WO2004014136A1 - 顆粒状農薬組成物 - Google Patents
顆粒状農薬組成物 Download PDFInfo
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- WO2004014136A1 WO2004014136A1 PCT/JP2003/010000 JP0310000W WO2004014136A1 WO 2004014136 A1 WO2004014136 A1 WO 2004014136A1 JP 0310000 W JP0310000 W JP 0310000W WO 2004014136 A1 WO2004014136 A1 WO 2004014136A1
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- composition
- salt
- sulfonation
- sodium
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/52—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing groups, e.g. carboxylic acid amidines
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
- A01N25/14—Powders or granules wettable
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
Definitions
- the present invention relates to a granular pesticidal composition excellent in dispersibility and stability in water, and particularly to a granular pesticidal composition containing cyflufenamide and an EBI agent as active ingredients.
- emulsions include toxicity, irritability, flammability, odor, etc. because they use organic solvents as carriers.
- hydrating agent is a finely powdered formulation, it is inconvenient to measure it, and the fine powder may soar during the preparation of the spray liquid, which may affect the safety of workers. It has become.
- flowables are suspension-type preparations, which eliminate the inconvenience of weighing wettable powders and the problem of powdering.However, because they are viscous liquid preparations, they are difficult to remove from containers. Since a small amount of the drug remains in the container, it may be difficult to dispose of the container, and these are problems.
- attempts have been made to granulate wettable powders (granular wettable powders). That is, by making the wettable powder into granules, the difficulty in powdering and measuring the wettable powder is improved.
- the hardness of the granule may generally be increased, which may cause a lack of efficacy due to a decrease in disintegration in water.
- the same level of disintegration in water as that of a wettable powder is to be imparted, there arises a problem that the hardness of the grains becomes low and the grains are easily powdered.
- the amount of fine powder in the preparation increases, and the sprayer easily sucks and scatters the powder outside the spray area when spraying, resulting in the same problems as conventional wettable powders.
- granulation of wettable powders has been studied a lot, and the following granular wettable powders are known. That is, a granular pesticide wettable powder containing a water-soluble inorganic salt such as starch and ammonium sulfate as the pesticidal active ingredient (Japanese Patent Application Laid-Open No. 51-16949), a plant protectant and a specific solid wetting agent And water-dispersible granules which form a good suspension (Japanese Unexamined Patent Publication (Kokai) No. 3-193702), a water-soluble pesticidal active ingredient, lactose and a surfactant.
- a granular pesticide wettable powder containing a water-soluble inorganic salt such as starch and ammonium sulfate as the pesticidal active ingredient
- Japanese Patent Application Laid-Open No. 51-16949 Japanese Patent Application Laid-Open No. 51-16949
- a water-soluble pesticidal granule comprising the following as essential ingredients (Japanese Patent Application Laid-Open No. 6-92083), and a novel composition containing an agrochemical active ingredient and diatomaceous earth, and preferably further containing a surfactant And a wettable powder made by extrusion granulation (Japanese Patent Application Laid-Open No. 6-128102).
- the following are examples of solid preparations using starch hydrolysates.
- a pesticidal composition in the form of powder JP-A-60-36402
- a pesticidal active ingredient having a melting point of 70 or less a surfactant, dextrin, and / or lactose and water. It is a pesticidal solid emulsion containing a spray-dried product of an aqueous emulsion containing the following as an essential component (Japanese Patent Application Laid-Open No. 3-471103).
- Examples of the granular pesticidal composition containing sodium ligninsulfonate include a water-dispersible granular pesticidal composition containing a ligninsulfonic acid, a formalin condensate of naphthalenesulfonic acid, and a surfactant such as an alkyl sulfate.
- Ru-Ichi-Rupoxamide is an agricultural chemical composition dispersed and emulsified in water containing a ligninsulfonic acid surfactant having a sulfonation degree of 2.5 or less (Japanese Patent Application Laid-Open No. 7-17881). No.
- a wettable powder or a granular wettable powder characterized by containing one or more pesticidal active ingredients and a high-purity partially desulfonated ligninsulfonate JP-A-8-347700 No. 2
- a wettable powder comprising an active ingredient of agrochemicals, lignin sulfonate, polyoxyethylene alkyl ether sulfate and water-soluble inorganic salt
- composition in which a sulfate salt or a phosphate salt of a polyoxyalkylene arylphenyl ether and sodium ligninsulfonate having a high degree of sulfonation are simultaneously added.
- the conventional granular pesticide composition has good disintegration in water but is easily powdered, or when hard to disintegrate, it has low disintegration in water and was not sufficiently satisfactory.
- granular pesticidal compositions with low disintegration in water have poor hydratability and dispersibility, so that a complete dispersion cannot be obtained even with sufficient stirring, and the sedimentation amount is large and the properties as a wettable powder are sufficient. Over time, there was a problem that the hydration and dispersibility became worse and the amount of sedimentation increased with time.
- the present invention provides a granular pesticidal composition which is hard to be powdered, hydrates and disperses immediately upon pouring the pesticidal composition into water at the time of preparation of a chemical solution, and is slow in sedimentation.
- an object is to provide a composition containing cyflufenamide as an active ingredient.
- the present invention contains an agrochemical active ingredient, a ligninsulfonic acid-based surfactant having a degree of sulfonation of 2.0 or more, and a polyoxyalkylene arylphenol sulfate salt or phosphite salt.
- the present invention provides a granular pesticidal composition characterized by the above characteristics, and particularly provides a composition containing cyflufenamide and triflumizole as pesticidal active ingredients.
- Lignin sulfonic acid type surfactants with low sulfonation degree are polar groups. Due to the small amount of the carboxylic acid residue, the dissolution rate in water is slow, the adsorption ability to solid particles is poor, and the dispersing performance may be poor. On the other hand, ligninsulfonic acid-based surfactants with a high degree of sulfonation have a very high dissolution rate in water, and have a very high ability to disperse solids because the sulfonic acid groups are strongly adsorbed on the solid surface. By using this surfactant in combination with the sulfate salt and the phosphate salt of polyoxyalkylene arylphenyl ether, it is possible to obtain a stable and well-dispersed agricultural chemical composition.
- the lignin sulfonic acid surfactant having a degree of sulfonation of 2.0 or more used in the present invention refers to an average number of sulfonic acid groups in one unit of lignin when the molecular weight of one unit is 1,000.
- 2.0 or more, usually 2 to 6 means a ligninsulfonic acid-based surfactant.
- the ligninsulfonic acid-based surfactant is generally an alkali metal salt such as a potassium salt or a sodium salt of ligninsulfonic acid, a calcium salt, or the like. Alkaline earth metal salts.
- POL YF ⁇ NT degree of sulfonation 2.0
- POLYFON F degree of sulfonation 4.0
- REAX80 C degree of sulfonation 2.0
- REAX manufactured by West Vac 0 82 degree of sulfonation 2.0
- REAX 83A degree of sulfonation 2.1
- REAX88 B degree of sulfonation 3.8
- REAX 100 ⁇ degree of sulfonation 4.7
- REAX45 DA degree of sulfonation
- REAX45DTC degree of sulfonation 3.8
- PC-825 degree of sulfonation 4.6
- PC_876A degree of sulfonation 2.4
- ligninsulfonic acid-based surfactants are used alone or in combination of two or more, and the amount of the ligninsulfonic acid-based surfactant is such that the pesticidal active ingredient can be dispersed. It is used in the composition of the present invention in an amount of 1 to 15% by weight, preferably about 2 to 10% by weight.
- a polyoxyalkylene group part has a polymerization degree of 2 to 50, preferably a polyoxyethylene group having a polymerization degree of 4 to 30; Polyoxypropylene, polyoxybutylene, etc.
- a monoaryl group having 6 to 40 carbon atoms such as a phenyl group, a naphthyl group, and a styryl group; a mono-, di-, or tri-substituted product; and a salt such as an alkali metal salt such as potassium or sodium; Examples thereof include those which are alkaline earth metal salts such as calcium and magnesium, ammonium salts, alkanolamine salts such as monono, di- or triethanolamine salts.
- These sulfate salts and phosphate salts of these polyoxyalkylene arylphenyl ethers may be used alone or in combination of two or more. As much as possible, more specifically, about 0.1 to 15% by weight, preferably about 0.5 to 10% by weight in the composition of the present invention.
- the wettable powder of the present invention may contain one or more kinds of pesticidal active ingredients.
- Fungicides include triflumizole, tebuconazole, fenprovidin, bromconazole, cyproconazole, diphenoconazole, fen buconazole, flusilazole, flutriahole, hexaconazole, propiconazol, tetraconazole, triadimezole, Triadimenol, Vitelnool, Imibenconazole, Diniconazole, Fenpropimorph, Tridemorph, Epoxyconazole, Fluquinconazole, Poutachloraz, Methoconazole, Azoxystrobin, Isoprothiolane, Iprodione, Iminoctazine Al Besylate, oxolinic acid, captan, 'cresoxime methyl, dietofencarp, streptomycin, lime-sulfur mixture, dazomet, thiuram, thiophane Methyl, triazine
- insecticides include acetamiprid, acephate, imidacloprid, ethylthiomethone, ethoxazole, ethofenprox, emamectin benzoate, chlorpicrin, chlorphenavir, fenbutatin oxide, spinosad, spinosad, cycloprothrine, methylbromide tartrate, and methyl tartrate bromide.
- Daia Examples include dinone, tralomethrin, bifenthrin, fipronil, fenpropatrin, flufenoxuron, hexthiazox, benfracarp, mil bemectin, mesomil, DD, DDVP, DMTP, MEP, and the like.
- Herbicides include aioxell, chlorate, glyphosate isopropylamine salt, dalfosinate, trifluralin, bialaphos, pretilachlor, pendimethalin and the like.
- the amount of these pesticidal active ingredients to be added to the preparation is not particularly limited, and is generally 0.1 to 90% by weight, preferably 0.1 to 60% by weight of the whole preparation. is there.
- composition of the present invention may contain other surfactants, binders and carriers in addition to the above two surfactants.
- Surfactants that can be blended include nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants. Specifically, the following can be blended.
- nonionic surfactants include polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyoxyethylene styrene phenyl ether, polyoxyethylene alkyl ester, polyoxyethylene sorbitan alkylate, Polyoxyethylene phenyl ether polymer, polyoxyethylene alkylene aryl phenyl ether, polyoxyethylene alkylene glycol, polyoxyethylene polyoxypropylene block polymer, polyoxyethylene vegetable oil ether, etc. .
- anionic surfactants include alkylaryl sulfonates such as sodium alkylarylsulfonate, calcium alkylarylsulfonate and ammonium alkylarylsulfonate; alkyls such as sodium dialkylsulfosuccinate and sodium alkylnaphthalenesulfonate. Naphthalene sulfonate, formaldehyde polycondensate of naphthalene sulfonate, polycarboxylate and the like can be mentioned.
- the cationic surfactant include an alkyl quaternary ammonium salt, an alkylamine salt, and an alkylpyridinium salt.
- amphoteric surfactant examples include alkyl betaine and amine oxide.
- the surfactants that can be blended in the present invention are not limited to these, and one or more of these can be used in combination.
- the amount of these surfactants to be added is not particularly limited, but is preferably 0.1 to 30 parts by weight in the preparation from the viewpoint of effect and economy.
- the binder that can be blended in the present invention is not particularly limited, and examples thereof include the following.
- Examples include bean gum, gum arabic, oxan gum, gelatin, casein, polyvinyl alcohol, polyethylene oxide, polyethylene glycol, ethylene-propylene block polymer, sodium polyacrylate, polypyrrolidone, and carrageenan.
- the amount of these binders to be added is not particularly limited, but is preferably 0.1 to 40 parts by weight from the viewpoint of effect and economy.
- the carrier that can be blended in the present invention may be an inorganic carrier or an organic carrier.
- the inorganic carrier include clay, bentonite, talc, calcium carbonate, calcium sulfate, and sodium carbonate. , Zeekrite, sericite, acid clay, silica stone, diatomaceous earth, pumice, zeolite, vermiculite, potassium chloride, urea, white carbon, ammonium sulfate, sodium sulfate, perlite, magnesium sulfate, etc.
- examples include glucose, maltose, sucrose, lactose, starch and the like.
- One or more of these inorganic or organic carriers Or two or more types can be used in combination.
- an inorganic carrier and an organic carrier can be used in combination.
- the pesticidal composition according to the present invention may further contain an auxiliary agent in addition to the above-mentioned components.
- an auxiliary agent in addition to the above-mentioned components.
- it can contain a preservative and a fungicide, and a solvent.
- an antioxidant, an ultraviolet ray inhibitor, a crystallization inhibitor and the like can be added as a stabilizer for the pesticidal active ingredient, as required.
- solvents that can be incorporated in the present invention include isoptyl adipate, dioleyl adipate, diisodecyl adipate, getylhexyl phthalate, didecyl phthalate, 2-ethylhexyl trimellitate, and triisodecyl trimellitate.
- Polybasic acid alcohol esters such as cetyl 2-ethylhexyl cetyl, cetyl coconut fatty acid, methyl laurate, methyl myristate, methyl oleate, octyl oleate, sorbitan monolaurate, sorbitan Polyalcohol fatty acid esters such as monooleate, higher alcohols such as octyl alcohol and lauryl alcohol, 1,2-dimethyl-4-ethylbenzene, methylnaphthalene, 1-phenyl-1-xylylethane, 1-xylyl-1 Aromatic hydrocarbons such as 3,3-diphenylbutane can be blended.
- fatty acid alcohol esters such as cetyl 2-ethylhexyl cetyl, cetyl coconut fatty acid, methyl laurate, methyl myristate, methyl oleate, octyl oleate, sorbitan monolaurate, sorbitan Polyal
- the method for preparing the pesticidal composition according to the present invention is not particularly limited, but can be prepared by the following method.
- the pesticidal active ingredient is mixed with a surfactant, a binder, and a carrier and, if necessary, an auxiliary agent such as an antiseptic / fungicide or a stabilizer for the pesticide active ingredient, and then mixed with an air crusher or the like.
- the pulverized pesticide composition is obtained by crushing with a crusher.
- Water may be added to the powdery pesticide composition thus obtained, kneaded, granulated by an extrusion granulator, dried and sized.
- the mixture may be granulated with a tumbling granulator while adding water, and dried and sized.
- the wettable pesticide composition before water addition may be dispersed in water and granulated by a spray granulator, and a binder solution or a pesticidally active ingredient may be sprayed while the powder mixture is fluidized.
- the granulation may be carried out by a fluidized bed granulator.
- Granular pesticide composition according to the present invention The particle size of the product is about the same as that of a conventional granular preparation, and specifically, it is desirable to be in the range of 0.1 to 2 mm.
- the pesticidal composition of the present invention can be in the form of powder, granules and water suspension, but is not particularly limited to these shapes.
- Example 1 Clay of Example 1 6 1.2 parts 60.2 parts Sodium ligninsulfonate 5.25 parts to 6 parts, enilrue monosulfate ammonium salt 1.75 parts to 2 parts The same operation as in Example 1 was performed to obtain a granular pesticide composition.
- Example 1 Clay of Example 1 61.2 parts in 59.2 parts, sodium ligninsulfonate 5.25 parts in 6.75 parts, polyoxyethylene tristyrylphen The same operation as in Example 1 was performed, except that 1.75 parts of nitrousulfate ammonium salt was replaced with 2.25 parts, to obtain a granular pesticide composition.
- Clay of Example 1 61.2 2 parts in 58.2 parts, sodium ligninsulfonate 5.25 parts in 7.5 parts, polyoxyethylene tristyrylphenyl tersulfate ammonium salt 1. The same operation as in Example 1 was performed, except that 75 parts was replaced with 2.5 parts, to obtain a granular pesticide composition.
- Example 4 The same operation as in Example 1 was performed, except that sodium dodecylbenzenesulfonate of Example 4 was replaced with sodium alkylnaphthalenesulfonate, to obtain a pesticidal pesticidal composition.
- Example 2 Lignin sulfonate sodium having a degree of sulfonation of 4.7 used in Example 1 was replaced with sodium lignin sulfonate having a degree of sulfonation of 4.0 (manufactured by West Vaco; P ⁇ L YF ON-F). The same operation as in Example 1 was performed to obtain a granular pesticide composition.
- Example 3 The polyoxyethylene (degree of polymerization 9) tristyrylphenyl ether sulfate ammonium salt of Example 2 was replaced with a polyoxyethylene (degree of polymerization 14) tristyrylphenyl ether sulfate ammonium salt. The same operation as in 1 was performed to obtain a granular pesticide composition.
- Example 1 was repeated except that the polyoxyethylene (degree of polymerization 9) tristyrylphenyl ether sulfate ammonium salt of Example 2 was replaced with a polyoxyethylene (degree of polymerization 7) tristyrylphenyl ether sulfate ammonium salt. The same operation as described above was performed to obtain a granular pesticide composition.
- the polyoxyethylene (degree of polymerization 9) tristyrylphenyl ether sulphate ammonium salt of Example 2 was converted to polyoxyethylene (degree of polymerization 4)
- the same operation as in Example 1 was performed, except that the styrylphenyl ether sulfate ammonium salt was used, to obtain a granular pesticide composition.
- Example 2 The same operation as in Example 1 was performed, except that cyflufenamide of Example 2 was replaced with clay, to obtain a granular pesticidal composition.
- Example 2 The same as in Example 1 except that the polyoxyethylene (degree of polymerization 9) tristyryl tersulfate ammonium salt of Example 2 was replaced with a polyoxyethylene (degree of polymerization 14) tristyril phenyl terephthalate potassium salt. The operation was performed to obtain a granular pesticide composition.
- Example 2 Same as Example 1 except that sodium ligninsulfonate having a degree of sulfonation of 4.7 used in Example 1 was replaced by sodium ligninsulfonate having a degree of sulfonation of 2.0 (manufactured by West Vaco; POLYFON-T) was performed to obtain a granular pesticidal composition.
- Clay of Example 1 61.2 parts to 54.2 parts, sulfonation degree 4.7 sodium lignin sulfonate 5.25 parts to 0.5 degree sulfonation degree 0.5 sodium lignin sulfonate (West Vaco POLYFON—H) 1 4 parts, sodium dodecylbenzenesulfonate replaced with sodium alkylnaphthalenesulfonate, polyoxyethylenetristyrylphenylethersulfonammonium salt 1.75 parts to 0 parts The operation was performed in the same manner as in Example 1 except that a granular pesticidal composition was obtained.
- Example 2 The same operation as in Example 1 was performed, except that potassium chloride in Comparative Example 1 was replaced with sodium chloride, to obtain a granular pesticide composition.
- Example 2 The same operation as in Example 1 was carried out, except that REAX 910) was used, to obtain a granular pesticidal composition.
- Example 2 The same operation as in Example 1 was performed, except that 10 parts of potassium chloride in Comparative Example 3 was replaced with 5 parts of potassium chloride and 5 parts of calcined diatomaceous earth, to obtain a granular pesticide composition.
- Example 6 6 parts of sodium ligninsulfonate of Example 2 and 2 parts of polyoxyethylene tristyryl phenyl ether sulfate ammonium salt were mixed with 8 parts of sodium polyruponate (Rerodia Nika, Geropon T-36). And performing the same operation as in Example 1 to obtain a granular pesticidal composition. Comparative Example 6
- Example 2 The same operation as in Example 1 was performed, except that sodium polyliponate of Comparative Example 5 was replaced with sodium ligninsulfonate having a sulfonation degree of 4.7 in Example 1, to obtain a granular pesticidal composition.
- Example 2 The same operation as in Example 1 was performed, except that the sodium polyrutroponate of Comparative Example 5 was replaced with sodium ligninsulfonate of Example 6 having a degree of sulfonation of 4.0, to obtain a granular pesticide composition.
- Example 2 The same operation as in Example 1 was performed, except that the sodium polycarboxylate of Comparative Example 5 was replaced with sodium ligninsulfonate of Comparative Example 3 having a sulfonation degree of 1.7, to obtain a granular pesticide composition.
- Example 10 The same operation as in Example 1 was performed, except that the sodium polyrutroponate of Comparative Example 5 was replaced with sodium lignin sulfonate having a sulfonation degree of 1.2 (manufactured by West Vaco; PQLYFON- ⁇ ). A composition was obtained. Comparative Example 10
- Example 2 The same operation as in Example 1 was performed, except that the sodium polycarboxylate of Comparative Example 5 was replaced with sodium ligninsulfonate of Comparative Example 1 having a degree of sulfonation of 0.5. Then, a granular pesticide composition was obtained.
- Example 4.7 The sodium ligninsulfonate having a degree of sulfonation of Example 4.7 and the sodium ligninsulfonate having a degree of sulfonation 0.5 of Example 1 were replaced with sodium ligninsulfonate 0.5, and the same operation as in Example 1 was carried out to obtain a granular pesticide composition.
- Example 2 The same operation as in Example 1, except that the sodium ligninsulfonate having a degree of sulfonation of 4.7 in Example 2 was replaced with sodium ligninsulfonate having a degree of sulfonation of 1.2 (manufactured by Westvaco; POL YFON-O) was performed to obtain a granular pesticide composition.
- Example 2 The same operation as in Example 1 was performed, except that cyflufenamide in Comparative Example 12 was replaced with clay, to obtain a granular pesticidal composition.
- the pesticidal composition of the present invention was gently poured into distilled water, the state of disintegration until the composition sank to the bottom was observed, and the quality was judged according to the following criteria.
- the pesticide composition of the present invention was gently poured into distilled water.After 30 seconds, the test tube was repeatedly inverted and reverted once every two seconds, and the number of times of inversion until the composition completely collapsed was repeated. It was measured.
- the test tube was repeatedly turned over and restored once every 2 seconds 30 times, and the sedimentation amount (mL) was measured 30 minutes later.
- Self-collapse Underwater collapse Sedimentation amount Self-collapse Underwater collapse Sedimentation amount Number of falls (30 min) Sex Fall (30 min)
- Example 1 ⁇ 2 0.01 ⁇ 4 0.01
- Example 2 ⁇ 2 0.01 ⁇ 4 0.01
- Example 3 ⁇ 2 0.01 ⁇ 4 0.01 0.01
- Example 4 ⁇ 3 0.01 ⁇ 5 ⁇ 0.01
- Example 5 ⁇ 4 0.01 ⁇ 5 0.01 0.01 0.01
- Example 6 ⁇ 3 0.01 0.01 ⁇ 3 0.01 0.01
- Example 7 ⁇ 3 0.01 0.01 ⁇ 3 0.01 0.01 0.01
- Example 8 ⁇ 3 0.01 0.01 ⁇ 3 0.01 0.01
- Example 9 ⁇ 3 0.01 0.01 ⁇ 3 0.01 0.01
- Example 10 ⁇ 2 0.01 ⁇ 3 0.01
- Example 11 ⁇ 2 0.01 ⁇ 5 0.01
- Example 12 ⁇ 2 0.01 ⁇ 3 0.01
- Comparative example 1 ⁇ 1 ⁇ 2 0.01 mm 17 0.3 Comparative example 2 ⁇ 1 0.01 ⁇ 4 0.3 Comparative example 3 X 10 0.01 X 11 0.2 Comparative example 4 ⁇ 5 0.03 X 12 0.2 Compar
- the pesticidal composition of the present invention has good hydration and dispersibility at the time of preparation of a chemical solution, has a small amount of sedimentation, is easy to prepare a chemical solution, and further has little change over time in dilution properties, and is sprayed.
- the liquor adheres to the crops evenly and provides a stable biological control effect.
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- General Health & Medical Sciences (AREA)
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- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
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Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MXPA05001429A MXPA05001429A (es) | 2002-08-07 | 2003-08-06 | Composicion agroquimica en forma granulada. |
US10/523,106 US8163674B2 (en) | 2002-08-07 | 2003-08-06 | Agricultural chemical composition in granular form |
BRPI0313257-9A BR0313257B1 (pt) | 2002-08-07 | 2003-08-06 | Composição pesticida granulada |
AU2003254824A AU2003254824B2 (en) | 2002-08-07 | 2003-08-06 | Granulated pesticidal composition |
JP2004527344A JP4850414B2 (ja) | 2002-08-07 | 2003-08-06 | 顆粒状農薬組成物 |
CA002494289A CA2494289C (en) | 2002-08-07 | 2003-08-06 | Granulated pesticidal composition |
EP03784542A EP1552743A4 (en) | 2002-08-07 | 2003-08-06 | AGRICULTURAL CHEMICAL COMPOSITION IN GRANULAR FORM |
IL166607A IL166607A (en) | 2002-08-07 | 2005-01-31 | Granule fungicide formulation |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002/229632 | 2002-08-07 | ||
JP2002229632 | 2002-08-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2004014136A1 true WO2004014136A1 (ja) | 2004-02-19 |
Family
ID=31711660
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2003/010000 WO2004014136A1 (ja) | 2002-08-07 | 2003-08-06 | 顆粒状農薬組成物 |
Country Status (13)
Country | Link |
---|---|
US (1) | US8163674B2 (ja) |
EP (1) | EP1552743A4 (ja) |
JP (1) | JP4850414B2 (ja) |
CN (1) | CN100508750C (ja) |
AR (1) | AR040813A1 (ja) |
AU (1) | AU2003254824B2 (ja) |
BR (1) | BR0313257B1 (ja) |
CA (1) | CA2494289C (ja) |
IL (1) | IL166607A (ja) |
MX (1) | MXPA05001429A (ja) |
TW (1) | TW200406149A (ja) |
WO (1) | WO2004014136A1 (ja) |
ZA (1) | ZA200501014B (ja) |
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JP2009184969A (ja) * | 2008-02-06 | 2009-08-20 | Sds Biotech Corp | 農薬粒剤 |
JP2010006802A (ja) * | 2008-05-28 | 2010-01-14 | Sumitomo Chemical Co Ltd | 顆粒状農薬製剤 |
CN102578129A (zh) * | 2012-02-06 | 2012-07-18 | 山东禾宜生物科技有限公司 | 一种防治香蕉叶斑病的杀菌剂 |
US8273685B2 (en) | 2006-08-10 | 2012-09-25 | Nippon Soda Co., Ltd. | Agrochemical composition |
EP2269452A4 (en) * | 2008-04-25 | 2013-10-23 | Nippon Soda Co | GRANULAR PESTICIDE COMPOSITION AND METHOD FOR PRODUCING THE SAME |
WO2014003438A1 (ko) * | 2012-06-26 | 2014-01-03 | 주식회사 경농 | 무기염을 포함하는 유화가능한 고상 농약 조성물의 제조방법 |
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- 2003-08-06 WO PCT/JP2003/010000 patent/WO2004014136A1/ja active Application Filing
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- 2003-08-06 EP EP03784542A patent/EP1552743A4/en not_active Withdrawn
- 2003-08-06 ZA ZA200501014A patent/ZA200501014B/en unknown
- 2003-08-06 MX MXPA05001429A patent/MXPA05001429A/es active IP Right Grant
- 2003-08-06 CA CA002494289A patent/CA2494289C/en not_active Expired - Lifetime
- 2003-08-06 JP JP2004527344A patent/JP4850414B2/ja not_active Expired - Lifetime
- 2003-08-06 BR BRPI0313257-9A patent/BR0313257B1/pt active IP Right Grant
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
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US8273685B2 (en) | 2006-08-10 | 2012-09-25 | Nippon Soda Co., Ltd. | Agrochemical composition |
WO2009063608A1 (ja) * | 2007-11-14 | 2009-05-22 | Nippon Soda Co., Ltd. | 乳剤組成物および農薬乳剤組成物 |
KR101211456B1 (ko) * | 2007-11-14 | 2012-12-12 | 닛뽕소다 가부시키가이샤 | 유제 조성물 및 농약 유제 조성물 |
JP2013224333A (ja) * | 2007-11-14 | 2013-10-31 | Nippon Soda Co Ltd | 乳剤組成物および農薬乳剤組成物 |
US9113626B2 (en) | 2007-11-14 | 2015-08-25 | Nippon Soda Co., Ltd. | Emulsion composition and agrochemical emulsion composition |
JP2009184969A (ja) * | 2008-02-06 | 2009-08-20 | Sds Biotech Corp | 農薬粒剤 |
EP2269452A4 (en) * | 2008-04-25 | 2013-10-23 | Nippon Soda Co | GRANULAR PESTICIDE COMPOSITION AND METHOD FOR PRODUCING THE SAME |
JP2010006802A (ja) * | 2008-05-28 | 2010-01-14 | Sumitomo Chemical Co Ltd | 顆粒状農薬製剤 |
CN102578129A (zh) * | 2012-02-06 | 2012-07-18 | 山东禾宜生物科技有限公司 | 一种防治香蕉叶斑病的杀菌剂 |
WO2014003438A1 (ko) * | 2012-06-26 | 2014-01-03 | 주식회사 경농 | 무기염을 포함하는 유화가능한 고상 농약 조성물의 제조방법 |
JP2015525746A (ja) * | 2012-06-26 | 2015-09-07 | キョン ノン コーポレーション | 無機塩を含有する乳化性固体農薬組成物の調製方法 |
US9801382B2 (en) | 2012-06-26 | 2017-10-31 | Kyung Nong Corporation | Method for preparing emulsifiable solid agrochemical composition containing inorganic salt |
Also Published As
Publication number | Publication date |
---|---|
AR040813A1 (es) | 2005-04-20 |
AU2003254824A1 (en) | 2004-02-25 |
JPWO2004014136A1 (ja) | 2005-11-24 |
US8163674B2 (en) | 2012-04-24 |
BR0313257A (pt) | 2005-06-14 |
EP1552743A4 (en) | 2009-07-22 |
TW200406149A (en) | 2004-05-01 |
CA2494289A1 (en) | 2004-02-19 |
TWI325760B (ja) | 2010-06-11 |
IL166607A (en) | 2014-07-31 |
CA2494289C (en) | 2008-11-18 |
MXPA05001429A (es) | 2005-09-30 |
US20060035787A1 (en) | 2006-02-16 |
CN100508750C (zh) | 2009-07-08 |
IL166607A0 (en) | 2006-01-15 |
CN1684584A (zh) | 2005-10-19 |
AU2003254824B2 (en) | 2006-08-24 |
JP4850414B2 (ja) | 2012-01-11 |
BR0313257B1 (pt) | 2014-02-11 |
EP1552743A1 (en) | 2005-07-13 |
ZA200501014B (en) | 2006-10-25 |
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