CN100339421C - 碳纤维增强树脂复合材料 - Google Patents

碳纤维增强树脂复合材料 Download PDF

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Publication number
CN100339421C
CN100339421C CNB2004800031004A CN200480003100A CN100339421C CN 100339421 C CN100339421 C CN 100339421C CN B2004800031004 A CNB2004800031004 A CN B2004800031004A CN 200480003100 A CN200480003100 A CN 200480003100A CN 100339421 C CN100339421 C CN 100339421C
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CN
China
Prior art keywords
carbon fiber
resin
epoxy
vinyl ester
mass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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CNB2004800031004A
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English (en)
Chinese (zh)
Other versions
CN1745127A (zh
Inventor
铃木庆宜
三浦裕
堀越桂
矢田光广
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resonac Holdings Corp
Original Assignee
Showa Highpolymer Co Ltd
Toho Tenax Co Ltd
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Application filed by Showa Highpolymer Co Ltd, Toho Tenax Co Ltd filed Critical Showa Highpolymer Co Ltd
Publication of CN1745127A publication Critical patent/CN1745127A/zh
Application granted granted Critical
Publication of CN100339421C publication Critical patent/CN100339421C/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/243—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
    • C08G59/1455—Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
    • C08G59/1461—Unsaturated monoacids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
    • C08G59/1455—Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
    • C08G59/1461—Unsaturated monoacids
    • C08G59/1466—Acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/248—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using pre-treated fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0025—Crosslinking or vulcanising agents; including accelerators
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
    • C08K5/3445—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Emergency Medicine (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Reinforced Plastic Materials (AREA)
  • Epoxy Resins (AREA)
CNB2004800031004A 2003-01-30 2004-01-28 碳纤维增强树脂复合材料 Expired - Lifetime CN100339421C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2003022384 2003-01-30
JP22384/2003 2003-01-30

Publications (2)

Publication Number Publication Date
CN1745127A CN1745127A (zh) 2006-03-08
CN100339421C true CN100339421C (zh) 2007-09-26

Family

ID=32820688

Family Applications (1)

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CNB2004800031004A Expired - Lifetime CN100339421C (zh) 2003-01-30 2004-01-28 碳纤维增强树脂复合材料

Country Status (7)

Country Link
US (1) US7585558B2 (https=)
EP (1) EP1589063B1 (https=)
JP (1) JP4695510B2 (https=)
KR (1) KR100938789B1 (https=)
CN (1) CN100339421C (https=)
TW (1) TW200416245A (https=)
WO (1) WO2004067612A1 (https=)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005247879A (ja) * 2004-03-01 2005-09-15 Showa Highpolymer Co Ltd 繊維強化複合材料用組成物及びその成形材料
JP4863630B2 (ja) * 2004-12-10 2012-01-25 Ａｇｃマテックス株式会社 炭素繊維強化樹脂
JP2007051183A (ja) * 2005-08-16 2007-03-01 Showa Highpolymer Co Ltd 炭素繊維強化複合材料およびその成形物
JPWO2007060833A1 (ja) * 2005-11-25 2009-05-07 東レ株式会社 炭素繊維束、プリプレグおよび炭素繊維強化複合材料
JP4231916B2 (ja) * 2006-04-28 2009-03-04 日信工業株式会社 炭素繊維複合樹脂材料の製造方法
JP4887323B2 (ja) 2007-05-22 2012-02-29 三洋化成工業株式会社 繊維用集束剤
NO20073832L (no) * 2007-07-20 2009-01-21 Fmc Kongsberg Subsea As Komposittkabel
DE102008021830A1 (de) * 2008-04-30 2009-11-12 Emil Frei Gmbh & Co. Kg Anodisches Tauchlacksystem
KR101294713B1 (ko) * 2009-08-17 2013-08-08 디아이씨 가부시끼가이샤 섬유 강화 복합 재료용 수지 조성물, 그 경화물, 섬유 강화 복합 재료, 섬유 강화 수지 성형품, 및 그 제조 방법
WO2011030784A1 (ja) * 2009-09-09 2011-03-17 三菱レイヨン株式会社 炭素繊維束及びその製造方法
US20110281063A1 (en) * 2009-11-20 2011-11-17 E. I. Du Pont De Nemours And Company Honeycomb core based on carbon fiber paper and articles made from same
GB2476115B8 (en) * 2009-12-14 2014-07-23 Gurit Uk Ltd Prepregs for manufacturing composite materials
CN103013041B (zh) * 2010-02-09 2016-08-03 上纬企业股份有限公司 一种环氧树脂组成物
CN102181140B (zh) * 2011-03-24 2012-07-04 北京化工大学 一种碳纤维废丝增强聚碳酸酯复合材料及其制备方法
CN102504488A (zh) * 2011-11-02 2012-06-20 上海交通大学 一种球-棒状短碳纤维增强环氧树脂基复合材料的制备方法
BR112014015754A8 (pt) * 2011-12-27 2017-07-04 Toray Industries fibras de carbono revestidas com agente de colagem, processo de produção das fibras de carbono, pré-impregnado e material compósito reforçado com fibras de carbono
CN103223756A (zh) * 2012-01-31 2013-07-31 廖树汉 一种能锯钻耐冲击的防火塑玻板
WO2014004998A1 (en) * 2012-06-28 2014-01-03 Henkel Ag & Co Kgaa A method of manufacturing a composite insert
CN104487495B (zh) 2012-07-25 2016-09-07 东丽株式会社 预浸料坯及碳纤维增强复合材料
JP6245630B2 (ja) * 2013-04-12 2017-12-13 コイト電工株式会社 車両用内装材
JP5730457B1 (ja) * 2013-09-27 2015-06-10 松本油脂製薬株式会社 強化繊維用サイジング剤及びその用途
DE102014207785A1 (de) * 2014-04-25 2015-10-29 Evonik Degussa Gmbh Verfahren zur Herstellung von lagerstabilen Epoxy-Prepregs und daraus hergestellte Composites auf Basis von radikalisch polymerisierbaren Säuren und Epoxiden
EP3026076B1 (en) 2014-11-27 2018-10-17 Polynt Composites France Vinyl ester powder pre-preg
JP6718737B2 (ja) * 2016-05-12 2020-07-08 ジャパンコンポジット株式会社 炭素繊維束の開繊装置
US11884591B2 (en) * 2016-08-26 2024-01-30 The Boeing Company Permeable pavement and cured carbon fiber composition and a related method
CN115453112B (zh) * 2017-03-28 2025-09-09 电化株式会社 膜载体和使用其的液体试样检测试剂盒
JP7009022B2 (ja) * 2017-05-23 2022-01-25 ジャパンコンポジット株式会社 炭素繊維強化シート状成形材料、その製造方法及び成形品
US20240002612A1 (en) * 2020-12-02 2024-01-04 Toray Industries, Inc. Fiber-reinforced pultrusion-molded article
EP4352140A1 (en) * 2021-08-02 2024-04-17 Gurit (UK) Ltd. Composite material layer and manufacture of sandwich panels
GB2609461A (en) * 2021-08-02 2023-02-08 Gurit Uk Ltd Polymerisable resin film
CN114057992A (zh) * 2021-11-02 2022-02-18 上纬新材料科技股份有限公司 一种可用于碳纤维模压的树脂组成物
CN115558065A (zh) * 2022-09-16 2023-01-03 华东理工大学华昌聚合物有限公司 一种碳纤维用环氧乙烯基酯树脂、预聚物及制备方法
CN115850764A (zh) * 2022-12-14 2023-03-28 安徽弘昌新材料股份有限公司 一种碳纤维复合材料生产用耐高温预浸料及其制备方法
CN116200941A (zh) * 2022-12-15 2023-06-02 深圳航天科技创新研究院 一种碳纤维用可回收型树脂上浆剂及其制备和应用
CN116178896B (zh) * 2023-03-06 2025-09-09 威海蓝科复合材料科技有限公司 一种高耐磨碳纤维预浸料及其制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5673174A (en) * 1979-11-19 1981-06-17 Mitsubishi Rayon Co Sizing of carbon fiber

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5828454B2 (ja) 1980-11-04 1983-06-16 大日本インキ化学工業株式会社 耐疲労特性に優れる自動車用ｆｒｐ板ばね
JPS62225537A (ja) * 1986-03-27 1987-10-03 Showa Highpolymer Co Ltd 繊維強化樹脂用硬化性組成物
JPS63105178A (ja) 1986-10-21 1988-05-10 東燃料株式会社 炭素繊維用サイジング剤
JPH0540768A (ja) 1991-08-05 1993-02-19 Hokuriku Nippon Denki Software Kk 処方データ入力装置
JPH06218671A (ja) 1993-01-20 1994-08-09 Mazda Motor Corp 塗膜研磨方法およびその装置
JP2624120B2 (ja) 1993-06-11 1997-06-25 日本電気株式会社 監視データ付け替え回路
JP3593760B2 (ja) * 1995-10-17 2004-11-24 東レ株式会社 繊維強化プラスチック成形品
JP3630380B2 (ja) * 1995-11-01 2005-03-16 三菱レイヨン株式会社 既存構造物の補修補強方法
JP3905957B2 (ja) * 1997-08-11 2007-04-18 日工株式会社 アスファルト合材製造装置
JP3755255B2 (ja) 1997-09-16 2006-03-15 東レ株式会社 炭素繊維およびその製造方法
TW467940B (en) * 1997-10-14 2001-12-11 Toray Industries Thermosetting resin composition for carbon-fiber reinforced composite material
JP3713164B2 (ja) 1999-06-16 2005-11-02 三菱レイヨン株式会社 炭素繊維用サイジング剤、炭素繊維用サイジング剤溶液、炭素繊維およびそれを用いた炭素繊維シート状物並びに炭素繊維強化樹脂組成物
JP4558149B2 (ja) 2000-06-29 2010-10-06 三菱レイヨン株式会社 炭素繊維用サイズ剤、炭素繊維のサイジング方法、サイジング処理された炭素繊維並びにそれを含むシート状物及び繊維強化複合材料
TW591157B (en) 2001-05-25 2004-06-11 Mitsubishi Rayon Co Sizing agent for carbon fiber, its water dispersing solution, carbon fiber with sizing handling, sheet matter with using the carbon fiber and carbon fiber reinforced composite
JP2003292633A (ja) 2002-03-29 2003-10-15 Toho Tenax Co Ltd 炭素繊維ストランド、及び炭素繊維強化不飽和マトリックス樹脂
KR20050071371A (ko) * 2002-10-31 2005-07-07 도호 테낙구스 가부시키가이샤 탄소 섬유 스트랜드

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5673174A (en) * 1979-11-19 1981-06-17 Mitsubishi Rayon Co Sizing of carbon fiber

Also Published As

Publication number Publication date
US20060154039A1 (en) 2006-07-13
EP1589063B1 (en) 2014-06-18
KR20050096966A (ko) 2005-10-06
TW200416245A (en) 2004-09-01
JPWO2004067612A1 (ja) 2006-05-18
EP1589063A4 (en) 2006-02-01
KR100938789B1 (ko) 2010-01-27
US7585558B2 (en) 2009-09-08
TWI329657B (https=) 2010-09-01
CN1745127A (zh) 2006-03-08
JP4695510B2 (ja) 2011-06-08
WO2004067612A1 (ja) 2004-08-12
EP1589063A1 (en) 2005-10-26

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