CN1835138B - 固体电解电容器及其制造方法 - Google Patents
固体电解电容器及其制造方法 Download PDFInfo
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- CN1835138B CN1835138B CN2006100086667A CN200610008666A CN1835138B CN 1835138 B CN1835138 B CN 1835138B CN 2006100086667 A CN2006100086667 A CN 2006100086667A CN 200610008666 A CN200610008666 A CN 200610008666A CN 1835138 B CN1835138 B CN 1835138B
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- China
- Prior art keywords
- electrolytic capacitor
- solid electrolytic
- solution
- oxidant
- manufacturing approach
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000003990 capacitor Substances 0.000 title claims abstract description 336
- 239000007787 solid Substances 0.000 title claims abstract description 180
- 238000000034 method Methods 0.000 title claims abstract description 149
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 144
- 230000008569 process Effects 0.000 title description 26
- 239000007784 solid electrolyte Substances 0.000 claims abstract description 158
- 229910052751 metal Inorganic materials 0.000 claims abstract description 91
- 239000002184 metal Substances 0.000 claims abstract description 91
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims abstract description 74
- 150000001450 anions Chemical class 0.000 claims abstract description 55
- 229920001940 conductive polymer Polymers 0.000 claims abstract description 36
- 239000010410 layer Substances 0.000 claims description 265
- 229920000642 polymer Polymers 0.000 claims description 180
- -1 sulfo group quinone anion Chemical class 0.000 claims description 178
- AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims description 165
- 150000001875 compounds Chemical class 0.000 claims description 145
- 230000001590 oxidative effect Effects 0.000 claims description 140
- 239000007800 oxidant agent Substances 0.000 claims description 132
- 238000013459 approach Methods 0.000 claims description 130
- 239000000203 mixture Substances 0.000 claims description 130
- 238000006116 polymerization reaction Methods 0.000 claims description 121
- 239000011248 coating agent Substances 0.000 claims description 89
- 238000000576 coating method Methods 0.000 claims description 89
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical group [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 51
- 238000007598 dipping method Methods 0.000 claims description 48
- 125000000129 anionic group Chemical group 0.000 claims description 42
- 239000000178 monomer Substances 0.000 claims description 35
- 239000000126 substance Substances 0.000 claims description 28
- 125000003545 alkoxy group Chemical group 0.000 claims description 24
- 230000015572 biosynthetic process Effects 0.000 claims description 24
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 20
- 125000004417 unsaturated alkyl group Chemical group 0.000 claims description 18
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 17
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 16
- 238000010276 construction Methods 0.000 claims description 15
- 238000011049 filling Methods 0.000 claims description 14
- 229920006395 saturated elastomer Polymers 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- 229910052760 oxygen Inorganic materials 0.000 claims description 13
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- 125000003368 amide group Chemical group 0.000 claims description 8
- IBGCXOFOCKCBNQ-UHFFFAOYSA-N nitro cyanate Chemical compound [O-][N+](=O)OC#N IBGCXOFOCKCBNQ-UHFFFAOYSA-N 0.000 claims description 8
- 229910052717 sulfur Inorganic materials 0.000 claims description 8
- 150000001449 anionic compounds Chemical class 0.000 claims description 7
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 7
- AFPRJLBZLPBTPZ-UHFFFAOYSA-N acenaphthoquinone Chemical compound C1=CC(C(C2=O)=O)=C3C2=CC=CC3=C1 AFPRJLBZLPBTPZ-UHFFFAOYSA-N 0.000 claims description 6
- 125000004122 cyclic group Chemical group 0.000 claims description 6
- 125000005843 halogen group Chemical group 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 229910052711 selenium Inorganic materials 0.000 claims description 6
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- 125000004953 trihalomethyl group Chemical group 0.000 claims description 6
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 5
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 150000004055 1,2-benzoquinones Chemical class 0.000 claims description 3
- 150000004057 1,4-benzoquinones Chemical class 0.000 claims description 3
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical class C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 claims description 3
- VNQXSTWCDUXYEZ-UHFFFAOYSA-N 1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione Chemical compound C1CC2(C)C(=O)C(=O)C1C2(C)C VNQXSTWCDUXYEZ-UHFFFAOYSA-N 0.000 claims description 3
- 229930006711 bornane-2,3-dione Natural products 0.000 claims description 3
- 239000011229 interlayer Substances 0.000 claims description 3
- RLCOXABDZNIZRQ-UHFFFAOYSA-N pyrene-2,7-dione Chemical compound C1=CC2=CC(=O)C=C(C=C3)C2=C2C3=CC(=O)C=C21 RLCOXABDZNIZRQ-UHFFFAOYSA-N 0.000 claims description 3
- BDJXVNRFAQSMAA-UHFFFAOYSA-N quinhydrone Chemical group OC1=CC=C(O)C=C1.O=C1C=CC(=O)C=C1 BDJXVNRFAQSMAA-UHFFFAOYSA-N 0.000 claims description 3
- KETQAJRQOHHATG-UHFFFAOYSA-N 1,2-naphthoquinone Chemical class C1=CC=C2C(=O)C(=O)C=CC2=C1 KETQAJRQOHHATG-UHFFFAOYSA-N 0.000 claims description 2
- 150000000344 2,6-naphthoquinones Chemical class 0.000 claims 1
- RZVHIXYEVGDQDX-UHFFFAOYSA-N 9,10-anthraquinone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 claims 1
- 229940076442 9,10-anthraquinone Drugs 0.000 claims 1
- ILFFFKFZHRGICY-UHFFFAOYSA-N anthracene-1-sulfonic acid Chemical class C1=CC=C2C=C3C(S(=O)(=O)O)=CC=CC3=CC2=C1 ILFFFKFZHRGICY-UHFFFAOYSA-N 0.000 abstract description 2
- 125000004151 quinonyl group Chemical group 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 170
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 90
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 89
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 79
- 238000007254 oxidation reaction Methods 0.000 description 61
- 230000003647 oxidation Effects 0.000 description 51
- 239000002019 doping agent Substances 0.000 description 49
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 46
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 46
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 46
- 238000012545 processing Methods 0.000 description 43
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- 239000007864 aqueous solution Substances 0.000 description 38
- 239000002253 acid Substances 0.000 description 35
- 239000002904 solvent Substances 0.000 description 34
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 33
- HXCVWRVCCRWCGP-UHFFFAOYSA-N C(C)=S1C=CC=C1 Chemical compound C(C)=S1C=CC=C1 HXCVWRVCCRWCGP-UHFFFAOYSA-N 0.000 description 31
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 31
- 230000000052 comparative effect Effects 0.000 description 30
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 28
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 26
- 230000000694 effects Effects 0.000 description 24
- 150000002500 ions Chemical class 0.000 description 24
- 229920002521 macromolecule Polymers 0.000 description 23
- 239000011734 sodium Substances 0.000 description 23
- 239000000758 substrate Substances 0.000 description 23
- 239000005030 aluminium foil Substances 0.000 description 22
- LYTMVABTDYMBQK-UHFFFAOYSA-N 2-benzothiophene Chemical compound C1=CC=CC2=CSC=C21 LYTMVABTDYMBQK-UHFFFAOYSA-N 0.000 description 21
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 21
- 229910052708 sodium Inorganic materials 0.000 description 21
- 238000012360 testing method Methods 0.000 description 21
- 230000008859 change Effects 0.000 description 20
- 238000001035 drying Methods 0.000 description 19
- 229920000123 polythiophene Polymers 0.000 description 19
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 18
- FLDCSPABIQBYKP-UHFFFAOYSA-N 5-chloro-1,2-dimethylbenzimidazole Chemical compound ClC1=CC=C2N(C)C(C)=NC2=C1 FLDCSPABIQBYKP-UHFFFAOYSA-N 0.000 description 15
- 239000001741 Ammonium adipate Substances 0.000 description 15
- 235000019293 ammonium adipate Nutrition 0.000 description 15
- 125000001424 substituent group Chemical group 0.000 description 14
- 230000008646 thermal stress Effects 0.000 description 14
- 229910052742 iron Inorganic materials 0.000 description 13
- 239000000047 product Substances 0.000 description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 12
- 229920005567 polycyclic polymer Polymers 0.000 description 12
- 239000002585 base Substances 0.000 description 11
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 11
- 229920002554 vinyl polymer Polymers 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 10
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- 238000006356 dehydrogenation reaction Methods 0.000 description 10
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- 150000007524 organic acids Chemical class 0.000 description 10
- 150000003233 pyrroles Chemical class 0.000 description 10
- 150000003254 radicals Chemical class 0.000 description 10
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 9
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 9
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- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 9
- 238000004220 aggregation Methods 0.000 description 9
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- 229910052783 alkali metal Inorganic materials 0.000 description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 9
- 229910052782 aluminium Inorganic materials 0.000 description 9
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- 229910044991 metal oxide Inorganic materials 0.000 description 9
- 150000004706 metal oxides Chemical class 0.000 description 9
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 9
- 235000019394 potassium persulphate Nutrition 0.000 description 9
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- 239000000460 chlorine Substances 0.000 description 8
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 8
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- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 7
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- YZMHQCWXYHARLS-UHFFFAOYSA-N naphthalene-1,2-disulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(S(=O)(=O)O)=CC=C21 YZMHQCWXYHARLS-UHFFFAOYSA-N 0.000 description 1
- IZJIQLPALMMUNB-UHFFFAOYSA-N naphtho[2,3-f][2]benzothiole Chemical group C1=CC=CC2=CC3=CC4=CSC=C4C=C3C=C21 IZJIQLPALMMUNB-UHFFFAOYSA-N 0.000 description 1
- ZZFMLOBIWZUABC-UHFFFAOYSA-N naphtho[2,3-g][2]benzothiole Chemical compound C1=C2C(=CS1)C=CC=1C=C3C=CC=CC3=CC=12 ZZFMLOBIWZUABC-UHFFFAOYSA-N 0.000 description 1
- BZLMPOBAHIIIDK-UHFFFAOYSA-N naphtho[2,3-g][2]benzothiole 2-oxide Chemical class C1=C2C(=CS1=O)C=CC=1C=C3C=CC=CC3=CC12 BZLMPOBAHIIIDK-UHFFFAOYSA-N 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000005447 octyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 125000005429 oxyalkyl group Chemical group 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 201000007094 prostatitis Diseases 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229940100890 silver compound Drugs 0.000 description 1
- 150000003379 silver compounds Chemical class 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- GTKIEPUIFBBXJQ-UHFFFAOYSA-M sodium;2-[(4-hydroxy-9,10-dioxoanthracen-1-yl)amino]-5-methylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O GTKIEPUIFBBXJQ-UHFFFAOYSA-M 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004577 thatch Substances 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
- H01G9/025—Solid electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/48—Conductive polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/56—Solid electrolytes, e.g. gels; Additives therein
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/15—Solid electrolytic capacitors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Materials Engineering (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Fixed Capacitors And Capacitor Manufacturing Machines (AREA)
- Conductive Materials (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
- Magnetic Heads (AREA)
- Looms (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Applications Claiming Priority (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP329086/1997 | 1997-11-28 | ||
| JP329087/1997 | 1997-11-28 | ||
| JP32908797 | 1997-11-28 | ||
| JP32908697 | 1997-11-28 | ||
| JP343254/1997 | 1997-12-12 | ||
| JP34325497 | 1997-12-12 | ||
| JP7090898 | 1998-03-19 | ||
| JP70908/1998 | 1998-03-19 | ||
| JP112552/1998 | 1998-04-22 | ||
| JP11255298 | 1998-04-22 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB98803803XA Division CN1252138C (zh) | 1997-11-28 | 1998-11-27 | 固体电解电容器及其制造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1835138A CN1835138A (zh) | 2006-09-20 |
| CN1835138B true CN1835138B (zh) | 2012-09-05 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006100086667A Expired - Lifetime CN1835138B (zh) | 1997-11-28 | 1998-11-27 | 固体电解电容器及其制造方法 |
| CNB98803803XA Expired - Lifetime CN1252138C (zh) | 1997-11-28 | 1998-11-27 | 固体电解电容器及其制造方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB98803803XA Expired - Lifetime CN1252138C (zh) | 1997-11-28 | 1998-11-27 | 固体电解电容器及其制造方法 |
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Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4478906B2 (ja) * | 2000-03-28 | 2010-06-09 | 株式会社村田製作所 | 固体電解コンデンサ及びその製造方法 |
| EP1281460B1 (en) * | 2000-04-24 | 2008-03-12 | Showa Denko K.K. | Niobium powder, sintered compact thereof and capacitor |
| EP2221840B1 (en) * | 2000-08-10 | 2013-10-09 | Showa Denko K.K. | Niobium powder, sintered body and capacitor using the body |
| JP2002134368A (ja) * | 2000-10-26 | 2002-05-10 | Showa Denko Kk | コンデンサ用粉体、焼結体及びその焼結体を用いたコンデンサ |
| JP5116130B2 (ja) * | 2001-08-24 | 2013-01-09 | 日本ケミコン株式会社 | 固体電解コンデンサ及びその製造方法 |
| JP2003133183A (ja) * | 2001-10-26 | 2003-05-09 | Matsushita Electric Ind Co Ltd | 固体電解コンデンサおよびその製造方法 |
| TW200516094A (en) * | 2003-09-25 | 2005-05-16 | Showa Denko Kk | Pi-Conjugated copolymer, production method thereof, and capacitor using the copolymer |
| CN101065816B (zh) * | 2004-11-19 | 2010-06-16 | 株式会社村田制作所 | 固体电解电容器及其制造方法 |
| CN101167148B (zh) | 2005-04-27 | 2013-02-27 | 株式会社村田制作所 | 固体电解电容器 |
| JP4978827B2 (ja) * | 2005-06-27 | 2012-07-18 | 株式会社村田製作所 | 固体電解コンデンサ及びその製造方法 |
| JP4720338B2 (ja) * | 2005-07-22 | 2011-07-13 | 株式会社村田製作所 | 複合材料の製造方法 |
| WO2007069738A1 (ja) * | 2005-12-16 | 2007-06-21 | Showa Denko K.K. | 固体電解質の製造方法、および固体電解コンデンサ |
| CN101351182B (zh) | 2005-12-29 | 2016-01-20 | 3M创新有限公司 | 牙科用组合物和具有多环芳族组分的引发剂体系 |
| JP2008004860A (ja) * | 2006-06-26 | 2008-01-10 | Nichicon Corp | 固体電解コンデンサの製造方法 |
| US20080283409A1 (en) * | 2007-05-16 | 2008-11-20 | Qingping Chen | Use of conjugated oligomer as additive for forming conductive polymers |
| EP2133063A1 (en) | 2008-06-10 | 2009-12-16 | 3M Innovative Properties Company | Initiator system with biphenylene derivates, method of production and use thereof |
| CN101350252B (zh) * | 2008-09-17 | 2012-06-27 | 中国振华（集团）新云电子元器件有限责任公司 | 一种常温稳定存放的导电高分子电解质聚合液配方及其应用 |
| TWI470002B (zh) * | 2010-10-20 | 2015-01-21 | Sanyo Chemical Ind Ltd | And a method for producing a conductive film and a conductive film |
| CN102464795A (zh) * | 2010-11-18 | 2012-05-23 | 财团法人工业技术研究院 | 用于形成固态电容的氧化剂、包含其的电解质组合物、固态电容、及其制造方法 |
| CN105810445A (zh) * | 2015-10-29 | 2016-07-27 | 钰邦电子（无锡）有限公司 | 一种高储能电容单元 |
| US11104659B2 (en) | 2016-12-28 | 2021-08-31 | Showa Denko K.K. | Fused heteropolycyclic compound, and method for producing conductive polymer in which said compound is used |
| KR102324388B1 (ko) * | 2016-12-28 | 2021-11-10 | 쇼와 덴코 가부시키가이샤 | 고체 전해 콘덴서의 제조 방법 |
| KR102214676B1 (ko) * | 2016-12-28 | 2021-02-10 | 쇼와 덴코 가부시키가이샤 | 폴리이소티아나프텐계 도전성 중합체의 제조 방법 |
| EP3734626A4 (en) * | 2017-12-25 | 2022-01-05 | Showa Denko K.K. | LIQUID DISPERSION COMPOSITION FOR THE PRODUCTION OF SOLID ELECTROLYTE CAPACITOR, AND PROCESS FOR THE PRODUCTION OF SOLID ELECTROLYTE CAPACITOR |
| CN113853662B (zh) * | 2019-05-17 | 2023-08-04 | 京瓷Avx元器件公司 | 固体电解电容器 |
| JP7357238B2 (ja) * | 2019-06-28 | 2023-10-06 | パナソニックＩｐマネジメント株式会社 | 電解コンデンサおよび電解コンデンサの製造方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4910645A (en) * | 1988-04-30 | 1990-03-20 | Bayer Aktiengesellschaft | Solid electrolytes, and electrolyte capacitors containing same |
| US5223120A (en) * | 1990-11-22 | 1993-06-29 | Matsushita Electric Industrial Co., Ltd. | Method for fabricating solid electrolytic capacitors using an organic conductive layer |
| EP0652576A2 (en) * | 1993-11-10 | 1995-05-10 | Nec Corporation | Method of manufacturing solid electrolytic capacitor |
| US5586001A (en) * | 1994-08-16 | 1996-12-17 | Nec Corporation | Solid electrolyte capacitor using polyaniline doped with disulfonic acid |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2703039B2 (ja) | 1989-03-16 | 1998-01-26 | 昭和電工株式会社 | イソチアナフテン構造を有する重合体およびその製造方法 |
| GB8913512D0 (en) * | 1989-06-13 | 1989-08-02 | Cookson Group Plc | Coated particulate metallic materials |
| JPH03155110A (ja) * | 1989-11-13 | 1991-07-03 | Kao Corp | 固体電解コンデンサの製造方法 |
| JPH05175082A (ja) * | 1991-12-20 | 1993-07-13 | Asahi Glass Co Ltd | 固体電解コンデンサの製造方法 |
| JPH06124728A (ja) * | 1992-10-09 | 1994-05-06 | Mitsubishi Cable Ind Ltd | 高分子固体電解質 |
| JPH0745481A (ja) * | 1993-07-29 | 1995-02-14 | Nec Corp | 固体電解コンデンサ及びその製造方法 |
| JP3694038B2 (ja) * | 1993-09-09 | 2005-09-14 | 日東電工株式会社 | 固体電解コンデンサ |
| JP3070408B2 (ja) * | 1993-12-28 | 2000-07-31 | 日本電気株式会社 | 固体電解コンデンサおよびその製造方法 |
| US5812367A (en) * | 1996-04-04 | 1998-09-22 | Matsushita Electric Industrial Co., Ltd. | Solid electrolytic capacitors comprising a conductive layer made of a polymer of pyrrole or its derivative |
| JP3092512B2 (ja) * | 1996-04-19 | 2000-09-25 | 日本電気株式会社 | 固体電解コンデンサの製造方法 |
| JP3235475B2 (ja) | 1996-07-16 | 2001-12-04 | 日本電気株式会社 | 固体電解コンデンサ及びその製造方法 |
| JP3228155B2 (ja) * | 1996-11-20 | 2001-11-12 | 日本電気株式会社 | 固体電解コンデンサの製造方法 |
-
1998
- 1998-11-27 CN CN2006100086667A patent/CN1835138B/zh not_active Expired - Lifetime
- 1998-11-27 CA CA2278643A patent/CA2278643C/en not_active Expired - Lifetime
- 1998-11-27 EP EP08014711A patent/EP1988556B1/en not_active Expired - Lifetime
- 1998-11-27 AT AT98955967T patent/ATE429705T1/de not_active IP Right Cessation
- 1998-11-27 DE DE69840770T patent/DE69840770D1/de not_active Expired - Lifetime
- 1998-11-27 AT AT08014711T patent/ATE455354T1/de not_active IP Right Cessation
- 1998-11-27 DE DE69841455T patent/DE69841455D1/de not_active Expired - Lifetime
- 1998-11-27 JP JP33687398A patent/JP3187380B2/ja not_active Expired - Lifetime
- 1998-11-27 KR KR1019997006760A patent/KR100596030B1/ko not_active IP Right Cessation
- 1998-11-27 EP EP09013005A patent/EP2146359B1/en not_active Expired - Lifetime
- 1998-11-27 CN CNB98803803XA patent/CN1252138C/zh not_active Expired - Lifetime
- 1998-11-27 WO PCT/JP1998/005352 patent/WO1999028932A1/ja active IP Right Grant
- 1998-11-27 EP EP98955967A patent/EP0971382B1/en not_active Expired - Lifetime
-
1999
- 1999-06-29 TW TW087119685A patent/TW421808B/zh not_active IP Right Cessation
-
2000
- 2000-08-21 JP JP2000249354A patent/JP4908672B2/ja not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4910645A (en) * | 1988-04-30 | 1990-03-20 | Bayer Aktiengesellschaft | Solid electrolytes, and electrolyte capacitors containing same |
| US5223120A (en) * | 1990-11-22 | 1993-06-29 | Matsushita Electric Industrial Co., Ltd. | Method for fabricating solid electrolytic capacitors using an organic conductive layer |
| EP0652576A2 (en) * | 1993-11-10 | 1995-05-10 | Nec Corporation | Method of manufacturing solid electrolytic capacitor |
| US5586001A (en) * | 1994-08-16 | 1996-12-17 | Nec Corporation | Solid electrolyte capacitor using polyaniline doped with disulfonic acid |
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| Title |
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| JP特开平8-337650A 1996.12.24 |
| 说明书第5栏第27行-第11栏第25行、附图1-32. |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1252138C (zh) | 2006-04-19 |
| JP2001076972A (ja) | 2001-03-23 |
| CA2278643C (en) | 2012-02-07 |
| JP2000012394A (ja) | 2000-01-14 |
| JP4908672B2 (ja) | 2012-04-04 |
| CA2278643A1 (en) | 1999-06-10 |
| EP2146359B1 (en) | 2012-05-16 |
| KR20000070516A (ko) | 2000-11-25 |
| EP0971382A1 (en) | 2000-01-12 |
| CN1297569A (zh) | 2001-05-30 |
| CN1835138A (zh) | 2006-09-20 |
| EP1988556A3 (en) | 2008-11-26 |
| EP1988556B1 (en) | 2010-01-13 |
| EP0971382A4 (en) | 2007-05-02 |
| JP3187380B2 (ja) | 2001-07-11 |
| EP1988556A2 (en) | 2008-11-05 |
| DE69841455D1 (de) | 2010-03-04 |
| ATE455354T1 (de) | 2010-01-15 |
| DE69840770D1 (de) | 2009-06-04 |
| EP2146359A1 (en) | 2010-01-20 |
| TW421808B (en) | 2001-02-11 |
| KR100596030B1 (ko) | 2006-07-05 |
| WO1999028932A1 (fr) | 1999-06-10 |
| ATE429705T1 (de) | 2009-05-15 |
| EP0971382B1 (en) | 2009-04-22 |
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