CN103140287B - 使用混合盐乙酰丙酮化物催化剂的酯交换方法 - Google Patents

使用混合盐乙酰丙酮化物催化剂的酯交换方法 Download PDF

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Publication number
CN103140287B
CN103140287B CN201180037399.5A CN201180037399A CN103140287B CN 103140287 B CN103140287 B CN 103140287B CN 201180037399 A CN201180037399 A CN 201180037399A CN 103140287 B CN103140287 B CN 103140287B
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alkyl
phenyl
catalyst
alcohol
substituted
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Expired - Fee Related
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CN201180037399.5A
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English (en)
Chinese (zh)
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CN103140287A (zh
Inventor
T·P·A·古森斯
F·A·C·韦利林科
N·G·C·霍斯滕
K·J·A·范阿肯
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Ecosynth NV
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Ecosynth NV
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C68/00—Preparation of esters of carbonic or haloformic acids
    • C07C68/06—Preparation of esters of carbonic or haloformic acids from organic carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/49—Esterification or transesterification
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN201180037399.5A 2010-06-15 2011-06-10 使用混合盐乙酰丙酮化物催化剂的酯交换方法 Expired - Fee Related CN103140287B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB201009969A GB201009969D0 (en) 2010-06-15 2010-06-15 Transesterification process using mixed salt acetylacetonates catalysts
GB1009969.5 2010-06-15
PCT/EP2011/059672 WO2011157645A2 (en) 2010-06-15 2011-06-10 Transesterification process using mixed salt acetylacetonates catalysts

Publications (2)

Publication Number Publication Date
CN103140287A CN103140287A (zh) 2013-06-05
CN103140287B true CN103140287B (zh) 2016-08-03

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Country Status (10)

Country Link
US (1) US8865931B2 (https=)
EP (1) EP2582453B1 (https=)
JP (1) JP5916722B2 (https=)
KR (1) KR101863154B1 (https=)
CN (1) CN103140287B (https=)
BR (1) BR112012031918B1 (https=)
GB (1) GB201009969D0 (https=)
MX (1) MX341537B (https=)
RS (1) RS55808B1 (https=)
WO (1) WO2011157645A2 (https=)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9150673B2 (en) * 2011-07-06 2015-10-06 Basf Se Process for preparing (meth)acrylic esters
CN105233874B (zh) * 2013-11-07 2017-07-14 山东科技大学 一步法制备卟啉功能化纳米硫化锌的工艺
KR20160107181A (ko) * 2013-12-26 2016-09-13 다우 글로벌 테크놀로지스 엘엘씨 리튬 염-촉매된 트랜스에스테르화 공정용 억제제 배합물 및 리튬 염의 제거방법
JP6643546B2 (ja) * 2015-03-10 2020-02-12 東亞合成株式会社 （メタ）アクリレートの製造方法
JP6633612B2 (ja) * 2015-03-12 2020-01-22 株式会社クラレ （メタ）アクリル酸エステル化合物の製造方法
EP3072879A1 (en) 2015-03-26 2016-09-28 Nitto Europe N.V Method for prevention of premature polymerization
JP6809043B2 (ja) * 2015-09-03 2021-01-06 東亞合成株式会社 単官能（メタ）アクリレートの製造方法
CN105330537A (zh) * 2015-11-30 2016-02-17 抚顺东联安信化学有限公司 丙烯酸甲氧基乙酯的制备方法
US10704262B2 (en) 2016-09-26 2020-07-07 U.S. Silica Company Self-cleaning cool roof system
CN109890483B (zh) * 2016-11-09 2022-03-01 株式会社可乐丽 氧吸收剂
JP6828500B2 (ja) * 2017-02-21 2021-02-10 三菱瓦斯化学株式会社 ２−メチル−２−ヒドロキシ−１−プロピル（メタ）アクリレートおよび／または３−メチル−３−ヒドロキシ−１−ブチル（メタ）アクリレートの製造方法ならびに組成物
TWI796324B (zh) * 2017-03-09 2023-03-21 日商東亞合成股份有限公司 (甲基)丙烯酸酯的製造方法
JP6991236B2 (ja) * 2017-10-24 2022-02-10 信越化学工業株式会社 ラジカル重合性オルガノポリシロキサンの製造方法、放射線硬化性オルガノポリシロキサン組成物、及び剥離シート
EP3778554B1 (en) 2018-04-12 2024-02-07 SNF Group Method for producing 2-dimethylaminoethyl (meth)acrylate
CN109748826B (zh) * 2018-12-28 2021-09-21 京博农化科技有限公司 一种茚虫威中间体肼基甲酸苄酯的合成方法
CN113348199B (zh) 2018-12-31 2023-02-17 美国陶氏有机硅公司 支链有机硅化合物、制备支链有机硅化合物的方法以及用其形成的共聚物
US12215198B2 (en) 2018-12-31 2025-02-04 Dow Silicones Corporation Branched organosilicon compound, method of preparing same, and compositions comprising same
CN113330054B (zh) 2018-12-31 2023-02-21 美国陶氏有机硅公司 支链有机硅化合物、其制备方法以及用其形成的共聚物
JP7561738B2 (ja) 2018-12-31 2024-10-04 ダウ シリコーンズ コーポレーション 組成物、コポリマーの調製方法、並びにその方法及び最終用途
EP3906244A1 (en) 2018-12-31 2021-11-10 Dow Silicones Corporation Method of preparing acryloxy-functional organosilicon compounds
EP3906274A1 (en) 2018-12-31 2021-11-10 Dow Silicones Corporation Acrylate-functional branched organosilicon compound, method of preparing same, and copolymer formed therewith
US12269833B2 (en) 2018-12-31 2025-04-08 Dow Silicones Corporation Branched organosilicon compound, method of preparing same, and compositions comprising same
CN113661195B (zh) * 2019-04-11 2025-05-30 株式会社可乐丽 聚合物、使用了该聚合物的氧吸收剂、及固化性组合物
CN110252396B (zh) * 2019-06-27 2022-03-11 山东第一医科大学(山东省医学科学院) 一种用于间苯二甲酸二甲酯-5-磺酸钠合成过程中的催化剂、制备方法及应用
WO2022220543A1 (ko) * 2021-04-12 2022-10-20 한국화학연구원 디메틸테레프탈레이트의 에스테르 교환 반응에 의한 테레프탈레이트 유도체 제조 방법
KR102480102B1 (ko) * 2021-05-14 2022-12-23 한국화학연구원 아크릴계 그라디언트 공중합체의 제조방법
AU2022329947A1 (en) 2021-08-16 2024-03-28 Rohm And Haas Company Preparation of ureido methacrylate
EP4467591A4 (en) * 2022-01-18 2025-04-16 Asahi Kasei Kabushiki Kaisha PROCESS FOR PRODUCING POLYCARBONATE DIOL, POLYCARBONATE DIOL, AND TRANSESTERIFICATION CATALYST
JP2024008235A (ja) * 2022-07-07 2024-01-19 旭化成株式会社 エステル交換触媒
CN120025247B (zh) * 2025-04-23 2025-07-04 抚顺东联安信化学有限公司 一种酯交换生产甲基丙烯酸正癸酯的方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4375361A (en) * 1980-03-24 1983-03-01 Suntech, Inc. Process for making a high octane fuel component
CN1127750A (zh) * 1994-11-18 1996-07-31 埃勒夫阿托化学有限公司 (甲基)丙烯酸烷基咪唑酮酯的制备方法
JP2005132790A (ja) * 2003-10-31 2005-05-26 Mitsubishi Gas Chem Co Inc ２−メチル−２−ヒドロキシ−１−プロピル（メタ）アクリレートの製造方法

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2845451A (en) * 1955-06-23 1958-07-29 Basf Ag Production of acrylic acid and its functional derivatives
US3528946A (en) 1967-08-30 1970-09-15 Fmc Corp Acetylacetonates as polycondensation catalysts in transesterification method of preparing polyesters
US3532671A (en) 1967-08-30 1970-10-06 Fmc Corp Acetylacetonate transesterification catalysts
US3528945A (en) 1967-08-30 1970-09-15 Fmc Corp Acetylacetonates as polycondensation catalysts in the direct esterification method of preparing polyesters
JPS491531A (https=) * 1972-04-28 1974-01-08
GB1573071A (en) 1977-02-10 1980-08-13 Mitsubishi Rayon Co Process for producing unsaturated carbocylic acid esters
JPS603292B2 (ja) 1977-02-28 1985-01-26 三菱レイヨン株式会社 アクリル酸エステルまたはメタクリル酸エステルの製造法
JPS57183745A (en) * 1981-05-06 1982-11-12 Asahi Chem Ind Co Ltd Production of carbonic ester
US4777265A (en) 1986-03-11 1988-10-11 Basf Aktiengesellschaft Preparation of acrylates and methacrylates
DE3740037A1 (de) 1987-11-26 1989-06-08 Basf Ag Neue di(meth)acrylate, verfahren zu deren herstellung und deren verwendung
JPH01180861A (ja) * 1988-01-11 1989-07-18 Sanyo Chem Ind Ltd アクリル系モノマーの製造法
JPH0217155A (ja) 1988-07-06 1990-01-22 Toagosei Chem Ind Co Ltd ジアルキルアミノアルキル（メタ）アクリレートの製造方法
US5037978A (en) 1990-03-12 1991-08-06 Rohm And Haas Company Hafnium-catalyzed transesterification
DE4227299C1 (de) 1992-08-18 1994-01-27 Hoechst Ag Verfahren zur Herstellung von monomeren Terephthalsäurediestern und Diolen aus Polyestern
FR2707290B1 (fr) 1993-07-06 1995-09-01 Atochem Elf Sa Procédé de préparation de l'acrylate ou du méthacrylate d'éthylthioéthyle à l'aide d'acétylacétonate de zirconium comme catalyseur.
DE69714373T2 (de) 1996-10-17 2003-02-13 Rohm And Haas Co., Philadelphia Verfahren zum Herstellen von Monomeren
AU743962B2 (en) 1997-08-29 2002-02-14 Rohm And Haas Company Transesterification process
JPH11158261A (ja) * 1997-12-01 1999-06-15 Mitsubishi Chemical Corp 芳香族ポリカーボネート樹脂の製造方法
US5840957A (en) 1998-03-16 1998-11-24 E. I. Du Pont De Nemours And Company Transesterification process using lanthanum compound catalyst
AT408882B (de) 1998-08-07 2002-03-25 Dsm Fine Chem Austria Gmbh Verfahren zur umesterung von alpha-ketocarbonsäureestern
US6350895B1 (en) 1999-03-26 2002-02-26 E. I. Du Pont De Nemours And Company Transesterification process using yttrium and samarium compound catalystis
DE10008901B4 (de) 2000-02-25 2009-01-29 Evonik Degussa Gmbh Verfahren zur Herstellung von Malonsäurediestern durch kontinuierliche Umesterung
DE10145228A1 (de) 2001-09-13 2003-04-24 Roehm Gmbh Synthese von t-Butylaminoethylmethacrylat durch Umesterung des Alkohols mit MMA
JP2004010551A (ja) 2002-06-07 2004-01-15 Nippon Shokubai Co Ltd ビニルエーテル基含有（メタ）アクリル酸エステル類の製造方法
DE10321149A1 (de) 2003-05-12 2004-12-02 Bayer Materialscience Ag Ytterbium(III)acetylacetonat als Katalysator zur Herstellung von aliphatischen Oligocarbonatpolyolen
US6971614B2 (en) 2003-07-11 2005-12-06 Jifram Extrusions, Inc. Slatwall hanger stabilizing chip
GB0324964D0 (en) * 2003-10-27 2003-11-26 Great Lakes Chemical Europ Preparation of hydroxyphenyl carboxylic acid esters
DE102004042843A1 (de) * 2004-09-04 2006-03-09 Bayer Materialscience Ag Metallacetylacetonate als Umesterungskatalysatoren
DE102007031468A1 (de) 2007-07-05 2009-01-08 Evonik Röhm Gmbh Verfahren zur Herstellung von Allylmethacrylat
DE102008043810A1 (de) 2007-11-20 2009-05-28 Basf Se Verfahren zur Herstellung von (Meth)acrylsäureestern von Prenol und Isoprenol
FR2949779B1 (fr) 2009-09-07 2011-09-09 Arkema France Procede de preparation de (meth)acrylates d'alkylimidazolidone

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4375361A (en) * 1980-03-24 1983-03-01 Suntech, Inc. Process for making a high octane fuel component
CN1127750A (zh) * 1994-11-18 1996-07-31 埃勒夫阿托化学有限公司 (甲基)丙烯酸烷基咪唑酮酯的制备方法
JP2005132790A (ja) * 2003-10-31 2005-05-26 Mitsubishi Gas Chem Co Inc ２−メチル−２−ヒドロキシ−１−プロピル（メタ）アクリレートの製造方法

Also Published As

Publication number Publication date
RS55808B1 (sr) 2017-08-31
GB201009969D0 (en) 2010-07-21
CN103140287A (zh) 2013-06-05
US8865931B2 (en) 2014-10-21
EP2582453B1 (en) 2016-12-28
JP2013533861A (ja) 2013-08-29
JP5916722B2 (ja) 2016-05-11
MX341537B (es) 2016-08-24
BR112012031918B1 (pt) 2019-07-02
US20130090492A1 (en) 2013-04-11
KR101863154B1 (ko) 2018-07-04
WO2011157645A2 (en) 2011-12-22
MX2012014722A (es) 2013-04-11
KR20140002591A (ko) 2014-01-08
EP2582453A2 (en) 2013-04-24
WO2011157645A3 (en) 2012-10-18
BR112012031918A2 (pt) 2016-11-08

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