CN106170501B - 制备支链聚合物的方法、支链聚合物和该聚合物的应用 - Google Patents

制备支链聚合物的方法、支链聚合物和该聚合物的应用 Download PDF

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CN106170501B
CN106170501B CN201580012806.5A CN201580012806A CN106170501B CN 106170501 B CN106170501 B CN 106170501B CN 201580012806 A CN201580012806 A CN 201580012806A CN 106170501 B CN106170501 B CN 106170501B
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polymer
monomer
optionally
chain transfer
mol
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CN106170501A (zh
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彼得·萧
琼·贝蒂
维吉妮·查布洛
莫妮卡·法雷尔
莉娜·森本
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Synthomer UK Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F16/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an alcohol radical
    • C08F16/04Acyclic compounds
    • C08F16/06Polyvinyl alcohol ; Vinyl alcohol
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02Esters of monocarboxylic acids
    • C08F218/04Vinyl esters
    • C08F218/08Vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02Monomers containing chlorine
    • C08F14/04Monomers containing two carbon atoms
    • C08F14/06Vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • C08F2/06Organic solvent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/18Suspension polymerisation
    • C08F2/20Suspension polymerisation with the aid of macromolecular dispersing agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10Esters
    • C08F222/26Esters of unsaturated alcohols
    • C08F222/28Diallyl maleate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/12Hydrolysis
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/07Aldehydes; Ketones

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
CN201580012806.5A 2014-03-28 2015-03-27 制备支链聚合物的方法、支链聚合物和该聚合物的应用 Active CN106170501B (zh)

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Application Number Priority Date Filing Date Title
CN201811312806.9A CN109354641B (zh) 2014-03-28 2015-03-27 制备支链聚合物的方法、支链聚合物和该聚合物的应用

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB1405624.6A GB201405624D0 (en) 2014-03-28 2014-03-28 Method of making a branched polymer, a branched polymer and uses of such a polymer
GB1405624.6 2014-03-28
PCT/GB2015/050937 WO2015145173A1 (en) 2014-03-28 2015-03-27 Method of making a branched polymer, a branched polymer and uses of such a polymer

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US (1) US10711073B2 (https=)
EP (2) EP3119815B1 (https=)
JP (2) JP7113617B2 (https=)
KR (1) KR102356385B1 (https=)
CN (2) CN106170501B (https=)
BR (1) BR112016022117A2 (https=)
ES (1) ES2684999T3 (https=)
GB (1) GB201405624D0 (https=)
MX (1) MX2016012327A (https=)
RU (1) RU2688179C2 (https=)
TW (1) TWI748930B (https=)
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Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014049137A1 (en) 2012-09-28 2014-04-03 Saint-Gobain Performance Plastics Pampus Gmbh Maintenance-free slide bearing with a combined adhesive sliding layer
CN112920293A (zh) 2015-03-05 2021-06-08 积水精细化工美国有限公司 用于vcm聚合的pvoh分散剂
GB2580909A (en) 2019-01-28 2020-08-05 Synthomer Uk Ltd Polymer latex and elastomeric film made therefrom having self-healing properties
GB2580910A (en) 2019-01-28 2020-08-05 Synthomer Uk Ltd Self-supported elastomeric film having self-healing properties made from a polymer latex
GB201918030D0 (en) 2019-12-09 2020-01-22 Synthomer Uk Ltd Improvements in, or relating to, binders and/or coatings
EP4538301A4 (en) * 2022-06-08 2025-09-03 Denka Company Ltd POLYVINYL ALCOHOL BASED POLYMER
US20240327553A1 (en) * 2023-03-01 2024-10-03 Halliburton Energy Services, Inc. Branched Polyvinyl Alcohol As A Shale Stabilizer For Drilling Fluid Applications

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4489192A (en) * 1983-10-05 1984-12-18 National Starch And Chemical Corporation Cationic vinyl ester based polymer latices, their preparation and use as formaldehyde-free binders
CN1306546A (zh) * 1998-06-19 2001-08-01 钟渊化学工业株式会社 支链聚合物的制备方法和聚合物
CN101421309A (zh) * 2006-04-12 2009-04-29 可乐丽股份有限公司 分散稳定剂
WO2013005050A1 (en) * 2011-07-06 2013-01-10 Unilever Plc Copolymers and membranes

Family Cites Families (70)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2888442A (en) 1954-04-09 1959-05-26 Phillips Petroleum Co New polymers from conjugated dienes and polyvinyl compounds prepared in the presence of mercaptans
GB967051A (en) 1963-01-14 1964-08-19 Du Pont Microgels and coating compositions containing same
GB1068135A (en) * 1964-03-04 1967-05-10 Baker Chem Co J T Suspension polymerization
DE1645624A1 (de) * 1966-02-04 1970-12-17 Vnii Sint Kaucuka Im Akademika Verfahren zur Herstellung reaktionsfaehiger Synthesekautschuke
IL46681A (en) * 1975-02-21 1977-06-30 Imi Inst For Research And Dev Interpolymers of vinyl chloride and their preparation
JPS51115587A (en) * 1975-03-24 1976-10-12 Kuraray Co Ltd Method of producing polyvinylchloride resins
JPS5445686A (en) 1977-08-11 1979-04-11 Nippon Synthetic Chem Ind Co Ltd:The Dispersion stabilizer for suspension polymerization of vinly compound
JPS5559241A (en) 1978-10-09 1980-05-02 Fuiritsupu Deii Supurangu Constructed body
JPS5594978A (en) * 1979-01-16 1980-07-18 Unitika Chem Kk Water-soluble or-dispersible hot melt adhesive
JPS5730945A (en) * 1980-06-25 1982-02-19 Asahi Chem Ind Co Ltd Hydrophilic filler for gel permeation chromatography
US4368275A (en) * 1980-06-25 1983-01-11 Asahi Kasei Kogyo Kabushiki Kaisha Isocyanurate-vinyl alcohol-vinyl ester chromatographic packing
JPS57108662A (en) * 1980-12-26 1982-07-06 Asahi Chem Ind Co Ltd Filler for high speed liquid chromatography
JPS5782847A (en) 1980-11-11 1982-05-24 Canon Inc Developing powder
CA1221196A (en) 1982-08-17 1987-04-28 Maynard A. Sherwin Humidity resistant coatings employing branched polymers of t-butyl acrylate
JPS59166505A (ja) 1983-03-10 1984-09-19 Kuraray Co Ltd 懸濁重合用分散安定剤
JPS60190223A (ja) * 1984-03-09 1985-09-27 Kuraray Co Ltd 乳化重合用分散安定剤
JPS61108602A (ja) 1984-11-02 1986-05-27 Nippon Synthetic Chem Ind Co Ltd:The ビニル化合物の懸濁重合用分散安定剤
JPH0621125B2 (ja) * 1984-11-02 1994-03-23 日本合成化学工業株式会社 分散安定剤
DE3534858A1 (de) 1985-09-30 1987-04-02 Basf Lacke & Farben Loesliches carboxylgruppenhaltiges acrylatcopolymerisat, verfahren zu seiner herstellung und ueberzugsmittel auf der basis des acrylatcopolymerisats
JP2565511B2 (ja) 1987-09-17 1996-12-18 株式会社クラレ 塩化ビニルの懸濁重合用分散安定剤
JP2629016B2 (ja) 1988-03-21 1997-07-09 株式会社クラレ ビニル系化合物の懸濁重合用分散安定剤
US5164282A (en) 1989-04-17 1992-11-17 Xerox Corporation Processes for the preparation of toners
IT1241660B (it) 1990-03-07 1994-01-26 3V Ltd Copolimero vinil acetato/vinil alcool,processo di produzione dello stesso e suo impiego
WO1991015518A1 (en) 1990-04-05 1991-10-17 Kuraray Co., Ltd. Suspension polymerization of vinylic compound
JPH0588251A (ja) 1991-09-26 1993-04-09 Ricoh Co Ltd カメラのリモートコントロール装置
TW222282B (https=) 1992-03-10 1994-04-11 Kuraray Co
US5484866A (en) 1993-11-09 1996-01-16 Mobil Oil Corporation Concentrates of a highly branched polymer and functional fluids prepared therefrom
JPH07330912A (ja) 1994-06-08 1995-12-19 Eastman Kodak Co ポリマー粒状物及びその製造方法
KR100377604B1 (ko) 1994-10-28 2003-07-18 스미또모 가가꾸 고오교오 가부시끼가이샤 메틸메타아크릴레이트중합체
US5529719A (en) 1995-03-27 1996-06-25 Xerox Corporation Process for preparation of conductive polymeric composite particles
JP3474307B2 (ja) * 1995-04-17 2003-12-08 株式会社クラレ ビニル系化合物の懸濁重合用分散安定剤
DE19519339A1 (de) 1995-05-26 1996-11-28 Basf Ag Wasserlösliche Copolymerisate, die Vernetzer einpolymerisiert enthalten, Verfahren zu ihrer Herstellung und ihre Verwendung
JP3385177B2 (ja) 1997-04-10 2003-03-10 株式会社日本触媒 星形ブロック重合体とその製造方法
EP0872494A3 (en) 1997-04-17 1999-05-12 Henkel Corporation Method of preparing inorganic pigment dispersions
US6402995B1 (en) * 1997-07-31 2002-06-11 Seed Co., Ltd. Process for preparing polyvinyl alcohol contact lenses
NZ505056A (en) 1998-03-12 2003-05-30 Lucite Int Uk Ltd A branched polymer composition containing a monofunctional monomer, a polyfunctional monomer and a chain transfer agent
SG91279A1 (en) * 1999-06-09 2002-09-17 Kuraray Co Polyvinyl alcohol polymer production method and polyvinyl alcohol polymer
US6881761B2 (en) 2000-05-29 2005-04-19 Showa Denko K.K. Porous polymer particle, anion exchanger, producing method thereof, column for ion chromatography, and method for measuring anions
EP1160260B1 (en) * 2000-05-29 2011-04-13 Showa Denko K.K. Porous polymer particle, anion exchanger, producing method thereof, column for ion chromatography, and method for measuring anions
DE10035119A1 (de) 2000-07-19 2002-01-31 Basf Ag Teilverzweigte Polymere
JP2004189889A (ja) * 2002-12-11 2004-07-08 Kuraray Co Ltd ビニル系化合物の懸濁重合用分散安定剤
DE60319201T2 (de) 2002-12-11 2009-02-12 KURARAY CO., LTD, Kurashiki Dispersionsstabilisator für die Suspensionspolymerisation einer Vinylverbindung und Verfahren zur Herstellung davon
JP3995584B2 (ja) * 2002-12-11 2007-10-24 株式会社クラレ ビニル系化合物の懸濁重合用分散安定剤の製造法
RU2265617C2 (ru) * 2002-12-30 2005-12-10 ФГУП ГНЦ РФ Научно-исследовательский физико-химический институт им. Л.Я. Карпова Малоразветвленный высокомолекулярный поливинилацетат, способ его получения и поливиниловый спирт на его основе
CN1274726C (zh) * 2003-07-09 2006-09-13 中国石油化工集团公司 一种聚乙烯醇合成方法
US20090076211A1 (en) 2003-08-18 2009-03-19 Yong Yang Copolymer surfactants
US7402627B2 (en) 2003-08-18 2008-07-22 Columbia Insurance Company Precursor colorant composition for latex paint
JP4391323B2 (ja) 2004-06-10 2009-12-24 日本合成化学工業株式会社 懸濁重合用分散剤
DE102004030019A1 (de) 2004-06-22 2006-01-19 Xetos Ag Photopolymerisierbare Zusammensetzung
US20080154007A1 (en) * 2004-12-28 2008-06-26 Kaneka Corporation Cross-Linked Polymer Particle and Manufacturing Method Thereof
JP5288683B2 (ja) 2005-02-02 2013-09-11 日本合成化学工業株式会社 ビニル系化合物の懸濁重合用分散安定剤
EP2295473B1 (en) * 2005-09-16 2016-12-28 Rohm and Haas Company Swellable particles
US20070184732A1 (en) 2006-02-07 2007-08-09 Lunsford David J High strength polyvinyl acetate binders
CN101460149A (zh) 2006-06-07 2009-06-17 巴斯夫欧洲公司 醋酸乙烯酯-磺酸盐共聚物作为微水溶性化合物的加溶剂的用途
CN101506255B (zh) 2006-08-01 2014-02-12 日本合成化学工业株式会社 乙烯基化合物的悬浮聚合用分散稳定剂
ATE542841T1 (de) 2006-12-12 2012-02-15 Unilever Nv Polymere
US20100145001A1 (en) 2006-12-12 2010-06-10 Unilever Plc branched organic-inorganic polymers
BRPI0720237A2 (pt) 2006-12-12 2013-12-31 Unilever Nv Polímero ramificado, método para preparar um copolímero ramificado, composição, e, uso de um copolímero ramificado
PL2112171T3 (pl) 2007-02-07 2012-04-30 Kuraray Co Stabilizator dyspersji do polimeryzacji suspensyjnej związku winylowego i sposób wytwarzania polimeru związku winylowego
DE102007033970A1 (de) 2007-07-19 2009-01-22 Kuraray Europe Gmbh Verwendung von getemperten Polyvinylalkoholen als Stabilisatorzusatz von PVC
EP2128180A1 (en) 2008-05-29 2009-12-02 Unilever N.V. Amphiphilic branched polymers and their use as emulsifiers
JP5088251B2 (ja) * 2008-06-30 2012-12-05 日本電気株式会社 通信システム
GB0902052D0 (en) 2009-02-09 2009-03-11 Unilever Plc Polymers,composition and use
GB0907273D0 (en) 2009-04-28 2009-06-10 Unilever Plc Improvements relating to branched polymers
FR2945539B1 (fr) 2009-05-15 2012-05-18 Arkema France Procede de preparation en suspension d'un pvc greffe sur elastomere.
GB0910750D0 (en) 2009-06-22 2009-08-05 Unilever Plc Branched polymer dispersants
CN102471388B (zh) * 2009-07-14 2014-08-06 埃克森美孚化学专利公司 高压自由基聚合方法
CN102108107A (zh) * 2011-01-21 2011-06-29 湖南省湘维有限公司 一种低聚合度聚乙烯醇的制备方法
WO2012113896A1 (en) 2011-02-25 2012-08-30 Basf Se Process for the preparation of an aqueous polymer latex
GB201310652D0 (en) * 2013-06-14 2013-07-31 Univ Liverpool Polydendrons

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4489192A (en) * 1983-10-05 1984-12-18 National Starch And Chemical Corporation Cationic vinyl ester based polymer latices, their preparation and use as formaldehyde-free binders
CN1306546A (zh) * 1998-06-19 2001-08-01 钟渊化学工业株式会社 支链聚合物的制备方法和聚合物
CN101421309A (zh) * 2006-04-12 2009-04-29 可乐丽股份有限公司 分散稳定剂
WO2013005050A1 (en) * 2011-07-06 2013-01-10 Unilever Plc Copolymers and membranes

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Facile synthesis of branched poly(vinyl alcohol)s;Baudry R et al;《Macromolecules, american chemical society》;20060806;第39卷;第5230-5237页 *

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JP6814851B2 (ja) 2021-01-20
TW201540737A (zh) 2015-11-01
JP7113617B2 (ja) 2022-08-05
JP2019196499A (ja) 2019-11-14
CN109354641A (zh) 2019-02-19
RU2688179C2 (ru) 2019-05-21
TWI748930B (zh) 2021-12-11
KR102356385B1 (ko) 2022-01-26
ES2684999T3 (es) 2018-10-05
US20170137542A1 (en) 2017-05-18
CN109354641B (zh) 2021-05-18
GB201405624D0 (en) 2014-05-14
CN106170501A (zh) 2016-11-30
WO2015145173A1 (en) 2015-10-01
EP3119815A1 (en) 2017-01-25
EP3119815B1 (en) 2018-06-20
KR20160140758A (ko) 2016-12-07
US10711073B2 (en) 2020-07-14
BR112016022117A2 (pt) 2017-08-15
JP2017509782A (ja) 2017-04-06
RU2016142485A (ru) 2018-04-28
MX2016012327A (es) 2017-04-06
RU2016142485A3 (https=) 2018-09-03
EP3434698A1 (en) 2019-01-30

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