TWI483951B - 聚烯烴之製造方法及聚烯烴暨直鏈狀低密度聚乙烯製造原料用１-己烯 - Google Patents

聚烯烴之製造方法及聚烯烴暨直鏈狀低密度聚乙烯製造原料用１-己烯 Download PDF

Info

Publication number
TWI483951B
TWI483951B TW096149649A TW96149649A TWI483951B TW I483951 B TWI483951 B TW I483951B TW 096149649 A TW096149649 A TW 096149649A TW 96149649 A TW96149649 A TW 96149649A TW I483951 B TWI483951 B TW I483951B
Authority
TW
Taiwan
Prior art keywords
hexene
compound
polyolefin
aluminum
ethylene
Prior art date
Application number
TW096149649A
Other languages
English (en)
Chinese (zh)
Other versions
TW200837082A (en
Inventor
Hiroki Emoto
Kazuyuki Yokoyama
Takashi Monoi
Kazuhiro Yamamoto
Original Assignee
Mitsubishi Chem Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chem Corp filed Critical Mitsubishi Chem Corp
Publication of TW200837082A publication Critical patent/TW200837082A/zh
Application granted granted Critical
Publication of TWI483951B publication Critical patent/TWI483951B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/24—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/107—Alkenes with six carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/69—Chromium, molybdenum, tungsten or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/18—Introducing halogen atoms or halogen-containing groups
    • C08F8/20—Halogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Closed-Circuit Television Systems (AREA)
  • Television Signal Processing For Recording (AREA)
TW096149649A 2006-12-27 2007-12-24 聚烯烴之製造方法及聚烯烴暨直鏈狀低密度聚乙烯製造原料用１-己烯 TWI483951B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2006351967 2006-12-27

Publications (2)

Publication Number Publication Date
TW200837082A TW200837082A (en) 2008-09-16
TWI483951B true TWI483951B (zh) 2015-05-11

Family

ID=39562256

Family Applications (1)

Application Number Title Priority Date Filing Date
TW096149649A TWI483951B (zh) 2006-12-27 2007-12-24 聚烯烴之製造方法及聚烯烴暨直鏈狀低密度聚乙烯製造原料用１-己烯

Country Status (13)

Country Link
US (1) US9272961B2 (enExample)
EP (1) EP2098543A4 (enExample)
JP (2) JP5277630B2 (enExample)
KR (1) KR101450925B1 (enExample)
CN (1) CN101547944B (enExample)
BR (1) BRPI0720610B8 (enExample)
CA (1) CA2673907C (enExample)
EA (1) EA016590B1 (enExample)
IN (1) IN2015DN02831A (enExample)
MX (1) MX2009007056A (enExample)
SG (1) SG171627A1 (enExample)
TW (1) TWI483951B (enExample)
WO (1) WO2008078462A1 (enExample)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2430116C1 (ru) * 2010-01-29 2011-09-27 Закрытое Акционерное Общество "Сибур Холдинг" Способ полимеризации и сополимеризации олефиновых олигомеров
CN104926589A (zh) * 2010-03-26 2015-09-23 三菱化学株式会社 α-烯烃低聚物的制造方法
JP6459587B2 (ja) * 2014-02-25 2019-01-30 三菱ケミカル株式会社 α−オレフィン低重合体の製造方法
US9175109B1 (en) 2014-05-20 2015-11-03 Chevron Phillips Chemical Company Lp Oligomerization processes and polymer compositions produced therefrom
CA2971698C (en) 2014-12-23 2019-08-13 Public Joint Stock Company "Sibur Holding" Methods of preparing oligomers of an olefin
US9505675B2 (en) 2015-02-09 2016-11-29 Chevron Phillips Chemical Company Lp Deactivation of a process by-product
JP6711029B2 (ja) * 2015-03-25 2020-06-17 三菱ケミカル株式会社 α−オレフィン低重合体の製造方法
WO2016158621A1 (ja) * 2015-03-27 2016-10-06 三菱化学株式会社 α－オレフィン低重合体の製造方法
WO2017010998A1 (en) 2015-07-14 2017-01-19 Chevron Phillips Chemical Company Lp Olefin compositions
US10519077B2 (en) 2015-09-18 2019-12-31 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
US10513473B2 (en) 2015-09-18 2019-12-24 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
KR102778099B1 (ko) * 2021-09-07 2025-03-10 한화솔루션 주식회사 올레핀계 중합체의 제조방법 및 이를 이용하여 제조된 올레핀계 중합체

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0399024A (ja) * 1989-09-11 1991-04-24 Idemitsu Petrochem Co Ltd α―オレフィンのハロゲン化不純物の除去方法
JPH07117171A (ja) * 1993-10-21 1995-05-09 Mitsui Toatsu Chem Inc 耐劣化性ポリプロピレン成形物
CN1140179A (zh) * 1995-01-18 1997-01-15 英国石油化学品有限公司 聚合烯烃的方法
US5910619A (en) * 1994-06-21 1999-06-08 Mitsubishi Chemical Corporation Process for producing α-olefin oligomers

Family Cites Families (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3093612A (en) * 1960-05-11 1963-06-11 Monsanto Chemicals Solutions of polyolefins and an alkoxyalkyl ester of an aliphatic monocarboxylic acid and a process for spinning same
US3423491A (en) * 1964-09-02 1969-01-21 Dow Chemical Co Permselective hollow fibers and method of making
US4020230A (en) * 1975-10-03 1977-04-26 The Dow Chemical Company Microporous polyethylene hollow fibers and process of preparing them
JPS53103411A (en) 1977-02-23 1978-09-08 Asahi Chem Ind Co Ltd Recovery of organic halides
US4406673A (en) 1979-12-27 1983-09-27 Teijin Limited Ultrathin solid membrane, process for production thereof, and use thereof for concentrating a specified gas in a gaseous mixture
FR2504914A1 (fr) 1981-04-29 1982-11-05 Inst Francais Du Petrole Procede d'elimination d'impuretes halogenees d'oligomeres d'olefines
US4666763A (en) * 1984-12-07 1987-05-19 Akzona Incorporated Fiber batts and the method of making
JPS63218707A (ja) * 1987-03-07 1988-09-12 Showa Denko Kk ポリオレフインの製造方法
JP2703230B2 (ja) * 1987-07-31 1998-01-26 株式会社 細川洋行 包装袋
US4874567A (en) * 1987-04-24 1989-10-17 Millipore Corporation Microporous membranes from polypropylene
JP2825910B2 (ja) 1990-02-13 1998-11-18 三井化学株式会社 オレフィン重合用固体触媒およびオレフィンの重合方法
JP2825911B2 (ja) * 1990-02-13 1998-11-18 三井化学株式会社 オレフィン重合用触媒およびオレフィンの重合方法
JP3255716B2 (ja) 1991-07-11 2002-02-12 出光興産株式会社 オレフィンの重合方法及びオレフィン重合用触媒
JPH05170828A (ja) 1991-12-19 1993-07-09 Mitsubishi Petrochem Co Ltd エチレン共重合体及びそれを含有する樹脂組成物
JPH08239329A (ja) * 1995-03-02 1996-09-17 Mitsubishi Chem Corp α−オレフイン低重合体の製造方法
JP3613642B2 (ja) 1994-09-05 2005-01-26 住友化学株式会社 １−ヘキセンの製造方法
JP3473192B2 (ja) * 1994-09-13 2003-12-02 三菱化学株式会社 α−オレフィン低重合体の製造方法
JPH08283325A (ja) * 1995-04-17 1996-10-29 Tonen Chem Corp オレフィンの重合方法
JPH0912627A (ja) * 1995-06-28 1997-01-14 Mitsubishi Chem Corp α−オレフィン低重合体の製造方法
JPH09194524A (ja) * 1995-11-15 1997-07-29 Tosoh Corp オレフィン低重合触媒及びそれを用いたオレフィンの低重合方法
US5856612A (en) * 1996-02-02 1999-01-05 Mitsubishi Chemical Corporation Process for producing α-olefin oligomer
JP3766170B2 (ja) * 1996-03-14 2006-04-12 三菱化学株式会社 α−オレフィン低重合体の製造方法
WO1997033924A1 (en) 1996-03-14 1997-09-18 Mitsubishi Chemical Corporation PROCESS FOR THE PRODUCTION OF α-OLEFIN OLIGOMERS
JP3881418B2 (ja) * 1996-03-15 2007-02-14 三菱化学株式会社 α−オレフィン低重合体の製造方法
JPH09268135A (ja) * 1996-04-02 1997-10-14 Tosoh Corp １−ヘキセンの製造方法
JPH09268133A (ja) * 1996-04-02 1997-10-14 Tosoh Corp １−ヘキセンの製造方法
JPH1036435A (ja) * 1996-07-29 1998-02-10 Mitsubishi Chem Corp α−オレフィン低重合体の製造方法
JPH10109946A (ja) * 1996-08-12 1998-04-28 Mitsubishi Chem Corp α−オレフィン低重合体の製造方法
JPH1160511A (ja) 1997-08-25 1999-03-02 Mitsubishi Chem Corp α−オレフィン低重合体の製造方法
JP3743788B2 (ja) 1997-09-03 2006-02-08 東ソー株式会社 高純度薬品容器用ポリエチレン樹脂、組成物及びそれよりなる高純度薬品容器
JP3685996B2 (ja) * 1998-09-16 2005-08-24 日本ポリオレフィン株式会社 電気絶縁用樹脂材料、電気絶縁材およびこれを用いた電線・ケーブル
GB2391549B (en) * 2001-05-09 2005-10-19 Mitsubishi Plastics Inc Porous film and its production process
US20020168912A1 (en) * 2001-05-10 2002-11-14 Bond Eric Bryan Multicomponent fibers comprising starch and biodegradable polymers
US20020168518A1 (en) * 2001-05-10 2002-11-14 The Procter & Gamble Company Fibers comprising starch and polymers
US6946506B2 (en) * 2001-05-10 2005-09-20 The Procter & Gamble Company Fibers comprising starch and biodegradable polymers
US6746755B2 (en) * 2001-09-24 2004-06-08 Siemens Westinghouse Power Corporation Ceramic matrix composite structure having integral cooling passages and method of manufacture
US7271209B2 (en) * 2002-08-12 2007-09-18 Exxonmobil Chemical Patents Inc. Fibers and nonwovens from plasticized polyolefin compositions
US8003725B2 (en) * 2002-08-12 2011-08-23 Exxonmobil Chemical Patents Inc. Plasticized hetero-phase polyolefin blends
US7998579B2 (en) * 2002-08-12 2011-08-16 Exxonmobil Chemical Patents Inc. Polypropylene based fibers and nonwovens
JP2004182971A (ja) * 2002-08-19 2004-07-02 Japan Polypropylene Corp ポリオレフィンの製造の改良方法
WO2004016661A1 (ja) 2002-08-19 2004-02-26 Japan Polypropylene Corporation ポリオレフィンの製造方法
US6906137B2 (en) * 2003-03-26 2005-06-14 Dupont Dow Elastomers Llc Process aid masterbatch for melt processable polymers
JP4714424B2 (ja) 2004-04-20 2011-06-29 Ｊｘ日鉱日石エネルギー株式会社 α−オレフィン重合体の製造方法
JP2006143893A (ja) 2004-11-19 2006-06-08 Unitika Ltd 水性分散体および積層フィルム
JP2006351967A (ja) 2005-06-17 2006-12-28 Sony Corp 多波長半導体レーザ素子
DE102006006396A1 (de) * 2006-02-11 2007-08-16 Cognis Ip Management Gmbh Verwendung von Triglyceriden als Weichmacher für Polyolefine
CN102014619B (zh) * 2008-04-04 2014-01-01 拜尔农作物科学股份公司 含有嵌入杀虫剂和添加剂的材料
US8026188B2 (en) * 2009-06-25 2011-09-27 Techmer Pm, Llc Hydrophobic additive for use with fabric, fiber, and film
IN2012DE00299A (enExample) * 2011-02-15 2015-04-10 Flow Polymers Llc
US20130004691A1 (en) * 2011-05-20 2013-01-03 William Maxwell Allen Molded articles of polymer-wax compositions
CN103547622A (zh) * 2011-05-20 2014-01-29 宝洁公司 聚合物-油组合物的膜
EP3103833A1 (en) * 2011-05-20 2016-12-14 The Procter and Gamble Company Fibers of polymer-wax compositions
RU2013156462A (ru) * 2011-05-20 2015-06-27 Дзе Проктер Энд Гэмбл Компани Формованные изделия на основе композиций, содержащих крахмал, полимер, воск и масло
WO2012162084A2 (en) * 2011-05-20 2012-11-29 The Procter & Gamble Company Starch-polymer-oil compositions, methods of making and using the same
RU2013147758A (ru) * 2011-05-20 2015-06-27 Дзе Проктер Энд Гэмбл Компани Пленки, выполненные из композиций, содержащих крахмал, полимер, воск и масло
EP2710059A1 (en) * 2011-05-20 2014-03-26 The Procter and Gamble Company Films of polymer-wax compositions
US20120328804A1 (en) * 2011-05-20 2012-12-27 William Maxwell Allen Molded articles of polymer-oil compositions
EP2710058B1 (en) * 2011-05-20 2018-07-25 The Procter and Gamble Company Fibers of polymer-oil compositions
EP2710062A1 (en) * 2011-05-20 2014-03-26 The Procter and Gamble Company Polymer-oil compositions, methods of making and using the same
US9155580B2 (en) * 2011-08-25 2015-10-13 Medos International Sarl Multi-threaded cannulated bone anchors

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0399024A (ja) * 1989-09-11 1991-04-24 Idemitsu Petrochem Co Ltd α―オレフィンのハロゲン化不純物の除去方法
JPH07117171A (ja) * 1993-10-21 1995-05-09 Mitsui Toatsu Chem Inc 耐劣化性ポリプロピレン成形物
US5910619A (en) * 1994-06-21 1999-06-08 Mitsubishi Chemical Corporation Process for producing α-olefin oligomers
CN1140179A (zh) * 1995-01-18 1997-01-15 英国石油化学品有限公司 聚合烯烃的方法

Also Published As

Publication number Publication date
CA2673907A1 (en) 2008-07-03
EA016590B1 (ru) 2012-06-29
US20100331503A1 (en) 2010-12-30
JP5541390B2 (ja) 2014-07-09
BRPI0720610B8 (pt) 2020-06-09
WO2008078462A1 (ja) 2008-07-03
TW200837082A (en) 2008-09-16
JP5277630B2 (ja) 2013-08-28
IN2015DN02831A (enExample) 2015-09-11
MX2009007056A (es) 2009-09-09
CN101547944B (zh) 2013-07-24
BRPI0720610B1 (pt) 2018-11-27
JP2008179801A (ja) 2008-08-07
BRPI0720610A2 (pt) 2014-04-15
EA200970636A1 (ru) 2010-02-26
EP2098543A4 (en) 2012-01-25
CA2673907C (en) 2014-09-23
KR101450925B1 (ko) 2014-10-14
JP2013155378A (ja) 2013-08-15
EP2098543A1 (en) 2009-09-09
BRPI0720610A8 (pt) 2018-04-03
SG171627A1 (en) 2011-06-29
CN101547944A (zh) 2009-09-30
KR20090093974A (ko) 2009-09-02
US9272961B2 (en) 2016-03-01

Similar Documents

Publication Publication Date Title
TWI483951B (zh) 聚烯烴之製造方法及聚烯烴暨直鏈狀低密度聚乙烯製造原料用１-己烯
EP2041190B1 (en) Process to produce polyolefins using metallocene catalysts
US8076524B2 (en) Process for generating alpha olefin comonomers
SA93140175B1 (ar) تحضير عامل حفاز لبلمرة أوليفين olefin
CA2815336C (en) Activator compositions, their preparation, and their use in catalysis
CN1214343A (zh) 烯烃聚合方法及其产品
KR101868188B1 (ko) 에틸렌-기재 중합 반응에서 사용되는 용매를 재활용시키는 방법 및 이를 위한 시스템
US20040068072A1 (en) Selective isomerization and linear dimerization of olefins using cobalt catalysts
CA2985611C (en) Process to produce modified clay, supported metallocene polymerization catalyst, catalyst produced and use thereof
CA2427094C (en) Process for the selective oligomerization of ethylene
JP2008179631A (ja) α−オレフィン低重合体の製造方法
CA2760549A1 (en) Process for the production of an ethylene polymer using a chromium containing catalyst
TWI434733B (zh) 催化劑組合物及其用於製備直鏈型α-烯烴之方法
JP2002020412A (ja) エチレン系重合用触媒、エチレン系重合体およびその製造方法
CN103464204A (zh) 制备烯烃低聚合催化剂的方法
KR100710963B1 (ko) 활성의 불균일 지지된 비덴테이트 또는 트리덴테이트계의올레핀 중합 촉매
JP2014159391A (ja) α−オレフィン低重合体の製造方法
Malpass Industrial metal alkyls and their use in polyolefin catalysts
JP2006117642A (ja) オレフィン低重合体ならびにオレフィン共重合体の製造方法
KR20220044202A (ko) 고분자량 폴리에틸렌 제조용 중합 촉매
KR101486135B1 (ko) 올레핀 중합용 희석 촉매의 제조 방법 및 이를 이용한 올레핀 중합 방법
Hashemzadeh et al. Homogeneous catalyzed olefin oligomerization
CN114127133B (zh) 使用齐格勒-纳塔催化剂和氢化催化剂在溶液工艺中聚合乙烯
JP2005511792A (ja) オレフィン類の重合のためのモノアミドベースの触媒組成物
Culver Well-Defined Heterogeneous Catalytically Active Ion Pairs on the Surface of Oxides