WO2016075791A1 - 半導体装置およびその製造方法 - Google Patents

半導体装置およびその製造方法 Download PDF

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Publication number
WO2016075791A1
WO2016075791A1 PCT/JP2014/080072 JP2014080072W WO2016075791A1 WO 2016075791 A1 WO2016075791 A1 WO 2016075791A1 JP 2014080072 W JP2014080072 W JP 2014080072W WO 2016075791 A1 WO2016075791 A1 WO 2016075791A1
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WIPO (PCT)
Prior art keywords
film
rewiring
metal film
cap
semiconductor device
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PCT/JP2014/080072
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English (en)
French (fr)
Inventor
和義 前川
河野 祐一
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ルネサスエレクトロニクス株式会社
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Application filed by ルネサスエレクトロニクス株式会社 filed Critical ルネサスエレクトロニクス株式会社
Priority to EP14890461.8A priority Critical patent/EP3220410A4/en
Priority to JP2015545230A priority patent/JPWO2016075791A1/ja
Priority to PCT/JP2014/080072 priority patent/WO2016075791A1/ja
Priority to CN201480027415.6A priority patent/CN105793964A/zh
Priority to US14/891,319 priority patent/US10083924B2/en
Priority to TW104135663A priority patent/TW201630075A/zh
Publication of WO2016075791A1 publication Critical patent/WO2016075791A1/ja

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Definitions

  • the present invention relates to a semiconductor device and a manufacturing method thereof, and more particularly to a semiconductor device having a rewiring composed of a metal film on a plurality of wiring layers formed on a main surface of a semiconductor substrate and a manufacturing method thereof. It is related to effective technology.
  • a multilayer wiring is formed of a metal film mainly composed of Cu (copper) or Al (aluminum) on a semiconductor substrate on which semiconductor elements such as CMIS (Complementary Metal Insulator Semiconductor) transistors are formed.
  • a final passivation film is formed on the multilayer wiring.
  • Patent Document 1 a rewiring mainly composed of Cu is formed on a final passivation film, and an electrode pad and a rewiring formed on the uppermost wiring under the final passivation film, A technique for electrically connecting the two is disclosed.
  • a wire 20 is connected to a pad 18 formed so as to partially cover the upper and side surfaces of the rewiring 15 containing Cu as a main component.
  • Patent Document 2 Japanese Patent Laying-Open No. 2012-4210
  • Patent Document 3 a barrier metal having a protruding portion 9 in which a rewiring layer 6 made of an aluminum alloy formed on a passivation film 4 is extended on the passivation film 6. It is disclosed that migration and corrosion of the rewiring layer 6 are suppressed by completely covering with the film 8.
  • a semiconductor device having a rewiring (semiconductor integrated circuit device) studied by the inventors of the present application includes a semiconductor chip, a wire connected to the semiconductor chip, and a sealing body that seals the semiconductor chip and the wire.
  • the semiconductor chip includes a semiconductor element, a rewiring mainly composed of Cu electrically connected to the semiconductor element, and a wiring formed of a multilayer wiring layer that electrically connects the semiconductor element and the rewiring.
  • the rewiring is connected to a pad electrode that is a part of the wiring formed by the uppermost wiring layer of the multilayer wiring layer.
  • the rewiring is electrically connected to the pad electrode through the opening of the surface protective film and the first organic protective film provided to expose the pad electrode.
  • the upper surface and the side surface of the rewiring are covered with the second organic protective film, and the second organic protective film has an opening exposing the external pad electrode formed on the upper surface of the rewiring. The wire is connected to the rewiring.
  • a plurality of rewirings are formed on the semiconductor chip, the minimum linewidth of rewiring is 12 ⁇ m, and the minimum interval between adjacent rewirings is 15 ⁇ m.
  • a seed layer made of a metal film (for example, a Cr film) for forming the rewiring is provided on the lower surface of the rewiring, but the upper surface and the side surface of the rewiring are in contact with the second organic protective film. .
  • HAST Highly Accelerated temperature and humidity Stress Test
  • the first and second organic protective films covering the rewiring made of Cu are made of a polyimide film and contain moisture and halogen ions.
  • Cu ions ionized Cu
  • the minimum interval (15 ⁇ m) between adjacent rewirings is large, there is a region where a high voltage is applied and a high electric field is applied between adjacent rewirings, and Cu dendritic precipitation occurs in this region. It turns out that it has occurred.
  • An object of the present invention is to provide a technique capable of improving reliability in a semiconductor device having rewiring.
  • a semiconductor device includes a pad electrode formed in an uppermost layer of a plurality of wiring layers, a protective film having an opening on the pad electrode, a base metal film formed on the protective film, and a base metal A rewiring formed on the film; and a cap metal film formed to cover an upper surface and a side surface of the rewiring. Then, in the region outside the rewiring, between the cap metal film and the protective film formed on the side wall of the rewiring, a base metal film different from the rewiring and a different material from the rewiring are used. A cap metal film is formed, and the base metal film and the cap metal film are in direct contact with each other in a region outside the rewiring.
  • the reliability of a semiconductor device having rewiring can be improved.
  • FIG. 1 is a circuit block diagram of a semiconductor device according to a first embodiment of the present invention.
  • 1 is an overall plan view of a semiconductor chip on which a semiconductor device according to a first embodiment of the present invention is formed. It is a top view which expands and shows a part of FIG.
  • FIG. 4 is a cross-sectional view taken along line AA in FIG. 3.
  • FIG. 6 is a cross-sectional view of the semiconductor device of First Embodiment during a manufacturing step thereof.
  • FIG. 6 is a cross-sectional view of the semiconductor device during a manufacturing step following that of FIG. 5;
  • FIG. 7 is a cross-sectional view of the semiconductor device during a manufacturing step following that of FIG. 6;
  • FIG. 8 is a cross-sectional view of the semiconductor device during a manufacturing step following that of FIG. 7;
  • FIG. 9 is a cross-sectional view of the semiconductor device during a manufacturing step following that of FIG. 8;
  • FIG. 10 is a cross-sectional view of the semiconductor device during a manufacturing step following that of FIG. 9;
  • FIG. 11 is a cross-sectional view of the semiconductor device during a manufacturing step following that of FIG. 10;
  • FIG. 12 is a cross-sectional view of the semiconductor device during a manufacturing step following that of FIG. 11;
  • FIG. 13 is a cross-sectional view of the semiconductor device during a manufacturing step following that of FIG. 12;
  • 11 is a cross-sectional view of the semiconductor device that is Modification 1 during the manufacturing process.
  • FIG. 10 is a cross-sectional view of the semiconductor device during a manufacturing step following that of FIG. 9;
  • FIG. 11 is a cross-sectional view of the semiconductor device during a manufacturing step following that of FIG. 10
  • FIG. 11 is a cross-sectional view of a semiconductor device that is a second modification during the manufacturing process.
  • FIG. FIG. 11 is a cross-sectional view of the semiconductor device that is Modification Example 3 during the manufacturing process.
  • FIG. 11 is a cross-sectional view of the semiconductor device that is Modification Example 4 during the manufacturing process. It is sectional drawing in the manufacturing process of the semiconductor device which is a comparative example.
  • FIG. 19 is a cross-sectional view of the semiconductor device as the comparative example following FIG. 18 during the manufacturing process thereof.
  • FIG. 10 is a sectional view of the semiconductor device of Second Embodiment during the manufacturing process thereof.
  • FIG. 21 is a cross-sectional view of the semiconductor device during a manufacturing step following that of FIG. 20;
  • FIG. 16 is a cross-sectional view of the semiconductor device that is Modification Example 5 during the manufacturing process.
  • the constituent elements are not necessarily indispensable unless otherwise specified or apparently indispensable in principle.
  • the shapes when referring to the shapes, positional relationships, etc. of the components, etc., the shapes are substantially the same unless otherwise specified, or otherwise apparent in principle. And the like are included. The same applies to the above numbers and the like (including the number, numerical value, quantity, range, etc.).
  • hatching may be omitted even in a cross-sectional view for easy understanding of the drawings. Further, even a plan view may be hatched to make the drawing easy to see.
  • the semiconductor device semiconductor integrated circuit device
  • the semiconductor device includes, for example, a plurality of semiconductor elements, a plurality of layers of wiring (multilayer wiring) formed above the plurality of semiconductor elements, and a plurality of semiconductor elements.
  • FIG. 1 is a circuit block diagram of a semiconductor device.
  • the semiconductor device includes, for example, an input / output (I / O) circuit, an analog circuit, a CMIS-logic circuit, a power MIS circuit, and a memory circuit formed on the device surface of the semiconductor chip 1A. Configure the device.
  • the CMIS-logic circuit is composed of, for example, a CMIS transistor having an operating voltage of 1 to 3 V, and the I / O circuit and the memory circuit are, for example, operated voltages of 1 to 3 V and 5 It is composed of ⁇ 8V CMIS transistors.
  • the CMIS transistor having an operating voltage of 1 to 3 V includes a first n-channel MISFET (Metal Insulator Semiconductor Field Effect Transistor) having a first gate insulating film and a first p-channel type having a first gate insulating film. It consists of MISFET.
  • the CMIS transistor having an operating voltage of 5 to 8 V is composed of a second n-channel MISFET having a second gate insulating film and a second p-channel MISFET having a second gate insulating film. Is done.
  • the film thickness of the second gate insulating film is configured to be larger than the film thickness of the first gate insulating film.
  • the MISFET is referred to as a MIS transistor.
  • the analog circuit is composed of, for example, a CMIS transistor (or bipolar transistor) having an operating voltage of 5 to 8 V, a resistor element, and a capacitor element
  • the power MIS circuit is a CMIS transistor having an operating voltage of 5 to 8 V, for example. It is composed of a high voltage MIS transistor (high voltage element) having an operating voltage of 20V to 100V.
  • the high-breakdown-voltage MIS transistor includes, for example, a third n-channel MISFET having a third gate insulating film, a third p-channel MISFET having a third gate insulating film, or both.
  • a voltage of 20 V to 100 V is applied between the gate electrode and the drain region or between the gate electrode and the source region, the thickness of the third gate insulating film is the thickness of the second gate insulating film. It is configured to be thicker.
  • FIG. 2 is an overall plan view showing an example of the semiconductor chip 1A
  • FIG. 3 is an enlarged plan view of a region surrounded by a broken line X in FIG. 2
  • FIG. 4 is a cross-sectional view taken along line AA in FIG. It is.
  • FIG. 2 shows an example of the layout of the redistribution lines RM, RMV, and RMS formed on the device surface of the semiconductor chip 1A.
  • the redistribution lines RM, RMV, and RMS have a film thickness and a thickness that are larger than those of a plurality of layers of the semiconductor chip 1A (the first layer Al wiring 5, the second layer Al wiring 7, and the third layer Al wiring 9 shown in FIG. 4). Since both the wiring widths are large, the impedance is very low compared to a multi-layer wiring.
  • the rewiring RM, RMV, and RMS are used as, for example, a rewiring RM for signal input / output, a rewiring RMV for supplying power (Vcc, GND), and a rewiring RMS for connection between internal circuits.
  • a plurality of rewiring RMs constituting external connection terminals of the semiconductor device are arranged in the periphery of the semiconductor chip 1A.
  • An external pad electrode 18 is formed at one end of each rewiring RM constituting the external connection terminal of the semiconductor device, and the other end is a pad formed in the uppermost layer wiring as shown in FIGS. It is connected to the electrode 9a.
  • the external pad electrodes 18 are not particularly limited, but are arranged in a line along each side of the semiconductor chip 1A. Needless to say, the external pad electrodes 18 may be arranged in a zigzag manner or in three or more rows along each side of the semiconductor chip 1A. That is, the rewiring RM is, for example, a signal input / output rewiring configuring the input / output (I / O) circuit of FIG.
  • the rewiring RMV shown in FIG. 2 is a rewiring for supplying power (Vcc, GND).
  • An external pad electrode 18 is formed at one end of the rewiring RMV, and the other end is connected to a pad electrode 9a formed in the power supply wiring in the semiconductor chip 1A. Therefore, the power supply (from the outside of the semiconductor chip 1A ( Vcc, GND) voltage can be supplied to the plurality of power supply wirings in the semiconductor chip 1A with low impedance.
  • the rewiring RMS shown in FIG. 2 is used as a wiring for connecting between circuits or elements formed in the semiconductor chip 1A. Therefore, the external pad electrode 18 is not formed on the rewiring RMS. Both ends of the rewiring RMS are connected to pad electrodes 9a formed on the wiring.
  • FIG. 3 is an enlarged plan view of two adjacent signal input / output rewiring RMs. Since two adjacent rewirings RM have the same planar shape, the rewiring RM located in the upper part of the drawing will be described as an example.
  • the rewiring RM extends in the X direction on the paper surface, and is electrically connected at one end to the pad electrode 9a of the wiring 9 extending in the X direction on the paper surface.
  • An external pad electrode 18 is formed at the other end of the rewiring RM.
  • the rewiring RM has a first plane pattern P1, and the base metal film UM and the cap metal film CM have a second plane pattern P2.
  • the first plane pattern P1 and the second plane pattern P2 are similar, and the second plane pattern P2 has a shape obtained by enlarging the first plane pattern P1.
  • An overhang PP formed of the base metal film UM and the cap metal film CM is disposed around the entire rewiring RM. That is, when the first plane pattern P1 is enlarged by the width S3 of the projecting portion PP, the second plane pattern P2 is obtained.
  • the minimum wiring width L of the rewiring RM is, for example, 12 ⁇ m, the minimum wiring interval S1 between adjacent rewiring RMs is 15 ⁇ m, the minimum spacing S2 between adjacent protruding portions PP is 10 ⁇ m, and the protruding amount S3 of the protruding portions PP. Is 2.5 ⁇ m.
  • the overhang amount S3 of the overhang portion PP is the same over the entire periphery of the rewiring RM, but the second plane pattern P2 is shifted from the first plane pattern P1, for example, by ⁇ in the X direction. Also good.
  • the second plane pattern P2 is shifted by ⁇ in the X direction with respect to the first plane pattern P1
  • a p-type well 2P, an n-type well 2N, and an element isolation trench 3 are formed in a semiconductor substrate 1P made of p-type single crystal silicon.
  • a semiconductor substrate 1P made of p-type single crystal silicon.
  • an element isolation insulating film 3a made of a silicon oxide film is buried.
  • An n-channel MIS transistor (Qn) is formed in the p-type well 2P.
  • the n-channel MIS transistor (Qn) is formed in the active region defined by the element isolation trench 3, and has a source region ns and a drain region nd formed in the p-type well 2P and a gate insulation on the p-type well 2P. And a gate electrode ng formed through the film ni.
  • a p-channel MIS transistor (Qp) is formed in the n-type well 2N, and a gate is formed on the source region ps and drain region pd and a gate insulating film pi on the n-type well 2N.
  • an electrode pg is formed in the p-type well 2P.
  • a wiring made of a metal film for connecting the semiconductor elements is formed above the n-channel MIS transistor (Qn) and the p-channel MIS transistor (Qn).
  • Wirings connecting semiconductor elements generally have a multilayer wiring structure of about 3 to 10 layers, but FIG. 4 is composed of a metal film mainly composed of an Al alloy as an example of the multilayer wiring. Three wiring layers (first layer Al wiring 5, second layer Al wiring 7, and third layer Al wiring 9) are shown.
  • the wiring layer is used to collectively represent a plurality of wirings formed in each wiring layer.
  • the second wiring layer is thicker than the first wiring layer, and the third wiring layer is thicker than the second wiring layer.
  • inter-layer insulating films 4, 6, and 8 made of silicon oxide films and plugs p1, p2, and p3 that electrically connect the three layers of wiring, respectively. Is formed.
  • the interlayer insulating film 4 is formed on the semiconductor substrate 1P so as to cover the semiconductor element, for example, and the first layer Al wiring 5 is formed on the interlayer insulating film 4.
  • the first layer Al wiring 5 is electrically connected to the source region ns, the drain region nd, and the gate electrode ng of the n-channel MIS transistor (Qn), which is a semiconductor element, via a plug p1 formed in the interlayer insulating film 4, for example.
  • the first-layer Al wiring 5 is electrically connected to the source region ps, drain region pd, and gate electrode pg of the p-channel type MIS transistor (Qp), which is a semiconductor element, via a plug p1 formed in the interlayer insulating film 4. Connected to.
  • the connection between the gate electrodes ng and pg and the first layer Al wiring 5 is not shown.
  • the second layer Al wiring 7 is electrically connected to the first layer Al wiring 5 via a plug p2 formed in the interlayer insulating film 6, for example.
  • the third layer Al wiring 9 is electrically connected to the second layer Al wiring 7 via a plug p3 formed in the interlayer insulating film 8, for example.
  • the plugs p1, p2, and p3 are made of a metal film, for example, a W (tungsten) film.
  • a multilayer wiring (three-layer wiring) is formed of a metal film mainly composed of Cu by a chemical mechanical polishing method (CMP method)
  • the wiring may be formed by a dual damascene method in which a wiring and a plug are integrally formed.
  • the interlayer insulating films 4, 6, and 8 are made of a silicon oxide film (SiO 2 ), and include a silicon oxide film containing carbon (SiOC film), a silicon oxide film containing nitrogen and carbon (SiCON film), and fluorine. Of course, it may be composed of a single layer film or a laminated film of a silicon oxide film (SiOF film).
  • the third layer Al wiring 9 which is the uppermost wiring layer of the multilayer wiring, as a final passivation film, for example, a single layer film such as a silicon oxide film or a silicon nitride film, or a surface composed of these two layer films
  • a protective film (protective film, insulating film) 10 is formed.
  • the third layer Al wiring 9 is not limited to the pad electrode 9a, and may be, for example, a wiring integrally formed with the pad electrode 9a, a wiring not connected to the pad electrode 9a, or the like.
  • the wiring that is not connected to the pad electrode 9a is used as a wiring that electrically connects between semiconductor elements or circuits and constitutes a semiconductor integrated circuit.
  • a base insulating film (organic protective film, insulating film) 11 which is an insulating film having an opening 11a above the pad opening 10a is formed. Further, a rewiring RM electrically connected to the pad electrode 9 a through the opening 11 a of the base insulating film 11 and the pad opening 10 a of the surface protective film 10 is formed on the base insulating film 11.
  • the opening 11a is larger than the pad opening 10a, and the upper surface (surface) of the surface protection film 10 that defines the pad opening 10a is exposed from the opening 11a on the entire circumference of the pad opening 10a.
  • the rewiring RM is formed inside the pad opening 10a and the opening 11a so as to completely fill the pad opening 10a and the opening 11a, and further extends on the base insulating film 11.
  • the base metal film UM is interposed between the pad electrode 9a and the rewiring RM.
  • the base metal film UM is in contact with and electrically connected to the pad electrode 9 a, and the side surface (side wall) and the top surface of the surface protective film 10 in the pad opening 10 a of the surface protective film 10 and the opening 11 a of the base insulating film 11. , And along the side surface (side wall) of the base insulating film 11, and further extends to the upper surface of the base insulating film 11.
  • the base metal film UM has an upper surface and a lower surface, the upper surface is in contact with the rewiring RM, and the lower surface is in contact with the pad electrode 9a, the surface protective film 10, and the base insulating film 11.
  • the base metal film UM is composed of a base barrier film having a three-layer structure. From the first base barrier film UM1, the second base barrier film UM2, and the third base barrier film UM3 from the pad electrode 9a side. Become. Therefore, the upper surface of the base metal film UM means the upper surface of the third base barrier film UM3, and the lower surface means the lower surface of the first base barrier film UM1.
  • the first base barrier film UM1, the second base barrier film UM2, and the third base barrier film UM3 are composed of, for example, a titanium (Ti) film, a titanium nitride (TiN) film, and a titanium (Ti) film in this order.
  • the film thickness is 10 nm, 50 nm, and 10 nm in this order. This film thickness is the film thickness on the upper surface of the base insulating film 11.
  • the rewiring RM has an upper surface, a lower surface, and side surfaces, and the lower surface of the rewiring RM is in contact with the upper surface of the base metal film UM.
  • the rewiring RM is a copper film containing copper (Cu) as a main component, and has a laminated structure of a seed film RM1 and a plating film RM2. Therefore, the lower surface of the rewiring RM means the lower surface of the seed film RM1, and the upper surface means the upper surface of the plating film RM2. Further, the side surface (side wall) of the rewiring RM means the side surface (side wall) of the stacked structure of the seed film RM1 and the plating film RM2.
  • the film thicknesses of the seed film RM1 and the plating film RM2 are 250 nm and 6 ⁇ m, respectively.
  • the rewiring RM is a film more than 10 times as thick as the third layer Al wiring 9, in other words, the wiring 9 on which the pad electrode 9a is formed.
  • This is a low-resistance wiring having a thickness. That is, the film thickness of the rewiring RM is larger than the film thickness of the wiring 9 on which the pad electrode 9a is formed. Desirably, the film thickness of the rewiring RM is not less than 10 times the film thickness of the wiring 9 on which the pad electrode 9a is formed.
  • the cap metal film CM is formed in contact with the upper surface and the side surface of the rewiring RM so as to completely cover the rewiring RM.
  • the cap metal film CM covers the entire upper surface and the entire side surface of the rewiring RM.
  • the cap metal film CM completely covers the side surface (side wall) of the seed film RM1 and the side surface (side wall) of the plating film RM2 constituting the rewiring RM.
  • the cap metal film CM has an upper surface and a lower surface, and the lower surface is in contact with the upper surface of the rewiring RM and the side surface of the rewiring RM, and in a region outside the rewiring RM (a region where the rewiring RM is not formed). In direct contact with the upper surface of the underlying metal film UM.
  • the base metal film UM and the cap metal film CM extend from the side surface of the rewiring RM (strictly, the lower end portion of the side surface of the rewiring RM) to the region outside the rewiring RM (region where the rewiring RM is not formed).
  • An overhang portion PP is provided, and the upper surface of the base metal film UM and the lower surface of the cap metal film CM are in direct contact with each other in the overhang portion PP.
  • the overhang amount S3 of the overhang portion PP is larger than the film thickness of the cap metal film CM formed on the side surface (side wall) of the rewiring RM, for example, 2.5 ⁇ m.
  • the ends of the base metal film UM and the cap metal film CM which are the tips of the overhanging portions PP, are formed on the rewiring RM more than the cap metal film CM formed on the side surface (side wall) of the rewiring RM.
  • the overhang portion PP is formed over the entire circumference of the rewiring RM in plan view.
  • the overhang amount S3 is the width of the overhang portion PP and means the distance from the end of the rewiring RM to the end of the base metal film UM or the cap metal film CM in the region outside the rewiring RM.
  • the cap metal film CM has a laminated structure of the first cap barrier film CM1 and the second cap barrier film CM2, and the lower surface of the first cap barrier film CM1 is in contact with the upper surface and the side surface of the rewiring RM. Further, it is in contact with the upper surface of the base metal film UM (more precisely, the upper surface of the third base barrier film UM3).
  • the lower surface of the cap metal film CM means the lower surface of the first cap barrier film CM1, and the upper surface means the upper surface of the second cap barrier film CM2.
  • the first cap barrier film CM1 is made of a titanium (Ti) film and has a film thickness of 50 nm.
  • the second cap barrier film CM2 is made of a palladium (Pd) film, and the film thickness thereof is 175 nm. This film thickness is the film thickness on the upper surface of the rewiring RM.
  • the third base barrier film UM3 constituting the base metal film UM and the first cap barrier film CM1 constituting the cap metal film CM are made of a film made of the same material (specifically, a titanium (Ti) film).
  • Ti titanium
  • the overhang portion PP has a structure in which the cap metal film CM is laminated on the base metal film UM, the film thickness of the base metal film UM and the cap metal in the overhang portion PP in the region outside the rewiring RM.
  • the sum of the film CM and the film thickness is larger than the film thickness of the base metal film UM sandwiched between the rewiring RM and the base insulating film 11.
  • the sum of the film thickness of the base metal film UM and the film thickness of the first cap barrier film CM1 in the overhanging portion PP in the region outside the rewiring RM is the base between the rewiring RM and the base insulating film 11 It is thicker than the film thickness of the metal film UM.
  • a protective film 12 is formed so as to entirely cover the rewiring RM.
  • the protective film 12 has an opening 12a that partially exposes the upper surface of the rewiring RM (more precisely, the upper surface of the cap metal film CM and the upper surface of the second cap barrier film CM2).
  • the portion is an external pad electrode 18.
  • both the base insulating film 11 and the protective film 12 can be made of an organic film such as a polyimide resin, a benzocyclobutene resin, an acrylic resin, an epoxy resin, or a silicon resin.
  • the base metal film UM and the cap metal film CM prevent the copper (Cu) film constituting the rewiring RM from moving (diffusing) to the outside as copper ions. What is the rewiring RM? It is composed of different materials (different materials). Further, the base metal film UM and the cap metal film CM do not include a copper (Cu) film.
  • the signal input / output rewiring RM has been described as an example, but the power supply rewiring RMV and the rewiring RMS for connecting between circuits or elements have the same structure as the rewiring RM.
  • the power supply rewiring RMV and the rewiring RMS for connecting between circuits or elements have the same structure as the rewiring RM.
  • the rewiring RM made of a copper film covers the lower surface of the rewiring RM, covers the base metal film UM made of a material different from the rewiring RM, and covers the upper surface and side surfaces of the rewiring RM and is made of a material different from the rewiring RM. It is completely surrounded by the cap metal film CM. In the region outside the rewiring RM, the base metal film UM and the cap metal film CM have an overhang portion PP, and the base metal film UM and the cap metal film CM are in direct contact with each other in the overhang portion PP. ing.
  • the copper constituting the redistribution line RM moves (diffuses) to an area outside the redistribution line RM and is adjacent to each other. It is possible to prevent a breakdown voltage deterioration or a short circuit between the rewiring RMs. Further, since moisture, halogen ions, etc. contained in the polyimide film constituting the base insulating film 11 or the protective film 12 can be prevented from entering the rewiring RM made of the copper film, oxidation of the copper film can be prevented, It is possible to prevent a breakdown voltage deterioration or a short circuit between adjacent rewirings RM.
  • the protruding amount of the protruding portion is larger than the film thickness of the cap metal film CM covering the side surface of the rewiring RM. Even when the overhang amount is reduced due to the deviation of the second pattern with respect to the first pattern, since the reduced overhang amount is larger than the film thickness of the cap metal film CM covering the side surface of the rewiring RM, there is a manufacturing variation. Even in this case, it is possible to prevent a breakdown voltage deterioration or a short circuit between adjacent rewirings RM. Oxidation of the copper film constituting the rewiring RM can be prevented.
  • the base barrier film that is the upper surface of the base metal film UM and the cap barrier film that is the lower surface of the cap metal film are films made of the same material. Therefore, the adhesion between the base metal film UM and the cap metal film CM in the overhanging portion can be improved, and the copper constituting the rewiring RM can be sufficiently prevented from moving (diffusing) to the region outside the rewiring RM. Therefore, it is possible to prevent a breakdown voltage deterioration or short circuit between adjacent rewiring RMs and oxidation of the rewiring RMs.
  • the overhang portion PP is formed over the entire circumference of the rewiring RM, it is possible to prevent breakdown voltage deterioration or short circuit between the rewiring RM adjacent in all directions and oxidation of the rewiring. it can.
  • the rewiring RM is completely wrapped by the base metal film UM having the second planar pattern P2 larger than the first planar pattern P1 of the rewiring RM made of a copper film and the cap metal film CM, and the rewiring RM In the outer region, the upper surface of the base metal film UM and the lower surface of the cap metal film CM are in direct contact.
  • the rewiring RM can be prevented from being oxidized, and a breakdown voltage deterioration or a short circuit between the adjacent rewirings RM can be prevented.
  • the copper film constituting the rewiring RM is oxidized and copper ions are generated, the copper ions can be prevented from moving (diffusing) outside the rewiring RM.
  • the second plane pattern P2 is larger than the first plane pattern P1 on the entire circumference of the first plane pattern P1, it is possible to prevent breakdown voltage deterioration or short circuit between the rewiring RMs adjacent in all directions. it can.
  • Method for Manufacturing Semiconductor Device Next, a method for manufacturing the semiconductor device according to the first embodiment will be described. The method for manufacturing a rewiring, which is a feature of the first embodiment, will be mainly described. The rewiring manufacturing method corresponds to the cross section shown in FIG.
  • 5 to 13 are cross-sectional views of the semiconductor device according to the first embodiment during the manufacturing process.
  • FIG. 5 shows a process of preparing a semiconductor substrate on which a plurality of wiring layers and pad electrodes are formed.
  • the semiconductor substrate 1P After the p-channel type MIS transistor (Qp) and the n-channel type MIS transistor (Qn) are formed, wiring composed of a plurality of wiring layers is formed. Specifically, as described with reference to FIG. 4, three wiring layers (first layer Al wiring 5, second layer Al wiring 7, and third layer Al wiring 9) are formed.
  • a surface protective film 10 is formed above the third layer Al wiring 9, and the surface protective film 10 has a pad opening 10a and is a third layer Al that is the uppermost wiring layer. A portion of the wiring 9 exposed from the pad opening 10a is a pad electrode 9a.
  • the cross-sectional structure shown in FIG. 5 is as described in FIG.
  • FIG. 6 shows a process of forming the base insulating film 11, the base metal film UM, and the seed film RM1.
  • a base insulating film 11 is formed on the surface protective film 10, and a photosensitive polyimide resin is used as the base insulating film 11.
  • Photosensitive polyimide is applied onto the surface protective film 10 and exposed to expose the pad openings 10a and the pad electrodes 9a, and then cured and cured. That is, the base insulating film 11 having the opening 11a larger than the pad opening 10a and the pad electrode 9a is formed.
  • a base metal film UM and a seed film RM1 that are electrically connected to the pad electrode 9a through the opening 11a and the pad opening 10a are formed (deposited).
  • the first base barrier film UM1, the second base barrier film UM2, and the third base barrier film UM3 constituting the base metal film UM are sequentially formed of a titanium (Ti) film of 5 to 50 nm and a titanium nitride (TiN) film of 10 to It is appropriate to form a 100 nm titanium (Ti) film with a thickness of 5 to 50 nm.
  • the titanium (Ti) film is 10 nm
  • the titanium nitride (TiN) film is 50 nm
  • the titanium (Ti) film is 10 nm.
  • the first base barrier film UM1, the second base barrier film UM2, and the third base barrier film UM3 are formed by, for example, a sputtering method.
  • a seed film RM1 made of a copper (Cu) film is formed on the third base barrier film UM3 by sputtering.
  • the seed film RM1 has a thickness of about 250 nm.
  • FIG. 7 shows the plating process of the rewiring RM formation process.
  • a resist mask (resist pattern) PR1 is formed to expose a region where the rewiring RM is formed and cover a region where the rewiring RM is not formed. That is, the resist mask PR1 is an inverted pattern of the first plane pattern P1, and has an opening corresponding to the first plane pattern P1.
  • the plating film RM2 made of a copper (Cu) film is selectively formed on the seed film RM1 in the region exposed from the resist mask PR1 by electrolytic (electric) plating using the base metal film UM and the seed film RM1 as seed layers. To form.
  • the thickness of the plating film RM2 is about 6 ⁇ m, for example.
  • the film thickness of the plating film RM2 is preferably in the range of 2 ⁇ m to 10 ⁇ m. If the film thickness of the plating film RM2 is too thin, the resistance of the rewiring RM increases, so that a resistance value that satisfies the requirements of the device can be obtained. It should be a film thickness, and a certain film thickness is generally required. However, if the thickness is too large, the warpage of the wafer becomes large, a transport error occurs in the subsequent lithography and processing apparatus, the processing becomes difficult, and the manufacturing cost increases and the productivity decreases. For example, the base metal film UM and the like are given the same reference numerals before and after patterning. In this step, the plating film RM2 having the first planar pattern P1 is formed.
  • FIG. 8 shows a removal (processing) process of the seed film RM1 which is a process of forming the rewiring RM.
  • the resist mask PR1 is removed.
  • the seed film RM1 in a region exposed from the plating film RM2 is removed, so that a patterned seed film RM1 having a planar pattern equal to the plating film RM2 remains under the plating film RM2.
  • a rewiring RM having the first planar pattern P1 and having a stacked structure of the seed film RM1 and the plating film RM2 is formed.
  • the base metal film UM in the region exposed from the plating film RM2 is important to leave the base metal film UM in the region exposed from the plating film RM2 (in other words, the region outside the rewiring RM) without being removed.
  • the base metal film UM remains in the region exposed from the plating film RM2.
  • the base metal film UM in the region exposed from the plating film RM2 is removed by etching by about half the film thickness. You may do it. That is, the thickness of the base metal film UM in the region exposed from the plating film RM2 may be about half the thickness of the base metal film UM in the region covered with the plating film RM2.
  • the etching is dry etching containing a chlorine-based gas using the plating film RM2 or the seed film RM1 as a heart mask.
  • FIG. 9 shows a part of the process of forming the cap metal film CM.
  • a cap metal film CM is formed (deposited) so as to completely cover the upper surface and side surfaces of the rewiring RM.
  • the cap metal film CM before patterning is called a cap metal material film.
  • the cap metal film CM is composed of a plurality of cap barrier films.
  • the first cap barrier film (first cap metal material film) CM1 the second cap barrier film (second cap metal material film) CM2, and the third cap barrier film (third cap metal film).
  • Material film) CM3 is formed sequentially.
  • the third cap barrier film CM3 is also handled as a part of the cap metal film CM.
  • the first cap barrier film CM1, the second cap barrier film CM2, and the third cap barrier film CM3 have a titanium (Ti) film of 10 to 200 nm, a palladium (Pd) film of 10 to 200 nm, and a titanium (Ti) film of 10 to 200 nm. It is appropriate to form the film with a thickness of 200 nm.
  • the lower titanium (Ti) film is 10 nm
  • the palladium (Pd) film is 50 nm
  • the upper titanium (Ti) film is 175 nm.
  • first cap barrier film CM1 the second cap barrier film CM2, and the third cap barrier film CM3
  • a conformal film forming method such as a CVD method in order to completely cover the side surface of the rewiring RM.
  • CVD method a conformal film forming method
  • the first cap barrier film CM1 in contact with the third base barrier film UM3 is made of the same material as the film of the third base barrier film UM3, so that the third base barrier film UM3 and the third base barrier film UM3 in the overhanging portion PP are formed.
  • Adhesiveness with 1 cap barrier film CM1 can be improved.
  • the base metal film UM and the cap metal film in the overhanging portion PP are made equal by using the same material for the film that becomes the upper surface of the base metal film UM having the laminated structure and the film that becomes the lower surface of the cap metal film CM having the multilayer structure.
  • Adhesiveness with CM can be improved, movement (diffusion) of copper ions constituting the rewiring RM can be prevented, and entry of moisture and the like from the base insulating film 11 or the protective film 12 can be prevented.
  • the surface of the rewiring RM and the base metal film UM (particularly, the third base barrier film UM3) is subjected to hydrogen plasma treatment, and the upper surface and side surfaces of the rewiring RM and the base
  • the oxide film on the upper surface of the metal film UM may be removed and cleaned to improve the adhesion between the base metal film UM and the cap metal film CM.
  • a resist mask PR2 is formed on the third cap barrier film CM3.
  • the resist mask PR2 corresponds to the second planar pattern P2, and is a pattern that covers the rewiring RM and the projecting portion PP around the rewiring RM and exposes the rest in plan view.
  • FIG. 10 shows a part of the process of forming the cap metal film CM subsequent to FIG.
  • the third cap barrier film CM3 in the region exposed from the resist mask PR2 is removed by dry etching or wet etching to form a third cap barrier film CM3 having the second planar pattern P2.
  • the third cap barrier film CM3 made of a titanium (Ti) film is wet-etched using an ammonia aqueous solution. That is, the third cap barrier film CM3 is patterned using the resist mask PR2.
  • the second cap barrier film CM2 is etched by using the patterned third cap barrier film CM3 made of a titanium (Ti) film as a hard mask to form a second cap barrier film CM2 having a second planar pattern P2.
  • the second cap barrier film CM2 made of a palladium (Pd) film is wet etched using a potassium iodide iodide solution, but may be etched by a dry etching method. That is, the second cap barrier film CM2 is patterned (etched) using the third cap barrier film CM3 as a mask.
  • the base metal film UM exists in the overhanging portion PP that is an area outside the rewiring RM, and in the overhanging portion PP, Since the cap metal film CM and the base metal film UM are in direct contact with each other, the etching solution does not penetrate into the rewiring RM.
  • FIG. 11 shows a part of the process of forming the cap metal film CM and the processing process of the base metal film UM following FIG.
  • the first cap barrier film CM1 and the base metal film UM in the regions exposed from the third cap barrier film CM3 and the second cap barrier film CM2 are removed by etching, and the upper surface of the base insulating film 11 is exposed. Since the first cap barrier film CM1 and the base metal film UM are formed of a titanium (Ti) film and a titanium nitride (TiN) film, for example, the first cap barrier film CM1 is formed by wet etching using an ammonia aqueous solution.
  • the base metal film UM can be removed to form the first cap barrier film CM1 and the base metal film UM having the second planar pattern P2.
  • the third cap barrier film CM3 formed of a titanium (Ti) film is also removed at the same time, and the upper surface of the second cap barrier film CM2 is exposed.
  • the film thickness of the third cap barrier film CM3 so as to be approximately equal to the etching time of the first cap barrier film CM1 and the base metal film UM, the first cap barrier film with respect to the end portion of the second cap barrier film CM2 is set. Side etching of the CM1 and the base metal film UM can be reduced.
  • the cap metal film CM covering the upper surface and the side surface of the adjacent rewiring RM and the base metal film UM in contact with the lower surface are separated, and the cap metal film CM and the base metal film UM having the same second planar pattern P2 are separated. Is formed.
  • “equal” includes the case where there is a dimensional difference due to the above-mentioned side etching.
  • the base metal film UM exists in the overhanging portion PP that is an area outside the rewiring RM.
  • the cap metal film CM and the base metal film UM are in direct contact with each other, so that the etching solution does not penetrate into the rewiring RM.
  • FIG. 12 shows a process for forming the protective film 12.
  • a protective film 12 having an opening 12a that covers the upper surface and the side surface of the rewiring RM and exposes the external pad electrode 18 provided on the upper surface of the rewiring RM is formed.
  • the protective film 12 is thicker than the rewiring RM and is in contact with the upper surface of the base insulating film 11 in a region between adjacent rewiring RMs.
  • a photosensitive polyimide resin is used as the protective film 12.
  • a photosensitive polyimide is applied on the rewiring RM and exposed to form an opening 12a exposing the external pad electrode 18, and then cured and cured.
  • FIG. 13 shows a mounting process of the semiconductor chip 1A.
  • the semiconductor chip 1A is mounted on the die pad portion 25D, the rewiring RM and the lead 25L are connected by the wire 27, and then a part of the lead 25L (inner lead portion), the die pad portion 25D, and the semiconductor chip 1A.
  • the wire 27 is sealed with a sealing body (sealing resin) 26 to complete the semiconductor device (semiconductor integrated circuit device) of the first embodiment.
  • a semiconductor chip 1A having a plurality of redistribution lines RM is mounted on a die pad portion 25D and electrically connected to a plurality of leads 25L by wires 27.
  • a part (inner lead part) of the lead 25L, the die pad part 25D, the semiconductor chip 1A, and the wire 27 are sealed with a sealing body (sealing resin) 26 such as a thermosetting epoxy resin.
  • the sealing body 26 contains a filler such as silica (SiO 2 ) in addition to the epoxy resin.
  • the lead 25 has an outer lead portion extending from the inner lead portion covered with the sealing body 26 to the outside of the sealing body 26.
  • the wire 27 is connected to the external pad electrode 18 formed on the upper surface of the rewiring RM of the semiconductor chip 1A shown in FIG. 4 or 12, and the other end is connected to the inner lead portion of the lead 25L.
  • the die pad portion 25D and the plurality of leads 25L are made of, for example, copper (Cu) or 42 alloy (iron nickel alloy), and the wire 27 is made of copper (Cu).
  • a second cap barrier film CM2 made of a palladium (Pd) film is exposed on the surface of the external pad electrode 18, and a wire 27 made of copper is bonded to the second cap barrier film CM2 made of a palladium (Pd) film. Therefore, stable and sufficient bonding strength is possible, and high-reliability bonding with high shear strength is possible.
  • a copper wire Pd-coated Cu wire
  • a gold wire Au wire whose surface is coated with palladium (Pd) may be used.
  • the titanium (Ti) film is used as the first cap barrier film CM1, an alloy containing Ni, Mo, W, Co, Ru, Ta, or the like as a main component or a laminated film of these metals may be used. Further, although a titanium (Ti) film is used as the third base barrier film UM3, alloys such as metals such as Ni, Mo, W, Co, Ru, Ta, nitrides thereof, carbides thereof, and the like containing these metals as main components are used. A laminated film of these metals may be used. ⁇ Characteristics of semiconductor device manufacturing method> The main features of the method for manufacturing the semiconductor device according to the first embodiment will be described below.
  • a base metal film UM continuously extends from below the rewiring RM in a certain projecting portion PP.
  • the base metal film UM exists between the cap metal film CM formed on the side surface (side wall) of the rewiring RM and the base insulating film 11. Therefore, it is possible to prevent the occurrence of a defect that the copper (Cu) film forming the rewiring RM is peeled off in both the etching steps. Next, this effect will be described.
  • FIG. 18 and FIG. 19 are cross-sectional views during a manufacturing process of a semiconductor device which is a comparative example of the first embodiment.
  • FIG. 18 shows a state in which the base metal film UM in the region exposed from the plating film RM2 is removed following the step of removing the seed film RM1 described with reference to FIG. Unlike the manufacturing method of the first embodiment, after removing the seed film RM1, the plating process RM2 or the underlying metal film UM in the region exposed from the seed film RM1 is completely removed, so that the etching process of the underlying metal film UM is performed. In this case, overetching is essential. That is, as shown in FIG. 18, a side etch occurs in which the end of the base metal film UM recedes from the end of the rewiring RM, and the rewiring RM protrudes from the end of the base metal film UM in a bowl shape. Become.
  • the cap metal film CM is deposited on the upper surface and the side surface of the rewiring RM.
  • the step breakage occurs due to the side etching of the base metal film UM.
  • the etching solution is discharged from the step breakage portion to the rewiring RM or the rewiring RM. It was found that the lower base metal film UM soaked and a part of the rewiring RM was peeled off.
  • the underlying metal film UM in the region exposed from the plating film RM2 is completely removed continuously.
  • the base metal film UM is left until the cap metal film CM in the region outside the rewiring RM is removed, and following the removal of the cap metal film CM (in the same process)
  • the base metal film UM in the region outside the rewiring RM is removed, the above disconnection can be prevented and the rewiring RM can be prevented from being peeled off.
  • a second cap barrier film CM2 made of a palladium (Pd) film is exposed on the surface of the external pad electrode 18, and a wire 27 made of copper is bonded to the second cap barrier film CM2 made of a palladium (Pd) film. Since they are connected, it is possible to perform bonding with stable and sufficient bonding strength.
  • FIG. 14 is a cross-sectional view of the semiconductor device as the first modification of the first embodiment during the manufacturing process.
  • the side surface (side wall) of the rewiring RM is between the step of removing the seed film RM1 described with reference to FIG. 8 and the step of forming the cap metal film CM described with reference to FIG. Is added to the forward taper.
  • argon (Ar) sputter etching on the rewiring RM, a trapezoidal rewiring RMa whose side surface is forward tapered in a cross-sectional view can be obtained.
  • the trapezoidal shape can be said to be a shape in which the lower surface of the rewiring RMa is wider than the upper surface, or a shape in which the width of the lower surface is larger than the width of the upper surface in a sectional view.
  • the rewiring RMa has a laminated structure of a seed film RM1a and a plating film RM2a, and the side surfaces of the seed film RM1a and the plating film RM2a have a continuous forward taper.
  • the plating film RM2 is formed by the electrolytic plating method described with reference to FIG. 7, since the side surface of the resist mask PR1 is a forward taper, the side surface of the plating film RM2 is a reverse taper, and in the sectional view of the plating film RM2.
  • the shape is an inverted trapezoidal shape.
  • the covering property of the cap metal film CM formed so as to cover the side surface of the rewiring RM is lowered, and the cap metal film CM having a discontinuous portion or a pinhole is formed.
  • an etching solution penetrates into the rewiring RM in the wet etching process of the cap metal film CM, and a side surface of the rewiring RM is etched (abnormal etching).
  • FIG. 15 is a cross-sectional view of the semiconductor device as the second modification of the first embodiment during the manufacturing process.
  • the shoulder or side surface of the rewiring RM is interposed between the step of removing the seed film RM1 described with reference to FIG. 8 and the step of forming the cap metal film CM described with reference to FIG. Add a rounding process.
  • the rewiring RMb with a rounded shoulder can be obtained.
  • the oxide film on the surface of the copper film of the rewiring RM is reduced by annealing at a temperature of about 300 ° C. to 450 ° C. in a hydrogen (H 2 ) plasma treatment or a hydrogen (H 2 ) atmosphere, the temperature of 300 ° C.
  • the rewiring RMb has a stacked structure of a seed film RM1b and a plating film RM2b.
  • the shoulder of the rewiring RM is rounded and the side surface is smooth, so that the coverage of the cap metal film CM is improved, and the rewiring RM is abnormally etched due to the discontinuity or pinhole of the cap metal film CM. Can be prevented.
  • FIG. 16 is a cross-sectional view of the semiconductor device as the third modification of the first embodiment during the manufacturing process.
  • FIG. 16 shows a semiconductor chip 1D which is a modification of the semiconductor chip 1A shown in FIG. 4.
  • the difference from the semiconductor chip 1A is rewiring without interposing a base insulating film 11 on the surface protective film 10.
  • RM is arranged.
  • the base metal film UM is in contact with and electrically connected to the pad electrode 9 a and extends to the side wall and the upper surface of the surface protective film 10 in the pad opening 10 a of the surface protective film 10.
  • the lower surface of the base metal film UM is in contact with the upper surface of the surface protective film 10.
  • the base metal film UM and the cap metal film CM in contact with the lower surface of the rewiring RM are the same as those in the first embodiment.
  • Other structures and manufacturing methods are the same as those in the first embodiment.
  • the bottom surface of the rewiring RM is completely covered with the base metal film UM, the top surface and the side surfaces are completely covered with the cap metal film CM, and the base metal film UM and the cap metal film CM are in direct contact with each other at the projecting portion PP.
  • the copper constituting the rewiring RM can be prevented from moving (diffusing) to the outside as copper ions. Moreover, it is possible to prevent the copper film constituting the rewiring RM from being oxidized by moisture, halogen ions, or the like contained in the protective film 12 or the sealing body 26. That is, since the electrical reliability between the adjacent rewirings RM can be improved, the base insulating film 11 shown in FIG. 4 can be omitted.
  • the protective film 12 made of an organic film is provided on the rewiring RM and the surface protective film, even if the semiconductor chip 1D is sealed with a sealing body 26 containing silica, as shown in FIG. It is possible to prevent cracks in the surface protective interlayer 10 resulting from the contact between the sealing body 26 and the surface protective film 10.
  • the electrical reliability between the adjacent rewiring RMs can be improved, not only the base insulating film 11 but also the protective film 12 may be omitted. Even if moisture and halogen ions are contained in the sealing body 26, the above structure can prevent moisture and halogen ions from entering the rewiring RM.
  • FIG. 17 is a cross-sectional view of the semiconductor device as the fourth modification of the first embodiment during the manufacturing process.
  • FIG. 17 is a modification of the mounting process described in FIG.
  • the semiconductor chip 1A is mounted on the wiring board 30 via the adhesive layer 39, and the rewiring RM and the bonding finger 32 are connected by the wire 37, and then the upper surface side of the wiring board 30, the semiconductor chip 1A, and the wire 37 are connected. Is sealed with a sealing body (sealing resin) 38 to complete the semiconductor device (semiconductor integrated circuit device) of Modification 4.
  • the wiring board 30 has a plurality of bonding fingers 32 made of a conductor layer on the upper surface of a core layer 31 made of an insulating layer, and a plurality of lands 33 made of a conductor layer on the lower surface.
  • the plurality of bonding fingers 32 and the plurality of lands 33 are electrically insulated by a solder resist 35 made of an insulating layer.
  • the bonding fingers 32 and the lands 33 are electrically connected via via wirings 34 made of a conductor layer formed on the core layer 31, and bump electrodes 36 made of solder are connected to the lands 33.
  • the sealing body 38 is made of a thermosetting epoxy resin or the like, and contains a filler such as silica (SiO 2).
  • the wire 37 is connected to the external pad electrode 18 formed on the upper surface of the rewiring RM of the semiconductor chip 1A shown in FIG. 4 or 16, and the other end is connected to the bonding finger 32.
  • the wire 27 is a copper (Cu) wire, but a copper wire (Pd-coated Cu wire) whose surface is covered with palladium (Pd) or a gold wire (Au wire) may be used.
  • the external pad electrode 18 and the bonding finger 32 are electrically connected with a wire.
  • a solder ball is formed on the external pad electrode 18 on the upper surface of the rewiring RM, and the external pad electrode 18 is connected with the solder ball.
  • the bonding fingers 32 may be electrically connected.
  • the external pad electrode 18 and the bonding finger 32 may be connected by a solder ball with the side of the semiconductor chip 1A on which the rewiring RM is formed facing the upper surface of the wiring board 30.
  • the second embodiment corresponds to a modification of the semiconductor device manufacturing method of the first embodiment.
  • 20 and 21 are sectional views of the semiconductor device according to the second embodiment during the manufacturing process.
  • the semiconductor device of the second embodiment is indicated as a semiconductor chip 1E. Parts common to the manufacturing method of the first embodiment are denoted by the same reference numerals.
  • the underlying metal film UM in the region exposed from the seed film RM1 is removed.
  • the base metal film UM in the region exposed from the seed film RM1 is completely removed, so that overetching is essential in the etching process of the base metal film UM.
  • a side etch occurs in which the end portion of the base metal film UMa recedes from the end portion of the rewiring RM, and the rewiring RM protrudes in a bowl shape from the end portion of the base metal film UMa.
  • the rewiring RM has a stacked structure of a seed film RM1 and a plating film RM2, and the base metal film UMa has a stacked structure of a first base barrier film UM1a, a second base barrier film UM2a, and a third base barrier film UM3a.
  • etching is performed on the rewiring RM, and the rewiring RM is processed until the side surface of the rewiring RM is coincident with the side surface of the base metal film UMa or until the inner side of the rewiring RM is closer to the side surface of the base metal film UMa. Sharpen. That is, the protruding portion is removed by etching.
  • a rewiring RMc having a side surface coinciding with the side surface of the base metal film UMa is formed.
  • the rewiring RMc has a laminated structure of a seed film RM1c and a plating film RM2c.
  • the side surface of the rewiring RMc is on the inner side of the rewiring RMc than the side surface of the base metal film UMa.
  • the wet etching for the base metal film UM uses, for example, an ammonia aqueous solution. Then, the etching for the rewiring RM may be either wet etching or dry etching.
  • the steps after the step of forming the cap metal film CM of the first embodiment are performed to complete the semiconductor device having the semiconductor chip 1E.
  • the cap metal film is removed. It is possible to prevent the rewiring RMc from being peeled off due to CM breakage. Since the lower surface of the cap metal film CM can be in contact with the side surface or the upper surface of the base metal film UM, oxidation of the copper film constituting the rewiring RMc or movement (diffusion) of copper ions can be prevented. .
  • Modification 5 corresponds to a modification of the method for manufacturing the semiconductor device of the second embodiment.
  • FIG. 22 is a cross-sectional view of a semiconductor device as a fifth modification of the second embodiment during the manufacturing process.
  • the semiconductor device of Modification 5 is indicated as a semiconductor chip 1F. Portions common to the manufacturing method of Embodiment 1 or 2 are denoted by the same reference numerals.
  • the rewiring RM is sputter-etched in order to fill the space under the protruding portion of the rewiring RM.
  • argon (Ar) sputter etching on the rewiring RM shown in FIG. 20, as shown in FIG. 22, a trapezoidal rewiring RMd whose side surface is forward tapered as shown in FIG. 22 is obtained. Can do.
  • the space between the protruding portion of the rewiring RMc and the base insulating film 11 can be filled with the redeposited material (reattached material) 13.
  • the rewiring RMd has a stacked structure of a seed film RM1d and a plating film RM1d.
  • the process after the formation process of the cap metal film CM of the first embodiment is performed to complete the semiconductor device having the semiconductor chip 1F. Since the space is filled, the cap metal film CM is formed. The disconnection can be prevented, and the rewiring RMd can be prevented from peeling off.
  • the space between the protruding portion of the rewiring RM and the base insulating film 11 can be eliminated by performing the reflow of Modification 2 instead of etching the protruding portion.
  • the mounting process of Modification 4 may be applied to the semiconductor chip 1E or 1F of Embodiment 2 or Modification 5.
  • [Appendix 1] (A) forming a pad electrode on the main surface of the semiconductor substrate; (B) forming a first insulating film having an opening on the pad electrode; (C) forming a base metal film electrically connected to the pad electrode through the opening on the first insulating film; (D) forming a rewiring electrically connected to the pad electrode through the base metal film on the base metal film; (E) forming a cap metal film that covers the top and side surfaces of the rewiring; Have The step (d) (D-1) forming the rewiring electrically connected to the pad electrode through the base metal film on the base metal film; (D-2) a step of completely etching the base metal film in a region exposed from the rewiring; (D-3) Thereafter, the step of retreating the rewiring by wet etching, Including The step (e) (E-1) forming a cap barrier film over the entire main surface of the semiconductor substrate; (E-2) forming the cap metal film by patterning the

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Abstract

 半導体装置は、複数の配線層の最上層に形成されたパッド電極9aと、パッド電極9a上に開口11aを有する下地絶縁膜11と、下地絶縁膜11上に形成された下地金属膜UMと、下地金属膜UM上に形成された再配線RMと、再配線RMの上面および側面を覆うように形成されたキャップ金属膜CMとを有する。そして、再配線RMの外側の領域において、再配線RMの側壁上に形成されたキャップ金属膜CMと下地絶縁膜11との間には、再配線RMとは別材料の下地金属膜UMと、再配線RMとは別材料のキャップ金属膜CMと、が形成されており、再配線RMの外側の領域において、下地金属膜UMとキャップ金属膜CMとが直接接している。

Description

半導体装置およびその製造方法
 本発明は、半導体装置およびその製造方法に関し、特に、半導体基板の主面上に形成された複数の配線層の上部に、金属膜で構成された再配線を有する半導体装置およびその製造方法に適用して有効な技術に関するものである。
 半導体装置は、例えばCMIS(Complementary Metal Insulator Semiconductor)トランジスタなどの半導体素子が形成された半導体基板の上部に、例えばCu(銅)またはAl(アルミニウム)を主成分とする金属膜で多層配線が形成され、多層配線の上部にファイナルパッシベーション膜が形成される。
 特開2003-234348号公報(特許文献1)には、ファイナルパッシベーション膜上にCuを主成分とする再配線を形成し、ファイナルパッシベーション膜の下の最上層配線に形成した電極パッドと再配線とを電気的に接続する技術が開示されている。
 特開2012-4210号公報(特許文献2)の図25には、Cuを主要な成分とする再配線15の上面および側面を部分的に覆うように形成されたパッド18にワイヤ20が接続された構造が開示されている。
 特開2000-306938号公報(特許文献3)の要約には、パッシベーション膜4上に形成されたアルミニウム合金からなる再配線層6を、パッシベーション膜6上に張り出した張出部位9を有するバリアメタル膜8により完全に被覆することで、再配線層6のマイグレーションやコロージョンの発生を抑制することが開示されている。
 “Development of highly reliable Cu wiring of L/S=1/1μm for chip to chip interconnection”(非特許文献1)には、SAP(Semi-Additive Process)法で形成したCu配線の信頼性向上の為に、Cu配線の上面および側面に無電解メッキ法で形成した金属バリア膜を設けた構造が開示されている。
特開2003-234348号公報 特開2012-4210号公報 特開2000-306938号公報
T.Kanki et al., "Development of highly reliable Cu wiring of L/S=1/1μm for chip to chip interconnection" Interconnect Technology Conference, 2012 IEEE International,4-6 June 2012
 本願発明者が検討している再配線を有する半導体装置(半導体集積回路装置)は、半導体チップと、半導体チップに接続されたワイヤと、半導体チップおよびワイヤを封止する封止体とを有する。半導体チップは、半導体素子と、半導体素子に電気的に接続されたCuを主成分とする再配線と、半導体素子と再配線とを電気的に接続する多層配線層からなる配線とを有する。再配線は、多層配線層の最上層の配線層で形成された配線の一部分であるパッド電極に接続されている。最上層の配線層で形成された配線と再配線との間は、最上層の配線層で形成された配線を覆う表面保護膜と、表面保護膜上に形成された第1有機保護膜とで電気的に分離されているが、パッド電極を露出するように設けられた表面保護膜と第1有機保護膜の開口を介して、再配線はパッド電極と電気的に接続されている。再配線の上面と側面は第2有機保護膜で覆われているが、第2有機保護膜は、再配線の上面に形成された外部パッド電極を露出する開口を有しており、この開口部でワイヤが再配線に接続されている。
 半導体チップには、複数の再配線が形成されており、再配線の最小の線幅は12μmであり、隣接する再配線の最小間隔は15μmである。再配線の下面には、再配線を形成するための金属膜(例えば、Cr膜)からなるシード層が設けられているが、再配線の上面および側面は、第2有機保護膜と接している。
 本願発明者が検討している半導体装置は、高耐圧、高信頼性が要求されるため、HAST(Highly Accelerated temperature and humidity Stress Test)試験と呼ばれる高温高湿度雰囲気中での動作試験を実施している。本願発明者の検討によれば、HAST試験において、隣り合う再配線の間で、一方の再配線からCuが樹枝状に析出して、隣り合う再配線間の耐圧劣化または短絡が発生し、半導体装置の信頼性が低下していることが判明した。そして、Cuの樹枝状の析出は、表面保護膜と第1有機保護膜との界面または第1および第2有機保護膜の界面で発生していることも分かった。
 本願発明者の分析によれば、Cuからなる再配線を覆う第1および第2有機保護膜は、ポリイミド膜からなり、水分やハロゲンイオンを含んでいるため、再配線を構成するCuの表面が酸化され、その結果、Cuイオン(イオン化したCu)が発生する。上記半導体装置では、隣り合う再配線の最小間隔(15μm)は大きいものの、高電圧が印加され、隣り合う再配線間に高電界がかかる領域が存在し、この領域でCuの樹枝状の析出が発生していることが分かった。つまり、Cuイオンが高電界の影響で、表面保護膜と第1有機保護膜との界面または第1および第2有機保護膜の界面を移動(拡散)することで隣り合う再配線間の耐圧劣化または短絡が発生し、半導体装置の信頼性が低下していると考えている。
 本発明の目的は、再配線を有する半導体装置において、信頼性を向上させることのできる技術を提供することにある。
 本発明の前記ならびにその他の目的と新規な特徴は、本明細書の記述および添付図面から明らかになるであろう。
 一実施の形態である半導体装置は、複数の配線層の最上層に形成されたパッド電極と、パッド電極上に開口を有する保護膜と、保護膜上に形成された下地金属膜と、下地金属膜上に形成された再配線と、再配線の上面および側面を覆うように形成されたキャップ金属膜とを有する。そして、再配線の外側の領域において、再配線の側壁上に形成されたキャップ金属膜と保護膜との間には、再配線とは別材料の下地金属膜と、再配線とは別材料のキャップ金属膜と、が形成されており、再配線の外側の領域において、下地金属膜とキャップ金属膜とが直接接している。
 一実施の形態によれば、再配線を有する半導体装置の信頼性を向上させることができる。
本発明の実施の形態1である半導体装置の回路ブロック図である。 本発明の実施の形態1である半導体装置が形成された半導体チップの全体平面図である。 図2の一部を拡大して示す平面図である。 図3のA-A線に沿った断面図である。 本実施の形態1の半導体装置の製造工程中の断面図である。 図5に続く半導体装置の製造工程中の断面図である。 図6に続く半導体装置の製造工程中の断面図である。 図7に続く半導体装置の製造工程中の断面図である。 図8に続く半導体装置の製造工程中の断面図である。 図9に続く半導体装置の製造工程中の断面図である。 図10に続く半導体装置の製造工程中の断面図である。 図11に続く半導体装置の製造工程中の断面図である。 図12に続く半導体装置の製造工程中の断面図である。 変形例1である半導体装置の製造工程中の断面図である。 変形例2である半導体装置の製造工程中の断面図である。 変形例3である半導体装置の製造工程中の断面図である。 変形例4である半導体装置の製造工程中の断面図である。 比較例である半導体装置の製造工程中の断面図である。 図18に続く比較例である半導体装置の製造工程中の断面図である。 実施の形態2の半導体装置の製造工程中の断面図である。 図20に続く半導体装置の製造工程中の断面図である。 変形例5である半導体装置の製造工程中の断面図である。
 以下の実施の形態においては便宜上その必要があるときは、複数のセクションまたは実施の形態に分割して説明するが、特に明示した場合を除き、それらはお互いに無関係なものではなく、一方は他方の一部または全部の変形例、応用例、詳細説明、補足説明等の関係にある。また、以下の実施の形態において、要素の数等(個数、数値、量、範囲等を含む)に言及する場合、特に明示した場合および原理的に明らかに特定の数に限定される場合等を除き、その特定の数に限定されるものではなく、特定の数以上でも以下でもよい。
 さらに、以下の実施の形態において、その構成要素(要素ステップ等も含む)は、特に明示した場合および原理的に明らかに必須であると考えられる場合等を除き、必ずしも必須のものではない。同様に、以下の実施の形態において、構成要素等の形状、位置関係等に言及するときは、特に明示した場合および原理的に明らかにそうでないと考えられる場合等を除き、実質的にその形状等に近似または類似するもの等を含むものとする。このことは、上記数等(個数、数値、量、範囲等を含む)についても同様である。
 以下、本発明の実施の形態を図面に基づいて詳細に説明する。なお、実施の形態を説明するための全図において、同一の機能を有する部材には同一または関連する符号を付し、その繰り返しの説明は省略する。また、複数の類似の部材(部位)が存在する場合には、総称の符号に記号を追加し個別または特定の部位を示す場合がある。また、以下の実施の形態では、特に必要なとき以外は同一または同様な部分の説明を原則として繰り返さない。
 また、実施の形態で用いる図面においては、断面図であっても図面を見易くするためにハッチングを省略する場合もある。また、平面図であっても図面を見易くするためにハッチングを付す場合もある。
 また、断面図および平面図において、各部位の大きさは実デバイスと対応するものではなく、図面を分かりやすくするため、特定の部位を相対的に大きく表示する場合がある。また、平面図と断面図が対応する場合においても、各部位の大きさを変えて表示する場合がある。
(実施の形態1)
 本実施の形態1および以下の実施の形態の半導体装置(半導体集積回路装置)は、例えば複数の半導体素子と、複数の半導体素子の上部に形成された複数層の配線(多層配線)と、複数層の内の最上層の配線に接続された複数の再配線を有する半導体チップを有し、複数の半導体素子を前記多層配線および複数の再配線により接続して構成される。
<半導体装置について>
 図1は、半導体装置の回路ブロック図である。図1に示すように、半導体装置は、例えば半導体チップ1Aのデバイス面に形成された入出力(I/O)回路、アナログ回路、CMIS-ロジック回路、パワーMIS回路、およびメモリ回路を備え、半導体装置を構成している。
 半導体装置を構成する上記回路のうち、CMIS-ロジック回路は、例えば動作電圧が1~3VのCMISトランジスタで構成されており、I/O回路およびメモリ回路は、例えば動作電圧が1~3Vおよび5~8VのCMISトランジスタで構成されている。
 動作電圧が1~3VのCMISトランジスタは、第1のゲート絶縁膜を有する第1のnチャネル型MISFET(Metal Insulator Semiconductor Field Effect Transistor)と、第1のゲート絶縁膜を有する第1のpチャネル型MISFETとで構成される。また、動作電圧が5~8VのCMISトランジスタは、第2のゲート絶縁膜を有す第2のnチャネル型MISFETと、第2のゲート絶縁膜を有す第2のpチャネル型MISFETとで構成される。第2のゲート絶縁膜の膜厚は、第1のゲート絶縁膜の膜厚よりも厚く構成される。以下の説明では、MISFETをMISトランジスタという。
 また、アナログ回路は、例えば動作電圧が5~8VのCMISトランジスタ(またはバイポーラトランジスタ)と抵抗素子と容量素子とで構成されており、パワーMIS回路は、例えば動作電圧が5~8VのCMISトランジスタと動作電圧が20V~100Vの高耐圧MISトランジスタ(高耐圧素子)とで構成されている。
 高耐圧MISトランジスタは、例えば第3のゲート絶縁膜を有する第3のnチャネル型MISFET、または第3のゲート絶縁膜を有する第3のpチャネル型MISFET、あるいは両方で構成される。ゲート電極とドレイン領域との間、またはゲート電極とソース領域との間に20V~100Vの電圧が印加される場合、第3のゲート絶縁膜の膜厚は、第2のゲート絶縁膜の膜厚よりも厚くなるように構成される。
 図2は、半導体チップ1Aの一例を示す全体平面図、図3は、図2の破線Xで囲まれた領域の拡大平面図、図4は、図3のA-A線に沿った断面図である。
 図2は、半導体チップ1Aのデバイス面上に形成された再配線RM、RMV、RMSのレイアウトの一例を示している。再配線RM、RMV、RMSは、半導体チップ1Aの複数層の配線(図4に示す第1層Al配線5、第2層Al配線7、第3層Al配線9)に比べ、その膜厚および配線幅ともに大きいため、複数層の配線に比べ、非常に低インピーダンスである。再配線RM、RMV、RMSは、例えば、信号入出力用の再配線RMと、電源(Vcc、GND)供給用の再配線RMVおよび内部回路間の接続用の再配線RMSとして使用されている。
 図2に示すように、半導体チップ1Aの周辺部には、半導体装置の外部接続端子を構成する複数の再配線RMが配置されている。半導体装置の外部接続端子を構成する再配線RMのそれぞれの一端には、外部パッド電極18が形成されており、他端は、図3、4に示すように最上層の配線に形成されたパッド電極9aに接続されている。外部パッド電極18は、特に限定されないが、半導体チップ1Aの各辺に沿って一列に配置される。なお、外部パッド電極18は、半導体チップ1Aの各辺に沿って千鳥状、あるいは3列以上の列となるように配置してもよいのは勿論である。つまり、再配線RMは、例えば、図1の入出力(I/O)回路を構成する信号入出力用の再配線である。
 また、図2に示す再配線RMVは、電源(Vcc、GND)供給用の再配線である。再配線RMVの一端には外部パッド電極18が形成され、他端は半導体チップ1A内の電源配線に形成されたパッド電極9aに接続されているので、半導体チップ1Aの外部から供給された電源(Vcc、GND)電圧を、半導体チップ1A内の複数の電源配線に低インピーダンスで供給することができる。
 また、図2に示す再配線RMSは、半導体チップ1Aに形成された回路間または素子間を接続する配線として使用されている。したがって、再配線RMSには外部パッド電極18は形成されていない。再配線RMSの両端は、配線に形成されたパッド電極9aに接続されている。
 図3は、隣り合う2つの信号入出力用の再配線RMの拡大平面図を示している。隣り合う2つの再配線RMは、互いに等しい平面形状を有するので、紙面上部に位置する再配線RMを例に説明する。再配線RMは、紙面のX方向に延在しており、その一端で、紙面のX方向に延在する配線9のパッド電極9aに電気的に接続されている。再配線RMの他端には、外部パッド電極18が形成されている。再配線RMは、第1平面パターンP1を有し、下地金属膜UMおよびキャップ金属膜CMは第2平面パターンP2を有している。第1平面パターンP1と第2平面パターンP2とは相似形であり、第2平面パターンP2は、第1平面パターンP1を拡大した形状を有する。再配線RMの全周囲には、下地金属膜UMおよびキャップ金属膜CMで構成された張り出し部PPが配置されている。つまり、第1平面パターンP1を張り出し部PPの幅S3だけ拡大すると第2平面パターンP2となる。
 また、再配線RMの最小配線幅Lは、例えば12μmであり、隣り合う再配線RMの最小配線間隔S1は15μm、隣り合う張り出し部PP間の最小間隔S2は10μm、張り出し部PPの張り出し量S3は2.5μm、である。
 理想的には、再配線RMの全周囲にわたって、張り出し部PPの張り出し量S3は等しくなるが、第2平面パターンP2が第1平面パターンP1に対して、例えば、X方向にαだけずれていても良い。第1平面パターンP1対して、第2平面パターンP2がX方向にαだけずれた場合、第1平面パターンP1の右側の辺の張り出し量はS3R=(S3+α)となり、左側の辺の張り出し量はS3L=(S3-α)となる。
 本実施の形態1では、張り出し量S3を充分に確保し、減少した側の張り出し量S3L=(S3-α)が、図4に示す、再配線RMの側面上に形成されたキャップ金属膜CMの膜厚よりも大きくしている。
 図4に示すように、例えばp型の単結晶シリコンからなる半導体基板1Pにはp型ウエル2P、n型ウエル2Nおよび素子分離溝3が形成されており、素子分離溝3の内部には、例えば酸化シリコン膜からなる素子分離絶縁膜3aが埋め込まれている。
 上記p型ウエル2P内にはnチャネル型MISトランジスタ(Qn)が形成されている。nチャネル型MISトランジスタ(Qn)は、素子分離溝3で規定された活性領域に形成され、p型ウエル2P内に形成されたソース領域nsおよびドレイン領域ndと、p型ウエル2P上にゲート絶縁膜niを介して形成されたゲート電極ngとを有している。また、上記n型ウエル2N内にはpチャネル型MISトランジスタ(Qp)が形成されており、ソース領域psおよびドレイン領域pdと、n型ウエル2N上にゲート絶縁膜piを介して形成されたゲート電極pgとを有している。
 上記nチャネル型MISトランジスタ(Qn)およびpチャネル型MISトランジスタ(Qn)の上部には、半導体素子間を接続する金属膜からなる配線が形成されている。半導体素子間を接続する配線は、一般に3層~10層程度の多層配線構造を有しているが、図4には、多層配線の一例として、Al合金を主体とする金属膜で構成された3層の配線層(第1層Al配線5、第2層Al配線7、第3層Al配線9)が示されている。配線層とは、各配線層で形成された複数の配線を纏めて表す場合に使用する。配線層の膜厚は、第2層の配線層は第1層の配線層より厚く、第3層の配線層は第2層の配線層よりも厚い。
 nチャネル型MISトランジスタ(Qn)およびpチャネル型MISトランジスタ(Qn)と第1層Al配線5との間、第1層Al配線5と第2層Al配線7との間、および第2層Al配線7と第3層Al配線9との間には、それぞれ酸化シリコン膜などからなる層間絶縁膜4、6、8と、3層の配線間を電気的に接続するプラグp1、p2、p3が形成されている。
 上記層間絶縁膜4は、例えば半導体素子を覆うように、半導体基板上1P上に形成され、第1層Al配線5はこの層間絶縁膜4上に形成される。第1層Al配線5は、例えば層間絶縁膜4に形成されたプラグp1を介して半導体素子であるnチャネル型MISトランジスタ(Qn)のソース領域ns、ドレイン領域nd、ゲート電極ngに電気的に接続される。また、第1層Al配線5は、層間絶縁膜4に形成されたプラグp1を介して半導体素子であるpチャネル型MISトランジスタ(Qp)のソース領域ps、ドレイン領域pd、ゲート電極pgに電気的に接続される。ゲート電極ng、pgと第1層Al配線5との接続は図示していない。
 第2層Al配線7は、例えば層間絶縁膜6に形成されたプラグp2を介して第1層Al配線5に電気的に接続される。第3層Al配線9は、例えば層間絶縁膜8に形成されたプラグp3を介して第2層Al配線7に電気的に接続される。プラグp1、p2、p3は金属膜、例えばW(タングステン)膜で構成される。
 なお、多層配線(3層配線)を化学的機械研磨法(CMP法)によりCuを主体とする金属膜で形成する場合は、配線とプラグとを一体に形成するデュアルダマシン法で形成してよいことは勿論である。また、層間絶縁膜4、6、8は、酸化シリコン膜(SiO)からなるが、炭素を含む酸化シリコン膜(SiOC膜)、窒素と炭素を含む酸化シリコン膜(SiCON膜)、フッ素を含む酸化シリコン膜(SiOF膜)の単層膜または積層膜で構成してよいことは勿論である。
 多層配線の最上層の配線層である上記第3層Al配線9の上部には、ファイナルパッシベーション膜として、例えば酸化シリコン膜、窒化シリコン膜などの単層膜、あるいはこれらの2層膜からなる表面保護膜(保護膜、絶縁膜)10が形成されている。そして、この表面保護膜10に形成されたパッド開口(開口)10aの底部に露出した最上層の配線層である第3層Al配線9は、Alパッドであるパッド電極(電極パッド、第1電極パッド)9aを構成している。
 上記第3層Al配線9は、パッド電極9aに限らず、例えばパッド電極9aに一体に形成される配線、パッド電極9aに接続されない配線などを構成する。パッド電極9aに接続されない配線は、半導体素子間あるいは回路間を電気的に接続し、半導体集積回路を構成する配線として使用される。
 上記表面保護膜10の上には、パッド開口10aの上方に開口11aを有する絶縁膜である下地絶縁膜(有機保護膜、絶縁膜)11が形成されている。また、下地絶縁膜11の上には、下地絶縁膜11の開口11a、および表面保護膜10のパッド開口10aを通じてパッド電極9aに電気的に接続された再配線RMが形成されている。開口11aはパッド開口10aよりも大きく、パッド開口10aの全周において、パッド開口10aを規定する表面保護膜10の上面(表面)が開口11aから露出している。再配線RMは、パッド開口10aおよび開口11aを完全に埋めるように、パッド開口10aおよび開口11aの内部に形成され、さらに、下地絶縁膜11の上に延在している。
 パッド電極9aと再配線RMとの間には、下地金属膜UMが介在している。下地金属膜UMは、パッド電極9aに接触して電気的に接続されており、表面保護膜10のパッド開口10aおよび下地絶縁膜11の開口11aにおいて、表面保護膜10の側面(側壁)および上面、ならびに下地絶縁膜11の側面(側壁)に沿って形成され、さらに、下地絶縁膜11の上面に延在している。下地金属膜UMは、上面と下面とを有し、上面は再配線RMと接しており、下面は、パッド電極9a、表面保護膜10および下地絶縁膜11に接している。後述するが、下地金属膜UMは、3層構造の下地バリア膜で構成されており、パッド電極9aの側から第1下地バリア膜UM1、第2下地バリア膜UM2および第3下地バリア膜UM3からなる。したがって、下地金属膜UMの上面とは、第3下地バリア膜UM3の上面を意味し、下面とは第1下地バリア膜UM1の下面を意味する。第1下地バリア膜UM1、第2下地バリア膜UM2および第3下地バリア膜UM3は、例えば、順に、チタン(Ti)膜、窒化チタン(TiN)膜およびチタン(Ti)膜で構成し、それらの膜厚は、順に、10nm、50nmおよび10nmとする。この膜厚は、下地絶縁膜11の上面上における膜厚である。
 また、再配線RMは、上面、下面および側面を有しており、再配線RMの下面は下地金属膜UMの上面と接している。再配線RMは、銅(Cu)を主成分とする銅膜であり、シード膜RM1とメッキ膜RM2との積層構造で構成されている。したがって、再配線RMの下面とは、シード膜RM1の下面を意味し、上面とはメッキ膜RM2の上面を意味する。また、再配線RMの側面(側壁)とは、シード膜RM1とメッキ膜RM2の積層構造の側面(側壁)を意味する。シード膜RM1およびメッキ膜RM2の膜厚は、それぞれ、250nmおよび6μmである。ちなみに、第3層Al配線9の膜厚は、400nm~600nmであるので、再配線RMは、第3層Al配線9、言い換えると、パッド電極9aが形成された配線9の10倍以上の膜厚を有する低抵抗の配線である。つまり、再配線RMの膜厚は、パッド電極9aが形成された配線9の膜厚よりも大きい。望ましくは、再配線RMの膜厚はパッド電極9aが形成された配線9の膜厚の10倍以上である。
 再配線RMの上面および側面に接して、再配線RMを完全に覆うようにキャップ金属膜CMが形成されている。キャップ金属膜CMは、再配線RMの上面の全体および側面の全体を覆っている。キャップ金属膜CMは、再配線RMを構成するシード膜RM1の側面(側壁)およびメッキ膜RM2の側面(側壁)を完全に覆っている。キャップ金属膜CMは、上面と下面を有し、下面は再配線RMの上面および再配線RMの側面と接しており、再配線RMの外側の領域(再配線RMが形成されていない領域)において、下地金属膜UMの上面と直接接している。
 下地金属膜UMおよびキャップ金属膜CMは、再配線RMの側面(厳密には、再配線RMの側面の下端部分)から再配線RMの外側の領域(再配線RMが形成されていない領域)に張り出し部PPを有しており、張り出し部PPにおいて、下地金属膜UMの上面とキャップ金属膜CMの下面とは直接接している。また、張り出し部PPの張り出し量S3は、再配線RMの側面(側壁)上に形成されたキャップ金属膜CMの膜厚よりも大きく、例えば、2.5μmである。つまり、平面視において、張り出し部PPの先端である下地金属膜UMおよびキャップ金属膜CMの端部は、再配線RMの側面(側壁)上に形成されたキャップ金属膜CMよりも再配線RMの外側に位置している。また、張り出し部PPは、平面視における再配線RMの全周にわたって形成されている。張り出し量S3は、張り出し部PPの幅であり、再配線RMの外側の領域における、再配線RMの端部から下地金属膜UMまたはキャップ金属膜CMの端部までの距離を意味する。
 後述するが、キャップ金属膜CMは、第1キャップバリア膜CM1および第2キャップバリア膜CM2の積層構造からなり、第1キャップバリア膜CM1の下面が再配線RMの上面および側面と接しており、さらに、下地金属膜UMの上面(正確には、第3下地バリア膜UM3の上面)と接している。キャップ金属膜CMの下面は、第1キャップバリア膜CM1の下面を意味し、上面は、第2キャップバリア膜CM2の上面を意味する。第1キャップバリア膜CM1は、チタン(Ti)膜からなり、その膜厚は50nmであり、第2キャップバリア膜CM2は、パラジウム(Pd)膜からなり、それらの膜厚は、175nmである。この膜厚は、再配線RMの上面上における膜厚である。
 また、下地金属膜UMを構成する第3下地バリア膜UM3とキャップ金属膜CMを構成する第1キャップバリア膜CM1を同じ材質からなる膜(具体的にはチタン(Ti)膜)としたことで、張り出し部PPにおける下地金属膜UMとキャップ金属膜CMの接着性を強固にでき、再配線RMを構成する銅の移動(拡散)を低減している。
 また、張り出し部PPにおいては、下地金属膜UM上にキャップ金属膜CMが積層した構造となっているため、再配線RMの外側の領域の張り出し部PPにおける下地金属膜UMの膜厚とキャップ金属膜CMの膜厚との和は、再配線RMと下地絶縁膜11とに挟まれた下地金属膜UMの膜厚よりも厚くなっている。また、再配線RMの外側の領域の張り出し部PPにおける下地金属膜UMの膜厚と第1キャップバリア膜CM1の膜厚との和は、再配線RMと下地絶縁膜11とに挟まれた下地金属膜UMの膜厚よりも厚くなっている。
 再配線RMを全体的に覆うように保護膜12が形成されている。保護膜12は、再配線RMの上面(正確には、キャップ金属膜CMの上面、第2キャップバリア膜CM2の上面)を部分的に露出する開口12aを有しており、再配線RMの露出部分が外部パッド電極18となっている。
 ここで、下地絶縁膜11および保護膜12は、ともに、有機膜、例えば、ポリイミド系樹脂やベンゾシクロブテン系樹脂、アクリル系樹脂、エポキシ系樹脂、シリコン系樹脂等を用いることができる。
 なお、下地金属膜UMおよびキャップ金属膜CMは、再配線RMを構成する銅(Cu)膜が銅イオンとなって外部に移動(拡散)するのを防止するものであり、再配線RMとは異なる材料(別材料)で構成されている。また、下地金属膜UMおよびキャップ金属膜CMには、銅(Cu)膜は含まれていない。
 また、信号入出力用の再配線RMを例に説明したが、電源供給用の再配線RMVおよび回路間又は素子間を接続する再配線RMSも、再配線RMと同様の構造である。
<半導体装置の特徴>
 以下に、本実施の形態1の半導体装置の主な特徴を説明する。
 銅膜からなる再配線RMは、再配線RMの下面を覆い、再配線RMとは異なる材料からなる下地金属膜UMと、再配線RMの上面および側面を覆い、再配線RMとは異なる材料からなるキャップ金属膜CMとで完全に囲まれている。そして、再配線RMの外側の領域において、下地金属膜UMとキャップ金属膜CMとは張り出し部PPを有しており、張り出し部PPにおいて、下地金属膜UMとキャップ金属膜CMとが直接接触している。このような構造により、隣り合う再配線RMの間に電界がかかったとしても、再配線RMを構成する銅が、再配線RMの外側の領域に移動(拡散)することで発生する、隣り合う再配線RM間の耐圧劣化または短絡を防止することができる。また、下地絶縁膜11または保護膜12を構成するポリイミド膜に含まれる水分、ハロゲンイオン等が、銅膜からなる再配線RM中に侵入するのを防止できるので、銅膜の酸化を防止でき、隣り合う再配線RM間の耐圧劣化または短絡を防止できる。
 上記張り出し部の張り出し量は、再配線RMの側面を覆うキャップ金属膜CMの膜厚よりも大きい。また、第1パターンに対する第2パターンのずれによって張り出し量が減少した場合にも、減少した張り出し量が、再配線RMの側面を覆うキャップ金属膜CMの膜厚よりも大きいので、製造ばらつきがあった場合でも、隣り合う再配線RM間の耐圧劣化または短絡を防止することができる。再配線RMを構成する銅膜の酸化を防止できる。
 また、下地金属膜UMの上面となる下地バリア膜とキャップ金属膜の下面となるキャップバリア膜とを同じ材質からなる膜としている。そのため、張り出し部における下地金属膜UMとキャップ金属膜CMとの接着性を向上でき、再配線RMを構成する銅が、再配線RMの外側の領域に移動(拡散)するのを十分に防止できるので、隣り合う再配線RM間の耐圧劣化または短絡、ならびに再配線RMの酸化を防止することができる。
 また、平面視において、再配線RMの全周にわたって張り出し部PPが形成されているので、全ての方向に隣り合う再配線RMとの間の耐圧劣化または短絡並びに再配線の酸化を防止することができる。
 平面視において、銅膜からなる再配線RMが有する第1平面パターンP1よりも大きい第2平面パターンP2を有する下地金属膜UMとキャップ金属膜CMとで再配線RMを完全に包み込み、再配線RMの外側の領域において、下地金属膜UMの上面とキャップ金属膜CMの下面とが直接接触している。この構造により、隣り合う再配線RM間に高電界が印加されても、再配線RMの酸化を防止でき、隣り合う再配線RM間の耐圧劣化または短絡を防止できる。また、再配線RMを構成する銅膜が酸化して銅イオンが発生したとしても、再配線RMの外側に銅イオンが移動(拡散)するのを防止できる。
 また、第1平面パターンP1の全周において、第2平面パターンP2は第1平面パターンP1よりも大きいので、全ての方向に隣り合う再配線RMとの間の耐圧劣化または短絡を防止することができる。
<半導体装置の製造方法>
 次に、本実施の形態1の半導体装置の製造方法について説明するが、本実施の形態1の特徴である再配線の製造方法を中心に説明する。再配線の製造方法は、図4に示した断面に対応している。
 図5~図13は、本実施の形態1の半導体装置の製造工程中の断面図である。
 図5は、複数の配線層とパッド電極が形成された半導体基板を準備する工程を示している。半導体基板1Pには、pチャネル型MISトランジスタ(Qp)およびnチャネル型MISトランジスタ(Qn)が形成された後、複数の配線層からなる配線が形成されている。具体的には、図4で説明したように、3層の配線層(第1層Al配線5、第2層Al配線7、第3層Al配線9)が形成されている。そして、第3層Al配線9の上部には、表面保護膜10が形成されているが、表面保護膜10は、パッド開口10aを有しており、最上層の配線層である第3層Al配線9のパッド開口10aから露出した部分が、パッド電極9aとなっている。図5に示された断面構造は、図4で説明した通りである。
 図6は、下地絶縁膜11、下地金属膜UMおよびシード膜RM1の形成工程を示している。まず、表面保護膜10上に下地絶縁膜11を形成するが、下地絶縁膜11として感光性ポリイミド樹脂を用いる。表面保護膜10上に感光性ポリイミドを塗布、露光してパッド開口10aおよびパッド電極9aを露出させた後、キュアを行い硬化させる。つまり、パッド開口10aおよびパッド電極9aより大きい開口11aを有する下地絶縁膜11を形成する。
 次に、開口11a、パッド開口10aを介してパッド電極9aに電気的に接続する下地金属膜UMおよびシード膜RM1を形成(堆積)する。下地金属膜UMを構成する第1下地バリア膜UM1、第2下地バリア膜UM2および第3下地バリア膜UM3は、順に、チタン(Ti)膜を5~50nm、窒化チタン(TiN)膜を10~100nm、チタン(Ti)膜を5~50nmの膜厚で形成するのが適当である。ここでは、一例として、チタン(Ti)膜を10nm、窒化チタン(TiN)膜を50nmおよびチタン(Ti)膜を10nmとする。これらの第1下地バリア膜UM1、第2下地バリア膜UM2および第3下地バリア膜UM3は、例えば、スパッタ法により形成する。次に、スパッタ法を用いて、銅(Cu)膜からなるシード膜RM1を第3下地バリア膜UM3上に形成する。シード膜RM1は、250nm程度の膜厚とする。
 図7は、再配線RMの形成工程のメッキ工程を示している。シード膜RM1の上に、再配線RMの形成領域を露出し、再配線RMが形成されない領域を覆うレジストマスク(レジストパターン)PR1を形成する。つまり、レジストマスクPR1は、第1平面パターンP1の反転パターンとなっており、第1平面パターンP1に対応する開口を有している。次に、下地金属膜UMおよびシード膜RM1をシード層として、電解(電気)めっき法により、銅(Cu)膜からなるメッキ膜RM2をレジストマスクPR1から露出した領域のシード膜RM1上に選択的に形成する。メッキ膜RM2の膜厚は、例えば、約6μmとする。メッキ膜RM2の膜厚は、2μm~10μmの範囲にするのが良く、メッキ膜RM2の膜厚は薄すぎると再配線RMの抵抗が高くなるため、デバイスの要求を満足する抵抗値を得られる膜厚にすべきであり、ある程度の膜厚が一般的には必要となる。但し、厚すぎるとウエハの反りが大きくなり、その後のリソグラフィや加工装置で搬送エラーが発生し、加工が困難となり、製造コスト増加や生産性低下の弊害が発生する。なお、例えば、下地金属膜UM等は、パターニングの前後で同様の符号を付している。この工程で、第1平面パターンP1を有するメッキ膜RM2が形成される。
 図8は、再配線RMの形成工程であるシード膜RM1の除去(加工)工程を示している。メッキ膜RM2形成後に、レジストマスクPR1を除去する。次に、メッキ膜RM2から露出した領域のシード膜RM1を除去することで、メッキ膜RM2の下に、メッキ膜RM2と等しい平面パターンを有するパターニングされたシード膜RM1が残る。この工程で、第1平面パターンP1を有し、シード膜RM1とメッキ膜RM2との積層構造からなる再配線RMが形成される。
 この時、メッキ膜RM2から露出した領域(言い換えると、再配線RMの外側の領域)の下地金属膜UMは、除去せずに残しておくことが重要である。ただし、下地金属膜UMは、メッキ膜RM2から露出した領域に残っていることが重要であり、例えば、メッキ膜RM2から露出した領域の下地金属膜UMを半分程度の膜厚分だけエッチングで除去しても良い。つまり、メッキ膜RM2から露出した領域の下地金属膜UMの膜厚を、メッキ膜RM2で覆われた領域の下地金属膜UMの膜厚の半分程度にしても良い。メッキ膜RM2から露出した領域の下地金属膜UMの膜厚を薄くすることで、下地絶縁膜11から下地金属膜UMが剥離するのを防止することができる。下地金属膜UMの膜厚を低減することで、下地金属膜UMの持つ応力を低減して下地絶縁膜11からの剥離を低減できるという効果が得られる。ここで、エッチングは、メッキ膜RM2またはシード膜RM1をハートマスクとして、塩素系のガスを含むドライエッチングとする。
 図9は、キャップ金属膜CMを形成する工程の一部を示している。再配線RMの上面および側面を完全に覆うようにキャップ金属膜CMを形成(堆積)する。パターニングされる前のキャップ金属膜CMは、キャップ金属材料膜と呼ぶ。キャップ金属膜CMは、複数層のキャップバリア膜で構成されている。キャップ金属膜CMを形成するために、第1キャップバリア膜(第1キャップ金属材料膜)CM1、第2キャップバリア膜(第2キャップ金属材料膜)CM2および第3キャップバリア膜(第3キャップ金属材料膜)CM3を順次形成する。なお、本実施の形態1においては、第3キャップバリア膜CM3もキャップ金属膜CMの一部として扱う。第1キャップバリア膜CM1、第2キャップバリア膜CM2および第3キャップバリア膜CM3は、チタン(Ti)膜を10~200nm、パラジウム(Pd)膜を10~200nm、チタン(Ti)膜を10~200nmの膜厚で形成するのが適当である。ここでは、一例として、下層のチタン(Ti)膜を10nm、パラジウム(Pd)膜を50nm、上層のチタン(Ti)膜を175nmとする。第1キャップバリア膜CM1、第2キャップバリア膜CM2および第3キャップバリア膜CM3は、再配線RMの側面を完全に覆うために、CVD法などのコンフォーマルな成膜方法を用いるのが良いが、これに限るものではない。
 ここで、第3下地バリア膜UM3と接する第1キャップバリア膜CM1を、第3下地バリア膜UM3の膜と同じ材質の膜としたことで、張り出し部PPにおける、第3下地バリア膜UM3と第1キャップバリア膜CM1との接着性を向上させることができる。言い換えると、積層構造の下地金属膜UMの上面となる膜と、積層構造のキャップ金属膜CMの下面となる膜の材質を等しくすることで、張り出し部PPにおける、下地金属膜UMとキャップ金属膜CMとの接着性を向上でき、再配線RMを構成する銅イオンの外部への移動(拡散)を防止でき、下地絶縁膜11または保護膜12からの水分などの侵入を防止できる。
 また、第1キャップバリア膜CM1の成膜前に、再配線RMおよび下地金属膜UM(特に、第3下地バリア膜UM3)の表面に水素プラズマ処理を施し、再配線RMの上面および側面ならびに下地金属膜UMの上面の酸化膜を除去して清浄化し、下地金属膜UMとキャップ金属膜CMとの接着性を向上させておくと良い。
 次に、図9に示すように、レジストマスクPR2を、第3キャップバリア膜CM3上に形成する。レジストマスクPR2は、第2平面パターンP2に対応しており、平面視において、再配線RMおよび再配線RMの周囲の張り出し部PPを覆い、それ以外を露出するパターンとなっている。
 図10は、図9に続く、キャップ金属膜CMを形成する工程の一部の工程を示している。レジストマスクPR2から露出した領域の第3キャップバリア膜CM3をドライエッチングまたはウェットエッチングで除去し、第2平面パターンP2を有する第3キャップバリア膜CM3を形成する。チタン(Ti)膜からなる第3キャップバリア膜CM3は、アンモニア過水溶液を用いてウェットエッチングする。つまり、レジストマスクPR2を用いて、第3キャップバリア膜CM3をパターニングする。
 次に、レジストマスクPR2を除去する。そして、パターニングされたチタン(Ti)膜からなる第3キャップバリア膜CM3をハードマスクとして第2キャップバリア膜CM2をエッチングし、第2平面パターンP2を有する第2キャップバリア膜CM2を形成する。パラジウム(Pd)膜からなる第2キャップバリア膜CM2は、ヨウ素ヨウ化カリウム溶液を用いてウェットエッチングするが、ドライエッチング法でエッチングしても良い。つまり、第3キャップバリア膜CM3をマスクとして、第2キャップバリア膜CM2をパターニング(エッチング)する。
 第3キャップバリア膜CM3および第2キャップバリア膜CM2にウェットエッチングを施したとしても、再配線RMの外側の領域である張り出し部PPに下地金属膜UMが存在しており、張り出し部PPにおいて、キャップ金属膜CMと下地金属膜UMとが直接接しているので、再配線RMにエッチング液が染み込むことはない。
 図11は、図10に続く、キャップ金属膜CMを形成する工程の一部および下地金属膜UMの加工工程を示している。第3キャップバリア膜CM3および第2キャップバリア膜CM2から露出した領域の第1キャップバリア膜CM1および下地金属膜UMをエッチングして除去し、下地絶縁膜11の上面を露出させる。第1キャップバリア膜CM1および下地金属膜UMを、チタン(Ti)膜および窒化チタン(TiN)膜で形成しているので、例えば、アンモニア過水溶液を用いたウェットエッチングにより、第1キャップバリア膜CM1および下地金属膜UMを除去して、第2平面パターンP2を有する第1キャップバリア膜CM1および下地金属膜UMを形成することができる。この時、チタン(Ti)膜で形成されている第3キャップバリア膜CM3も同時に除去され、第2キャップバリア膜CM2の上面が露出する。第1キャップバリア膜CM1および下地金属膜UMのエッチング時間とほぼ等しくなるように第3キャップバリア膜CM3の膜厚を設定することで、第2キャップバリア膜CM2の端部に対する第1キャップバリア膜CM1および下地金属膜UMのサイドエッチングを低減できる。
 上記工程を経て、隣り合う再配線RMの上面および側面の覆うキャップ金属膜CMおよび下面に接する下地金属膜UMが分離され、等しい第2平面パターンP2を有するキャップ金属膜CMと下地金属膜UMとが形成される。ここで、「等しい」とは、上記のサイドエッチングによる寸法差が有る場合も含んでいる。
 第3キャップバリア膜CM3、第1キャップバリア膜CM1および下地金属膜UMにウェットエッチングを施したとしても、再配線RMの外側の領域である張り出し部PPに下地金属膜UMが存在しており、張り出し部PPにおいて、キャップ金属膜CMと下地金属膜UMとが直接接しているので、再配線RMにエッチング液が染み込むことはない。
 図12は、保護膜12の形成工程を示している。再配線RMの上面および側面を覆い、再配線RMの上面に設けられた外部パッド電極18を露出する開口12aを有する保護膜12を形成する。保護膜12は、再配線RMの膜厚よりも厚く、隣り合う再配線RMの間の領域で、下地絶縁膜11の上面と接している。保護膜12として、例えば、感光性ポリイミド樹脂を用いる。再配線RM上に感光性ポリイミドを塗布、露光して外部パッド電極18を露出させる開口12aを形成した後、キュアを行い硬化させる。
 図13は、半導体チップ1Aの実装工程を示している。上記工程の後、半導体チップ1Aをダイパッド部25D上に搭載し、再配線RMとリード25Lとをワイヤ27で接続した後、リード25Lの一部(インナーリード部)、ダイパッド部25D、半導体チップ1Aおよびワイヤ27を、封止体(封止樹脂)26で封止して、本実施の形態1の半導体装置(半導体集積回路装置)が完成する。
 図13に示すように、複数の再配線RMを有する半導体チップ1Aは、ダイパッド部25Dに搭載され、複数のリード25Lにワイヤ27で電気的に接続されている。リード25Lの一部(インナーリード部)、ダイパッド部25D、半導体チップ1Aおよびワイヤ27を、例えば熱硬化性エポキシ樹脂などの封止体(封止樹脂)26で封止されている。また、封止体26中には、エポキシ樹脂の他にシリカ(SiO)等のフィラーが含有している。リード25は、封止体26で覆われたインナーリード部から封止体26の外側に延在するアウターリード部を有している。
 ワイヤ27の一端は、図4又は図12に示す半導体チップ1Aの再配線RMの上面に形成された外部パッド電極18に接続され、他端は、リード25Lのインナーリード部に接続されている。ダイパッド部25Dおよび複数のリード25Lは、例えば、銅(Cu)または42アロイ(鉄ニッケル合金)からなり、ワイヤ27は、銅(Cu)からなる。
 外部パッド電極18の表面にはパラジウム(Pd)膜からなる第2キャップバリア膜CM2が露出しており、銅からなるワイヤ27がパラジウム(Pd)膜からなる第2キャップバリア膜CM2にボンディング接続されるので、安定かつ十分なボンディング強度を有する接合が可能となり、シェア強度の高い高信頼性のボンディングが可能となる。
 なお、ワイヤ27として、表面にパラジウム(Pd)を被覆した銅ワイヤ(PdコートCuワイヤ)、金ワイヤ(Auワイヤ)を用いても良い。
 第1キャップバリア膜CM1としてチタン(Ti)膜を用いたが、Ni、Mo、W、Co、Ru、Ta等を主成分とする合金やこれら金属の積層膜であっても良い。また、第3下地バリア膜UM3としてチタン(Ti)膜を用いたが、Ni、Mo、W、Co、Ru、Ta等の金属やその窒化物、炭化物など、これら金属を主成分とする合金やこれら金属の積層膜であっても良い。
<半導体装置の製造方法の特徴>
 以下に、本実施の形態1の半導体装置の製造方法の主な特徴を説明する。
 図10および図11を用いて説明したとおり、第2キャップバリア膜CM2のエッチング工程、ならびに、第1キャップバリア膜CM1および第3キャップバリア膜CM3のエッチング工程において、再配線RMの外側の領域である張り出し部PPに下地金属膜UMが再配線RMの下から連続的に延在している。また、再配線RMの側面(側壁)上に形成されたキャップ金属膜CMと下地絶縁膜11との間に下地金属膜UMが存在している。したがって、上記の両エッチング工程において、再配線RMを形成する銅(Cu)膜が剥離するという不良の発生を防止することができる。次に、この効果について説明する。
 図18と図19は、本実施の形態1の比較例である半導体装置の製造工程中の断面図である。
 図18は、図8を用いて説明したシード膜RM1の除去工程に続いて、メッキ膜RM2から露出した領域の下地金属膜UMを除去した状態を示している。上記本実施の形態1の製造方法とは異なり、シード膜RM1を除去後に、メッキ膜RM2またはシード膜RM1から露出した領域の下地金属膜UMを完全に除去するため、下地金属膜UMのエッチング工程においてオーバーエッチが必須となる。つまり、図18に示すように下地金属膜UMの端部が再配線RMの端部から後退するサイドエッチが発生し、下地金属膜UMの端部から再配線RMが庇状にせり出した構造となる。
 次に、図19に示すようにキャップ金属膜CMを再配線RMの上面および側面上に堆積するが、図19の破線Yで囲った部分において、「段切れ」と呼ばれるキャップ金属膜CMの不連続部分が発生することが本願発明者の検討により判明した。また、この段切れは、上記の下地金属膜UMのサイドエッチに起因して発生すること、さらに、キャップ金属膜CMのエッチング工程において、段切れ部からエッチング液が再配線RMまたは再配線RMの下の下地金属膜UMに染み込み、再配線RMの一部が剥離することが判明した。
 比較例では、シード膜RM1を除去後に、連続して、メッキ膜RM2から露出した領域の下地金属膜UMを完全に除去している。しかし、本実施の形態1では、再配線RMの外側の領域のキャップ金属膜CMを除去する段階まで下地金属膜UMは残しておき、キャップ金属膜CMの除去に続いて(同一工程であっても良い)、再配線RMの外側の領域の下地金属膜UM除去するため、上記の段切れを防止することができ、再配線RMの剥離を防止できる。
 また、外部パッド電極18の表面にはパラジウム(Pd)膜からなる第2キャップバリア膜CM2が露出しており、銅からなるワイヤ27がパラジウム(Pd)膜からなる第2キャップバリア膜CM2にボンディング接続されるので、安定かつ十分なボンディング強度を有する接合が可能となる。
 <変形例1>
 図14は、本実施の形態1の変形例1である半導体装置の製造工程中の断面図である。
 半導体チップ1Bの製造方法では、図8を用いて説明したシード膜RM1の除去工程と、図9を用いて説明したキャップ金属膜CMの形成工程との間に、再配線RMの側面(側壁)を順テーパにする工程を追加する。具体的には、再配線RMに対してアルゴン(Ar)スパッタエッチングを施すことで、断面視にて、側面が順テーパとなった台形形状の再配線RMaを得ることができる。台形形状とは、再配線RMaの下面が上面よりも広い形状、または、断面視において、下面の幅が上面の幅よりも大きい形状とも言える。また、再配線RMaは、シード膜RM1aとメッキ膜RM2aの積層構造となっており、シード膜RM1aとメッキ膜RM2aの側面は、連続的な順テーパとなっている。
 図7を用いて説明した電解めっき法でメッキ膜RM2を形成した場合、レジストマスクPR1の側面が順テーパとなっているため、メッキ膜RM2の側面は逆テーパとなり、メッキ膜RM2の断面視における形状は逆台形形状となる。側面が逆テーパの場合、再配線RMの側面を覆うように形成するキャップ金属膜CMの被覆性が低下して、不連続部またはピンホールをともなうキャップ金属膜CMとなってしまう。そのため、キャップ金属膜CMのウェットエッチング工程でエッチング液が再配線RMに染み込み、再配線RMの側面がエッチングされる(異常エッチング)現象が発生することが、本願発明者の検討で判明した。
 再配線RMの側面を順テーパにすることで、キャップ金属膜CMの不連続部またはピンホールの発生を防止でき、再配線RMの異常エッチングを防止することができる。
 上記工程の後、実施の形態1のキャップ金属膜CMの形成工程が続く。
 <変形例2>
 図15は、本実施の形態1の変形例2である半導体装置の製造工程中の断面図である。
 半導体チップ1Cの製造方法では、図8を用いて説明したシード膜RM1の除去工程と、図9を用いて説明したキャップ金属膜CMの形成工程との間に、再配線RMの肩部または側面全体を丸める工程を追加する。具体的には、再配線RMにリフロー(熱処理)を施すことにより、肩部が丸くなった再配線RMbとすることができる。例えば、水素(H)プラズマ処理や水素(H)雰囲気で300℃~450℃程度の温度でアニールすることにより再配線RMの銅膜の表面の酸化膜を還元した上で、300℃~450℃でアニールして銅膜をリフローする。また、再配線RMbは、シード膜RM1bとメッキ膜RM2bの積層構造となっている。
 再配線RMの肩部が丸くなり、側面が滑らかになることで、キャップ金属膜CMの被覆性が向上し、キャップ金属膜CMの不連続部またはピンホールに起因する、再配線RMの異常エッチングを防止することができる。
 上記工程の後、実施の形態1のキャップ金属膜CMの形成工程が続く。
 <変形例3>
 図16は、本実施の形態1の変形例3である半導体装置の製造工程中の断面図である。
 図16は、図4に示す半導体チップ1Aの変形例である半導体チップ1Dを示しており、半導体チップ1Aと異なる点は、表面保護膜10の上に下地絶縁膜11を介在させることなく再配線RMを配置している。下地金属膜UMは、パッド電極9aに接触して電気的に接続されており、表面保護膜10のパッド開口10aにおいて、表面保護膜10の側壁および上面に延在している。下地金属膜UMの下面は、表面保護膜10の上面に接している。再配線RMの下面に接する下地金属膜UMおよびキャップ金属膜CMは、実施の形態1と同様である。また、その他の構造、製造方法も実施の形態1と同様である。
 再配線RMの下面を下地金属膜UMで、上面および側面をキャップ金属膜CMで、完全に被覆し、張り出し部PPで下地金属膜UMとキャップ金属膜CMとが直接接触した構造としたことで、再配線RMを構成する銅が銅イオンとなって外部へ移動(拡散)するのを防止できる。また、保護膜12または封止体26に含まれる水分やハロゲンイオンなどにより再配線RMを構成する銅膜が酸化されるのを防止することができる。つまり、隣り合う再配線RM間の電気的信頼性を向上できるため、図4に示した下地絶縁膜11を省略することができる。
 再配線RMおよび表面保護膜の上に、有機膜からなる保護膜12を設けているので、半導体チップ1Dを、図13に示すように、シリカを含む封止体26で封止したとしても、封止体26と表面保護膜10とが接触することに起因する表面保護間膜10のクラックを防止することができる。
 また、上記のとおり、隣り合う再配線RM間の電気的信頼性を向上できるので、下地絶縁膜11だけでなく、保護膜12も省略しても良い。封止体26に水分やハロゲンイオンが含まれていたとしても、上記の構造としたことで、再配線RM中への水分やハロゲンイオンの侵入を防止することができる。
 <変形例4>
 図17は、本実施の形態1の変形例4である半導体装置の製造工程中の断面図である。
 図17は、図13で説明した実装工程の変形例である。半導体チップ1Aを、接着層39を介して配線基板30上に搭載し、再配線RMとボンディングフィンガ32とをワイヤ37で接続した後、配線基板30の上面側、半導体チップ1A、および、ワイヤ37を、封止体(封止樹脂)38で封止して、変形例4の半導体装置(半導体集積回路装置)が完成する。
 図17に示すように、配線基板30は、絶縁層からなるコア層31の上面には導体層からなる複数のボンディングフィンガ32を有し、下面には導体層からなる複数のランド33を有する。複数のボンディングフィンガ32間および複数のランド33間は、絶縁層からなるソルダレジスト35によって電気的に絶縁されている。さらに、ボンディングフィンガ32とランド33とは、コア層31に形成された導体層からなるビア内配線34を介して電気的に接続されており、ランド33には、半田からなるバンプ電極36が接続されている。さらに、封止体38は、熱硬化性エポキシ樹脂などからなり、シリカ(SiO2)等のフィラーを含有している。
 ワイヤ37の一端は、図4又は図16に示す半導体チップ1Aの再配線RMの上面に形成された外部パッド電極18に接続され、他端は、ボンディングフィンガ32に接続されている。ワイヤ27は、銅(Cu)ワイヤであるが、表面にパラジウム(Pd)を被覆した銅ワイヤ(PdコートCuワイヤ)、金ワイヤ(Auワイヤ)を用いても良い。
 また、外部パッド電極18とボンディングフィンガ32間をワイヤで電気的に接続する例を説明したが、再配線RMの上面の外部パッド電極18に半田ボールを形成し、半田ボールで外部パッド電極18とボンディングフィンガ32間を電気的に接続しても良い。その場合には、半導体チップ1Aの再配線RMが形成された側を、配線基板30の上面側に対向させて、外部パッド電極18とボンディングフィンガ32間を半田ボールで接続すると良い。
 なお、半導体チップ1Aに代えて、半導体チップ1B~1Fとしても良い。
(実施の形態2)
 実施の形態2は、実施の形態1の半導体装置の製造方法の変形例に対応している。
 図20および図21は、実施の形態2の半導体装置の製造工程中の断面図である。実施の形態1の半導体装置と区別するために、実施の形態2の半導体装置を半導体チップ1Eと表示している。実施の形態1の製造方法と共通する部分には同様の符号を付している。
 実施の形態1の図8を用いて説明したシード膜RM1の除去工程に続いて、シード膜RM1から露出した領域の下地金属膜UMを除去する。実施の形態1の製造方法とは異なり、シード膜RM1を除去後に、シード膜RM1から露出した領域の下地金属膜UMを完全に除去するため、下地金属膜UMのエッチング工程においてオーバーエッチが必須となる。つまり、図20に示すように下地金属膜UMaの端部が再配線RMの端部から後退するサイドエッチが発生し、下地金属膜UMaの端部から再配線RMが庇状にせり出した構造となる。つまり、再配線RMにせり出し部が出来、再配線RMと下地絶縁膜11との間に空間(スリット、ギャップ)が出来てしまう。再配線RMは、シード膜RM1とメッキ膜RM2の積層構造、下地金属膜UMaは、第1下地バリア膜UM1a、第2下地バリア膜UM2a、および、第3下地バリア膜UM3aの積層構造である。
 次に、再配線RMにエッチングを施し、再配線RMの側面が下地金属膜UMaの側面と一致するまで、または、下地金属膜UMaの側面よりも再配線RMの内部側となるまで再配線RMを削り込む。つまり、上記せり出し部をエッチングで除去する。こうして、図21に示すように、下地金属膜UMaの側面と一致した側面を有する再配線RMcを形成する。再配線RMcは、シード膜RM1cとメッキ膜RM2cの積層構造となっている。また、上記のとおり、再配線RMcの側面が、下地金属膜UMaの側面よりも再配線RMcの内部側となっている方が好ましい。
 なお、上記の下地金属膜UMに対するウェットエッチングは、例えば、アンモニア過水溶液を用いる。そして、再配線RMに対するエッチングは、ウェットエッチングまたはドライエッチングのどちらでも良い。
 上記エッチング工程の後に、実施の形態1のキャップ金属膜CMの形成工程以降の工程を実施して半導体チップ1Eを有する半導体装置が完成するが、上記せり出し部を除去しているので、キャップ金属膜CMの段切れに起因する再配線RMcの剥離を防止することができる。そして、キャップ金属膜CMの下面が、下地金属膜UMの側面または上面と接触する構造にできるので、再配線RMcを構成する銅膜の酸化または銅イオンの移動(拡散)を防止することができる。
 <変形例5>
 変形例5は、実施の形態2の半導体装置の製造方法の変形例に対応している。
 図22は、実施の形態2の変形例5である半導体装置の製造工程中の断面図である。実施の形態2の半導体装置と区別するために、変形例5の半導体装置を半導体チップ1Fと表示している。実施の形態1または2の製造方法と共通する部分には同様の符号を付している。
 実施の形態2において、図20を用いて説明した下地金属膜UMのエッチング工程の後に、再配線RMのせり出し部の下の空間を埋めるために再配線RMにスパッタエッチングを施す。図20に示す再配線RMに対して、アルゴン(Ar)スパッタエッチングを施すことで、図22に示すように、断面視にて、側面が順テーパとなった台形形状の再配線RMdを得ることができる。さらに、アルゴンスパッタエッチングの工程において、再配線RMcのせり出し部と下地絶縁膜11の間をリデポ物(再付着物)13で埋めることができる。再配線RMdは、シード膜RM1dとメッキ膜RM1dの積層構造である。
 上記スパッタエッチング工程の後に、実施の形態1のキャップ金属膜CMの形成工程以降の工程を実施して半導体チップ1Fを有する半導体装置が完成する、上記空間が埋まっているので、キャップ金属膜CMの段切れを防止することができ、再配線RMdの剥がれを防止することができる。
 以上、本発明者によってなされた発明を実施の形態に基づき具体的に説明したが、本発明は前記実施の形態に限定されるものではなく、その要旨を逸脱しない範囲で種々変更可能であることはいうまでもない。
 例えば、実施の形態2において、せり出し部をエッチング除去する代わりに、変形例2のリフローを施すことで、再配線RMのせり出し部と下地絶縁膜11との間の空間をなくすこともできる。また、実施の形態2または変形例5の半導体チップ1Eまたは1Fに、変形例4の実装工程を適用しても良い。
 その他、上記実施の形態に記載された内容の一部を以下に記載する。
 [付記1]
 (a)半導体基板の主面上にパッド電極を形成する工程、
 (b)前記パッド電極上に開口を有する第1絶縁膜を形成する工程、
 (c)前記第1絶縁膜上に、前記開口を介して前記パッド電極に電気的に接続する下地金属膜を形成する工程、
 (d)前記下地金属膜上に、前記下地金属膜を介して前記パッド電極に電気的に接続する再配線を形成する工程、
 (e)前記再配線の上面および側面を覆うキャップ金属膜を形成する工程、
 を有し、
 前記工程(d)は、
 (d-1)前記下地金属膜上に、前記下地金属膜を介して前記パッド電極に電気的に接続する前記再配線を形成する工程、
 (d-2)前記再配線から露出する領域の前記下地金属膜を完全にエッチングする工程、
 (d-3)その後、前記再配線をウエットエッチして後退させる工程、
 を含み、
 前記工程(e)は、
 (e-1)前記半導体基板の主面の全面上に、キャップバリア膜を形成する工程、
 (e-2)前記キャップバリア膜をパターニングすることによって、前記キャップ金属膜を形成する工程、
 を含む、半導体装置の製造方法。
[付記2]
 前記付記1に記載の半導体装置の製造方法において、
 前記再配線は、Cu膜からなり、前記パッド電極はAl膜からなる、半体装置の製造方法。
[付記3]
 前記付記1に記載の半導体装置の製造方法において、
 前記再配線の膜厚は、前記パッド電極の膜厚よりも厚く、前記パッド電極は複数の配線層の中で最も厚い、半導体装置の製造方法。
[付記4]
 半導体基板と、
 前記半導体基板上に形成された複数の配線層と、
 前記複数の配線層の最上層に形成されたパッド電極と、
 前記パッド電極上に開口を有する絶縁膜と、
 前記絶縁膜上に形成され、第1下面と第1上面を有する下地金属膜と、
 前記下地金属膜の前記第1上面に形成され、第2下面と第2上面と、側面とを有する再配線と、
 前記再配線の前記第2上面および前記側面を覆うように形成され、第3下面と第3上面を有するキャップ金属膜と、
 を有し、
 前記再配線は、第1平面パターンを有し、
 前記下地金属膜および前記キャップ金属膜は、前記第1平面パターンよりも大きい第2平面パターンを有し、
 前記再配線の外側において、前記下地金属膜の前記第1上面と前記キャップ金属膜の前記第3下面とは接している、半導体装置。
[付記5]
 前記付記4に記載の半導体装置において、
 前記第1平面パターンの全周囲において、前記第2平面パターンは、前記第1平面パターンよりも大きく、
 前記再配線の外側において、前記下地金属膜の前記第1上面と前記キャップ金属膜の前記第3下面とは接している、半導体装置。
CM キャップ金属膜
CM1、CM2、CM3 キャップバリア膜
PP 張り出し部
PR レジストマスク
p1、p2、p3 プラグ
P1 第1平面パターン
P2 第2平面パターン
Qn nチャネル型MISトランジスタ
Qp pチャネル型MISトランジスタ
RM、RMa、RMb、RMc、RMd、RMS、RMV 再配線
RM1 シード膜
RM2 メッキ膜
UM 下地金属膜
UMa、UM1、UM2、UM3 下地バリア膜
1A、1B、1C、1D、1E、1F 半導体チップ
1P 半導体基板
2P p型ウエル
2N n型ウエル
3 素子分離溝
3a 素子分離絶縁膜
4,6,8 層間絶縁膜
5、7、9 Al配線
9a パッド電極
10 表面保護膜
10a パッド開口
11 下地絶縁膜
11a 開口
12 保護膜
13 再付着物
18 外部パッド電極
25D ダイパッド部
25L リード
26、38 封止体
27、37 ワイヤ
30 配線基板
31 コア層
32 ボンディングフィンガ
33 ランド
34 ビア内配線
35 ソルダレジスト
36 バンプ電極
39 接着層

Claims (19)

  1.  半導体基板と、
     前記半導体基板上に形成された複数の配線層と、
     前記複数の配線層の最上層に形成されたパッド電極と、
     前記パッド電極上に開口を有する絶縁膜と、
     前記絶縁膜上に形成された下地金属膜と、
     前記下地金属膜上に形成された再配線と、
     前記再配線の上面および側面を覆うように形成されたキャップ金属膜と、
     を有し、
     前記再配線の外側の領域において、前記再配線の側壁上に形成された前記キャップ金属膜と前記絶縁膜との間には、前記下地金属膜が形成されており、
     前記再配線と前記下地金属膜は別材料で形成されており、
     前記再配線と前記キャップ金属膜は別材料で形成されており、
     前記再配線の外側の領域において、前記下地金属膜と前記キャップ金属膜とが直接接している、半導体装置。
  2.  請求項1に記載の半導体装置であって、
     前記再配線の外側の領域に存在する前記下地金属膜の膜厚と前記キャップ金属膜の膜厚の和は、前記再配線の下の前記下地金属膜の膜厚よりも厚い、半導体装置。
  3.  請求項1に記載の半導体装置であって、
     前記キャップ金属膜は、第1キャップバリア膜、第2キャップバリア膜を含む積層膜で形成されており、
     前記第1キャップバリア膜はTi膜であり、
     前記第2キャップバリア膜はPd膜であり、
     前記下地金属膜はTi膜およびTiN膜を含む積層膜である、半導体装置。
  4.  請求項1に記載の半導体装置であって、
     前記再配線はCuを主成分として構成されており、
     前記パッド電極はAlを主成分として構成されており、
     前記再配線の膜厚は前記パッド電極の膜厚よりも厚い、半導体装置。
  5.  請求項3に記載の半導体装置において、
     前記再配線の上に形成された前記第2キャップ金属膜上に、銅ワイヤを有する、半導体装置。
  6.  (a)複数の配線層と、前記複数の配線層の最上層に形成されたパッド電極とを有する半導体基板を準備する工程、
     (b)前記パッド電極上に第1開口を有する第1絶縁膜を形成する工程、
     (c)前記第1絶縁膜上に、前記第1開口を介して前記パッド電極に電気的に接続する下地金属膜を形成する工程、
     (d)前記下地金属膜上に、前記下地金属膜を介して前記パッド電極に電気的に接続する再配線を形成する工程、
     (e)前記再配線の上面および側面を覆うキャップ金属膜を形成する工程、
     を有し、
     前記工程(e)は、
     (e‐1)前記半導体基板の主面上に、キャップ金属材料膜を形成する工程と、
     (e‐2)前記第1絶縁膜上の前記キャップ金属材料膜をエッチングすることにより、前記キャップ金属膜を形成する工程と、を含み、
     前記工程(e‐2)における前記エッチングは、前記下地金属膜の一部が前記再配線の外側の領域に存在する状態において施され、
     前記工程(e‐2)の後では、前記再配線の外側の領域において、前記下地金属膜と前記キャップ金属膜とが直接接している、半導体装置の製造方法。
  7.  請求項6に記載の半導体装置の製造方法において、
     前記再配線と前記下地金属膜は別材料で形成されており、
     前記再配線と前記キャップ金属膜は別材料で形成されている、半導体装置の製造方法。
  8.  請求項6に記載の半導体装置の製造方法において、
     前記キャップ金属材膜料は、第1キャップバリア膜、第2キャップバリア膜および第3キャップバリア膜を含む積層膜で形成されており、
     前記下地金属膜と前記第3キャップバリア膜は同じ材料を含む、半導体装置の製造方法。
  9.  請求項6に記載の半導体装置の製造方法において、
     前記工程(d)は、
     (d‐1)前記下地金属膜上にシード膜を形成する工程と、
     (d‐2)前記シード膜上に前記シード膜の一部を露出するレジストパターンを形成する工程と、
     (d‐3)前記レジストパターンから露出する前記シード膜上に電気メッキにより前記再配線を形成する工程と、
     (d‐4)前記レジストパターンを除去する工程と、
     (d‐5)前記再配線の外側の領域の前記シード膜を除去する工程と、
     を含み、
     前記工程(e)において、
     前記キャップ金属膜は、前記シード膜の側面を覆うように形成される、半導体装置の製造方法。
  10.  請求項6に記載の半導体装置の製造方法において、
     前記工程(e-2)は、前記下地金属膜のウエットエッチをおこなう工程を含む、半導体装置の製造方法。
  11.  請求項6に記載の半導体装置の製造方法において、
     前記再配線はCuを主成分として構成されており、
     前記パッド電極はAlを主成分として構成されており、
     前記再配線の膜厚は前記パッド電極の膜厚よりも厚い、半導体装置の製造方法。
  12.  請求項6に記載の半導体装置の製造方法において、
     前記第1絶縁膜と前記パッド電極の間には第2絶縁膜が形成されており、
     前記第2絶縁膜は、前記第1絶縁膜の前記第1開口内に、前記第1開口より小さい第2開口を有する、半導体装置の製造方法。
  13.  請求項6に記載の半導体装置の製造方法において、さらに、
     前記工程(e)の後、前記キャップ金属膜上に第3開口を有する第3絶縁膜を形成する工程、を有し、
     前記第1絶縁膜と前記第3絶縁膜の夫々は、ポリイミド膜を含む、半導体装置の製造方法。
  14.  請求項6に記載の半導体装置の製造方法において、
     前記再配線の上の前記キャップ金属膜に、銅ワイヤを接続する、半導体装置の製造方法。
  15.  請求項6に記載の半導体装置の製造方法において、さらに、
     前記工程(d)の後であって、前記工程(e)の前に、
     前記下地金属膜を一部エッチングする工程を有する、半導体装置の製造方法。
  16.  (a)半導体基板を準備する工程、
     (b)前記半導体基板上に絶縁膜を形成する工程、
     (c)前記絶縁膜上に、下地金属膜を形成する工程、
     (d)前記下地金属膜上に、再配線を形成する工程、
     (e)前記再配線の上面および側面を覆うように、前記絶縁膜上に、第1キャップバリア膜、第1キャップバリア膜、および、第1キャップバリア膜を順番に形成する工程、
     (f)レジストマスクを用いて、前記再配線の上面上および側面上に前記第3キャップバリア膜を残しつつ、前記絶縁膜上に形成された前記第3キャップバリア膜をパターニングする工程と、
     (g)前記レジストマスクを除去する工程と、
     (h)パターニングされた前記第3キャップバリア膜をマスクとして、前記絶縁膜上に形成された前記第2キャップバリア膜をエッチングする工程と、
     (i)前記再配線の上面上および側面上の前記第3キャップバリア膜をエッチングすると共に、前記絶縁膜上の前記第1キャップバリア膜および前記下地金属膜をエッチングする工程と、
    を有する、半導体装置の製造方法。
  17.  請求項16に記載の半導体装置の製造方法において、
     前記工程(i)後に、前記再配線の外側の領域であって、且つ、前記絶縁膜上の領域には、前記下地金属膜と前記第1キャップバリア膜が存在しており、
     前記再配線の外側の領域に存在する前記下地金属膜の膜厚と前記第1キャップバリア膜の膜厚の和は、前記再配線下の前記下地金属膜の膜厚よりも厚い、半導体装置の製造方法。
  18.  請求項16に記載の半導体装置の製造方法において、
     前記第1、第2および第3キャップバリア膜は、それぞれTi膜,Pd膜およびTi膜であり、
     前記下地金属膜は、Ti膜,TiN膜およびTi膜を含む積層膜である、半導体装置の製造方法。
  19.  請求項16に記載の半導体装置の製造方法において、
     前記(i)工程の後、前記再配線の上面に形成されている前記第2キャップバリア膜は露出しており、
     前記(i)工程の後に、更に、
     (j)前記第2キャップバリア膜上に、銅ワイヤを形成する工程、
    を有する、半導体装置の製造方法。
     
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