CA1134094A - Process for stabilising organic polymeric materials - Google Patents
Process for stabilising organic polymeric materialsInfo
- Publication number
- CA1134094A CA1134094A CA345,017A CA345017A CA1134094A CA 1134094 A CA1134094 A CA 1134094A CA 345017 A CA345017 A CA 345017A CA 1134094 A CA1134094 A CA 1134094A
- Authority
- CA
- Canada
- Prior art keywords
- hydrogen
- phenyl
- process according
- 18alkyl
- optionally substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 40
- 239000000463 material Substances 0.000 title claims abstract description 30
- 230000003019 stabilising effect Effects 0.000 title claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims abstract description 59
- 239000003381 stabilizer Substances 0.000 claims abstract description 18
- 239000001257 hydrogen Substances 0.000 claims description 107
- 229910052739 hydrogen Inorganic materials 0.000 claims description 107
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 86
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 45
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 42
- -1 2-thienyl-carbonyloxy Chemical group 0.000 claims description 30
- 125000004432 carbon atom Chemical group C* 0.000 claims description 29
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 29
- 125000000217 alkyl group Chemical group 0.000 claims description 25
- 125000001424 substituent group Chemical group 0.000 claims description 25
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 claims description 23
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 20
- 239000000460 chlorine Substances 0.000 claims description 19
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical group C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 12
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims description 10
- 125000006704 (C5-C6) cycloalkyl group Chemical group 0.000 claims description 9
- 125000003356 phenylsulfanyl group Chemical group [*]SC1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 9
- 239000004698 Polyethylene Substances 0.000 claims description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
- 229910052801 chlorine Inorganic materials 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 8
- 229920000573 polyethylene Polymers 0.000 claims description 8
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims description 8
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 7
- 239000004743 Polypropylene Substances 0.000 claims description 7
- 125000003884 phenylalkyl group Chemical group 0.000 claims description 7
- 229920001155 polypropylene Polymers 0.000 claims description 7
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 6
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 6
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 5
- 229920001897 terpolymer Polymers 0.000 claims description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 4
- FNIATMYXUPOJRW-UHFFFAOYSA-N cyclohexylidene Chemical group [C]1CCCCC1 FNIATMYXUPOJRW-UHFFFAOYSA-N 0.000 claims description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 239000005864 Sulphur Substances 0.000 claims description 3
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 3
- 229920002647 polyamide Polymers 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 125000006545 (C1-C9) alkyl group Chemical group 0.000 claims description 2
- 125000002941 2-furyl group Chemical group O1C([*])=C([H])C([H])=C1[H] 0.000 claims description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 claims description 2
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 claims description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 2
- 229920001748 polybutylene Polymers 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 125000004076 pyridyl group Chemical group 0.000 claims description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims 20
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims 5
- 125000006705 (C5-C7) cycloalkyl group Chemical group 0.000 claims 2
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims 2
- 125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims 1
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 claims 1
- 125000004172 4-methoxyphenyl group Chemical group [H]C1=C([H])C(OC([H])([H])[H])=C([H])C([H])=C1* 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 239000011368 organic material Substances 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 230000015556 catabolic process Effects 0.000 abstract description 3
- 238000006731 degradation reaction Methods 0.000 abstract description 3
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 abstract 2
- 238000010094 polymer processing Methods 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 24
- 239000000843 powder Substances 0.000 description 12
- 239000000203 mixture Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000000243 solution Substances 0.000 description 8
- 239000000654 additive Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 5
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 5
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 125000004423 acyloxy group Chemical group 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- QBYIENPQHBMVBV-HFEGYEGKSA-N (2R)-2-hydroxy-2-phenylacetic acid Chemical compound O[C@@H](C(O)=O)c1ccccc1.O[C@@H](C(O)=O)c1ccccc1 QBYIENPQHBMVBV-HFEGYEGKSA-N 0.000 description 2
- ICKWICRCANNIBI-UHFFFAOYSA-N 2,4-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C(C(C)(C)C)=C1 ICKWICRCANNIBI-UHFFFAOYSA-N 0.000 description 2
- XSXYESVZDBAKKT-UHFFFAOYSA-N 2-hydroxybenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1O XSXYESVZDBAKKT-UHFFFAOYSA-N 0.000 description 2
- TUAMRELNJMMDMT-UHFFFAOYSA-N 3,5-di-methylphenol Natural products CC1=CC(C)=CC(O)=C1 TUAMRELNJMMDMT-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- IWYDHOAUDWTVEP-UHFFFAOYSA-N R-2-phenyl-2-hydroxyacetic acid Natural products OC(=O)C(O)C1=CC=CC=C1 IWYDHOAUDWTVEP-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 229940078456 calcium stearate Drugs 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 150000002240 furans Chemical class 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000005457 ice water Substances 0.000 description 2
- 229960002510 mandelic acid Drugs 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- VQIRPKSLELOUKW-UHFFFAOYSA-N (3-hydroxyphenyl) octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC1=CC=CC(O)=C1 VQIRPKSLELOUKW-UHFFFAOYSA-N 0.000 description 1
- MQQKTNDBASEZSD-UHFFFAOYSA-N 1-(octadecyldisulfanyl)octadecane Chemical compound CCCCCCCCCCCCCCCCCCSSCCCCCCCCCCCCCCCCCC MQQKTNDBASEZSD-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
- UIAFKZKHHVMJGS-UHFFFAOYSA-N 2,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1O UIAFKZKHHVMJGS-UHFFFAOYSA-N 0.000 description 1
- KUFFULVDNCHOFZ-UHFFFAOYSA-N 2,4-xylenol Chemical compound CC1=CC=C(O)C(C)=C1 KUFFULVDNCHOFZ-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- VMZCDNSFRSVYKQ-UHFFFAOYSA-N 2-phenylacetyl chloride Chemical compound ClC(=O)CC1=CC=CC=C1 VMZCDNSFRSVYKQ-UHFFFAOYSA-N 0.000 description 1
- 229940061334 2-phenylphenol Drugs 0.000 description 1
- TVEAZHOLMPKUGM-UHFFFAOYSA-N 2-piperidinobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1N1CCCCC1 TVEAZHOLMPKUGM-UHFFFAOYSA-N 0.000 description 1
- ASHGTJPOSUFTGB-UHFFFAOYSA-N 3-methoxyphenol Chemical compound COC1=CC=CC(O)=C1 ASHGTJPOSUFTGB-UHFFFAOYSA-N 0.000 description 1
- CYEKUDPFXBLGHH-UHFFFAOYSA-N 3-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC(O)=C1 CYEKUDPFXBLGHH-UHFFFAOYSA-N 0.000 description 1
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- 239000003508 Dilauryl thiodipropionate Substances 0.000 description 1
- 239000002656 Distearyl thiodipropionate Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- UTTHLMXOSUFZCQ-UHFFFAOYSA-N benzene-1,3-dicarbohydrazide Chemical compound NNC(=O)C1=CC=CC(C(=O)NN)=C1 UTTHLMXOSUFZCQ-UHFFFAOYSA-N 0.000 description 1
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- RHDGNLCLDBVESU-UHFFFAOYSA-N but-3-en-4-olide Chemical compound O=C1CC=CO1 RHDGNLCLDBVESU-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 150000001851 cinnamic acid derivatives Chemical class 0.000 description 1
- 238000012505 colouration Methods 0.000 description 1
- 150000001907 coumarones Chemical class 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 150000001470 diamides Chemical class 0.000 description 1
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 1
- 235000019305 distearyl thiodipropionate Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 125000003844 furanonyl group Chemical group 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- JISVIRFOSOKJIU-UHFFFAOYSA-N hexylidene Chemical group [CH2+]CCCC[CH-] JISVIRFOSOKJIU-UHFFFAOYSA-N 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 150000005165 hydroxybenzoic acids Chemical class 0.000 description 1
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- JYGFTBXVXVMTGB-UHFFFAOYSA-N indolin-2-one Chemical class C1=CC=C2NC(=O)CC2=C1 JYGFTBXVXVMTGB-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- GTIBACHAUHDNPH-WHYMJUELSA-N n,n'-bis[(z)-benzylideneamino]oxamide Chemical compound C=1C=CC=CC=1\C=N/NC(=O)C(=O)N\N=C/C1=CC=CC=C1 GTIBACHAUHDNPH-WHYMJUELSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- RPBCDDTWDKYNQY-UHFFFAOYSA-N o-dodecyl propanethioate Chemical compound CCCCCCCCCCCCOC(=S)CC RPBCDDTWDKYNQY-UHFFFAOYSA-N 0.000 description 1
- WTBAHSZERDXKKZ-UHFFFAOYSA-N octadecanoyl chloride Chemical compound CCCCCCCCCCCCCCCCCC(Cl)=O WTBAHSZERDXKKZ-UHFFFAOYSA-N 0.000 description 1
- OBYWBISWWBUSET-UHFFFAOYSA-N octadecyl 3-(4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC=C(O)C=C1 OBYWBISWWBUSET-UHFFFAOYSA-N 0.000 description 1
- IIGMITQLXAGZTL-UHFFFAOYSA-N octyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCC IIGMITQLXAGZTL-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 235000010292 orthophenyl phenol Nutrition 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000012667 polymer degradation Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000006798 ring closing metathesis reaction Methods 0.000 description 1
- 150000003873 salicylate salts Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000003335 secondary amines Chemical group 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- MGMXGCZJYUCMGY-UHFFFAOYSA-N tris(4-nonylphenyl) phosphite Chemical compound C1=CC(CCCCCCCCC)=CC=C1OP(OC=1C=CC(CCCCCCCCC)=CC=1)OC1=CC=C(CCCCCCCCC)C=C1 MGMXGCZJYUCMGY-UHFFFAOYSA-N 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/78—Benzo [b] furans; Hydrogenated benzo [b] furans
- C07D307/82—Benzo [b] furans; Hydrogenated benzo [b] furans with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
- C07D307/83—Oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1535—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3415—Five-membered rings
- C08K5/3417—Five-membered rings condensed with carbocyclic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Furan Compounds (AREA)
- Indole Compounds (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH110479 | 1979-02-05 | ||
| CH1104/79 | 1979-02-05 | ||
| CH879379 | 1979-09-28 | ||
| CH8793/79 | 1979-09-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1134094A true CA1134094A (en) | 1982-10-19 |
Family
ID=25686661
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA345,017A Expired CA1134094A (en) | 1979-02-05 | 1980-02-04 | Process for stabilising organic polymeric materials |
| CA000345018A Expired CA1150257A (en) | 1979-02-05 | 1980-02-04 | Benzofuranone and indolinone derivatives |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000345018A Expired CA1150257A (en) | 1979-02-05 | 1980-02-04 | Benzofuranone and indolinone derivatives |
Country Status (14)
Families Citing this family (269)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2044272B (en) * | 1979-02-05 | 1983-03-16 | Sandoz Ltd | Stabilising polymers |
| JPS61138648A (ja) * | 1984-12-10 | 1986-06-26 | Mitsui Petrochem Ind Ltd | 光学デイスク |
| US4665112A (en) * | 1986-01-02 | 1987-05-12 | General Electric Company | Ultraviolet radiation stabilized polyphenylene ether resins |
| DE3601900A1 (de) * | 1986-01-23 | 1987-07-30 | Bayer Ag | Verwendung von 3-benzalphthaliden als uv-stabilisatoren fuer thermoplastische, aromatische polyester, polycarbonate und polyestercarbonate |
| US4741860A (en) * | 1986-10-02 | 1988-05-03 | Ppg Industries, Inc. | Adhesion promoters containing optical brightener |
| US4888205A (en) * | 1986-10-02 | 1989-12-19 | Ppg Industries, Inc. | Method of treating a polyolefin substrate with adhesion promoters containing optical brightener |
| FR2611713B1 (fr) * | 1987-02-27 | 1990-11-30 | Adir | Nouveaux derives de l'acide (dihydro-2,3 oxo-2 benzofurannyl-3)-2 acetique, leurs procedes de preparation et les compositions pharmaceutiques qui les contiennent |
| FR2611715B1 (fr) * | 1987-02-27 | 1989-05-12 | Adir | Nouveaux acetamides derives de la dihydro-2,3 phenyl-3 benzofurannone-2, leurs procedes de preparation et les compositions pharmaceutiques qui les contiennent |
| US4849428A (en) * | 1987-11-23 | 1989-07-18 | The Procter & Gamble Company | Cyclic anti-inflammatory derivatives of di-tert-butylphenol compounds, compositions and use |
| US4982006A (en) * | 1987-12-18 | 1991-01-01 | Norwich Eaton Pharmaceuticals, Inc. | Process for the preparation of certain substituted aromatic compounds |
| US4954544A (en) * | 1989-03-23 | 1990-09-04 | Conros Corporation | Modified adhesive composition which undergoes color changes upon application |
| EP0415887B1 (de) * | 1989-08-31 | 1994-10-05 | Ciba-Geigy Ag | 3-Phenylbenzofuran-2-one |
| US5175312A (en) * | 1989-08-31 | 1992-12-29 | Ciba-Geigy Corporation | 3-phenylbenzofuran-2-ones |
| US5250592A (en) * | 1990-04-12 | 1993-10-05 | Ciba-Geigy Corporation | Isoindolinone compounds as stabilizers for organic materials |
| GB2252325A (en) * | 1991-01-31 | 1992-08-05 | Ciba Geigy Ag | Stabilised polyolefin |
| US5252643A (en) * | 1991-07-01 | 1993-10-12 | Ciba-Geigy Corporation | Thiomethylated benzofuran-2-ones |
| TW206220B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1991-07-01 | 1993-05-21 | Ciba Geigy Ag | |
| MX9205504A (es) * | 1991-11-01 | 1993-06-01 | Ciba Geigy Ag | Composicion y proceso para la preparacion de articulos que tienen estabilidad de moldeo |
| EP0543778A1 (de) * | 1991-11-19 | 1993-05-26 | Ciba-Geigy Ag | Gegen Oxidation bzw. Kernverbräunung geschützte Polyetherpolyol- und Polyurethanzusammensetzungen |
| DE59204845D1 (de) * | 1991-11-29 | 1996-02-08 | Ciba Geigy Ag | Diphenylessigsäurederivate als Stabilisatoren für organisches Material |
| MX9207621A (es) * | 1992-01-21 | 1993-07-01 | Ciba Geigy Ag | Nuevos bisfenolfosfitos de cicloalquilideno |
| DE59306149D1 (de) * | 1992-04-08 | 1997-05-22 | Ciba Geigy | Flüssige Antioxidantien als Stabilisatoren |
| US5356546A (en) * | 1992-04-16 | 1994-10-18 | The Lubrizol Corporation | Metal salts useful as additives for fuels and lubricants |
| US5281346A (en) * | 1992-04-16 | 1994-01-25 | The Lubrizol Corporation | Two-cycle engine lubricant and method of using same comprising alkali or alkaline earth metal salts of carboxylic aromatic acids |
| GB2267490B (en) * | 1992-05-22 | 1995-08-09 | Ciba Geigy Ag | 3-(Carboxymethoxyphenyl)benzofuran-2-one stabilisers |
| TW260686B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1992-05-22 | 1995-10-21 | Ciba Geigy | |
| NL9300801A (nl) * | 1992-05-22 | 1993-12-16 | Ciba Geigy | 3-(acyloxyfenyl)benzofuran-2-on als stabilisatoren. |
| TW255902B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1992-09-23 | 1995-09-01 | Ciba Geigy | |
| MX9305489A (es) * | 1992-09-23 | 1994-03-31 | Ciba Geigy Ag | 3-(dihidrobenzofuran-5-il)benzofuran-2-onas, estabilizadores. |
| TW283148B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1992-09-25 | 1996-08-11 | Ciba Geigy Ag | |
| DE59306328D1 (de) * | 1992-10-21 | 1997-06-05 | Ciba Geigy | Phenylphosphite als Stabilisatoren für organische Materialien |
| TW252991B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1992-12-04 | 1995-08-01 | Ciba Geigy | |
| EP0608198A1 (de) * | 1993-01-18 | 1994-07-27 | Ciba-Geigy Ag | Cyclische Diphenylacetonitrile als Stabilisatoren |
| DE59402281D1 (de) * | 1993-06-28 | 1997-05-07 | Bayer Ag | Massefärben von Kunststoffen |
| TW270133B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1993-09-17 | 1996-02-11 | Ciba Geigy | |
| TW284762B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1993-09-17 | 1996-09-01 | Ciba Geigy Ag | |
| CH686306A5 (de) * | 1993-09-17 | 1996-02-29 | Ciba Geigy Ag | 3-Aryl-benzofuranone als Stabilisatoren. |
| TW327185B (en) * | 1993-09-20 | 1998-02-21 | Ciba Sc Holding Ag | Liquid antioxidants |
| IT1269197B (it) | 1994-01-24 | 1997-03-21 | Ciba Geigy Spa | Composti 1-idrocarbilossi piperidinici contenenti gruppi silanici atti all'impiego come stabilizzanti per materiali organici |
| TW317568B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1994-04-13 | 1997-10-11 | Ciba Sc Holding Ag | |
| TW350859B (en) * | 1994-04-13 | 1999-01-21 | Ciba Sc Holding Ag | HALS phosphonites as stabilizers |
| TW297822B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1994-04-13 | 1997-02-11 | Ciba Geigy Ag | |
| US5556973A (en) | 1994-07-27 | 1996-09-17 | Ciba-Geigy Corporation | Red-shifted tris-aryl-s-triazines and compositions stabilized therewith |
| EP0698637A3 (en) | 1994-08-22 | 1996-07-10 | Ciba Geigy Ag | Polyurethanes stabilized with selected UV absorbers of 5-substituted benzotriazole |
| JP3303546B2 (ja) * | 1994-08-29 | 2002-07-22 | 住友化学工業株式会社 | ビスラクトン系化合物及びその製造方法 |
| EP0711804A3 (de) | 1994-11-14 | 1999-09-22 | Ciba SC Holding AG | Kryptolichtschutzmittel |
| TW303381B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1994-12-05 | 1997-04-21 | Ciba Sc Holding Ag | |
| TW399079B (en) * | 1995-05-12 | 2000-07-21 | Ciba Sc Holding Ag | Polyether polyol and polyurethane compositions protected against oxidation and core scorching |
| TW325490B (en) | 1995-06-23 | 1998-01-21 | Ciba Sc Holding Ag | Polysiloxane light stabilizers |
| EP0771814A1 (en) | 1995-11-02 | 1997-05-07 | Ciba SC Holding AG | Amorphous and crystalline modifications of 1,1',1"-nitrilo triethyl-tris[2,2'-methylene-bis(4,6-di-tert-butyl-phenyl)]phosphite |
| US6521681B1 (en) | 1996-07-05 | 2003-02-18 | Ciba Specialty Chemicals Corporation | Phenol-free stabilization of polyolefin fibres |
| EP0839623B1 (de) * | 1996-10-30 | 2001-01-31 | Ciba SC Holding AG | Stabilisatorkombination für das Rotomolding-Verfahren |
| FR2756561B1 (fr) | 1996-12-04 | 1999-01-08 | Cird Galderma | Composes heteroaryles, compositions pharmaceutiques et cosmetiques les contenant et utilisations |
| EP0850946A1 (de) * | 1996-12-24 | 1998-07-01 | Ciba SC Holding AG | Cyclische Phosphinsäurederivate als Stabilisatoren |
| DE59810298D1 (de) * | 1997-02-05 | 2004-01-15 | Ciba Sc Holding Ag | Stabilisatoren für Pulverlacke |
| ES2149678B1 (es) | 1997-03-06 | 2001-05-16 | Ciba Sc Holding Ag | Estabilizacion de policarbonatos, poliesteres y policetonas. |
| US5922794A (en) * | 1997-03-26 | 1999-07-13 | General Electric Company | Compositions stabilized with tertiary amine oxides |
| US5834541A (en) * | 1997-05-02 | 1998-11-10 | Montell North America Inc. | Olefin polymer composition having low smoke generation and fiber and film prepared therefrom |
| DE19820157B4 (de) | 1997-05-13 | 2010-04-08 | Clariant Produkte (Deutschland) Gmbh | Neue Verbindungen auf Basis von Polyalkyl-1-oxa-diazaspirodecan-Verbindungen |
| US5844026A (en) * | 1997-06-30 | 1998-12-01 | Ciba Specialty Chemicals Corporation | N,N',N''-tris{2,4-bis Hydrocarbyloxy-2,2,6,6-tetra-methylpiperidin-4-yl)alkylamino!-s-triazin-6-yl}-3,3'-ethylenediiminodipropylamines, their isomers and bridged derivatives and polymer compositions stabilized therewith |
| AU8399398A (en) | 1997-07-14 | 1999-02-10 | Dover Chemical Corporation | Lactone/phosphite blends |
| DE19730629C2 (de) * | 1997-07-17 | 2001-06-13 | Borealis Gmbh Schwechat Mannsw | Modifizierte, Methylensequenzen enthaltende Polymere, Verfahren zur Herstellung und Verwendung |
| JPH1160556A (ja) * | 1997-08-11 | 1999-03-02 | Sumitomo Chem Co Ltd | ピペリジン系化合物、その製法及びその用途 |
| IL136409A0 (en) * | 1997-12-08 | 2001-06-14 | Cytec Tech Corp | Morpholino end-capped, hindered amine substituted aminotriazine and their use as light stabilizers |
| GB2333296B (en) * | 1998-01-15 | 2000-09-27 | Ciba Sc Holding Ag | Stabilisers and anti-ozonants for elastomers |
| WO1999041307A1 (en) * | 1998-02-17 | 1999-08-19 | The Dow Chemical Company | Hydrogenated aromatic polymer compositions containing stabilizers |
| US6294604B1 (en) | 1998-03-06 | 2001-09-25 | Dyneon Llc | Polymer processing additive having improved stability |
| AU4695699A (en) | 1998-06-22 | 2000-01-10 | Ciba Specialty Chemicals Holding Inc. | Poly-trisaryl-1,3,5-triazine carbamate ultraviolet light absorbers |
| US6239276B1 (en) | 1998-06-22 | 2001-05-29 | Cytec Technology Corporation | Non-yellowing para-tertiary-alkyl phenyl substituted triazine and pyrimidine ultraviolet light absorbers |
| US6297377B1 (en) | 1998-06-22 | 2001-10-02 | Cytec Technology Corporation | Benzocycle-substituted triazine and pyrimidine ultraviolet light absorbers |
| CN1306522A (zh) | 1998-06-22 | 2001-08-01 | Cytec技术有限公司 | 红移的三芳基－1,3,5－三嗪紫外光吸收剂 |
| EP1089991B1 (en) | 1998-06-25 | 2003-03-19 | Ciba SC Holding AG | Process for the preparation of 3-aryl-benzofuranones |
| GB2368063B (en) * | 1998-10-19 | 2002-12-11 | Ciba Sc Holding Ag | Colour photographic material |
| GB2343007B (en) * | 1998-10-19 | 2001-11-07 | Ciba Sc Holding Ag | Colour photographic material |
| JP5313419B2 (ja) * | 1999-03-10 | 2013-10-09 | チバ ホールディング インコーポレーテッド | 有機材料用着色剤としてのベンゾフラン−２−オン |
| US6069225A (en) * | 1999-03-17 | 2000-05-30 | Bayer Corporation | Polycarbonate composition useful in optical storage applications |
| US6191199B1 (en) | 1999-05-03 | 2001-02-20 | Ciba Speciatly Chemicals Corporation | Stabilized adhesive compositions containing highly soluble, high extinction photostable hydroxyphenyl-s-triazine UV absorbers and laminated articles derived therefrom |
| AU6624800A (en) | 1999-09-01 | 2001-03-26 | Dow Chemical Company, The | Polycarbonate resin compositions comprising cyanacrylic acid ester stabilizer compounds |
| WO2001059000A1 (en) | 2000-02-14 | 2001-08-16 | Ciba Specialty Chemicals Holding Inc. | New 3-arylbenzofuranones with electron-withdrawing substituents as stabilizers |
| GB0004437D0 (en) | 2000-02-25 | 2000-04-12 | Clariant Int Ltd | Synergistic combinations of phenolic antioxidants |
| GB0004436D0 (en) * | 2000-02-25 | 2000-04-12 | Clariant Int Ltd | Synergistic stabilizer compositions for thermoplastic polymers in prolonged contact with water |
| US6197854B1 (en) | 2000-04-03 | 2001-03-06 | Bayer Corporation | Polycarbonate composition resistant to gamma radiation |
| JP2003531944A (ja) * | 2000-05-04 | 2003-10-28 | ゼネラル・エレクトリック・カンパニイ | 相溶化ポリフェニレンエーテル−ポリアミド組成物の塗料密着性を改善する方法 |
| ATE499375T1 (de) | 2000-05-19 | 2011-03-15 | Basf Se | Verfahren zur kontrollierten erhöhung des molekulargewichts von polyethylen und polyethylenmischungen |
| EP1170296B1 (en) * | 2000-07-07 | 2005-07-20 | Ciba SC Holding AG | Process for the preparation of 3-aryl-benzofuran-2-ones |
| US6890978B2 (en) * | 2000-08-09 | 2005-05-10 | A&M Styrene Co., Ltd. | Aromatic monovinyl resin composition |
| GB0019465D0 (en) * | 2000-08-09 | 2000-09-27 | Clariant Int Ltd | Synergistic stabilizer for color stable pigmented thermoplastic polyners in prolonged contact with water |
| US6569927B1 (en) | 2000-10-06 | 2003-05-27 | Uniroyal Chemical Company, Inc. | Thermoplastic resins stabilized by blends of sterically hindered phenols, secondary amines, and lactones |
| ITMI20012085A1 (it) | 2000-10-17 | 2003-04-09 | Ciba Sc Holding Ag | Polpropilene metallocene stabilizzato |
| US6867250B1 (en) | 2000-10-30 | 2005-03-15 | Cytec Technology Corp. | Non-yellowing ortho-dialkyl aryl substituted triazine ultraviolet light absorbers |
| US6545156B1 (en) | 2000-11-03 | 2003-04-08 | Cytec Technology Corp. | Oligomeric hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same |
| US6414155B1 (en) | 2000-11-03 | 2002-07-02 | Cytec Technology Corp. | Oligomeric hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same |
| US6492521B2 (en) | 2000-11-03 | 2002-12-10 | Cytec Technology Corp. | Hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same |
| US6727300B2 (en) | 2000-11-03 | 2004-04-27 | Cytec Technology Corp. | Polymeric articles containing hindered amine light stabilizers based on multi-functional carbonyl compounds |
| IL156281A0 (en) | 2001-01-15 | 2004-01-04 | Ciba Sc Holding Ag | Antistatic flexible intermediate bulk container |
| TW570931B (en) * | 2001-02-15 | 2004-01-11 | Clariant Int Ltd | Lactone compounds as novel photoinitiators |
| GB0104371D0 (en) * | 2001-02-22 | 2001-04-11 | Clariant Int Ltd | Color improving stabilizing compositions comprising leucine |
| ATE302814T1 (de) * | 2001-03-20 | 2005-09-15 | Ciba Sc Holding Ag | Flammhemmende zusammensetzungen |
| GB0119137D0 (en) * | 2001-08-06 | 2001-09-26 | Clariant Int Ltd | Property enhancement of polyamides by co-condensation with lightstabilizers |
| TW593303B (en) * | 2001-09-11 | 2004-06-21 | Ciba Sc Holding Ag | Stabilization of synthetic polymers |
| DE10204690A1 (de) * | 2002-02-06 | 2003-08-07 | Clariant Gmbh | Verfahren zur Herstellung synergistischer Stabilisatormischungen |
| US20030225191A1 (en) | 2002-04-12 | 2003-12-04 | Francois Gugumus | Stabilizer mixtures |
| DE10254548A1 (de) * | 2002-11-21 | 2004-06-17 | Basf Ag | Verwendung UV-Absorber enthaltender Polymerpulver zur Stabilisierung von Polymeren gegen die Einwirkung von UV-Strahlung |
| GB0228647D0 (en) | 2002-12-09 | 2003-01-15 | Ciba Sc Holding Ag | Polyeric material containing a latent acid |
| CN1753871A (zh) | 2003-02-26 | 2006-03-29 | 西巴特殊化学品控股有限公司 | 水相容空间位阻烷氧基胺和羟基取代的烷氧基胺 |
| DE602004013584D1 (de) * | 2003-06-19 | 2008-06-19 | Basell Poliolefine Srl | Olefinpolymere mit stabilisatoren und daraus hergestellte polyolefinfasern |
| MY145571A (en) | 2003-12-19 | 2012-02-29 | Ciba Holding Inc | Fluorocarbon terminated oligo-and poly-carbonates as surface modifiers |
| CA2554119A1 (en) * | 2004-01-22 | 2005-08-04 | University Of Ottawa | Thermally modulated antioxidants |
| US20070208112A1 (en) * | 2004-04-16 | 2007-09-06 | Basf Aktiengesellschaft | Use of Pyridindione Derivatives for Protecting Organic Material Against Detrimental Effects of Light |
| CA2464551C (en) * | 2004-05-18 | 2012-01-03 | Nova Chemicals Corporation | Phenol free stabilization of polyethylene film |
| CA2576808C (en) | 2004-08-31 | 2012-12-18 | Ciba Specialty Chemicals Holding Inc. | Stabilization of organic materials |
| ATE512191T1 (de) * | 2004-08-31 | 2011-06-15 | Basf Se | Stabilisierung von organischen materialien |
| WO2006045713A1 (en) | 2004-10-25 | 2006-05-04 | Ciba Specialty Chemicals Holding Inc. | Functionalized nanoparticles |
| EP1807395B1 (en) | 2004-11-02 | 2015-12-23 | Basf Se | Process for the synthesis of n-alkoxyamines |
| US20060116456A1 (en) * | 2004-11-30 | 2006-06-01 | Lin Thomas S | Composition with enhanced heat resistance property |
| US7390912B2 (en) * | 2004-12-17 | 2008-06-24 | Milliken & Company | Lactone stabilizing compositions |
| EP1676887B1 (en) | 2004-12-29 | 2007-05-23 | Ciba Specialty Chemicals Holding Inc. | Composition and process for improving heat and weathering stability of segmented polyurethane polymers |
| CN1318417C (zh) * | 2005-01-07 | 2007-05-30 | 东北大学 | 一种双吲哚类无色苯并呋喃酮化合物及制备方法 |
| SI1928454T1 (sl) | 2005-05-10 | 2015-01-30 | Intermune, Inc. | Piridonski derivati za moduliranje s stresom aktiviranega protein kinaznega sistema |
| WO2007120749A1 (en) * | 2006-04-13 | 2007-10-25 | Cytec Technology Corp. | Stabilized spandex compositions |
| JP5169828B2 (ja) * | 2006-07-05 | 2013-03-27 | コニカミノルタアドバンストレイヤー株式会社 | 偏光板保護フィルムの製造方法 |
| JP4747985B2 (ja) * | 2006-08-02 | 2011-08-17 | コニカミノルタオプト株式会社 | 光学フィルム、それを用いた偏光板及び液晶表示装置 |
| US20100003426A1 (en) * | 2006-08-04 | 2010-01-07 | Takatugu Suzuki | Optical Film, Manufacturing Method Thereof, Polarizing Plate Employing it and Liquid Crystal Display Device |
| JP5419871B2 (ja) | 2007-06-29 | 2014-02-19 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 非フェノール系安定剤を含む照射ポリオレフィン組成物 |
| CN101801676B (zh) * | 2007-07-18 | 2012-10-03 | 巴斯夫欧洲公司 | 激光敏感涂料制剂 |
| ATE527327T1 (de) * | 2007-07-18 | 2011-10-15 | Datalase Ltd | Beschichtungszusammensetzungen |
| EP2185641B1 (de) * | 2007-08-28 | 2010-12-29 | Basf Se | Stabilisatormischung |
| DE102007040925A1 (de) | 2007-08-30 | 2009-03-05 | Bayer Materialscience Ag | Thermoplastische Zusammensetzungen mit geringer Trübung |
| EP2190903B1 (en) | 2007-09-04 | 2012-04-04 | Basf Se | Cyclic phosphines as flame retardants |
| US8252862B2 (en) * | 2007-09-13 | 2012-08-28 | Basf Se | Silane coupling agents for filled rubbers |
| WO2009068492A2 (de) | 2007-11-28 | 2009-06-04 | Basf Se | Flüssige stabilisatormischung |
| WO2009124998A2 (de) * | 2008-04-11 | 2009-10-15 | Basf Se | Hochverzweigte polymere und oligomere mit terminalen aminogruppen als härter für epoxidharze |
| ITMI20080739A1 (it) * | 2008-04-23 | 2009-10-24 | 3V Sigma Spa | Ammine stericamente impedite oligomeriche e loro uso come stabilizzanti per polimeri |
| ITMI20080747A1 (it) | 2008-04-24 | 2009-10-25 | 3V Sigma Spa | Miscele di ammine stericamente impedite per la stabilizzazione di polimeri |
| JP5474055B2 (ja) | 2008-05-15 | 2014-04-16 | ビーエーエスエフ ソシエタス・ヨーロピア | 乳化重合ゴムの塩基性安定化系 |
| US8304413B2 (en) | 2008-06-03 | 2012-11-06 | Intermune, Inc. | Compounds and methods for treating inflammatory and fibrotic disorders |
| JP5260418B2 (ja) | 2008-06-26 | 2013-08-14 | 住友化学株式会社 | ポリエステル組成物 |
| JP5511821B2 (ja) | 2008-08-27 | 2014-06-04 | ビーエーエスエフ ソシエタス・ヨーロピア | 高分子分散剤を有する難燃性組成物 |
| EP2318454B1 (de) | 2008-08-28 | 2012-02-29 | Basf Se | Stabilisatoren für unbelebte organische materialien |
| US8349925B2 (en) | 2008-09-05 | 2013-01-08 | Thor Gmbh | Flame-retardant composition comprising a phosphonic acid derivative |
| EP2160945A1 (en) | 2008-09-09 | 2010-03-10 | Polymers CRC Limited | Antimicrobial Article |
| US7988881B2 (en) * | 2008-09-30 | 2011-08-02 | E. I. Du Pont De Nemours And Company | Multilayer laminates comprising chiral nematic liquid crystals |
| KR101691898B1 (ko) | 2008-10-23 | 2017-01-02 | 데이터레이즈 리미티드 | 열 흡수 첨가제 |
| WO2010049282A1 (en) | 2008-10-27 | 2010-05-06 | Basf Se | Coating composition for marking substrates |
| EP2186845A1 (en) | 2008-11-18 | 2010-05-19 | Basf Se | Ammonium Functionalized Polymers as Antistatic Additives |
| WO2010072768A1 (de) | 2008-12-23 | 2010-07-01 | Basf Se | Uv-absorber agglomerate |
| WO2010076278A1 (en) | 2009-01-05 | 2010-07-08 | Basf Se | Phosphorus based dispersants for inorganic particles in polymer matrices |
| IT1393333B1 (it) | 2009-02-09 | 2012-04-20 | 3V Sigma Spa | Nuove ammine stericamente impedite e loro uso come stabilizzanti per polimeri |
| AU2010227626B2 (en) | 2009-03-24 | 2014-03-27 | Basf Se | Preparation of shaped metal particles and their uses |
| WO2010112395A1 (en) | 2009-04-02 | 2010-10-07 | Basf Se | S-perfluoroalkyl substituted hydroxybenzylthioethers and derivatives as surface modifiers |
| WO2011005631A2 (en) | 2009-07-07 | 2011-01-13 | Basf Se | Potassium cesium tungsten bronze particles |
| JP2013500349A (ja) | 2009-07-24 | 2013-01-07 | ビーエーエスエフ ソシエタス・ヨーロピア | 芳香族及び／又はヘテロ芳香族エポキシ樹脂における難燃剤としてのジホスフィンの誘導体 |
| US8286405B1 (en) * | 2009-08-11 | 2012-10-16 | Agp Plastics, Inc. | Fire and impact resistant window and building structures |
| EP2467878A1 (en) | 2009-08-18 | 2012-06-27 | Basf Se | An uv-stabilized photovoltaic module |
| US20120145241A1 (en) | 2009-08-18 | 2012-06-14 | Basf Se | Photovoltaic module with stabilized polymeric encapsulant |
| AU2010288716B2 (en) | 2009-08-27 | 2015-09-17 | Polymers Crc Ltd. | Nano silver-zinc oxide composition |
| BR112012005454A2 (pt) | 2009-09-10 | 2015-09-08 | Basf Se | composto, composição, e, métodos para estabilizar um material orgânico suscetível à degradação oxidativa, térmica ou induzida por luz e para aprimorar retardância de chama de um material orgânico. |
| EP2319832A1 (en) | 2009-10-20 | 2011-05-11 | Basf Se | Sterically hindered amines |
| EP2504387B1 (en) | 2009-11-27 | 2015-08-12 | Basf Se | Photovoltaic module with uv-stabilized encapsulant |
| EP2545035B1 (en) | 2010-03-05 | 2017-08-09 | Basf Se | Sterically hindered amines |
| CA2789067A1 (en) | 2010-03-05 | 2011-09-09 | Basf Se | Sterically hindered amines |
| AR080385A1 (es) | 2010-03-09 | 2012-04-04 | Polymers Crc Ltd | Procedimiento para la preparacion de un articulo antimicrobiano |
| IT1399477B1 (it) | 2010-03-15 | 2013-04-19 | 3V Sigma Spa | Miscele di ammine stericamente impedite per la stabilizzazione di polimeri |
| JP2013529615A (ja) | 2010-06-24 | 2013-07-22 | ビーエーエスエフ ソシエタス・ヨーロピア | 除草剤組成物 |
| WO2012000992A1 (en) | 2010-06-29 | 2012-01-05 | Basf Se | Process for improving the flow properties of polymer melts |
| EP2402390A1 (en) | 2010-06-30 | 2012-01-04 | Basf Se | Particles with a hindered amine light stabilizer and a microporous organic polymer |
| CN103168053B (zh) | 2010-10-20 | 2015-11-25 | 巴斯夫欧洲公司 | 具有特定功能化的低聚光稳定剂 |
| JP5992422B2 (ja) | 2010-10-20 | 2016-09-14 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 混合官能化による立体障害アミン型光安定剤 |
| IT1403086B1 (it) | 2010-10-28 | 2013-10-04 | 3V Sigma Spa | Nuove ammine stericamente impedite polimeriche e loro uso come stabilizzanti per polimeri |
| MX2013005437A (es) | 2010-11-16 | 2013-07-03 | Basf Se | Composicion estabilizadora para polimeros. |
| US11267951B2 (en) | 2010-12-13 | 2022-03-08 | Cytec Technology Corp. | Stabilizer compositions containing substituted chroman compounds and methods of use |
| NZ611802A (en) | 2010-12-13 | 2015-09-25 | Cytec Tech Corp | Processing additives and uses of same in rotational molding |
| TWI403507B (zh) | 2011-03-17 | 2013-08-01 | Chitec Technology Co Ltd | 苯并呋喃衍生物及其應用 |
| ITMI20110802A1 (it) | 2011-05-10 | 2012-11-11 | 3V Sigma Spa | Miscele di ammine stericamente impedite per la stabilizzazione di polimeri |
| JP6095667B2 (ja) | 2011-09-23 | 2017-03-15 | ボレアリス アーゲーＢｏｒｅａｌｉｓ Ａｇ | アミノトリアジン系マンニッヒ化合物を用いた有機材料の安定化 |
| CN102603686A (zh) * | 2012-02-01 | 2012-07-25 | 华东理工大学 | 2’位含活泼氢的氢键接受体取代基取代的苯并呋喃酮衍生物及其在聚丙烯中的应用 |
| KR20140144704A (ko) | 2012-03-20 | 2014-12-19 | 바스프 에스이 | 폴리아미드 수지의 고체 상태 특성을 개선하기 위한 우레아 화합물 |
| EP2828329B1 (en) | 2012-03-20 | 2015-12-30 | Basf Se | Polyamide compositions with improved optical properties |
| WO2013139799A1 (en) | 2012-03-20 | 2013-09-26 | Basf Se | Isoindolo[2,1-a]quinazoline derivatives for stabilization of organic materials |
| US9328219B2 (en) | 2012-03-20 | 2016-05-03 | Basf Se | Polyamide compositions with improved optical properties |
| JP6155683B2 (ja) * | 2012-05-23 | 2017-07-05 | 横浜ゴム株式会社 | ゴム組成物および空気入りタイヤ |
| WO2013188490A1 (en) | 2012-06-13 | 2013-12-19 | Cytec Technology Corp. | Stabilizer compositions containing substituted chroman compounds and methods of use |
| CN104428291B (zh) * | 2012-07-13 | 2016-09-07 | 巴斯夫欧洲公司 | 作为有机材料稳定剂的二-[3-(7-叔丁基-2-氧代-3-苯基-3h-苯并呋喃-5-基)丙酰基]聚乙二醇衍生物 |
| AR092742A1 (es) | 2012-10-02 | 2015-04-29 | Intermune Inc | Piridinonas antifibroticas |
| CN105358528B (zh) | 2013-07-08 | 2021-07-20 | 巴斯夫欧洲公司 | 新型光稳定剂 |
| MX385675B (es) | 2013-09-27 | 2025-03-18 | Basf Se | Composiciones de poliolefina para materiales de construccion. |
| US20160237063A1 (en) | 2013-10-17 | 2016-08-18 | Basf Se | Hindered amine light stabilizers |
| EP3068839B1 (en) | 2013-10-29 | 2019-01-16 | Basf Se | The use of 2-(2-hydroxyphenyl)benzotriazole compounds as an uv absorbing agent in coatings |
| WO2015077635A2 (en) | 2013-11-22 | 2015-05-28 | Polnox Corporation | Macromolecular antioxidants based on dual type moiety per molecule: structures methods of making and using the same |
| EP2876126A1 (en) | 2013-11-25 | 2015-05-27 | Basf Se | A stabilizer mixture |
| TWI685524B (zh) | 2013-12-17 | 2020-02-21 | 美商畢克美國股份有限公司 | 預先脫層之層狀材料 |
| EP3428228B1 (en) * | 2014-02-17 | 2020-11-25 | Basf Se | 3-phenyl-benzofuran-2-one derivatives containing phosphorus as stabilizers |
| US9718775B2 (en) * | 2014-03-14 | 2017-08-01 | Milliken & Company | Oxindole compounds and compositions comprising the same |
| KR102373700B1 (ko) | 2014-04-02 | 2022-03-11 | 인터뮨, 인크. | 항섬유성 피리디논 |
| US9732254B2 (en) | 2014-04-29 | 2017-08-15 | Basf Se | Multi-layered film and the use thereof |
| MA39529B1 (fr) | 2014-05-15 | 2018-11-30 | Basf Se | Agent stabilisant hautement efficace |
| CA2955260C (en) | 2014-08-05 | 2022-06-28 | Basf Se | 3-phenyl-benzofuran-2-one diphosphite derivatives as stabilizers |
| CN104447647B (zh) * | 2014-10-31 | 2017-05-10 | 优缔股份有限公司 | 一种3‑芳基苯并呋喃酮化合物及其构成的组合物 |
| CA2870027C (en) | 2014-11-07 | 2022-04-26 | Matthew Zaki Botros | Blow molding composition and process |
| EP3050919A1 (de) | 2015-01-29 | 2016-08-03 | Basf Se | Lignocellulosehaltige materialen enthaltend mischungen mit salzen von n-substituierten carbamidsäuren |
| SA116370295B1 (ar) | 2015-02-20 | 2016-12-06 | باسف اس اى | رقائق، وأشرطة وفتائل أحادية من البولي أوليفين مثبتة للضوء |
| EP3564299B1 (en) | 2015-07-20 | 2023-09-06 | Basf Se | Flame retardant polyolefin articles |
| MX2018001214A (es) | 2015-07-27 | 2018-04-24 | Basf Se | Mezcla aditiva. |
| ES2814128T3 (es) | 2015-08-10 | 2021-03-26 | Basf Se | Derivados de 3-fenil-benzofuran-2-ona que contienen fósforo como estabilizadores |
| CA2913280C (en) | 2015-11-25 | 2022-07-26 | Nova Chemicals Corporation | Phenol free stabilization of polyethylene |
| PL3405519T3 (pl) | 2016-01-21 | 2020-04-30 | Basf Se | Mieszanina dodatków do stabilizacji poliolu i poliuretanu |
| MY199339A (en) | 2016-09-12 | 2023-10-24 | Basf Se | Additive mixture |
| CA2953610A1 (en) | 2017-01-05 | 2018-07-05 | Nova Chemicals Corporation | Mixed phosphite stabilization of polyethylene film |
| BR112019016446A2 (pt) | 2017-02-09 | 2020-04-07 | Dow Global Technologies Llc | espuma de poliuretano com baixos níveis de emissões de aldeído |
| CN110446732A (zh) | 2017-02-20 | 2019-11-12 | 陶氏环球技术有限责任公司 | 具有降低的醛排放的聚氨酯 |
| AU2018246964B2 (en) | 2017-03-28 | 2023-08-17 | Basf Se | Light stabilizer mixture |
| TWI788348B (zh) | 2017-05-03 | 2023-01-01 | 德商巴地斯顏料化工廠 | 成核劑、其製造方法及相關聚合物組合物 |
| IT201700073726A1 (it) | 2017-06-30 | 2018-12-30 | 3V Sigma Spa | Ammine impedite polimeriche |
| WO2019008002A1 (en) | 2017-07-03 | 2019-01-10 | Basf Se | PHENOLIC METAL SALTS AND THEIR PHENOLIC ACIDS AS STABILIZERS OF POLYMERS |
| JP2020526609A (ja) | 2017-07-06 | 2020-08-31 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | ベンゾフラノンおよびヒンダードフェノール系酸化防止剤を含む安定化ポリオレフィン組成物 |
| JP7326168B2 (ja) | 2017-07-06 | 2023-08-15 | ビーエーエスエフ ソシエタス・ヨーロピア | ポリエチレンパイプ |
| IT201700078234A1 (it) | 2017-07-11 | 2019-01-11 | 3V Sigma Spa | Ammine impedite |
| CA3072577A1 (en) | 2017-09-18 | 2019-03-21 | Basf Se | Additive mixture |
| JP7220536B2 (ja) * | 2017-09-27 | 2023-02-10 | 住友化学株式会社 | 塩、酸発生剤、レジスト組成物及びレジストパターンの製造方法 |
| US10947370B2 (en) | 2018-01-22 | 2021-03-16 | Milliken & Company | 3-phenyl-3H-1-benzofuran-2-one compounds and compositions comprising the same |
| US11773277B2 (en) | 2018-04-04 | 2023-10-03 | Basf Se | Use of an ultraviolet radiation absorbing polymer composition (UVRAP) as an UV absorbing agent in a coating for non-living and non-keratinous materials |
| WO2019192943A1 (en) | 2018-04-04 | 2019-10-10 | Basf Se | Use of an ultraviolet radiation absorbing composition as a light stabilizer for a shaped artificial polymer article |
| AU2019289707A1 (en) | 2018-06-21 | 2021-01-07 | Basf Se | 3-phenyl-benzofuran-2-one diphosphate derivatives as stabilizers |
| CN112585184B (zh) | 2018-08-02 | 2023-04-11 | 陶氏环球技术有限责任公司 | 减少聚氨酯泡沫中醛排放的方法 |
| WO2020024231A1 (en) | 2018-08-02 | 2020-02-06 | Dow Global Technologies Llc | Methods for reducing aldehyde emissions in polyurethane foams |
| WO2020024233A1 (en) | 2018-08-02 | 2020-02-06 | Dow Global Technologies Llc | Methods for reducing aldehyde emissions in polyurethane foams |
| WO2020024235A1 (en) | 2018-08-02 | 2020-02-06 | Dow Global Technologies Llc | Methods for reducing aldehyde emissions in polyurethane foams |
| US20210301102A1 (en) | 2018-08-22 | 2021-09-30 | Basf Se | Stabilized rotomolded polyolefin |
| US12269938B2 (en) | 2018-12-04 | 2025-04-08 | Basf Se | Polyethylene or polypropylene articles |
| JP7512286B2 (ja) | 2018-12-21 | 2024-07-08 | ビーエーエスエフ ソシエタス・ヨーロピア | ポリプロピレン組成物 |
| EP3935052A1 (en) | 2019-03-08 | 2022-01-12 | Basf Se | Sterically hindered amine stabilizer mixtures |
| IL286206B1 (en) | 2019-03-12 | 2025-08-01 | Basf Se | Artificial polymer items designed |
| US20220282064A1 (en) | 2019-07-30 | 2022-09-08 | Basf Se | Stabilizer composition |
| KR102820284B1 (ko) | 2019-08-30 | 2025-06-16 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리에테르 폴리올 및 폴리우레탄 폼에서 알데히드 방출을 감소시키는 방법 |
| KR20220139320A (ko) | 2020-02-10 | 2022-10-14 | 바스프 에스이 | 광 안정화제 혼합물 |
| IL295819A (en) | 2020-02-26 | 2022-10-01 | Basf Se | Additive mixtures for rheology modification of polymers |
| MX2022010677A (es) | 2020-02-27 | 2022-09-23 | Basf Se | Composiciones de poliolefina. |
| ES2980582T3 (es) | 2020-04-07 | 2024-10-02 | Nova Chem Int Sa | Polietileno de alta densidad para artículos rígidos |
| CN116096803A (zh) | 2020-11-03 | 2023-05-09 | 巴斯夫欧洲公司 | 使用稳定剂混合物稳定有机材料的方法 |
| CA3201687A1 (en) | 2020-12-09 | 2022-06-16 | Gregor Huber | An organic material based shaped article |
| CN116547346A (zh) | 2020-12-09 | 2023-08-04 | 巴斯夫欧洲公司 | 添加剂混合物 |
| JP2022155208A (ja) | 2021-03-30 | 2022-10-13 | 住友化学株式会社 | 亜リン酸エステル化合物、その製造方法及びその用途 |
| EP4314141A1 (en) | 2021-04-01 | 2024-02-07 | Basf Se | Stabilizer mixture |
| CA3219591A1 (en) | 2021-05-21 | 2022-11-24 | Simon GUELEN | Stabilized polymer resin systems having heteropolyoxometalates for antimicrobial properties and uses thereof |
| JP2022183907A (ja) | 2021-05-31 | 2022-12-13 | 住友化学株式会社 | 亜リン酸エステル組成物 |
| JP7670567B2 (ja) | 2021-07-15 | 2025-04-30 | 住友化学株式会社 | フェノール化合物、有機材料用安定剤、樹脂組成物、及び有機材料の安定化方法 |
| WO2023001717A1 (en) | 2021-07-17 | 2023-01-26 | Basf Se | An additive mixture for stabilization of organic material |
| MX2024002731A (es) | 2021-09-02 | 2024-03-20 | Basf Se | Combinacion de estabilizantes para prevenir la degradacion de polimeros sinteticos. |
| TW202323421A (zh) | 2021-09-16 | 2023-06-16 | 德商巴地斯顏料化工廠 | 穩定劑調配物 |
| CN113831309B (zh) * | 2021-09-22 | 2023-02-24 | 湖北大学 | 基于氧化苯并呋喃结构光驱动分子马达的制备方法 |
| US20250145796A1 (en) * | 2021-10-22 | 2025-05-08 | Mitsubishi Gas Chemical Company, Inc. | Thermoplastic resin composition, molded article, and method for producing and method for improving transmittance of thermoplastic resin composition |
| CN116396250B (zh) * | 2021-12-20 | 2025-04-08 | 天津利安隆新材料股份有限公司 | 苯二甲酸酯型苯并呋喃酮类化合物、其制备方法及应用 |
| WO2023118015A1 (en) | 2021-12-21 | 2023-06-29 | Basf Se | Environmental attributes for care composition ingredients |
| US20250145792A1 (en) | 2022-01-01 | 2025-05-08 | Cytec Industries Inc. | Polymer compositions having densification accelerators and rotational molding processes for making hollow articles therefrom |
| KR20240137607A (ko) | 2022-01-18 | 2024-09-20 | 바스프 에스이 | 독립-기포 금속 산화물 입자를 갖는 성형된 인공 중합체 물품 |
| WO2023141089A1 (en) | 2022-01-18 | 2023-07-27 | Basf Se | Shaped artificial polymer articles with hybrid metal oxide particles |
| JP2023128376A (ja) | 2022-03-03 | 2023-09-14 | 住友化学株式会社 | 加工安定剤、有機材料組成物、及び有機材料の安定化方法。 |
| WO2023202971A1 (en) | 2022-04-20 | 2023-10-26 | Basf Se | An aqueous antioxidant suspoemulsion and a process for preparing the same |
| AU2023277700A1 (en) | 2022-05-24 | 2024-12-05 | Basf Se | Polycarbonate composition containing combination of hydroxyphenyl triazines and uv absorbers |
| CN119731255A (zh) | 2022-08-19 | 2025-03-28 | 巴斯夫欧洲公司 | 添加剂用于改善聚乙烯的加工的用途 |
| CN119855855A (zh) | 2022-09-07 | 2025-04-18 | 巴斯夫欧洲公司 | 用自由基引发剂和硫代尿烷对聚合物进行流变学改性 |
| WO2024068415A1 (en) | 2022-09-29 | 2024-04-04 | Basf Se | Co-stabilizers for hydroxyphenyl triazine stabilized polymers |
| JP2024053404A (ja) | 2022-10-03 | 2024-04-15 | 住友化学株式会社 | 安定剤、有機材料組成物、及び有機材料の安定化方法 |
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| JP2024100231A (ja) | 2023-01-13 | 2024-07-26 | 住友化学株式会社 | 加工安定剤、樹脂組成物、および有機材料の安定化方法。 |
| CN120615102A (zh) | 2023-01-16 | 2025-09-09 | 巴斯夫欧洲公司 | 用于稳定的聚氨酯的苯基三嗪共稳定剂 |
| CN120530161A (zh) | 2023-01-16 | 2025-08-22 | 巴斯夫欧洲公司 | 用于稳定的聚酯的羟基苯基三嗪共稳定剂 |
| WO2024208842A1 (en) | 2023-04-04 | 2024-10-10 | Basf Se | Thermoplastic polymer compositions containing stabiliser mixtures |
| WO2025087886A1 (en) | 2023-10-26 | 2025-05-01 | Basf Se | Polyolefin pipe comprising a hydrotalcite mineral and a hydrazide |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2535058A (en) * | 1947-03-03 | 1950-12-26 | Universal Oil Prod Co | Stabilization process |
| LU37064A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1958-04-04 | Hercules Powder Co Ltd | ||
| US2968645A (en) * | 1958-08-25 | 1961-01-17 | Dow Chemical Co | Synthetic rubber emulsion polymerizations in the presence of alpha or beta conidendrol |
| US3043775A (en) * | 1959-07-24 | 1962-07-10 | Thomas H Coffield | Organic material containing a 4, 4'-methylenebis phenol |
| BE605950A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1960-07-11 | |||
| US3275595A (en) * | 1963-03-07 | 1966-09-27 | Hercules Inc | Polyolefins of improved light stability and dry receptivity containing chromium phenolates |
| US3370063A (en) * | 1964-10-05 | 1968-02-20 | Mcneilab Inc | Substituted dimethoxy indoles and method of making the same |
| US3325499A (en) * | 1964-11-02 | 1967-06-13 | Mcneilab Inc | 1-(1-hydrocarbyl-4-piperdyl)-2-indolinone |
| US3547947A (en) * | 1967-04-21 | 1970-12-15 | Sandoz Ag | Nitrogen-containing tricyclic compounds |
| US3454524A (en) * | 1967-12-14 | 1969-07-08 | Bell Telephone Labor Inc | Polyolefins stabilized with substituted indoles |
| US3428649A (en) * | 1968-01-23 | 1969-02-18 | Mcneilab Inc | Oxindole derivatives |
| US3577430A (en) * | 1969-02-17 | 1971-05-04 | Mcneilab Inc | Oxindole acetic acid amides |
| US3751417A (en) * | 1971-08-12 | 1973-08-07 | American Cyanamid Co | 1-acyl-3-(2-(4-phenyl-1-piperazinyl)ethyl)indolines |
| US3862133A (en) * | 1973-04-30 | 1975-01-21 | Goodrich Co B F | Gamma-lactones of o-hydroxyphenylacetic acids |
| DE2519583A1 (de) * | 1975-05-02 | 1976-11-18 | Basf Ag | Thermoplastische polybutylenterephthalat-formmassen |
| US4053613A (en) * | 1975-09-17 | 1977-10-11 | E. R. Squibb & Sons, Inc. | 1,3,thiazolinyl and 1,3 thiazinyl substituted indolinones |
| FR2328014A1 (fr) * | 1975-10-14 | 1977-05-13 | Rhone Poulenc Ind | Stabilisation des polymeres du chlorure de vinyle a l'aide de composes lactoniques |
| GB2044272B (en) * | 1979-02-05 | 1983-03-16 | Sandoz Ltd | Stabilising polymers |
-
1980
- 1980-02-01 GB GB8003482A patent/GB2044272B/en not_active Expired
- 1980-02-01 GB GB8003483A patent/GB2042562B/en not_active Expired
- 1980-02-04 CA CA345,017A patent/CA1134094A/en not_active Expired
- 1980-02-04 CA CA000345018A patent/CA1150257A/en not_active Expired
- 1980-02-04 US US06/118,054 patent/US4325863A/en not_active Expired - Lifetime
- 1980-02-04 US US06/118,011 patent/US4338244A/en not_active Expired - Lifetime
- 1980-02-05 IT IT47806/80A patent/IT1188889B/it active
- 1980-02-05 DE DE80CH8000017D patent/DE3030673D2/de not_active Expired
- 1980-02-05 WO PCT/CH1980/000017 patent/WO1980001566A1/de active Application Filing
- 1980-02-05 JP JP55500338A patent/JPS6326771B2/ja not_active Expired
- 1980-02-05 BR BR8006453A patent/BR8006453A/pt unknown
- 1980-02-05 FR FR8002417A patent/FR2464278A1/fr active Granted
- 1980-02-05 NL NL8020018A patent/NL8020018A/nl not_active Application Discontinuation
- 1980-02-05 CH CH749580A patent/CH645908A5/de not_active IP Right Cessation
- 1980-02-05 FR FR8002418A patent/FR2449106B1/fr not_active Expired
- 1980-02-05 ES ES488290A patent/ES488290A0/es active Granted
- 1980-09-22 FR FR8020309A patent/FR2460943A1/fr active Granted
- 1980-10-03 SE SE8006932A patent/SE443570B/sv not_active IP Right Cessation
- 1980-10-03 NO NO802930A patent/NO802930L/no unknown
- 1980-10-03 FR FR8021217A patent/FR2464261A1/fr active Granted
-
1981
- 1981-12-28 US US06/335,066 patent/US4611016A/en not_active Expired - Lifetime
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