BRPI0413493B1 - composição para formar composições poliméricas de poliuretano, uso da composição, e, método para formar um polímero a base de poliuretano - Google Patents
composição para formar composições poliméricas de poliuretano, uso da composição, e, método para formar um polímero a base de poliuretano Download PDFInfo
- Publication number
- BRPI0413493B1 BRPI0413493B1 BRPI0413493-1A BRPI0413493A BRPI0413493B1 BR PI0413493 B1 BRPI0413493 B1 BR PI0413493B1 BR PI0413493 A BRPI0413493 A BR PI0413493A BR PI0413493 B1 BRPI0413493 B1 BR PI0413493B1
- Authority
- BR
- Brazil
- Prior art keywords
- polyurethane
- nano
- clay
- epoxy
- composition
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 110
- 239000004814 polyurethane Substances 0.000 title claims abstract description 43
- 229920002635 polyurethane Polymers 0.000 title claims abstract description 42
- 229920000642 polymer Polymers 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims abstract description 15
- 239000012802 nanoclay Substances 0.000 claims abstract description 39
- 239000004848 polyfunctional curative Substances 0.000 claims abstract description 23
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical class O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052615 phyllosilicate Inorganic materials 0.000 claims abstract description 6
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract description 4
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims abstract 3
- 229920005989 resin Polymers 0.000 claims description 32
- 239000011347 resin Substances 0.000 claims description 32
- 239000002114 nanocomposite Substances 0.000 claims description 21
- 125000003700 epoxy group Chemical group 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- -1 for example Substances 0.000 claims description 9
- 230000001070 adhesive effect Effects 0.000 claims description 8
- 239000011368 organic material Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- 239000000853 adhesive Substances 0.000 claims description 7
- 239000002131 composite material Substances 0.000 claims description 7
- 239000000835 fiber Substances 0.000 claims description 6
- 239000003973 paint Substances 0.000 claims description 6
- 150000004760 silicates Chemical class 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 5
- 239000012744 reinforcing agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 4
- 239000003607 modifier Substances 0.000 claims description 4
- 230000002787 reinforcement Effects 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000004645 aluminates Chemical class 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 239000003085 diluting agent Substances 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 150000004706 metal oxides Chemical class 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 239000013008 thixotropic agent Substances 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
- 150000004677 hydrates Chemical class 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 2
- 150000004692 metal hydroxides Chemical class 0.000 claims description 2
- 239000012778 molding material Substances 0.000 claims description 2
- 239000002808 molecular sieve Substances 0.000 claims description 2
- 239000012860 organic pigment Substances 0.000 claims description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 235000012222 talc Nutrition 0.000 claims description 2
- MSACGCINQCCHBD-UHFFFAOYSA-N 2,4-dioxo-4-(4-piperidin-1-ylphenyl)butanoic acid Chemical compound C1=CC(C(=O)CC(=O)C(=O)O)=CC=C1N1CCCCC1 MSACGCINQCCHBD-UHFFFAOYSA-N 0.000 claims 1
- KEZYHIPQRGTUDU-UHFFFAOYSA-N 2-[dithiocarboxy(methyl)amino]acetic acid Chemical compound SC(=S)N(C)CC(O)=O KEZYHIPQRGTUDU-UHFFFAOYSA-N 0.000 claims 1
- 229910052582 BN Inorganic materials 0.000 claims 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims 1
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 claims 1
- 229910052581 Si3N4 Inorganic materials 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 235000018660 ammonium molybdate Nutrition 0.000 claims 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims 1
- 239000000920 calcium hydroxide Substances 0.000 claims 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims 1
- 239000002274 desiccant Substances 0.000 claims 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims 1
- 239000000347 magnesium hydroxide Substances 0.000 claims 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims 1
- 239000000391 magnesium silicate Substances 0.000 claims 1
- 235000012243 magnesium silicates Nutrition 0.000 claims 1
- 230000003014 reinforcing effect Effects 0.000 claims 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims 1
- 229910052814 silicon oxide Inorganic materials 0.000 claims 1
- 125000005402 stannate group Chemical group 0.000 claims 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims 1
- VLCLHFYFMCKBRP-UHFFFAOYSA-N tricalcium;diborate Chemical class [Ca+2].[Ca+2].[Ca+2].[O-]B([O-])[O-].[O-]B([O-])[O-] VLCLHFYFMCKBRP-UHFFFAOYSA-N 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 239000004593 Epoxy Substances 0.000 abstract description 42
- 239000003822 epoxy resin Substances 0.000 abstract description 24
- 229920000647 polyepoxide Polymers 0.000 abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 23
- 239000012948 isocyanate Substances 0.000 abstract description 19
- 150000002513 isocyanates Chemical class 0.000 abstract description 18
- 239000000178 monomer Substances 0.000 abstract description 9
- 238000010521 absorption reaction Methods 0.000 abstract description 6
- 238000006243 chemical reaction Methods 0.000 description 23
- 238000009472 formulation Methods 0.000 description 23
- 150000001412 amines Chemical class 0.000 description 18
- 239000000463 material Substances 0.000 description 15
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 12
- 239000002105 nanoparticle Substances 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 8
- 125000003277 amino group Chemical group 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 230000009477 glass transition Effects 0.000 description 7
- 238000001157 Fourier transform infrared spectrum Methods 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 229910052901 montmorillonite Inorganic materials 0.000 description 6
- 230000035699 permeability Effects 0.000 description 6
- 239000004927 clay Substances 0.000 description 5
- 238000004132 cross linking Methods 0.000 description 5
- 150000002118 epoxides Chemical class 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 4
- 229920003986 novolac Polymers 0.000 description 4
- 229920000768 polyamine Polymers 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 230000009974 thixotropic effect Effects 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 3
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical group O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 239000011229 interlayer Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000004005 microsphere Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 229920001515 polyalkylene glycol Polymers 0.000 description 3
- 150000003141 primary amines Chemical group 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 2
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- 229920002748 Basalt fiber Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
- 229920000459 Nitrile rubber Polymers 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 238000005341 cation exchange Methods 0.000 description 2
- 150000001767 cationic compounds Chemical class 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000011258 core-shell material Substances 0.000 description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 2
- 239000000539 dimer Substances 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- VGEWEGHHYWGXGG-UHFFFAOYSA-N ethyl n-hydroxycarbamate Chemical compound CCOC(=O)NO VGEWEGHHYWGXGG-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 229910001411 inorganic cation Inorganic materials 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000012766 organic filler Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000011164 primary particle Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 150000003335 secondary amines Chemical class 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 150000003573 thiols Chemical class 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- ALKYHXVLJMQRLQ-UHFFFAOYSA-N 3-Hydroxy-2-naphthoate Chemical compound C1=CC=C2C=C(O)C(C(=O)O)=CC2=C1 ALKYHXVLJMQRLQ-UHFFFAOYSA-N 0.000 description 1
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229920003319 Araldite® Polymers 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 150000004984 aromatic diamines Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- IFDVQVHZEKPUSC-UHFFFAOYSA-N cyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCC=CC1C(O)=O IFDVQVHZEKPUSC-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- PWZFXELTLAQOKC-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide;tetrahydrate Chemical compound O.O.O.O.[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O PWZFXELTLAQOKC-UHFFFAOYSA-A 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000001962 electrophoresis Methods 0.000 description 1
- UPCIBFUJJLCOQG-UHFFFAOYSA-L ethyl-[2-[2-[ethyl(dimethyl)azaniumyl]ethyl-methylamino]ethyl]-dimethylazanium;dibromide Chemical compound [Br-].[Br-].CC[N+](C)(C)CCN(C)CC[N+](C)(C)CC UPCIBFUJJLCOQG-UHFFFAOYSA-L 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- 125000001072 heteroaryl group Chemical group 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- WJRBRSLFGCUECM-UHFFFAOYSA-N hydantoin Chemical compound O=C1CNC(=O)N1 WJRBRSLFGCUECM-UHFFFAOYSA-N 0.000 description 1
- 229940091173 hydantoin Drugs 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 125000001841 imino group Chemical group [H]N=* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000002649 leather substitute Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000004010 onium ions Chemical class 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- HWCKGOZZJDHMNC-UHFFFAOYSA-M tetraethylammonium bromide Chemical compound [Br-].CC[N+](CC)(CC)CC HWCKGOZZJDHMNC-UHFFFAOYSA-M 0.000 description 1
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G71/00—Macromolecular compounds obtained by reactions forming a ureide or urethane link, otherwise, than from isocyanate radicals in the main chain of the macromolecule
- C08G71/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Epoxy Resins (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Sealing Material Composition (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03255011A EP1506975A1 (en) | 2003-08-13 | 2003-08-13 | Nanocomposites based on polyurethane or polyurethane-epoxy hybrid resins prepared avoiding isocyanates |
| EP03255011.3 | 2003-08-13 | ||
| PCT/EP2004/051796 WO2005016993A1 (en) | 2003-08-13 | 2004-08-13 | Nanocomposites based on polyurethane or polyurethane-epoxy hybrid resins prepared avoiding isocyanates |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0413493A BRPI0413493A (pt) | 2006-10-17 |
| BRPI0413493B1 true BRPI0413493B1 (pt) | 2020-11-03 |
Family
ID=33560891
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0413493-1A BRPI0413493B1 (pt) | 2003-08-13 | 2004-08-13 | composição para formar composições poliméricas de poliuretano, uso da composição, e, método para formar um polímero a base de poliuretano |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US8143346B2 (enExample) |
| EP (2) | EP1506975A1 (enExample) |
| JP (1) | JP4772675B2 (enExample) |
| KR (1) | KR101097602B1 (enExample) |
| CN (1) | CN100528934C (enExample) |
| BR (1) | BRPI0413493B1 (enExample) |
| CA (1) | CA2534795C (enExample) |
| IN (1) | IN2006DE00554A (enExample) |
| WO (1) | WO2005016993A1 (enExample) |
Families Citing this family (78)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2595399C (en) * | 2005-01-24 | 2014-05-06 | Lubrizol Advanced Materials, Inc. | Aqueous dispersions of nanoparticle/polyurethane composites |
| WO2007062812A1 (en) * | 2005-11-30 | 2007-06-07 | Nv Bekaert Sa | Process for preparing a metal wire with a non-isocyanate polyurethane coating |
| JP5307714B2 (ja) | 2006-07-31 | 2013-10-02 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | 硬化性エポキシ樹脂系粘着組成物 |
| WO2008045270A1 (en) * | 2006-10-06 | 2008-04-17 | Henkel Ag & Co. Kgaa | Pumpable epoxy paste adhesives resistant to wash-off |
| US9005755B2 (en) | 2007-01-03 | 2015-04-14 | Applied Nanostructured Solutions, Llc | CNS-infused carbon nanomaterials and process therefor |
| US8951631B2 (en) | 2007-01-03 | 2015-02-10 | Applied Nanostructured Solutions, Llc | CNT-infused metal fiber materials and process therefor |
| US8951632B2 (en) | 2007-01-03 | 2015-02-10 | Applied Nanostructured Solutions, Llc | CNT-infused carbon fiber materials and process therefor |
| US8158217B2 (en) | 2007-01-03 | 2012-04-17 | Applied Nanostructured Solutions, Llc | CNT-infused fiber and method therefor |
| WO2009127000A1 (en) * | 2008-04-15 | 2009-10-22 | The University Of Queensland | Polymer composites having particles with mixed organic modifications |
| AU2010259234B2 (en) | 2009-02-17 | 2014-11-20 | Applied Nanostructured Solutions, Llc | Composites comprising carbon nanotubes on fiber |
| US8580342B2 (en) | 2009-02-27 | 2013-11-12 | Applied Nanostructured Solutions, Llc | Low temperature CNT growth using gas-preheat method |
| US20100227134A1 (en) | 2009-03-03 | 2010-09-09 | Lockheed Martin Corporation | Method for the prevention of nanoparticle agglomeration at high temperatures |
| US7820779B2 (en) * | 2009-03-13 | 2010-10-26 | Polymate, Ltd. | Nanostructured hybrid oligomer composition |
| US9111658B2 (en) | 2009-04-24 | 2015-08-18 | Applied Nanostructured Solutions, Llc | CNS-shielded wires |
| JP2012525012A (ja) | 2009-04-24 | 2012-10-18 | アプライド ナノストラクチャード ソリューションズ リミテッド ライアビリティー カンパニー | Ｃｎｔ浸出ｅｍｉ遮蔽複合材料及びコーティング |
| WO2010129234A2 (en) | 2009-04-27 | 2010-11-11 | Lockheed Martin Corporation | Cnt-based resistive heating for deicing composite structures |
| GB0912201D0 (en) | 2009-07-14 | 2009-08-26 | Imerys Minerals Ltd | Coating compositions |
| JP5823393B2 (ja) | 2009-08-03 | 2015-11-25 | アプライド ナノストラクチャード ソリューションズ リミテッド ライアビリティー カンパニーＡｐｐｌｉｅｄ Ｎａｎｏｓｔｒｕｃｔｕｒｅｄｓｏｌｕｔｉｏｎｓ， Ｌｌｃ | 複合繊維へのナノ粒子の組み込み |
| JP5799490B2 (ja) * | 2009-08-27 | 2015-10-28 | 住友化学株式会社 | 膨張抑制用組成物、多層構造体および基材の膨張の抑制方法 |
| BR112012009785B1 (pt) * | 2009-10-28 | 2021-03-02 | Dow Global Technologies Llc | composição e fio condutor eletricamente isolado |
| AU2010350690A1 (en) | 2009-11-23 | 2012-04-19 | Applied Nanostructured Solutions, Llc | CNT-tailored composite air-based structures |
| EP2504164A4 (en) | 2009-11-23 | 2013-07-17 | Applied Nanostructured Sols | CERAMIC COMPOSITE MATERIALS CONTAINING FIBER MATERIALS IMPREGNATED WITH CARBON NANOTUBES AND METHODS OF MAKING SAME |
| JP5367679B2 (ja) * | 2009-11-25 | 2013-12-11 | 大日精化工業株式会社 | 擬革 |
| US8951933B2 (en) | 2009-11-25 | 2015-02-10 | Dainichiseika Color & Chemicals Mfg. Co., Ltd. | Polysiloxane-modified polyhydroxy polyurethane resin, method for producing same, heat-sensitive recording material using the resin, imitation leather, thermoplastic polyolefin resin skin material, material for weather strip, and weather strip |
| JP2011132208A (ja) | 2009-11-25 | 2011-07-07 | Dainichiseika Color & Chem Mfg Co Ltd | ５員環環状カーボネートポリシロキサン化合物およびその製造方法 |
| RU2518095C2 (ru) * | 2009-11-26 | 2014-06-10 | Дайнитисейка Колор & Кемикалс Мфг. Ко., Лтд. | Полигидрокси-полиуретановая смола, модифицированная полисилоксаном, способ ее получения, содержащий эту смолу термочувствительный материал для записи, искусственная кожа, кожеподобный материал из термопластичной полиолефиновой смолы, материал для уплотнителя и уплотнитель |
| JP5705511B2 (ja) * | 2009-11-26 | 2015-04-22 | 大日精化工業株式会社 | ポリシロキサン変性ポリヒドロキシポリウレタン樹脂、該樹脂含有組成物及び樹脂の製造方法 |
| JP5456647B2 (ja) * | 2009-11-26 | 2014-04-02 | 大日精化工業株式会社 | 擬革 |
| KR20120104600A (ko) | 2009-12-14 | 2012-09-21 | 어플라이드 나노스트럭처드 솔루션스, 엘엘씨. | 탄소 나노튜브 주입된 섬유 물질을 포함하는 방염 복합재 물질 및 물품 |
| US9167736B2 (en) | 2010-01-15 | 2015-10-20 | Applied Nanostructured Solutions, Llc | CNT-infused fiber as a self shielding wire for enhanced power transmission line |
| EP2531558B1 (en) | 2010-02-02 | 2018-08-22 | Applied NanoStructured Solutions, LLC | Carbon nanotube-infused fiber materials containing parallel-aligned carbon nanotubes, methods for production thereof, and composite materials derived therefrom |
| WO2011109480A2 (en) | 2010-03-02 | 2011-09-09 | Applied Nanostructed Solution, Llc | Spiral wound electrical devices containing carbon nanotube-infused electrode materials and methods and apparatuses for production thereof |
| AU2011223743A1 (en) | 2010-03-02 | 2012-08-30 | Applied Nanostructured Solutions,Llc | Electrical devices containing carbon nanotube-infused fibers and methods for production thereof |
| JP5998931B2 (ja) * | 2010-06-10 | 2016-09-28 | 日産化学工業株式会社 | 液晶配向処理剤、液晶配向膜、及び液晶表示素子 |
| WO2011155576A1 (ja) | 2010-06-10 | 2011-12-15 | 日産化学工業株式会社 | 液晶配向処理剤、液晶配向膜及び液晶表示素子 |
| US8780526B2 (en) | 2010-06-15 | 2014-07-15 | Applied Nanostructured Solutions, Llc | Electrical devices containing carbon nanotube-infused fibers and methods for production thereof |
| EP2586814B1 (en) | 2010-06-24 | 2016-01-20 | Dainichiseika Color & Chemicals Mfg. Co., Ltd. | Self-crosslinkable polyhydroxy polyurethane resin, resinaceous material that contains the resin, process for production of the resin, and imitation leather, surfacing material and weatherstrip material, using the resin |
| JP5554173B2 (ja) * | 2010-07-29 | 2014-07-23 | 大日精化工業株式会社 | 熱可塑性ポリオレフィン樹脂製の表皮材 |
| JP5596435B2 (ja) * | 2010-06-24 | 2014-09-24 | 大日精化工業株式会社 | 自己架橋型ポリヒドロキシポリウレタン樹脂およびその製造方法 |
| JP5554156B2 (ja) * | 2010-06-24 | 2014-07-23 | 大日精化工業株式会社 | 擬革 |
| US9096717B2 (en) * | 2010-07-05 | 2015-08-04 | Bayer Intellectual Property Gmbh | Process for the preparation of polyol mixtures |
| CN103270071B (zh) | 2010-08-26 | 2014-11-26 | 大日精化工业株式会社 | 自交联型聚硅氧烷改性多羟基聚氨酯树脂、含有该树脂的树脂材料、该树脂的制造方法、使用该树脂形成的人造革及热塑性聚烯烃表皮材料 |
| US9017854B2 (en) | 2010-08-30 | 2015-04-28 | Applied Nanostructured Solutions, Llc | Structural energy storage assemblies and methods for production thereof |
| US8604091B2 (en) | 2010-09-03 | 2013-12-10 | Owens Corning Intellectual Capital, Llc | Non-isocyanate spray foam |
| CN104475313B (zh) | 2010-09-14 | 2017-05-17 | 应用奈米结构公司 | 长有碳纳米管玻璃基板及其制造方法 |
| EP2619133A1 (en) | 2010-09-22 | 2013-07-31 | Applied NanoStructured Solutions, LLC | Carbon fiber substrates having carbon nanotubes grown thereon and processes for production thereof |
| EP2619767A2 (en) | 2010-09-23 | 2013-07-31 | Applied NanoStructured Solutions, LLC | Cnt-infused fiber as a self shielding wire for enhanced power transmission line |
| JP5892323B2 (ja) | 2011-03-02 | 2016-03-23 | Jsr株式会社 | 液晶表示素子の製造方法 |
| WO2012137726A1 (ja) | 2011-04-04 | 2012-10-11 | 大日精化工業株式会社 | 自己架橋型ポリシロキサン変性ポリヒドロキシポリウレタン樹脂、該樹脂の製造方法、該樹脂を含む樹脂材料および該樹脂を利用した擬革 |
| AU2012298491B2 (en) * | 2011-08-22 | 2014-07-10 | Sylvia R. Hofmann | Isocyanate free polymers and methods of their production |
| FR2981931B1 (fr) | 2011-10-28 | 2014-07-04 | Gen Produits Ind S E G Soc D Expl | Procede de preparation d'un compose comprenant au moins un motif beta-hydroxy-urethane et/ou au moins un motif gamma-hydroxy-urethane. |
| US8664040B2 (en) * | 2011-12-20 | 2014-03-04 | Taiwan Semiconductor Manufacturing Company, Ltd. | Exposing connectors in packages through selective treatment |
| US9085464B2 (en) | 2012-03-07 | 2015-07-21 | Applied Nanostructured Solutions, Llc | Resistance measurement system and method of using the same |
| JP5936272B2 (ja) * | 2012-11-12 | 2016-06-22 | 大日精化工業株式会社 | 太陽電池モジュール用バックシート |
| FR2999591B1 (fr) * | 2012-12-19 | 2015-02-13 | Arkema France | Resine organique porteuse de groupements carbonates cycliques et dispersion aqueuse pour polyurethanes reticules |
| US9228058B2 (en) | 2013-03-15 | 2016-01-05 | EcoSurg | Comfort apparatus and method of manufacture |
| JP6050726B2 (ja) * | 2013-06-25 | 2016-12-21 | 大日精化工業株式会社 | 粘土鉱物含有ポリヒドロキシウレタン樹脂組成物の製造方法、粘土鉱物含有ポリヒドロキシウレタン樹脂組成物及び該組成物を用いたガスバリア性フィルム |
| CN103360906A (zh) * | 2013-07-24 | 2013-10-23 | 张运泉 | 磁环用环氧非异氰酸酯聚氨酯绝缘漆 |
| US10442914B2 (en) | 2013-08-13 | 2019-10-15 | 3M Innovative Properties Company | Nanocomposites containing silica nanoparticles and dispersant, composites, articles, and methods of making same |
| TWI504734B (zh) * | 2013-12-31 | 2015-10-21 | Ind Tech Res Inst | 防火耐燃複合材料、板材與塗層 |
| US9062160B1 (en) | 2014-01-23 | 2015-06-23 | International Business Machines Corporation | Catalyst-free methods of forming polyurethanes from pentafluorophenyl carbonates |
| US9260564B2 (en) | 2014-03-03 | 2016-02-16 | Dow Global Technologies Llc | Catalyst for non-isocyanate based polyurethane |
| JP6298421B2 (ja) * | 2015-04-28 | 2018-03-20 | 大日精化工業株式会社 | ポリヒドロキシウレタン水分散体組成物、及び該水分散体組成物を用いてなるガスバリア性水性コーティング剤、ガスバリア性フィルム |
| CN105111411B (zh) * | 2015-05-07 | 2018-03-02 | 山西誉邦科技有限公司 | 一种环氧改性聚氨酯‑水玻璃复合注浆材料 |
| JP6803343B2 (ja) * | 2015-06-30 | 2020-12-23 | エボニック オペレーションズ ゲーエムベーハー | イソシアネート非含有反応性ポリウレタン組成物 |
| US9957356B2 (en) * | 2015-08-17 | 2018-05-01 | Elevance Renewable Sciences, Inc. | Non-isocyanate polyurethanes and methods of making and using the same |
| WO2017156132A1 (en) | 2016-03-08 | 2017-09-14 | 3D Systems, Incorporated | Non-isocyanate polyurethane inks for 3d printing |
| US20180274107A1 (en) * | 2017-03-22 | 2018-09-27 | Hamilton Sundstrand Corporation | Corrosion protection via nanomaterials |
| EP3668917A1 (en) * | 2017-08-17 | 2020-06-24 | Basf Se | Process for the manufacturing of a polymer with urethane groups |
| TWI663188B (zh) * | 2017-09-08 | 2019-06-21 | 國立清華大學 | 聚氨酯樹脂的製備方法 |
| EP3755740A1 (en) | 2018-02-21 | 2020-12-30 | Cryovac, LLC | Method and formulation for an isocyanate-free foam using isocyanate-free polyurethane chemistry |
| EP3760664A1 (en) * | 2019-07-05 | 2021-01-06 | Université de Liège | Self-blowing isocyanate-free polyurethane foams |
| US11932774B2 (en) | 2019-07-29 | 2024-03-19 | The University Of Akron | Waterborne isocyanate-free polyurethane epoxy hybrid coatings |
| US11920033B2 (en) | 2019-10-05 | 2024-03-05 | 62911255 | Non-isocyanate polyurethane foam composition and method of making the same |
| US11822117B2 (en) * | 2019-10-08 | 2023-11-21 | Corning Incorporated | Primary coating compositions with improved microbending performance |
| CN115074072B (zh) * | 2022-05-16 | 2023-06-27 | 青岛亿联建设集团股份有限公司 | 一种非开挖管道修复用聚氨酯胶粘剂及其加工工艺 |
| KR102749132B1 (ko) * | 2023-12-07 | 2025-01-03 | 주식회사 헵스켐 | 환경친화형 논 이소시아네이트 타입의 폴리우레탄 방수재 |
| CN117534421B (zh) * | 2024-01-09 | 2024-03-26 | 长江岩土工程有限公司 | 一种防渗材料、制备方法及在坝体建筑方面的应用 |
Family Cites Families (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3072613A (en) | 1957-08-20 | 1963-01-08 | Union Carbide Corp | Multiple cyclic carbonate polymers |
| US4066625A (en) | 1967-05-02 | 1978-01-03 | Amicon Corporation | Unitary curable resin compositions |
| FR1566468A (enExample) | 1968-03-04 | 1969-05-09 | ||
| DE2210837A1 (de) * | 1972-03-07 | 1973-09-20 | Bayer Ag | Verfahren zur herstellung von schaumstofformkoerpern |
| US4268656A (en) | 1980-01-16 | 1981-05-19 | National Starch And Chemical Corporation | Co-curing agents for epoxy resins |
| US4360649A (en) | 1980-04-30 | 1982-11-23 | Sumitomo Chemical Company, Limited | Curable composition |
| DE3170477D1 (en) * | 1980-07-11 | 1985-06-20 | Ici Plc | Foamed plastics laminates |
| DE3382736T2 (de) | 1982-09-21 | 1994-05-26 | Ajinomoto Kk | Latente Härter für Epoxyharze. |
| JPS6072917A (ja) | 1983-09-30 | 1985-04-25 | Ajinomoto Co Inc | エポキシ樹脂用潜在性硬化剤 |
| US4785615A (en) | 1983-11-28 | 1988-11-22 | Leigh Monstevens Keith V | Hydraulic shift for motor vehicle automatic transmission |
| US5134239A (en) | 1984-07-17 | 1992-07-28 | The Dow Chemical Company | Latent catalysts for epoxy-phenolic reactions |
| US4699974A (en) | 1986-08-07 | 1987-10-13 | General Electric Company | Method of preparing copolyester carbonate from cyclic aromatic polycarbonate oligomer and lactone |
| DE3617705A1 (de) | 1986-05-26 | 1987-12-03 | Hoechst Ag | Urethangruppenhaltige polymere, deren loesungen und deren waessrige dispersionen, verfahren zu ihrer herstellung und ihre verwendung |
| JPH0730253B2 (ja) | 1987-03-09 | 1995-04-05 | 株式会社豊田中央研究所 | 複合材料及びその製造方法 |
| SU1754748A1 (ru) | 1990-04-19 | 1992-08-15 | Всесоюзный Научно-Исследовательский Институт По Защите Металлов От Коррозии | Состав дл покрытий полов |
| US5548058A (en) | 1990-05-28 | 1996-08-20 | W. R. Grace & Co.-Conn. | Spherical curing agent for epoxy resin, curing agent masterbatch for epoxy resin and their preparation |
| JP3092249B2 (ja) | 1991-10-11 | 2000-09-25 | 味の素株式会社 | 酸無水物系一液性エポキシ樹脂組成物 |
| US5175231A (en) * | 1992-04-17 | 1992-12-29 | Fiber-Cote Corporation | Urethane oligomers and polyurethanes |
| EP0594133B1 (en) | 1992-10-22 | 1998-05-06 | Ajinomoto Co., Inc. | Polythiol epoxy resin composition with extended working life |
| US5407978A (en) | 1993-05-07 | 1995-04-18 | Minnesota Mining And Manufacturing Company | Rapid curing powder epoxy coating compositions having increased flexibility, incorporating minor amounts of aliphatic triepoxides |
| US5340889A (en) | 1993-07-19 | 1994-08-23 | Texaco Chemical Company | Liquification of bis-carbonates of bis-glycidyl ethers |
| US5464910A (en) | 1993-12-22 | 1995-11-07 | Shikoku Chemicals Corporation | Epoxy resin adduct combined with a borate ester and phenolic compound |
| JP3391074B2 (ja) | 1994-01-07 | 2003-03-31 | 味の素株式会社 | エポキシ樹脂組成物 |
| DE19512316A1 (de) * | 1995-04-01 | 1996-10-02 | Hoechst Ag | Härtungsmittel für elastische Epoxidharz-Systeme |
| JP3579959B2 (ja) * | 1995-04-17 | 2004-10-20 | 大日本インキ化学工業株式会社 | 半導体封止材料 |
| US5733954A (en) | 1995-12-14 | 1998-03-31 | Minnesota Mining And Manufacturing Company | Epoxy resin curing agent made via aqueous dispersion of an epoxide and an imidazole |
| US5717011A (en) | 1995-12-14 | 1998-02-10 | Minnesota Mining And Manufacturing Company | Curing agent compositions and a method of making |
| JPH1030015A (ja) | 1996-07-15 | 1998-02-03 | Kansai Paint Co Ltd | エポキシ樹脂用硬化触媒及びそれを用いてなる熱硬化性塗料組成物 |
| US6218480B1 (en) | 1997-06-16 | 2001-04-17 | Mmr Technologies, Inc. | Water-compatible urethane-containing amine hardener |
| CN1297470A (zh) * | 1998-02-20 | 2001-05-30 | 范蒂科股份公司 | 亲有机物的页硅酸盐 |
| US6120905A (en) | 1998-06-15 | 2000-09-19 | Eurotech, Ltd. | Hybrid nonisocyanate polyurethane network polymers and composites formed therefrom |
| US6300049B2 (en) | 1998-10-15 | 2001-10-09 | Eastman Kodak Company | Imaging element containing an electrically-conductive layer |
| US6403670B1 (en) * | 1998-12-28 | 2002-06-11 | Nof Corporation | Thermosetting composition containing polyhemiacetal ester resin and powdery thermosetting composition |
| EP1020457A1 (en) | 1999-01-14 | 2000-07-19 | Polymate Ltd. | The method of synthesis polyfunctional polyclocarbonate oligomers and polymers formed therefrom |
| JP2000280243A (ja) * | 1999-03-30 | 2000-10-10 | Sumitomo Bakelite Co Ltd | プリプレグ及び積層板の製造方法 |
| EP1070733A1 (en) | 1999-07-21 | 2001-01-24 | Polymate Ltd. | Method of synthesis of polyaminofunctional hydroxyurethane oligomers and hybride polymers formed therefrom |
| US6303690B1 (en) * | 1999-12-15 | 2001-10-16 | Basf Corporation | Cathodic electrocoat having a carbamate functional resin and a carbamate functional reactive additive |
| US6737464B1 (en) * | 2000-05-30 | 2004-05-18 | University Of South Carolina Research Foundation | Polymer nanocomposite comprising a matrix polymer and a layered clay material having a low quartz content |
| EP1172407B1 (en) * | 2000-06-29 | 2009-06-10 | Kuraray Co., Ltd. | Aqueous adhesive dispersion containing a block copolymer and a polyurethane |
| US7166656B2 (en) * | 2001-11-13 | 2007-01-23 | Eastman Kodak Company | Smectite clay intercalated with polyether block polyamide copolymer |
| JP4004787B2 (ja) * | 2001-12-14 | 2007-11-07 | 新日本石油株式会社 | フェノール樹脂、エポキシ樹脂、その製造方法及び半導体封止材用樹脂組成物 |
-
2003
- 2003-08-13 EP EP03255011A patent/EP1506975A1/en not_active Withdrawn
-
2004
- 2004-08-13 KR KR1020067002858A patent/KR101097602B1/ko not_active Expired - Lifetime
- 2004-08-13 CA CA2534795A patent/CA2534795C/en not_active Expired - Lifetime
- 2004-08-13 US US10/567,945 patent/US8143346B2/en not_active Expired - Lifetime
- 2004-08-13 CN CNB2004800296791A patent/CN100528934C/zh not_active Expired - Lifetime
- 2004-08-13 WO PCT/EP2004/051796 patent/WO2005016993A1/en not_active Ceased
- 2004-08-13 EP EP04766498A patent/EP1656411A1/en not_active Withdrawn
- 2004-08-13 BR BRPI0413493-1A patent/BRPI0413493B1/pt active IP Right Grant
- 2004-08-13 JP JP2006523018A patent/JP4772675B2/ja not_active Expired - Lifetime
-
2006
- 2006-02-02 IN IN554DE2006 patent/IN2006DE00554A/en unknown
-
2012
- 2012-02-15 US US13/397,015 patent/US8450413B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP1656411A1 (en) | 2006-05-17 |
| JP2007501886A (ja) | 2007-02-01 |
| CN100528934C (zh) | 2009-08-19 |
| EP1506975A1 (en) | 2005-02-16 |
| US20070135588A1 (en) | 2007-06-14 |
| US8143346B2 (en) | 2012-03-27 |
| US20120149842A1 (en) | 2012-06-14 |
| CA2534795A1 (en) | 2005-02-24 |
| CA2534795C (en) | 2012-06-26 |
| JP4772675B2 (ja) | 2011-09-14 |
| IN2006DE00554A (enExample) | 2007-08-10 |
| WO2005016993A1 (en) | 2005-02-24 |
| BRPI0413493A (pt) | 2006-10-17 |
| KR20060071395A (ko) | 2006-06-26 |
| CN1867612A (zh) | 2006-11-22 |
| US8450413B2 (en) | 2013-05-28 |
| KR101097602B1 (ko) | 2011-12-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BRPI0413493B1 (pt) | composição para formar composições poliméricas de poliuretano, uso da composição, e, método para formar um polímero a base de poliuretano | |
| US20120296012A1 (en) | Room temperature ionic liquid-epoxy systems as dispersants and matrix materials for nanocomposites | |
| Triantafillidis et al. | Homostructured mixed inorganic− organic ion clays: a new approach to epoxy polymer− exfoliated clay nanocomposites with a reduced organic modifier content | |
| Brown et al. | Thermoset-layered silicate nanocomposites. Quaternary ammonium montmorillonite with primary diamine cured epoxies | |
| CA2540893C (en) | Two component curable compositions | |
| BRPI1102649B1 (pt) | Composição, e, compósito | |
| MXPA00002760A (es) | Nanocompuestos formados por medio de arcilla intercalada con iones de ionio y resinas epoxi endurecidas son anhidrido rigido. | |
| Jelić et al. | Design of halloysite modification for improvement of mechanical properties of the epoxy based nanocomposites | |
| JPH10505871A (ja) | 層状珪酸塩−エポキシナノ複合物 | |
| US12338383B2 (en) | 3D-printed polyrotaxane additives and compositions | |
| Fröhlich et al. | High‐performance epoxy hybrid nanocomposites containing organophilic layered silicates and compatibilized liquid rubber | |
| KR20120014942A (ko) | 열경화성 수지용 경화제로서 회합기를 갖는 분자의 용도 | |
| Gnanasekar et al. | Synthesis and thermo-mechanical properties of novel spirobiindane based epoxy nanocomposites with tryptophan as a green hardener: Curing kinetics using model free approach | |
| TW202023942A (zh) | 包含化學連結氟石墨衍生的奈米粒子之複合材料 | |
| EP2917252A1 (en) | Ncc as functional scaffold for amine-cured epoxy nanocomposite materials of tunable properties | |
| Jeon et al. | Synthesis of graphitic carbon nitride-based nanocomposites and their mechanical properties in epoxy compositions | |
| EP2826797A1 (de) | Härterkomponente, diese enthaltende Mörtelmasse und deren Verwendung | |
| KR100526761B1 (ko) | 유기-무기 나노복합재료 및 아미노실란 전구체를 이용한이의 제조방법 | |
| Ratna et al. | Nanoreinforcement of flexible epoxy using layered silicate | |
| Rajasekaran et al. | Synthesis, characterization and properties of organoclay-modified polysulfone/epoxy interpenetrating polymer network nanocomposites | |
| RU2749379C2 (ru) | Эпоксидная композиция холодного отверждения | |
| Fröhlich | Nanostructured thermoset resins and nanocomposites containing hyperbranched blockcopolyether liquid rubbers and organophilic layered silicates | |
| Siddans | Epoxy/clay nanocomposites: effect of clay and resin chemistry on cure and properties | |
| PL245698B1 (pl) | Kompozycja klejowa i sposób jej wytwarzania | |
| León et al. | Incorporation of silica nanospherical particles in epoxy–amine crosslinked materials II. Dynamic mechanical measurements of epoxy matrix-silica nanocomposites |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: INDEFIRO O PEDIDO DE ACORDO COM O(S) ARTIGO(S) DA LPI |
|
| B12B | Appeal against refusal [chapter 12.2 patent gazette] | ||
| B25A | Requested transfer of rights approved |
Owner name: HUNTSMAN ADVANCED MATERIALS LICENSING (SWITZERLAND |
|
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 03/11/2020, OBSERVADAS AS CONDICOES LEGAIS. |