KR101863154B1 - 혼합된 염 아세틸아세토네이트 촉매를 이용한 에스터교환 방법 - Google Patents

혼합된 염 아세틸아세토네이트 촉매를 이용한 에스터교환 방법 Download PDF

Info

Publication number
KR101863154B1
KR101863154B1 KR1020137000243A KR20137000243A KR101863154B1 KR 101863154 B1 KR101863154 B1 KR 101863154B1 KR 1020137000243 A KR1020137000243 A KR 1020137000243A KR 20137000243 A KR20137000243 A KR 20137000243A KR 101863154 B1 KR101863154 B1 KR 101863154B1
Authority
KR
South Korea
Prior art keywords
alkyl
catalyst
group
alcohol
phenyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020137000243A
Other languages
English (en)
Korean (ko)
Other versions
KR20140002591A (ko
Inventor
토마스 피터 안느 구센스
프릭 애니 카미엘 브리에린크
노엘 가브리엘 코넬리우스 호스텐
코엔 잔느 알폰스 반 아켄
Original Assignee
에코신스 비브이비에이
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 에코신스 비브이비에이 filed Critical 에코신스 비브이비에이
Publication of KR20140002591A publication Critical patent/KR20140002591A/ko
Application granted granted Critical
Publication of KR101863154B1 publication Critical patent/KR101863154B1/ko
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C68/00—Preparation of esters of carbonic or haloformic acids
    • C07C68/06—Preparation of esters of carbonic or haloformic acids from organic carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/49—Esterification or transesterification
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
KR1020137000243A 2010-06-15 2011-06-10 혼합된 염 아세틸아세토네이트 촉매를 이용한 에스터교환 방법 Expired - Fee Related KR101863154B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB201009969A GB201009969D0 (en) 2010-06-15 2010-06-15 Transesterification process using mixed salt acetylacetonates catalysts
GB1009969.5 2010-06-15
PCT/EP2011/059672 WO2011157645A2 (en) 2010-06-15 2011-06-10 Transesterification process using mixed salt acetylacetonates catalysts

Publications (2)

Publication Number Publication Date
KR20140002591A KR20140002591A (ko) 2014-01-08
KR101863154B1 true KR101863154B1 (ko) 2018-07-04

Family

ID=42471652

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020137000243A Expired - Fee Related KR101863154B1 (ko) 2010-06-15 2011-06-10 혼합된 염 아세틸아세토네이트 촉매를 이용한 에스터교환 방법

Country Status (10)

Country Link
US (1) US8865931B2 (https=)
EP (1) EP2582453B1 (https=)
JP (1) JP5916722B2 (https=)
KR (1) KR101863154B1 (https=)
CN (1) CN103140287B (https=)
BR (1) BR112012031918B1 (https=)
GB (1) GB201009969D0 (https=)
MX (1) MX341537B (https=)
RS (1) RS55808B1 (https=)
WO (1) WO2011157645A2 (https=)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9150673B2 (en) * 2011-07-06 2015-10-06 Basf Se Process for preparing (meth)acrylic esters
CN105233874B (zh) * 2013-11-07 2017-07-14 山东科技大学 一步法制备卟啉功能化纳米硫化锌的工艺
KR20160107181A (ko) * 2013-12-26 2016-09-13 다우 글로벌 테크놀로지스 엘엘씨 리튬 염-촉매된 트랜스에스테르화 공정용 억제제 배합물 및 리튬 염의 제거방법
JP6643546B2 (ja) * 2015-03-10 2020-02-12 東亞合成株式会社 （メタ）アクリレートの製造方法
JP6633612B2 (ja) * 2015-03-12 2020-01-22 株式会社クラレ （メタ）アクリル酸エステル化合物の製造方法
EP3072879A1 (en) 2015-03-26 2016-09-28 Nitto Europe N.V Method for prevention of premature polymerization
JP6809043B2 (ja) * 2015-09-03 2021-01-06 東亞合成株式会社 単官能（メタ）アクリレートの製造方法
CN105330537A (zh) * 2015-11-30 2016-02-17 抚顺东联安信化学有限公司 丙烯酸甲氧基乙酯的制备方法
US10704262B2 (en) 2016-09-26 2020-07-07 U.S. Silica Company Self-cleaning cool roof system
CN109890483B (zh) * 2016-11-09 2022-03-01 株式会社可乐丽 氧吸收剂
JP6828500B2 (ja) * 2017-02-21 2021-02-10 三菱瓦斯化学株式会社 ２−メチル−２−ヒドロキシ−１−プロピル（メタ）アクリレートおよび／または３−メチル−３−ヒドロキシ−１−ブチル（メタ）アクリレートの製造方法ならびに組成物
TWI796324B (zh) * 2017-03-09 2023-03-21 日商東亞合成股份有限公司 (甲基)丙烯酸酯的製造方法
JP6991236B2 (ja) * 2017-10-24 2022-02-10 信越化学工業株式会社 ラジカル重合性オルガノポリシロキサンの製造方法、放射線硬化性オルガノポリシロキサン組成物、及び剥離シート
EP3778554B1 (en) 2018-04-12 2024-02-07 SNF Group Method for producing 2-dimethylaminoethyl (meth)acrylate
CN109748826B (zh) * 2018-12-28 2021-09-21 京博农化科技有限公司 一种茚虫威中间体肼基甲酸苄酯的合成方法
CN113348199B (zh) 2018-12-31 2023-02-17 美国陶氏有机硅公司 支链有机硅化合物、制备支链有机硅化合物的方法以及用其形成的共聚物
US12215198B2 (en) 2018-12-31 2025-02-04 Dow Silicones Corporation Branched organosilicon compound, method of preparing same, and compositions comprising same
CN113330054B (zh) 2018-12-31 2023-02-21 美国陶氏有机硅公司 支链有机硅化合物、其制备方法以及用其形成的共聚物
JP7561738B2 (ja) 2018-12-31 2024-10-04 ダウ シリコーンズ コーポレーション 組成物、コポリマーの調製方法、並びにその方法及び最終用途
EP3906244A1 (en) 2018-12-31 2021-11-10 Dow Silicones Corporation Method of preparing acryloxy-functional organosilicon compounds
EP3906274A1 (en) 2018-12-31 2021-11-10 Dow Silicones Corporation Acrylate-functional branched organosilicon compound, method of preparing same, and copolymer formed therewith
US12269833B2 (en) 2018-12-31 2025-04-08 Dow Silicones Corporation Branched organosilicon compound, method of preparing same, and compositions comprising same
CN113661195B (zh) * 2019-04-11 2025-05-30 株式会社可乐丽 聚合物、使用了该聚合物的氧吸收剂、及固化性组合物
CN110252396B (zh) * 2019-06-27 2022-03-11 山东第一医科大学(山东省医学科学院) 一种用于间苯二甲酸二甲酯-5-磺酸钠合成过程中的催化剂、制备方法及应用
WO2022220543A1 (ko) * 2021-04-12 2022-10-20 한국화학연구원 디메틸테레프탈레이트의 에스테르 교환 반응에 의한 테레프탈레이트 유도체 제조 방법
KR102480102B1 (ko) * 2021-05-14 2022-12-23 한국화학연구원 아크릴계 그라디언트 공중합체의 제조방법
AU2022329947A1 (en) 2021-08-16 2024-03-28 Rohm And Haas Company Preparation of ureido methacrylate
EP4467591A4 (en) * 2022-01-18 2025-04-16 Asahi Kasei Kabushiki Kaisha PROCESS FOR PRODUCING POLYCARBONATE DIOL, POLYCARBONATE DIOL, AND TRANSESTERIFICATION CATALYST
JP2024008235A (ja) * 2022-07-07 2024-01-19 旭化成株式会社 エステル交換触媒
CN120025247B (zh) * 2025-04-23 2025-07-04 抚顺东联安信化学有限公司 一种酯交换生产甲基丙烯酸正癸酯的方法

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2845451A (en) * 1955-06-23 1958-07-29 Basf Ag Production of acrylic acid and its functional derivatives
US3528946A (en) 1967-08-30 1970-09-15 Fmc Corp Acetylacetonates as polycondensation catalysts in transesterification method of preparing polyesters
US3532671A (en) 1967-08-30 1970-10-06 Fmc Corp Acetylacetonate transesterification catalysts
US3528945A (en) 1967-08-30 1970-09-15 Fmc Corp Acetylacetonates as polycondensation catalysts in the direct esterification method of preparing polyesters
JPS491531A (https=) * 1972-04-28 1974-01-08
GB1573071A (en) 1977-02-10 1980-08-13 Mitsubishi Rayon Co Process for producing unsaturated carbocylic acid esters
JPS603292B2 (ja) 1977-02-28 1985-01-26 三菱レイヨン株式会社 アクリル酸エステルまたはメタクリル酸エステルの製造法
US4375361A (en) 1980-03-24 1983-03-01 Suntech, Inc. Process for making a high octane fuel component
JPS57183745A (en) * 1981-05-06 1982-11-12 Asahi Chem Ind Co Ltd Production of carbonic ester
US4777265A (en) 1986-03-11 1988-10-11 Basf Aktiengesellschaft Preparation of acrylates and methacrylates
DE3740037A1 (de) 1987-11-26 1989-06-08 Basf Ag Neue di(meth)acrylate, verfahren zu deren herstellung und deren verwendung
JPH01180861A (ja) * 1988-01-11 1989-07-18 Sanyo Chem Ind Ltd アクリル系モノマーの製造法
JPH0217155A (ja) 1988-07-06 1990-01-22 Toagosei Chem Ind Co Ltd ジアルキルアミノアルキル（メタ）アクリレートの製造方法
US5037978A (en) 1990-03-12 1991-08-06 Rohm And Haas Company Hafnium-catalyzed transesterification
DE4227299C1 (de) 1992-08-18 1994-01-27 Hoechst Ag Verfahren zur Herstellung von monomeren Terephthalsäurediestern und Diolen aus Polyestern
FR2707290B1 (fr) 1993-07-06 1995-09-01 Atochem Elf Sa Procédé de préparation de l'acrylate ou du méthacrylate d'éthylthioéthyle à l'aide d'acétylacétonate de zirconium comme catalyseur.
FR2727112B1 (fr) * 1994-11-18 1996-12-20 Atochem Elf Sa Procede de preparation de (meth)acrylates d'alkylimidazolidone
DE69714373T2 (de) 1996-10-17 2003-02-13 Rohm And Haas Co., Philadelphia Verfahren zum Herstellen von Monomeren
AU743962B2 (en) 1997-08-29 2002-02-14 Rohm And Haas Company Transesterification process
JPH11158261A (ja) * 1997-12-01 1999-06-15 Mitsubishi Chemical Corp 芳香族ポリカーボネート樹脂の製造方法
US5840957A (en) 1998-03-16 1998-11-24 E. I. Du Pont De Nemours And Company Transesterification process using lanthanum compound catalyst
AT408882B (de) 1998-08-07 2002-03-25 Dsm Fine Chem Austria Gmbh Verfahren zur umesterung von alpha-ketocarbonsäureestern
US6350895B1 (en) 1999-03-26 2002-02-26 E. I. Du Pont De Nemours And Company Transesterification process using yttrium and samarium compound catalystis
DE10008901B4 (de) 2000-02-25 2009-01-29 Evonik Degussa Gmbh Verfahren zur Herstellung von Malonsäurediestern durch kontinuierliche Umesterung
DE10145228A1 (de) 2001-09-13 2003-04-24 Roehm Gmbh Synthese von t-Butylaminoethylmethacrylat durch Umesterung des Alkohols mit MMA
JP2004010551A (ja) 2002-06-07 2004-01-15 Nippon Shokubai Co Ltd ビニルエーテル基含有（メタ）アクリル酸エステル類の製造方法
DE10321149A1 (de) 2003-05-12 2004-12-02 Bayer Materialscience Ag Ytterbium(III)acetylacetonat als Katalysator zur Herstellung von aliphatischen Oligocarbonatpolyolen
US6971614B2 (en) 2003-07-11 2005-12-06 Jifram Extrusions, Inc. Slatwall hanger stabilizing chip
GB0324964D0 (en) * 2003-10-27 2003-11-26 Great Lakes Chemical Europ Preparation of hydroxyphenyl carboxylic acid esters
JP4336961B2 (ja) 2003-10-31 2009-09-30 三菱瓦斯化学株式会社 ２−メチル−２−ヒドロキシ−１−プロピル（メタ）アクリレートの製造方法
DE102004042843A1 (de) * 2004-09-04 2006-03-09 Bayer Materialscience Ag Metallacetylacetonate als Umesterungskatalysatoren
DE102007031468A1 (de) 2007-07-05 2009-01-08 Evonik Röhm Gmbh Verfahren zur Herstellung von Allylmethacrylat
DE102008043810A1 (de) 2007-11-20 2009-05-28 Basf Se Verfahren zur Herstellung von (Meth)acrylsäureestern von Prenol und Isoprenol
FR2949779B1 (fr) 2009-09-07 2011-09-09 Arkema France Procede de preparation de (meth)acrylates d'alkylimidazolidone

Also Published As

Publication number Publication date
RS55808B1 (sr) 2017-08-31
GB201009969D0 (en) 2010-07-21
CN103140287A (zh) 2013-06-05
US8865931B2 (en) 2014-10-21
EP2582453B1 (en) 2016-12-28
JP2013533861A (ja) 2013-08-29
CN103140287B (zh) 2016-08-03
JP5916722B2 (ja) 2016-05-11
MX341537B (es) 2016-08-24
BR112012031918B1 (pt) 2019-07-02
US20130090492A1 (en) 2013-04-11
WO2011157645A2 (en) 2011-12-22
MX2012014722A (es) 2013-04-11
KR20140002591A (ko) 2014-01-08
EP2582453A2 (en) 2013-04-24
WO2011157645A3 (en) 2012-10-18
BR112012031918A2 (pt) 2016-11-08

Similar Documents

Publication Publication Date Title
KR101863154B1 (ko) 혼합된 염 아세틸아세토네이트 촉매를 이용한 에스터교환 방법
US8067633B2 (en) Method for the synthesis of (meth)acrylic esters catalysed by a polyol titanate
JP5575883B2 (ja) ジアルキル酸化錫を含む組成物と、その（メタ）アクリル酸エステル合成のエステル交換触媒としての使用
AU2720088A (en) High yield method for preparation of dialkyl esters of polyhaloaromatic acids
CN101186568B (zh) 制备(甲基)丙烯酸的方法
US5037978A (en) Hafnium-catalyzed transesterification
CN108350158A (zh) 3-羟基丙酸酯和丙烯酸的制备
JP2009515914A5 (https=)
JP4042212B2 (ja) ヒドロキシアルキルモノアクリレートの製造方法
JPH0747563B2 (ja) ビニルエステルの合成
JPWO2013133377A1 (ja) ラクチドの製造方法
RU2656338C1 (ru) Способ получения сложных эфиров карбоновых кислот в присутствии титансодержащего катализатора
JP2015145345A (ja) 環状α−ヒドロキシカルボン酸２量体エステルの製造方法
JP4656351B2 (ja) エステル交換反応によるエステルの製造方法
CN105330556A (zh) 一种丙烯酸二甲氨基乙酯的制备方法及其催化剂
JP3261730B2 (ja) アリルエステル類の製法
JP5167483B2 (ja) エステル化合物の製造方法
JP3264154B2 (ja) シュウ酸アリールエステルの製法
JP2010505780A (ja) γ−ブチロラクトンの調製のための方法
JPS5842861B2 (ja) アクリル酸エステル又はメタクリル酸エステルの製造法
MXPA06001071A (en) Transesterification process for production of (meth)acrylate ester monomers

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

D13-X000 Search requested

St.27 status event code: A-1-2-D10-D13-srh-X000

D14-X000 Search report completed

St.27 status event code: A-1-2-D10-D14-srh-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

FPAY Annual fee payment

Payment date: 20210513

Year of fee payment: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20220526

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20220526