TWI507295B - 積層體 - Google Patents
積層體 Download PDFInfo
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- TWI507295B TWI507295B TW100107112A TW100107112A TWI507295B TW I507295 B TWI507295 B TW I507295B TW 100107112 A TW100107112 A TW 100107112A TW 100107112 A TW100107112 A TW 100107112A TW I507295 B TWI507295 B TW I507295B
- Authority
- TW
- Taiwan
- Prior art keywords
- layer
- laminate
- polycarbonate resin
- dihydroxy compound
- resin
- Prior art date
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- 239000010410 layer Substances 0.000 claims description 181
- 229920005668 polycarbonate resin Polymers 0.000 claims description 82
- 239000004431 polycarbonate resin Substances 0.000 claims description 82
- 150000001875 compounds Chemical class 0.000 claims description 55
- 125000003118 aryl group Chemical group 0.000 claims description 53
- 229920005989 resin Polymers 0.000 claims description 32
- 239000011347 resin Substances 0.000 claims description 32
- 230000003373 anti-fouling effect Effects 0.000 claims description 14
- 239000004566 building material Substances 0.000 claims description 12
- 238000012545 processing Methods 0.000 claims description 11
- 238000003856 thermoforming Methods 0.000 claims description 11
- 238000001746 injection moulding Methods 0.000 claims description 4
- 239000011247 coating layer Substances 0.000 claims 1
- 238000000034 method Methods 0.000 description 36
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 28
- 239000004925 Acrylic resin Substances 0.000 description 17
- 229920000178 Acrylic resin Polymers 0.000 description 17
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 15
- 239000011248 coating agent Substances 0.000 description 15
- 238000007639 printing Methods 0.000 description 13
- 239000002344 surface layer Substances 0.000 description 13
- 238000004383 yellowing Methods 0.000 description 13
- 238000000576 coating method Methods 0.000 description 12
- 230000006866 deterioration Effects 0.000 description 12
- 125000002723 alicyclic group Chemical group 0.000 description 11
- 230000009477 glass transition Effects 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 150000004292 cyclic ethers Chemical group 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- 238000005809 transesterification reaction Methods 0.000 description 7
- 125000001931 aliphatic group Chemical group 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
- 150000004650 carbonic acid diesters Chemical class 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- KLDXJTOLSGUMSJ-JGWLITMVSA-N Isosorbide Chemical compound O[C@@H]1CO[C@@H]2[C@@H](O)CO[C@@H]21 KLDXJTOLSGUMSJ-JGWLITMVSA-N 0.000 description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 5
- 239000006096 absorbing agent Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 229960002479 isosorbide Drugs 0.000 description 5
- 230000031700 light absorption Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- -1 4-(2-hydroxyethoxy)-3-methyl Phenyl Chemical group 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 4
- 239000012964 benzotriazole Substances 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 4
- 238000002834 transmittance Methods 0.000 description 4
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 150000008064 anhydrides Chemical class 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000001723 curing Methods 0.000 description 3
- 238000010030 laminating Methods 0.000 description 3
- 229930195143 oxyphenol Natural products 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- XYWDBAKATHNVAA-YZXKGSGOSA-N (2r,3s,6r,8r,10s)-2-[(2s)-butan-2-yl]-8-(2-hydroxyethyl)-3-methyl-1,7-dioxaspiro[5.5]undecan-10-ol Chemical compound C1C[C@H](C)[C@@H]([C@@H](C)CC)O[C@@]21O[C@H](CCO)C[C@H](O)C2 XYWDBAKATHNVAA-YZXKGSGOSA-N 0.000 description 2
- GPFJHNSSBHPYJK-UHFFFAOYSA-N (3-methylphenyl) hydrogen carbonate Chemical compound CC1=CC=CC(OC(O)=O)=C1 GPFJHNSSBHPYJK-UHFFFAOYSA-N 0.000 description 2
- JAKQQNJMLCVDDC-UHFFFAOYSA-N 1,1'-biphenyl;carbonic acid Chemical compound OC(O)=O.C1=CC=CC=C1C1=CC=CC=C1.C1=CC=CC=C1C1=CC=CC=C1 JAKQQNJMLCVDDC-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 230000004075 alteration Effects 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 230000003667 anti-reflective effect Effects 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- MUCRFDZUHPMASM-UHFFFAOYSA-N bis(2-chlorophenyl) carbonate Chemical compound ClC1=CC=CC=C1OC(=O)OC1=CC=CC=C1Cl MUCRFDZUHPMASM-UHFFFAOYSA-N 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- VEIOBOXBGYWJIT-UHFFFAOYSA-N cyclohexane;methanol Chemical compound OC.OC.C1CCCCC1 VEIOBOXBGYWJIT-UHFFFAOYSA-N 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- QLVWOKQMDLQXNN-UHFFFAOYSA-N dibutyl carbonate Chemical compound CCCCOC(=O)OCCCC QLVWOKQMDLQXNN-UHFFFAOYSA-N 0.000 description 2
- FYIBPWZEZWVDQB-UHFFFAOYSA-N dicyclohexyl carbonate Chemical compound C1CCCCC1OC(=O)OC1CCCCC1 FYIBPWZEZWVDQB-UHFFFAOYSA-N 0.000 description 2
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 2
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- PAJKBYQWGBVBPE-UHFFFAOYSA-N ethene;terephthalic acid Chemical compound C=C.C=C.C=C.OC(=O)C1=CC=C(C(O)=O)C=C1 PAJKBYQWGBVBPE-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 125000001033 ether group Chemical group 0.000 description 2
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 2
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- OTLDLKLSNZMTTA-UHFFFAOYSA-N octahydro-1h-4,7-methanoindene-1,5-diyldimethanol Chemical compound C1C2C3C(CO)CCC3C1C(CO)C2 OTLDLKLSNZMTTA-UHFFFAOYSA-N 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000011342 resin composition Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- KLDXJTOLSGUMSJ-BXKVDMCESA-N (3s,3as,6s,6as)-2,3,3a,5,6,6a-hexahydrofuro[3,2-b]furan-3,6-diol Chemical compound O[C@H]1CO[C@H]2[C@@H](O)CO[C@H]21 KLDXJTOLSGUMSJ-BXKVDMCESA-N 0.000 description 1
- HCNHNBLSNVSJTJ-UHFFFAOYSA-N 1,1-Bis(4-hydroxyphenyl)ethane Chemical compound C=1C=C(O)C=CC=1C(C)C1=CC=C(O)C=C1 HCNHNBLSNVSJTJ-UHFFFAOYSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- OLFNXLXEGXRUOI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-phenylpropan-2-yl)phenol Chemical compound C=1C(N2N=C3C=CC=CC3=N2)=C(O)C(C(C)(C)C=2C=CC=CC=2)=CC=1C(C)(C)C1=CC=CC=C1 OLFNXLXEGXRUOI-UHFFFAOYSA-N 0.000 description 1
- QJIIIQKTRUDEHY-UHFFFAOYSA-N 2-[2-(benzotriazol-2-yl)phenyl]-4,6-di(propan-2-yl)phenol Chemical compound OC1=C(C=C(C=C1C(C)C)C(C)C)C1=C(C=CC=C1)N1N=C2C(=N1)C=CC=C2 QJIIIQKTRUDEHY-UHFFFAOYSA-N 0.000 description 1
- ZPSJMUFCIHMFIL-UHFFFAOYSA-N 2-[2-tert-butyl-4-[9-[3-tert-butyl-4-(2-hydroxyethoxy)phenyl]-10H-anthracen-9-yl]phenoxy]ethanol Chemical compound OCCOC1=C(C=C(C=C1)C1(C2=CC=CC=C2CC=2C=CC=CC1=2)C1=CC(=C(C=C1)OCCO)C(C)(C)C)C(C)(C)C ZPSJMUFCIHMFIL-UHFFFAOYSA-N 0.000 description 1
- BPZIYBJCZRUDEG-UHFFFAOYSA-N 2-[3-(1-hydroxy-2-methylpropan-2-yl)-2,4,8,10-tetraoxaspiro[5.5]undecan-9-yl]-2-methylpropan-1-ol Chemical compound C1OC(C(C)(CO)C)OCC21COC(C(C)(C)CO)OC2 BPZIYBJCZRUDEG-UHFFFAOYSA-N 0.000 description 1
- HBJMKJBAWNZXDT-UHFFFAOYSA-N 2-[3-[4-(hydroxymethyl)heptan-4-yl]-2,4,8,10-tetraoxaspiro[5.5]undecan-9-yl]-2-propylpentan-1-ol Chemical compound C1OC(C(CO)(CCC)CCC)OCC21COC(C(CO)(CCC)CCC)OC2 HBJMKJBAWNZXDT-UHFFFAOYSA-N 0.000 description 1
- FMEHTSALWYROKA-UHFFFAOYSA-N 2-[4-[9-[4-(2-hydroxyethoxy)-3-phenylphenyl]-10H-anthracen-9-yl]-2-phenylphenoxy]ethanol Chemical compound C1(=CC=CC=C1)C=1C=C(C=CC=1OCCO)C1(C2=CC=CC=C2CC=2C=CC=CC1=2)C1=CC(=C(C=C1)OCCO)C1=CC=CC=C1 FMEHTSALWYROKA-UHFFFAOYSA-N 0.000 description 1
- CAAGBEOHCLPBTF-UHFFFAOYSA-N 2-[4-[9-[4-(2-hydroxyethoxy)-3-propan-2-ylphenyl]-10H-anthracen-9-yl]-2-propan-2-ylphenoxy]ethanol Chemical compound OCCOC1=C(C=C(C=C1)C1(C2=CC=CC=C2CC=2C=CC=CC1=2)C1=CC(=C(C=C1)OCCO)C(C)C)C(C)C CAAGBEOHCLPBTF-UHFFFAOYSA-N 0.000 description 1
- NCMRSHZOFGKWRG-UHFFFAOYSA-N 2-[4-[9-[4-(2-hydroxyethoxy)phenyl]-10h-anthracen-9-yl]phenoxy]ethanol Chemical compound C1=CC(OCCO)=CC=C1C1(C=2C=CC(OCCO)=CC=2)C2=CC=CC=C2CC2=CC=CC=C21 NCMRSHZOFGKWRG-UHFFFAOYSA-N 0.000 description 1
- PRDGTYZDVYIODY-UHFFFAOYSA-N 2-ethyl-2-[3-[3-(hydroxymethyl)pentan-3-yl]-2,4,8,10-tetraoxaspiro[5.5]undecan-9-yl]butan-1-ol Chemical compound C1OC(C(CC)(CO)CC)OCC21COC(C(CC)(CC)CO)OC2 PRDGTYZDVYIODY-UHFFFAOYSA-N 0.000 description 1
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 1
- YMTYZTXUZLQUSF-UHFFFAOYSA-N 3,3'-Dimethylbisphenol A Chemical compound C1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=CC=2)=C1 YMTYZTXUZLQUSF-UHFFFAOYSA-N 0.000 description 1
- OROLBLYPXFRKNI-UHFFFAOYSA-N 3-[4-[9-[4-(3-hydroxy-2,2-dimethylpropoxy)phenyl]-10H-anthracen-9-yl]phenoxy]-2,2-dimethylpropan-1-ol Chemical compound OCC(COC1=CC=C(C=C1)C1(C2=CC=CC=C2CC=2C=CC=CC1=2)C1=CC=C(C=C1)OCC(CO)(C)C)(C)C OROLBLYPXFRKNI-UHFFFAOYSA-N 0.000 description 1
- VWGKEVWFBOUAND-UHFFFAOYSA-N 4,4'-thiodiphenol Chemical compound C1=CC(O)=CC=C1SC1=CC=C(O)C=C1 VWGKEVWFBOUAND-UHFFFAOYSA-N 0.000 description 1
- NZGQHKSLKRFZFL-UHFFFAOYSA-N 4-(4-hydroxyphenoxy)phenol Chemical compound C1=CC(O)=CC=C1OC1=CC=C(O)C=C1 NZGQHKSLKRFZFL-UHFFFAOYSA-N 0.000 description 1
- OPKQAOBTBQLNCB-UHFFFAOYSA-N 4-[10-(4-hydroxyphenyl)anthracen-9-yl]phenol Chemical compound C1=CC(O)=CC=C1C(C1=CC=CC=C11)=C(C=CC=C2)C2=C1C1=CC=C(O)C=C1 OPKQAOBTBQLNCB-UHFFFAOYSA-N 0.000 description 1
- ODJUOZPKKHIEOZ-UHFFFAOYSA-N 4-[2-(4-hydroxy-3,5-dimethylphenyl)propan-2-yl]-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=C(C)C=2)=C1 ODJUOZPKKHIEOZ-UHFFFAOYSA-N 0.000 description 1
- KWWMNLQDGJZHSK-UHFFFAOYSA-N 4-anthracen-1-ylphenol Chemical compound C1=CC(O)=CC=C1C1=CC=CC2=CC3=CC=CC=C3C=C12 KWWMNLQDGJZHSK-UHFFFAOYSA-N 0.000 description 1
- ZYZWCJWINLGQRL-UHFFFAOYSA-N 4-phenylcyclohexa-2,4-diene-1,1-diol Chemical group C1=CC(O)(O)CC=C1C1=CC=CC=C1 ZYZWCJWINLGQRL-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229920005497 Acrypet® Polymers 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- SDDLEVPIDBLVHC-UHFFFAOYSA-N Bisphenol Z Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCCC1 SDDLEVPIDBLVHC-UHFFFAOYSA-N 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
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- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- QYFACSDTKGXDDM-UHFFFAOYSA-N OC.OC.C1CCCCCCCCCCCCCC1.C1CCCCCCCCCCCCCC1.C1CCCCCCCCCCCCCC1.C1CCCCCCCCCCCCCC1.C1CCCCCCCCCCCCCC1 Chemical compound OC.OC.C1CCCCCCCCCCCCCC1.C1CCCCCCCCCCCCCC1.C1CCCCCCCCCCCCCC1.C1CCCCCCCCCCCCCC1.C1CCCCCCCCCCCCCC1 QYFACSDTKGXDDM-UHFFFAOYSA-N 0.000 description 1
- MORZPMLOHLLUFS-UHFFFAOYSA-N OCCOC1=C(C=C(C=C1)C1(C2=CC=CC=C2CC=2C=CC=CC12)C1=CC(=C(C=C1)OCCO)CC(C)C)CC(C)C Chemical compound OCCOC1=C(C=C(C=C1)C1(C2=CC=CC=C2CC=2C=CC=CC12)C1=CC(=C(C=C1)OCCO)CC(C)C)CC(C)C MORZPMLOHLLUFS-UHFFFAOYSA-N 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- KYPYTERUKNKOLP-UHFFFAOYSA-N Tetrachlorobisphenol A Chemical compound C=1C(Cl)=C(O)C(Cl)=CC=1C(C)(C)C1=CC(Cl)=C(O)C(Cl)=C1 KYPYTERUKNKOLP-UHFFFAOYSA-N 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- 239000003522 acrylic cement Substances 0.000 description 1
- RVIZJROSQMQZCG-UHFFFAOYSA-N adamantane-1,2-diol Chemical compound C1C(C2)CC3CC1C(O)C2(O)C3 RVIZJROSQMQZCG-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
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- 239000012790 adhesive layer Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
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- C—CHEMISTRY; METALLURGY
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
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- C08G64/0208—Aliphatic polycarbonates saturated
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31507—Of polycarbonate
Landscapes
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Liquid Crystal (AREA)
- Polyesters Or Polycarbonates (AREA)
- Devices For Indicating Variable Information By Combining Individual Elements (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
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| JP2010046630 | 2010-03-03 |
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| CN102470657A (zh) * | 2009-08-21 | 2012-05-23 | 帝人株式会社 | 注射成型用装饰片 |
| CN102892833B (zh) * | 2010-05-19 | 2016-01-06 | 三菱化学株式会社 | 卡用片及卡 |
| EP3476897B1 (en) | 2010-06-25 | 2025-06-25 | Mitsubishi Chemical Corporation | Polycarbonate resin composition and molded article |
| CN103003361A (zh) | 2010-07-14 | 2013-03-27 | 三菱化学株式会社 | 聚碳酸酯树脂组合物、以及使用该组合物得到的成型品、膜、板、注塑成型品 |
| JP5771021B2 (ja) * | 2011-02-16 | 2015-08-26 | 帝人株式会社 | 積層フィルム |
| EP2677003B1 (en) | 2011-02-17 | 2023-09-27 | Mitsubishi Chemical Corporation | Polycarbonate resin composition |
| EP2692498B1 (en) | 2011-03-31 | 2019-10-02 | Mitsubishi Chemical Corporation | Method for manufacturing polycarbonate resin |
| JP2013203042A (ja) * | 2012-03-29 | 2013-10-07 | Mitsubishi Chemicals Corp | 積層体 |
| EP2650103A1 (de) * | 2012-04-12 | 2013-10-16 | Senoplast Klepsch & Co. GmbH | Halogenfreier Verbundkörper |
| JP2014012366A (ja) * | 2012-07-04 | 2014-01-23 | Mitsubishi Gas Chemical Co Inc | 高弾性透明樹脂積層体の製造方法 |
| USD717593S1 (en) * | 2012-11-30 | 2014-11-18 | Schroeder Industries, Inc. | Beverage dispensing bar gun |
| USD717592S1 (en) * | 2012-11-30 | 2014-11-18 | Schroeder Industries, Inc. | Beverage dispensing bar gun |
| USD717591S1 (en) * | 2012-11-30 | 2014-11-18 | Schroeder Industries, Inc. | Beverage dispensing bar gun |
| USD717590S1 (en) * | 2012-11-30 | 2014-11-18 | Schroeder Industries, Inc. | Beverage dispensing bar gun |
| JP6050681B2 (ja) * | 2012-12-28 | 2016-12-21 | 共和レザー株式会社 | 成形品の製造方法 |
| EP3106306B1 (en) * | 2014-02-10 | 2019-06-12 | Teijin Limited | Multilayer body |
| JP6287318B2 (ja) * | 2014-02-21 | 2018-03-07 | 三菱ケミカル株式会社 | 樹脂組成物及び三次元物体の製造方法 |
| JP6303726B2 (ja) * | 2014-03-31 | 2018-04-04 | 住友ベークライト株式会社 | 窓部材 |
| JP6459444B2 (ja) * | 2014-11-28 | 2019-01-30 | 住友ベークライト株式会社 | 工作機用窓 |
| EP3050915A1 (en) * | 2015-01-27 | 2016-08-03 | Keiwa Inc. | Glass plate substitute film, and display device |
| JP2016147485A (ja) * | 2015-01-27 | 2016-08-18 | 恵和株式会社 | ガラス板代替フィルム及びディスプレイデバイス |
| JP6544187B2 (ja) * | 2015-10-08 | 2019-07-17 | 三菱ケミカル株式会社 | 積層体、およびディスプレイ用前面板 |
| JP2017140818A (ja) * | 2016-02-08 | 2017-08-17 | 三菱ケミカル株式会社 | 樹脂積層体、建築部材、および、樹脂積層体の製造方法 |
| WO2017199916A1 (ja) * | 2016-05-16 | 2017-11-23 | 株式会社ポラテクノ | 偏光部材及びそれを備えたヘッドアップディスプレイ装置 |
| JP6729144B2 (ja) * | 2016-08-02 | 2020-07-22 | 三菱ケミカル株式会社 | 積層体、ディスプレイ前面板 |
| JP7155472B2 (ja) * | 2016-10-14 | 2022-10-19 | 大日本印刷株式会社 | 光学フィルムおよび画像表示装置 |
| CN110248808B (zh) | 2017-02-03 | 2021-10-29 | 帝人株式会社 | 多层体 |
| KR102398049B1 (ko) * | 2017-06-13 | 2022-05-17 | 삼성디스플레이 주식회사 | 표시 장치 윈도우 및 이를 포함하는 표시 장치 |
| CN111511558A (zh) | 2017-12-21 | 2020-08-07 | 帝人株式会社 | 多层体 |
| US11873370B2 (en) | 2018-06-08 | 2024-01-16 | Mitsubishi Chemical Corporation | Polycarbonate resin composition, molded article, and multilayer body |
| JP7403768B2 (ja) * | 2019-03-13 | 2023-12-25 | 積水樹脂株式会社 | 積層体およびその製造方法 |
| CN110607068B (zh) * | 2019-08-19 | 2021-03-16 | 武汉华星光电半导体显示技术有限公司 | 聚合物薄膜及其制备方法、柔性折叠面板 |
| CN117120263A (zh) * | 2021-04-08 | 2023-11-24 | 三菱化学株式会社 | 层叠体、卡片、护照和它们的制造方法 |
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| EP4197783A1 (en) * | 2021-12-17 | 2023-06-21 | Covestro Deutschland AG | At least partially biobased layered structure with good flame resistance |
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- 2011-03-02 EP EP15202523.5A patent/EP3034302B1/en active Active
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- 2011-03-02 WO PCT/JP2011/054776 patent/WO2011108594A1/ja not_active Ceased
- 2011-03-03 JP JP2011045898A patent/JP5718679B2/ja active Active
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2012
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2015
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2016
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Also Published As
| Publication number | Publication date |
|---|---|
| KR101953921B1 (ko) | 2019-03-04 |
| EP3034302B1 (en) | 2018-08-22 |
| WO2011108594A1 (ja) | 2011-09-09 |
| JP2017109494A (ja) | 2017-06-22 |
| JP5718679B2 (ja) | 2015-05-13 |
| TW201136767A (en) | 2011-11-01 |
| EP2543510B1 (en) | 2016-05-04 |
| CN102762380A (zh) | 2012-10-31 |
| EP2543510A1 (en) | 2013-01-09 |
| KR20130014492A (ko) | 2013-02-07 |
| US20120328855A1 (en) | 2012-12-27 |
| CN106003958A (zh) | 2016-10-12 |
| JP2011201304A (ja) | 2011-10-13 |
| EP2543510A4 (en) | 2013-08-14 |
| JP6068538B2 (ja) | 2017-01-25 |
| EP3034302A1 (en) | 2016-06-22 |
| CN102762380B (zh) | 2016-06-08 |
| JP2015143028A (ja) | 2015-08-06 |
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