CN101068845B - 组合物、固化物和物品 - Google Patents
组合物、固化物和物品 Download PDFInfo
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- CN101068845B CN101068845B CN2005800411741A CN200580041174A CN101068845B CN 101068845 B CN101068845 B CN 101068845B CN 2005800411741 A CN2005800411741 A CN 2005800411741A CN 200580041174 A CN200580041174 A CN 200580041174A CN 101068845 B CN101068845 B CN 101068845B
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- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- 238000006276 transfer reaction Methods 0.000 description 1
- 125000005369 trialkoxysilyl group Chemical group 0.000 description 1
- 125000005409 triarylsulfonium group Chemical group 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 description 1
- PZJJKWKADRNWSW-UHFFFAOYSA-N trimethoxysilicon Chemical group CO[Si](OC)OC PZJJKWKADRNWSW-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/22—Esters containing halogen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/22—Esters containing halogen
- C08F220/24—Esters containing halogen containing perhaloalkyl radicals
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
- C08F220/325—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals containing glycidyl radical, e.g. glycidyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/442—Block-or graft-polymers containing polysiloxane sequences containing vinyl polymer sequences
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L43/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Compositions of derivatives of such polymers
- C08L43/04—Homopolymers or copolymers of monomers containing silicon
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/10—Block or graft copolymers containing polysiloxane sequences
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
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- Chemical & Material Sciences (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
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- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Epoxy Resins (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
雾度值(%) | 铅笔硬度 | 接触角(水/度) | 接触角(十六烷/度) | 粘附性 | |
实施例1 | 1.0 | H | 111 | 53 | ○ |
实施例2 | 1.1 | F | 109 | 46 | ○ |
实施例3 | 1.1 | 2H | 111 | 43 | ○ |
实施例4 | 1.1 | H | 110 | 62 | ○ |
实施例5 | 1.1 | F | 94 | 9 | ○ |
比较例1 | 1.1 | 5B | 108 | 66 | ○ |
比较例2 | 1.1 | 2B | 104 | 62 | ○ |
比较例3 | 1.1 | F | 71 | 4 | ○ |
比较例4 | 1.1 | H | 78 | 22 | ○ |
比较例7 | 1.1 | B | 108 | 37 | ○ |
实施例6 | 1.0 | 2H | 111 | 52 | ○ |
实施例7 | 1.1 | 2H | 110 | 52 | ○ |
雾度值(%) | 铅笔硬度 | 接触角(水/度) | 接触角(十六烷/度) | 粘附性 | |
实施例8 | 0.4 | H | 110 | 55 | ○ |
实施例9 | 1.0 | 2H | 110 | 51 | ○ |
实施例10 | 0.3 | H | 110 | 53 | ○ |
实施例11 | 1.0 | 3H | 110 | 52 | ○ |
实施例12 | 1.1 | 2H | 111 | 44 | ○ |
实施例13 | 0.4 | H | 109 | 45 | ○ |
实施例14 | 1.1 | 2H | 109 | 45 | ○ |
实施例15 | 0.3 | H | 109 | 44 | ○ |
实施例16 | 1.0 | 3H | 93 | 9 | ○ |
实施例17 | 0.6 | F | 110 | 43 | ○ |
比较例5 | 1.1 | H | 104 | 63 | ○ |
比较例6 | 1.1 | H | 110 | 61 | ○ |
指纹擦除性(1-1) | 指纹擦除性(1-50) | 指纹擦除性(2) | 指纹擦除耐久性 | 擦除感 | |
实施例1 | 1 | 1 | 1.5 | ○ | ○ |
实施例2 | 1.5 | 1.5 | 1.5 | ○ | ○ |
实施例3 | 1.5 | 1.5 | 1.5 | ○ | ○ |
实施例4 | 1 | 1 | 1.5 | ○ | ○ |
实施例5 | 1 | 1 | 1.5 | ○ | ○ |
实施例6 | 1.5 | 1.5 | 1.5 | ○ | ○ |
实施例7 | 2 | 2 | 2 | ○ | ○ |
实施例8 | 2 | 2 | 2 | ○ | ○ |
实施例9 | 2 | 2 | 2 | ○ | ○ |
实施例10 | 2 | 2 | 2 | ○ | ○ |
实施例11 | 1.5 | 1.5 | 1.5 | ○ | ○ |
实施例12 | 2 | 2 | 2 | ○ | ○ |
实施例13 | 2 | 2 | 2 | ○ | ○ |
实施例14 | 2 | 2 | 2 | ○ | ○ |
实施例15 | 2 | 2 | 2 | ○ | ○ |
实施例16 | 1.5 | 1.5 | 1.5 | ○ | ○ |
实施例17 | 2 | 2 | 2 | ○ | ○ |
比较例1 | 6 | 8 | 10 | × | △ |
比较例2 | 2.5 | 5 | 6 | × | △ |
指纹擦除性(1-1) | 指纹擦除性(1-50) | 指纹擦除性(2) | 指纹擦除耐久性 | 擦除感 | |
比较例3 | 8 | 10 | 10 | × | × |
比较例4 | 5 | 6 | 8 | × | ○ |
比较例5 | 4 | 7 | 6 | × | △ |
比较例6 | 4 | 6 | 6 | × | △ |
比较例7 | 4 | 7 | 8 | × | ○ |
成分(A)或其它聚合物 | 成分(Bi) | 成分(Bii) | 成分(C) | 成分(D) | (A)或聚合物/B1/B2/C/D(质量比) | 涂布液浓度(质量%) | |
实施例18 | a-3 | b-4 | - | - | I184 | 5/95/0/0/2 | 30 |
实施例19 | a-3 | b-4 | DPHA | - | I184 | 5/45/50/0/2 | 30 |
实施例20 | a-2 | b-4 | - | I250 | I184 | 5/95/0/2/2 | 30 |
实施例21 | a-3 | - | DPHA | - | I184 | 5/0/95/0/2 | 30 |
比较例8 | X-22-164A | b-4 | - | - | I184 | 0.3/100/0/0/2 | 30 |
比较例9 | X-22-164B | b-4 | - | - | I184 | 3/97/0/0/2 | 30 |
比较例10 | KF-412 | b-4 | - | - | I184 | 3/97/0/0/2 | 30 |
比较例11 | KF945A | b-4 | - | - | I184 | 3/97/0/0/2 | 30 |
透明性 | 铅笔硬度 | 接触角(水/度) | 接触角(十六烷/度) | 粘附性 | 人工指纹液耐附着性 | 人工指纹液擦除性 | 人工指纹液擦除耐久性 | 滑爽性(动摩擦系数) | |
实施例18 | ○ | F | 109 | 47 | ○ | L4 | 2 | ○ | >1.0 |
透明性 | 铅笔硬度 | 接触角(水/度) | 接触角(十六烷/度) | 粘附性 | 人工指纹液耐附着性 | 人工指纹液擦除性 | 人工指纹液擦除耐久性 | 滑爽性(动摩擦系数) | |
实施例19 | ○ | F | 108 | 49 | ○ | L4 | 2 | ○ | >1.0 |
实施例20 | ○ | F | 108 | 50 | ○ | L4 | 2 | ○ | >1.0 |
实施例21 | ○ | F | 109 | 51 | ○ | L4 | 2 | ○ | >1.0 |
比较例8 | ○ | F | 102 | 38 | ○ | L4 | 3.5 | × | 0.8 |
比较例9 | △ | F | 106 | 33 | ○ | L3 | 4 | × | 0.3 |
比较例10 | △ | F | 105 | 33 | ○ | L3 | 4 | × | 0.1 |
比较例11 | △ | F | 106 | 34 | ○ | L3 | 6 | × | 0.5 |
接触角(水/度) | 接触角(十六烷/度) | 人工指纹液耐附着性 | 人工指纹液擦除性 | 人工指纹液擦除耐久性 | |
参考例1 | 96 | 44 | L4 | 3.5 | × |
参考例2 | 101 | 41 | L4 | 4 | × |
参考例3 | 100 | 37 | L4 | 3.5 | × |
Claims (46)
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JP2004350658 | 2004-12-03 | ||
PCT/JP2005/022150 WO2006059702A1 (ja) | 2004-12-03 | 2005-12-02 | 組成物、硬化物および物品 |
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US (1) | US8017211B2 (zh) |
JP (1) | JP4872670B2 (zh) |
KR (1) | KR101215805B1 (zh) |
CN (1) | CN101068845B (zh) |
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US20100129587A1 (en) | 2010-05-27 |
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JP4872670B2 (ja) | 2012-02-08 |
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