CN1660857B - 二烷基次膦酸盐 - Google Patents
二烷基次膦酸盐 Download PDFInfo
- Publication number
- CN1660857B CN1660857B CN2004101046916A CN200410104691A CN1660857B CN 1660857 B CN1660857 B CN 1660857B CN 2004101046916 A CN2004101046916 A CN 2004101046916A CN 200410104691 A CN200410104691 A CN 200410104691A CN 1660857 B CN1660857 B CN 1660857B
- Authority
- CN
- China
- Prior art keywords
- flame
- weight
- polymer
- dialkylphosphinic salts
- retardant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 150000003839 salts Chemical class 0.000 title claims description 63
- 239000002253 acid Substances 0.000 title claims description 40
- 150000007513 acids Chemical class 0.000 title 1
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 32
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 18
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 8
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 6
- 229910052718 tin Inorganic materials 0.000 claims abstract description 5
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 5
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 4
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 3
- 229910052732 germanium Inorganic materials 0.000 claims abstract description 3
- 229910052742 iron Inorganic materials 0.000 claims abstract description 3
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 3
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 3
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 3
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 3
- 229910052712 strontium Inorganic materials 0.000 claims abstract description 3
- 239000003063 flame retardant Substances 0.000 claims description 159
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 151
- 239000000203 mixture Substances 0.000 claims description 111
- 229920000642 polymer Polymers 0.000 claims description 100
- -1 butyl butyl Chemical group 0.000 claims description 90
- 239000000206 moulding compound Substances 0.000 claims description 67
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- 238000013329 compounding Methods 0.000 claims description 30
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 28
- 239000004411 aluminium Substances 0.000 claims description 27
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 27
- 229920000388 Polyphosphate Polymers 0.000 claims description 24
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 24
- 239000001205 polyphosphate Substances 0.000 claims description 24
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- 238000001746 injection moulding Methods 0.000 claims description 21
- 230000000996 additive effect Effects 0.000 claims description 20
- 239000002245 particle Substances 0.000 claims description 19
- 239000011701 zinc Substances 0.000 claims description 17
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 14
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- 229920002223 polystyrene Polymers 0.000 claims description 12
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical class NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 claims description 11
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- YZEZMSPGIPTEBA-UHFFFAOYSA-N 2-n-(4,6-diamino-1,3,5-triazin-2-yl)-1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(NC=2N=C(N)N=C(N)N=2)=N1 YZEZMSPGIPTEBA-UHFFFAOYSA-N 0.000 claims description 8
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 8
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- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 8
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- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims description 7
- 239000010936 titanium Substances 0.000 claims description 7
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- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 6
- HVHZIOXTVVFZGV-UHFFFAOYSA-N diphosphono hydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical class NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(=O)OP(O)(O)=O HVHZIOXTVVFZGV-UHFFFAOYSA-N 0.000 claims description 6
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- 125000003003 spiro group Chemical group 0.000 claims description 6
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- GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 claims description 4
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims description 4
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims description 4
- VPVSTMAPERLKKM-UHFFFAOYSA-N glycoluril Chemical compound N1C(=O)NC2NC(=O)NC21 VPVSTMAPERLKKM-UHFFFAOYSA-N 0.000 claims description 4
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- 229920001169 thermoplastic Polymers 0.000 claims description 4
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- 239000011135 tin Substances 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims description 3
- 239000004110 Zinc silicate Substances 0.000 claims description 3
- FDJZNXLKZOXHPN-UHFFFAOYSA-N [hydroxy(phosphonooxy)phosphoryl] phosphono hydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(=O)OP(O)(=O)OP(O)(O)=O FDJZNXLKZOXHPN-UHFFFAOYSA-N 0.000 claims description 3
- OXIACMHTSQNJCY-UHFFFAOYSA-N bis[hydroxy(phosphonooxy)phosphoryl] hydrogen phosphate 1,3,5-triazine-2,4,6-triamine Chemical class OP(O)(=O)OP(=O)(O)OP(=O)(O)OP(=O)(O)OP(=O)(O)O.N1=C(N)N=C(N)N=C1N OXIACMHTSQNJCY-UHFFFAOYSA-N 0.000 claims description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 150000001718 carbodiimides Chemical class 0.000 claims description 3
- 230000001788 irregular Effects 0.000 claims description 3
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229920001228 polyisocyanate Polymers 0.000 claims description 3
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- 239000004634 thermosetting polymer Substances 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium(II) oxide Chemical compound [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
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- XSMMCTCMFDWXIX-UHFFFAOYSA-N zinc silicate Chemical compound [Zn+2].[O-][Si]([O-])=O XSMMCTCMFDWXIX-UHFFFAOYSA-N 0.000 claims description 3
- 235000019352 zinc silicate Nutrition 0.000 claims description 3
- XAEWLETZEZXLHR-UHFFFAOYSA-N zinc;dioxido(dioxo)molybdenum Chemical compound [Zn+2].[O-][Mo]([O-])(=O)=O XAEWLETZEZXLHR-UHFFFAOYSA-N 0.000 claims description 3
- OAQMANYMWYGWEP-UHFFFAOYSA-N CCCCCC(CC)O[PH2]=O Chemical class CCCCCC(CC)O[PH2]=O OAQMANYMWYGWEP-UHFFFAOYSA-N 0.000 claims description 2
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- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920003251 poly(α-methylstyrene) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920002480 polybenzimidazole Polymers 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920001444 polymaleic acid Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 125000005402 stannate group Chemical group 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000003351 stiffener Substances 0.000 description 1
- 229920000638 styrene acrylonitrile Polymers 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 229920001866 very low density polyethylene Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/301—Acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34928—Salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
Description
蜜胺多磷酸盐 | Melapur 200/70,Ciba SC |
蜜胺氰尿酸酯 | Melapur MC,Ciba SC |
硼酸锌 | Firebrake 500,Borax |
氧化锌 | Rheinchemie |
聚对苯二甲酸丁二醇酯1 | Celanex 2300-GV1/30,Celanese,USA |
聚对苯二甲酸丁二醇酯2 | Celanex 2500,Celanese,USA |
聚酰胺-6,6 | Ultramid A3,BASF |
聚酰胺-6 | Zytel 7301,DuPont |
聚苯乙烯 | 聚苯乙烯143 E,BASF |
玻璃纤维1 | Vetrotex EC 10983,4.5mm,Saint Gobain |
玻璃纤维2 | Chop Vantage 3540,PPG |
实施例 | 1(对比) | 2(对比) | 3 | 4 | 5 | |
二乙基次膦酸的Al盐 | mol% | 87.2 | 90.8 | 98.6 | 96.5 | 93.9 |
乙基丁基次膦酸的Al盐 | mol% | 11.9 | 8.4 | 0.9 | 2.7 | 5.5 |
乙基膦酸的Al盐 | mol% | 0.9 | 0.8 | 0.5 | 0.8 | 0.6 |
残余乙酸根 | %重量 | 0.88 | 0.45 | 0 | 0 | 0 |
实施例 | 6 | 7 | 8 | 9 | 10 | 11 | 12 | 13 | 14 | 15 | 16 | 17 | 18 | 19 | |
产物实施例1的产物 | %重量 | 25 | 12 | 11.4 | |||||||||||
产物实施例2的产物 | %重量 | 25 | |||||||||||||
产物实施例3的产物 | %重量 | 25 | 12 | 11.4 | |||||||||||
产物实施例4的产物 | %重量 | 25 | 11. 4 | 12 | 30 | ||||||||||
产物实施例5的产物 | %重量 | 25 | |||||||||||||
蜜胺多磷酸盐 | %重量 | 5.7 | 5.7 | 5.7 | 6 | ||||||||||
蜜胺氰尿酸酯 | %重量 | 6 | 6 | ||||||||||||
硼酸锌 | %重量 | 0.9 | 0.9 | 0.9 | |||||||||||
氧化锌 | %重量 | ||||||||||||||
聚对苯二甲酸丁二醇酯1 | %重量 | 100 | 75 | 75 | 75 | 75 | 75 | ||||||||
聚对苯二甲酸丁二醇酯2 | %重量 | 52 | 52 | ||||||||||||
聚酰胺-6,6 | %重量 | 70 | 52 | 52 | 52 | ||||||||||
聚酰胺-6 | %重量 | 52 | |||||||||||||
聚苯乙烯 | %重量 | 70 | |||||||||||||
玻璃纤维1 | %重量 | 30 | 30 | 30 | 30 | 30 | 30 | ||||||||
玻璃纤维2 | %重量 | 30 | |||||||||||||
粘度值 | - | 1072 | 719 | 758 | 1023 | 1034 | 995 | 716 | 1005 | - | - | - | - | - | - |
熔体流动指数,275℃ | 2cm<sup>3</sup>/min | - | - | - | - | - | - | - | - | 5.8 | 16.7 | 4.1 | 5.6 | 4.9 | - |
UL 94分级 | - | Nk1 | V-2 | V-2 | V-0 | V-0 | V-0 | V-1 | V-0 | Nk1 | V-2 | V-0 | V-0 | V-0 | V-0 |
Claims (45)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10359814A DE10359814A1 (de) | 2003-12-19 | 2003-12-19 | Dialkylphosphinsäure-Salze |
DE10359814.6 | 2003-12-19 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1660857A CN1660857A (zh) | 2005-08-31 |
CN1660857B true CN1660857B (zh) | 2010-08-04 |
Family
ID=34485510
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2004101046916A Ceased CN1660857B (zh) | 2003-12-19 | 2004-12-17 | 二烷基次膦酸盐 |
Country Status (8)
Country | Link |
---|---|
US (1) | US7420007B2 (zh) |
EP (1) | EP1544206B1 (zh) |
JP (1) | JP4870924B2 (zh) |
CN (1) | CN1660857B (zh) |
AT (1) | ATE388155T1 (zh) |
DE (2) | DE10359814A1 (zh) |
ES (1) | ES2301920T3 (zh) |
HK (1) | HK1080863A1 (zh) |
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TWI834617B (zh) | 2017-07-14 | 2024-03-11 | 瑞士商克萊瑞特國際股份有限公司 | 阻燃黑色聚醯胺組成物及其用途 |
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WO2019144331A1 (zh) | 2018-01-24 | 2019-08-01 | 金发科技股份有限公司 | 一种氨基三亚甲基膦酸铝及其制备方法和应用 |
CN109851852A (zh) * | 2018-12-28 | 2019-06-07 | 江苏利思德新材料有限公司 | 一种低腐蚀性的二烷基次膦酸盐组合物及其应用 |
CN114685856A (zh) * | 2022-04-21 | 2022-07-01 | 兰州瑞朴科技有限公司 | 二乙基次膦酸铝的制备方法 |
CN114685856B (zh) * | 2022-04-21 | 2024-02-20 | 兰州瑞朴科技有限公司 | 二乙基次膦酸铝的制备方法 |
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JP2005179360A (ja) | 2005-07-07 |
ATE388155T1 (de) | 2008-03-15 |
DE10359814A1 (de) | 2005-07-28 |
DE502004006400D1 (zh) | 2008-04-17 |
JP4870924B2 (ja) | 2012-02-08 |
HK1080863A1 (en) | 2006-05-04 |
ES2301920T3 (es) | 2008-07-01 |
US20060074157A1 (en) | 2006-04-06 |
EP1544206A1 (de) | 2005-06-22 |
EP1544206B1 (de) | 2008-03-05 |
CN1660857A (zh) | 2005-08-31 |
US7420007B2 (en) | 2008-09-02 |
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