DE2230672A1 - Verfahren zur stereoregulären Polymerisation von alpha-Olefinen - Google Patents

Verfahren zur stereoregulären Polymerisation von alpha-Olefinen

Info

Publication number
DE2230672A1
DE2230672A1 DE19722230672 DE2230672A DE2230672A1 DE 2230672 A1 DE2230672 A1 DE 2230672A1 DE 19722230672 DE19722230672 DE 19722230672 DE 2230672 A DE2230672 A DE 2230672A DE 2230672 A1 DE2230672 A1 DE 2230672A1
Authority
DE
Germany
Prior art keywords
compound
polymerization
catalyst
anhydrous
ethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19722230672
Other languages
German (de)
English (en)
Other versions
DE2230672C2 (instruction
Inventor
Umberto; Casseta Antonio; Longi PaolorMazzocchi Romano; Mailand Giannini (Italien). CO8f3-O2
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Montedison SpA
Original Assignee
Montedison SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montedison SpA filed Critical Montedison SpA
Publication of DE2230672A1 publication Critical patent/DE2230672A1/de
Application granted granted Critical
Publication of DE2230672C2 publication Critical patent/DE2230672C2/de
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE19722230672 1971-06-25 1972-06-23 Verfahren zur stereoregulären Polymerisation von alpha-Olefinen Granted DE2230672A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT2627571 1971-06-25

Publications (2)

Publication Number Publication Date
DE2230672A1 true DE2230672A1 (de) 1972-12-28
DE2230672C2 DE2230672C2 (instruction) 1987-11-12

Family

ID=11219117

Family Applications (3)

Application Number Title Priority Date Filing Date
DE19722230672 Granted DE2230672A1 (de) 1971-06-25 1972-06-23 Verfahren zur stereoregulären Polymerisation von alpha-Olefinen
DE19722230728 Withdrawn DE2230728A1 (de) 1971-06-25 1972-06-23 Verfahren zur stereoregulären Polymerisation von alpha-Olefinen
DE19722230752 Granted DE2230752A1 (de) 1971-06-25 1972-06-23 Verfahren zur stereoregulären Polymerisation von alpha-Olefinen

Family Applications After (2)

Application Number Title Priority Date Filing Date
DE19722230728 Withdrawn DE2230728A1 (de) 1971-06-25 1972-06-23 Verfahren zur stereoregulären Polymerisation von alpha-Olefinen
DE19722230752 Granted DE2230752A1 (de) 1971-06-25 1972-06-23 Verfahren zur stereoregulären Polymerisation von alpha-Olefinen

Country Status (27)

Country Link
US (1) US4336360A (instruction)
JP (4) JPS5236153B1 (instruction)
AR (1) AR192799A1 (instruction)
AT (1) AT327540B (instruction)
AU (1) AU471393B2 (instruction)
BE (3) BE785334A (instruction)
BG (1) BG26815A3 (instruction)
BR (1) BR7204175D0 (instruction)
CA (3) CA1002695A (instruction)
CS (1) CS175433B2 (instruction)
DD (1) DD98289A5 (instruction)
DE (3) DE2230672A1 (instruction)
DK (1) DK141781B (instruction)
ES (1) ES404230A1 (instruction)
FI (1) FI54488C (instruction)
FR (3) FR2143348B1 (instruction)
GB (3) GB1387888A (instruction)
HU (1) HU166276B (instruction)
IL (1) IL39747A (instruction)
NL (4) NL160285B (instruction)
PL (1) PL83672B1 (instruction)
RO (1) RO62447A (instruction)
SE (1) SE440508B (instruction)
SU (1) SU403193A3 (instruction)
TR (1) TR17593A (instruction)
YU (1) YU39898B (instruction)
ZA (1) ZA724335B (instruction)

Cited By (33)

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DE1958488A1 (de) * 1968-11-25 1970-05-27 Montedison Spa Neue Polymerisationskatalysatoren,ihre Herstellung und Verwendung
DE2504036A1 (de) * 1974-02-01 1975-08-07 Mitsui Petrochemical Ind Verfahren zur polymerisation von alpha-olefinen
DE2505825A1 (de) * 1974-02-15 1975-08-21 Montedison Spa Thermoplastische kautschuke und verfahren zu ihrer herstellung
DE2620886A1 (de) * 1975-05-16 1976-11-25 Montedison Spa Verfahren zur polymerisation von alpha-olefinen mit wenigstens drei c-atomen
DE2638429A1 (de) * 1975-08-29 1977-03-03 Montedison Spa Kristalline propylenpolymerisate und -copolymerisate und verfahren zu ihrer herstellung
DE2553104A1 (de) * 1975-11-26 1977-06-08 Mitsui Petrochemical Ind Verfahren zur herstellung einer auf einen traeger mit hoher leistungsfaehigkeit aufgebrachten katalysatorkomponente
DE2735672A1 (de) * 1976-08-09 1978-02-16 Mitsui Petrochemical Ind Zur polymerisation von alpha-olefinen verwendbare katalysatorkomponenten und hieraus erhaltene katalysatoren
DE2738627A1 (de) * 1976-08-27 1978-03-02 Mitsui Petrochemical Ind Verfahren zur herstellung von olefinpolymeren oder -copolymeren
DE2640679A1 (de) * 1976-09-09 1978-03-16 Montedison Spa Katalysatoren und katalysatorkomponenten zur polymerisation von olefinen
DE2743415A1 (de) * 1976-09-27 1978-03-30 Mitsui Petrochemical Ind Verfahren zur herstellung von stereoregulaeren polymeren oder copolymeren von olefinen
US4143223A (en) 1976-03-01 1979-03-06 Mitsui Petrochemical Industries Ltd. Process for polymerizing alpha-olefins and catalyst therefor
US4157435A (en) 1974-08-10 1979-06-05 Mitsui Petrochemical Industries, Ltd. Process for preparing highly stereoregular polyolefins and catalyst used therefor
DE2914812A1 (de) * 1978-04-11 1979-10-18 Nippon Oil Co Ltd Verfahren zur polymerisation oder copolymerisation von olefinen
US4175171A (en) * 1976-08-02 1979-11-20 Mitsui Toatsu Chemicals, Inc. Catalyst for polymerizing α-olefins
US4180636A (en) * 1976-06-24 1979-12-25 Showa Denko Kabushiki Kaisha Process for polymerizing or co-polymerizing propylene
DE2924033A1 (de) * 1978-06-13 1980-01-03 Nippon Oil Co Ltd Verfahren zur herstellung von olefinpolymeren
EP0007061A1 (de) * 1978-07-07 1980-01-23 Hoechst Aktiengesellschaft Verfahren zur Polymerisation von 1-Oelfinen
US4194076A (en) * 1976-05-14 1980-03-18 Phillips Petroleum Company Washing magnesium reducing agent prepared in absence of complexing diluent
US4194075A (en) * 1976-05-14 1980-03-18 Phillips Petroleum Company Magnesium reducing agent-hydrocarbylaluminum halide cocatalyst for titanium tetrahalide
DE3012272A1 (de) * 1979-04-01 1980-10-09 Stamicarbon Katalytische titankomponente, verfahren zu deren herstellung und verfahren zur polymerisation von alkylenen-1 unter anwendung einer solchen titankomponente
US4234710A (en) 1976-07-08 1980-11-18 Phillips Petroleum Company Catalyst and a polymerization process employing the catalyst
US4237254A (en) * 1977-04-30 1980-12-02 Mitsubishi Petrochemical Company Limited Process for producing olefin polymers
US4246384A (en) 1978-11-08 1981-01-20 Phillips Petroleum Company Magnesium reducing agent for producing titanium trihalide catalyst component
US4272404A (en) 1977-12-09 1981-06-09 Wristers Harry J Supported Ziegler catalysts and method therefor
EP0036536A1 (de) * 1980-03-15 1981-09-30 BASF Aktiengesellschaft Verfahren zum Herstellen von Homo- und Copolymerisaten von alpha-Monoolefinen
US4354010A (en) * 1975-01-09 1982-10-12 Imperial Chemical Industries Limited Transition metal compound
US4933403A (en) * 1985-03-13 1990-06-12 Hoechst Aktiengesellschaft Process for the preparation of optically active polyolefins
US6303715B1 (en) 1998-12-04 2001-10-16 Samsung General Chemicals Co., Ltd. Method for polymerization and copolymerization of alpha-olefin
US6482764B1 (en) 1998-04-17 2002-11-19 Samsung General Chemicals Co., Ltd. Method for producing a supported catalyst for ethylene polymerization and ethylene/α-olefin copolymerization
US6559249B2 (en) 2000-04-24 2003-05-06 Samsung General Chemicals Co. Ltd. Catalyst for producing an ultrahigh molecular weight polyethylene (UHWMP) and method for producing an UHWMP using the same
US6559250B2 (en) 2000-12-27 2003-05-06 Samsung General Chemicals Co., Ltd. Method of homo- or co-polymerization of α-olefin
US6803427B2 (en) 2000-05-31 2004-10-12 Samsung General Chemicals Co., Ltd. Method for producing ethylene homo- and co-polymer
WO2012156989A1 (en) * 2011-05-13 2012-11-22 Reliance Industries Limited Catalyst system for polymerization of propylene

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US4107413A (en) 1971-06-25 1978-08-15 Montedison S.P.A. Process for the stereoregular polymerization of alpha olefins
IT967867B (it) * 1972-09-26 1974-03-11 Montedison Spa Procedimento per la polimerizzazio ne stereospecifica delle alfa ole fine
IT1054410B (it) * 1975-11-21 1981-11-10 Mitsui Petrochemical Ind Catalizzatori per la polimerizzazione delle alfa olefine
DK151969C (da) * 1975-11-21 1988-07-11 Montedison Spa Fast katalysatorkomponent til anvendelse i katalysatorer til brug ved polymerisation af alfa-alkener
SE7613662L (sv) 1975-12-10 1977-06-11 Mitsui Petrochemical Ind Polymerisation av alfa-olefiner
IT1054584B (it) * 1976-01-30 1981-11-30 Montedison Spa Modificazione cristallina del cloruro di magnesio anidro
JPS5948003B2 (ja) * 1976-06-02 1984-11-22 三井化学株式会社 ポリオレフイン類の製造方法
JPS58448B2 (ja) * 1976-09-27 1983-01-06 三井化学株式会社 ポリオレフインの製造方法
US4107412A (en) 1976-11-24 1978-08-15 Phillips Petroleum Company Olefin polymerization process and catalyst therefor
GB1603724A (en) 1977-05-25 1981-11-25 Montedison Spa Components and catalysts for the polymerisation of alpha-olefins
NL7711974A (nl) * 1977-11-01 1979-05-03 Stamicarbon Werkwijze voor het polymeriseren van alkenen-1.
US4242480A (en) * 1977-12-13 1980-12-30 Phillips Petroleum Company Catalyst and process of polymerization of alpha monoolefins
US4312784A (en) 1977-12-13 1982-01-26 Phillips Petroleum Co. Catalyst and process of polymerization of alpha monoolefins
US4330648A (en) 1977-12-13 1982-05-18 Phillips Petroleum Company Catalyst and process of polymerization of alpha-monoolefins
US4397763A (en) 1977-12-13 1983-08-09 Phillips Petroleum Company Catalyst and process of polymerization of alpha-monoolefins
US4130503A (en) 1977-12-23 1978-12-19 Phillips Petroleum Company Phosphite in MgX2 supported TiX3 /AlCl3 catalyst system
JPS54112982A (en) * 1978-02-02 1979-09-04 Sumitomo Chem Co Ltd Polymerization of olefins
US4302565A (en) * 1978-03-31 1981-11-24 Union Carbide Corporation Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization
JPS54132494A (en) * 1978-04-06 1979-10-15 Mitsubishi Petrochem Co Ltd Solid catalyst component for polymerization of olefins
JPS5534238A (en) * 1978-08-31 1980-03-10 Chisso Corp Preparation of alpha-olefin polymer
US4260708A (en) * 1978-09-01 1981-04-07 Phillips Petroleum Company Phosphite in MgX2 supported TiX3 /AlCl3 catalyst system
US4243552A (en) 1978-12-11 1981-01-06 Phillips Petroleum Company Polymerization catalyst and process
IT1121993B (it) * 1979-07-02 1986-04-23 Montedison Spa Procedimento migliorato per l'essiccamento di materiali incoerenti
EP0041362A1 (en) * 1980-06-02 1981-12-09 Hercules Incorporated 1-Olefin polymerization process and catalyst
US4325836A (en) * 1980-07-18 1982-04-20 Stauffer Chemical Company Novel titanium halide containing catalyst
US6777508B1 (en) 1980-08-13 2004-08-17 Basell Poliolefine Italia S.P.A. Catalysts for the polymerization of olefins
IT1209255B (it) 1980-08-13 1989-07-16 Montedison Spa Catalizzatori per la polimerizzazione di olefine.
US4351930A (en) * 1981-02-05 1982-09-28 El Paso Polyolefins Company Propylene copolymerization process and product
US4491652A (en) * 1981-05-13 1985-01-01 Uniroyal, Inc. Sequentially prepared thermoplastic elastomer and method of preparing same
DE3269975D1 (en) 1981-08-07 1986-04-24 Ici Plc Spraying solid
JPS5883006A (ja) * 1981-11-13 1983-05-18 Mitsui Petrochem Ind Ltd オレフインの重合方法
IT1190682B (it) * 1982-02-12 1988-02-24 Montedison Spa Catalizzatori per la polimerizzazione di olefine
JPS58138706A (ja) * 1982-02-12 1983-08-17 Mitsui Petrochem Ind Ltd オレフイン系重合体の製造方法
JPS58138705A (ja) * 1982-02-12 1983-08-17 Mitsui Petrochem Ind Ltd オレフイン系重合体の製造方法
JPS58138711A (ja) * 1982-02-12 1983-08-17 Mitsui Petrochem Ind Ltd オレフインの重合方法
FR2529206A1 (fr) * 1982-06-24 1983-12-30 Bp Chimie Sa Procede de preparation de supports a base de chlorure de magnesium pour la preparation de catalyseurs de polymerisation des alpha-olefines et supports obtenus
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JP5627670B2 (ja) * 2009-04-16 2014-11-19 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ １−ブテンから成るポリマーの製造方法

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DE1958488A1 (de) * 1968-11-25 1970-05-27 Montedison Spa Neue Polymerisationskatalysatoren,ihre Herstellung und Verwendung
DE2504036A1 (de) * 1974-02-01 1975-08-07 Mitsui Petrochemical Ind Verfahren zur polymerisation von alpha-olefinen
DE2505825A1 (de) * 1974-02-15 1975-08-21 Montedison Spa Thermoplastische kautschuke und verfahren zu ihrer herstellung
DK151893B (da) * 1974-02-15 1988-01-11 Montedison Spa Copolymere af propylen med ethylen og fremgangsmaade til fremstilling deraf
US4298721A (en) 1974-02-15 1981-11-03 Montedison S.P.A. Thermoplastic rubbers and process for preparing same
US4157435A (en) 1974-08-10 1979-06-05 Mitsui Petrochemical Industries, Ltd. Process for preparing highly stereoregular polyolefins and catalyst used therefor
US4354010A (en) * 1975-01-09 1982-10-12 Imperial Chemical Industries Limited Transition metal compound
DE2620886A1 (de) * 1975-05-16 1976-11-25 Montedison Spa Verfahren zur polymerisation von alpha-olefinen mit wenigstens drei c-atomen
DE2638429A1 (de) * 1975-08-29 1977-03-03 Montedison Spa Kristalline propylenpolymerisate und -copolymerisate und verfahren zu ihrer herstellung
DE2553104A1 (de) * 1975-11-26 1977-06-08 Mitsui Petrochemical Ind Verfahren zur herstellung einer auf einen traeger mit hoher leistungsfaehigkeit aufgebrachten katalysatorkomponente
US4143223A (en) 1976-03-01 1979-03-06 Mitsui Petrochemical Industries Ltd. Process for polymerizing alpha-olefins and catalyst therefor
US4194075A (en) * 1976-05-14 1980-03-18 Phillips Petroleum Company Magnesium reducing agent-hydrocarbylaluminum halide cocatalyst for titanium tetrahalide
US4194076A (en) * 1976-05-14 1980-03-18 Phillips Petroleum Company Washing magnesium reducing agent prepared in absence of complexing diluent
US4180636A (en) * 1976-06-24 1979-12-25 Showa Denko Kabushiki Kaisha Process for polymerizing or co-polymerizing propylene
US4234710A (en) 1976-07-08 1980-11-18 Phillips Petroleum Company Catalyst and a polymerization process employing the catalyst
US4175171A (en) * 1976-08-02 1979-11-20 Mitsui Toatsu Chemicals, Inc. Catalyst for polymerizing α-olefins
DE2735672A1 (de) * 1976-08-09 1978-02-16 Mitsui Petrochemical Ind Zur polymerisation von alpha-olefinen verwendbare katalysatorkomponenten und hieraus erhaltene katalysatoren
DE2738627A1 (de) * 1976-08-27 1978-03-02 Mitsui Petrochemical Ind Verfahren zur herstellung von olefinpolymeren oder -copolymeren
DE2640679A1 (de) * 1976-09-09 1978-03-16 Montedison Spa Katalysatoren und katalysatorkomponenten zur polymerisation von olefinen
DE2743415A1 (de) * 1976-09-27 1978-03-30 Mitsui Petrochemical Ind Verfahren zur herstellung von stereoregulaeren polymeren oder copolymeren von olefinen
US4237254A (en) * 1977-04-30 1980-12-02 Mitsubishi Petrochemical Company Limited Process for producing olefin polymers
US4272404A (en) 1977-12-09 1981-06-09 Wristers Harry J Supported Ziegler catalysts and method therefor
DE2914812A1 (de) * 1978-04-11 1979-10-18 Nippon Oil Co Ltd Verfahren zur polymerisation oder copolymerisation von olefinen
DE2924033A1 (de) * 1978-06-13 1980-01-03 Nippon Oil Co Ltd Verfahren zur herstellung von olefinpolymeren
EP0007061A1 (de) * 1978-07-07 1980-01-23 Hoechst Aktiengesellschaft Verfahren zur Polymerisation von 1-Oelfinen
US4329256A (en) * 1978-07-07 1982-05-11 Hoechst Aktiengesellschaft Process for the manufacture of a mixed catalyst
US4246384A (en) 1978-11-08 1981-01-20 Phillips Petroleum Company Magnesium reducing agent for producing titanium trihalide catalyst component
DE3012272A1 (de) * 1979-04-01 1980-10-09 Stamicarbon Katalytische titankomponente, verfahren zu deren herstellung und verfahren zur polymerisation von alkylenen-1 unter anwendung einer solchen titankomponente
EP0036536A1 (de) * 1980-03-15 1981-09-30 BASF Aktiengesellschaft Verfahren zum Herstellen von Homo- und Copolymerisaten von alpha-Monoolefinen
US4933403A (en) * 1985-03-13 1990-06-12 Hoechst Aktiengesellschaft Process for the preparation of optically active polyolefins
US6482764B1 (en) 1998-04-17 2002-11-19 Samsung General Chemicals Co., Ltd. Method for producing a supported catalyst for ethylene polymerization and ethylene/α-olefin copolymerization
US6303715B1 (en) 1998-12-04 2001-10-16 Samsung General Chemicals Co., Ltd. Method for polymerization and copolymerization of alpha-olefin
US6559249B2 (en) 2000-04-24 2003-05-06 Samsung General Chemicals Co. Ltd. Catalyst for producing an ultrahigh molecular weight polyethylene (UHWMP) and method for producing an UHWMP using the same
US6803427B2 (en) 2000-05-31 2004-10-12 Samsung General Chemicals Co., Ltd. Method for producing ethylene homo- and co-polymer
US6559250B2 (en) 2000-12-27 2003-05-06 Samsung General Chemicals Co., Ltd. Method of homo- or co-polymerization of α-olefin
WO2012156989A1 (en) * 2011-05-13 2012-11-22 Reliance Industries Limited Catalyst system for polymerization of propylene

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DE2230672C2 (instruction) 1987-11-12
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GB1387889A (en) 1975-03-19
BE785333A (fr) 1972-12-27
BG26815A3 (bg) 1979-06-12
TR17593A (tr) 1975-07-23
CA1002694A (en) 1976-12-28
AU4384972A (en) 1974-01-03
FR2143347B1 (instruction) 1977-12-23
AR192799A1 (es) 1973-03-14
DD98289A5 (instruction) 1973-06-12
IL39747A (en) 1976-01-30
DK141781C (instruction) 1980-11-03
CA1002693A (en) 1976-12-28
YU39898B (en) 1985-06-30
CS175433B2 (instruction) 1977-05-31
YU166672A (en) 1982-02-28
NL7208567A (instruction) 1972-12-28
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JPS5236153B1 (instruction) 1977-09-13
JPS57119903A (en) 1982-07-26
FI54488B (fi) 1978-08-31
GB1387888A (en) 1975-03-19
FR2143347A1 (instruction) 1973-02-02
BE785334A (fr) 1972-12-27
FR2143348A1 (instruction) 1973-02-02
FR2143348B1 (instruction) 1977-12-23
DE2230752A1 (de) 1972-12-28
AU471393B2 (en) 1976-04-29
DK141781B (da) 1980-06-16
RO62447A (fr) 1978-02-15
NL160286B (nl) 1979-05-15
DE2230752C2 (instruction) 1987-11-19
SE440508B (sv) 1985-08-05
NL7208558A (instruction) 1972-12-28
NL7208556A (instruction) 1972-12-28
DE2230728A1 (de) 1972-12-28
US4336360A (en) 1982-06-22
CA1002695A (en) 1976-12-28
AT327540B (de) 1976-02-10
NL160287B (nl) 1979-05-15
FI54488C (fi) 1978-12-11
HU166276B (instruction) 1975-02-28
JPS6228963B2 (instruction) 1987-06-23
ATA547572A (de) 1975-04-15
ES404230A1 (es) 1975-06-01
ZA724335B (en) 1973-03-28
JPS5239431B1 (instruction) 1977-10-05
NL160286C (instruction)
IL39747A0 (en) 1972-08-30
NL160285B (nl) 1979-05-15
PL83672B1 (instruction) 1975-12-31
SU403193A3 (instruction) 1973-10-19
JPS5323871B1 (instruction) 1978-07-17
BE785332A (fr) 1972-12-27

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