TW202239700A - 包含聚磷酸銨之組成物 - Google Patents
包含聚磷酸銨之組成物 Download PDFInfo
- Publication number
- TW202239700A TW202239700A TW110141515A TW110141515A TW202239700A TW 202239700 A TW202239700 A TW 202239700A TW 110141515 A TW110141515 A TW 110141515A TW 110141515 A TW110141515 A TW 110141515A TW 202239700 A TW202239700 A TW 202239700A
- Authority
- TW
- Taiwan
- Prior art keywords
- sulfate
- weight
- composition
- styrene
- ammonium polyphosphate
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 125
- 229920001276 ammonium polyphosphate Polymers 0.000 title claims abstract description 55
- 235000019826 ammonium polyphosphate Nutrition 0.000 title claims abstract description 53
- 238000000576 coating method Methods 0.000 claims abstract description 49
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 47
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 76
- 229920001577 copolymer Polymers 0.000 claims description 70
- 229920000642 polymer Polymers 0.000 claims description 57
- -1 plasterboard Substances 0.000 claims description 51
- 239000000654 additive Substances 0.000 claims description 26
- 229910000831 Steel Inorganic materials 0.000 claims description 24
- 239000010959 steel Substances 0.000 claims description 24
- 239000000126 substance Substances 0.000 claims description 23
- 239000003063 flame retardant Substances 0.000 claims description 21
- 239000004952 Polyamide Substances 0.000 claims description 18
- 229920002647 polyamide Polymers 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 14
- 229920000877 Melamine resin Polymers 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 13
- 239000011248 coating agent Substances 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 13
- 239000004800 polyvinyl chloride Substances 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 239000004814 polyurethane Substances 0.000 claims description 12
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 12
- 239000000047 product Substances 0.000 claims description 12
- 229920000728 polyester Polymers 0.000 claims description 11
- 229920000570 polyether Polymers 0.000 claims description 11
- 239000002904 solvent Substances 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 10
- 229920000098 polyolefin Polymers 0.000 claims description 10
- 229920002635 polyurethane Polymers 0.000 claims description 10
- 239000000725 suspension Substances 0.000 claims description 10
- 239000002562 thickening agent Substances 0.000 claims description 10
- 239000004604 Blowing Agent Substances 0.000 claims description 9
- 239000005977 Ethylene Substances 0.000 claims description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- 239000000839 emulsion Substances 0.000 claims description 9
- 229920005862 polyol Polymers 0.000 claims description 9
- 229920002554 vinyl polymer Polymers 0.000 claims description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 8
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 8
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- 239000004753 textile Substances 0.000 claims description 8
- 239000000853 adhesive Substances 0.000 claims description 7
- 230000001070 adhesive effect Effects 0.000 claims description 7
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical group NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 7
- 150000003077 polyols Chemical class 0.000 claims description 7
- 239000011877 solvent mixture Substances 0.000 claims description 7
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 239000006254 rheological additive Substances 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 229920001169 thermoplastic Polymers 0.000 claims description 6
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- 229920001971 elastomer Polymers 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 239000004744 fabric Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 229920001568 phenolic resin Polymers 0.000 claims description 5
- 229920000058 polyacrylate Polymers 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- 229920000193 polymethacrylate Polymers 0.000 claims description 5
- 229920001282 polysaccharide Polymers 0.000 claims description 5
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 5
- 239000005060 rubber Substances 0.000 claims description 5
- 239000004416 thermosoftening plastic Substances 0.000 claims description 5
- 239000002023 wood Substances 0.000 claims description 5
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 229920001519 homopolymer Polymers 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 4
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 4
- GJQIMXVRFNLMTB-UHFFFAOYSA-N nonyl acetate Chemical compound CCCCCCCCCOC(C)=O GJQIMXVRFNLMTB-UHFFFAOYSA-N 0.000 claims description 4
- 239000005011 phenolic resin Substances 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 4
- 239000011118 polyvinyl acetate Substances 0.000 claims description 4
- 150000005846 sugar alcohols Polymers 0.000 claims description 4
- 239000008096 xylene Substances 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 claims description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 3
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 150000004945 aromatic hydrocarbons Chemical group 0.000 claims description 3
- 239000004359 castor oil Substances 0.000 claims description 3
- 235000019438 castor oil Nutrition 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 235000010980 cellulose Nutrition 0.000 claims description 3
- 230000009970 fire resistant effect Effects 0.000 claims description 3
- 150000004676 glycans Chemical class 0.000 claims description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- 238000009434 installation Methods 0.000 claims description 3
- 239000011490 mineral wool Substances 0.000 claims description 3
- NKNFUMKGJYKPCT-UHFFFAOYSA-N n,n-diethylethanamine;sulfuric acid Chemical compound [O-]S([O-])(=O)=O.CC[NH+](CC)CC.CC[NH+](CC)CC NKNFUMKGJYKPCT-UHFFFAOYSA-N 0.000 claims description 3
- 239000003791 organic solvent mixture Substances 0.000 claims description 3
- 239000000123 paper Substances 0.000 claims description 3
- 229920002401 polyacrylamide Polymers 0.000 claims description 3
- 239000005017 polysaccharide Substances 0.000 claims description 3
- 229920002050 silicone resin Polymers 0.000 claims description 3
- 229910000679 solder Inorganic materials 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- 229920001187 thermosetting polymer Polymers 0.000 claims description 3
- 239000004634 thermosetting polymer Substances 0.000 claims description 3
- 238000009736 wetting Methods 0.000 claims description 3
- ZNBNBTIDJSKEAM-UHFFFAOYSA-N 4-[7-hydroxy-2-[5-[5-[6-hydroxy-6-(hydroxymethyl)-3,5-dimethyloxan-2-yl]-3-methyloxolan-2-yl]-5-methyloxolan-2-yl]-2,8-dimethyl-1,10-dioxaspiro[4.5]decan-9-yl]-2-methyl-3-propanoyloxypentanoic acid Chemical compound C1C(O)C(C)C(C(C)C(OC(=O)CC)C(C)C(O)=O)OC11OC(C)(C2OC(C)(CC2)C2C(CC(O2)C2C(CC(C)C(O)(CO)O2)C)C)CC1 ZNBNBTIDJSKEAM-UHFFFAOYSA-N 0.000 claims description 2
- FUSNOPLQVRUIIM-UHFFFAOYSA-N 4-amino-2-(4,4-dimethyl-2-oxoimidazolidin-1-yl)-n-[3-(trifluoromethyl)phenyl]pyrimidine-5-carboxamide Chemical compound O=C1NC(C)(C)CN1C(N=C1N)=NC=C1C(=O)NC1=CC=CC(C(F)(F)F)=C1 FUSNOPLQVRUIIM-UHFFFAOYSA-N 0.000 claims description 2
- 241000220479 Acacia Species 0.000 claims description 2
- 229920001817 Agar Polymers 0.000 claims description 2
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 2
- 235000010643 Leucaena leucocephala Nutrition 0.000 claims description 2
- 229920000881 Modified starch Polymers 0.000 claims description 2
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims description 2
- 229920005830 Polyurethane Foam Polymers 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- RJFAYQIBOAGBLC-BYPYZUCNSA-N Selenium-L-methionine Chemical compound C[Se]CC[C@H](N)C(O)=O RJFAYQIBOAGBLC-BYPYZUCNSA-N 0.000 claims description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- SSBRSHIQIANGKS-UHFFFAOYSA-N [amino(hydroxy)methylidene]azanium;hydrogen sulfate Chemical compound NC(N)=O.OS(O)(=O)=O SSBRSHIQIANGKS-UHFFFAOYSA-N 0.000 claims description 2
- 239000002671 adjuvant Substances 0.000 claims description 2
- 239000008272 agar Substances 0.000 claims description 2
- 235000010443 alginic acid Nutrition 0.000 claims description 2
- 229920000615 alginic acid Polymers 0.000 claims description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 2
- 230000004888 barrier function Effects 0.000 claims description 2
- JXRVKYBCWUJJBP-UHFFFAOYSA-L calcium;hydrogen sulfate Chemical compound [Ca+2].OS([O-])(=O)=O.OS([O-])(=O)=O JXRVKYBCWUJJBP-UHFFFAOYSA-L 0.000 claims description 2
- 239000003990 capacitor Substances 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- OZECDDHOAMNMQI-UHFFFAOYSA-H cerium(3+);trisulfate Chemical compound [Ce+3].[Ce+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O OZECDDHOAMNMQI-UHFFFAOYSA-H 0.000 claims description 2
- 229940044175 cobalt sulfate Drugs 0.000 claims description 2
- 229910000361 cobalt sulfate Inorganic materials 0.000 claims description 2
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 claims description 2
- 239000007859 condensation product Substances 0.000 claims description 2
- 238000004132 cross linking Methods 0.000 claims description 2
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims description 2
- DENRZWYUOJLTMF-UHFFFAOYSA-N diethyl sulfate Chemical compound CCOS(=O)(=O)OCC DENRZWYUOJLTMF-UHFFFAOYSA-N 0.000 claims description 2
- 229940008406 diethyl sulfate Drugs 0.000 claims description 2
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 claims description 2
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical compound [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 2
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical class CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 claims description 2
- 239000000499 gel Substances 0.000 claims description 2
- 239000003365 glass fiber Substances 0.000 claims description 2
- 239000012493 hydrazine sulfate Substances 0.000 claims description 2
- 229910000377 hydrazine sulfate Inorganic materials 0.000 claims description 2
- 229910000378 hydroxylammonium sulfate Inorganic materials 0.000 claims description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 2
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 2
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 claims description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 239000000347 magnesium hydroxide Substances 0.000 claims description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 2
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 2
- FXBYOMANNHFNQV-UHFFFAOYSA-L magnesium;hydrogen sulfate Chemical compound [Mg+2].OS([O-])(=O)=O.OS([O-])(=O)=O FXBYOMANNHFNQV-UHFFFAOYSA-L 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 claims description 2
- 239000002557 mineral fiber Substances 0.000 claims description 2
- 235000019426 modified starch Nutrition 0.000 claims description 2
- DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 claims description 2
- 150000003097 polyterpenes Chemical class 0.000 claims description 2
- 229920003009 polyurethane dispersion Polymers 0.000 claims description 2
- 239000011496 polyurethane foam Substances 0.000 claims description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 2
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 claims description 2
- CHKVPAROMQMJNQ-UHFFFAOYSA-M potassium bisulfate Chemical compound [K+].OS([O-])(=O)=O CHKVPAROMQMJNQ-UHFFFAOYSA-M 0.000 claims description 2
- 229910000343 potassium bisulfate Inorganic materials 0.000 claims description 2
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 2
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 2
- 235000011151 potassium sulphates Nutrition 0.000 claims description 2
- 238000004382 potting Methods 0.000 claims description 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- 150000004760 silicates Chemical class 0.000 claims description 2
- 229920002379 silicone rubber Polymers 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 claims description 2
- 229910000342 sodium bisulfate Inorganic materials 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- 239000000600 sorbitol Substances 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000000346 sugar Nutrition 0.000 claims description 2
- 150000008163 sugars Chemical class 0.000 claims description 2
- CSMFSDCPJHNZRY-UHFFFAOYSA-N sulfuric acid monodecyl ester Natural products CCCCCCCCCCOS(O)(=O)=O CSMFSDCPJHNZRY-UHFFFAOYSA-N 0.000 claims description 2
- LTURHSAEWJPFAA-UHFFFAOYSA-N sulfuric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OS(O)(=O)=O.NC1=NC(N)=NC(N)=N1 LTURHSAEWJPFAA-UHFFFAOYSA-N 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 150000003505 terpenes Chemical class 0.000 claims description 2
- 235000007586 terpenes Nutrition 0.000 claims description 2
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 claims description 2
- KJFVITRRNTVAPC-UHFFFAOYSA-L tetramethylazanium;sulfate Chemical compound C[N+](C)(C)C.C[N+](C)(C)C.[O-]S([O-])(=O)=O KJFVITRRNTVAPC-UHFFFAOYSA-L 0.000 claims description 2
- FAKFSJNVVCGEEI-UHFFFAOYSA-J tin(4+);disulfate Chemical compound [Sn+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O FAKFSJNVVCGEEI-UHFFFAOYSA-J 0.000 claims description 2
- 229910000348 titanium sulfate Inorganic materials 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- 150000003673 urethanes Chemical class 0.000 claims description 2
- 229920001567 vinyl ester resin Polymers 0.000 claims description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 2
- 229960001763 zinc sulfate Drugs 0.000 claims description 2
- 239000004368 Modified starch Substances 0.000 claims 1
- 229920002125 Sokalan® Polymers 0.000 claims 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims 1
- 235000012216 bentonite Nutrition 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 239000004088 foaming agent Substances 0.000 claims 1
- 238000005470 impregnation Methods 0.000 claims 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
- 239000004584 polyacrylic acid Substances 0.000 claims 1
- 229920000768 polyamine Polymers 0.000 claims 1
- UWSCPROMPSAQOL-UHFFFAOYSA-N trimethylazanium;sulfate Chemical compound CN(C)C.CN(C)C.OS(O)(=O)=O UWSCPROMPSAQOL-UHFFFAOYSA-N 0.000 claims 1
- 238000009472 formulation Methods 0.000 description 30
- 239000005062 Polybutadiene Substances 0.000 description 17
- 229920002857 polybutadiene Polymers 0.000 description 17
- 239000000758 substrate Substances 0.000 description 16
- 229920001684 low density polyethylene Polymers 0.000 description 13
- 239000004702 low-density polyethylene Substances 0.000 description 13
- 239000004417 polycarbonate Substances 0.000 description 13
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 12
- 150000001993 dienes Chemical class 0.000 description 12
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 11
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 11
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
- 229920006324 polyoxymethylene Polymers 0.000 description 10
- 229920009204 Methacrylate-butadiene-styrene Polymers 0.000 description 9
- 239000004677 Nylon Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 229920001903 high density polyethylene Polymers 0.000 description 9
- 239000004700 high-density polyethylene Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 229920001778 nylon Polymers 0.000 description 9
- 229920000515 polycarbonate Polymers 0.000 description 9
- 229920002943 EPDM rubber Polymers 0.000 description 8
- 239000004721 Polyphenylene oxide Substances 0.000 description 8
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 8
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 8
- 229920001707 polybutylene terephthalate Polymers 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000005038 ethylene vinyl acetate Substances 0.000 description 7
- 239000004698 Polyethylene Substances 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 6
- 239000006260 foam Substances 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 229920001155 polypropylene Polymers 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 5
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 5
- 239000008199 coating composition Substances 0.000 description 5
- 229920000638 styrene acrylonitrile Polymers 0.000 description 5
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- 229930040373 Paraformaldehyde Natural products 0.000 description 4
- 229920002367 Polyisobutene Polymers 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 229920001400 block copolymer Polymers 0.000 description 4
- 239000004202 carbamide Substances 0.000 description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 description 4
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 4
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 4
- 150000001991 dicarboxylic acids Chemical class 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 150000005673 monoalkenes Chemical class 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 229920006380 polyphenylene oxide Polymers 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 230000008961 swelling Effects 0.000 description 4
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 3
- 229920002292 Nylon 6 Polymers 0.000 description 3
- 229920013620 Pliolite Polymers 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- 229920002396 Polyurea Polymers 0.000 description 3
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 229920000800 acrylic rubber Polymers 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 229920000092 linear low density polyethylene Polymers 0.000 description 3
- 239000004707 linear low-density polyethylene Substances 0.000 description 3
- 229920001179 medium density polyethylene Polymers 0.000 description 3
- 239000004701 medium-density polyethylene Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920001955 polyphenylene ether Polymers 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 229920001897 terpolymer Polymers 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 3
- 239000013008 thixotropic agent Substances 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 2
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 2
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 239000004709 Chlorinated polyethylene Substances 0.000 description 2
- 239000004921 DEGALAN® Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical compound CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 2
- 229920000299 Nylon 12 Polymers 0.000 description 2
- 229920007019 PC/ABS Polymers 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920003006 Polybutadiene acrylonitrile Polymers 0.000 description 2
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 125000005250 alkyl acrylate group Chemical group 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- BXOUVIIITJXIKB-UHFFFAOYSA-N ethene;styrene Chemical group C=C.C=CC1=CC=CC=C1 BXOUVIIITJXIKB-UHFFFAOYSA-N 0.000 description 2
- 239000004794 expanded polystyrene Substances 0.000 description 2
- 239000004795 extruded polystyrene foam Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229920000578 graft copolymer Polymers 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 229920005669 high impact polystyrene Polymers 0.000 description 2
- 239000004797 high-impact polystyrene Substances 0.000 description 2
- 229920000554 ionomer Polymers 0.000 description 2
- 150000002596 lactones Chemical class 0.000 description 2
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 2
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N perisophthalic acid Natural products OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 229920001627 poly(4-methyl styrene) Polymers 0.000 description 2
- 229920003251 poly(α-methylstyrene) Polymers 0.000 description 2
- 229920001748 polybutylene Polymers 0.000 description 2
- 239000005056 polyisocyanate Substances 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 229920006327 polystyrene foam Polymers 0.000 description 2
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 2
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 239000011115 styrene butadiene Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical class CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 2
- 150000003672 ureas Chemical class 0.000 description 2
- JLYXXMFPNIAWKQ-UHFFFAOYSA-N γ Benzene hexachloride Chemical compound ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 1
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
- GXSSZJREKCITAD-ARJAWSKDSA-N (z)-4-ethenoxy-4-oxobut-2-enoic acid Chemical compound OC(=O)\C=C/C(=O)OC=C GXSSZJREKCITAD-ARJAWSKDSA-N 0.000 description 1
- YMOSUBJHLKNJIU-UHFFFAOYSA-N 1,1-dichloroethene Chemical compound ClC(Cl)=C.ClC(Cl)=C YMOSUBJHLKNJIU-UHFFFAOYSA-N 0.000 description 1
- RMCLVYNUTRHDDI-UHFFFAOYSA-N 1,1-dichloroethene;ethenyl acetate Chemical compound ClC(Cl)=C.CC(=O)OC=C RMCLVYNUTRHDDI-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- BSYJHYLAMMJNRC-UHFFFAOYSA-N 2,4,4-trimethylpentan-2-ol Chemical compound CC(C)(C)CC(C)(C)O BSYJHYLAMMJNRC-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- FFODZTFGFDDGQQ-UHFFFAOYSA-N 2-methylprop-2-enoic acid;5-phenylpenta-2,4-dienenitrile Chemical class CC(=C)C(O)=O.N#CC=CC=CC1=CC=CC=C1 FFODZTFGFDDGQQ-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 1
- XUNOTVCHDSGWNA-UHFFFAOYSA-N C[NH3+].S(=O)(=O)([O-])[O-].C[NH+](C)C Chemical compound C[NH3+].S(=O)(=O)([O-])[O-].C[NH+](C)C XUNOTVCHDSGWNA-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- 239000004970 Chain extender Substances 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- 229920004022 Makrolon® 2205 Polymers 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920001007 Nylon 4 Polymers 0.000 description 1
- 229920003189 Nylon 4,6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 229920000572 Nylon 6/12 Polymers 0.000 description 1
- 229920000577 Nylon 6/66 Polymers 0.000 description 1
- 229920006778 PC/PBT Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229920006292 Polyphenylene isophthalamide Polymers 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 229920001756 Polyvinyl chloride acetate Polymers 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- WAKTWVHWRCNIKU-UHFFFAOYSA-N S(=O)(=O)(O)O.[AlH3] Chemical compound S(=O)(=O)(O)O.[AlH3] WAKTWVHWRCNIKU-UHFFFAOYSA-N 0.000 description 1
- 229920006328 Styrofoam Polymers 0.000 description 1
- 229920006329 Styropor Polymers 0.000 description 1
- 229920006097 Ultramide® Polymers 0.000 description 1
- 229920010346 Very Low Density Polyethylene (VLDPE) Polymers 0.000 description 1
- 239000004708 Very-low-density polyethylene Substances 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- NXDJCCBHUGWQPG-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol;terephthalic acid Chemical compound OCC1CCC(CO)CC1.OC(=O)C1=CC=C(C(O)=O)C=C1 NXDJCCBHUGWQPG-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000004840 adhesive resin Substances 0.000 description 1
- 229920006223 adhesive resin Polymers 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- TZYHIGCKINZLPD-UHFFFAOYSA-N azepan-2-one;hexane-1,6-diamine;hexanedioic acid Chemical compound NCCCCCCN.O=C1CCCCCN1.OC(=O)CCCCC(O)=O TZYHIGCKINZLPD-UHFFFAOYSA-N 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- SYWDWCWQXBUCOP-UHFFFAOYSA-N benzene;ethene Chemical group C=C.C1=CC=CC=C1 SYWDWCWQXBUCOP-UHFFFAOYSA-N 0.000 description 1
- DWSWCPPGLRSPIT-UHFFFAOYSA-N benzo[c][2,1]benzoxaphosphinin-6-ium 6-oxide Chemical compound C1=CC=C2[P+](=O)OC3=CC=CC=C3C2=C1 DWSWCPPGLRSPIT-UHFFFAOYSA-N 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004841 bisphenol A epoxy resin Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical group CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- YWJUZWOHLHBWQY-UHFFFAOYSA-N decanedioic acid;hexane-1,6-diamine Chemical compound NCCCCCCN.OC(=O)CCCCCCCCC(O)=O YWJUZWOHLHBWQY-UHFFFAOYSA-N 0.000 description 1
- 230000000368 destabilizing effect Effects 0.000 description 1
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- ZMUCVNSKULGPQG-UHFFFAOYSA-N dodecanedioic acid;hexane-1,6-diamine Chemical compound NCCCCCCN.OC(=O)CCCCCCCCCCC(O)=O ZMUCVNSKULGPQG-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical class OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000011151 fibre-reinforced plastic Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 229920005555 halobutyl Polymers 0.000 description 1
- 125000004968 halobutyl group Chemical group 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 229920002681 hypalon Polymers 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229920000831 ionic polymer Polymers 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- SXQFCVDSOLSHOQ-UHFFFAOYSA-N lactamide Chemical class CC(O)C(N)=O SXQFCVDSOLSHOQ-UHFFFAOYSA-N 0.000 description 1
- 238000010330 laser marking Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- NYBDEQVBEYXMHK-UHFFFAOYSA-N methyl prop-2-enoate;5-phenylpenta-2,4-dienenitrile Chemical compound COC(=O)C=C.N#CC=CC=CC1=CC=CC=C1 NYBDEQVBEYXMHK-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229910052615 phyllosilicate Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920003055 poly(ester-imide) Polymers 0.000 description 1
- 229920001643 poly(ether ketone) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Chemical group 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920002480 polybenzimidazole Polymers 0.000 description 1
- 229920001692 polycarbonate urethane Polymers 0.000 description 1
- 150000003071 polychlorinated biphenyls Chemical class 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920000232 polyglycine polymer Polymers 0.000 description 1
- 229920006123 polyhexamethylene isophthalamide Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000004313 potentiometry Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229920003124 powdered cellulose Polymers 0.000 description 1
- 235000019814 powdered cellulose Nutrition 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000008261 styrofoam Substances 0.000 description 1
- 150000003458 sulfonic acid derivatives Chemical class 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 229920001866 very low density polyethylene Polymers 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L85/00—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers
- C08L85/02—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/016—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
- C09D5/185—Intumescent paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/69—Particle size larger than 1000 nm
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/02—Inorganic materials
- C09K21/04—Inorganic materials containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
- C08K2003/3054—Ammonium sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
- C08K2003/3063—Magnesium sulfate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
- C08K2003/3072—Iron sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
- C08K2003/3081—Aluminum sulfate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Fireproofing Substances (AREA)
Abstract
本發明關於組成物,其包含,
0.1重量%至99.9重量%之結晶相II聚磷酸銨作為組分(A),及
0.1重量%至99.9重量%之結晶相I及/或結晶相III、IV、V及/或VI聚磷酸銨作為組分(B),其中該等組分的總和為100重量%,且關於其在膨脹型塗料中的用途。
Description
本發明關於包含聚磷酸銨之組成物。
聚磷酸銨被廣泛地用作為阻燃劑。另外,有可能使用聚磷酸銨防止在含有游離硝酸及適用於金屬之表面處理的(酸)浴中釋放亞硝氣體(EP-A-0004560)。
聚磷酸銨可以幾種晶形(I至VI)出現,其中晶形I的聚磷酸銨可自縮合劑及磷酸或磷酸鹽合成。
晶形II的聚磷酸銨為微溶於水的產品且已知其作為用於合成樹脂之阻燃成分。其通常係自五氧化二磷製備。
用於製備晶形II的聚磷酸銨之已知方法的特徵在於將晶形I的聚磷酸銨經受一段特定時間的熱處理為特徵(C. Y. Shen等人之Journal of American Chemical Society, vol. 91, p. 62 (1969)。在此同樣提出用於製備晶形II和IV之方法。
M. Watanabe, M. Sakurai和M. Takahashi之Phosphorus Research Bulletin 2003, 16, p. 39-46說明晶形I和晶形V的聚磷酸銨。
用於製備晶形II的聚磷酸銨之不同方法係由M. Watanabe, N. Narita, M. Sakurai, H. Suzuki之Bulletin of the Chemical Society of Japan 2000, 73, 115-119及R. C. Sheridan, J. F. McCullough, N. E. Stahlheber, C. Y. Shen於Inorganic Syntheses, John Wiley & Sons, Inc, 1979, 278-280中及K. R. Waerstad, G. H. McClellan之J. Agric. Food Chem. 1976, 24, 412-415說明。
US-A-3,978,195請求用於製備基本上不溶於水的鏈狀聚磷酸銨之方法,其中將等莫耳量的正磷酸銨與五氧化二磷在具備有混合工具的反應器中在介於170與350℃之間的溫度下及在氨氣的存在下於不斷的混合、捏合及粉碎下反應。
在EP-A-0537475所述之另一方法中,將正磷酸銨、五氧化二磷及氣態氨在第一階段中相互反應,以便於中間物在第二階段在氨氛圍下於盤式乾燥器上進一步冷凝且乾燥。
聚磷酸銨通常難以高純度及均質形式製得;其殘留水分含量及吸濕性質特別在儲存和運輸方面出現相當大的問題。
現今已知的聚磷酸銨最常用於膨脹型調配物中,其接著又用作耐火塗料。
鑑於習知的耐火調配物主要用於保護熱敏感性較低的基材,諸如鋼材、鋁材及/或混凝土,但發展對熱穩定性較低的基材之絕緣(保護)需求日益增長。該等可能為有機及無機材料。該等可能具有聚合及非聚合特徵。
在低溫下的熱絕緣為所有基材必不可少的,因為不僅抑制發生的熱解反應;且在惰性基材(例如鋼材)的情況下,亦由於在低溫下發生膨脹而於整個火災過程期間增加絕緣效應。有可能達成更長的耐火時間或明顯地減少所應用的量。
因此,本發明之目的係提供穩定及易於處理且導致增加的基材保護之聚磷酸銨,尤其在用於膨脹型塗料的情況下。
此目的係由包含下列之組成物達成:
0.1重量%至99.9重量%之結晶相II聚磷酸銨作為組分(A),及
0.1重量%至99.9重量%之結晶相I及/或結晶相III、IV、V及/或VI聚磷酸銨作為組分(B),其中該等組分的總和為100重量%。
組成物較佳地含有60重量%至99.9重量%之組分A及0.1重量%至40重量%之組分B。
組成物更加地含有65重量%至92重量%之組分A及8重量%至35重量%之組分B。
優先選擇為其中組分A為結晶相II聚磷酸銨及組分B為結晶相I聚磷酸銨之組成物。
組分A較佳為具有式(NH
4)
n+2P
nO
3n+1,以n=300至100000之結晶相II聚磷酸銨。
組分A更佳為具有式(NH
4)
n+2P
nO
3n+1,以n=1000至25000之結晶相II聚磷酸銨。
組分B較佳為具有式(NH
4)
n+2P
nO
3n+1,以n=5至100之結晶相I聚磷酸銨。
根據本發明之組成物較佳地具有
- 根據ISO 760的少於0.5%之殘留水分含量(水含量),
- 0.3至0.9g/cm
3之整體密度,
- 少於1.5%之水溶度(在25℃下在水中的10%之懸浮液),
- 少於40 mPas之黏度(Brookfield DV3T,速度50rpm,轉軸1),
- 以雷射繞射所測量的1至50µm之粒度d
50,
- 以雷射繞射所測量的10至60µm之粒度d
90,及
- 4至8之pH (在25℃下在水中的10%之懸浮液)。
在根據本發明之組成物中,較佳的是聚磷酸銨業經以有機官能性(聚)矽烷、(聚)矽氧烷、(聚)矽氮烷、改質蠟、聚胺甲酸酯、聚環氧化物、脲甲醛樹脂、三聚氰胺-甲醛樹脂、基於(甲基)丙烯酸酯樹脂之乳液、基於苯乙烯/丙烯酸酯共聚物之乳液、胺甲酸酯、基於乙烯/乙酸壬酯之乳液、基於橡膠之乳液及/或彼之混合物微封裝。
優先選擇為亦含有以組分(A)及(B)的量為基礎計達至10重量%之下列組分的組成物:
硫酸銨、硫酸三乙基銨、硫酸四甲基銨、硫酸三甲基銨、二甲基硫酸鹽、二乙基硫酸鹽、二丙基硫酸鹽、辛基硫酸鈉、癸基硫酸鈉、十八烷基硫酸鈉、月桂基硫酸鹽、硫酸脲(urea sulfate)、硫酸三聚氰胺、硫酸羥胺、硫酸肼(hydrazine sulfate)、硫酸鉀、硫酸氫鉀、硫酸鈉、硫酸氫鈉、硫酸鎂、硫酸氫鎂、硫酸鈣、硫酸氫鈣、硫酸鋇、硫酸鋁鉀、硫酸鋁、硫酸鐵(III)、硫酸鐵(II)、硫酸鈷、硫酸鈦、硫酸鋅、硫酸錫、硫酸鈰、硫酸鋰、甲基硫酸三甲基鋶或彼之混合物。
本發明亦關於根據請求項1至10中至少一項之組成物之用途,其係用於降低膨脹型塗料之起始反應溫度、用於增加膨脹型塗料之耐火能力、作為透明塗料和膨脹型塗料之阻燃劑、用於木材和其他纖維素產品之阻燃劑中或作為阻燃劑、用於聚合物、凝膠塗料及/或不飽和聚酯樹脂之反應性及/或不反應性阻燃劑中或作為其反應性及/或不反應性阻燃劑、用於生產阻燃聚合物模製化合物、用於生產阻燃聚合物模製物、用於使聚酯及純和混紡纖維素織物成為阻燃性、用於聚胺甲酸酯發泡體中、用於聚烯烴中、用於不飽和聚酯和酚樹脂中、及用於使紡織品成為阻燃性。
本發明同樣地關於根據請求項1至10中至少一項之組成物之用途,其係用在或用於插頭連接器、配電器中的載流組件(殘餘電流保護)、電路板、灌封化合物、電力連接器、斷路器、燈殼、LED燈殼、電容器箱、線圈元件、通風器、接地觸頭、插頭、印刷電路板內/上、插頭之外殼、電池外殼、電纜、撓性電路板、充電電纜、電動機蓋、紡織品塗料及其他產品。
本發明特別關於根據請求項1至10中至少一項之組成物之用途,其係用於鋼材、木材、木質材料、紙、礦物綿、石膏板、塑料、金屬、合金、由合成或天然纖維製成的織物和其他材料上,及/或用作為防焊罩(solder mask)及用於電氣開關和電路之耐火塗料。
特別優先選擇使用根據請求項1至10中至少一項之組成物塗佈鋼材結構(諸如鋼樑和鋼支架)、屋頂、牆壁、電纜、管道、導管、電纜和組合式艙壁、門、窗簾、防煙垂壁、百葉窗、安全櫃、安裝櫃及其他物件。
本發明亦關於包含膜成形黏合劑、發泡劑、作為泡沫成形物質(foam-forming substance)的根據請求項1至10中一或多項之組成物、碳成形物質(carbon-forming substance)、輔助劑和添加劑、及視需要的增稠劑、分散添加劑和溶劑及/或溶劑混合物之耐火塗料。
此等耐火塗料較佳地包含膜成形黏合劑、發泡劑、作為泡沫成形物質的根據請求項1至10中一或多項之組成物、作為碳成形物質的至少一種多元醇、輔助劑及/或添加劑、增稠劑、分散添加劑和溶劑及/或溶劑混合物。
在此特別優先選擇為包含下列之耐火塗料:
5重量%至69.4重量%之膜成形黏合劑,
5重量%至25重量%之發泡劑,
5重量%至40重量%之作為泡沫成形物質的根據請求項1至10中一或多項之組成物,
5重量%至25重量%之碳成形物質,
5重量%至40重量%之輔助劑及/或添加劑,
0.5重量%至10重量%之增稠劑,
0.1重量%至10重量%之潤濕及/或分散添加劑,及
10重量%至40重量%之溶劑及/或溶劑混合物,其中該等組分加總至100重量%。
膜成形黏合劑較佳地包含基於苯乙烯與丙烯酸酯之共聚物、基於丙烯酸酯之共聚物、乙烯基甲苯/丙烯酸酯共聚物、苯乙烯/丙烯酸酯聚合物、基於乙酸乙烯酯之均聚物、基於乙酸乙烯酯、乙烯與氯乙烯之共聚物、基於乙酸乙烯酯與長支鏈羧酸的乙烯酯之共聚物、基於乙酸乙烯酯與順丁烯二酸二正丁酯及/或丙烯酸酯之共聚物、乙烯基/丙烯酸酯共聚物、自交聯聚胺甲酸酯分散物、萜烯及/或聚萜烯及/或彼之混合物;
發泡劑為三聚氰胺、三聚氰胺-甲醛縮合物、胍、其鹽類、三聚氰胺縮合產物及/或二氰二胺;
碳成形物質為澱粉、改質澱粉、多元醇(polyhydric alcohol或polyol),諸如醣和多醣、及/或熱塑性或熱固性聚合物樹脂黏合劑,諸如酚樹脂、脲樹脂、聚胺甲酸酯、聚氯乙烯、聚(甲基)丙烯酸酯、聚乙酸乙烯酯、聚乙烯醇、聚矽氧樹脂及/或橡膠;
輔助劑和添加劑為玻璃纖維、礦物纖維、金屬纖維、碳纖維、高嶺土、滑石、氧化鋁、氫氧化鋁、氫氧化鎂和其他金屬氧化物、沉澱矽石、矽酸鹽及/或粉狀纖維素;
增稠劑及/或流變添加劑為(改質)纖維素、矽石、膨土、蓖麻油衍生物、脂肪衍生物、聚醯胺、聚(甲基)丙烯酸酯、聚丙烯醯胺、聚醚、聚胺甲酸酯、聚乙烯醇、聚乙烯基吡咯啶酮、糖聚合物,諸如阿拉伯膠、海藻酸鹽、三仙膠及/或瓊脂;
潤濕和分散添加劑為烷基酚乙氧化物、聚丙烯酸及/或聚胺甲酸酯;
有機溶劑及/或溶劑混合物為芳族烴,較佳為二甲苯及/或烷基苯,較佳為甲苯和乙苯;醇,較佳為甲醇,及/或烷醇,較佳為2-甲基-1-丙醇;酮,諸如丙酮或丁酮;烷酸酯,及/或聚醚,較佳為聚乙二醇醚。
多元醇較佳為三新戊四醇、及/或新戊四醇之聚縮物、及/或新戊四醇系酯與多元醇、聚乙酸乙烯酯、聚乙烯醇、山梨醇及/或環氧乙烷-環氧丙烷多元醇之混合物。
本發明亦關於生產根據請求項1至10中一或多項之混合物之方法,其特徵在於將分別呈粉末形式或成為顆粒之組分(A)及組分(B)相互混合或將溶解之組分(B)引入組分(A)中。
用於生產根據本發明之混合物之其他方法的特徵在於將等莫耳量的正磷酸二氫銨及脲經0.5至4小時的時間加熱至250至300℃之溫度。
用於生產根據本發明之混合物之另一方法的特徵在於將等莫耳量的正磷酸銨及脲在濕氨氛圍下經0.1至4小時的時間加熱至250至305℃之溫度。
用於生產根據本發明之混合物之替代方法的特徵在於將等莫耳量的正磷酸銨及脲在濕氨氛圍下經0.1至4小時的時間加熱至320至350℃之溫度,同時添加組分(B)。
聚磷酸銨之較佳的使用領域為膨脹型調配物,接著於後來適合作為通用的耐火塗料。
亦稱為形成絕緣層之耐火塗料的膨脹型塗料的特性在於彼等在火災事件中於相應的熱作用下發泡且此發泡之耐火塗料阻礙或至少防止熱通向基材,諸如鋼材結構、屋頂、牆壁、電纜、管道及類似者。
自本發明之塗料所形成的絕緣層已具有優異的強度及熱絕緣性質,且與習知的塗料調配物相比而具有更早起始反應的特性。因此,根據本發明所述之膨脹型塗料組成物適合於有效保護鋼材結構和其他物質及熱敏感性基材。
例如,鋼材架構建築具有許多超越習知施工方法的優點,但主要缺點在於未受保護的鋼材溫度在火災事件中迅速升高至鋼材軟化、失去剛度且因此危及結構穩定性的此種程度(倒塌的風險,阻礙自建築物離去等)。因此,建議使鋼材熱絕緣。例如,可將膨脹型塗料施加於各種結構,以便延遲火災的熱效應。此塗料減慢施加塗料之個別基材的溫度升高速率且因此延長由於來自火的熱量而使結構倒塌前的時間。額外的時間增加滅火及冷卻建築物的機會,且延長可用於逃生的時間。
視需要地有可能添加一或多種反應性阻燃劑至根據本發明之組成物中。在本發明之上下文中,一個實例為反應性有機磷化合物,諸如9,10-二氫-9-氧雜-10-磷雜菲10-氧化物(DOPO)及其衍生物和加成物。
本發明之組成物可較佳地另外包含亞膦酸鹽(phosphinic salt)(EP-A-1544206)。
與不含亞膦酸鹽之調配物相比,使用前述亞膦酸鹽或二亞膦酸鹽使膨脹反應的起始溫度降低超過15℃。
有機溶劑較佳為芳族烴,較佳為二甲苯、及/或烷基苯,較佳為乙苯;醇,較佳為甲醇、及/或烷醇,更佳為2-甲基-1-丙醇;聚醚,較佳為聚乙二醇醚,更佳為α-異十三烷基-ω-羥基-聚乙二醇醚。
可將額外的添加劑(諸如增稠劑及/或流變添加劑)及填充劑添加至組成物中。所使用的流變添加劑(諸如抗沈降劑、抗流動劑和觸變劑)較佳為聚羥基甲醯胺、脲衍生物、不飽和羧酸酯之鹽類、酸性磷酸衍生物之烷基銨鹽類、對甲苯磺酸之胺鹽類、磺酸衍生物之胺鹽類和化合物之水溶液或有機溶液或混合物。另外,有可能使用基於發煙矽石或沉澱矽石或基於矽烷化發煙矽石或沉澱矽石之流變添加劑。流變添加劑較佳地包含發煙矽石、改質和未改質之片狀矽酸鹽、沉澱矽石、纖維素醚、多醣、聚胺甲酸酯和丙烯酸酯增稠劑、脲衍生物、蓖麻油衍生物、聚醯胺、脂肪酸醯胺及聚烯烴,先決條件為彼等係呈固體形式的粉碎纖維素及/或懸浮介質,例如三仙膠。
此等耐火塗料(膨脹型塗料)主要以可塗漆、可塗抹或可滾塗的形式使用以保護各種廣泛的不同基材,較佳為鋼樑和鋼柱、屋頂、牆壁、電纜、管道、電纜槽、電纜和組合式艙壁、門、窗簾、煙簾、百葉窗、安全櫃、安裝櫃及類似者。
本發明尤其關於根據本發明之耐火塗料在鋼材、木材、木質材料、紙、礦物綿、石膏板、塑料、金屬、合金、由合成或天然纖維製成的織物和其他適合的材料上,及/或作為防焊罩及用於電氣開關和電路之用途。根據本發明之耐火塗料對中空型材及H型材之結構防火及工作間應用具有非常良好的適合性;其同樣適合於需要提高耐候穩定性的區域。
根據本發明之混合物對前述於膨脹型調配物中的用途及接著於後來用作為耐火塗料具有優異的適合性。
根據本發明之混合物較佳地亦可用於或用作為基於聚烯烴之膨脹型塗料。
較佳的聚烯烴為例如單烯烴和二烯烴(例如乙烯、丙烯、異丁烯、丁烯、4-甲基戊烯、異戊二烯、丁二烯、苯乙烯)之聚合物,例如聚丙烯、聚異丁烯、聚丁-1-烯、聚-4-甲基戊-1-烯、聚苯乙烯、聚(對甲基苯乙烯)及/或聚(α-甲基苯乙烯)、聚異戊二烯或聚丁二烯及聚乙烯(視需要地交聯),例如高密度聚乙烯(HDPE)、高密度高分子量聚乙烯(HDPE-HMW)、高密度超高分子量聚乙烯(HDPE-UHMW)、中密度聚乙烯(HMDPE)、低密度聚乙烯(LDPE)、直鏈低密度聚乙烯(LLDPE)、非常低密度聚乙烯(VLDPE)、支鏈低密度聚乙烯(BLDPE),且亦為環烯烴(例如環戊烯或降莰烯)之聚合物。
較佳的聚合物另外為上文列出的聚烯烴之混合物(摻合物),例如聚丙烯(PP)與聚異丁烯、聚乙烯與聚異丁烯、聚丙烯與聚乙烯(例如PP/HDPE/LDPE)及各種類型的聚乙烯(例如LDPE/HDPE)之混合物。
優先選擇使用的聚合物另外為單烯烴和二烯烴彼此之共聚物及單烯烴和二烯烴與其他乙烯基單體之共聚物,例如乙烯-丙烯共聚物;LLDPE、VLDPE及彼等與LDPE之混合物;丙烯-丁-1-烯共聚物、丙烯-異丁烯共聚物、乙烯-丁-1-烯共聚物、乙烯-己烯共聚物、乙烯-甲基戊烯共聚物、乙烯-庚烯共聚物、乙烯-辛烯共聚物、丙烯-丁二烯共聚物、異丁烯-異戊二烯共聚物、乙烯-丙烯酸烷酯共聚物、乙烯-甲基丙烯酸烷酯共聚物、乙烯-乙酸乙烯酯共聚物、苯乙烯或α-甲基苯乙烯與二烯或丙烯酸衍生物之共聚物,例如苯乙烯-丁二烯、苯乙烯-丙烯腈、苯乙烯-甲基丙烯酸烷酯、苯乙烯-丁二烯-丙烯酸烷酯和甲基丙烯酸烷酯、苯乙烯-順丁烯二酸酐、苯乙烯-丙烯腈-丙烯酸甲酯;苯乙烯共聚物與另一聚合物(例如聚丙烯酸酯、二烯聚合物或乙烯-丙烯-二烯三元共聚物)之高耐衝擊性混合物;及苯乙烯之嵌段共聚物,例如苯乙烯-丁二烯-苯乙烯、苯乙烯-異戊二烯-苯乙烯、苯乙烯-乙烯/丁烯-苯乙烯或苯乙烯-乙烯/丙烯-苯乙烯,且亦為苯乙烯或α-甲基苯乙烯之接枝共聚物,例如苯乙烯接枝在聚丁二烯上、苯乙烯接枝在聚丁二烯-苯乙烯-或聚丁二烯-丙烯腈共聚物上、苯乙烯和丙烯腈(或甲基丙烯腈)接枝在聚丁二烯上;苯乙烯、丙烯腈和甲基丙烯酸甲酯接枝在聚丁二烯上;苯乙烯和順丁烯二酸酐接枝在聚丁二烯上;苯乙烯、丙烯腈和順丁烯二酸酐或順丁烯二醯亞胺接枝在聚丁二烯上;苯乙烯和順丁烯二醯亞胺接枝在聚丁二烯上、苯乙烯和丙烯酸烷酯或甲基丙烯酸烷酯接枝在聚丁二烯上、苯乙烯和丙烯腈接枝在乙烯-丙烯-二烯三元共聚物上、苯乙烯和丙烯腈接枝在聚丙烯酸烷酯或聚甲基丙烯酸烷酯上、苯乙烯和丙烯腈接枝在丙烯酸酯-丁二烯共聚物上、及彼之混合物,如已知例如凡稱為ABS、MBS、ASA或AES聚合物;且亦為彼等與一氧化碳之共聚物或乙烯-丙烯酸共聚物及其鹽類(離子聚合物),且亦為乙烯與丙烯及二烯(例如己二烯、環戊二烯或亞乙基降莰烯)之三元共聚物;及此等共聚物彼此及/或與其他聚合物之混合物,例如聚丙烯-乙烯-丙烯共聚物、LDPE-乙烯-乙酸乙烯酯共聚物、LDPE-乙烯-丙烯酸共聚物、LLDPE-乙烯-乙酸乙烯酯共聚物、LLDPE-乙烯-丙烯酸共聚物、及交替或無規聚烯-一氧化碳共聚物、及彼等與其他聚合物(例如聚醯胺)之混合物。
根據本發明之混合物亦可用於熱塑性聚合物(諸如聚酯、聚苯乙烯或聚醯胺)及熱固性聚合物(諸如不飽和聚酯樹脂、環氧樹脂、聚胺甲酸酯或丙烯酸酯)。
適合的聚酯衍生自二羧酸和其酯及二醇及/或衍生自羥基羧酸或對應的內酯。特別優先選擇使用對苯二甲酸及乙二醇、丙-1,3-二醇和丁-1,3-二醇。
適合的聚酯包括聚對苯二甲酸乙二酯、聚對苯二甲酸丁二酯(來自Celanese之Celanex
®2500、Celanex
®2002;來自BASF之Ultradur
®)、聚-1,4-二羥甲基環己烷對苯二甲酸酯、對羥基苯甲酸酯和衍生自具有末端羥基之聚醚的嵌段聚醚酯;且亦包括以聚碳酸酯或MBS改質之聚酯。
聚合物較佳為單烯烴和二烯烴之聚合物,例如聚丙烯、聚異丁烯、聚丁烯-1、聚-4-甲基戊烯-1、聚異戊二烯或聚丁二烯,及環烯烴(例如環戊烯或降莰烯)之加成聚合物;且亦為聚乙烯(其可視需要地交聯),例如高密度聚乙烯(HDPE)、高密度、高分子量聚乙烯(HDPE-HMW)、高密度、超高分子量聚乙烯(HDPE-UHMW)、中密度聚乙烯(MDPE)、低密度聚乙烯(LDPE)、直鏈低密度聚乙烯(LLDPE)、支鏈低密度聚乙烯(BLDPE)及彼之混合物。
聚合物較佳為單烯烴和二烯烴彼此或與其他乙烯基單體之共聚物,例如乙烯-丙烯共聚物、直鏈低密度聚乙烯(LLDPE)及彼等與低密度聚乙烯(LDPE)之混合物、丙烯-丁烯-1共聚物、丙烯-異丁烯共聚物、乙烯-丁烯-1共聚物、乙烯-己烯共聚物、乙烯-甲基戊烯共聚物、乙烯-庚烯共聚物、乙烯-辛烯共聚物、丙烯-丁二烯共聚物、異丁烯-異戊二烯共聚物、乙烯-丙烯酸烷酯共聚物、乙烯-甲基丙烯酸烷酯共聚物、乙烯-乙酸乙烯酯共聚物及彼等與一氧化碳之共聚物或乙烯-丙烯酸共聚物其鹽類(離子聚合物),且亦為乙烯與丙烯及二烯(例如己二烯、環戊二烯或亞乙基降莰烯)之三元共聚物;且亦為此等共聚物彼此之混合物,例如聚丙烯/乙烯-丙烯共聚物、LDPE/乙烯-乙酸乙烯酯共聚物、LDPE/乙烯-丙烯酸共聚物、LLDPE/乙烯-乙酸乙烯酯共聚物、LLDPE/乙烯-丙烯酸共聚物、及交替或無規聚烯/一氧化碳共聚物、及彼等與其他聚合物(例如聚醯胺)之混合物。
聚合物較佳為烴樹脂(例如C
5-C
9)(包括其氫化改質物(例如膠黏劑樹脂))及聚烯與澱粉之混合物。
聚合物較佳為聚苯乙烯(Polystyrol® 143E (BASF))、聚(對甲基苯乙烯)、聚(α-甲基苯乙烯)。
聚合物較佳為苯乙烯或α-甲基苯乙烯與二烯或丙烯酸衍生物之共聚物,例如苯乙烯-丁二烯、苯乙烯-丙烯腈、苯乙烯-甲基丙烯酸烷酯、苯乙烯-丁二烯-丙烯酸烷酯和甲基丙烯酸烷酯、苯乙烯-順丁烯二酸酐、苯乙烯-丙烯腈-甲基丙烯酸酯;苯乙烯共聚物與另一聚合物(例如聚丙烯酸酯、二烯聚合物或乙烯-丙烯-二烯三元共聚物)之高耐衝擊性混合物;及苯乙烯之嵌段共聚物,例如苯乙烯-丁二烯-苯乙烯、苯乙烯-異戊二烯-苯乙烯、苯乙烯-乙烯/丁烯-苯乙烯或苯乙烯-乙烯/丙烯-苯乙烯。
聚合物較佳為苯乙烯或α-甲基苯乙烯之接枝共聚物,例如苯乙烯接枝在聚丁二烯上、苯乙烯接枝在聚丁二烯-苯乙烯或聚丁二烯-丙烯腈共聚物上、苯乙烯和丙烯腈(或甲基丙烯腈)接枝在聚丁二烯上;苯乙烯、丙烯腈和甲基丙烯酸甲酯接枝在聚丁二烯上;苯乙烯和順丁烯二酸酐接枝在聚丁二烯上;苯乙烯、丙烯腈和順丁烯二酸酐或順丁烯二醯亞胺接枝在聚丁二烯上;苯乙烯和順丁烯二醯亞胺接枝在聚丁二烯上、苯乙烯和丙烯酸烷酯/甲基丙烯酸烷酯接枝在聚丁二烯上、苯乙烯和丙烯腈接枝在乙烯-丙烯-二烯三元共聚物上、苯乙烯和丙烯腈接枝在聚丙烯酸烷酯或聚甲基丙烯酸烷酯上、苯乙烯和丙烯腈接枝在丙烯酸酯-丁二烯共聚物上、及彼之混合物,諸如已知為例如ABS、MBS、ASA或AES聚合物。
苯乙烯聚合物較佳為比較粗孔的發泡體,諸如EPS (擴展型聚苯乙烯),例如Styropor
®(BASF)及/或具有相對細孔的發泡體,諸如XPS (擠壓型硬質聚苯乙烯發泡體),例如Styrodur
®(BASF)。優先選擇為聚苯乙烯發泡體(例如Austrotherm
®XPS、Styrofoam
®(Dow Chemical))及類似者。
聚合物較佳為鹵化聚合物,例如聚氯平、氯橡膠、異丁烯-異戊二烯之氯化和溴化共聚物(鹵丁基橡膠)、氯化或氯磺酸化聚乙烯、乙烯與氯化乙烯之共聚物、表氯醇均聚物和共聚物,尤其為鹵化乙烯基化合物之聚合物,例如聚氯乙烯、聚偏二氯乙烯、聚氟乙烯、聚偏二氟乙烯;及其共聚物,諸如氯乙烯-偏二氯乙烯、氯乙烯-乙酸乙烯酯或偏二氯乙烯-乙酸乙烯酯。
聚合物較佳為衍生自α,β-不飽和酸及其衍生物之聚合物,諸如聚丙烯酸酯和聚甲基丙烯酸酯、經丙烯酸丁酯耐衝擊改質之聚甲基丙烯酸甲酯、聚丙烯醯胺和聚丙烯腈、及所提及之單體彼此或與其他不飽和單體之共聚物,例如丙烯腈-丁二烯共聚物、丙烯腈-丙烯酸烷酯共聚物、丙烯腈-丙烯酸烷氧基烷酯共聚物、丙烯腈-鹵乙烯共聚物或丙烯腈-甲基丙烯酸烷酯-丁二烯三元共聚物。
聚合物較佳為衍生自不飽和醇及胺或自其醯基衍生物或縮醛之聚合物,諸如聚乙烯醇、聚乙酸乙烯酯、聚硬脂酸乙烯酯、聚苯甲酸乙烯酯或聚順丁烯二酸乙烯酯、聚乙烯丁醛、聚苯二甲酸烯丙酯、聚烯丙基三聚氰胺;及彼等與烯烴之共聚物。
聚合物較佳為環醚之均聚物和共聚物,諸如聚烷二醇、聚環氧乙烷、聚環氧丙烷或彼等與雙環氧丙基醚之共聚物。
聚合物較佳為聚縮醛,諸如聚甲醛和那些包含共單體(例如環氧乙烷)之聚甲醛;經熱塑性聚胺甲酸酯、丙烯酸酯或MBS改質之聚縮醛。
聚合物較佳為聚伸苯醚和聚伸苯硫、及彼等與苯乙烯聚合物或聚醯胺之混合物。
聚合物較佳為衍生自具有兩個末端羥基的聚醚、聚酯和聚丁二烯之聚胺甲酸酯、及脂族或芳族聚異氰酸酯及其前驅物。
聚合物較佳為衍生自二胺和二羧酸及/或自胺基羧酸或對應的內醯胺之聚醯胺及共聚醯胺,諸如耐綸2/12、耐綸4、耐綸4/6、耐綸6、耐綸6/6、耐綸6/9、耐綸6/10、耐綸6/12、耐綸6/66、耐綸7、耐綸7,7、耐綸8、耐綸8,8、耐綸9、耐綸9,9、耐綸10、耐綸10,9、耐綸10,10、耐綸11、耐綸12、基於間-二甲苯、二胺和己二酸之芳族聚醯胺;自六亞甲基二胺及間及/或對苯二甲酸製備之聚醯胺(聚六亞甲基間苯二甲醯胺、聚六亞甲基對苯二甲醯胺)、及視需要作為改質劑之彈性體,例如聚-2,4,4-三甲基六亞甲基對苯二甲醯胺或聚間伸苯基間苯二甲醯胺。前述聚醯胺與聚烯烴、烯烴共聚物、離子聚合物或經化學鍵結或接枝之彈性體之嵌段共聚物;或與聚醚(例如與聚乙二醇、聚丙二醇或聚伸丁二醇)之嵌段共聚物。另外,經EPDM或ABS改質之聚醯胺或共聚醯胺;及在加工期間縮合之聚醯胺(「RIM聚醯胺系統」)。
聚合物較佳為聚脲、聚醯亞胺、聚醯胺醯亞胺、聚醚醯亞胺、聚酯醯亞胺、聚乙內醯脲和聚苯并咪唑。
聚合物較佳為衍生自二羧酸及二醇及/或自羥基羧酸或對應的內酯之聚酯,諸如聚對苯二甲酸乙二酯、聚對苯二甲酸丁二酯、聚-1,4-二羥甲基環己烷對苯二甲酸酯、對羥基苯甲酸酯和衍生自具有末端羥基的聚醚之嵌段聚醚酯;此外為經聚碳酸酯或MBS改質之聚酯。
聚合物較佳為聚碳酸酯及聚酯碳酸酯。
聚合物較佳為聚碸、聚醚碸和聚醚酮。
聚合物較佳為一方面衍生自醛及另一方面衍生自酚、脲或三聚氰胺的經交聯之聚合物,諸如酚-甲醛、脲-甲醛和三聚氰胺-甲醛樹脂。
聚合物較佳為乾燥和非乾燥醇酸樹脂。
聚合物較佳為不飽和聚酯樹脂,其係衍生自飽和和不飽和二羧酸與多元醇及作為交聯劑的乙烯基化合物之共聚酯,且亦為其鹵化阻燃性改質物。
聚合物較佳為可交聯的丙烯酸系樹脂,其係衍生自經取代之丙烯酸酯,例如衍生自環氧基丙烯酸酯、胺甲酸酯丙烯酸酯或聚酯丙烯酸酯。
聚合物較佳為已與三聚氰胺樹脂、脲樹脂、異氰酸酯、異氰尿酸酯(isocyanurate)、聚異氰酸酯或環氧樹脂交聯之醇酸樹脂、聚酯樹脂和丙烯酸酯樹脂。
聚合物較佳為經交聯之環氧樹脂,其係衍生自脂族、環脂族、雜環或芳族環氧丙基化合物,例如雙酚A二環氧丙基醚、雙酚F二環氧丙基醚之產物,其係利用慣例的硬化劑(例如酸酐或胺)與或未與催速劑交聯。
聚合物較佳為前述聚合物之混合物(聚摻合物),例如PP/EPDM (聚丙烯/乙烯-丙烯-二烯橡膠)、聚醯胺/EPDM或ABS (聚醯胺/乙烯-丙烯-二烯橡膠或丙烯腈-丁二烯-苯乙烯)、PVC/EVA (聚氯乙烯/乙烯-乙酸乙烯酯)、PVC/ABS (聚氯乙烯/丙烯腈-丁二烯-苯乙烯)、PVC/MBS (聚氯乙烯/甲基丙烯酸酯-丁二烯-苯乙烯)、PC/ABS (聚碳酸酯/丙烯腈-丁二烯-苯乙烯)、PBTP/ABS (聚對苯二甲酸丁二酯/丙烯腈-丁二烯-苯乙烯)、PC/ASA (聚碳酸酯/丙烯酸酯-苯乙烯-丙烯腈)、PC/PBT (聚碳酸酯/聚對苯二甲酸丁二酯)、PVC/CPE (聚氯乙烯/氯化聚乙烯)、PVC/丙烯酸酯(聚氯乙烯/丙烯酸酯)、POM/熱塑性PUR (聚甲醛/熱塑性聚胺甲酸酯)、PC/熱塑性PUR (聚碳酸酯/熱塑性聚胺甲酸酯)、POM/丙烯酸酯(聚甲醛/丙烯酸酯)、POM/MBS (聚甲醛/甲基丙烯酸酯-丁二烯-苯乙烯)、PPO/HIPS (聚伸苯醚/高衝擊性聚苯乙烯)、PPO/PA 6,6 (聚伸苯醚/耐綸6,6)和共聚物、PA/HDPE (聚醯胺/高密度聚乙烯)、PA/PP (聚醯胺/聚乙烯)、PA/PPO (聚醯胺/聚伸苯醚)、PBT/PC/ABS (聚對苯二甲酸丁二酯/聚碳酸酯/丙烯腈-丁二烯-苯乙烯)及/或PBT/PET/PC (聚對苯二甲酸丁二酯/聚對苯二甲酸乙二酯/聚碳酸酯)。
根據本發明之混合物亦可對應地用於紡織品中或紡織品上而不損害其性質。
根據本發明之混合物可以隨機分布或以特定圖案(例如以點圖案)應用於柔性材料,尤其為紡織品材料。此等紡織品係用於例如旅館、劇院和會議中心的內部裝修,及運輸模式中(公共汽車、火車、汽車、飛機等)。
根據本發明之混合物可與如以例如“Flammschutzmittel”於第9版(1996) Römpps Chemie-Lexikon,第1369至1371頁中所述之其他阻燃劑一起使用。
總體而言,單獨或與其他物質一起作用的根據本發明之混合物可具有促進碳化、窒息滅火、形成阻擋層、形成絕緣層或一些其他種類的作用。
關於在聚合物(尤其為聚烯烴)中或基於聚合物(尤其為聚烯烴)及在形成絕緣層之膨脹型塗料和紡織品中或用於形成絕緣層之膨脹型塗料和紡織品的所有前述應用,有可能添加其他的添加劑,尤其為抗氧化劑、抗靜電劑、發泡劑、其他阻燃劑、熱穩定劑、耐衝擊改質劑、加工輔助劑、潤滑劑、光穩定劑、抗滴落劑、增容劑、強化劑、填充劑、成核劑、用於雷射標記之添加劑、水解穩定劑、鏈伸長劑、顏料及/或增塑劑。
接著於後來作為防火塗料應用之膨脹型調配物係如下方式生產:
a) 先於室溫下裝入溶劑或溶劑混合物且將個別樹脂在攪拌的同時溶解於其中,接著在攪拌的同時添加塗料添加劑,諸如分散添加劑及視需要的消泡劑,
b) 在低速下攪拌的同時噴灑膜成形物質、發泡劑及碳成形物質,以及輔助劑和添加劑(例如二氧化鈦、纖維和填充劑),
c) 以攪拌噴灑觸變劑,
d) 以高剪切力分散至少25分鐘,同時維持50℃至60℃之溫度,
e) 經至少5分鐘均勻分散且藉由添加溶劑或溶劑混合物建立所欲黏度。
該等調配物可用於例如根據本發明用以形成絕緣層之耐火塗料的生產方法中。在此例子中,將聚矽氧樹脂乳液(黏合劑)與在火災事件中形成泡沫之劑及視需要的其他輔助劑和添加劑在高剪切溶解器中混合且調整至所欲稠度。
本發明之塗料組成物可直接施加至欲塗佈之表面上或經由底漆塗層施加。塗料組成物通常係在介於-10與60℃之間的溫度下以液體形式施加。施加可例如藉由無氣噴塗、澆注(於模具中使用)、塗刷或刮塗來達成。
本發明之塗料組成物可施加至各種基材。在此優先選擇為鋼和鋁基材及複合材料,例如玻璃纖維強化塑料。
本發明係於隨後的非限制性實施例中闡述。
首先,聚磷酸銨混合物係藉由將可見於表1的結晶相II聚磷酸銨的量與結晶相I聚磷酸銨的個別量在轉筒式混合器(來自Heidolph)中以每分鐘320轉(rpm)混合5 h而產出。
純結晶相II聚磷酸銨係用於實施例1中。
純結晶相I聚磷酸銨係用於實施例11中。
因此獲得的混合物顯示在表1中重現的性質。
上述值係如下方式測定:
黏度
為了測定黏度,在25℃下於水中製備來自實施例1至11之個別產物的10重量%之懸浮液且攪拌。黏度係利用Brookfield黏度計根據DIN ISO 2555 (轉軸61,100 rpm)測定。
電導率
為了測定pH,在25℃下於水中製備來自實施例1至11之個別產物的10重量%之懸浮液且攪拌5分鐘。電導率係以電位測定法(來自Knick之703型電導計)測定。
pH
為了測定pH,在25℃下於水中製備來自實施例1至11之個別產物的10重量%之懸浮液且攪拌5分鐘。pH係利用電位測定法(Metrohm,LL Aquatrode Plus WOC)測定。
酸值
為了測定酸值,在25℃下於水中製備來自實施例1至11之個別產物的10重量%之懸浮液且攪拌5分鐘。酸值係根據ISO 2114測定。
水溶度
在25℃下於水中製備聚磷酸銨或其混合物的10重量%之懸浮液且攪拌及過濾。以所使用的量(10%之懸浮液)為基礎的過濾物之乾燥殘餘物相當於此聚磷酸銨之水溶度。
質量損失
質量損失可以多種方式表示:
1) 達到2%之質量損失的溫度(℃)
2) 在300℃下以%計的質量損失
質量損失係在氮氛圍下利用來自Sartorius之MA35M-230N儀器以熱重量法測定。
阻燃劑混合物之整體密度係根據EN ISO;DIN 53468在25℃下測定。
粒度d
50係藉助於Malvern Mastersizer測定。
自表1中的實施例1至11可看出其中產物的一些性質受到結晶相I聚磷酸銨添加至結晶相II聚磷酸銨的不利影響。例如,升高至超過3%之溶解度及顯著增加的電導率。當混合物中的結晶相I聚磷酸銨含量增加時,升高至超過5 mg KOH/g之酸值及降低的熱穩定性成為進一步的缺點。
當對應的塗料用於暴露於風化或其他外部影響的區域時,水分的效應可導致聚磷酸銨的浸析,其不可再用於膨脹反應。預期這導致膨脹作用降低。出於此原因,保持低的APP溶解度才有成效。
與短鏈(聚)磷酸銨之溶解度相關聯的上升之溶液中的鹽濃度尤其可以測定電導率來例證。
另外,高鹽負荷在具有水性黏合劑之膨脹型系統的儲存期間可通過破壞分散液穩定性而導致不希望縮短的儲存穩定性,其以不可逆增加的黏度體現。
例如,在實施例1、4和6併入WO2017153227A1所述之膨脹型調配物中的情況下,觀察到良好的相容性。
與使用純結晶相II APP (實施例1)相比,在實施例4和6的情況下,無法在24小時後於最終產物中檢測出任何增加的黏度。無法觀察到業經結晶相混合物生產之膨脹型塗料(實施例4和6)之任何增加的耐火時間(2000µm之乾層厚度)。泡沫特徵另外顯示輕微的不均勻性及降低的穩定性。尤其在施加層厚度相對較厚的的情況下,這可導致泡沫在火災測試期間脫落。
相反地,若本發明混合物係用於溶劑系膨脹型塗料中,則觀察到明顯升高的絕緣作用。
使用來自實施例1至11的產物生產實施例12和13之溶液系膨脹型調配物。
實施例12
使用來自實施例1的聚磷酸銨生產以下組成之膨脹型調配物:
來自實施例1的28重量份之聚磷酸銨,
10重量份之樹脂(Omnova,Pliolite
®Ultra 100),
8重量份之三聚氰胺(OCI,Melafine
®),
8重量份之新戊四醇(Perstorp,Charmor
®PT 40),
9重量份之二氧化鈦(Cristal,Tiona
®696),
6重量份之氯石蠟(Dover Chemicals,Hordaresin
®NP 70),
添加100重量份之增稠劑(Luvotix
®VP 031)、輔助劑和添加劑(丁基二甘醇乙酸酯(butyldiglycol acetate) (BDGA),Texanol
®)、分散添加劑、漆料添加劑、溶劑(Shellsol
®100/140,二甲苯)。
實施例13
程序係如實施例12,除了不使用來自實施例1的28重量份之聚磷酸銨,而使用來自實施例6的結晶相II聚磷酸銨(80重量%)與結晶相I聚磷酸銨(20重量%)的28重量份之混合物。
個別的膨脹型調配物係如以下方式生產:
a) 先於室溫下裝入溶劑且在攪拌的同時添加漆料添加劑(來自BYK之Disperbyk
®-2163)、分散助劑及視需要的消泡劑,
b) 在低速下攪拌的同時噴灑來自實施例1至11的個別混合物、發泡劑、碳來源、二氧化鈦、填充劑,隨後噴灑觸變劑,
c) 將混合物以高剪切力分散20至60分鐘,同時維持30℃至70℃之溫度,且接著在低剪切力下添加溶劑以確立所欲黏度。
將因此生產之膨脹型調配物作為膨脹型塗料施加至經塗佈之鋼板(根據標準EN 10025-2:2004之S235JR編號1.0122;尺寸:280 x 280 x 5mm),且以2000µm之乾膜厚度進行類似於DIN 4102第8部分,火災曲線ISO 834之火災試驗。圖1顯示板材反面的溫度隨時間而變動的進程。
在此發現驚訝的是在板材反面上到達T
臨界=500℃之溫度前的時間在使用來自實施例4之混合物的情況下係在109分鐘,其與來自實施例1之純物質相比的100分鐘而顯著地更長。這意指在根據本發明使用的情況下,鋼材之臨界軟化溫度僅會在較晚的時刻達到且因此保護作用更有效。鋼材結構的結構完整性可因此維持更長的時間。
這因此為9%之性能獲益。在反面達到僅300℃之溫度在實施例1的情況下需要32分鐘及在實施例4的情況下需要48分鐘;這意指防火時間增加50%。
如圖2中,若將實施例12和13之鋼材反面上的溫度之溫差隨時間繪製,則發現實施例13之絕緣效應在整個火災進程中都比較高。在約27 min的時間後觀察到45℃之最大溫差。
尤其以來自實施例12和13的本發明混合物,起始反應已在比實施例1低的溫度下發生,因此絕緣作用更早(更快)開始且根據本發明之膨脹型調配物塗佈之基材可更好地熱絕緣。當所述之系統用於建築鋼材結構時,這能成為存留更長及/或更有效的防火系統。由於較長的耐火時間,使建築物的居民在火災事件中可於更長的時間內離開且使消防員能夠在安全的環境中滅火。
根據本發明之膨脹型調配物係由於較早開始的絕緣作用而於今可用於使得迄今由於其低熔點而不能防熱之基材成為耐火性。例如,亦有可能保護甚至在低溫下(例如300℃)軟化或釋放可燃及/或有毒的熱解氣體之聚合物及其他基材。
根據本發明之膨脹型調配物的優點自另一個角度來看亦為顯而易見的:
例如,250℃之基材溫度在實施例1(比較)中僅於17分鐘後到達,而在本發明之實施例4中直到29分鐘。因此,根據本發明之膨脹型塗料在適當的溫度範圍內幾乎為純結晶相II聚磷酸銨的兩倍有效性。
因此,有可能在非金屬系基材(例如熱塑性物)的情況下更極其有效地防止火通過,該等基材時常具有300℃或更低的熔點或毀溫度。實際的實例在此為例如建築材料板,諸如屋頂板、隔牆等,或用於關鍵環境(電池外殼或加壓儲氫設施)之其他複合材料。
由於使用根據本發明之混合物,在較低溫度下較長的耐火時間有利地導致材料節省;同樣有可能應用較薄的層厚度達成相同的效應。
性能增加百分比在相對低溫範圍內的250℃下為71%。
不同的結晶相之聚磷酸銨的本發明混合物具有用於生產作用更快的膨脹型塗料之優異的適合性,其另外具有提高的材料效率。
將基於實施例1和4之實施例12和13的膨脹型塗料施加至由各種塑料所製成的板材料,且根據DIN 4102第8部分,火災曲線ISO 834以2000 µm之乾膜厚度進行火災試驗。
實施例14
施加至Ultramid
®A3K (BASF;根據ISO 11357之熔化溫度:260℃):以實施例12的膨脹型調配物僅在21分鐘後達到聚合物的260℃之臨界軟化溫度,但以來自實施例13的本發明之膨脹型調配物僅在35分鐘後達到該溫度。由此可見,當使用根據本發明之膨脹型調配物時,使耐火時間更長了67%。
實施例15
施加至Makrolon
®2205聚碳酸酯板(Covestro;根據ISO 11357之熔化溫度:300℃):
以實施例12的膨脹型調配物僅在37分鐘後達到聚合物的300℃之臨界軟化溫度,但以來自實施例13的本發明之膨脹型調配物僅在58分鐘後達到該溫度。由此可見,當使用根據本發明之膨脹型調配物時,使耐火時間更長了57%。
實施例16
施加至實驗室生產的經玻璃纖維填充之複合板(經DICY固化之雙酚A環氧樹脂):
以實施例12的膨脹型調配物僅在62分鐘後達到基材的320℃之臨界毀壞溫度,但以來自實施例13的本發明之膨脹型調配物僅在74分鐘後達到該溫度。由此可見,當使用根據本發明之膨脹型調配物時,使耐火時間更長了19%。
實施例17
施加至鋁板
以實施例12的膨脹型調配物僅在62分鐘後達到基材的320℃之臨界軟化溫度,但以來自實施例13的本發明之膨脹型調配物僅在74分鐘後達到該溫度。由此可見,當使用根據本發明之膨脹型調配物時,使耐火時間更長了19%。
來自本發明之實施例4的混合物亦用於生產使用以下樹脂(表3)之溶劑系膨脹型調配物:
實施例18:苯乙烯-丙烯酸酯共聚物-Pliolite
®Ultra 100 (Omnova/Synthomer)
實施例19:甲基丙烯酸酯共聚物-Dianal
®TB 080 (Evonik)
實施例20:甲基丙烯酸酯-Degalan
®LP 65/11 (Evonik)
實施例21:苯乙烯-丙烯酸酯共聚物-Pliolite
®AC 80 (Omnova/Synthomer)
實施例22:甲基丙烯酸酯-Viacryl
®SC 124 / 50WS (Allnex)
實施例23:甲基丙烯酸酯-Degalan
®LP 63/11 (Evonik)
1使用實施例7
表3說明根據本發明之阻燃劑混合物的可變性。儘管在一些情況下未觀察到FRT延伸達至500℃,但較早的啟動係以全面較早開始的起始反應體現。
而且,在所有的實驗中,維持關於表面黏附性、膨脹、均質性及孔徑之較佳的泡沫性質。
與來自實施例1的混合物相比,在此發現來自實施例4的本發明混合物在根據本發明之個別膨脹型調配物中導致在各情況下以更長的時間達到臨界溫度。
結晶相II聚磷酸銨與結晶相I聚磷酸銨的本發明混合物因此具有用於生產膨脹型調配物之優異的適合性。
[圖1]為顯示板材反面的溫度隨時間而變動的進程。
[圖2]為將實施例12和13之鋼材反面上的溫度之溫差隨時間繪製的圖。
Claims (18)
- 一種組成物,其包含, 0.1重量%至99.9重量%之結晶相II聚磷酸銨作為組分(A),及 0.1重量%至99.9重量%之結晶相I及/或結晶相III、IV、V及/或VI聚磷酸銨作為組分(B),其中該等組分的總和為100重量%。
- 如請求項1之組成物,其包含 60重量%至99.9重量%之組分A,及 0.1重量%至40重量%之組分B。
- 如請求項1或2之組成物,其包含 75重量%至92重量%之組分A,及8重量%至35重量%之組分B。
- 如請求項1至3中至少一項之組成物,其中組分A為結晶相II聚磷酸銨及組分B為結晶相I聚磷酸銨。
- 如請求項1至4中至少一項之組成物,其中組分A為具有式(NH 4) n+2P nO 3n+1,以n = 300至100 000之結晶相II聚磷酸銨。
- 如請求項1至5中至少一項之組成物,其中組分A為具有式(NH 4) n+2P nO 3n+1,以n = 1000至25 000之結晶相II聚磷酸銨。
- 如請求項1至6中至少一項之組成物,其中組分B為具有式(NH 4) n+2P nO 3n+1,以n = 5至100之結晶相I聚磷酸銨。
- 如請求項1至7中至少一項之組成物,其中該組成物具有: - 根據ISO 760的少於0.5%之殘留水分含量(水含量), - 0.3至0.9 g/cm 3之整體密度, - 少於1.5%之水溶度(在25℃下在水中的10%之懸浮液), - 少於40 mPas之黏度(Brookfield DV3T,速度50 rpm,轉軸1), - 以雷射繞射所測量的5至50 µm之粒度d 50, - 以雷射繞射所測量的10至60 µm之粒度d 90,及 - 4至8之pH (在25℃下在水中的10%之懸浮液)。
- 如請求項1至8中至少一項之組成物,其中該聚磷酸銨業經以有機官能性(聚)矽烷、(聚)矽氧烷、(聚)矽氮烷、改質蠟、聚胺甲酸酯、聚環氧化物、脲-甲醛樹脂、三聚氰胺-甲醛樹脂、基於(甲基)丙烯酸酯樹脂之乳液、基於苯乙烯/丙烯酸酯共聚物之乳液、胺甲酸酯、基於乙烯/乙酸壬酯共聚物之乳液、基於橡膠之乳液及/或彼之混合物微封裝。
- 如請求項1至9中至少一項之組成物,其中該組成物另外包含以組分(A)及(B)的量為基礎計達至10重量%之硫酸銨、硫酸三乙基銨、硫酸四甲基銨、硫酸三甲基銨、二甲基硫酸鹽、二乙基硫酸鹽、二丙基硫酸鹽、辛基硫酸鈉、癸基硫酸鈉、十八烷基硫酸鈉、月桂基硫酸鹽、硫酸脲(urea sulfate)、硫酸三聚氰胺、硫酸羥胺、硫酸肼(hydrazine sulfate)、硫酸鉀、硫酸氫鉀、硫酸鈉、硫酸氫鈉、硫酸鎂、硫酸氫鎂、硫酸鈣、硫酸氫鈣、硫酸鋇、硫酸鋁鉀、硫酸鋁、硫酸鐵(III)、硫酸鐵(II)、硫酸鈷、硫酸鈦、硫酸鋅、硫酸錫、硫酸鈰、硫酸鋰、甲基硫酸三甲基鋶或彼之混合物。
- 一種如請求項1至10中至少一項之組成物之用途,其係用於降低膨脹型塗料之起始反應溫度、用於增加膨脹型塗料之耐火能力、作為透明塗料和膨脹型塗料之阻燃劑、用於木材和其他纖維素產品之阻燃劑中或作為阻燃劑、用於聚合物、凝膠塗料、不飽和聚酯樹脂之反應性及/或不反應性阻燃劑中或作為其反應性及/或不反應性阻燃劑、用於生產阻燃聚合物模製化合物、用於生產阻燃聚合物模製物、用於藉由浸漬而使聚酯及純和混紡纖維素織物成為阻燃性、用於聚胺甲酸酯發泡體中、用於聚烯烴中、用於不飽和聚酯和酚樹脂中、及用於使紡織品成為阻燃性。
- 一種如請求項1至10中至少一項之組成物之用途,其係用在或用於插頭連接器、配電器中的載流組件(殘餘電流保護)、電路板、灌封化合物、電力連接器、斷路器、燈殼、LED燈殼、電容器箱、線圈元件、通風器、接地觸頭、插頭、印刷電路板內/上、插頭之外殼、電池外殼、電纜、撓性電路板、充電電纜、電動機蓋、紡織品塗料及其他產品。
- 一種如請求項1至10中至少一項之組成物之用途,其係用於鋼材、木材、木質材料、紙、礦物綿、石膏板、塑料、金屬、合金、由合成或天然纖維製成的織物和其他適合的材料上,及/或用作為防焊罩(solder mask)及用於電氣開關和電路之耐火塗料。
- 一種如請求項1至10中至少一項之組成物之用途,其係用於塗佈鋼材結構(諸如鋼樑和鋼支架)、屋頂、牆壁、電纜、管道、導管、電纜和組合式艙壁、門、窗簾、防煙垂壁、百葉窗、安全櫃、安裝櫃及其他物件。
- 一種耐火塗料,其包含膜成形黏合劑、發泡劑、作為泡沫成形物質(foam-forming substance)的如請求項1至10中一或多項之組成物、碳成形物質(carbon-forming substance)、輔助劑和添加劑、及視需要的增稠劑、分散添加劑和溶劑及/或溶劑混合物。
- 如請求項15之耐火塗料,其包含 5重量%至69.4重量%之膜成形黏合劑, 5重量%至25重量%之發泡劑, 5重量%至40重量%之作為泡沫成形物質的如請求項1至10中一或多項之組成物, 5重量%至25重量%之碳成形物質, 5重量%至40重量%之輔助劑和添加劑, 0.5重量%至10重量%之增稠劑, 0.1重量%至10重量%之分散添加劑,及 10重量%至40重量%之溶劑及/或溶劑混合物,其中該等組分總和至100重量%。
- 如請求項15或16之耐火塗料,其中該膜成形黏合劑包含基於苯乙烯與丙烯酸酯之共聚物、基於丙烯酸酯之共聚物、乙烯基甲苯/丙烯酸酯共聚物、苯乙烯/丙烯酸酯聚合物、基於乙酸乙烯酯之均聚物、基於乙酸乙烯酯、乙烯與氯乙烯之共聚物、基於乙酸乙烯酯與長支鏈羧酸的乙烯酯之共聚物、基於乙酸乙烯酯與順丁烯二酸二正丁酯及/或丙烯酸酯之共聚物、乙烯基/丙烯酸酯共聚物、自交聯聚胺甲酸酯分散液、萜烯及/或聚萜烯及/或彼之混合物; 該發泡劑為三聚氰胺、三聚氰胺-甲醛縮合物、胍、其鹽類、三聚氰胺縮合產物及/或二氰二胺; 該碳成形物質為澱粉、改質澱粉、多元醇(polyhydric alcohol或polyol),諸如醣和多醣、及/或熱塑性或熱固性聚合物樹脂黏合劑,諸如酚樹脂、脲樹脂、聚胺甲酸酯、聚氯乙烯、聚(甲基)丙烯酸酯、聚乙酸乙烯酯、聚乙烯醇、聚矽氧樹脂及/或橡膠; 該輔助劑和添加劑為玻璃纖維、礦物纖維、金屬纖維、碳纖維、高嶺土、滑石、氧化鋁、氫氧化鋁、氫氧化鎂和其他金屬氧化物、沉澱矽石、矽酸鹽及/或粉狀纖維素; 該增稠劑及/或流變添加劑為(改質)纖維素、矽石、膨土、蓖麻油衍生物、脂肪衍生物、聚醯胺、聚(甲基)丙烯酸酯、聚丙烯醯胺、聚醚、聚胺甲酸酯、聚乙烯醇、聚乙烯基吡咯啶酮、糖聚合物,諸如阿拉伯膠、海藻酸鹽、三仙膠及/或瓊脂; 該潤濕和分散添加劑為烷基酚乙氧化物、聚丙烯酸及/或聚胺甲酸酯; 該有機溶劑及/或溶劑混合物為芳族烴,較佳為二甲苯,及/或烷基苯,較佳為甲苯和乙苯;醇,較佳為甲醇,及/或烷醇,較佳為2-甲基-1-丙醇;酮,諸如丙酮或丁酮;烷酸酯,及/或聚醚,較佳為聚乙二醇醚。
- 如請求項15至17中一或多項之耐火塗料,其中該多元醇為三新戊四醇、及/或新戊四醇之聚縮物、及/或新戊四醇系酯與多元醇、聚乙酸乙烯酯、聚乙烯醇、山梨醇及/或環氧乙烷-環氧丙烷多元醇之混合物。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP21157118.7 | 2021-02-15 | ||
EP21157118 | 2021-02-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
TW202239700A true TW202239700A (zh) | 2022-10-16 |
Family
ID=74625885
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW110141515A TW202239700A (zh) | 2021-02-15 | 2021-11-08 | 包含聚磷酸銨之組成物 |
Country Status (7)
Country | Link |
---|---|
US (1) | US20240002680A1 (zh) |
EP (1) | EP4291605A1 (zh) |
JP (1) | JP2024502853A (zh) |
KR (1) | KR20230146085A (zh) |
CN (1) | CN116829633A (zh) |
TW (1) | TW202239700A (zh) |
WO (1) | WO2022171489A1 (zh) |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE408787B (sv) | 1973-06-14 | 1979-07-09 | Hoechst Ag | Sett och anordning for framstellning av hyvudsakligen vattenolosliga kedjeformiga ammoniumpolyfosfater |
DE2813870A1 (de) | 1978-03-31 | 1979-10-18 | Hoechst Ag | Verwendung von ammoniumpolyphosphat |
JPH0733245B2 (ja) * | 1991-01-10 | 1995-04-12 | チッソ株式会社 | Ii型ポリリン酸アンモニウムの微粒子 |
DE4133811A1 (de) | 1991-10-12 | 1993-04-15 | Hoechst Ag | Verfahren zur herstellung von ammoniumpolyphosphat |
JPH07187626A (ja) * | 1993-10-22 | 1995-07-25 | Mitsui Toatsu Chem Inc | 被覆処理されたポリリン酸アンモニウム |
JPH09286985A (ja) * | 1996-04-22 | 1997-11-04 | Chisso Corp | 発泡耐火材 |
DE10359814A1 (de) | 2003-12-19 | 2005-07-28 | Clariant Gmbh | Dialkylphosphinsäure-Salze |
CN101348721B (zh) * | 2008-09-11 | 2011-03-23 | 北京理工大学 | 一种聚磷酸铵与蒙脱土纳米复合物及其制备方法 |
CN103554999B (zh) * | 2013-11-06 | 2015-04-08 | 四川大学 | 改性聚磷酸铵及其制备方法和用途 |
CN103588992B (zh) * | 2013-11-06 | 2015-10-28 | 四川大学 | 原位聚合双层包覆改性聚磷酸铵及其制备方法和用途 |
WO2017067906A1 (de) * | 2015-10-20 | 2017-04-27 | Clariant International Ltd | Mischungen aus ammoniumpolyphosphat und mindestens einer löslichen ionischen verbindung die sulfat enthält und/oder in der lage ist sulfat-ionen freizusetzen |
DE102016203911A1 (de) | 2016-03-10 | 2017-09-14 | Clariant Plastics & Coatings Ltd | Halogenfreie, dämmschichtbildende Brandschutzbeschichtung sowie deren Verwendung |
CN108219233A (zh) * | 2017-12-18 | 2018-06-29 | 襄阳华虹高科新材料有限公司 | 一种梯度阻燃剂及其制备方法 |
CN112955317A (zh) * | 2018-12-25 | 2021-06-11 | Dic株式会社 | 粘合带 |
KR20210106414A (ko) * | 2018-12-25 | 2021-08-30 | 디아이씨 가부시끼가이샤 | 난연성 점착제 및 난연성 점착 테이프 |
-
2021
- 2021-11-08 TW TW110141515A patent/TW202239700A/zh unknown
-
2022
- 2022-02-01 US US18/038,575 patent/US20240002680A1/en active Pending
- 2022-02-01 EP EP22703609.2A patent/EP4291605A1/en active Pending
- 2022-02-01 JP JP2023541772A patent/JP2024502853A/ja active Pending
- 2022-02-01 CN CN202280010768.XA patent/CN116829633A/zh active Pending
- 2022-02-01 KR KR1020237031742A patent/KR20230146085A/ko not_active Application Discontinuation
- 2022-02-01 WO PCT/EP2022/052317 patent/WO2022171489A1/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
WO2022171489A1 (en) | 2022-08-18 |
JP2024502853A (ja) | 2024-01-23 |
KR20230146085A (ko) | 2023-10-18 |
CN116829633A (zh) | 2023-09-29 |
EP4291605A1 (en) | 2023-12-20 |
US20240002680A1 (en) | 2024-01-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20200369963A1 (en) | Process for preparing flame retardant compositions | |
CA2246888C (en) | Intumescent coating stable under tropical conditions | |
Shen | Review of recent advances on the use of boron-based flame retardants | |
CN110191928B (zh) | 用于膨胀型泡沫稳定化的表面活性剂 | |
WO2011085531A1 (zh) | 一种阻燃聚合物泡沫材料及其制备方法 | |
WO2004050777A1 (en) | Flame retardant coating composition and method of preparing the same | |
Kaur et al. | The role of bentonite clay on improvement in char adhesion of intumescent fire-retardant coating with steel substrate | |
NO321152B1 (no) | Oppsvulmende laminater med hoy varmegjennomtrengningsmotstand og anvendelse derav | |
KR20180120258A (ko) | 할로겐 비함유, 발포성 내화 도료 및 이의 용도 | |
KR20190030148A (ko) | 불연성 코팅층이 형성된 건축용 판넬 및 불연성 코팅층 형성 방법 | |
US11628589B2 (en) | Mixtures of ammonium polyphosphate and at least one soluble ionic compound containing sulfate and/or is capable of releasing sulfate ions | |
WO2000032707A1 (fr) | Materiau de revetement resistant au feu | |
Duquesne et al. | Intumescent systems | |
JP2004107665A (ja) | 耐火性塗料 | |
TW202239700A (zh) | 包含聚磷酸銨之組成物 | |
CN104080849B (zh) | 用于阻燃应用的含有阻燃化学品的纳米粘土 | |
JP3832703B2 (ja) | 耐火性塗料 | |
CN105255394B (zh) | 一种真金板用阻燃型胶黏剂及其制备方法和应用 | |
US20160017230A1 (en) | Pulverulent Coated Flame Retardant | |
JP2001152081A (ja) | 耐火性塗料 | |
EP3990570A1 (en) | Polymer flame retardant and method for its manufacture | |
CN115485340A (zh) | 膨胀型涂料 | |
KR20160112516A (ko) | 난연성 조성물 및 이를 포함하는 난연성 성형물 | |
CN102229424B (zh) | 聚磷酸铵接枝改性制备方法 | |
Kang et al. | Development of an ABS Nanocomposite Material and its Application to a Fire-resistant Glazing System-Part I: Development of an ABS Nanocomposite Material |