WO2017018011A1 - 溶剤組成物、洗浄方法、塗膜の形成方法、熱移動媒体および熱サイクルシステム - Google Patents
溶剤組成物、洗浄方法、塗膜の形成方法、熱移動媒体および熱サイクルシステム Download PDFInfo
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- WO2017018011A1 WO2017018011A1 PCT/JP2016/062476 JP2016062476W WO2017018011A1 WO 2017018011 A1 WO2017018011 A1 WO 2017018011A1 JP 2016062476 W JP2016062476 W JP 2016062476W WO 2017018011 A1 WO2017018011 A1 WO 2017018011A1
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- PGQAXGHQYGXVDC-UHFFFAOYSA-N dodecyl(dimethyl)azanium;chloride Chemical compound Cl.CCCCCCCCCCCCN(C)C PGQAXGHQYGXVDC-UHFFFAOYSA-N 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
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- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical class C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
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- 229960001867 guaiacol Drugs 0.000 description 1
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- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000004255 ion exchange chromatography Methods 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- LAQFLZHBVPULPL-UHFFFAOYSA-N methyl(phenyl)silicon Chemical compound C[Si]C1=CC=CC=C1 LAQFLZHBVPULPL-UHFFFAOYSA-N 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002828 nitro derivatives Chemical class 0.000 description 1
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
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- 229920000728 polyester Polymers 0.000 description 1
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- 238000002360 preparation method Methods 0.000 description 1
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- 239000002964 rayon Substances 0.000 description 1
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- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
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- NHGXDBSUJJNIRV-UHFFFAOYSA-M tetrabutylammonium chloride Chemical compound [Cl-].CCCC[N+](CCCC)(CCCC)CCCC NHGXDBSUJJNIRV-UHFFFAOYSA-M 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
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- AOBORMOPSGHCAX-DGHZZKTQSA-N tocofersolan Chemical compound OCCOC(=O)CCC(=O)OC1=C(C)C(C)=C2O[C@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C AOBORMOPSGHCAX-DGHZZKTQSA-N 0.000 description 1
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- 150000003852 triazoles Chemical class 0.000 description 1
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C21/00—Acyclic unsaturated compounds containing halogen atoms
- C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
- C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C19/00—Acyclic saturated compounds containing halogen atoms
- C07C19/08—Acyclic saturated compounds containing halogen atoms containing fluorine
- C07C19/10—Acyclic saturated compounds containing halogen atoms containing fluorine and chlorine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C21/00—Acyclic unsaturated compounds containing halogen atoms
- C07C21/22—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon triple bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B3/00—Preparation of cellulose esters of organic acids
- C08B3/08—Preparation of cellulose esters of organic acids of monobasic organic acids with three or more carbon atoms, e.g. propionate or butyrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/08—Materials not undergoing a change of physical state when used
- C09K5/10—Liquid materials
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/28—Organic compounds containing halogen
- C11D7/30—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5018—Halogenated solvents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/126—Unsaturated fluorinated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Definitions
- the present invention relates to a solvent composition excellent in solubility of various organic substances, excellent in cleaning properties, having no adverse effect on the global environment, excellent in stability, and capable of suppressing metal corrosion.
- the solvent composition of the present invention can be used in a wide range of applications such as a cleaning solvent, a diluted coating solvent, and a heat transfer medium.
- a cleaning solvent in the manufacturing process, assembly process, final finishing process, etc., and flux, processing oil, wax, separation, etc. Removal of molds, dust and the like has been performed.
- a method of manufacturing an article having a coating film containing various organic chemical substances such as a lubricant, for example, a solution in which the organic chemical substance is dissolved in a diluted coating solvent is prepared, and the solution is applied onto an object to be coated. Then, a method of forming a coating film by evaporating the diluted coating solvent is known.
- the diluted coating solvent is required to sufficiently dissolve the organic chemical substance and to have sufficient drying properties.
- Solvents used for such applications are non-flammable, have low toxicity, are excellent in stability, do not attack metals, plastics, elastomers and other base materials, and are excellent in chemical and thermal stability.
- CFCs 2-trichloro-1,2,2-trifluoroethane and other chlorofluorocarbons
- 2,2-dichloro-1,1,1-trifluoroethane 1,1 Hydro such as dichloro-1-fluoroethane, 3,3-dichloro-1,1,1,2,2-pentafluoropropane, 1,3-dichloro-1,1,2,2,3-pentafluoropropane
- HCFCs chlorofluorocarbons
- CFCs and HCFCs are chemically very stable, they have a long lifetime in the troposphere after vaporization and diffuse to reach the stratosphere. Therefore, there is a problem that CFCs and HCFCs that have reached the stratosphere are decomposed by ultraviolet rays, generating chlorine radicals and destroying the ozone layer.
- perfluorocarbons (hereinafter referred to as “PFCs”) are known as solvents that have no chlorine atom and do not adversely affect the ozone layer.
- PFCs perfluorocarbons
- HFCs hydrofluorocarbons
- HFEs hydrofluoroethers
- HFCs and PFCs are regulated substances of the Kyoto Protocol because of their high global warming potential.
- Fluoroolefins having a double bond between carbon and carbon atoms have been proposed as new solvents that replace HFCs, HFEs, and PFCs. These fluoroolefins have an excellent property of having a short life in the atmosphere because they are easily decomposed and having a small impact on the global environment because of their low ozone depletion potential and global warming potential. On the other hand, since it is easily decomposed, it is inferior in stability, and when used as a cleaning solvent or a diluted coating solvent, there is a problem that it decomposes and acidifies during use.
- Patent Documents 1 and 2 disclose that a wide variety of fluoroolefins having a double bond between carbon atoms including 1-chloro-2,3,3-trifluoro-1-propene are used as lubricants. Disclosed are techniques for adding additional components as stabilizers, metal passivators, corrosion inhibitors, flame inhibitors, and other compounds and / or components that modulate specific properties of the composition Yes.
- 1,1,2,2,3-pentafluoro is obtained by reacting 1-chloro-2,2,3,3-tetrafluoropropane with hydrogen fluoride in a gas phase.
- a small amount of 1-chloro-2,3,3-trifluoro-1-propene is described as a by-product along with propane.
- Patent Documents 1 to 3 disclose that 1-chloro-2,3,3-trifluoro-1-propene is added with a small amount of 1-chloro-2,2,3,3-tetrafluoropropane to add 1-chloro-2,3,3-trifluoro-1-propene. There is no description regarding the technology for stabilizing chloro-2,3,3-trifluoro-1-propene.
- the present invention is a solvent composition excellent in solubility of various organic substances, excellent in cleaning properties, having no adverse effect on the global environment, excellent in stability, and capable of suppressing metal corrosion, and a cleaning method using the solvent composition
- An object of the present invention is to provide a method for forming a coating film using the solvent composition, a heat transfer medium containing the solvent composition, and a heat cycle system using the heat transfer medium.
- this invention consists of the following.
- a solvent composition comprising 1-chloro-2,3,3-trifluoro-1-propene and 1-chloro-2,2,3,3-tetrafluoropropane, 1-chloro-2,2,3 with respect to the sum of the content of 1-chloro-2,3,3-trifluoro-1-propene and the content of 1-chloro-2,2,3,3-tetrafluoropropane , 3-Tetrafluoropropane content ratio is 0.0001 to 1% by mass.
- the solvent composition according to [1] wherein the ratio of the content of 1-chloro-2,3,3-trifluoro-1-propene to the total amount of the solvent composition is 80% by mass or more.
- a cleaning method comprising bringing the solvent composition according to any one of [1] to [3] into contact with an article to be cleaned.
- the processing oil is at least one selected from the group consisting of cutting oil, quenching oil, rolling oil, lubricating oil, machine oil, pressing oil, punching oil, drawing oil, assembly oil, and drawing oil.
- [7] The cleaning method according to any one of [4] to [6], wherein the article to be cleaned is clothing.
- a non-volatile organic compound is dissolved in the solvent composition according to any one of [1] to [3] to prepare a coating film-forming composition, and the coating film-forming composition is coated on the object to be coated.
- a method for forming a coating film comprising: evaporating the solvent composition after application to form a coating film composed of the nonvolatile organic compound.
- a heat transfer medium comprising the solvent composition according to any one of [1] to [3].
- the solvent composition of the present invention is excellent in solubility of various organic substances, excellent in cleaning properties, does not adversely affect the global environment, has excellent stability, and can suppress metal corrosion.
- the cleaning method of the present invention does not adversely affect the global environment and is excellent in cleaning properties.
- the coating film forming method of the present invention can form a uniform coating film without adversely affecting the global environment.
- the heat transfer medium containing the solvent composition of the present invention does not adversely affect the global environment and is excellent in stability.
- the heat cycle system using the heat transfer medium of the present invention does not adversely affect the global environment.
- HCFO-1233yd is a component having the following excellent characteristics as a solvent
- HCFC-244ca is a component contained in the solvent composition as a stabilizer for stabilizing HCFO-1233yd.
- HCFO-1233yd Since HCFO-1233yd is a fluoroolefin having a double bond between carbon atoms, the lifetime in the atmosphere is short, and the ozone depletion coefficient and global warming coefficient are small.
- HCFO-1233yd has Z and E isomers, which are geometric isomers, depending on the position of the substituent on the double bond.
- E isomers
- HCFO-1233yd indicates the Z form
- E indicates the E form.
- HCFO-1233yd (Z) has a boiling point of about 54 ° C. and HCFO-1233yd (E) has a boiling point of about 48 ° C., both of which are excellent in drying properties.
- HCFO-1233yd (Z) has a boiling point of about 54 ° C.
- HCFO-1233yd (E) has a boiling point of about 48 ° C., both of which are excellent in drying properties.
- HCFO-1233yd (Z) has a boiling point of about 54 ° C.
- E has a boiling point of about 48 ° C., both of which are excellent in drying properties.
- HCFO-1233yd even if it is boiled into steam, it is about 54 ° C for HCFO-1233yd (Z) and about 48 ° C for HCFO-1233yd (E), so even parts that are easily affected by heat such as resin parts. It is hard to have an adverse effect.
- HCFO-1233yd does not have a flash
- the boiling point of a compound is a boiling point at normal pressure unless otherwise specified.
- normal pressure means 760 mmHg
- normal temperature means 25 ° C.
- HCFO-1233yd is not stable enough, and there is a problem that when HCFO-1233yd is stored at room temperature and normal pressure, it decomposes within a few days and generates chlorine ions. Therefore, in the solvent composition of the present invention, HCFO-1233yd is stabilized by containing the predetermined amount of HCFC-244ca together with HCFO-1233yd.
- the ratio of the content of HCFO-1233yd in the solvent composition of the present invention is preferably 80% by mass or more, more preferably 90% by mass or more with respect to the total amount of the solvent composition. If it is more than the said lower limit, it is excellent in the solubility of various organic substance of a solvent composition, and is excellent in a washability.
- the content of HCFO-1233yd is particularly preferably the total amount obtained by removing HCFC-244ca from the solvent composition. That is, it is particularly preferable that the solvent composition is composed only of HCFO-1233yd and HCFC-244ca.
- the solvent composition includes components that are difficult to separate from HCFO-1233yd produced in the process of producing HCFO-1233yd and components that are difficult to separate from HCFC-244ca produced in the process of producing HCFC-244ca.
- You may contain in the range which does not impair an effect, for example, the quantity used as 10 mass% or less with respect to the solvent composition whole quantity, Preferably it is 5 mass% or less.
- the boiling point of HCFC-244ca is about 53 ° C.
- HCFO-1233yd (Z) is preferable to HCFO-1233yd (E) because the boiling point of HCFO-1233yd (Z) is closer to that of HCFC-244ca.
- a composition having compounds having close boiling points is used, the composition change is unlikely to occur between the liquid phase and the gas phase even in use in which a phase change occurs between the liquid phase and the gas phase.
- a solvent composition composed of HCFO-1233yd (Z) and HCFC-244ca has a solvent contact step in which an article to be cleaned is brought into contact with a liquid phase solvent composition, and the solvent composition is evaporated after the solvent contact step.
- the article to be cleaned is treated with the same composition for a long period of time because there is almost no composition change between the liquid phase and the gas phase. Can do.
- the ratio of the content of HCFO-1233yd (Z) to the total amount of HCFO-1233yd is preferably 80 to 100% by mass, more preferably 90 to 100% by mass. If it is the said range, the stable use is possible, hardly causing the composition change of a solvent composition.
- the upper limit of the content ratio of HCFO-1233yd (Z) is 99% of the total amount of HCFO-1233yd, from the viewpoint of suppressing an increase in production cost due to distillation separation of the Z-form and E-form of HCFO-1233yd. About 9% by mass is more preferable.
- HCFO-1233yd can be produced, for example, by dehydrofluorinating HCFC-244ca, which is industrially available stably. According to this method, HCFO-1233yd is produced by a dehydrofluorination reaction at a temperature of 50 to 80 ° C. using HCFC-244ca as a raw material and potassium hydroxide or sodium hydroxide as a reactant.
- the produced HCFO-1233yd includes structural isomers HCFO-1233yd (Z) and HCFO-1233yd (E).
- HCFO-1233yd (Z) is obtained from HCFO-1233yd (E). Also generate a lot. These isomers can be separated into HCFO-1233yd (Z) and HCFO-1233yd (E) in a subsequent purification step.
- HCFO-1233yd obtained by appropriately purifying the reaction solution containing HCFO-1233yd generated above, components that are difficult to separate from HCFO-1233yd are effective for the present invention.
- a crudely purified product of HCFO-1233yd may be used in a range that does not impair, for example, in an amount of 10% by mass or less, preferably 5% by mass or less, based on the total amount of the solvent composition. If a crude product of HCFO-1233yd is used, the cost for distillation separation is reduced, which is preferable.
- HCFO-1233yd is obtained by further dehydrofluorination as a component that is difficult to separate from HCFO-1233yd brought into the solvent composition in the form contained in the crude product of HCFO-1233yd.
- 1-chloro-3,3-difluoro-1-propyne as a by-product can be mentioned.
- the content ratio of 1-chloro-3,3-difluoro-1-propyne in the solvent composition is 0.0001 to 0.1 mass with respect to the total amount of HCFO-1233yd from the viewpoint of stability and separation cost. % Is preferable, and 0.0001 to 0.001 mass% is more preferable.
- HCFC-244ca is a compound soluble in HCFO-1233yd that is used as a raw material for producing HCFO-1233yd as described above, and can be stably obtained industrially, for example, by the method described below.
- HCFC-244ca has properties as HCFC and suppresses and stabilizes decomposition of HCFO-1233yd (Z) and HCFO-1233yd (E) by an effect that is not necessarily clear but is presumed to be radical scavenging. It is considered to have a function as a stabilizer.
- a substance is soluble in HCFO-1233yd by mixing the substance with HCFO-1233yd so as to have a desired concentration and stirring at room temperature (25 ° C.). It means the property of being able to dissolve uniformly without causing layer separation or turbidity.
- the stability of the solvent composition of the present invention can be evaluated using, for example, the difference between the initial pH of the solvent composition and the pH after the solvent composition has been stored for a certain period as an index.
- the pH of the solvent composition in the present invention refers to the pH of the upper aqueous layer when the solvent composition and pure water of pH 7 are mixed, shaken for a predetermined time, and then allowed to stand to separate into two layers. .
- specific pH measurement conditions the conditions described in the section of pH measurement described in Examples described later can be employed.
- the pH measured before and after storing the solvent composition at the boiling point of HCFO-1233yd (Z) (about 54 ° C.) for 7 days. Can be suppressed to 1.5 or less.
- the difference in pH when evaluated in the same manner as described above can be 1.0 or less, or 0.
- the content of HCFC-244ca in the solvent composition of the present invention is such that HCFO-1233yd can exhibit the above performance as a solvent and that HCFO-1233yd is stabilized, that is, the content of HCFO-1233yd and the HCFC.
- the amount is 0.0001 to 1% by mass with respect to the total content of ⁇ 244ca.
- the ratio of the content of HCFC-244ca is preferably 0.0005 to 0.1% by mass, and 0.01 to 0.05% by mass with respect to the total content of HCFO-1233yd and HCFC-244ca Is more preferable.
- HCFC-244ca and HCFO-1233yd have close boiling points. Therefore, in the solvent composition of the present invention containing them, even in applications that are used repeatedly with phase change. In addition, decomposition of HCFO-1233yd is suppressed, and stable use is possible with almost no change in composition.
- HCFC-244ca is a compound known as a raw material or intermediate for producing a fluorine-containing compound, and can be easily obtained.
- the method for obtaining HCFC-244ca is not particularly limited.
- 2,2,3,3-tetrafluoropropanol (TFPO) is chlorinated with thionyl chloride (SOCl 2 ) in the presence of N, N-dimethylformamide (DMF). It can be manufactured by the method of converting. This process can be carried out in the liquid phase or in the gas phase.
- HCFC-244ca isolated from the reaction solution obtained by the above method may be used.
- components that are difficult to separate from HCFC-244ca are within the range not impairing the effects of the present invention.
- a roughly purified product of HCFC-244ca containing 10% by mass or less, preferably 5% by mass or less based on the total amount of the solvent composition may be used.
- the reaction liquid containing HCFO-1233yd obtained is usually an HCFC that is an unreacted raw material as a component that is difficult to separate from HCFO-1233yd.
- -244ca is included.
- the boiling point of HCFC-244ca is about 53 ° C., and the boiling point is close to that of HCFO-1233yd (Z). In particular, it can be included in the crude product.
- a mixture containing both HCFO-1233yd and HCFC-244ca and having a content reduced to an amount that does not impair the effects of the present invention for other components is separated from the reaction solution obtained by the above method. It is also possible to use the mixture as it is as the solvent composition of the present invention.
- the solvent composition of the present invention is produced in the process of producing HCFO-1233yd and HCFC-244ca and HCFO-1233yd or 1-chloro-3,3-difluoro-1-propyne together with HCFO-1233yd and HCFC-244ca.
- components other than components difficult to separate from HCFO-1233yd or HCFC-244ca may be contained within a range not impairing the effects of the present invention.
- Other components include, for example, a component that functions as a solvent other than HCFO-1233yd that is soluble in HCFO-1233yd used for various purposes such as increasing solubility and adjusting the volatilization rate (however, HCFC-244ca Hereinafter, it may be referred to as “other solvent”).
- the other component may also be, for example, a stabilizer other than HCFC-244ca that stabilizes HCFO-1233yd (hereinafter referred to as “other stabilizer”).
- other stabilizer a stabilizer other than HCFC-244ca that stabilizes HCFO-1233yd
- stabilizers include at least one selected from the group consisting of phenols, ethers, epoxides, amines, alcohols, and hydrocarbons. 1 type may be sufficient as a stabilizer and 2 or more types may be sufficient as it.
- Phenols are preferably phenol, 1,2-benzenediol, 2,6-ditertiarybutyl-4-methylphenol, m-cresol, 2-isopropyl-5-methylphenol, ⁇ -tocopherol and 2-methoxyphenol. .
- ethers 4- to 6-membered cyclic ethers are preferable, and among them, 1,4-dioxane, 1,3-dioxane, 1,3,5-trioxane, 2-methylfuran and tetrahydrofuran are preferable.
- 1,2-propylene oxide, 1,2-butylene oxide and butyl glycidyl ether are preferable.
- amines alkylamines and cyclic amines are preferable, and pyrrole, N-methylpyrrole, 2-methylpyridine, n-propylamine, diisopropylamine, N-methylmorpholine and N-ethylmorpholine are particularly preferable.
- alcohols methanol, ethanol, isopropyl alcohol, and 2-propyn-1-ol, which are linear or branched alcohols having 1 to 3 carbon atoms, are preferable.
- n-pentane, cyclopentane, n-hexane, cyclohexane and n-heptane are preferable for saturated hydrocarbons.
- unsaturated hydrocarbons 2-methyl-2-butene, 2-methyl-1-pentene, 2-methyl-2-pentene, 3-ethyl-2-butene, 2,3-dimethyl-2-butene, 2,4,4-trimethyl-1-pentene and 2,4,4-trimethyl-2-pentene are preferred.
- stabilizers include 2-methyl-1-pentene, 2-methyl-2-pentene, 3-ethyl-2-butene, and 2,3-dimethyl-2-butene among these from the viewpoint of stability. 2,4,4-trimethyl-1-pentene, 2,4,4-trimethyl-2-pentene, N-methylpyrrole and 2-propyn-1-ol are more preferable.
- the solvent composition of the present invention When the solvent composition of the present invention comes into contact with copper or a copper alloy, it may contain nitro compounds or triazoles in order to avoid corrosion of those metals.
- the content of other components in the solvent composition of the present invention is appropriately adjusted within a range that does not impair the effects of the present invention, depending on the type of other components.
- the proportion of the content of other components is preferably approximately 1% by mass or less, and more preferably 0.1% by mass or less for each component with respect to the total amount of the solvent composition. Further, the total content of other components is preferably 10% by mass or less, and more preferably 1% or less.
- the solvent composition of the present invention is a stable solvent composition that is excellent in solubility of various organic substances, excellent in cleaning properties, and has no adverse effect on the global environment, and is stabilized and suppressed from being decomposed. It is preferably used for cleaning applications such as flux cleaning, precision cleaning, and dry cleaning.
- the solvent composition of the present invention also includes a lubricant such as a silicone-based lubricant and a fluorine-based lubricant, a rust-preventing agent composed of mineral oil or synthetic oil, a moisture-proof coating agent for performing water-repellent treatment, and an antifouling treatment.
- An antifouling coating agent such as an antifouling anti-fouling agent or the like can be dissolved and applied as a coating film forming composition to the surface of an article to form a coating film.
- the solvent composition of the present invention is further suitable as a heat transfer medium for heating and cooling an article.
- Articles to which the solvent composition of the present invention can be applied include capacitors and diodes, electronic parts such as substrates on which these are mounted, optical parts such as lenses and polarizing plates, fuel injection needles used in automobile engine parts, It can be widely used for automobile parts such as gears for driving parts, parts for driving parts used for industrial robots, machine parts such as exterior parts, and carbide tools used for machine tools such as cutting tools.
- materials to which the solvent composition of the present invention can be applied include a wide range of materials such as metals, plastics, elastomers, glasses, ceramics, and fabrics. Among these, iron, copper, nickel, gold, silver It is suitable for metals such as platinum, sintered metal, glass, fluororesin, and engineering plastics such as PEEK.
- the cleaning method of the present invention is a method of cleaning the deposit adhered to the article to be cleaned by the solvent composition of the present invention, and is characterized by bringing the solvent composition of the present invention into contact with the article to be cleaned. .
- the deposits to be cleaned and removed include fluxes adhering to various articles to be cleaned; cutting oil, quenching oil, rolling oil, lubricating oil, machine oil, pressing oil, punching oil, and drawing oil. And processing oils such as assembly oil and wire drawing oil; mold release agents; dust and the like. Since this solvent composition is superior in solubility of processing oil as compared with conventional solvent compositions such as HFC and HFE, it is preferably used for cleaning of processing oil.
- the solvent composition of the present invention can be applied to cleaning articles to be cleaned of various materials such as metals, plastics, elastomers, glass, ceramics and composite materials thereof, fabrics made of natural fibers or synthetic fibers.
- objects to be cleaned include textile products, medical instruments, electrical equipment, precision machines, optical articles, and parts thereof.
- electrical devices, precision machines, optical articles, and parts thereof include ICs, capacitors, printed boards, micromotors, relays, bearings, optical lenses, glass substrates, and the like.
- the method for cleaning an object to be cleaned using the solvent composition of the present invention is not particularly limited except that the solvent composition of the present invention and the article to be cleaned are brought into contact with each other. By this contact, the dirt adhering to the surface of the article to be cleaned can be removed.
- specific cleaning methods for example, hand-wiping cleaning, immersion cleaning, spray cleaning, immersion rocking cleaning, immersion ultrasonic cleaning, steam cleaning, and a combination of these may be employed.
- the cleaning conditions such as the contact time and frequency and the temperature of the solvent composition of the present invention at that time may be appropriately selected according to the cleaning method.
- a well-known thing can also be suitably selected also according to each washing
- the cleaning method of the present invention includes, for example, a solvent contact step in which an article to be cleaned is brought into contact with a liquid-phase solvent composition, and the article to be cleaned is exposed to vapor generated by evaporating the solvent composition after the solvent contact step. And a vapor contact process.
- a cleaning method and a cleaning apparatus to which the cleaning method can be applied include a cleaning method and a cleaning apparatus disclosed in International Publication No. 2008/149907.
- FIG. 1 is a diagram schematically showing an example of a cleaning apparatus similar to the cleaning apparatus shown in International Publication No. 2008/149907, which performs a cleaning method having the solvent contact step and the vapor contact step.
- the cleaning device 10 includes a cleaning tank 1, a rinse tank 2, and a steam generation tank 3 in which the solvent composition L is accommodated.
- the cleaning device 10 further has a vapor zone 4 filled with vapor generated from the solvent composition L, a cooling pipe 9 for cooling the vapor, and a solvent composition obtained by condensation through the cooling pipe 9 above these tanks.
- a water separation tank 5 is provided for static separation of L and water adhering to the cooling pipe.
- the article D to be cleaned is placed in a dedicated jig or basket, and the cleaning is completed while moving in the cleaning device 10 in the order of the cleaning tank 1, the rinsing tank 2, and the steam zone 43 directly above the steam generation tank 3.
- a heater 7 and an ultrasonic vibrator 8 are provided in the lower part of the washing tank 1.
- the solvent composition L is heated and heated by the heater 7, and a physical force is applied to the article D to be cleaned by cavitation generated by the ultrasonic vibrator 8 while being controlled at a constant temperature.
- the dirt adhering to the cleaning article D is cleaned and removed.
- any method that has been employed in conventional washing machines such as rocking or jetting of the solvent composition L in liquid may be used.
- ultrasonic vibration is not essential, and cleaning may be performed without ultrasonic vibration as necessary.
- the dirt component adhering to the article to be cleaned D while being dissolved in the solvent composition L is removed by immersing the article to be cleaned D in the solvent composition L.
- the cleaning device 10 is designed such that the overflow of the solvent composition L accommodated in the rinsing tank 2 flows into the cleaning tank 1. Further, the cleaning tank 1 is provided with a pipe 11 for feeding the solvent composition L to the steam generation tank 3 for the purpose of preventing the liquid level from exceeding a predetermined height.
- a heater 6 for heating the solvent composition L in the steam generation tank 3 is provided at the lower part of the steam generation tank 3.
- the solvent composition L accommodated in the steam generation tank 3 is heated and boiled by the heater 6, part or all of the composition becomes steam and rises upward as indicated by the arrow 13, and immediately above the steam generation tank 3.
- a steam zone 43 filled with steam is formed.
- the article to be cleaned D that has been cleaned in the rinse layer 2 is transferred to the steam zone 43 and exposed to steam for steam cleaning (steam contact process).
- the space above each tank is commonly used as the vapor zone 4.
- the steam generated from the cleaning tank 1, the rinsing tank 2 and the steam generation tank 3 is recovered from the steam zone 4 as the solvent composition L by being cooled and condensed by the cooling pipe 9 provided on the upper wall surface of the cleaning device 10. Is done.
- the agglomerated solvent composition L is then accommodated in the water separation tank 5 via a pipe 14 connecting the cooling pipe 9 and the water separation tank 5.
- water separation tank 5 water mixed in the solvent composition L is separated.
- the solvent composition L from which water has been separated is returned to the rinsing tank 2 through the pipe 12 connecting the water separation tank 5 and the rinsing tank 2.
- the temperature of the solvent composition of the present invention in the cleaning tank 1 is preferably 25 ° C. or higher and lower than the boiling point of the solvent composition. If it is in the said range, degreasing cleaning of processing oil etc. can be performed easily and the cleaning effect by an ultrasonic wave is high.
- the temperature of the solvent composition of the present invention in the rinsing tank 2 is preferably 10 to 45 ° C. If it is within the above range, a sufficient temperature difference between the temperature of the article and the solvent composition vapor can be obtained in the vapor washing step, so that a sufficient amount of the solvent composition can be condensed on the surface of the article for rinsing washing. High effect.
- the temperature of the solvent composition of this invention in the washing tank 1 is higher than the temperature of the solvent composition of the rinse tank 2 from the point of detergency.
- the solvent composition of the present invention is suitable as a washing solvent for clothes, that is, a dry cleaning solvent.
- the dry cleaning application using the solvent composition of the present invention includes washing and removing dirt adhered to clothes such as shirts, sweaters, jackets, skirts, trousers, jumpers, gloves, mufflers, and stalls.
- the solvent composition of the present invention can be applied to dry cleaning of clothing made of fibers such as cotton, hemp, wool, rayon, polyester, acrylic, nylon and the like.
- HCFO-1233yd contained in the solvent composition of the present invention contains chlorine atoms in the molecule, so that the solubility of dirt is high, and it is the same as HCFCs such as HCFC-225 (dichloropentafluoropropane) having a wide solubility. It has been found that there is a detergency against a certain degree of oil stains.
- the solvent composition of the present invention when used as a dry cleaning solvent, it is used as a dry cleaning solvent composition by adding soap to improve the removal performance of water-soluble dirt such as sweat and mud. Can do.
- Soap refers to a surfactant used for dry cleaning, and it is preferable to use a surfactant such as a cationic, nonionic, anionic or amphoteric surfactant.
- HCFO-1233yd is known to have a wide range of solubility in various organic compounds because it has a chlorine atom in its molecule, and it is not necessary to optimize the soap with a solvent like HFEs and HFCs. Soap can be used.
- the dry cleaning solvent composition using the solvent composition of the present invention is selected from the group consisting of a cationic surfactant, a nonionic surfactant, an anionic surfactant, and an amphoteric surfactant. At least one surfactant.
- soaps include quaternary ammonium salts such as dodecyldimethylammonium chloride and trimethylammonium chloride as cationic surfactants.
- Nonionic surfactants include polyoxyalkylene nonyl phenyl ether, polyoxyalkylene alkyl ether, fatty acid alkanolamide, glycerin fatty acid ester, sorbitan fatty acid ester, sucrose fatty acid ester, propylene glycol fatty acid ester, phosphoric acid and fatty acid ester, etc. An activator is mentioned.
- anionic surfactant examples include alkyl sulfates such as polyoxyethylene alkyl sulfates, carboxylates such as fatty acid salts (soap), and sulfonates such as ⁇ -olefin sulfonates and lauryl sulfates.
- amphoteric surfactants include betaine compounds such as alkyl betaines.
- the content ratio of the soap in the dry cleaning solvent composition is 0.01 to 10% by mass, preferably 0.1 to 5% by mass, further based on the total amount of the solvent composition contained in the dry cleaning solvent composition.
- the content is preferably 0.2 to 2% by mass.
- the cleaning method of the present invention described above, by using the solvent composition of the present invention, decomposition of the solvent composition is suppressed, and long-term repeated cleaning is possible. Moreover, if the solvent composition of the present invention is used, regeneration operations such as distillation regeneration and filtration regeneration, gas recovery for recovering the vapor of the scattered solvent composition, and the like can be appropriately combined without any problem.
- the solvent composition of the present invention can be used as a solvent for dilute coating of non-volatile organic compounds (diluted coating solvent). That is, the method for forming a coating film of the present invention comprises preparing a coating film forming composition by dissolving a non-volatile organic compound in the solvent composition of the present invention, and applying the coating film forming composition on an object to be coated. After coating, the solvent composition is evaporated to form a coating film made of the nonvolatile organic compound.
- the non-volatile organic compound in the present invention means a compound having a boiling point higher than that of the solvent composition of the present invention and the organic compound remaining on the surface even after the solvent composition evaporates.
- a non-volatile organic compound a lubricant for imparting lubricity to an article, a rust inhibitor for imparting a rust preventive effect to metal parts, and a moisture-proof coating agent for imparting water repellency to an article
- antifouling coating agents such as fingerprint removal adhesion preventing agents for imparting antifouling performance to articles.
- a lubricant is preferably used as the nonvolatile organic compound from the viewpoint of solubility.
- Lubricant means a material used to reduce friction on the contact surface and prevent heat generation and wear damage when the two members move with their surfaces in contact with each other.
- the lubricant may be in any form of liquid (oil), semi-solid (grease), and solid.
- a fluorine-based lubricant or a silicone-based lubricant is preferable from the viewpoint of excellent solubility in HCFO-1233yd.
- a fluorine-type lubricant means the lubricant which has a fluorine atom in a molecule
- the silicone-based lubricant means a lubricant containing silicone.
- 1 type may be sufficient as the lubricant contained in the composition for coating-film formation, and 2 or more types may be sufficient as it.
- Each of the fluorine-based lubricant and the silicone-based lubricant may be used alone or in combination.
- fluorine-based lubricant examples include fluorine-based solid lubricants such as fluorine oil, fluorine grease, and polytetrafluoroethylene resin powder.
- fluorine oil perfluoropolyether or a low polymer of chlorotrifluoroethylene is preferable.
- commercially available fluorine oil include “Crytox (registered trademark) GPL102” (manufactured by DuPont), “Daiflooil # 1”, “Daiflooil # 3”, “Daiflooil # 10”, and “Daiflooil # 20”. ”,“ Daifloil # 50 ”,“ Daifloil # 100 ”,“ DEMNUM S-65 ”(manufactured by Daikin Industries, Ltd.), and the like.
- Fluorine grease is preferably a blend of polytetrafluoroethylene powder or other thickener with a fluorine oil such as perfluoropolyether or a low polymer of chlorotrifluoroethylene as a base oil.
- fluorine greases include, for example, product names “Crytox (registered trademark) 240AC” (manufactured by DuPont), “Daiflooil grease DG-203”, “Demnam L65”, “Demnam L100”, “ “DEMNUM L200” (manufactured by Daikin Corporation), “Sumitec F936” (manufactured by Sumiko Lubricant Co., Ltd.), "Molicoat (registered trademark) HP-300", “Molicoat (registered trademark) HP-500", “Molicoat” (Registered trademark) HP-870 “,” Moricoat (registered trademark) 6169 "(manufactured by Toray Dow Corning Co., Ltd.), and the like
- Silicone lubricants and silicone greases are examples of silicone lubricants.
- silicone oil dimethyl silicone, methyl hydrogen silicone, methylphenyl silicone, cyclic dimethyl silicone, amine group-modified silicone, diamine group-modified silicone, and modified silicone oil in which an organic group is introduced into a side chain or a terminal are preferable.
- examples of commercially available silicone oil products include “Shin-Etsu Silicone KF-96”, “Shin-Etsu Silicone KF-965”, “Shin-Etsu Silicone KF-968”, “Shin-Etsu Silicone KF-99”, and “Shin-Etsu Silicone KF-50”.
- the silicone grease is preferably a product in which various silicone oils listed above are used as a base oil and a thickener such as metal soap and various additives are blended.
- a thickener such as metal soap and various additives are blended.
- commercially available silicone greases include “Shin-Etsu Silicone G-30 Series”, “Shin-Etsu Silicone G-40 Series”, “Shin-Etsu Silicone FG-720 Series”, “Shin-Etsu Silicone G-411”, and “Shin-Etsu Silicone”.
- fluorine-based lubricants and silicone-based lubricants include fluorosilicone oils that are modified silicone oils whose terminal or side chains are substituted with fluoroalkyl groups.
- fluorosilicone oil for example, product names “Unidyne (registered trademark) TG-5601” (manufactured by Daikin Industries, Ltd.), “Molicoat (registered trademark) 3451”, “Molicoat (registered trademark) 3452” (above) , Manufactured by Toray Dow Corning Co., Ltd.), “Shin-Etsu Silicone FL-5”, “Shin-Etsu Silicone X-22-821”, “Shin-Etsu Silicone X-22-822”, “Shin-Etsu Silicone FL-100” (above, Shin-Etsu Chemical) Kogyo Co., Ltd.).
- These lubricants are used as coatings, for example, industrial equipment in which fluorine-based lubricants are usually used as coatings, CD and DVD tray parts in personal computers and audio equipment, printers, copying equipment, flux equipment, and other household equipment. Can be used for office equipment. Further, for example, it can be used for syringe needles and cylinders, medical tube parts, metal blades, catheters and the like in which a silicone-based lubricant is usually used as a coating film.
- the rust preventive agent means a material used to prevent rust of a metal material by covering a metal surface that is easily oxidized by oxygen in the air to cause rust and blocking the metal surface and oxygen.
- Examples of the rust preventive agent include mineral oils and synthetic oils such as polyol esters, polyalkylene glycols, and polyvinyl ethers.
- the moisture proof coating agent and the antifouling coating agent are used for imparting moisture proofing and antifouling properties to plastic, rubber, metal, glass, mounted circuit boards and the like.
- moisture-proof coating agents include TOPAS 5013, TOPAS 6013, TOPAS 8007 (manufactured by Polyplastics), ZEONOR 1020R, ZEONOR 1060R (manufactured by Nippon Zeon), APPEL 6011T, APEL 8008T (manufactured by Mitsui Chemicals), SFE -DP02H, SNF-DP20H (manufactured by Seimi Chemical Co., Ltd.).
- antifouling coating agents such as fingerprint adhesion preventing agents
- fingerprint adhesion preventing agents include OPTOOL DSX, OPTOOL DAC (manufactured by Daikin Industries), Fluoro Surf FG-5000 (manufactured by Fluoro Technology), SR-4000A (manufactured by Seimi Chemical).
- the composition for forming a coating film is usually produced as a solution composition in which a nonvolatile organic compound is dissolved in the solvent composition of the present invention.
- the method for producing the composition for forming a coating film is not particularly limited as long as it is a method capable of uniformly dissolving the nonvolatile organic compound in the solvent composition of the present invention at a predetermined ratio.
- the composition for forming a coating film is basically composed only of a nonvolatile organic compound and the solvent composition of the present invention.
- a composition for forming a coating film using a lubricant as a nonvolatile organic compound is referred to as a “lubricant solution”. The same applies to the coating film forming composition using other nonvolatile organic compounds.
- the ratio of the content of the lubricant to the total amount of the lubricant solution is preferably 0.01 to 50% by mass, more preferably 0.05 to 30% by mass, and further preferably 0.1 to 20% by mass.
- the remainder of the lubricant solution excluding the lubricant is the solvent composition.
- compositions such as rust preventive solution, moisture proof coating agent solution, and antifouling coating agent solution (composition for coating film formation)
- the content relative to the total amount is preferably in the same range as the content of the lubricant in the lubricant solution.
- a coating film-forming composition containing the solvent composition and the non-volatile organic compound is applied onto an object to be coated, and the solvent composition is evaporated from the film-forming composition applied onto the object to be coated.
- the coating film which consists of a non-volatile organic compound can be formed on a to-be-coated article.
- Films such as lubricants, rust preventives, moisture-proof coatings, and antifouling coatings are formed. That is, the coating materials to be coated with the coating-forming composition containing these include metals, plastics, and elastomers. Various materials such as glass and ceramics can be applied. Specific articles include the articles described above for each nonvolatile organic compound.
- Examples of the application method of the coating film forming composition include, for example, application by brush, application by spraying, application by immersing an article in the coating film forming composition, sucking up the coating film forming composition, tube or injection
- Examples thereof include a coating method in which the coating film-forming composition is brought into contact with the inner wall of the needle.
- drying method As a method for evaporating the solvent composition from the coating film forming composition, a known drying method may be mentioned. Examples of the drying method include air drying and drying by heating. The drying temperature is preferably 20 to 100 ° C.
- the coating film is formed even in the state of the solvent composition of the present invention before dissolving these lubricant, rust preventive agent, moisture proof coating agent, antifouling coating agent and the like. Even in the state of the composition for use, it can be used with almost no decomposition during storage or use.
- the solvent composition of the present invention can be used as a working medium (heat transfer medium) for a heat cycle system. That is, this invention provides the heat transfer medium containing the solvent composition of this invention.
- the heat transfer medium of the present invention can be applied to a heat cycle system that heats or cools a substance.
- Examples of the heat cycle system include a Rankine cycle system, a heat pump cycle system, a refrigeration cycle system, a heat transport system, a secondary refrigerant cooling system, and the like.
- a refrigeration cycle system will be described as an example of a heat cycle system.
- the refrigeration cycle system is a system that cools the load fluid to a lower temperature by removing the thermal energy from the load fluid in the evaporator.
- a compressor that compresses the working medium vapor A into a high-temperature and high-pressure working medium steam B
- a condenser that cools and compresses the compressed working medium vapor B into a low-temperature and high-pressure working medium C.
- An expansion valve that expands the working medium C discharged from the condenser to form a low-temperature and low-pressure working medium D, and evaporation that heats the working medium D discharged from the expansion valve to form a high-temperature and low-pressure working medium vapor A
- a pump for supplying the load fluid E to the evaporator and a pump for supplying the fluid F to the condenser.
- the heat transfer medium of the present invention may contain components other than the solvent composition of the present invention as long as the effects of the present invention are not impaired, but is preferably composed only of the solvent composition of the present invention.
- Lubricating oil can be added to the heat transfer medium of the present invention.
- the lubricating oil a known lubricating oil used in a heat cycle system is used.
- the lubricating oil include oxygen-containing synthetic oils (such as ester-based lubricating oils and ether-based lubricating oils), fluorine-based lubricating oils, mineral oils, and hydrocarbon-based synthetic oils.
- the heat transfer medium of the present invention can also be applied to a secondary circulation cooling system.
- the secondary circulation cooling system circulates a primary cooling means for cooling a primary refrigerant made of ammonia or a hydrocarbon refrigerant and a secondary refrigerant for a secondary circulation cooling system (hereinafter referred to as “secondary refrigerant”). It is a system having a secondary circulation cooling means for cooling a cooled object, and a heat exchanger for cooling the secondary refrigerant by exchanging heat between the primary refrigerant and the secondary refrigerant. An object to be cooled can be cooled by this secondary circulation cooling system.
- the heat transfer medium of the present invention is suitable for use as a secondary refrigerant.
- Examples 1 to 5, 8 to 12, and 15 to 19 are examples of the solvent composition of the present invention, and Examples 6 to 7, 13 to 14, and 20 to 21 are comparative examples.
- the reactor was heated to 100 ° C., and reactive distillation was performed with a reflux timer at a reflux time / distillation time ratio of 5/1.
- the distilled HCFC-244ca was neutralized with a 20% by mass aqueous potassium hydroxide solution.
- the recovered HCFC-244ca (purity 100%) was 979 g (6.50 mol).
- HCFO-1233yd (Z) having a purity of 100% by mass
- HCFO-1233yd (E) having a purity of 100% by mass
- 140 g of “HCFO-1233yd (E)” was obtained. This test was repeated to produce the required amounts of 1233yd (Z) and 1233yd (E).
- Examples 1 to 5, 8 to 12, 15 to 19 Production of solvent composition (Example)) Using HCFC-244ca, HCFO-1233yd (Z), and HCFO-1233yd (E) obtained above, the HCFO-1233yd (Z) and / or HCFO-1233yd are obtained so as to have the content shown in Table 1. 51 kg each of the solvent compositions of Examples 1 to 5, 8 to 12, and 15 to 19 containing (E) and HCFC-244ca as a stabilizer are prepared.
- the numerical values of HCFO-1233yd (Z) and HCFO-1233yd (E) shown in Table 1 are the ratio of the content of each component to the total of the content of HCFO-1233yd and the content of HCFC-244ca, and HCFC-244ca
- the numerical value of is the ratio of the content of HCFC-244ca to the total amount of the solvent composition.
- the solvent compositions of Examples 1 to 5, 8 to 12, and 15 to 19 are solvent compositions composed only of HCFO-1233yd and HCFC-244ca.
- Examples 6 to 7, 13 to 14, 20 to 21 Production of solvent composition (comparative example)) Using HCFO-1233yd (Z) and HCFO-1233yd (E) obtained above, HCFO-1233yd containing only HCFO-1233yd (Z) and HCFO-1233yd (E) in the ratio shown in Table 1 51 kg of each of the solvent compositions of Examples 6 to 7, 13 to 14, and 20 to 21 are produced.
- PH measurement 40 g of the solvent composition of each example and 40 g of pure water adjusted to pH 7 are placed in a 200 mL separatory funnel and shaken for 1 minute. Thereafter, the upper aqueous layer which has been allowed to stand and separated into two layers is separated, and the pH of the aqueous layer is measured with a pH meter (model number: HM-30R, manufactured by Toa DKK Corporation).
- the change in the metal surface before and after the test is evaluated visually with an untested product of each metal as a comparison target.
- the evaluation criteria are as follows.
- Table 1 shows that the solvent compositions of the examples of the present invention all inhibited acidification as compared with the comparative examples. Moreover, it turns out that the corrosion of the metal test piece was suppressed in the Example compared with the comparative example. Thereby, it is clear that the solvent composition of the present invention not only exhibits an excellent stabilizing effect of the solvent composition but also can suppress metal corrosion.
- the concentrations in the evaluation index are all chloride ion concentrations.
- evaluation index “S (excellent)”: less than 10 mass ppm “A (good)”: 10 mass ppm or more and less than 50 mass ppm “B (somewhat poor)”: 50 mass ppm or more and less than 100 mass ppm “ ⁇ (defect)”: 100 ppm more than
- the obtained lubricant solution is applied in a thickness of 0.4 mm on the surface of an aluminum vapor deposition plate obtained by vapor-depositing aluminum on an iron plate, and air-dried under conditions of 19 to 21 ° C.
- a lubricant coating is formed on the surface.
- Evaluation of the solvent composition of the present invention as a lubricant dilution coating solvent is performed as follows. As a result of the evaluation of each lubricant diluted coating solvent, in Examples 1 to 21, the evaluation is S (excellent).
- a lubricant coating is formed on the surface of the aluminum vapor deposition plate in the same manner as the application of the lubricant solution of the fluorine-based lubricant.
- the evaluation method and the evaluation criteria are the same as the evaluation in the application of the lubricant solution of the fluorine-based lubricant.
- the evaluation is S (excellent).
- the solvent composition of the present invention is excellent in solubility of various organic substances, excellent in cleaning properties, has sufficient drying properties, does not adversely affect the global environment, has excellent stability, and is a metal in the presence of metals. It is a stable solvent composition that suppresses corrosion, and has an adverse effect on articles made of various materials such as metals, plastics, elastomers, and fabrics in a wide range of industrial applications such as cleaning solvents, diluted coating solvents, and propellant compositions. Can be used without giving.
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Abstract
Description
1-クロロ-2,3,3-トリフルオロ-1-プロペンの含有量と1-クロロ-2,2,3,3-テトラフルオロプロパンの含有量の合計に対する1-クロロ-2,2,3,3-テトラフルオロプロパンの含有量の割合が、0.0001~1質量%であることを特徴とする溶剤組成物。
[2]前記溶剤組成物全量に対する1-クロロ-2,3,3-トリフルオロ-1-プロペンの含有量の割合が80質量%以上である、[1]に記載の溶剤組成物。
[3]前記1-クロロ-2,3,3-トリフルオロ-1-プロペンが、(Z)-1-クロロ-2,3,3-トリフルオロ-1-プロペンと(E)-1-クロロ-2,3,3-トリフルオロ-1-プロペンからなり、1-クロロ-2,3,3-トリフルオロ-1-プロペン全量に対する(Z)-1-クロロ-2,3,3-トリフルオロ-1-プロペンの含有量の割合が80~100質量%である、[1]または[2]に記載の溶剤組成物。
[5]前記被洗浄物品に付着した加工油を洗浄する、[4]に記載の洗浄方法。
[6]前記加工油が、切削油、焼き入れ油、圧延油、潤滑油、機械油、プレス加工油、打ち抜き油、引き抜き油、組立油および線引き油からなる群より選ばれる1種以上である、[5]に記載の洗浄方法。
[7]前記被洗浄物品が衣類である、[4]~[6]のいずれかに記載の洗浄方法。
[9][1]~[3]のいずれかに記載の溶剤組成物を含む熱移動媒体。
[10][9]に記載の熱移動媒体を用いた熱サイクルシステム。
本発明の洗浄方法は、地球環境に悪影響を及ぼさず、洗浄性に優れる。
本発明の塗膜の形成方法は、地球環境に悪影響を及ぼさず、均一な塗膜を形成することができる。
本発明の該溶剤組成物を含む熱移動媒体は、地球環境に悪影響を及ぼさず、安定性に優れる。
本発明の該熱移動媒体を用いた熱サイクルシステムは、地球環境に悪影響を及ぼさない。
本発明の溶剤組成物は、1-クロロ-2,3,3-トリフルオロ-1-プロペン(CHCl=CF-CHF2。以下「HCFO-1233yd」と記す。)と、1-クロロ-2,2,3,3-テトラフルオロプロパン(CHF2-CF2-CHFCl。以下「HCFC-244ca」と記す。)を含む溶剤組成物であって、HCFO-1233ydの含有量とHCFC-244caの含有量の合計に対するHCFC-244caの含有量の割合が、0.0001~1質量%である。
HCFO-1233ydは、炭素原子-炭素原子間に二重結合を持つフルオロオレフィンであるため、大気中での寿命が短く、オゾン破壊係数や地球温暖化係数が小さい。
HCFC-244caは、上記のとおりHCFO-1233ydを製造する際の原料として使用される、例えば、後述の方法により工業的に安定的に入手可能な、HCFO-1233ydに可溶な化合物である。HCFC-244caは、HCFCとしての性質を有するとともに、必ずしも明確ではないがラジカルの捕捉と推定される効果により、HCFO-1233yd(Z)およびHCFO-1233yd(E)の分解を抑制し、安定化させる安定剤としての機能を有すると考えられる。
本発明の溶剤組成物は、HCFO-1233ydとHCFC-244caとともに、HCFO-1233ydとHCFC-244caおよび前記したHCFO-1233ydまたは1-クロロ-3,3-ジフルオロ-1-プロピンの製造過程において生成し、HCFO-1233ydまたはHCFC-244caと分離が困難な成分以外の成分(以下、単に「その他の成分」という。)を本発明の効果を損なわない範囲で含有してもよい。その他の成分は、例えば、溶解性を高める、揮発速度を調節する等の各種の目的に応じて用いられるHCFO-1233ydに可溶なHCFO-1233yd以外の溶剤として機能する成分(ただし、HCFC-244caを除く。以下、「その他の溶剤」という。)であってもよい。
本発明の洗浄方法は、上記本発明の溶剤組成物によって被洗浄物品に付着された付着物を洗浄する方法であり、本発明の溶剤組成物と被洗浄物品とを接触させることを特徴とする。
次に、本発明の溶剤組成物を、各種衣類の汚れの除去洗浄に用いる場合について説明する。本発明の溶剤組成物は、衣類の洗浄用溶剤、すなわち、ドライクリーニング用溶剤、として適している。
本発明の溶剤組成物は、不揮発性有機化合物の希釈塗布用の溶剤(希釈塗布溶剤)に使用できる。すなわち本発明の塗膜の形成方法は、上記本発明の溶剤組成物に不揮発性有機化合物を溶解させて塗膜形成用組成物を作製し、該塗膜形成用組成物を被塗布物上に塗布した後、前記溶剤組成物を蒸発させて、前記不揮発性有機化合物からなる塗膜を形成することを特徴とする。
本発明の溶剤組成物は、熱サイクルシステム用の作動媒体(熱移動媒体)として用いることができる。すなわち、本発明は、本発明の溶剤組成物を含む熱移動媒体を提供する。本発明の熱移動媒体は、物質を加熱したり冷却したりする熱サイクルシステムに適用できる。
以下、熱サイクルシステムの一例として、冷凍サイクルシステムについて説明する。
二次循環冷却システムとは、アンモニアや炭化水素冷媒からなる一次冷媒を冷却する一次冷却手段と、二次循環冷却システム用二次冷媒(以下、「二次冷媒」という。)を循環させて被冷却物を冷却する二次循環冷却手段と、一次冷媒と二次冷媒とを熱交換させ、二次冷媒を冷却する熱交換器と、を有するシステムである。この二次循環冷却システムにより、被冷却物を冷却できる。本発明の熱移動媒体は、二次冷媒としての使用に好適である。
撹拌機、ジムロート、冷却器、ラシヒリングを充填したガラス蒸留塔(段数測定値5段)を設置した2リットル四つ口フラスコに2,2,3,3-テトラフルオロプロパノール(TFPO)の1204g(9.12モル)およびN,N-ジメチルホルムアミド(DMF)の12g(0.17モル)を加えた。塩化チオニルの1078g(9.12モル)を滴下し、常温で12時間撹拌した。反応器を100℃に加熱し、還流タイマーにより還流時間/留出時間の比を5/1で反応蒸留を行った。留出したHCFC-244caは20質量%水酸化カリウム水溶液で中和した。回収したHCFC-244ca(純度100%)は、979g(6.50モル)であった。
2000gのHCFC-244caを原料にして、テトラ-n-ブチルアンモニウムクロリドの19.9gを入れ、反応温度を50℃に保ち、40質量%水酸化カリウム水溶液の2792gを30分かけて滴下した。その後、52時間反応を続け、有機層を回収した。回収した有機層を精製した結果、純度100質量%のHCFO-1233yd(Z)(以下、単に「HCFO-1233yd(Z)」という。)を1520g、純度100質量%のHCFO-1233yd(E)(以下、単に「HCFO-1233yd(E)」という。)を140g得た。この試験を繰返し実施し、必要量の1233yd(Z)および1233yd(E)を製造した。
上記で得られた、HCFC-244ca、HCFO-1233yd(Z)およびHCFO-1233yd(E)を用いて、表1に示す含有割合になるように、HCFO-1233yd(Z)および/またはHCFO-1233yd(E)と、安定剤としてのHCFC-244caを含有する例1~5、8~12、15~19の溶剤組成物をそれぞれ51kgずつ調製する。
上記で得られたHCFO-1233yd(Z)およびHCFO-1233yd(E)を用いて、表1に示す割合でHCFO-1233yd(Z)とHCFO-1233yd(E)を含む、HCFO-1233ydのみからなる例6~7、13~14、20~21の溶剤組成物をそれぞれ51kgずつ製造する。
1.安定性試験および金属耐食試験
例1~21の溶剤組成物の100gを、一般用冷間圧延鋼板(SPCC)の試験片を入れた耐熱ガラス瓶に入れ、HCFO-1233yd(Z)の沸点(約54℃)で7日間保存する。調製直後(試験前)と7日間保存後(試験後)のpHの測定結果、および7日間保存後(試験後)のSPCC表面の外観観察の評価結果を表1に示す。
各例の溶剤組成物40gとpH7に調製した40gの純水とを、200mL容分液漏斗に入れ、1分間振盪する。その後、静置して2層分離した上層の水層を分取し、その水層のpHをpHメーター(型番:HM-30R、東亜ディーケーケー株式会社製)で測定する。
「A(良)」:試験前に比べて試験後では光沢が失われたが、実用上は問題ない。
「B(やや不良)」:試験後の表面がわずかに錆びている。
「×(不良)」:試験後の表面の全面に錆びが認められる。
図1と同様の3槽式洗浄装置10の洗浄槽1、リンス槽2、蒸気発生槽3に例1~21の溶剤組成物の50kgを入れて、それぞれ300時間循環運転する。運転開始前(初期)、運転開始後10時間、100時間、300時間後に蒸気発生槽3、洗浄槽1、水分離槽5の溶剤組成物Lを100g採取し、塩素イオン濃度を以下の方法で測定する。結果を表2、3に示す。
採取した溶剤組成物50gを100mLのサンプル瓶に入れた後、50gのイオン交換水を加えて、30秒間手で振り混ぜることにより、溶剤組成物中に含まれる塩素イオンをイオン交換水中に抽出する。静置してイオン交換水を分離後、イオン交換水中に含まれる塩素イオン濃度(ppm)をイオンクロマトグラフィー(ICS-1000、日本ダイオネクス社製)により測定する。
[評価の指標]
「S(優良)」:10質量ppm未満
「A(良)」:10質量ppm以上50質量ppm未満
「B(やや不良)」:50質量ppm以上100質量ppm未満
「×(不良)」:100ppm以上
上記の例1~5、8~12、15~19(実施例)および例6~7、13~14、20~21(比較例)の溶剤組成物をさらに作製し、以下の各洗浄試験を行う。
ステンレス鋼SUS304の試験片(25mm×30mm×2mm)を、切削油である製品名「ダフニーマーグプラスHT-10」(出光興産株式会社製)中に浸漬した後、例1~21の溶剤組成物50mL中に1分間浸漬し、引き上げて切削油が除去された度合を観察する。洗浄性の評価は以下の基準で行う。
「S(優良)」:切削油が完全に除去される。
「A(良好)」:切削油がほぼ除去される。
「B(やや不良)」:切削油が微量に残存する。
「×(不良)」:切削油がかなり残存する。
切削油として製品名「ダフニーマーグプラスAM20」(出光興産株式会社製)を使用する以外は洗浄試験Aと同様に試験し、同じ基準で洗浄性を評価する。
切削油として製品名「ダフニーマーグプラスHM25」(出光興産株式会社製)を使用する以外は洗浄試験Aと同様に試験し、同じ基準で洗浄性を評価する。
切削油として製品名「G-6318FK」(日本工作油株式会社製)を使用する以外は洗浄試験Aと同様に試験し、同じ基準で洗浄性を評価する。
(フッ素系潤滑剤の希釈塗布溶剤としての評価)
上記の例1~5、8~12、15~19(実施例)および例6~7、13~14、20~21(比較例)の溶剤組成物をさらに作製し、各溶剤組成物とフッ素系潤滑剤である製品名「クライトックス(登録商標)GPL102」(デュポン株式会社製、フッ素系オイル)を混合し、該フッ素系潤滑剤の量が溶液全量に対して0.5質量%である潤滑剤溶液を調製する。
[溶解状態]
各例の溶剤組成物を用いた潤滑剤溶液の溶解状態を目視で確認し、以下の基準で評価する。
「S(優良)」:直ちに均一に溶解し、透明になる。
「A(良好)」:振盪すれば均一に溶解し、透明になる。
「B(やや不良)」:若干白濁する。
「×(不良)」:白濁もしくは相分離する。
各例の溶剤組成物を用いた潤滑剤溶液により形成された潤滑剤塗膜の状態を目視で確認して以下の基準で評価する。
「S(優良)」:均一な塗膜である。
「A(良好)」:ほぼ均一な塗膜である。
「B(やや不良)」:塗膜に部分的にムラが見られる。
「×(不良)」:塗膜にかなりムラが見られる。
各例の溶剤組成物を用いた潤滑剤溶液により潤滑剤塗膜が形成される際の潤滑剤溶液の乾燥性を以下の基準で乾燥性を評価する。
「S(優良)」:直ちに溶剤組成物が蒸発する。
「A(良好)」:10分間以内に溶剤組成物が蒸発する。
「B(可)」:10分超1時間以内で溶剤組成物が蒸発する。
「×(不良)」:1時間経過しても溶剤組成物が残存している。
上記の例1~5、8~12、15~19(実施例)および例6~7、13~14、20~21(比較例)の溶剤組成物をさらに作製し、各溶剤組成物とシリコーン系潤滑剤である製品名「信越シリコーンKF-96-50CS」(信越化学工業株式会社製、シリコーンオイル)と混合して、該シリコーン系潤滑剤の量が溶液全量に対して3質量%である潤滑剤溶液を調製する。
Claims (10)
- 1-クロロ-2,3,3-トリフルオロ-1-プロペンと1-クロロ-2,2,3,3-テトラフルオロプロパンを含む溶剤組成物であって、
1-クロロ-2,3,3-トリフルオロ-1-プロペンの含有量と1-クロロ-2,2,3,3-テトラフルオロプロパンの含有量の合計に対する1-クロロ-2,2,3,3-テトラフルオロプロパンの含有量の割合が、0.0001~1質量%であることを特徴とする溶剤組成物。 - 前記溶剤組成物全量に対する1-クロロ-2,3,3-トリフルオロ-1-プロペンの含有量の割合が80質量%以上である、請求項1に記載の溶剤組成物。
- 前記1-クロロ-2,3,3-トリフルオロ-1-プロペンが、(Z)-1-クロロ-2,3,3-トリフルオロ-1-プロペンと(E)-1-クロロ-2,3,3-トリフルオロ-1-プロペンからなり、1-クロロ-2,3,3-トリフルオロ-1-プロペン全量に対する(Z)-1-クロロ-2,3,3-トリフルオロ-1-プロペンの含有量の割合が80~100質量%である、請求項1または2に記載の溶剤組成物。
- 請求項1~3のいずれか一項に記載の溶剤組成物と被洗浄物品とを接触させることを特徴とする洗浄方法。
- 前記被洗浄物品に付着した加工油を洗浄する、請求項4に記載の洗浄方法。
- 前記加工油が、切削油、焼き入れ油、圧延油、潤滑油、機械油、プレス加工油、打ち抜き油、引き抜き油、組立油および線引き油からなる群より選ばれる1種以上である、請求項5に記載の洗浄方法。
- 前記被洗浄物品が衣類である、請求項4~6のいずれか一項に記載の洗浄方法。
- 請求項1~3のいずれか一項に記載の溶剤組成物に不揮発性有機化合物を溶解させて塗膜形成用組成物を調製し、該塗膜形成用組成物を被塗布物上に塗布した後、前記溶剤組成物を蒸発させて、前記不揮発性有機化合物からなる塗膜を形成することを特徴とする、塗膜の形成方法。
- 請求項1~3のいずれか一項に記載の溶剤組成物を含む熱移動媒体。
- 請求項9に記載の熱移動媒体を用いた熱サイクルシステム。
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US11440862B2 (en) | 2015-07-27 | 2022-09-13 | AGC Inc. | Solvent composition, cleaning method, method of forming a coating film, heat transfer fluid, and heat cycle system |
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