AU777683B2 - Components and catalysts for the polymerization of olefins - Google Patents
Components and catalysts for the polymerization of olefins Download PDFInfo
- Publication number
- AU777683B2 AU777683B2 AU45486/00A AU4548600A AU777683B2 AU 777683 B2 AU777683 B2 AU 777683B2 AU 45486/00 A AU45486/00 A AU 45486/00A AU 4548600 A AU4548600 A AU 4548600A AU 777683 B2 AU777683 B2 AU 777683B2
- Authority
- AU
- Australia
- Prior art keywords
- catalyst component
- hydrogen
- diethyl
- formula
- solid catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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- 239000003054 catalyst Substances 0.000 title claims description 74
- 238000006116 polymerization reaction Methods 0.000 title claims description 56
- 150000001336 alkenes Chemical class 0.000 title claims description 28
- 239000011949 solid catalyst Substances 0.000 claims description 59
- 238000000034 method Methods 0.000 claims description 48
- 150000001875 compounds Chemical class 0.000 claims description 44
- 229910052739 hydrogen Inorganic materials 0.000 claims description 43
- 239000001257 hydrogen Substances 0.000 claims description 43
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 claims description 40
- -1 hydrocarbyl radical Chemical group 0.000 claims description 38
- 239000000203 mixture Substances 0.000 claims description 38
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 33
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 32
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims description 31
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 28
- 125000004432 carbon atom Chemical group C* 0.000 claims description 28
- 125000000217 alkyl group Chemical group 0.000 claims description 26
- 239000005977 Ethylene Substances 0.000 claims description 25
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 25
- 239000010936 titanium Substances 0.000 claims description 21
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 18
- 125000003118 aryl group Chemical group 0.000 claims description 14
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 14
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 13
- WGFNXLQURMLAGC-UHFFFAOYSA-N diethyl 2,3-di(propan-2-yl)butanedioate Chemical compound CCOC(=O)C(C(C)C)C(C(C)C)C(=O)OCC WGFNXLQURMLAGC-UHFFFAOYSA-N 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 125000005842 heteroatom Chemical group 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 12
- 229910052749 magnesium Inorganic materials 0.000 claims description 12
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 11
- 150000002148 esters Chemical class 0.000 claims description 11
- 229910052736 halogen Inorganic materials 0.000 claims description 10
- 229920001155 polypropylene Polymers 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 229910052719 titanium Inorganic materials 0.000 claims description 9
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- 150000002367 halogens Chemical class 0.000 claims description 8
- 229930195733 hydrocarbon Natural products 0.000 claims description 8
- ZWINORFLMHROGF-UHFFFAOYSA-N 9,9-bis(methoxymethyl)fluorene Chemical compound C1=CC=C2C(COC)(COC)C3=CC=CC=C3C2=C1 ZWINORFLMHROGF-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- 150000003377 silicon compounds Chemical group 0.000 claims description 7
- 150000007513 acids Chemical class 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
- 150000003609 titanium compounds Chemical class 0.000 claims description 6
- 150000002430 hydrocarbons Chemical group 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 4
- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 150000002170 ethers Chemical class 0.000 claims description 4
- 125000005498 phthalate group Chemical class 0.000 claims description 4
- 125000003342 alkenyl group Chemical group 0.000 claims description 3
- WNVMVIYFKFGESM-UHFFFAOYSA-N bis(2-methylpropyl) 2,3-di(propan-2-yl)butanedioate Chemical compound CC(C)COC(=O)C(C(C)C)C(C(C)C)C(=O)OCC(C)C WNVMVIYFKFGESM-UHFFFAOYSA-N 0.000 claims description 3
- VTCHFSNTCCVHRC-UHFFFAOYSA-N dibutyl 2,3-di(propan-2-yl)butanedioate Chemical compound CCCCOC(=O)C(C(C)C)C(C(C)C)C(=O)OCCCC VTCHFSNTCCVHRC-UHFFFAOYSA-N 0.000 claims description 3
- DODIKAULZAKDIN-UHFFFAOYSA-N diethyl 2,2-dimethylbutanedioate Chemical compound CCOC(=O)CC(C)(C)C(=O)OCC DODIKAULZAKDIN-UHFFFAOYSA-N 0.000 claims description 3
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 2
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims description 2
- FPGRDBPTRVSBLF-UHFFFAOYSA-N bis(2-methylpropyl) 2,2-dimethylbutanedioate Chemical compound CC(C)COC(=O)CC(C)(C)C(=O)OCC(C)C FPGRDBPTRVSBLF-UHFFFAOYSA-N 0.000 claims description 2
- WXZPTYMAKLPJMV-UHFFFAOYSA-N bis(2-methylpropyl) 2,3-dicyclohexyl-2-methylbutanedioate Chemical compound C1CCCCC1C(C)(C(=O)OCC(C)C)C(C(=O)OCC(C)C)C1CCCCC1 WXZPTYMAKLPJMV-UHFFFAOYSA-N 0.000 claims description 2
- RQRAFBDBIOAJDS-UHFFFAOYSA-N bis(2-methylpropyl) 2-ethyl-2-methylbutanedioate Chemical compound CC(C)COC(=O)C(C)(CC)CC(=O)OCC(C)C RQRAFBDBIOAJDS-UHFFFAOYSA-N 0.000 claims description 2
- NGYVWDKTEXNEAK-UHFFFAOYSA-N diethyl 2,3-dicyclohexyl-2-methylbutanedioate Chemical compound C1CCCCC1C(C)(C(=O)OCC)C(C(=O)OCC)C1CCCCC1 NGYVWDKTEXNEAK-UHFFFAOYSA-N 0.000 claims description 2
- DJHQJVJMROPIHP-UHFFFAOYSA-N diethyl 2-ethyl-2-methylbutanedioate Chemical compound CCOC(=O)CC(C)(CC)C(=O)OCC DJHQJVJMROPIHP-UHFFFAOYSA-N 0.000 claims description 2
- KHUNNBABXKBKAH-UHFFFAOYSA-N diethyl 3-(cyclohexylmethyl)-2-ethyl-2-methylbutanedioate Chemical compound CCOC(=O)C(C)(CC)C(C(=O)OCC)CC1CCCCC1 KHUNNBABXKBKAH-UHFFFAOYSA-N 0.000 claims description 2
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 claims description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims description 2
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims description 2
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 claims description 2
- 150000003254 radicals Chemical class 0.000 claims 9
- 150000003890 succinate salts Chemical class 0.000 claims 3
- 125000004367 cycloalkylaryl group Chemical group 0.000 claims 1
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical class [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 claims 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 claims 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 35
- 229920000642 polymer Polymers 0.000 description 34
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 28
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 28
- 150000003900 succinic acid esters Chemical class 0.000 description 24
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 22
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 239000001294 propane Substances 0.000 description 14
- 238000003756 stirring Methods 0.000 description 13
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 12
- 239000011777 magnesium Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 229910052757 nitrogen Inorganic materials 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 9
- 238000011282 treatment Methods 0.000 description 8
- 239000008096 xylene Substances 0.000 description 8
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 6
- 235000011147 magnesium chloride Nutrition 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 238000007334 copolymerization reaction Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000012044 organic layer Substances 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- HSCLUIKEZDGKBP-UHFFFAOYSA-N 2,3-di(propan-2-yl)butanedioic acid Chemical compound CC(C)C(C(O)=O)C(C(C)C)C(O)=O HSCLUIKEZDGKBP-UHFFFAOYSA-N 0.000 description 4
- XHLXMRJWRKQMCP-UHFFFAOYSA-N Diethyl methylsuccinate Chemical compound CCOC(=O)CC(C)C(=O)OCC XHLXMRJWRKQMCP-UHFFFAOYSA-N 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 4
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 4
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- HRAQMGWTPNOILP-UHFFFAOYSA-N 4-Ethoxy ethylbenzoate Chemical compound CCOC(=O)C1=CC=C(OCC)C=C1 HRAQMGWTPNOILP-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- 230000008878 coupling Effects 0.000 description 3
- 238000010168 coupling process Methods 0.000 description 3
- 238000005859 coupling reaction Methods 0.000 description 3
- 229940043279 diisopropylamine Drugs 0.000 description 3
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
- XRSDVKXFCVCMKF-UHFFFAOYSA-N 2-(2,2-dimethylpropyl)butanedioic acid Chemical compound C(C(C)(C)C)C(C(=O)O)CC(=O)O XRSDVKXFCVCMKF-UHFFFAOYSA-N 0.000 description 2
- GTOFKXZQQDSVFH-UHFFFAOYSA-N 2-benzylsuccinic acid Chemical compound OC(=O)CC(C(O)=O)CC1=CC=CC=C1 GTOFKXZQQDSVFH-UHFFFAOYSA-N 0.000 description 2
- LVFFZQQWIZURIO-UHFFFAOYSA-N 2-phenylbutanedioic acid Chemical compound OC(=O)CC(C(O)=O)C1=CC=CC=C1 LVFFZQQWIZURIO-UHFFFAOYSA-N 0.000 description 2
- YUXIBTJKHLUKBD-UHFFFAOYSA-N Dibutyl succinate Chemical compound CCCCOC(=O)CCC(=O)OCCCC YUXIBTJKHLUKBD-UHFFFAOYSA-N 0.000 description 2
- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 235000019502 Orange oil Nutrition 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 150000001934 cyclohexanes Chemical class 0.000 description 2
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- UIZHEHICSUOPQL-UHFFFAOYSA-N diethyl 2,3-dibenzylbutanedioate Chemical compound C=1C=CC=CC=1CC(C(=O)OCC)C(C(=O)OCC)CC1=CC=CC=C1 UIZHEHICSUOPQL-UHFFFAOYSA-N 0.000 description 2
- CXKANZAMPQTLBJ-UHFFFAOYSA-N diethyl 2,3-dicyclohexylbutanedioate Chemical compound C1CCCCC1C(C(=O)OCC)C(C(=O)OCC)C1CCCCC1 CXKANZAMPQTLBJ-UHFFFAOYSA-N 0.000 description 2
- DQNUPKXJISAAFG-UHFFFAOYSA-N diethyl 2,3-diethyl-2-propan-2-ylbutanedioate Chemical compound CCOC(=O)C(CC)C(CC)(C(C)C)C(=O)OCC DQNUPKXJISAAFG-UHFFFAOYSA-N 0.000 description 2
- GRVYPVYGTIWYIC-UHFFFAOYSA-N diethyl 2-(cyclohexylmethyl)butanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)CC1CCCCC1 GRVYPVYGTIWYIC-UHFFFAOYSA-N 0.000 description 2
- JZJPBADSXBZWAZ-UHFFFAOYSA-N diethyl 2-benzylbutanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)CC1=CC=CC=C1 JZJPBADSXBZWAZ-UHFFFAOYSA-N 0.000 description 2
- RQPNECGZAMRIRP-UHFFFAOYSA-N diethyl 2-cyclohexylbutanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)C1CCCCC1 RQPNECGZAMRIRP-UHFFFAOYSA-N 0.000 description 2
- LNJFNANUELFZBL-UHFFFAOYSA-N diethyl 2-methyl-2,3-di(propan-2-yl)butanedioate Chemical compound CCOC(=O)C(C(C)C)C(C)(C(C)C)C(=O)OCC LNJFNANUELFZBL-UHFFFAOYSA-N 0.000 description 2
- JVQDNCKPHSZFSO-UHFFFAOYSA-N diethyl 2-phenylbutanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)C1=CC=CC=C1 JVQDNCKPHSZFSO-UHFFFAOYSA-N 0.000 description 2
- YPLYFEUBZLLLIY-UHFFFAOYSA-N dipropan-2-yl butanedioate Chemical compound CC(C)OC(=O)CCC(=O)OC(C)C YPLYFEUBZLLLIY-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 239000010502 orange oil Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000012798 spherical particle Substances 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 239000003039 volatile agent Substances 0.000 description 2
- VFIOZKTXVHLWRA-UHFFFAOYSA-N (2-ethylpiperidin-1-yl)-dimethoxy-(1,1,1-trifluoropropan-2-yl)silane Chemical compound CCC1CCCCN1[Si](OC)(OC)C(C)C(F)(F)F VFIOZKTXVHLWRA-UHFFFAOYSA-N 0.000 description 1
- PJSFQEVODHCOOF-UHFFFAOYSA-N (2-ethylpiperidin-1-yl)-dimethoxy-(3,3,3-trifluoropropyl)silane Chemical compound CCC1CCCCN1[Si](CCC(F)(F)F)(OC)OC PJSFQEVODHCOOF-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- CDPPYCZVWYZBJH-UHFFFAOYSA-N 2,2,3,3-tetramethylbutanedioic acid Chemical compound OC(=O)C(C)(C)C(C)(C)C(O)=O CDPPYCZVWYZBJH-UHFFFAOYSA-N 0.000 description 1
- KJDGGLOKWHMBOX-UHFFFAOYSA-N 2,2,3-trimethylbutanedioic acid Chemical compound OC(=O)C(C)C(C)(C)C(O)=O KJDGGLOKWHMBOX-UHFFFAOYSA-N 0.000 description 1
- GOHPTLYPQCTZSE-UHFFFAOYSA-N 2,2-dimethylsuccinic acid Chemical compound OC(=O)C(C)(C)CC(O)=O GOHPTLYPQCTZSE-UHFFFAOYSA-N 0.000 description 1
- NVSRLSRGXUGMCX-UHFFFAOYSA-N 2,3-bis(2,2-dimethylpropyl)butanedioic acid Chemical compound CC(C)(C)CC(C(O)=O)C(C(O)=O)CC(C)(C)C NVSRLSRGXUGMCX-UHFFFAOYSA-N 0.000 description 1
- XAWQEEBNIPCURG-UHFFFAOYSA-N 2,3-bis(2-methylpropyl)butanedioic acid Chemical compound CC(C)CC(C(O)=O)C(C(O)=O)CC(C)C XAWQEEBNIPCURG-UHFFFAOYSA-N 0.000 description 1
- STZTXZMTXDIAOR-UHFFFAOYSA-N 2,3-bis(trimethylsilyl)butanedioic acid Chemical compound C[Si](C)(C)C(C(O)=O)C(C(O)=O)[Si](C)(C)C STZTXZMTXDIAOR-UHFFFAOYSA-N 0.000 description 1
- UVGKQRAGAYVWQV-UHFFFAOYSA-N 2,3-dimethylbutan-2-yl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(C)(C)C(C)C UVGKQRAGAYVWQV-UHFFFAOYSA-N 0.000 description 1
- UJSZYVBRRRWXIO-UHFFFAOYSA-N 2-(2-methylpropyl)-3-propan-2-ylbutanedioic acid Chemical compound CC(C)CC(C(O)=O)C(C(C)C)C(O)=O UJSZYVBRRRWXIO-UHFFFAOYSA-N 0.000 description 1
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- HSLLCWNHQWGGHZ-UHFFFAOYSA-N bis(2-methylpropyl) 2-methyl-2,3-di(propan-2-yl)butanedioate Chemical compound CC(C)COC(=O)C(C(C)C)C(C)(C(C)C)C(=O)OCC(C)C HSLLCWNHQWGGHZ-UHFFFAOYSA-N 0.000 description 1
- OZDHKWHZRMIESW-UHFFFAOYSA-N bis(2-methylpropyl) 2-methyl-2-(1,1,1-trifluoropropan-2-yl)butanedioate Chemical compound CC(C)COC(=O)CC(C)(C(C)C(F)(F)F)C(=O)OCC(C)C OZDHKWHZRMIESW-UHFFFAOYSA-N 0.000 description 1
- OJROLSYRLFEHDR-UHFFFAOYSA-N bis(2-methylpropyl) 2-methyl-2-propan-2-ylbutanedioate Chemical compound CC(C)COC(=O)CC(C)(C(C)C)C(=O)OCC(C)C OJROLSYRLFEHDR-UHFFFAOYSA-N 0.000 description 1
- JOWQRCCPCPOILK-UHFFFAOYSA-N bis(2-methylpropyl) 2-methyl-3-(3,3,3-trifluoropropyl)butanedioate Chemical compound CC(C)COC(=O)C(C)C(CCC(F)(F)F)C(=O)OCC(C)C JOWQRCCPCPOILK-UHFFFAOYSA-N 0.000 description 1
- QCOAPBRVQHMEPF-UHFFFAOYSA-N bis(2-methylpropyl) butanedioate Chemical compound CC(C)COC(=O)CCC(=O)OCC(C)C QCOAPBRVQHMEPF-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
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- 238000012512 characterization method Methods 0.000 description 1
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- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- MEWFSXFFGFDHGV-UHFFFAOYSA-N cyclohexyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C1CCCCC1 MEWFSXFFGFDHGV-UHFFFAOYSA-N 0.000 description 1
- ZXNUJAGOAPJBEV-UHFFFAOYSA-N dibutyl 2-ethylbutanedioate Chemical compound CCCCOC(=O)CC(CC)C(=O)OCCCC ZXNUJAGOAPJBEV-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- OZDDMYZVHZPZJS-UHFFFAOYSA-N diethyl 2,2,3,3-tetraethylbutanedioate Chemical compound CCOC(=O)C(CC)(CC)C(CC)(CC)C(=O)OCC OZDDMYZVHZPZJS-UHFFFAOYSA-N 0.000 description 1
- DRVYAVWIBGKJNA-UHFFFAOYSA-N diethyl 2,2,3,3-tetramethylbutanedioate Chemical compound CCOC(=O)C(C)(C)C(C)(C)C(=O)OCC DRVYAVWIBGKJNA-UHFFFAOYSA-N 0.000 description 1
- REHGOUOFAJQGSN-UHFFFAOYSA-N diethyl 2,2-bis(2-methylpropyl)butanedioate Chemical compound CCOC(=O)CC(CC(C)C)(CC(C)C)C(=O)OCC REHGOUOFAJQGSN-UHFFFAOYSA-N 0.000 description 1
- ZEKAIFREAFGGIC-UHFFFAOYSA-N diethyl 2,3-bis(2-ethylbutyl)butanedioate Chemical compound CCOC(=O)C(CC(CC)CC)C(CC(CC)CC)C(=O)OCC ZEKAIFREAFGGIC-UHFFFAOYSA-N 0.000 description 1
- AVLHXEDOBYYTGV-UHFFFAOYSA-N diethyl 2,3-bis(2-methylpropyl)butanedioate Chemical compound CCOC(=O)C(CC(C)C)C(CC(C)C)C(=O)OCC AVLHXEDOBYYTGV-UHFFFAOYSA-N 0.000 description 1
- OTUNNRWESSPIBH-UHFFFAOYSA-N diethyl 2,3-bis(trimethylsilyl)butanedioate Chemical compound CCOC(=O)C([Si](C)(C)C)C([Si](C)(C)C)C(=O)OCC OTUNNRWESSPIBH-UHFFFAOYSA-N 0.000 description 1
- MTFYCMNQWCTXII-UHFFFAOYSA-N diethyl 2,3-diethyl-2,3-di(propan-2-yl)butanedioate Chemical compound CCOC(=O)C(CC)(C(C)C)C(CC)(C(C)C)C(=O)OCC MTFYCMNQWCTXII-UHFFFAOYSA-N 0.000 description 1
- PYQDOTSNFYFMQJ-UHFFFAOYSA-N diethyl 2,3-diethylbutanedioate Chemical compound CCOC(=O)C(CC)C(CC)C(=O)OCC PYQDOTSNFYFMQJ-UHFFFAOYSA-N 0.000 description 1
- AMAMWUWLDQUKAP-UHFFFAOYSA-N diethyl 2,3-diphenylbutanedioate Chemical compound C=1C=CC=CC=1C(C(=O)OCC)C(C(=O)OCC)C1=CC=CC=C1 AMAMWUWLDQUKAP-UHFFFAOYSA-N 0.000 description 1
- WWIDLUJSQINFMG-UHFFFAOYSA-N diethyl 2,3-dipropylbutanedioate Chemical compound CCOC(=O)C(CCC)C(CCC)C(=O)OCC WWIDLUJSQINFMG-UHFFFAOYSA-N 0.000 description 1
- YMSISMQFJRKKET-UHFFFAOYSA-N diethyl 2-(1,1,1-trifluoropropan-2-yl)butanedioate Chemical compound CCOC(=O)CC(C(C)C(F)(F)F)C(=O)OCC YMSISMQFJRKKET-UHFFFAOYSA-N 0.000 description 1
- JGGZCPROKCVDLL-UHFFFAOYSA-N diethyl 2-(2,3-dimethylbutan-2-yl)butanedioate Chemical compound CCOC(=O)CC(C(C)(C)C(C)C)C(=O)OCC JGGZCPROKCVDLL-UHFFFAOYSA-N 0.000 description 1
- CJTCCDQONNMHTP-UHFFFAOYSA-N diethyl 2-(2-methylpropyl)-3-propan-2-ylbutanedioate Chemical compound CCOC(=O)C(CC(C)C)C(C(C)C)C(=O)OCC CJTCCDQONNMHTP-UHFFFAOYSA-N 0.000 description 1
- QILIJPUOBXQLLC-UHFFFAOYSA-N diethyl 2-(2-methylpropyl)butanedioate Chemical compound CCOC(=O)CC(CC(C)C)C(=O)OCC QILIJPUOBXQLLC-UHFFFAOYSA-N 0.000 description 1
- WAHPMEKTSDWXIH-UHFFFAOYSA-N diethyl 2-(3-methylbutyl)butanedioate Chemical compound CCOC(=O)CC(CCC(C)C)C(=O)OCC WAHPMEKTSDWXIH-UHFFFAOYSA-N 0.000 description 1
- XDNCCPSEVLZCHO-UHFFFAOYSA-N diethyl 2-(4-chlorophenyl)butanedioate;diethyl 2-phenylbutanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)C1=CC=CC=C1.CCOC(=O)CC(C(=O)OCC)C1=CC=C(Cl)C=C1 XDNCCPSEVLZCHO-UHFFFAOYSA-N 0.000 description 1
- GBEDNFHCEKAPAV-UHFFFAOYSA-N diethyl 2-(4-methoxyphenyl)butanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)C1=CC=C(OC)C=C1 GBEDNFHCEKAPAV-UHFFFAOYSA-N 0.000 description 1
- XJRRVTBMSAGXGY-UHFFFAOYSA-N diethyl 2-(9h-fluoren-9-yl)butanedioate Chemical compound C1=CC=C2C(C(CC(=O)OCC)C(=O)OCC)C3=CC=CC=C3C2=C1 XJRRVTBMSAGXGY-UHFFFAOYSA-N 0.000 description 1
- URZDPTYHEBVBEZ-UHFFFAOYSA-N diethyl 2-(cyclohexylmethyl)-2-(2-methylpropyl)butanedioate Chemical compound CCOC(=O)CC(CC(C)C)(C(=O)OCC)CC1CCCCC1 URZDPTYHEBVBEZ-UHFFFAOYSA-N 0.000 description 1
- UKZUISCHPZZJME-UHFFFAOYSA-N diethyl 2-butan-2-ylbutanedioate Chemical compound CCOC(=O)CC(C(C)CC)C(=O)OCC UKZUISCHPZZJME-UHFFFAOYSA-N 0.000 description 1
- GKCJIKJXEOGKJU-UHFFFAOYSA-N diethyl 2-butyl-2-phenylbutanedioate Chemical compound CCOC(=O)CC(CCCC)(C(=O)OCC)C1=CC=CC=C1 GKCJIKJXEOGKJU-UHFFFAOYSA-N 0.000 description 1
- RKYAIEFZJCCTFW-UHFFFAOYSA-N diethyl 2-cyclohexyl-3-(3-methylbutyl)butanedioate Chemical compound CCOC(=O)C(CCC(C)C)C(C(=O)OCC)C1CCCCC1 RKYAIEFZJCCTFW-UHFFFAOYSA-N 0.000 description 1
- VCDQCWPPWOKHRK-UHFFFAOYSA-N diethyl 2-cyclohexyl-3-cyclopentylbutanedioate Chemical compound C1CCCC1C(C(=O)OCC)C(C(=O)OCC)C1CCCCC1 VCDQCWPPWOKHRK-UHFFFAOYSA-N 0.000 description 1
- HRQCCDRWTZGQDE-UHFFFAOYSA-N diethyl 2-cyclohexyl-3-propan-2-ylbutanedioate Chemical compound CCOC(=O)C(C(C)C)C(C(=O)OCC)C1CCCCC1 HRQCCDRWTZGQDE-UHFFFAOYSA-N 0.000 description 1
- XMVGCOWCTAZJNT-UHFFFAOYSA-N diethyl 2-cyclopropylbutanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)C1CC1 XMVGCOWCTAZJNT-UHFFFAOYSA-N 0.000 description 1
- LRDULBKZNVGLIH-UHFFFAOYSA-N diethyl 2-ethyl-2,3-di(propan-2-yl)butanedioate Chemical compound CCOC(=O)C(C(C)C)C(CC)(C(C)C)C(=O)OCC LRDULBKZNVGLIH-UHFFFAOYSA-N 0.000 description 1
- CRFNZTOCCSXWQM-UHFFFAOYSA-N diethyl 2-methoxybutanedioate Chemical compound CCOC(=O)CC(OC)C(=O)OCC CRFNZTOCCSXWQM-UHFFFAOYSA-N 0.000 description 1
- GEVHQTAWODKPAI-UHFFFAOYSA-N diethyl 2-methyl-3-(3,3,3-trifluoropropyl)butanedioate Chemical compound CCOC(=O)C(C)C(CCC(F)(F)F)C(=O)OCC GEVHQTAWODKPAI-UHFFFAOYSA-N 0.000 description 1
- SSQLHHBLAVHVOU-UHFFFAOYSA-N diethyl 2-propan-2-ylbutanedioate Chemical compound CCOC(=O)CC(C(C)C)C(=O)OCC SSQLHHBLAVHVOU-UHFFFAOYSA-N 0.000 description 1
- AQFKFFFGIFNPMT-UHFFFAOYSA-N diethyl 2-trimethylsilylbutanedioate Chemical compound CCOC(=O)CC([Si](C)(C)C)C(=O)OCC AQFKFFFGIFNPMT-UHFFFAOYSA-N 0.000 description 1
- ZRGHKDUYPKELJO-UHFFFAOYSA-N diethyl 3-benzyl-2-ethyl-2-methylbutanedioate Chemical compound CCOC(=O)C(C)(CC)C(C(=O)OCC)CC1=CC=CC=C1 ZRGHKDUYPKELJO-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
- VHPUZTHRFWIGAW-UHFFFAOYSA-N dimethoxy-di(propan-2-yl)silane Chemical compound CO[Si](OC)(C(C)C)C(C)C VHPUZTHRFWIGAW-UHFFFAOYSA-N 0.000 description 1
- BTJCEVZMRIJBSM-UHFFFAOYSA-N dimethoxy-methyl-(1,1,1-trifluoropropan-2-yl)silane Chemical compound CO[Si](C)(OC)C(C)C(F)(F)F BTJCEVZMRIJBSM-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
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- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- HCBWCZGDFODQIF-UHFFFAOYSA-N ethyl 1-(3-ethoxy-2-oxopropyl)-2-methylcyclohexane-1-carboxylate Chemical compound CCOCC(=O)CC1(C(=O)OCC)CCCCC1C HCBWCZGDFODQIF-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical class OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 230000002140 halogenating effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- FMKOJHQHASLBPH-UHFFFAOYSA-N isopropyl iodide Chemical compound CC(C)I FMKOJHQHASLBPH-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
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- 239000002243 precursor Substances 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000012721 stereospecific polymerization Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 235000011044 succinic acid Nutrition 0.000 description 1
- 150000003444 succinic acids Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- HXLWJGIPGJFBEZ-UHFFFAOYSA-N tert-butyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(C)(C)C HXLWJGIPGJFBEZ-UHFFFAOYSA-N 0.000 description 1
- NETBVGNWMHLXRP-UHFFFAOYSA-N tert-butyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C(C)(C)C NETBVGNWMHLXRP-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 1
- 229920001866 very low density polyethylene Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/651—Pretreating with non-metals or metal-free compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
- C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Emergency Medicine (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP99201172 | 1999-04-15 | ||
| EP99201172 | 1999-04-15 | ||
| PCT/EP2000/003333 WO2000063261A1 (en) | 1999-04-15 | 2000-04-12 | Components and catalysts for the polymerization of olefins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU4548600A AU4548600A (en) | 2000-11-02 |
| AU777683B2 true AU777683B2 (en) | 2004-10-28 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU45486/00A Ceased AU777683B2 (en) | 1999-04-15 | 2000-04-12 | Components and catalysts for the polymerization of olefins |
Country Status (22)
| Country | Link |
|---|---|
| US (2) | US6818583B1 (enExample) |
| EP (1) | EP1088009B1 (enExample) |
| JP (2) | JP4717219B2 (enExample) |
| KR (1) | KR100700957B1 (enExample) |
| CN (2) | CN1240729C (enExample) |
| AR (1) | AR043275A1 (enExample) |
| AT (1) | ATE335014T1 (enExample) |
| AU (1) | AU777683B2 (enExample) |
| BR (1) | BR0006095B1 (enExample) |
| CA (1) | CA2334743C (enExample) |
| DE (1) | DE60029714T2 (enExample) |
| ES (1) | ES2269135T3 (enExample) |
| HU (1) | HUP0103083A3 (enExample) |
| ID (1) | ID28200A (enExample) |
| IL (1) | IL140154A (enExample) |
| MY (1) | MY124016A (enExample) |
| NO (1) | NO20006388L (enExample) |
| PL (1) | PL345209A1 (enExample) |
| RU (1) | RU2225415C2 (enExample) |
| SA (1) | SA00210385B1 (enExample) |
| TW (1) | TWI229086B (enExample) |
| WO (1) | WO2000063261A1 (enExample) |
Families Citing this family (268)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7049377B1 (en) * | 1995-02-21 | 2006-05-23 | Basell Poliolefine Italia S.R.L. | 1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers |
| WO2000063261A1 (en) * | 1999-04-15 | 2000-10-26 | Basell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
| US6716939B2 (en) | 2000-02-02 | 2004-04-06 | Basell Poliolefine Italia S.P.A. | Components and catalysts for the polymerization of olefins |
| PL355609A1 (en) * | 2000-10-13 | 2004-05-04 | Basell Poliolefine Italia S.P.A. | Catalyst components for the polymerization of olefines |
| EP1483301B1 (en) * | 2002-03-08 | 2009-02-18 | Basell Poliolefine Italia S.r.l. | Process for preparing a diether-based catalyst component |
| WO2003099883A1 (en) * | 2002-05-29 | 2003-12-04 | Basell Poliolefine Italia S.P.A. | Butene-1 (co)polymers and process for their preparation |
| JP2005529224A (ja) * | 2002-06-13 | 2005-09-29 | バセル ポリオレフィン イタリア エス．ピー．エー． | オレフィンの重合のための触媒成分 |
| AU2003249866A1 (en) * | 2002-07-02 | 2004-01-23 | Basell Poliolefine Italia S.P.A. | Catalyst system for the polymerization of olefins |
| US7005487B2 (en) | 2002-07-02 | 2006-02-28 | Basell Poliolefine Italia S.R.L. | Catalyst system for the polymerization of olefins |
| CN1218951C (zh) | 2002-07-17 | 2005-09-14 | 中国石油化工股份有限公司 | 一种硅醚化合物及其制备方法和应用 |
| EP1527106A2 (en) * | 2002-08-01 | 2005-05-04 | Basell Poliolefine Italia S.P.A. | Highly stereoregular polypropylene with improved properties |
| US7202314B2 (en) | 2002-09-16 | 2007-04-10 | Basell Poliolefine Italia S.P.A. | Components and catalysts for the polymerization of olefins |
| CA2506650A1 (en) * | 2002-11-28 | 2004-06-10 | Basell Poliolefine Italia S.P.A. | Butene-1 copolymers and process for their preparation |
| EP1613670B1 (en) | 2003-03-26 | 2017-05-10 | Ineos Technologies USA LLC | Olefin polymerisation catalyst component containing a bicyclic cycloakane dicarboxylate as electron donor |
| TW200427763A (en) * | 2003-04-03 | 2004-12-16 | Basell Poliolefine Spa | Impact resistant polyolefin compositions |
| WO2005014713A1 (en) | 2003-08-05 | 2005-02-17 | Basell Poliolefine Italia S.R.L. | Polyolefin articles |
| EP1678218A1 (en) * | 2003-10-28 | 2006-07-12 | Basell Poliolefine Italia S.r.l. | Components and catalysts for the polymerization of olefins |
| CN1957034B (zh) * | 2004-05-21 | 2011-07-13 | 巴塞尔聚烯烃意大利有限责任公司 | 耐冲击聚烯烃组合物 |
| CA2583225A1 (en) | 2004-10-04 | 2006-04-13 | Basell Poliolefine Italia S.R.L. | Elastomeric polyolefin compositions |
| EP1827673B1 (en) | 2004-12-20 | 2012-02-01 | Basell Poliolefine Italia S.r.l. | Process and apparatus for the polymerization of propylene |
| BRPI0517492A (pt) * | 2004-12-21 | 2008-10-14 | Basell Poliolefine Srl | composições poliolefìnicas e filmes permeáveis obtidos a partir delas |
| US7795352B2 (en) | 2004-12-23 | 2010-09-14 | Basell Poliolefine Italia S.R.L. | Polyolefinic compositions having good whitening resistance |
| JP4688135B2 (ja) * | 2005-01-18 | 2011-05-25 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分および触媒 |
| US7888438B2 (en) | 2005-01-19 | 2011-02-15 | Mitsui Chemicals, Inc. | Catalyst for olefin polymerization and process for olefin polymerization |
| TWI315318B (en) | 2005-01-19 | 2009-10-01 | Mitsui Chemicals Inc | Process for producing olefin polymer and solid titanium catalyst component |
| JP4632299B2 (ja) * | 2005-01-26 | 2011-02-16 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分、その製造方法および触媒 |
| ATE446987T1 (de) | 2005-02-03 | 2009-11-15 | Basell Poliolefine Srl | Propylen-polymer-zusammensetzung zum spritzgiessen |
| EP1871832B1 (en) * | 2005-04-21 | 2012-06-13 | Basell Poliolefine Italia S.r.l. | Biaxially oriented propylene polymer films |
| EP1874530A2 (en) * | 2005-04-28 | 2008-01-09 | Basell Poliolefine Italia S.r.l. | Reinforced polypropylene pipe |
| CN101175778B (zh) | 2005-05-12 | 2011-12-07 | 巴塞尔聚烯烃意大利有限责任公司 | 丙烯-乙烯共聚物和它们的制备方法 |
| BRPI0613247A2 (pt) | 2005-05-27 | 2010-12-28 | Basell Poliolefine Srl | composições poliolefìnicas tendo boa resistência ao branqueamento |
| AU2006265203A1 (en) | 2005-07-01 | 2007-01-11 | Basell Poliolefine Italia S.R.L. | Propylene polymers having broad molecular weight distribution |
| RU2412823C2 (ru) * | 2005-07-11 | 2011-02-27 | Базелль Полиолефин Италия С.Р.Л. | Металлизированная полипропиленовая пленка с хорошим сохранением барьерных свойств |
| AU2006278060A1 (en) * | 2005-08-08 | 2007-02-15 | Basell Poliolefine Italia S.R.L. | Process for the nucleation of Polypropylene resins |
| CA2629788A1 (en) * | 2005-11-15 | 2007-05-24 | Basell Poliolefine Italia S.R.L. | Propylene-ethylene copolymers and process for their preparation |
| ATE499409T1 (de) * | 2005-11-22 | 2011-03-15 | Basell Poliolefine Srl | Schlagzähe polyolefinzusammensetzungen |
| CN101341209B (zh) | 2005-12-20 | 2011-08-31 | 巴塞尔聚烯烃意大利有限责任公司 | 用于拉伸制品的聚丙烯组合物 |
| WO2007071496A1 (en) * | 2005-12-20 | 2007-06-28 | Basell Poliolefine Italia S.R.L. | Soft non-woven fabrics |
| CA2643339A1 (en) | 2006-02-23 | 2007-08-30 | Basell Poliolefine Italia S.R.L. | Propylene polymers for injection molding applications |
| EP1849807A1 (en) * | 2006-04-24 | 2007-10-31 | Total Petrochemicals Research Feluy | Catalyst composition for the copolymerization of propylene |
| JP2009541515A (ja) * | 2006-06-21 | 2009-11-26 | トータル・ペトロケミカルズ・リサーチ・フエリユイ | プロピレンの（共）重合用の触媒組成物 |
| CN101472961A (zh) * | 2006-06-22 | 2009-07-01 | 巴塞尔聚烯烃意大利有限责任公司 | 基于1,3-二醚的用于烯烃聚合的催化剂组分 |
| ES2350014T3 (es) * | 2006-06-22 | 2011-01-14 | Basell Poliolefine Italia S.R.L. | Componente catalítico para la polimerización de olefinas. |
| WO2008010459A1 (en) | 2006-07-18 | 2008-01-24 | Mitsui Chemicals, Inc. | Solid titanium catalyst ingredient, catalyst for olefin polymerization, and method of olefin polymerization |
| US8178632B2 (en) * | 2006-07-28 | 2012-05-15 | Basell Poliolefine Italia, s.r.l. | Propylene polymers |
| ATE475691T1 (de) * | 2006-11-23 | 2010-08-15 | Basell Poliolefine Srl | Polyolefinzusammensetzungen |
| CN101195666B (zh) * | 2006-12-06 | 2012-03-07 | 中国石油天然气股份有限公司 | 一种烯烃聚合用负载型催化剂及其制备方法 |
| WO2008074636A1 (en) | 2006-12-21 | 2008-06-26 | Basell Poliolefine Italia S.R.L. | High shrink polypropylene films |
| US8455072B2 (en) * | 2006-12-22 | 2013-06-04 | Basell Poliolefine Italia S.R.L. | Polyolefin composition for pipe system and sheets |
| EP2097459A1 (en) * | 2006-12-29 | 2009-09-09 | Fina Technology, Inc. | Succinate-containing polymerization catalyst system using n-butylmethyldimethoxysilane for preparation of polypropylene film grade resins |
| MX2009012580A (es) * | 2007-05-22 | 2009-12-08 | Basell Poliolefine Srl | Procedimiento para la preparacion de composiciones suaves de polimero de propileno. |
| EP2147026B1 (en) * | 2007-05-22 | 2010-10-20 | Basell Poliolefine Italia S.r.l. | Soft propylene polymer compositions |
| BRPI0815246A2 (pt) * | 2007-08-24 | 2015-03-31 | Dow Global Technologies Inc | Composição de catalisador |
| KR101716609B1 (ko) * | 2007-08-24 | 2017-03-14 | 더블유.알. 그레이스 앤드 캄파니-콘. | 조절된 알루미늄 대 ｓｃａ 비를 갖는 자기-제한성 촉매 시스템 및 방법 |
| JP2010537026A (ja) * | 2007-08-29 | 2010-12-02 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | オレフィン重合用の触媒 |
| FR2921368B1 (fr) | 2007-09-25 | 2012-10-12 | Pf Medicament | Nouveau procede de synthese de derives anticancereux de (poly) aminoalkylaminoacetamide d'epipodophyllotoxine. |
| CN101397246B (zh) * | 2007-09-28 | 2011-08-03 | 中国石油化工股份有限公司 | 一种2,3-二烃基琥珀酸及其酯类化合物的制备方法 |
| US8507628B2 (en) | 2007-10-02 | 2013-08-13 | Fina Technology, Inc. | Propylene based polymers for injection stretch blow molding |
| JP5524068B2 (ja) * | 2007-10-15 | 2014-06-18 | サンアロマー株式会社 | 高流動性プロピレンポリマーの製造方法 |
| CN101423571B (zh) * | 2007-11-01 | 2010-09-01 | 中国石油天然气股份有限公司 | 烯烃聚合催化组分及其催化剂 |
| CN101423566B (zh) * | 2007-11-01 | 2010-11-03 | 中国石油天然气股份有限公司 | 一种固体催化组分及其催化剂 |
| CN101423572B (zh) * | 2007-11-01 | 2011-09-07 | 中国石油天然气股份有限公司 | 用于烯烃聚合的催化组分及其催化剂 |
| HUE035826T2 (hu) | 2007-11-27 | 2018-08-28 | Mitsui Chemicals Inc | Szilárd titán katalizátor alkotórész, katalizátor olefin polimerizációhoz, és eljárás olefin polimerizálására |
| EP2070954A1 (en) * | 2007-12-14 | 2009-06-17 | Total Petrochemicals Research Feluy | Process for the production of a propylene polymer having a broad molecular weight distribution and a low ash content |
| EP2222781B1 (en) | 2007-12-18 | 2014-01-15 | Basell Poliolefine Italia S.r.l. | Transparent polyolefin compositions |
| EP2222730B2 (en) | 2007-12-18 | 2019-12-25 | Basell Poliolefine Italia S.r.l. | Copolymers of propylene with hexene-1 and blown films obtained from them |
| WO2009080497A2 (en) * | 2007-12-20 | 2009-07-02 | Basell Poliolefine Italia S.R.L. | Highly stereoregular polypropylene with improved properties |
| US20100273641A1 (en) * | 2007-12-21 | 2010-10-28 | Linfeng Chen | Self-Limiting Catalyst Composition with Non-Phthalate Internal Donor |
| CN101910219B (zh) * | 2007-12-28 | 2012-11-21 | 巴塞尔聚烯烃意大利有限责任公司 | 从丙烯和己烯-1的无规共聚物制造的塑料罐 |
| CN101735346B (zh) * | 2008-11-07 | 2012-05-30 | 中国石油天然气股份有限公司 | 一种丙烯均聚和共聚的催化剂及其制备方法和应用 |
| US8088872B2 (en) | 2008-11-25 | 2012-01-03 | Dow Global Technologies Llc | Procatalyst composition including silyl ester internal donor and method |
| EP2194070B1 (en) | 2008-12-03 | 2012-08-22 | Süd-Chemie IP GmbH & Co. KG | Electron donor composition for a solid catalyst, solid catalyst composition used in the polymerisation of alpha-olefins, and process for the production of a polymer consisting of alpha-olefin units using the solid catalyst composition |
| CN102264527B (zh) | 2008-12-24 | 2014-06-25 | 巴塞尔聚烯烃意大利有限责任公司 | 压力管以及用于制造该管的聚烯烃组合物 |
| WO2010076285A1 (en) | 2008-12-30 | 2010-07-08 | Basell Poliolefine Italia S.R.L. | Steaming of a polyolefin |
| CN101811983B (zh) | 2009-02-19 | 2013-02-06 | 中国石油化工股份有限公司 | 2，3-二异丙基-2-氰基丁二酸二酯类化合物的制备方法 |
| CN101811982B (zh) * | 2009-02-19 | 2013-02-06 | 中国石油化工股份有限公司 | 2，3-二异丙基-2，3-二氰基丁二酸二酯类化合物及其制备方法和应用 |
| CN101824107B (zh) * | 2009-03-04 | 2013-04-24 | 中国石油天然气股份有限公司 | 用于烯烃聚合的固体主催化剂 |
| CN101831016B (zh) * | 2009-03-10 | 2011-10-05 | 中国石油天然气股份有限公司 | 一种烯烃聚合催化组分及其催化剂 |
| EP2411464B1 (en) | 2009-03-23 | 2013-05-08 | Basell Poliolefine Italia S.r.l. | Polyolefin masterbatch and composition suitable for injection molding |
| JP5689232B2 (ja) * | 2009-03-24 | 2015-03-25 | 三井化学株式会社 | 固体状チタン触媒成分、オレフィン重合用触媒およびオレフィンの重合方法 |
| US9090000B2 (en) * | 2009-03-26 | 2015-07-28 | Fina Technology, Inc. | Injection stretch blow molded articles and random copolymers for use therein |
| RU2532543C2 (ru) * | 2009-04-17 | 2014-11-10 | Чайна Петролеум Энд Кемикал Корпорейшн | Компонент катализатора, применяемый для полимеризации олефинов, способ его получения и катализатор, содержащий такой компонент |
| EP2264099A1 (en) | 2009-05-21 | 2010-12-22 | Basell Poliolefine Italia S.R.L. | Propylene polymer compositions |
| KR101538910B1 (ko) | 2009-05-21 | 2015-07-23 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 프로필렌 중합체 조성물 |
| BRPI1014019B1 (pt) * | 2009-06-19 | 2019-10-22 | Basell Poliolefine Italia Srl | processo para a preparação de composições de polímeros de propileno resistentes ao impacto |
| EP2445962B1 (en) | 2009-06-26 | 2013-06-05 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions |
| US8722803B2 (en) | 2009-07-31 | 2014-05-13 | Basell Poliolefine Italia S.R.L. | Polyolefinic compositions |
| CN102471550B (zh) | 2009-07-31 | 2014-03-12 | 巴塞尔聚烯烃意大利有限责任公司 | 聚烯烃组合物 |
| CN102146146B (zh) * | 2010-02-10 | 2013-08-14 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组分及其催化剂 |
| US8541333B2 (en) * | 2009-08-13 | 2013-09-24 | China Petroleum & Chemical Corporation | Catalyst component for olefin polymerization and a catalyst comprising the same |
| WO2011035994A1 (en) | 2009-09-22 | 2011-03-31 | Basell Poliolefine Italia S.R.L. | Propylene polymer compositions |
| US8729188B2 (en) | 2009-09-22 | 2014-05-20 | Basell Poliolefine Italia S.R.L. | Propylene polymer compositions |
| CN102549062B (zh) | 2009-09-22 | 2013-11-20 | 巴塞尔聚烯烃意大利有限责任公司 | 丙烯聚合物组合物 |
| WO2011036002A1 (en) | 2009-09-22 | 2011-03-31 | Basell Poliolefine Italia S.R.L. | Propylene polymer compositions |
| US20120178883A1 (en) | 2009-09-22 | 2012-07-12 | Basell Poliolefine Italia S.R.L. | Propylene Polymer Compositions |
| WO2011036077A1 (en) | 2009-09-24 | 2011-03-31 | Basell Poliolefine Italia S.R.L. | Heat-sealable polyolefin films |
| WO2011039314A1 (en) | 2009-09-29 | 2011-04-07 | Basell Poliolefine Italia Srl | Heat-sealable polyolefin films |
| EP2488583B1 (en) | 2009-10-13 | 2014-01-15 | Basell Poliolefine Italia S.r.l. | Propylene polymer compositions |
| CN102597022B (zh) * | 2009-11-19 | 2014-11-19 | 巴塞尔聚烯烃意大利有限责任公司 | 用于制备耐冲击丙烯聚合物组合物的方法 |
| KR101114073B1 (ko) * | 2009-12-08 | 2012-02-22 | 삼성토탈 주식회사 | 프로필렌 중합용 고체촉매의 제조 방법 |
| US8211819B2 (en) * | 2009-12-21 | 2012-07-03 | Basf Corporation | Internal and external donor compounds for olefin polymerization catalysts |
| WO2011076611A1 (en) | 2009-12-23 | 2011-06-30 | Basell Poliolefine Italia S.R.L. | Polyolefinic compositions for injection-moulded drainage systems |
| US8536289B2 (en) | 2009-12-29 | 2013-09-17 | Basell Polyolefine Gmbh | Process for the production of polyolefin films |
| EP2520594B1 (en) | 2009-12-31 | 2014-12-10 | Hyosung Corporation | Ziegler-natta catalyst for olefin polymerization |
| EP2553016B1 (en) | 2010-03-26 | 2019-05-29 | Basell Poliolefine Italia S.r.l. | Heterophasic polyolefin composition |
| CN102234337B (zh) | 2010-04-22 | 2013-08-14 | 中国石油化工股份有限公司 | 用于烯烃聚合反应的催化剂组分及其催化剂 |
| EP2566919B1 (en) | 2010-05-05 | 2016-05-11 | Basell Poliolefine Italia S.r.l. | Propylene polymer compositions |
| CN102884123B (zh) | 2010-05-19 | 2015-03-25 | 巴塞尔聚烯烃意大利有限责任公司 | 用于洗涤机的聚丙烯桶 |
| BR112012029119B1 (pt) | 2010-05-20 | 2020-11-17 | Basell Poliolefine Italia S.R.L. | composição de polímero de propileno, película e artigo moldado |
| JP5539789B2 (ja) * | 2010-06-09 | 2014-07-02 | 株式会社プライムポリマー | 微多孔膜形成用プロピレン重合体およびその用途 |
| CN102971373B (zh) | 2010-06-23 | 2015-11-25 | 巴塞尔聚烯烃意大利有限责任公司 | 用于管道系统和片材的聚烯烃组合物 |
| RU2567750C2 (ru) | 2010-06-23 | 2015-11-10 | Базелль Полиолефин Италия Срл | Трубы и полиолефиновая композиция для их изготовления |
| EP2585527B1 (en) | 2010-06-23 | 2015-01-14 | Basell Poliolefine Italia S.r.l. | Polyolefin composition for pipe systems and sheets |
| CN102958953B (zh) * | 2010-06-24 | 2015-08-05 | 巴塞尔聚烯烃意大利有限责任公司 | 用于烯烃聚合的催化剂体系 |
| CN102311513B (zh) * | 2010-06-29 | 2013-02-06 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组分及催化剂 |
| US9303159B2 (en) | 2010-07-23 | 2016-04-05 | Basell Poliolefine Italia S.R.L. | Propylene polymer compositions |
| EP2598544B1 (en) | 2010-07-29 | 2016-11-02 | Basell Poliolefine Italia S.r.l. | Random copolymers of propylene |
| CN102372651B (zh) * | 2010-08-12 | 2013-12-04 | 中国石油化工股份有限公司 | 2-环烷基-3-仲烷基-2-氰基丁二酸酯类化合物、制备方法及其应用 |
| CN102372797A (zh) | 2010-08-12 | 2012-03-14 | 中国石油化工股份有限公司 | 用于烯烃聚合反应的催化剂组分及其催化剂 |
| CN102432710A (zh) * | 2010-09-29 | 2012-05-02 | 中国石油化工股份有限公司 | 一种用于乙烯聚合催化剂载体的制备方法、催化剂组分及催化剂 |
| US10239267B2 (en) | 2010-10-26 | 2019-03-26 | Basell Poliolefine Italia S.R.L. | Process for producing injection stretch blow molded polyolefin containers |
| WO2012076447A1 (en) | 2010-12-07 | 2012-06-14 | Basell Poliolefine Italia S.R.L. | Polyolefin based corrugated boards |
| EP2463413B1 (en) | 2010-12-07 | 2014-01-29 | Basell Poliolefine Italia S.r.l. | Polyolefin fibres |
| BR112013017661B1 (pt) | 2011-01-18 | 2020-10-13 | Basell Poliolefine Italia S.R.L. | composição de poliolefina, artigo moldado por injeção, em particular uma caixa de bateria, e veículo |
| BR112013019990B1 (pt) | 2011-03-10 | 2020-06-09 | Basell Poliolefine Italia Srl | recipiente à base de poliolefinas e seu processo de preparação |
| EP2505606B1 (en) | 2011-03-29 | 2017-03-01 | Basell Poliolefine Italia S.r.l. | Polyolefin composition for pipe systems |
| US20140148564A1 (en) | 2011-04-01 | 2014-05-29 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
| US9593171B2 (en) | 2011-04-12 | 2017-03-14 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| KR101868664B1 (ko) | 2011-07-06 | 2018-06-18 | 도호 티타늄 가부시키가이샤 | 올레핀류 중합용 고체 촉매 성분, 올레핀류 중합용 촉매 및 올레핀류 중합체의 제조 방법 |
| US9000097B2 (en) | 2011-07-07 | 2015-04-07 | Basell Poliolefine Italia S.R.L. | Polypropylene composition |
| JP5816481B2 (ja) * | 2011-07-28 | 2015-11-18 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分、その製造方法、オレフィン類重合触媒およびオレフィン類重合体の製造方法 |
| JP5785809B2 (ja) * | 2011-07-28 | 2015-09-30 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分、その製造方法、オレフィン類重合触媒およびオレフィン類重合体の製造方法 |
| JP2014522804A (ja) | 2011-08-08 | 2014-09-08 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 二塩化マグネシウムエタノール付加物とそれから得られる触媒成分 |
| CN103857651B (zh) * | 2011-08-29 | 2016-05-04 | 沙特基础工业公司 | 用于制备二取代的琥珀酸酯的方法 |
| EP2583999A1 (en) | 2011-10-20 | 2013-04-24 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions |
| EP2594593A1 (en) * | 2011-11-17 | 2013-05-22 | Basell Poliolefine Italia S.r.l. | Process for the preparation of heterophasic propylene polymer compositions |
| WO2013083576A1 (en) | 2011-12-05 | 2013-06-13 | Basell Poliolefine Italia S.R.L. | Propylene terpolymers |
| EP2607384A1 (en) * | 2011-12-21 | 2013-06-26 | Basell Poliolefine Italia S.r.l. | Catalyst system for the polymerization of olefins |
| WO2013125504A1 (ja) * | 2012-02-20 | 2013-08-29 | サンアロマー株式会社 | シート成形用ポリプロピレン系樹脂組成物 |
| EP2666793A1 (en) | 2012-05-21 | 2013-11-27 | Basell Poliolefine Italia S.r.l. | Propylene based terpolymer |
| WO2014013401A1 (en) * | 2012-07-14 | 2014-01-23 | Indian Oil Corporation Limited | Ziegler-natta catalyst systems comprising a 1,2-phenylenedioate as internal donor and process for preparing the same |
| EP2712874A1 (en) * | 2012-09-26 | 2014-04-02 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| CN104736627B (zh) | 2012-10-03 | 2018-04-17 | 胜亚诺盟股份有限公司 | 蒸煮膜用丙烯树脂组合物 |
| EP2722348A1 (en) * | 2012-10-16 | 2014-04-23 | Basell Poliolefine Italia S.r.l. | Process for the preparation of propylene random copolymers |
| BR112015009432B1 (pt) | 2012-10-31 | 2021-03-30 | Exxonmobil Chemical Patents Inc. | Resinas de polipropileno de ampla distribuição de peso molecular |
| BR112015009509B1 (pt) | 2012-10-31 | 2021-09-21 | Exxonmobil Chemical Patents Inc | Artigos moldado compreendendo resinas de polipropileno de ampla distribuição de peso molecular e resina espumável |
| US9481741B2 (en) | 2012-11-26 | 2016-11-01 | Lummus Novolen Technology Gmbh | High performance Ziegler-Natta catalyst systems, process for producing such supported catalysts and use thereof |
| US9522968B2 (en) | 2012-11-26 | 2016-12-20 | Lummus Novolen Technology Gmbh | High performance Ziegler-Natta catalyst systems, process for producing such MgCl2 based catalysts and use thereof |
| EP2743307A1 (en) | 2012-12-12 | 2014-06-18 | Basell Poliolefine Italia S.r.l. | Polyolefin composition |
| EP2743073A1 (en) * | 2012-12-12 | 2014-06-18 | Basell Poliolefine Italia S.r.l. | Propylene-based terpolymers |
| JP6144045B2 (ja) * | 2012-12-28 | 2017-06-07 | サンアロマー株式会社 | ポリプロピレン樹脂組成物およびその製造方法ならびにポリプロピレンシートおよび二軸延伸ポリプロピレンフィルム |
| EP2757114A1 (en) * | 2013-01-18 | 2014-07-23 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| CN103145553B (zh) * | 2013-03-06 | 2016-06-01 | 大连理工大学 | 2,3-烃基取代琥珀酸二酯的合成与应用 |
| EP2778265A1 (en) | 2013-03-11 | 2014-09-17 | Basell Polyolefine GmbH | Multilayer fibers |
| WO2014139811A2 (en) * | 2013-03-15 | 2014-09-18 | Basell Poliolefine Italia S.R.L. | Process for the preparation of propylene terpolymers and terpolymers obtained thereby |
| JP6235805B2 (ja) * | 2013-06-17 | 2017-11-22 | サンアロマー株式会社 | 二軸延伸フィルム用ポリプロピレン樹脂組成物 |
| JP6235804B2 (ja) * | 2013-06-17 | 2017-11-22 | サンアロマー株式会社 | シート成形用ポリプロピレン樹脂組成物 |
| CN103304709B (zh) * | 2013-07-10 | 2016-03-30 | 河北工业大学 | 一种用于1-丁烯聚合的固体催化剂 |
| EP2829397A1 (en) | 2013-07-22 | 2015-01-28 | Basell Poliolefine Italia S.r.l. | Heat sealable polyolefin films and sheets |
| CN104418770B (zh) * | 2013-09-03 | 2016-03-30 | 中国石油化工股份有限公司 | 一种2,3-二非直链烷基-2-氰基丁二酸二酯化合物的制备方法 |
| CN104558287B (zh) * | 2013-10-24 | 2017-03-01 | 中国石油化工股份有限公司 | 烯烃聚合用催化剂组分及催化剂 |
| US9567418B2 (en) | 2013-10-30 | 2017-02-14 | Basell Poliolefine Italia S.R.L. | Multimodal copolymers of propylene and 1-hexene |
| US9382348B2 (en) * | 2013-11-13 | 2016-07-05 | Chevron Phillips Chemical Company Lp | System and method for polymerization |
| WO2015200586A1 (en) | 2014-06-25 | 2015-12-30 | Exxonmobil Chemcal Patents Inc. | High melt strength polypropylene and extrusion process for preserving melt strength |
| US9593184B2 (en) | 2014-10-28 | 2017-03-14 | Formosa Plastics Corporation, Usa | Oxalic acid diamides as modifiers for polyolefin catalysts |
| JP6598283B2 (ja) * | 2014-11-10 | 2019-10-30 | サンアロマー株式会社 | α−オレフィン類の重合方法 |
| WO2016146578A1 (en) | 2015-03-19 | 2016-09-22 | Basell Poliolefine Italia S.R.L. | Propylene based terpolymer |
| JP7014609B2 (ja) * | 2015-06-19 | 2022-02-01 | サウジ アラビアン オイル カンパニー | 防汚オリゴマー化触媒系 |
| CN106608841B (zh) * | 2015-10-27 | 2018-06-12 | 中国石油化工股份有限公司 | 2-氰基-2,3-二烃基丁二酸二烷基酯类化合物的制备方法 |
| US9777084B2 (en) | 2016-02-19 | 2017-10-03 | Formosa Plastics Corporation, Usa | Catalyst system for olefin polymerization and method for producing olefin polymer |
| US11427660B2 (en) | 2016-08-17 | 2022-08-30 | Formosa Plastics Corporation, Usa | Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same |
| RU2758673C2 (ru) * | 2016-09-23 | 2021-11-01 | Чайна Петролеум Энд Кемикал Корпорейшн | Компонент катализатора для полимеризации олефина, катализатор и их применение |
| WO2018054362A1 (zh) * | 2016-09-23 | 2018-03-29 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分、催化剂及其应用 |
| US9815920B1 (en) | 2016-10-14 | 2017-11-14 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
| KR101963009B1 (ko) * | 2016-12-15 | 2019-03-27 | 한화토탈 주식회사 | 에틸렌 올리고머화 방법 |
| KR101853569B1 (ko) * | 2016-12-15 | 2018-04-30 | 한화토탈 주식회사 | 에틸렌 올리고머화 반응용 촉매계 및 이를 이용한 에틸렌 올리고머화 방법 |
| WO2018147944A1 (en) | 2017-02-07 | 2018-08-16 | Exxonmobil Chemical Patents Inc. | High melt strength polypropylenes with improved processability |
| CN110352203B (zh) | 2017-03-27 | 2022-04-19 | 巴塞尔聚烯烃意大利有限公司 | 丙烯乙烯无规共聚物 |
| US10822438B2 (en) | 2017-05-09 | 2020-11-03 | Formosa Plastics Corporation | Catalyst system for enhanced stereo-specificity of olefin polymerization and method for producing olefin polymer |
| US10124324B1 (en) | 2017-05-09 | 2018-11-13 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
| EP3645625B1 (en) | 2017-06-27 | 2024-03-27 | ExxonMobil Chemical Patents Inc. | High stiffness polypropylene impact copolymer |
| US10246530B2 (en) | 2017-06-27 | 2019-04-02 | Toho Titanium Co., Ltd. | Method for producing solid catalyst component for olefin polymerization, catalyst for olefin polymerization and a process for propylene polymerization |
| WO2019005262A1 (en) | 2017-06-27 | 2019-01-03 | Exxonmobil Chemical Patents Inc. | POLYPROPYLENE SHOCK COPOLYMER WITH HIGH SHOCK RESISTANCE |
| WO2019052822A1 (en) | 2017-09-14 | 2019-03-21 | Basell Poliolefine Italia S.R.L. | STATISTIC COPOLYMER OF PROPYLENE AND ETHYLENE |
| JP7096682B2 (ja) | 2018-03-16 | 2022-07-06 | サンアロマー株式会社 | ポリプロピレン組成物および成形品 |
| JP7096681B2 (ja) | 2018-03-16 | 2022-07-06 | サンアロマー株式会社 | ポリプロピレン組成物および成形品 |
| JP7114361B2 (ja) | 2018-06-19 | 2022-08-08 | サンアロマー株式会社 | ポリプロピレン組成物および成形品 |
| US11708468B2 (en) | 2018-09-20 | 2023-07-25 | Basell Doliolefine Italia S.r.l. | Propylene terpolymer |
| EP3861068B1 (en) | 2018-10-03 | 2022-09-07 | Basell Poliolefine Italia S.r.l. | Pipes and polypropylene composition for the manufacture thereof |
| JP7249126B2 (ja) | 2018-10-18 | 2023-03-30 | サンアロマー株式会社 | ポリプロピレン組成物および成形品 |
| EP3890969B1 (en) | 2018-12-05 | 2024-02-14 | Basell Poliolefine Italia S.r.l. | Bopp multilayer film |
| WO2020231526A1 (en) | 2019-05-15 | 2020-11-19 | Exxonmobil Chemical Patents Inc. | Polypropylene-based compositions |
| EP3766652B1 (en) | 2019-07-16 | 2023-04-12 | Basell Poliolefine Italia S.r.l. | Use of injection molded container for microwave |
| EP4107196A1 (en) | 2020-02-17 | 2022-12-28 | ExxonMobil Chemical Patents Inc. | Propylene-based polymer compositions having a high molecular weight tail |
| US20230257562A1 (en) | 2020-06-30 | 2023-08-17 | Basell Poliolefine Italia S.R.L. | Polyolefins compositions obtained from recycled polyolefins |
| US20230250266A1 (en) | 2020-06-30 | 2023-08-10 | Basell Poliolefine Italia S.R.L. | Polyolefins compositions obtained from recycled polyolefins |
| EP4185636A1 (en) | 2020-07-21 | 2023-05-31 | Basell Poliolefine Italia S.r.l. | High flow heterophasic polypropylene as appearance improver in polyolefin compositions |
| RU2752516C1 (ru) * | 2020-07-22 | 2021-07-28 | Федеральное государственное бюджетное учреждение науки Новосибирский институт органической химии им. Н.Н. Ворожцова Сибирского отделения Российской академии наук (НИОХ СО РАН) | Способ получения диалкил 2,3-диизобутилсукцината, компонента титан-магниевых катализаторов полимеризации олефинов |
| CN115996844A (zh) | 2020-07-24 | 2023-04-21 | 巴塞尔聚烯烃意大利有限公司 | 用于屋顶应用的聚烯烃组合物 |
| CN115803186B (zh) | 2020-08-07 | 2025-07-15 | 巴塞尔聚烯烃意大利有限公司 | 柔软柔性的聚烯烃组合物 |
| US20240025838A1 (en) | 2020-08-26 | 2024-01-25 | Mitsui Chemicals, Inc. | Ester compound |
| KR102623661B1 (ko) | 2020-11-26 | 2024-01-10 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 재생 폴리올레핀으로부터 수득되는 폴리올레핀 조성물 |
| EP4259719A1 (en) | 2020-12-14 | 2023-10-18 | Basell Poliolefine Italia S.r.l. | Ultrasoft polyolefin composition |
| JP7651593B2 (ja) | 2020-12-21 | 2025-03-26 | 三井化学株式会社 | エステル化合物 |
| US20240052148A1 (en) | 2021-02-08 | 2024-02-15 | Basell Poliolefine Italia S.R.L. | Polyolefin composition for functional films |
| WO2022179788A1 (en) | 2021-02-26 | 2022-09-01 | Basell Polyolefine Gmbh | Printing platform for extrusion additive manufacturing |
| US20240352165A1 (en) | 2021-08-24 | 2024-10-24 | Basell Poliolefine Italia S.R.L. | Propylene ethylene copolymer |
| CN117916306A (zh) | 2021-09-28 | 2024-04-19 | 巴塞尔聚烯烃意大利有限公司 | 软质聚丙烯组合物 |
| JP2024537225A (ja) | 2021-10-28 | 2024-10-10 | バーゼル・ポリオレフィン・ゲーエムベーハー | 強化ポリプロピレン組成物 |
| CN116041577B (zh) | 2021-10-28 | 2024-12-06 | 中国石油化工股份有限公司 | 烯烃聚合催化剂组分、催化剂体系及应用和烯烃聚合方法 |
| EP4453087A1 (en) | 2021-12-22 | 2024-10-30 | Basell Poliolefine Italia S.r.l. | Compositions obtained from recycled polyolefins |
| CN118401602A (zh) | 2021-12-23 | 2024-07-26 | 巴塞尔聚烯烃意大利有限公司 | 软质聚烯烃组合物 |
| WO2023124742A1 (zh) * | 2021-12-30 | 2023-07-06 | 中国石油天然气股份有限公司 | 聚丙烯树脂及其制备方法 |
| EP4479446B1 (en) | 2022-02-17 | 2025-11-26 | Basell Poliolefine Italia S.r.l. | Pipes and polypropylene composition for the manufacture thereof |
| WO2023171433A1 (ja) * | 2022-03-11 | 2023-09-14 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分、オレフィン類重合用固体触媒成分の製造方法、オレフィン類重合用触媒、オレフィン類重合体の製造方法及びオレフィン類重合体 |
| JP2023132923A (ja) * | 2022-03-11 | 2023-09-22 | 東邦チタニウム株式会社 | オレフィン類重合用触媒、オレフィン類重合体の製造方法及びプロピレン単独重合体 |
| JP2025513771A (ja) | 2022-05-06 | 2025-04-30 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | プラスチック材料およびそれから得られる成形品 |
| WO2023247227A1 (en) | 2022-06-20 | 2023-12-28 | Basell Poliolefine Italia S.R.L. | Multilayer film |
| CN119630709A (zh) | 2022-07-27 | 2025-03-14 | 埃克森美孚化学专利公司 | 应变硬化增强的聚丙烯组合物及其生产方法 |
| JP2025521958A (ja) | 2022-08-03 | 2025-07-10 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ヒートシールフィルム用ポリプロピレン組成物 |
| EP4317300A1 (en) | 2022-08-04 | 2024-02-07 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions obtained from recycled polyolefins |
| EP4317301A1 (en) | 2022-08-04 | 2024-02-07 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions obtained from recycled polyolefins |
| WO2024028191A1 (en) | 2022-08-04 | 2024-02-08 | Basell Poliolefine Italia S.R.L. | Polyolefin compositions obtained from recycled polyolefins |
| EP4565649A1 (en) | 2022-08-04 | 2025-06-11 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions obtained from recycled polyolefins |
| EP4317299A1 (en) | 2022-08-04 | 2024-02-07 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions obtained from recycled polyolefins |
| WO2024028048A1 (en) | 2022-08-04 | 2024-02-08 | Basell Poliolefine Italia S.R.L. | Polyolefin compositions obtained from recycled polyolefins |
| CN119604573B (zh) | 2022-08-04 | 2025-10-21 | 巴塞尔聚烯烃意大利有限公司 | 由再循环聚烯烃获得的聚烯烃组合物 |
| WO2024056321A1 (en) | 2022-09-14 | 2024-03-21 | Basell Poliolefine Italia S.R.L. | Polyolefins compositions obtained from recycled polyolefins |
| EP4339240A1 (en) | 2022-09-14 | 2024-03-20 | Basell Poliolefine Italia S.r.l. | Polyolefins compositions obtained from recycled polyolefins |
| EP4339239A1 (en) | 2022-09-14 | 2024-03-20 | Basell Poliolefine Italia S.r.l. | Polyolefins compositions obtained from recycled polyolefins |
| CN119731258B (zh) | 2022-09-14 | 2025-08-26 | 巴塞尔聚烯烃意大利有限公司 | 由再循环聚烯烃获得的聚烯烃组合物 |
| CN117924562A (zh) * | 2022-10-24 | 2024-04-26 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其制备方法和用途 |
| WO2024099691A1 (en) | 2022-11-07 | 2024-05-16 | Basell Poliolefine Italia S.R.L. | Polyolefin composition containing a recycled material |
| WO2024099644A1 (en) | 2022-11-07 | 2024-05-16 | Basell Poliolefine Italia S.R.L. | Molded article comprising propylene homopolymer |
| WO2024193835A1 (en) | 2022-11-07 | 2024-09-26 | Basell Poliolefine Italia S.R.L. | Polypropylene resin compositon |
| EP4615886A1 (en) | 2022-11-07 | 2025-09-17 | Basell Poliolefine Italia S.r.l. | Propylene homopolymer |
| EP4615888A1 (en) | 2022-11-07 | 2025-09-17 | Basell Poliolefine Italia S.r.l. | Molded article comprising a propylene homopolymer composition |
| WO2024193834A1 (en) | 2022-11-07 | 2024-09-26 | Basell Poliolefine Italia S.R.L. | Polypropylene resin compositon |
| WO2024099628A1 (en) | 2022-11-07 | 2024-05-16 | Basell Poliolefine Italia S.R.L. | Propylene homopolymer |
| WO2024132732A1 (en) | 2022-12-19 | 2024-06-27 | Basell Poliolefine Italia S.R.L. | Colored thermoplastic composition |
| WO2024188683A1 (en) | 2023-03-14 | 2024-09-19 | Basell Poliolefine Italia S.R.L. | Soft polypropylene composition containing a recycled material |
| WO2024204847A1 (ja) | 2023-03-30 | 2024-10-03 | 三井化学株式会社 | アミド化合物 |
| KR20250149173A (ko) | 2023-03-31 | 2025-10-15 | 미쓰이 가가쿠 가부시키가이샤 | 카바메이트 화합물 |
| WO2024217885A1 (en) | 2023-04-18 | 2024-10-24 | Basell Poliolefine Italia S.R.L. | Soft polypropylene composition containing a recycled material |
| WO2024223264A1 (en) | 2023-04-26 | 2024-10-31 | Basell Poliolefine Italia S.R.L. | Propylene-based copolymer compositon |
| WO2024223249A1 (en) | 2023-04-26 | 2024-10-31 | Basell Poliolefine Italia S.R.L. | Propylene-based copolymer compositon |
| WO2025021459A1 (en) | 2023-07-27 | 2025-01-30 | Basell Poliolefine Italia S.R.L. | Polyolefin compositions obtained from recycled polyolefins |
| WO2025026685A1 (en) | 2023-08-03 | 2025-02-06 | Basell Poliolefine Italia S.R.L. | Soft polypropylene composition containing a recycled material |
| US20250066513A1 (en) | 2023-08-23 | 2025-02-27 | Formosa Plastics Corporation, U.S.A. | Catalyst System For Enhanced Stereo-Specificity Of Olefin Polymerization |
| US20250066514A1 (en) | 2023-08-24 | 2025-02-27 | Formosa Plastics Corporation, U.S.A. | Catalysts component and process for the production of polypropylene having high melt flow rate with high isotacticity |
| US20250109218A1 (en) | 2023-09-29 | 2025-04-03 | Formosa Plastics Corporation, U.S.A. | Method for preparing catalyst component for polymerization of polyolefin without the use of internal electron donors |
| US20250115687A1 (en) | 2023-10-06 | 2025-04-10 | Formosa Plastics Corporation, U.S.A. | Production method for solid catalyst component for polymerizing olefins, and catalyst for polymerizaing olefins |
| US20250115686A1 (en) | 2023-10-09 | 2025-04-10 | Formosa Plastics Corporation, U.S.A. | Olefin polymerization catalyst components containing silane and process for the production of polypropylene having high isotacticity at high melt flow rate |
| IT202300025932A1 (it) | 2023-12-05 | 2025-06-05 | Basell Poliolefine Italia Srl | Composizioni polipropileniche con proprietà meccaniche migliorate |
| WO2025125124A1 (en) | 2023-12-14 | 2025-06-19 | Basell Poliolefine Italia S.R.L. | Polypropylene composition for wire and cable applications |
| WO2025168499A1 (en) | 2024-02-07 | 2025-08-14 | Basell Poliolefine Italia S.R.L. | Translucent polypropylene-based material for additive manufacturing |
| EP4613808A1 (en) | 2024-03-07 | 2025-09-10 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions obtained from recycled polyolefins |
| EP4613810A1 (en) | 2024-03-07 | 2025-09-10 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions obtained from recycled polyolefins |
| EP4613809A1 (en) | 2024-03-07 | 2025-09-10 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions obtained from recycled polyolefins |
| US20250297039A1 (en) | 2024-03-19 | 2025-09-25 | Formosa Plastics Corporation, U.S.A. | Olefin polymerization catalyst components containing diglycidylester components and its use for the production of polypropylene having high isotacticity at high melt flow rate |
| EP4636025A1 (en) | 2024-04-19 | 2025-10-22 | Basell Poliolefine Italia S.r.l. | Polyolefins compositions obtained from recycled polyolefins |
| EP4636026A1 (en) | 2024-04-19 | 2025-10-22 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions obtained from recycled polyolefins |
| EP4636027A1 (en) | 2024-04-19 | 2025-10-22 | Basell Poliolefine Italia S.r.l. | Polyolefins compositions obtained from recycled polyolefins |
| EP4636022A1 (en) | 2024-04-19 | 2025-10-22 | Basell Poliolefine Italia S.r.l. | Polyolefins compositions obtained from recycled polyolefins |
| WO2025228762A1 (en) | 2024-04-30 | 2025-11-06 | Basell Poliolefine Italia S.R.L. | Polyolefin composition for painted articles |
| EP4660238A1 (en) | 2024-06-06 | 2025-12-10 | Basell Poliolefine Italia S.r.l. | Polypropylene compositions containing recycled polyolefin |
| EP4660237A1 (en) | 2024-06-06 | 2025-12-10 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions comprising recycled polyolefins and propylene homopolymer |
| EP4660239A1 (en) | 2024-06-06 | 2025-12-10 | Basell Poliolefine Italia S.r.l. | Polypropylene compositions containing recycled polyolefins |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58138209A (ja) * | 1982-02-08 | 1983-08-17 | Hitachi Ltd | 蒸気タ−ビン用ロ−タシヤフト |
| EP0702052A1 (en) * | 1994-09-19 | 1996-03-20 | Unilever Plc | Conical wound polyolefin packaging |
| US5532325A (en) * | 1988-04-04 | 1996-07-02 | Chisso Corporation | Process for producing high stiffness polypropylene |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE363977B (enExample) | 1968-11-21 | 1974-02-11 | Montedison Spa | |
| YU35844B (en) | 1968-11-25 | 1981-08-31 | Montedison Spa | Process for obtaining catalysts for the polymerization of olefines |
| GB1603724A (en) | 1977-05-25 | 1981-11-25 | Montedison Spa | Components and catalysts for the polymerisation of alpha-olefins |
| IT1096661B (it) | 1978-06-13 | 1985-08-26 | Montedison Spa | Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente |
| IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| IT1209255B (it) * | 1980-08-13 | 1989-07-16 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine. |
| JPS58138709A (ja) * | 1982-02-12 | 1983-08-17 | Mitsui Petrochem Ind Ltd | オレフインの重合方法 |
| IT1190683B (it) * | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
| JPS59206415A (ja) * | 1983-05-11 | 1984-11-22 | Mitsui Petrochem Ind Ltd | １−ブテンの重合方法 |
| JPS59206418A (ja) * | 1983-05-11 | 1984-11-22 | Mitsui Petrochem Ind Ltd | ４−メチル−１−ペンテン重合体の製法 |
| JPS59207904A (ja) | 1983-05-11 | 1984-11-26 | Mitsui Petrochem Ind Ltd | オレフイン重合体の製造方法 |
| JPH0721018B2 (ja) | 1985-07-05 | 1995-03-08 | 東燃料株式会社 | オレフイン重合用触媒成分の製造方法 |
| KR920000173B1 (ko) | 1986-10-09 | 1992-01-09 | 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 | 저결정성 프로필렌계 랜덤 공중합체 조성물, 그 제조방법 및 폴리프로필렌 복합 적층체 |
| CA1334841C (en) * | 1988-09-13 | 1995-03-21 | Mamoru Kioka | Olefin polymerization catalyst component, process for production thereof, olefin polymerization catalysts, and process for polymerizing olefins |
| KR920007040B1 (ko) | 1988-09-14 | 1992-08-24 | 미쓰이세끼유 가가꾸 고오교오 가부시끼가이샤 | 올레핀 중합용 촉매와 그 촉매의 성분 및 그 촉매에 의한 올레핀 중합법과 그 폴리올레핀에 의한 필름 및 사출성형품 |
| IT1227259B (it) * | 1988-09-30 | 1991-03-28 | Himont Inc | Catalizzatori per la polimerizzazione di olefine. |
| JPH0733407B2 (ja) | 1988-12-26 | 1995-04-12 | 台湾塑膠工業股▲ひん▼有限公司 | ポリオレフィンの製造方法 |
| IT1230134B (it) | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
| EP0414202B1 (en) * | 1989-08-24 | 1995-11-15 | MITSUI TOATSU CHEMICALS, Inc. | Novel extruded polypropylene films and sheets |
| US5504169A (en) * | 1989-09-13 | 1996-04-02 | Exxon Chemical Patents Inc. | Process for producing amorphous poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
| TW203083B (enExample) * | 1990-05-11 | 1993-04-01 | Sumitomo Chemical Co | |
| JPH0488003A (ja) * | 1990-07-30 | 1992-03-19 | Mitsui Petrochem Ind Ltd | 分枝α‐オレフィンの重合方法 |
| IT1262934B (it) | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1262935B (it) | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1256648B (it) | 1992-12-11 | 1995-12-12 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione delle olefine |
| CA2128920C (en) * | 1993-07-28 | 1999-06-01 | Akihiko Yamamoto | Propylene polymer compositions |
| WO1996020225A2 (en) * | 1994-12-20 | 1996-07-04 | Montell Technology Company B.V. | Reactor blend polypropylene, process for the preparation thereof and process for preparing metallocene ligands |
| BR9804806A (pt) | 1997-03-29 | 1999-08-17 | Montell Technology Company Bv | Adutos de alcool-dicloreto de magnesio processo para sua prepara-Æo e componentes de catalisadores obtidos a partir deles |
| EP0919572B8 (en) * | 1997-05-30 | 2004-09-08 | Mitsui Chemicals, Inc. | Polypropylene resin composition and injection-molded article |
| US6265512B1 (en) * | 1997-10-23 | 2001-07-24 | 3M Innovative Company | Elastic polypropylenes and catalysts for their manufacture |
| WO2000063261A1 (en) * | 1999-04-15 | 2000-10-26 | Basell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
| US6716939B2 (en) * | 2000-02-02 | 2004-04-06 | Basell Poliolefine Italia S.P.A. | Components and catalysts for the polymerization of olefins |
| PL355609A1 (en) * | 2000-10-13 | 2004-05-04 | Basell Poliolefine Italia S.P.A. | Catalyst components for the polymerization of olefines |
-
2000
- 2000-04-12 WO PCT/EP2000/003333 patent/WO2000063261A1/en not_active Ceased
- 2000-04-12 HU HU0103083A patent/HUP0103083A3/hu unknown
- 2000-04-12 PL PL00345209A patent/PL345209A1/xx not_active IP Right Cessation
- 2000-04-12 ES ES00926912T patent/ES2269135T3/es not_active Expired - Lifetime
- 2000-04-12 CA CA002334743A patent/CA2334743C/en not_active Expired - Lifetime
- 2000-04-12 CN CNB008011230A patent/CN1240729C/zh not_active Expired - Lifetime
- 2000-04-12 DE DE60029714T patent/DE60029714T2/de not_active Expired - Lifetime
- 2000-04-12 BR BRPI0006095-0B1A patent/BR0006095B1/pt active IP Right Grant
- 2000-04-12 AU AU45486/00A patent/AU777683B2/en not_active Ceased
- 2000-04-12 EP EP00926912A patent/EP1088009B1/en not_active Expired - Lifetime
- 2000-04-12 ID IDW20010114A patent/ID28200A/id unknown
- 2000-04-12 IL IL140154A patent/IL140154A/en active IP Right Grant
- 2000-04-12 RU RU2001101489/04A patent/RU2225415C2/ru active
- 2000-04-12 AT AT00926912T patent/ATE335014T1/de active
- 2000-04-12 US US09/762,363 patent/US6818583B1/en not_active Expired - Lifetime
- 2000-04-12 JP JP2000612346A patent/JP4717219B2/ja not_active Expired - Lifetime
- 2000-04-12 CN CNB2003101242368A patent/CN1294159C/zh not_active Expired - Lifetime
- 2000-04-12 KR KR1020007014289A patent/KR100700957B1/ko not_active Expired - Lifetime
- 2000-04-13 TW TW089106866A patent/TWI229086B/zh not_active IP Right Cessation
- 2000-04-14 MY MYPI20001602A patent/MY124016A/en unknown
- 2000-04-17 AR ARP000101780A patent/AR043275A1/es active IP Right Grant
- 2000-09-24 SA SA00210385A patent/SA00210385B1/ar unknown
- 2000-12-14 NO NO20006388A patent/NO20006388L/no not_active Application Discontinuation
-
2004
- 2004-08-31 US US10/930,452 patent/US20050032633A1/en not_active Abandoned
-
2011
- 2011-01-11 JP JP2011003209A patent/JP5372030B2/ja not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58138209A (ja) * | 1982-02-08 | 1983-08-17 | Hitachi Ltd | 蒸気タ−ビン用ロ−タシヤフト |
| US5532325A (en) * | 1988-04-04 | 1996-07-02 | Chisso Corporation | Process for producing high stiffness polypropylene |
| EP0702052A1 (en) * | 1994-09-19 | 1996-03-20 | Unilever Plc | Conical wound polyolefin packaging |
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