MX341537B - Proceso de transesterificacion que utiliza catalizadores de sal mixta de acetilacetonatos. - Google Patents

Proceso de transesterificacion que utiliza catalizadores de sal mixta de acetilacetonatos.

Info

Publication number
MX341537B
MX341537B MX2012014722A MX2012014722A MX341537B MX 341537 B MX341537 B MX 341537B MX 2012014722 A MX2012014722 A MX 2012014722A MX 2012014722 A MX2012014722 A MX 2012014722A MX 341537 B MX341537 B MX 341537B
Authority
MX
Mexico
Prior art keywords
catalysts
acetylacetonates
pref
reaction
mixed salt
Prior art date
Application number
MX2012014722A
Other languages
English (en)
Other versions
MX2012014722A (es
Inventor
Jeanne Alfons Van Aken Koen
Peter Anne Goossens Thomas
Annie Camiel Vrielynck Freek
Gabriel Cornelius Hosten Noel
Original Assignee
Ecosynth Bvba *
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ecosynth Bvba * filed Critical Ecosynth Bvba *
Publication of MX2012014722A publication Critical patent/MX2012014722A/es
Publication of MX341537B publication Critical patent/MX341537B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C68/00—Preparation of esters of carbonic or haloformic acids
    • C07C68/06—Preparation of esters of carbonic or haloformic acids from organic carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/49—Esterification or transesterification
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Esta invención se refiere a un catalizador general de alta actividad y selectividad para la producción de una variedad de ésteres, particularmente ésteres basados en acrilato y metacrilato, mediante una reacción de transesterificación. Este objetivo es llevado a cabo por reacción de un éster de un ácido carboxílico o un carbónico, en particular de uno saturado o insaturado, típicamente, de átomos de ácido carboxílico de 3 a 4 carbonos; con un alcohol en presencia de un catalizador que comprende la combinación de un complejo metálico de 1,3-dicarbonilo (preferentemente acetilacetona de Zn o Fe) y una sal, en particular una sal inorgánica, prefeferentemente ZnCl2, LiCl, NaC, NH4Cl o LiI. Estos catalizadores se preparan a partir de materiales de inicio fácilmente disponibles con reacción media sin la necesidad de aislamiento (preparación in-situ).
MX2012014722A 2010-06-15 2011-06-10 Proceso de transesterificacion que utiliza catalizadores de sal mixta de acetilacetonatos. MX341537B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB201009969A GB201009969D0 (en) 2010-06-15 2010-06-15 Transesterification process using mixed salt acetylacetonates catalysts
PCT/EP2011/059672 WO2011157645A2 (en) 2010-06-15 2011-06-10 Transesterification process using mixed salt acetylacetonates catalysts

Publications (2)

Publication Number Publication Date
MX2012014722A MX2012014722A (es) 2013-04-11
MX341537B true MX341537B (es) 2016-08-24

Family

ID=42471652

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2012014722A MX341537B (es) 2010-06-15 2011-06-10 Proceso de transesterificacion que utiliza catalizadores de sal mixta de acetilacetonatos.

Country Status (10)

Country Link
US (1) US8865931B2 (es)
EP (1) EP2582453B1 (es)
JP (1) JP5916722B2 (es)
KR (1) KR101863154B1 (es)
CN (1) CN103140287B (es)
BR (1) BR112012031918B1 (es)
GB (1) GB201009969D0 (es)
MX (1) MX341537B (es)
RS (1) RS55808B1 (es)
WO (1) WO2011157645A2 (es)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9150673B2 (en) * 2011-07-06 2015-10-06 Basf Se Process for preparing (meth)acrylic esters
CN103586084B (zh) * 2013-11-07 2015-07-01 山东科技大学 一步法制备卟啉功能化纳米硫化物的工艺
KR20160107181A (ko) * 2013-12-26 2016-09-13 다우 글로벌 테크놀로지스 엘엘씨 리튬 염-촉매된 트랜스에스테르화 공정용 억제제 배합물 및 리튬 염의 제거방법
US10065916B2 (en) * 2015-03-10 2018-09-04 Toagosei Co., Ltd Method for producing (meth)acrylate
CN107428664B (zh) * 2015-03-12 2020-07-10 株式会社可乐丽 (甲基)丙烯酸酯化合物的制造方法
EP3072879A1 (en) 2015-03-26 2016-09-28 Nitto Europe N.V Method for prevention of premature polymerization
JP6809043B2 (ja) * 2015-09-03 2021-01-06 東亞合成株式会社 単官能（メタ）アクリレートの製造方法
CN105330537A (zh) * 2015-11-30 2016-02-17 抚顺东联安信化学有限公司 丙烯酸甲氧基乙酯的制备方法
US10704262B2 (en) 2016-09-26 2020-07-07 U.S. Silica Company Self-cleaning cool roof system
EP3539640B1 (en) * 2016-11-09 2021-06-16 Kuraray Co., Ltd. Oxygen absorbing agent
JP6828500B2 (ja) * 2017-02-21 2021-02-10 三菱瓦斯化学株式会社 ２−メチル−２−ヒドロキシ−１−プロピル（メタ）アクリレートおよび／または３−メチル−３−ヒドロキシ−１−ブチル（メタ）アクリレートの製造方法ならびに組成物
TWI796324B (zh) * 2017-03-09 2023-03-21 日商東亞合成股份有限公司 (甲基)丙烯酸酯的製造方法
JP6991236B2 (ja) * 2017-10-24 2022-02-10 信越化学工業株式会社 ラジカル重合性オルガノポリシロキサンの製造方法、放射線硬化性オルガノポリシロキサン組成物、及び剥離シート
CN109748826B (zh) * 2018-12-28 2021-09-21 京博农化科技有限公司 一种茚虫威中间体肼基甲酸苄酯的合成方法
WO2020142388A1 (en) 2018-12-31 2020-07-09 Dow Silicones Corporation Composition, method of preparing copolymer, and methods and end uses thereof
CN110252396B (zh) * 2019-06-27 2022-03-11 山东第一医科大学(山东省医学科学院) 一种用于间苯二甲酸二甲酯-5-磺酸钠合成过程中的催化剂、制备方法及应用
KR102480102B1 (ko) * 2021-05-14 2022-12-23 한국화학연구원 아크릴계 그라디언트 공중합체의 제조방법
KR20240049573A (ko) 2021-08-16 2024-04-16 롬 앤드 하스 캄파니 우레이도 메타크릴레이트의 제조
WO2023140247A1 (ja) * 2022-01-18 2023-07-27 旭化成株式会社 ポリカーボネートジオールの製造方法、ポリカーボネートジオール及びエステル交換触媒

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2845451A (en) * 1955-06-23 1958-07-29 Basf Ag Production of acrylic acid and its functional derivatives
US3528946A (en) 1967-08-30 1970-09-15 Fmc Corp Acetylacetonates as polycondensation catalysts in transesterification method of preparing polyesters
US3532671A (en) 1967-08-30 1970-10-06 Fmc Corp Acetylacetonate transesterification catalysts
US3528945A (en) 1967-08-30 1970-09-15 Fmc Corp Acetylacetonates as polycondensation catalysts in the direct esterification method of preparing polyesters
JPS491531A (es) * 1972-04-28 1974-01-08
GB1573071A (en) 1977-02-10 1980-08-13 Mitsubishi Rayon Co Process for producing unsaturated carbocylic acid esters
JPS603292B2 (ja) 1977-02-28 1985-01-26 三菱レイヨン株式会社 アクリル酸エステルまたはメタクリル酸エステルの製造法
US4375361A (en) * 1980-03-24 1983-03-01 Suntech, Inc. Process for making a high octane fuel component
JPS57183745A (en) 1981-05-06 1982-11-12 Asahi Chem Ind Co Ltd Production of carbonic ester
US4777265A (en) 1986-03-11 1988-10-11 Basf Aktiengesellschaft Preparation of acrylates and methacrylates
DE3740037A1 (de) 1987-11-26 1989-06-08 Basf Ag Neue di(meth)acrylate, verfahren zu deren herstellung und deren verwendung
JPH01180861A (ja) * 1988-01-11 1989-07-18 Sanyo Chem Ind Ltd アクリル系モノマーの製造法
JPH0217155A (ja) 1988-07-06 1990-01-22 Toagosei Chem Ind Co Ltd ジアルキルアミノアルキル（メタ）アクリレートの製造方法
US5037978A (en) 1990-03-12 1991-08-06 Rohm And Haas Company Hafnium-catalyzed transesterification
DE4227299C1 (de) 1992-08-18 1994-01-27 Hoechst Ag Verfahren zur Herstellung von monomeren Terephthalsäurediestern und Diolen aus Polyestern
FR2707290B1 (fr) 1993-07-06 1995-09-01 Atochem Elf Sa Procédé de préparation de l'acrylate ou du méthacrylate d'éthylthioéthyle à l'aide d'acétylacétonate de zirconium comme catalyseur.
FR2727112B1 (fr) * 1994-11-18 1996-12-20 Atochem Elf Sa Procede de preparation de (meth)acrylates d'alkylimidazolidone
EP0837049B1 (en) 1996-10-17 2002-07-31 Rohm And Haas Company A process for preparing monomers
AU743962B2 (en) * 1997-08-29 2002-02-14 Rohm And Haas Company Transesterification process
JPH11158261A (ja) * 1997-12-01 1999-06-15 Mitsubishi Chemical Corp 芳香族ポリカーボネート樹脂の製造方法
US5840957A (en) 1998-03-16 1998-11-24 E. I. Du Pont De Nemours And Company Transesterification process using lanthanum compound catalyst
AT408882B (de) 1998-08-07 2002-03-25 Dsm Fine Chem Austria Gmbh Verfahren zur umesterung von alpha-ketocarbonsäureestern
US6350895B1 (en) 1999-03-26 2002-02-26 E. I. Du Pont De Nemours And Company Transesterification process using yttrium and samarium compound catalystis
DE10008901B4 (de) 2000-02-25 2009-01-29 Evonik Degussa Gmbh Verfahren zur Herstellung von Malonsäurediestern durch kontinuierliche Umesterung
DE10145228A1 (de) 2001-09-13 2003-04-24 Roehm Gmbh Synthese von t-Butylaminoethylmethacrylat durch Umesterung des Alkohols mit MMA
JP2004010551A (ja) 2002-06-07 2004-01-15 Nippon Shokubai Co Ltd ビニルエーテル基含有（メタ）アクリル酸エステル類の製造方法
DE10321149A1 (de) 2003-05-12 2004-12-02 Bayer Materialscience Ag Ytterbium(III)acetylacetonat als Katalysator zur Herstellung von aliphatischen Oligocarbonatpolyolen
US6971614B2 (en) 2003-07-11 2005-12-06 Jifram Extrusions, Inc. Slatwall hanger stabilizing chip
GB0324964D0 (en) * 2003-10-27 2003-11-26 Great Lakes Chemical Europ Preparation of hydroxyphenyl carboxylic acid esters
JP4336961B2 (ja) 2003-10-31 2009-09-30 三菱瓦斯化学株式会社 ２−メチル−２−ヒドロキシ−１−プロピル（メタ）アクリレートの製造方法
DE102004042843A1 (de) * 2004-09-04 2006-03-09 Bayer Materialscience Ag Metallacetylacetonate als Umesterungskatalysatoren
DE102007031468A1 (de) 2007-07-05 2009-01-08 Evonik Röhm Gmbh Verfahren zur Herstellung von Allylmethacrylat
DE102008043810A1 (de) 2007-11-20 2009-05-28 Basf Se Verfahren zur Herstellung von (Meth)acrylsäureestern von Prenol und Isoprenol
FR2949779B1 (fr) 2009-09-07 2011-09-09 Arkema France Procede de preparation de (meth)acrylates d'alkylimidazolidone

Also Published As

Publication number Publication date
WO2011157645A2 (en) 2011-12-22
JP5916722B2 (ja) 2016-05-11
EP2582453B1 (en) 2016-12-28
RS55808B1 (sr) 2017-08-31
MX2012014722A (es) 2013-04-11
JP2013533861A (ja) 2013-08-29
EP2582453A2 (en) 2013-04-24
US20130090492A1 (en) 2013-04-11
CN103140287B (zh) 2016-08-03
KR20140002591A (ko) 2014-01-08
KR101863154B1 (ko) 2018-07-04
GB201009969D0 (en) 2010-07-21
WO2011157645A3 (en) 2012-10-18
BR112012031918B1 (pt) 2019-07-02
CN103140287A (zh) 2013-06-05
US8865931B2 (en) 2014-10-21
BR112012031918A2 (pt) 2016-11-08

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