft Foods Group Brands Llc | Processed cheese without emulsifying salts |
| US20090053959A1 (en) * | 2007-08-21 | 2009-02-26 | Sudhin Datta | Soft and Elastic Nonwoven Polypropylene Compositions |
| US7868104B2 (en) * | 2007-10-26 | 2011-01-11 | Exxonmobil Chemical Patents Inc. | Crystallizable propylene copolymers |
| US20090111945A1 (en) * | 2007-10-26 | 2009-04-30 | Sudhin Datta | Soft Homogeneous Isotactic Polypropylene Compositions |
| US7906588B2 (en) * | 2007-10-26 | 2011-03-15 | Exxonmobil Chemical Patents Inc. | Soft heterogeneous isotactic polypropylene compositions |
| DE102008005945A1 (de) | 2008-01-24 | 2009-07-30 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Polyolefinen mit syndiotaktischen Strukturelementen, Polyolefine und deren Verwendung |
| DE102008005947A1 (de) | 2008-01-24 | 2009-07-30 | Evonik Degussa Gmbh | Polyolefine mit Ataktischen Strukturelementen, Verfahren zu deren Herstellung und deren Verwendung |
| DE102008005949A1 (de) | 2008-01-24 | 2009-07-30 | Evonik Degussa Gmbh | Polyolefine mit Isotaktischen Strukturelementen, Verfahren zu deren Herstellung und deren Verwendung |
| US8242198B2 (en) | 2008-06-09 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions |
| US8283400B2 (en) * | 2008-06-09 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions |
| US8431642B2 (en) * | 2008-06-09 | 2013-04-30 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| DE102008045802A1 (de) | 2008-09-05 | 2010-03-11 | Henkel Ag & Co. Kgaa | Schmelzklebstoff auf Basis von Metallocene-katalysierten Olefin-α-Olefin Copolymeren |
| CN102159660B (zh) | 2008-09-18 | 2013-10-16 | 三井化学株式会社 | 粘合剂组合物以及由该组合物构成的粘合剂 |
| US20100266824A1 (en) * | 2009-04-21 | 2010-10-21 | Alistair Duncan Westwood | Elastic Meltblown Laminate Constructions and Methods for Making Same |
| US8710148B2 (en) | 2011-12-02 | 2014-04-29 | Exxonmobil Chemical Patents Inc. | Polymer compositions and nonwoven compositions prepared therefrom |
| US8748693B2 (en) * | 2009-02-27 | 2014-06-10 | Exxonmobil Chemical Patents Inc. | Multi-layer nonwoven in situ laminates and method of producing the same |
| US9498932B2 (en) * | 2008-09-30 | 2016-11-22 | Exxonmobil Chemical Patents Inc. | Multi-layered meltblown composite and methods for making same |
| US8664129B2 (en) | 2008-11-14 | 2014-03-04 | Exxonmobil Chemical Patents Inc. | Extensible nonwoven facing layer for elastic multilayer fabrics |
| US20100266818A1 (en) * | 2009-04-21 | 2010-10-21 | Alistair Duncan Westwood | Multilayer Composites And Apparatuses And Methods For Their Making |
| US10161063B2 (en) * | 2008-09-30 | 2018-12-25 | Exxonmobil Chemical Patents Inc. | Polyolefin-based elastic meltblown fabrics |
| US9168718B2 (en) * | 2009-04-21 | 2015-10-27 | Exxonmobil Chemical Patents Inc. | Method for producing temperature resistant nonwovens |
| JP5481489B2 (ja) * | 2008-11-19 | 2014-04-23 | エクソンモービル・ケミカル・パテンツ・インク | 粘着性組成物及び粘着性組成物を作成する方法 |
| DE102008063723A1 (de) | 2008-12-19 | 2010-06-24 | Henkel Ag & Co. Kgaa | Kontaktklebstoff aus Basis von Metallocene-katalysierten Olefin-C3-C20-Olefin Copolymeren |
| KR101576907B1 (ko) * | 2009-02-20 | 2015-12-14 | 엘에스전선 주식회사 | 유연성과 가교 특성이 뛰어난 전선용 절연 재료 및 이를 갖춘 전선 |
| CN102365300B (zh) * | 2009-03-27 | 2014-08-27 | 汉高股份有限及两合公司 | 含有聚合物体系的粘合剂 |
| US20100276057A1 (en) * | 2009-04-30 | 2010-11-04 | H.B. Fuller Company | Ethylene-butene copolymer, adhesive composition including the same, and method of making and using the same |
| CN102449091B (zh) * | 2009-05-29 | 2014-05-07 | 埃克森美孚化学专利公司 | 聚烯烃粘合剂组合物及其制备方法 |
| WO2010147706A2 (en) * | 2009-06-16 | 2010-12-23 | Exxonmobil Chemical Patents Inc. | Polyolefin compositions for coating applications |
| US20100316820A1 (en) * | 2009-06-16 | 2010-12-16 | Rainer Kolb | Composite Materials Comprising Propylene-Based Polymer Blend Coatings |
| US20110059277A1 (en) * | 2009-09-04 | 2011-03-10 | Rainer Kolb | Elastomeric Surface Coatings for Plastic Articles |
| US9017593B2 (en) * | 2009-06-16 | 2015-04-28 | Exxonmobil Chemical Patents Inc. | Composite materials comprising propylene-based polymer blend coatings |
| DE102009027445A1 (de) | 2009-07-03 | 2011-01-05 | Evonik Degussa Gmbh | Modifizierte Polyolefine mit besonderem Eigenschaftsprofil, Verfahren zu deren Herstellung und deren Verwendung |
| DE102009027446A1 (de) * | 2009-07-03 | 2011-01-05 | Evonik Degussa Gmbh | Modifizierte Polyolefine mit besonderem Eigenschaftsprofil, Verfahren zu deren Herstellung und deren Verwendung |
| TR201900737T4 (tr) * | 2009-07-24 | 2019-02-21 | Bostik Inc | Olefin blok kopoli̇merleri̇ bazli sicakta eri̇yen yapişkan. |
| US8709315B2 (en) | 2009-08-18 | 2014-04-29 | Exxonmobil Chemical Patents Inc. | Process for making thermoplastic polymer pellets |
| EP2467441B1 (en) | 2009-08-20 | 2014-03-05 | Henkel Corporation | Low application temperature hot melt adhesive |
| US20110054117A1 (en) * | 2009-08-27 | 2011-03-03 | Hall Gregory K | Polyolefin Adhesive Compositions and Method of Making Thereof |
| WO2011053406A1 (en) * | 2009-10-29 | 2011-05-05 | Exxonmobil Chemical Patents Inc. | Pressure-sensitive hot melt adhesive compositions |
| US8668975B2 (en) * | 2009-11-24 | 2014-03-11 | Exxonmobil Chemical Patents Inc. | Fabric with discrete elastic and plastic regions and method for making same |
| RU2557614C2 (ru) | 2010-02-26 | 2015-07-27 | Интерконтинентал Грейт Брэндс ЛЛС | Уф-отверждаемый самоклеющийся материал с низкой липкостью для повторно укупориваемых упаковок |
| EP2539414A1 (en) | 2010-02-26 | 2013-01-02 | Kraft Foods Global Brands LLC | Reclosable package using low tack adhesive |
| KR101816334B1 (ko) * | 2010-07-27 | 2018-01-08 | 헨켈 아게 운트 코. 카게아아 | 압출에 의한 접착제 제조 방법 |
| WO2012041838A1 (de) * | 2010-09-27 | 2012-04-05 | Henkel Ag & Co. Kgaa | Verklebung mit schmelzklebstoffen |
| WO2012051239A1 (en) * | 2010-10-15 | 2012-04-19 | Exxonmobil Chemical Patents Inc. | Polypropylene-based adhesive compositions |
| WO2012064468A2 (en) | 2010-11-09 | 2012-05-18 | Exxonmobil Chemical Patents Inc. | Meltblown nonwoven compositions and methods for making them |
| US9376597B2 (en) | 2010-11-19 | 2016-06-28 | Henkel Ag & Co. Kgaa | Adhesive composition and use thereof |
| EP3480273B1 (en) * | 2010-11-19 | 2020-10-07 | Henkel AG & Co. KGaA | Adhesive compositions and use thereof |
| JP5705241B2 (ja) | 2011-01-18 | 2015-04-22 | 三井化学株式会社 | 接着性樹脂組成物およびそれから得られるホットメルト接着剤 |
| US20120213956A1 (en) * | 2011-02-23 | 2012-08-23 | Adherent Laboratories, Inc. | Fugitive adhesive and method |
| WO2012149391A1 (en) | 2011-04-28 | 2012-11-01 | Adherent Laboratories, Inc. | Polyolefin based hot melt adhesive composition |
| US8623480B2 (en) | 2011-06-27 | 2014-01-07 | H. B. Fuller Company | Hot melt adhesive compositions including olefinic polymer blends and articles including the same |
| CN103649258B (zh) * | 2011-06-27 | 2016-07-06 | H.B.富勒公司 | 自由基引发剂改性的包含官能化聚乙烯和丙烯-α-烯烃聚合物的热熔粘合剂组合物 |
| US8614271B2 (en) | 2011-06-27 | 2013-12-24 | H.B. Fuller Company | Propylene-alpha-olefin polymers, hot melt adhesive compositions that include propylene-alpha-olefin polymers and articles that include the same |
| JP5850682B2 (ja) | 2011-09-16 | 2016-02-03 | ヘンケルジャパン株式会社 | ホットメルト接着剤 |
| JP5850683B2 (ja) | 2011-09-16 | 2016-02-03 | ヘンケルジャパン株式会社 | ホットメルト接着剤 |
| JP5924894B2 (ja) | 2011-09-16 | 2016-05-25 | ヘンケルジャパン株式会社 | 使い捨て製品用ホットメルト接着剤 |
| US10059081B2 (en) | 2011-12-22 | 2018-08-28 | Exxonmobil Chemical Patents Inc. | Fibers and nonwoven materials prepared therefrom |
| US9505957B2 (en) * | 2012-03-09 | 2016-11-29 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions comprising nucleating agents for improved set time |
| EP2823011B1 (en) * | 2012-03-09 | 2017-01-18 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions |
| JP5826378B2 (ja) * | 2012-03-28 | 2015-12-02 | 三井化学株式会社 | プロピレン・α−オレフィン共重合体及びその用途 |
| AU2013290789B2 (en) * | 2012-07-16 | 2016-06-30 | Bostik, Inc. | Polypropylene impact copolymer based hot melt adhesive |
| BR112015000625A2 (pt) | 2012-07-17 | 2017-06-27 | Henkel Ag & Co Kgaa | elementos protetores feitos de adesivos de poliolefina termofundidos |
| JP5947153B2 (ja) | 2012-08-28 | 2016-07-06 | ヘンケルジャパン株式会社 | ホットメルト接着剤 |
| US9241843B2 (en) | 2012-09-19 | 2016-01-26 | The Procter & Gamble Company | Article with tackifier-free adhesive |
| US8865824B2 (en) | 2012-09-19 | 2014-10-21 | IFS Industries Inc. | Hot melt adhesive |
| SG11201501860SA (en) * | 2012-10-12 | 2015-04-29 | Exxonmobil Chem Patents Inc | Polyolefin adhesive compositions comprising nucleating agents for improved set time |
| WO2014070414A1 (en) * | 2012-10-31 | 2014-05-08 | Exxonmobil Chemical Patents Inc. | Propylene copolymer compositions and processes to produce them |
| US9322114B2 (en) | 2012-12-03 | 2016-04-26 | Exxonmobil Chemical Patents Inc. | Polypropylene fibers and fabrics |
| US9267060B2 (en) | 2013-02-15 | 2016-02-23 | H.B. Fuller Company | Reaction product of propylene polymer and wax, graft copolymers derived from polypropylene polymer and wax, hot melt adhesive compositions including the same, and methods of using and making the same |
| US9593235B2 (en) | 2013-02-15 | 2017-03-14 | H.B. Fuller Company | Reaction product of propylene polymer and wax, graft copolymers derived from polypropylene polymer and wax, hot melt adhesive compositions including the same, and methods of using and making the same |
| MX363710B (es) | 2013-05-23 | 2019-03-29 | Bostik Inc | Adhesivo termofusible basado en homopolimeros de polipropileno de bajo punto de fusion. |
| EP3003410B1 (en) * | 2013-05-29 | 2018-10-24 | H. B. Fuller Company | An elastic attachment adhesive and a disposable absorbent article made with the same |
| SG10201709919RA (en) | 2013-06-04 | 2017-12-28 | Exxonmobil Chemical Patents Inc | Polymer compositions and nonwoven compositions prepared therefrom |
| US9522213B2 (en) | 2013-06-18 | 2016-12-20 | H.B. Fuller Company | Pressure-sensitive hot melt adhesive composition including propylene thermoplastic elastomer and articles including the same |
| US11549201B2 (en) | 2013-06-18 | 2023-01-10 | Exxonmobil Chemicals Patents Inc. | Fibers and nonwoven materials prepared therefrom |
| JP6142085B2 (ja) | 2013-06-18 | 2017-06-07 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 繊維及びこれから調製された不織材料 |
| US10307995B2 (en) | 2013-07-16 | 2019-06-04 | Bostik, Inc. | Polypropylene impact copolymer based hot melt adhesive |
| US10022941B2 (en) * | 2013-09-12 | 2018-07-17 | Inteplast Group Corporation | Multilayer matte biaxially oriented polypropylene film with ultra low seal initiation temperature |
| US9290589B2 (en) * | 2013-12-13 | 2016-03-22 | Exxonmobil Chemical Patents Inc. | Cyclopentadienyl-substituted salan catalysts |
| US20150174281A1 (en) | 2013-12-19 | 2015-06-25 | The Procter & Gamble Company | Hot melt adhesive |
| US9399686B2 (en) | 2014-02-07 | 2016-07-26 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
| US11267916B2 (en) | 2014-02-07 | 2022-03-08 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
| US10696765B2 (en) | 2014-02-07 | 2020-06-30 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer |
| US10308740B2 (en) | 2014-02-07 | 2019-06-04 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
| US10647795B2 (en) | 2014-02-07 | 2020-05-12 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
| US10723824B2 (en) | 2014-02-07 | 2020-07-28 | Eastman Chemical Company | Adhesives comprising amorphous propylene-ethylene copolymers |
| US20150299525A1 (en) | 2014-04-18 | 2015-10-22 | IFS Industries Inc. | Low density and high performance packaging hot melt |
| WO2016053468A1 (en) | 2014-09-30 | 2016-04-07 | Exxonmobil Chemical Patents Inc. | Bimodal polypropylenes and method of making same |
| WO2016057124A1 (en) | 2014-10-06 | 2016-04-14 | Exxonmobil Chemical Patents Inc. | Thermoplastic polyolefin containing amorphous ethylene elastomer |
| PL3209742T3 (pl) | 2014-10-23 | 2022-03-21 | Henkel Ag & Co. Kgaa | Kleje topliwe do folii poliolefinowych |
| WO2016073868A1 (en) | 2014-11-07 | 2016-05-12 | H.B. Fuller Company | Hot melt adhesive compositions that include semi-crystalline propylene polymer and wax and articles including the same |
| EP3029101B1 (en) * | 2014-12-04 | 2017-02-15 | ExxonMobil Chemical Patents Inc. | Multi-modal polymer blend, hot melt adhesive comprising same and use thereof |
| CN104479594A (zh) * | 2014-12-31 | 2015-04-01 | 广州鹿山新材料股份有限公司 | 一种粘接非极性材料用的热熔胶及其制备方法 |
| EP3268442B1 (en) * | 2015-03-02 | 2022-08-10 | Henkel IP & Holding GmbH | Stretch laminates |
| CN107949613B (zh) * | 2015-07-24 | 2021-02-26 | 陶氏环球技术有限责任公司 | 含有低分子量丙烯类聚合物的组合物 |
| EP3159387A1 (en) * | 2015-10-23 | 2017-04-26 | Bostik Sa | Hot-melt adhesive composition for elastic attachments |
| CN105219324B (zh) * | 2015-10-27 | 2018-06-29 | 深圳市同德新材料科技有限公司 | 一种用于汽车滤清器的热熔胶及其制备方法 |
| WO2017105411A1 (en) * | 2015-12-15 | 2017-06-22 | Halliburton Energy Services, Inc. | Real time tracking of bending forces and fatigue in a tubing guide |
| ES2813613T3 (es) | 2016-01-14 | 2021-03-24 | Bostik Inc | Composición adhesiva termofusible basada en una mezcla de copolímeros de propileno preparados usando catalizadores y procedimientos de sitio único |
| WO2017177164A1 (en) * | 2016-04-08 | 2017-10-12 | H.B. Fuller Company | High cohesive strength polyolefin construction adhesive |
| PT3235833T (pt) * | 2016-04-22 | 2019-02-19 | Borealis Ag | Processo de viscorredução |
| CA3024733C (en) | 2016-07-01 | 2023-07-04 | H.B. Fuller Company | Propylene polymer-based hot melt adhesive composition exhibiting fast set time and articles including the same |
| MX2019001331A (es) | 2016-08-03 | 2019-07-08 | Fuller H B Co | Una composicion adhesiva termofusible para fijacion elastica y un articulo absorbente desechable elaborado con esta. |
| US10822481B2 (en) | 2017-01-05 | 2020-11-03 | Exxonmobil Chemical Patents Inc. | Thermoplastic polyolefin compositions with ethylene-propylene copolymers |
| US11365329B2 (en) | 2017-11-10 | 2022-06-21 | Bostik, Inc. | Hot melt adhesive compositions based on propylene-based polymers and methods for using same |
| IT201800005783A1 (it) | 2018-05-28 | 2019-11-28 | Adesivi termofusibili comprendenti una composizione polimerica bimodale formata da poliolefine a bassa stereospecificità | |
| CN112119119A (zh) | 2018-06-13 | 2020-12-22 | 陶氏环球技术有限责任公司 | 含有低分子量丙烯基聚合物和烯烃多嵌段共聚物的组合物 |
| WO2021011390A1 (en) * | 2019-07-12 | 2021-01-21 | Bostik, Inc. | Tackifier-free hot melt adhesive compositions suitable for use in a disposable hygiene article |
| CN113429920A (zh) * | 2021-07-13 | 2021-09-24 | 安徽国风塑业股份有限公司 | 一种耐水耐热的pp热熔胶及其制备方法 |
Family Cites Families (156)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US133966A (en) | 1872-12-17 | Improvement in reel-rakes for harvesters | ||
| NL270258A (enExample) | 1960-10-17 | |||
| NL296509A (enExample) | 1962-09-10 | |||
| BE755430A (fr) | 1969-08-30 | 1971-02-01 | Fahr Ag Maschf | Roue de ratelage pour machines de fenaison |
| US3987122A (en) * | 1972-04-03 | 1976-10-19 | Exxon Research And Engineering Company | Thermoplastic adhesive compositions |
| US3821143A (en) * | 1973-03-22 | 1974-06-28 | Du Pont | Hot melt adhesive composition containing a branched elastomeric copolymer |
| US3882197A (en) | 1973-06-21 | 1975-05-06 | Du Pont | Alpha-olefin copolymer blends |
| US3888949A (en) | 1973-06-21 | 1975-06-10 | Du Pont | Blends of propylene-alpha-olefin copolymers and polypropylene |
| US4217428A (en) | 1975-03-31 | 1980-08-12 | Eastman Kodak Company | Blends of substantially amorphous higher 1-olefin copolymers and tackifying resins useful as pressure-sensitive adhesives |
| US3954697A (en) | 1975-03-31 | 1976-05-04 | Eastman Kodak Company | Poly(higher-1-olefin-co-propylene) copolymers as hot-melt, pressure-sensitive adhesives |
| GB1489108A (en) | 1975-05-12 | 1977-10-19 | Uniroyal Ltd | Olefin polymer compositions |
| US4178272A (en) | 1977-03-02 | 1979-12-11 | Eastman Kodak Company | Hot-melt adhesvies for bonding polyethylene |
| US4120916A (en) * | 1977-03-02 | 1978-10-17 | Eastman Kodak Company | Amorphous and crystalline polyolefin based hot-melt adhesive |
| US4210570A (en) * | 1978-01-06 | 1980-07-01 | Eastman Kodak Company | Blends of substantially amorphous olefin copolymers, compatible tackifying resins and plasticizing oils useful as hot melt, pressure-sensitive adhesives |
| DE3127133A1 (de) | 1981-07-09 | 1983-01-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von polyolefinen und deren copolymerisaten |
| US4345349A (en) | 1981-07-30 | 1982-08-24 | National Starch And Chemical Corporation | Adhesive for perfect bound books and method of using same |
| IT1156552B (it) | 1982-03-02 | 1987-02-04 | Gian Luigi Gamberini | Centralina idraulica miniaturizzata con pompa a doppio senso di rotazione |
| US4394915A (en) | 1982-04-12 | 1983-07-26 | Findley Adhesives Inc. | Hot melt adhesive compositions and bottle assemblies using said compositions |
| US4461872A (en) | 1983-02-22 | 1984-07-24 | E. I. Du Pont De Nemours And Company | Blends of a propylene/α-olefin copolymer with isotactic prolypropylene |
| US4743391A (en) | 1983-03-28 | 1988-05-10 | Chevron Research Company | Method for oxidatively degrading an olefinic polymer |
| US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| US4540753A (en) | 1983-06-15 | 1985-09-10 | Exxon Research & Engineering Co. | Narrow MWD alpha-olefin copolymers |
| US5231126A (en) * | 1985-04-01 | 1993-07-27 | Shi Guan Yi | Beta-crystalline form of isotactic polypropylene and method for forming the same |
| US4749505A (en) | 1985-07-08 | 1988-06-07 | Exxon Chemical Patents Inc. | Olefin polymer viscosity index improver additive useful in oil compositions |
| US4665208A (en) | 1985-07-11 | 1987-05-12 | Exxon Chemical Patents Inc. | Process for the preparation of alumoxanes |
| JPH06104698B2 (ja) | 1985-11-20 | 1994-12-21 | 三井石油化学工業株式会社 | プロピレン系ランダム共重合体およびそれからなる熱可塑性樹脂用ヒートシール性改善剤 |
| JPH06104699B2 (ja) | 1985-11-20 | 1994-12-21 | 三井石油化学工業株式会社 | １―ブテン系ランダム共重合体およびそれからなる熱可塑性樹脂用ヒートシール性改善剤 |
| US4752597A (en) | 1985-12-12 | 1988-06-21 | Exxon Chemical Patents Inc. | New polymerization catalyst |
| EP0594218B1 (en) | 1986-09-24 | 1999-03-17 | Mitsui Chemicals, Inc. | Process for polymerizing olefins |
| JPH0780933B2 (ja) | 1986-11-20 | 1995-08-30 | 三井石油化学工業株式会社 | オレフインの重合方法 |
| US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| US5198401A (en) | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US5391629A (en) | 1987-01-30 | 1995-02-21 | Exxon Chemical Patents Inc. | Block copolymers from ionic catalysts |
| PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
| US5241025A (en) | 1987-01-30 | 1993-08-31 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| IL85097A (en) | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
| JPH0742301B2 (ja) | 1987-02-14 | 1995-05-10 | 三井石油化学工業株式会社 | 微粒子状アルミノオキサン、その製法およびその用途 |
| JP2538588B2 (ja) | 1987-04-03 | 1996-09-25 | 三井石油化学工業株式会社 | オレフイン重合用固体触媒の製法 |
| US5206199A (en) | 1987-04-20 | 1993-04-27 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing an olefin and process for polymerizing an olefin |
| US4931417A (en) | 1987-11-09 | 1990-06-05 | Chisso Corporation | Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure |
| IT1221653B (it) | 1987-11-27 | 1990-07-12 | Ausimonti Spa | Copolimeri cristallini del propilene |
| US5017714A (en) | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
| US5120867A (en) | 1988-03-21 | 1992-06-09 | Welborn Jr Howard C | Silicon-bridged transition metal compounds |
| US4871705A (en) | 1988-06-16 | 1989-10-03 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst |
| US5001205A (en) | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
| DE3821571A1 (de) | 1988-06-25 | 1989-12-28 | Schloemann Siemag Ag | Vorrichtung zum axialen verschieben von walzen im geruest eines walzwerkes |
| US4892851A (en) | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| US5091352A (en) | 1988-09-14 | 1992-02-25 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins |
| US4908463A (en) | 1988-12-05 | 1990-03-13 | Ethyl Corporation | Aluminoxane process |
| DE3904468A1 (de) | 1989-02-15 | 1990-08-16 | Hoechst Ag | Polypropylenwachs und verfahren zu seiner herstellung |
| US5103031A (en) | 1989-02-21 | 1992-04-07 | Ethyl Corporation | Falling film aluminoxane process |
| US4968827A (en) | 1989-06-06 | 1990-11-06 | Ethyl Corporation | Alkylaluminoxane process |
| US4924018A (en) | 1989-06-26 | 1990-05-08 | Ethyl Corporation | Alkylaluminoxane process |
| US5143968A (en) | 1989-08-11 | 1992-09-01 | The Dow Chemical Company | Polystyrene-polyisoprene-polystyrene block copolymers, hot melt adhesive compositions, and articles produced therefrom |
| IL95097A0 (en) * | 1989-08-23 | 1991-06-10 | Himont Inc | Thermoplastic olefin polymer and its preparation |
| US5548014A (en) * | 1989-09-13 | 1996-08-20 | Exxon Chemical Patents Inc. | Blends of ethylene copolymers for hot melt adhesives |
| US5057475A (en) | 1989-09-13 | 1991-10-15 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization |
| DD300443A5 (de) * | 1989-09-13 | 1992-06-11 | Exxon Chemical Patents Inc | Heissschmelzklebstoff |
| DE3930669A1 (de) | 1989-09-14 | 1991-03-28 | Basf Ag | Verfahren zur herstellung von uretdiongruppen aufweisenden polyisocyanaten |
| US5206324A (en) | 1989-10-06 | 1993-04-27 | Mitsui Toatsu Chemicals, Inc. | Butene-1 copolymer and resin composition containing the same |
| US5387568A (en) | 1989-10-30 | 1995-02-07 | Fina Technology, Inc. | Preparation of metallocene catalysts for polymerization of olefins |
| DE69018376T3 (de) | 1989-10-30 | 2002-05-16 | Fina Technology, Inc. | Herstellung von Metallocenkatalysatoren für Olefinpolymerisation. |
| DK0627448T3 (da) | 1990-01-02 | 2000-05-22 | Exxon Chemical Patents Inc | Ioniske metallocenkatalysatorer på bærere til olefinpolymerisation |
| DE4000696A1 (de) * | 1990-01-12 | 1991-07-18 | Huels Chemische Werke Ag | Spruehbare heissschmelzmasse mit massgeschneiderter rheologie |
| EP0442245A1 (en) | 1990-02-12 | 1991-08-21 | KELLER S.p.A. | Device for locking the wheels of vehicles on a vehicle wagon |
| DE4005947A1 (de) | 1990-02-26 | 1991-08-29 | Basf Ag | Loesliche katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen |
| US5118762A (en) | 1990-04-11 | 1992-06-02 | Shell Oil Company | Styrene-isoprene-styrene block copolymer composition for low viscosity low temperature hot melt adhesives |
| US5075386A (en) * | 1990-04-12 | 1991-12-24 | Eastman Kodak Company | Cross-linkable hot-melt adhesive and method of producing same |
| WO1992001723A1 (fr) | 1990-07-24 | 1992-02-06 | Mitsui Toatsu Chemicals, Incorporated | CATALYSEUR POUR POLYMERISATION α-OLEFINIQUE ET PRODUCTION D'UNE POLY-α-OLEFINE A L'AIDE DE CE CATALYSEUR |
| US5317070A (en) | 1990-11-09 | 1994-05-31 | Exxon Chemical Patents, Inc. | Syndiotactic hot melt adhesive |
| US5243001A (en) | 1990-11-12 | 1993-09-07 | Hoechst Aktiengesellschaft | Process for the preparation of a high molecular weight olefin polymer |
| US5239022A (en) | 1990-11-12 | 1993-08-24 | Hoechst Aktiengesellschaft | Process for the preparation of a syndiotactic polyolefin |
| ES2090209T3 (es) | 1990-11-12 | 1996-10-16 | Hoechst Ag | Metalocenos con ligandos basados en derivados de indenilo sustituidos en posicion 2, procedimiento para su preparacion y su empleo como catalizadores. |
| EP0485823B1 (de) | 1990-11-12 | 1995-03-08 | Hoechst Aktiengesellschaft | 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation |
| EP0569388B1 (en) | 1990-12-27 | 1996-03-13 | Exxon Chemical Patents Inc. | An amido transition metal compound and a catalyst system for the production of isotactic polypropylene |
| DE4120009A1 (de) | 1991-06-18 | 1992-12-24 | Basf Ag | Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen |
| US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
| US5235081A (en) | 1992-03-18 | 1993-08-10 | Ethyl Corporation | Method of removing gel forming materials from methylaluminoxanes |
| US5157137A (en) | 1991-07-26 | 1992-10-20 | Ethyl Corporation | Method of making gel free alkylaluminoxane solutions |
| US5308815A (en) | 1991-07-26 | 1994-05-03 | Ethyl Corporation | Heterogeneous methylaluminoxane catalyst system |
| DE69225749T2 (de) * | 1991-08-08 | 1998-10-01 | Rexene Corp | Harzzusammensetzung aus amorphem Polyolefin und crystallinem Polypropylen |
| TW300901B (enExample) | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
| ATE286918T1 (de) | 1991-10-15 | 2005-01-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung eines olefinpolymers unter verwendung von metallocenen mit speziell substituierten indenylliganden |
| CA2123426A1 (en) | 1991-11-22 | 1993-05-27 | Bruce P. Pelrine | Dehydrocyclization of polyalpha-olefin lubricants |
| TW318184B (enExample) | 1991-11-30 | 1997-10-21 | Hoechst Ag | |
| JP3371118B2 (ja) | 1991-11-30 | 2003-01-27 | バーゼル・ポリオレフィン・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング | 配位子としてベンゼン融合したインデニル誘導体を持つメタロセン、その製造方法および触媒としてのその用途 |
| ES2111656T3 (es) | 1992-01-06 | 1998-03-16 | Dow Chemical Co | Composicion de catalizador mejorada. |
| WO1993019103A1 (en) | 1992-03-16 | 1993-09-30 | Exxon Chemical Patents Inc. | IONIC CATALYST FOR THE PRODUCTION OF POLY-α-OLEFINS OF CONTROLLED TACTICITY |
| US5329032A (en) | 1992-03-18 | 1994-07-12 | Akzo Chemicals Inc. | Polymethylaluminoxane of enhanced solution stability |
| US5296433A (en) | 1992-04-14 | 1994-03-22 | Minnesota Mining And Manufacturing Company | Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom |
| EP0578838A1 (en) | 1992-04-29 | 1994-01-19 | Hoechst Aktiengesellschaft | Olefin polymerization catalyst, process for its preparation, and its use |
| US5710222A (en) | 1992-06-22 | 1998-01-20 | Fina Technology, Inc. | Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems |
| TW294669B (enExample) | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
| DE69332811T2 (de) | 1992-07-01 | 2004-01-29 | Exxonmobil Chem Patents Inc | Auf Übergangsmetallen der Gruppen 5 und 6 basierende Katalysator-Vorläufer |
| JPH07509752A (ja) | 1992-08-05 | 1995-10-26 | エクソン・ケミカル・パテンツ・インク | オレフィン重合用の担持されたイオン遷移金属触媒 |
| EP0584609B1 (de) | 1992-08-15 | 1999-03-10 | TARGOR GmbH | Verfahren zur Herstellung von Polyolefinen |
| US5248801A (en) | 1992-08-27 | 1993-09-28 | Ethyl Corporation | Preparation of methylaluminoxanes |
| EP0591756B1 (en) | 1992-09-22 | 1998-11-25 | Idemitsu Kosan Company Limited | Polymerization catalysts and process for producing polymers |
| US5939346A (en) | 1992-11-02 | 1999-08-17 | Akzo Nobel N.V. | Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group |
| US5391793A (en) | 1992-11-02 | 1995-02-21 | Akzo Nobel N.V. | Aryloxyaluminoxanes |
| EP0666890B2 (en) | 1992-11-02 | 2007-04-04 | ExxonMobil Chemical Patents Inc. | Blends of ethylene copolymers for hot melt adhesives |
| US5391529A (en) | 1993-02-01 | 1995-02-21 | Albemarle Corporation | Siloxy-aluminoxane compositions, and catalysts which include such compositions with a metallocene |
| JP3307704B2 (ja) | 1993-02-19 | 2002-07-24 | 三菱化学株式会社 | α‐オレフィン重合体の製造法 |
| JP3293927B2 (ja) | 1993-02-19 | 2002-06-17 | 三菱化学株式会社 | α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法 |
| US5859088A (en) | 1993-04-13 | 1999-01-12 | Minnesota Mining And Manufacturing Company | Radiation-curable poly(α-olefin) adhesives |
| CA2118777A1 (en) | 1993-04-13 | 1994-10-14 | Gaddam N. Babu | Radiation-curable poly(alpha-olefin) adhesives |
| AT403581B (de) | 1993-06-07 | 1998-03-25 | Danubia Petrochem Polymere | Verfahren zur herstellung von neuen polypropylenen durch chemische degradierung |
| EP1070729B1 (en) * | 1993-06-07 | 2011-09-28 | Mitsui Chemicals, Inc. | Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said component, process for olefin polymerization using said catalyst, propylene homopolymer, propylene copolymer and propylene elastomer |
| GB9319340D0 (en) | 1993-09-17 | 1993-11-03 | Exxon Chemical Patents Inc | Olefin polymersisation process |
| WO1995010575A1 (en) * | 1993-10-13 | 1995-04-20 | Exxon Chemical Patents Inc. | Adhesives from low molecular weight polypropylene |
| WO1995012623A1 (en) | 1993-11-03 | 1995-05-11 | Exxon Chemical Patents Inc. | Aromatic tackifier resin |
| US5397843A (en) | 1993-11-22 | 1995-03-14 | Igi Baychem, Inc. | Polymer compositions comprising amorphous propylene polymer |
| DE4344689A1 (de) | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
| DE4344688A1 (de) | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
| US5502017A (en) | 1994-03-10 | 1996-03-26 | Northwestern University | Metallocene catalyst containing bulky organic group |
| US5455111A (en) * | 1994-04-12 | 1995-10-03 | Minnesota Mining And Manufacturing Company | Construction adhesive for porous film |
| US5643847A (en) | 1994-08-03 | 1997-07-01 | Exxon Chemical Patents Inc. | Supported ionic catalyst composition |
| CA2164461C (en) * | 1994-12-06 | 2000-08-08 | Tatsuya Tanizaki | Polypropylene composition and uses thereof |
| JP3491849B2 (ja) * | 1995-03-03 | 2004-01-26 | 三井化学株式会社 | ポリプロピレン複合フィルム |
| DE4446923A1 (de) | 1994-12-28 | 1996-07-04 | Hoechst Ag | Polyolefinwachs |
| AU729324B2 (en) | 1995-01-24 | 2001-02-01 | E.I. Du Pont De Nemours And Company | Alpha-olefins and olefin polymers and processes therefor |
| US5516848A (en) * | 1995-01-31 | 1996-05-14 | Exxon Chemical Patents Inc. | Process to produce thermoplastic elastomers |
| US5539056A (en) * | 1995-01-31 | 1996-07-23 | Exxon Chemical Patents Inc. | Thermoplastic elastomers |
| US5696213A (en) | 1995-04-21 | 1997-12-09 | Exxon Chemical Patents Inc. | Ethylene-α-olefin-diolefin elastomers solution polymerization process |
| US6143682A (en) | 1995-06-07 | 2000-11-07 | Exxon Chemical Patents Inc. | Bimetallocyclic transition metal catalyst systems |
| GB9521494D0 (en) * | 1995-10-20 | 1995-12-20 | Exxon Chemical Patents Inc | Sprayable ethylene based hot metal adhesives |
| CN1176960C (zh) * | 1995-12-07 | 2004-11-24 | 埃克森美孚化学专利公司 | 增粘剂和其制备方法 |
| WO1997022639A1 (en) | 1995-12-19 | 1997-06-26 | Exxon Chemical Patents Inc. | High temperature solution polymerization process |
| US5856256A (en) | 1996-02-20 | 1999-01-05 | Northwestern University | Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations |
| JP3578426B2 (ja) * | 1996-03-08 | 2004-10-20 | 三井化学株式会社 | ポリプロピレンフィルムおよびその積層体 |
| ID17196A (id) | 1996-03-14 | 1997-12-11 | Dow Chemical Co | Bahan-bahan perekat yang mengandung polimer-polimer olefin |
| GB9612188D0 (en) | 1996-06-10 | 1996-08-14 | Smith Matthias F | Sound insulation system |
| DE69717450T2 (de) | 1996-07-22 | 2003-07-10 | H.B. Fuller Licensing & Financing, Inc. | Heissschmelzklebstoffe |
| WO1998014585A1 (en) | 1996-10-04 | 1998-04-09 | Cheil Jedang Corporation | Nucleocapsid gene of seoul virus r22, recombinant plasmid, transformed e. coli and diagnostic agent and vaccine for haemorrhagic fever with renal syndrome |
| US6086996A (en) * | 1996-10-11 | 2000-07-11 | Illinois Tool Works Inc. | Ethylene-propylene copolymer low noise film additive |
| KR100536794B1 (ko) | 1996-11-15 | 2005-12-14 | 바셀 테크놀로지 캄파니 비이브이 | 복소환 메탈로센 및 중합 촉매 |
| US5723546A (en) | 1997-03-24 | 1998-03-03 | Rexene Corporation | Low- and high-molecular weight amorphous polyalphaolefin polymer blends having high melt viscosity, and products thereof |
| US6080818A (en) | 1997-03-24 | 2000-06-27 | Huntsman Polymers Corporation | Polyolefin blends used for non-woven applications |
| JPH10338778A (ja) | 1997-04-07 | 1998-12-22 | Mitsui Chem Inc | ラミネート用プロピレン・１−ブテンランダム共重合体組成物およびその組成物を用いた複合フィルム |
| SG67489A1 (en) | 1997-04-07 | 1999-09-21 | Mitsui Chemicals Inc | Laminating propylene/1-butene random copolymer composition and composite film using the same |
| TW482770B (en) * | 1997-08-15 | 2002-04-11 | Chisso Corp | Propylene/ethylene random copolymer, molding material, and molded article |
| WO1999009306A1 (en) | 1997-08-20 | 1999-02-25 | Implico B.V. | Catalytic convertor |
| CA2306457A1 (en) | 1997-10-18 | 1999-04-29 | Genetics Institute, Inc. | Secreted proteins and polynucleotides encoding them |
| US6265512B1 (en) * | 1997-10-23 | 2001-07-24 | 3M Innovative Company | Elastic polypropylenes and catalysts for their manufacture |
| KR20010032005A (ko) | 1997-11-12 | 2001-04-16 | 그래햄 이. 테일러 | 수성 감압성 접착제 배합물 |
| US5986009A (en) * | 1997-12-03 | 1999-11-16 | The Dow Chemical Company | Blends of polypropylenes |
| DE19827328A1 (de) | 1998-06-19 | 1999-12-23 | Targor Gmbh | Propen-Terpolymere mit geringem extrahierbarem Anteil |
| EP1091984A1 (en) * | 1998-07-02 | 2001-04-18 | Exxon Chemical Patents Inc. | Propylene olefin copolymers |
| WO2000017286A1 (de) * | 1998-09-21 | 2000-03-30 | Henkel Kommanditgesellschaft Auf Aktien | Sprühbarer schmelzklebstoff |
| DE19949235A1 (de) * | 1998-10-16 | 2000-05-11 | Chisso Corp | Propylen/Ethylen/alpha-Olefin-Terpolymere und Verfahren zu ihrer Herstellung |
| JP2001011128A (ja) * | 1998-10-16 | 2001-01-16 | Chisso Corp | プロピレン／エチレン／α−オレフィン三元共重合体およびその製造法 |
| US6639020B1 (en) * | 1999-09-03 | 2003-10-28 | Exxon Mobil Chemical Patents Inc. | Plasticized polypropylene thermoplastics |
| US6395847B2 (en) * | 1999-11-19 | 2002-05-28 | Exxonmobil Chemical Patents Inc. | Supported organometallic catalysts and their use in olefin polymerization |
| US6407171B1 (en) * | 1999-12-20 | 2002-06-18 | Exxon Chemical Patents Inc. | Blends of polyethylene and polypropylene |
| WO2001046277A2 (en) * | 1999-12-22 | 2001-06-28 | Exxonmobil Chemical Patents, Inc. | Polypropylene-based adhesive compositions |
| CA2388850A1 (en) | 2000-04-21 | 2001-11-01 | Exxonmobil Chemical Patents, Inc. | Process for spraying hot melt adhesives |
-
2000
- 2000-12-21 WO PCT/US2000/035000 patent/WO2001046277A2/en not_active Ceased
- 2000-12-21 EP EP00986700A patent/EP1263815B1/en not_active Revoked
- 2000-12-21 EP EP09151336.6A patent/EP2045304B1/en not_active Revoked
- 2000-12-21 AU AU25926/01A patent/AU777944B2/en not_active Expired
- 2000-12-21 CA CA002414498A patent/CA2414498C/en not_active Expired - Fee Related
- 2000-12-21 CN CNB008187142A patent/CN1333032C/zh not_active Expired - Lifetime
- 2000-12-21 AU AU22891/01A patent/AU780051B2/en not_active Ceased
- 2000-12-21 JP JP2001547184A patent/JP4966463B2/ja not_active Expired - Lifetime
- 2000-12-21 US US09/745,394 patent/US6747114B2/en not_active Expired - Lifetime
- 2000-12-21 ES ES00986700T patent/ES2282158T3/es not_active Expired - Lifetime
- 2000-12-21 BR BRPI0016618-9B1A patent/BR0016618B1/pt not_active IP Right Cessation
- 2000-12-21 CA CA002395532A patent/CA2395532A1/en not_active Abandoned
- 2000-12-21 EP EP00989420A patent/EP1263909A2/en not_active Withdrawn
- 2000-12-21 KR KR1020027007981A patent/KR100718424B1/ko not_active Expired - Lifetime
- 2000-12-21 AT AT00986700T patent/ATE358144T1/de not_active IP Right Cessation
- 2000-12-21 DE DE60034151T patent/DE60034151T2/de not_active Expired - Lifetime
- 2000-12-21 MX MXPA02006199A patent/MXPA02006199A/es active IP Right Grant
- 2000-12-21 WO PCT/US2000/035016 patent/WO2001046278A2/en not_active Ceased
- 2000-12-21 US US09/746,332 patent/US6627723B2/en not_active Expired - Lifetime
-
2003
- 2003-11-24 US US10/720,512 patent/US7521507B2/en not_active Expired - Lifetime
-
2009
- 2009-02-24 US US12/391,286 patent/US8383731B2/en not_active Expired - Fee Related
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE60034151T2 (de) | Klebstoffe auf der basis von alpha-olefinpolymeren | |
| DE69220675T2 (de) | ETHYLEN/HöHERE ALPHA-OLEFINCOPOLYMERE | |
| DE69433347T2 (de) | Ethylen Copolymerisation | |
| DE69836415T3 (de) | Herstellung von vinyl enthaltenden polymeren | |
| DE602004010412T2 (de) | Mischpolymerisate als schmelzkleber und verfahren zu deren herstellung | |
| US6582762B2 (en) | Sprayable hot melt adhesives | |
| DE69818862T2 (de) | Elastische propylenpolymere | |
| DE60128377T2 (de) | Metallocenkatalysatoren hergestelltem polyethylen sehr niedriger dichte | |
| DE60304595T2 (de) | Flüssige und gelartige niedermolekulare ethylenpolymere | |
| EP3183315B1 (en) | Adhesive compositon | |
| DE60121585T2 (de) | Verfahren zur versprühung eines schmelzklebers | |
| DE60211013T2 (de) | Zweistufen-polymerisationsverfahren | |
| DE112015005338B4 (de) | Heißschmelzkleber zur Holzverarbeitung und ein Verfahren zum Kleben von Substraten der Holzverarbeitung | |
| US20080306194A1 (en) | Hot-Melt Adhesive Compositions Based on Olefin Co-Polymers | |
| US7067603B1 (en) | Adhesive alpha-olefin inter-polymers | |
| DE112021003081T5 (de) | Weichmacher für Harze | |
| KR20070057085A (ko) | 올레핀 공중합체 기재 열-용해 접착제 조성물 | |
| EP4051202A1 (en) | Tackifier-free hot melt adhesive composition, method for using the same, and article made using the same | |
| EP1795568A2 (en) | Adhesive alpha-olefin inter-polymers |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8363 | Opposition against the patent |