TW301795B - - Google Patents
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- Publication number
- TW301795B TW301795B TW085109810A TW85109810A TW301795B TW 301795 B TW301795 B TW 301795B TW 085109810 A TW085109810 A TW 085109810A TW 85109810 A TW85109810 A TW 85109810A TW 301795 B TW301795 B TW 301795B
- Authority
- TW
- Taiwan
- Prior art keywords
- layer
- wafer
- wafer carrier
- material layer
- electrically conductive
- Prior art date
Links
- 239000000758 substrate Substances 0.000 claims description 31
- 239000004020 conductor Substances 0.000 claims description 12
- 229910000679 solder Inorganic materials 0.000 claims description 11
- 239000007769 metal material Substances 0.000 claims description 7
- 239000011368 organic material Substances 0.000 claims description 4
- 239000004065 semiconductor Substances 0.000 claims description 4
- PCTMTFRHKVHKIS-BMFZQQSSSA-N (1s,3r,4e,6e,8e,10e,12e,14e,16e,18s,19r,20r,21s,25r,27r,30r,31r,33s,35r,37s,38r)-3-[(2r,3s,4s,5s,6r)-4-amino-3,5-dihydroxy-6-methyloxan-2-yl]oxy-19,25,27,30,31,33,35,37-octahydroxy-18,20,21-trimethyl-23-oxo-22,39-dioxabicyclo[33.3.1]nonatriaconta-4,6,8,10 Chemical compound C1C=C2C[C@@H](OS(O)(=O)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2.O[C@H]1[C@@H](N)[C@H](O)[C@@H](C)O[C@H]1O[C@H]1/C=C/C=C/C=C/C=C/C=C/C=C/C=C/[C@H](C)[C@@H](O)[C@@H](C)[C@H](C)OC(=O)C[C@H](O)C[C@H](O)CC[C@@H](O)[C@H](O)C[C@H](O)C[C@](O)(C[C@H](O)[C@H]2C(O)=O)O[C@H]2C1 PCTMTFRHKVHKIS-BMFZQQSSSA-N 0.000 claims 1
- 230000017525 heat dissipation Effects 0.000 abstract description 10
- 239000003989 dielectric material Substances 0.000 abstract description 4
- 229910010293 ceramic material Inorganic materials 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 127
- 235000012431 wafers Nutrition 0.000 description 97
- 239000002184 metal Substances 0.000 description 25
- 229910052751 metal Inorganic materials 0.000 description 25
- 239000000919 ceramic Substances 0.000 description 23
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 13
- 229910052802 copper Inorganic materials 0.000 description 13
- 239000010949 copper Substances 0.000 description 13
- 230000000875 corresponding effect Effects 0.000 description 13
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- 238000000034 method Methods 0.000 description 9
- 238000005553 drilling Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 230000003287 optical effect Effects 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 5
- 239000000969 carrier Substances 0.000 description 5
- 229920002120 photoresistant polymer Polymers 0.000 description 5
- 239000011521 glass Substances 0.000 description 4
- 239000002356 single layer Substances 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000012044 organic layer Substances 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000002079 cooperative effect Effects 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 238000012634 optical imaging Methods 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- JQCVPZXMGXKNOD-UHFFFAOYSA-N 1,2-dibenzylbenzene Chemical compound C=1C=CC=C(CC=2C=CC=CC=2)C=1CC1=CC=CC=C1 JQCVPZXMGXKNOD-UHFFFAOYSA-N 0.000 description 1
- WSULUIILRBXVFA-UHFFFAOYSA-N 2-methyloxirane;propane Chemical compound CCC.CC1CO1 WSULUIILRBXVFA-UHFFFAOYSA-N 0.000 description 1
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- 241000237519 Bivalvia Species 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 235000020639 clam Nutrition 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- UNKQPEQSAGXBEV-UHFFFAOYSA-N formaldehyde;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound O=C.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 UNKQPEQSAGXBEV-UHFFFAOYSA-N 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 238000003079 width control Methods 0.000 description 1
Classifications
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/0201—Thermal arrangements, e.g. for cooling, heating or preventing overheating
- H05K1/0203—Cooling of mounted components
- H05K1/021—Components thermally connected to metal substrates or heat-sinks by insert mounting
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/50—Assembly of semiconductor devices using processes or apparatus not provided for in a single one of the subgroups H01L21/06 - H01L21/326, e.g. sealing of a cap to a base of a container
- H01L21/60—Attaching or detaching leads or other conductive members, to be used for carrying current to or from the device in operation
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- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/12—Mountings, e.g. non-detachable insulating substrates
- H01L23/14—Mountings, e.g. non-detachable insulating substrates characterised by the material or its electrical properties
- H01L23/145—Organic substrates, e.g. plastic
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/36—Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
- H01L23/367—Cooling facilitated by shape of device
- H01L23/3677—Wire-like or pin-like cooling fins or heat sinks
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- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/48—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor
- H01L23/488—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor consisting of soldered or bonded constructions
- H01L23/498—Leads, i.e. metallisations or lead-frames on insulating substrates, e.g. chip carriers
- H01L23/49822—Multilayer substrates
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- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/44—Structure, shape, material or disposition of the wire connectors prior to the connecting process
- H01L2224/45—Structure, shape, material or disposition of the wire connectors prior to the connecting process of an individual wire connector
- H01L2224/45001—Core members of the connector
- H01L2224/45099—Material
- H01L2224/451—Material with a principal constituent of the material being a metal or a metalloid, e.g. boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te) and polonium (Po), and alloys thereof
- H01L2224/45138—Material with a principal constituent of the material being a metal or a metalloid, e.g. boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te) and polonium (Po), and alloys thereof the principal constituent melting at a temperature of greater than or equal to 950°C and less than 1550°C
- H01L2224/45144—Gold (Au) as principal constituent
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- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
- H01L2224/4805—Shape
- H01L2224/4809—Loop shape
- H01L2224/48091—Arched
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- H01L24/42—Wire connectors; Manufacturing methods related thereto
- H01L24/44—Structure, shape, material or disposition of the wire connectors prior to the connecting process
- H01L24/45—Structure, shape, material or disposition of the wire connectors prior to the connecting process of an individual wire connector
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- H01L24/42—Wire connectors; Manufacturing methods related thereto
- H01L24/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L24/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
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- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/00014—Technical content checked by a classifier the subject-matter covered by the group, the symbol of which is combined with the symbol of this group, being disclosed without further technical details
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- H01L2924/01046—Palladium [Pd]
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- H01L2924/01078—Platinum [Pt]
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- H01L2924/01—Chemical elements
- H01L2924/01079—Gold [Au]
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- H01L2924/11—Device type
- H01L2924/12—Passive devices, e.g. 2 terminal devices
- H01L2924/1204—Optical Diode
- H01L2924/12042—LASER
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- H01L2924/11—Device type
- H01L2924/12—Passive devices, e.g. 2 terminal devices
- H01L2924/1204—Optical Diode
- H01L2924/12044—OLED
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- H01L2924/10—Details of semiconductor or other solid state devices to be connected
- H01L2924/11—Device type
- H01L2924/14—Integrated circuits
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- H—ELECTRICITY
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- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/15—Details of package parts other than the semiconductor or other solid state devices to be connected
- H01L2924/151—Die mounting substrate
- H01L2924/1515—Shape
- H01L2924/15153—Shape the die mounting substrate comprising a recess for hosting the device
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- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
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- H01L2924/15165—Monolayer substrate
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- H01L2924/15—Details of package parts other than the semiconductor or other solid state devices to be connected
- H01L2924/151—Die mounting substrate
- H01L2924/153—Connection portion
- H01L2924/1531—Connection portion the connection portion being formed only on the surface of the substrate opposite to the die mounting surface
- H01L2924/15311—Connection portion the connection portion being formed only on the surface of the substrate opposite to the die mounting surface being a ball array, e.g. BGA
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- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/15—Details of package parts other than the semiconductor or other solid state devices to be connected
- H01L2924/151—Die mounting substrate
- H01L2924/153—Connection portion
- H01L2924/1532—Connection portion the connection portion being formed on the die mounting surface of the substrate
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- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/15—Details of package parts other than the semiconductor or other solid state devices to be connected
- H01L2924/181—Encapsulation
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/18—Printed circuits structurally associated with non-printed electric components
- H05K1/182—Printed circuits structurally associated with non-printed electric components associated with components mounted in the printed circuit board, e.g. insert mounted components [IMC]
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/09—Shape and layout
- H05K2201/09009—Substrate related
- H05K2201/09127—PCB or component having an integral separable or breakable part
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/09—Shape and layout
- H05K2201/09818—Shape or layout details not covered by a single group of H05K2201/09009 - H05K2201/09809
- H05K2201/09981—Metallised walls
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/04—Soldering or other types of metallurgic bonding
- H05K2203/049—Wire bonding
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/0058—Laminating printed circuit boards onto other substrates, e.g. metallic substrates
- H05K3/0061—Laminating printed circuit boards onto other substrates, e.g. metallic substrates onto a metallic substrate, e.g. a heat sink
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49117—Conductor or circuit manufacturing
- Y10T29/49124—On flat or curved insulated base, e.g., printed circuit, etc.
- Y10T29/4913—Assembling to base an electrical component, e.g., capacitor, etc.
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49117—Conductor or circuit manufacturing
- Y10T29/49124—On flat or curved insulated base, e.g., printed circuit, etc.
- Y10T29/49155—Manufacturing circuit on or in base
Landscapes
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Production Of Multi-Layered Print Wiring Board (AREA)
- Cooling Or The Like Of Semiconductors Or Solid State Devices (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Transforming Light Signals Into Electric Signals (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
- Structure Of Printed Boards (AREA)
- Die Bonding (AREA)
- Resistance Heating (AREA)
- Led Device Packages (AREA)
- Structures For Mounting Electric Components On Printed Circuit Boards (AREA)
- Wire Bonding (AREA)
Description
經濟部中央標準局員工消費合作社印製 A7 ______B7 ~~~ ~〜 1.發明領域 本發明係概括地關於引線接合型晶片之有機晶片載體。 2 ·相關技術敘述 半導體積體電路裝置(下文中轉爲半導體晶片或僅稱爲晶 片)的電氣包裝一般係將一個或幾個晶片貼置於—諸如礬土 等陶瓷晶片載體基底上,並使用引線接合以便將各晶片上 的輸入/輸出(input/output I/O)接觸墊電氣連接至陶瓷晶片载 體基底上的對應接觸墊(並從而連接至對應之扇出電路)。其 結果的陶瓷晶片載體則再貼置在印刷電路板(pcB)或印刷電 路卡(PCC)上,並藉此(經由1>(:3或1>(:(:上之電路)電氣連接 到貼置在PCB或PCC上的其他此類陶瓷晶片載體及/或其他 電子元件。 ' 雖然上述包裝方法當然很有用,但使用陶瓷晶片載體的確 會有某些限制與缺點。例如,如已知的實況,電氣信號推 進通過介電層上一引線或二介電層之間引線的速率正比於 介電層或諸介電層之介電常數的均方値倒數。但是陶瓷的 介電常數卻相當大,譬如礬土的介電常數約爲9,此會導致 陶免晶片載艟的信號推進速率相當低,且在某些情況下低 得不能接受。 陶瓷晶片載體基底之使用亦導致某些〗/〇限制。例如,單 層陶竞晶片載體基底僅包括單一層的扇出電路在單陶瓷層 的上侧表面,延伸至圍繞該單一陶瓷層外側週邊之接觸墊 。(一接線框之内側接線連接至這些週邊接觸墊,且該種接 線框一般被用以將此種陶瓷晶片載體電氣連接至PCB或PCc • 4 - 本紙張尺度適财g ®家標準(CNS >A4規格(公着了 (請先閔讀背面之注意事項再填育本頁) .裝. -訂- 1 • - ^1» Hi - · 301795 A7 B7五、發明説明(2 ) ~ 經濟部中央標準局貝工消費合作社印装 。)但當晶片I/O數目増加時,就需要增加扇出化線數目 從而減少扇出引線間之間隔,該間隔減少的程度小接 扇出引線間的不良串音變得無法接受。此外,要 資層外側週邊形成對應的大量接㈣即使*是何能, 愈形困難。故單層陶资晶片載體基底在處理高1/〇晶片方面 的能力確實受到限制。 容納具有相當大量1/0之晶片的企圖導致使用採取所謂球 格降列(ban gdd an:ay BGA)代替接線框之多層H晶片載 體基底。it些型式的陶瓷晶片載體基底異於單層陶瓷晶片 載體基底,因其在二個或更多個构瓷層上包括二個或更多 個扇出電路層。重要的是’這些扇出電路層被以機械方式 穿孔而在電氣上相互連接,這些孔被導電材料電鍍並/或填 无。此外,這些孔中的某一些自扇出電路層延伸至降落在 ^片載體基底的底部上,纟晶片g基底的底部上貼置有 銲球(諸銲球形成格子陣列,所以稱爲球格陣列)。這些銲球 之作用疋在機械上或電氣上連接PCB或pcc上對應的可銲接 接觸墊。然而用來在電氣上相互連接諸扇出電路層之機械 錄孔有相當大的直徑,故要求扇出引線間的間隔相當大。 仁此種扇出引線間相當大的間隔限制了此種多層陶瓷I晶片 載體基底所能容納的晶片I/O數目。 包裝具有相當大數量晶片I/O之晶片的其他企圖導致使用 多層陶瓷基底中之多段空穴。(本文中所指”空穴”是基底内 的—個凹陷而非延伸穿透基底厚度的孔。)當使用此種包裝 型態時’一晶片面朝上貼置在多段空穴的底部。引線接合 本紙張尺度適用中國國家橾隼(CNS ) A4規格(210>〇97公釐〉 • tl^i ^I裝— (請先閲讀背面之注意事項再填驾本頁) 訂. 7 經濟部中央標準局員工消费合作社印製 A7 B7 五、發明説明(3 ) 從阳片上側表面上的I/O接觸誓延伸至構成多段空穴之不同 段的多層陶瓷基底之不同層的暴露在外之各上側表面上的 接觸墊《雖然此種型態確實使容納相當大數量的晶片1/0成 爲可能’但其造成相當長的引線接合自晶片延伸至多段空 穴的諸上側段。結果對應電氣信號之"飛越時間"不良地増 加。 陶瓷:晶片載體在其散熱能力方面亦受限制。譬如在晶片置 於多段空穴底部之多層陶瓷晶片載體的情形下,散熱一般 係藉提供一直接在空穴下方的散熱片來達成。但此表示晶 片產生的熱量在達到散熱片之前;必須傳導通過空穴底部之 陶瓷層。結果就限制了散熱率。 故從事於晶片載體開發者迄今尚未成功地尋找到符合下 列條件之晶片載體:(1)呈現相當高的電氣信號推進速率; (2)容納相當高的I/O之晶片,同時在相互連接扇出電路之諸 不同層時避免需要機械鋒孔;(3)呈現相當短的,,飛越時間" •,及(4)呈現相當高的散熱率。 發明概述 本發明係關於一種晶片載體,該種晶片載體:(丨)呈現相 當高的電氣信號推進速率;(2)容納相當高的I/O之晶片,同 時在相互連接扇出電路之諸不同層時避免需要機械鑽孔;(3) 避免使用相當長的引線接合,並藉此達成相當短的"飛越時 間";及(4)達成相當高的散熱率。 重要的是’本發明性晶片載體採用諸如以FR4及DriClad 商標銷售之環乳基樹脂/玻璃形式的有機介電材料代替陶竞 -6 - 本紙伕尺度適用中國國家橾準(CNS ) A4規格(210X297公釐) --------叫裝丨丨 (請先閱讀背面之注意事項再填驾本頁) 訂 -泉_ Β7 五、發明説明(4 介電材料。這些有機材料有相當低的介電常數,誓如FR4之 介電常數爲4.0。結果使本發明性晶片載體呈現相當高的電 氣信號推進速率。 —本發明性晶片載體亦採用—有機可光學成像之介電層做爲 薄膜重分配層(film redistributi〇n layer FRL)。亦即此特殊 有機a電層對光敏感,且正如光阻劑般輕易地選擇性地透 過-覆罩曝光並顯影以在可光學成像介電層内形成通過孔( 此處稱爲光通路以有別於機械鑽穿的通過孔)。重要的是, ^•些光通路可輕易地形成,而其直徑遠小於使用傳統機械 鑽孔技術形成之通路的直徑如,傳統鑽孔通路孔的直 徑一般不小於约仟分之12英吋(〇〇12英吋),而光通路的直 徑可小到諸如仟分之2英吋(0.002英吋)。所以當此種可光學 成像介電層(或諸介電層)包含在本發明性晶片載體内時,就 有可能相互連接2(或更多)層扇出電路,而其對諸扇出引線 間間隔的限制程度低於使用機械鑽孔通路者。結果使本發 明性晶片載體所容纳的晶片具有之1/0數大於傳統陶竞晶 載體所可能具有的。 - 本發明性晶片載體進一步採用單段空穴以容納—晶片而 經濟部中央橾準局員工消費合作社印製 不採用多段空穴。結果避免了相當長的引線接合。從而使 本,發明性晶片㈣對應電氣信號而言達成相當短的"飛越時 間"〇 在本發明的一種具體實例中’熱通路孔配置在單段空穴下 方,延伸至晶片載體底部以將晶片產生的熱放出。在另V 一 種具趙㈣中…錢片直接配£在熱通路孔的下面以進 本紙張尺度適用中國國家標準(CNS ) A4規格(21〇χ297公釐 A7 B7 301795 五、發明説明(5 :步提昇教熱率。還有另-種具趙實例,晶片載趙包括一 諸如銅的金屬層當做教熱器且單段空穴之深度延伸至一甚 至進入金屬層。此會使空穴中的晶片與散熱器間有實體的 直接接觸,從而造成甚至更大的散熱率。 在另-種具體實例中,本發明性晶片載體包括至少二個 有機層,而有-接地平面夾層在其間。與此種具雜實例關 聯之單段空穴的深度延伸至少到該接地平面。重要的是, 此具體實例#包括一幾乎連續的金屬;裒,該金屬環環繞空 穴的侧壁並垂直延伸到晶片載體的頂部表面。此金屬環之 存在是有益的,因爲其容許輕易'的電氣接觸至接地平面, 同時又避免需要讓一機械鑽洞通路孔延伸至接地平面。結 果可使諸扇出引線間的間隔有利地縮減。 圖式簡述 本發明將參考諸附圖而描述,其中: 圖1是本發明性晶片載體之第一種具體實例的截面圖 圖2是本發明性晶片載體之第二種具體實例的截面圖 圖3是本發明性晶片載體之第三種具體實例的截面圖 圖4是本發明性晶片載體之第四種具體實例的截面圖 圖5是本發明性晶片載體之第五種具體實例的截面圖;且 圖6是一基底的頂視圖,描寫用以製造本發明性晶片載體 之第五種具體實例的程序。 較佳具體實例詳述 本發明係關於一種引線接合型晶片之晶片載體,該發明 性晶片載體:(1)呈現相當高的電氣信號推進速率;(2)輕易 本紙張尺度遑用中國國家揉準(CNS ) Α4洗格(210X297公釐) 請 先I W I 讀 | I 面 I 之 # 1 I | 項 I 再叫 f裝 頁 訂 Λ 輕濟部中央棣準局員工消費合作社印製 五'發明説明(6 A7 B7 經濟部中央標準局貝工消費合作社印製 地容納相當高I/O的晶片;⑴避免需要長引線接合,藉此達 成使電氣信號推進通過引線接合之,,飛越時間"相當短;且(4) 達成相當高的散熱率。 如上所述,本發明性晶片載趙達成相當高的電氣推進速 率,因其採用諸如以FR4及DriClad商標銷售之環基樹脂/玻 璃形式的有機材料取代陶瓷材料。本發明性晶片載體亦輕 易地容納相當高U0之晶片,因其採用至少一個有機可光學 成像介電層,在該介電層中已形成有光通路且其作用是做 爲一薄膜重分佈層(film redistribution layer FRL)以在電氣 上相互連接二(或更多)層扇出電蛤?本發明性晶片載體避免 了相當長的引線接合,並從而達成在電氣信號推進通過引 線接合時間相當短的’,飛越時間",因其採用單段空穴來容納 晶片而不採用多段空穴。此外,本發明性晶片載體的某些 具體實例亦在緊靠晶片下方包括諸如熱通道或一層金屬物 質以提昇熱傳導》 現參考圖1,本發明性晶片載體1 〇的第一種具链實例包括 具有相對表面30與40的晶片載體基底20。此基底2〇亦包括 許多·例如3—個積層有機介電層50、6〇及7〇,該等有機介電 層係由例如以FR4及DriClad商標銷售之環氧基樹脂/玻璃形 式構成的。雖然未清楚地顯示於圖1,有機介電層5〇的作用 是支律一層例如是銅的扇出電路8〇。夾層在有機介電層 與60之間的是一層例如是銅的電氣導通物質9〇,做爲—電 源平面。夾層在有機介電層60與70之間的是另一層例如是 銅的電氣導通物質100,做爲一接地平面。 c请先閱讀背面之注意事項再填鳴本页) τ 装. 訂 -9- A7 B7 經濟部中央標準局貝工消費合作杜印製 五、發明説明( 各個有機介電層50、60與70之厚度範圍由約什 到約什分之2㈣H約什分之如的厚度是不好;^ 因爲對應的有機介電層將會不良地脆弱,不可靠且難 理。大於約仟分之20英忖的厚度是不好的,因爲如此厚的 介電層-般非必要且要鑽通路孔進人如此厚的層也很困難 〇 各個電氣導通物質層8〇(扇出電路)、9〇(電源平面)及1〇〇( 接地平面)之厚度範圍由約什分之0125英吋到約仟分之2 5 英对。小於仟分之0.!25英叶的厚度是不好的,因爲對應的 電氣導通層時常證明爲不能忍耐毐片載體所將承受之溫度 變動型態。大於約仟分之2.5英吋的厚度是不好的,因2使 用傳統電鍍技術需要不利地花很長的時間來形成如此厚的 層,且伴隨線寬控制的困難度大幅提昇。 如圖1中所示,晶片載體基底20亦包括—覆蓋在扇出電路 層80上的有機可光學成像介電層11〇β層11〇的-種有用的 合成品例如是以納入本案供卓參之第5,026,624號美國專利 中所述材料爲基礎之可光學或像可陽離子聚合環氧基樹脂 。此特殊材料包括環氧基樹脂系統,其基本上包含重量在 約10%到80%之多羥基樹脂(環氧氣丙烷之濃縮產品)及分子 量在約40,000到130,000間之雙酚八;重量在約20。/。與約90〇/〇 之間分子量從4,000到1〇,〇〇〇的環氧化八功能雙酚a甲醛紛接 樹脂·’且右要求火焰防止,則重量在約3 5 %與5 0 %之間、软 化點在約60 C與約110°C之間、且分子量在約600與2,500之 間的四溴雙酚A之環氧化縮水甘油醚。此種樹脂系統的每 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先聞讀背面之注意事項再填驾本頁) 訂 經濟部中央標準局貝工消費合作社印製 A7 ______B7_ 五、發明説明(8 ) 100份重量被加入約0.1至約15份重量的陽離子光激發劑,該 陽離子激發劑能夠在暴露於陽離子輕射中時激發該環氧化 樹脂系統之聚合·,該系統尚有一特點爲對仟分之2 0英吋厚 度的薄膜在330到700毫微米範圍有小於〇..1的光吸收度。另 可依需要加入諸如二莕嵌苯及其衍生物或並三笨及其衍生 物之光敏感化劑。 有機可光學成像介電層110可輕易地使用諸如簾狀塗膜或 乳輕塗膜等傳統塗膜技術沈殿安置。光學可成像介電層 之厚度範圍從約仟分之2英吋到約仟分之2〇英吋。小於什分 之2英吋的厚度是不好的,因爲要、形成如此薄層又要達成期 望的光學成像及介電特性很困難。大於仟分之2〇英对的厚 度是不好的’因在此厚層内形成小的光通路很困難。 使用傳統的光學平版印刷技術,可光學成像介電層丨1〇可 透過一光罩輕易地選擇性曝光、然後顯影以在層11〇内形成 如圖1所示之光通路120。(請注意被曝光區域進行交叉連妹 ,故而在顯劑下較未被曝光區域不可溶解。)然後可使用傳 統電鍍技術將這些光通路120輕易地用諸如銅等導電材料電 錄0 雖然未清晰地顯示於圖丨,可光學成像介電層11〇支撑—層 包括接觸墊之諸如銅的扇出電路13〇β很明顯的是,可光學 成像介電層110内之電鍍光通路120的作用是電氣相互連接 扇出電路的130與80層。重要的是,如上文所述,光通路的 直徑小於機械鑽孔通路洞的直徑。結果使扇出引線間的 隔可小於以前的情況。 -11 - 財關家標準((2獻297公產) ^訂--------^-^ (請先閏讀背面之注意事項再填驾本頁) 五、發明説明(9 ) 如圖1所示,晶片載體基底20包括一單段空穴14〇,該單 段空穴140之深度僅延伸穿過可光學成像介電層11〇之厚度 。一引線接合型晶片150面朝上放置在空穴的底部,其諸引 線接合160從晶片150上的諸接觸墊延伸到扇出電路13〇層之 諸接觸墊。 較佳的是,如圖1中所示,晶片載體基底2〇包括(機械鑽孔 的)熱通路孔170,該等熱通路孔17〇位於緊貼晶片15〇下方並 延伸穿過有機層80、90及1〇〇的厚度。這些熱通路孔17〇之 作用在將晶片150產生之熱量排出至大氣中,故而其作用可 提昇散熱率。(請注意這些熱通路·札最好填以加銀環氧基樹 脂糊以提昇熱傳導率。請亦注意在製造的最後階段中,一 層銲接覆罩材料加諸晶片載體1〇的表面4〇,故此銲接覆罩 材料蓋在加銀環氧基樹脂糊上。) 熱通路孔170的直徑範圍從約仟分之6英吋到約仟分之丨之英 吋。小於約仟分之6英吋的直徑是不好的,因爲對應的熱通 路孔達成的熱傳導太小。大於約仟分之12英吋的直徑是不 好的,因爲與對應熱通路孔中加銀環氧基樹脂糊接觸的銲 接覆罩材料層會破碎’且置於其上的晶片會從晶片載體基 底上鬆税。 如圖1中所示般,叩片載體基底2〇尚包括許多個用機械鑽 孔之電鍍通路孔180。每個此種孔18〇終止於表面4〇,通路 孔180在該處被附接至表面4〇的諸如銅之導電擋圈19〇圍繞 。表4〇上亦附接有許多個導電墊2〇〇以及將墊2〇〇連接至電 鍵通路孔180之例如是銅的電路線(未顯示)。貼置在擔圈ι9〇 .經濟部中央標準局員工消費合作社印製 A7 ----一___ B7 五、發明説明(10 ) 與導電墊200上的是銲球210,每個銲球的成份包括例如67% 的鉛和33%的錫◊很明顯的是,這些銲球將附接至pcB或 pcc上的可銲接接觸墊。 現參照圖2,晶片載體1〇的第二種具體實例與第一種具體 實例的差異在於單段空穴140之深度亦延伸穿過例如有機層 80與90。此外,一散熱器22〇附接至表面4〇而大致垂直對齊 於晶片150與熱通路孔no。而且,銲球21〇附接至表面3〇上 的擋圏與接觸塾。 現參考圖3,晶片載體1〇的第三種具體實例與第一種及第 二種具體實例的差異在於晶片載韙基底2〇包括—緊鄰表面 3〇的相當厚之可光學成像介電層11〇,及—緊鄰表面4〇的例 如是銅的金屬材料層230.此處金屬材料層23〇的—部份作用 是做爲補強層且最好是在電氣上接地。另_方面,如前文 所述般,可光學成像介電層110支承一層包含接觸墊之扇出 電路130。此外’可光學成像介電層11〇包括光通路12〇延伸 穿過層110之厚度到達在電氣上接地之金屬層230。而且, 銲球210附接至扇出電路層13〇之某些接觸墊。 如圖3中所示,晶片載體1〇的第三種具體實例包括一單段 空穴140延伸穿過可光學成像介電層11〇之厚度到達金屬材 料層230。一引線接合型晶片15〇安置在空穴14〇的底部,故 與金屬層230直接實際接觸,結果使散熱度獲得提昇,因爲 金屬層230亦當做一熱散器。 在晶片載體10的此第三種具體實例中,可光學成像介電 層110之厚度範圍從約仟分之2英吋到约什分之2〇英吋。此 -13- 本紙伕尺度適用中國國家揉準(CNS ) A4規格(2丨〇 χ 公釐) — (請先閲讀背面之注意事項再填窝本頁) ,1Τ A' 301795五、發明説明(11 ) A7 B7 經濟部中央標準局負工消費合作社印製 範園以外之厚度是不好的,其原因如上文所述。 金屬層230之厚度範圍從約仟分之4英吋到約仟分之2〇英吋 。厚度小於仟分之4英吋是不好的,因爲對應的金屬層缺乏 剛性而不佳。厚度大於仟分之2〇英吋是不好的,因爲對應 金屬層之熱脹係數(coefficients of thermal expansion CTE) 主導了對應晶片載體基底之CTE,此會導致晶片載體基底 與對應晶片間CTE的不配合,進而導致晶片破裂。 現參考圖4,晶片載體10的第四種具體實例與第三種具體 實例的差異在於可光學成像介電層U0相當薄,且金屬層 230相當厚。此外,單段空穴14〇之深度延伸穿過可光學成 像層110之全部厚度並部份穿過金屬層230的厚度。 在晶片載體10之第四種具體實例中,可光學成像介電層 110之厚度仍維持在約仟分之2英吋到約什分之2〇英忖範圍 中。超過此範圍之厚度因上文所述相同原因而不佳。 金屬層230之(全部)厚度仍在從約什分之4英吋到約仟分之 2〇英叶的範圍内。超過此範圍之厚度亦因上文所述相 因而不佳。 緊接在空穴140下方的金屬層230之(部份)厚度應至少约仟 分之4英忖。小於仟分之4英吋的厚度是不好的,因爲對庶 金屬層的剛性會太低》 〜 現參考圖5 ’晶片載體1〇的第五種具體實例類似於第— 與第二種具體實例的地方是晶片載體基底2〇包括許多-例3 3-層積層有機介電層5〇、60及70,該等介電層例如由口 DriClad商標銷售之環氧基樹脂/玻璃合成物。如前所迷, 以 有 -- (請先聞讀背面之注意事項再填驾本頁)
*1T -14- 良紙張;^度適用中國國家榡準(CNS ) A4規格(210X297公釐) 經濟部中央標準局員工消费合作社印製 A7 B7 五、發明説明(12 ) 機介電層50支撑一包括有接觸墊之扇出電路層80〇夹層在 有機介電層50與60之間的是一諸如銅之電氣導通材料層90 ,該導電層90在本範例中做爲一接地平面。夬層在有機介 電層60與70之間的是另一諸如銅之做爲電源平面的電氣導 通材料層1〇〇。請注意接地平面側向延伸至空穴140之側壁 ,而電源平面則否。 有機介電層50、60與70之厚度類似於上文所述者。而且電 氣導通層80(扇出電路)、90(接地平面)及100(電源平面)之厚 度亦類似於上文所述者。 晶片載體1〇的第五種具體實例>類似於第三種與第四種 具體實例的地方是晶片載體基底20亦包括一最好是被接地 的金屬層230。金屬層230之厚度類似於第三種具體實例中 的金屬層230者。 如圖5中所亲者,晶片載體10的第五種具體實例亦包括一 單段空穴140,該單段空穴140之深度延伸穿過有機介電層 50、60及70的厚度而達金屬層230。一晶片150座落在空穴 140的底部,且所以與金屬層230直接實體接觸。結果提昇 了散熱率,因爲如上文所述般,金屬層230當做一散熱器。 重要的是,晶片載體10的第五種具體實例與其他具體實 例差異處在於其包括一幾乎連續的例如是銅的電氣導通材 料層240,該導電層240附接至並包圍空穴140之側壁。此層 240自空穴140的底部垂直延伸至空穴140的頂部,並側向延 伸於有機介電層50的上側表面上而鄰接於扇出電路層80。 因爲接地平面90側向延伸至空穴140的側壁,故層240與接 -15 - 本紙張尺度適用中國國家標準(CNS ) A4規格(2丨0X297公釐) (請先聞讀背面之注意事項再填驾本頁) 訂 五、發明説明() 地平面直接貫體並在電氣上接觸,所以在電氣上接地。 層240之存在是有利的,因爲縮減了許多個機械鍊洞通路 孔延伸穿過有機介電層50的厚度到達接地平面之需要。故 右某些晶片接觸整要在電氣上接地,則來自這些晶片接觸 墊的引線接合被延伸到有機介電層50之表面上的層240之部 份,而不延伸到環繞延伸至接地平面9〇之機械鑽洞通路孔 的擋圈。因爲在第五種具體實例中僅需要很少此種機械鑽 洞通路孔,故諸扇出引線間之間隔可有利地縮減。 請注意晶片載體10的第五種具體實例包括一機械鑽洞的 電鍍通路孔180延伸穿過有機介電、層5〇與6〇的厚度而達電源 平面100。而且第五種具體實例亦包括一例如是銅的金屬環 250圍繞空穴140並在實體上與電氣上接觸延伸至電源平面 1〇〇的電鍍通路孔180。此環25〇是有益的,因爲其免除了額 外延伸至電源平面之通路孔的需要。故在電氣上與電源平 面100之接觸僅藉電氣接觸環250即達成。 經濟部中央標準局貝工消費合作社印製 ^-- f請先聞讀背面之注意事硕再填寫本頁} -β 圖6顯示形成層240與環250的一種方法。如圖6中所示,當 形成空穴140時,二直角狹縫26〇與27〇被以機械方式切割穿 過有機介電層50、60及70的厚度。這些狹縫之寬度範圍從 約仟分之25英吋到約仟分之1〇〇英吋。這些狹缝之外側表面 界定將成爲空穴140之側壁。然後有一層光阻劑28〇沈澱在 有機介電層50之表面上。接著將此光阻層曝光並顯影以便 將光阻劑田下涵盘全邵的有機介電層5〇,除了狹縫2 與 27〇、有機介電層50表面上要被層240佔據之區域241、及要 被環250佔據之區域251。(請注意此層光阻劑係由被狹缝 16- B7 五、發明説明(Μ ) 與270環繞之有機介電材料層支撑^ )然後,狹縫260與270、 要被層240佔據之區域241、以及要被環250佔據之區域被使 用傳統的種晶法及金屬電鍍技術金屬化。接著以機械方式 切割穿過狹缝260與270之中心線,這些切割延伸以便結合 這些中心線,然後移除切割掉的材料。如此可造成空穴14 0 ,並有金屬幾乎連續地延伸(除了諸狹縫在開始時未延伸的 空穴角落之外)環繞空穴140之諸側壁。 雖然本發明已參考其較佳具體實例特別顯示並敘述,精於 本技術領域者當了解其中可進行各種形式與細節的修改而 不背離本發明之精神與範疇。 ^装 訂 ^ (請先閱讀背面之注意事項再填驾本頁) 經濟部中央標準局員工消費合作社印製 -17- 本紙張尺度適用中國國家揉準(CNS ) A4规格(210X 297公釐)
Claims (1)
- 301795 8 8 88 ABCD 經濟部中央標準局員工消費合作社印製 六、申請專利範圍 1. 一種晶片載體,包括: 一晶片載體基底*該晶片載體基底包括一.第一表面、 一相對於該第一表面之第二表面、至少第一及第二有機材 料層,該第一層緊鄰該第一表面且支承一包含有接觸整之 第一電路層,有一第二電氣導通材料層夹層在該第一與第 二有機材料層之間,該晶片載體基底亦包括一緊鄰該第 二表面之金屬材料層; 一單段空穴,該單段空穴之深度從該第一表面向該第二 表面延伸,該深度延伸至少達該金屬材料層; 一半導體晶片,該半導體晶片舞上地位在該空穴内部且 接觸該金屬材料層,該晶片包括晶片接觸墊與自該等晶片 接觸墊延伸至該第一電路層之接觸墊的引線接合;及 一電氣導通材料區域,該導電區域在電氣上與該第二電 氣導通材料層接觸,且至少部份圍繞該空穴之側壁並延伸 至該第一表面上,一引線接合亦自該晶片延伸至該第一表 面上之該區域的一部份。 2. 根據申請專利範圍第1項之晶片載體,其中該第二電氣導 通材料層在電氣上接地。 3. 根據申請專利範圍第1項之晶片載體,其中該第一電路層 包括許多個電氣導通墊及/或擋圈,且其中該晶片載體尚 包括附接至該等墊及/或擋圈之銲球。 -18- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先閱讀背面之注意事項再填驾本頁) -裝- 訂· 泉
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US08/390,344 US5798909A (en) | 1995-02-15 | 1995-02-15 | Single-tiered organic chip carriers for wire bond-type chips |
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- 1995-11-29 TW TW085109810A patent/TW301795B/zh not_active IP Right Cessation
- 1995-11-29 TW TW084112717A patent/TW297935B/zh not_active IP Right Cessation
- 1995-12-11 CA CA002164901A patent/CA2164901C/en not_active Expired - Fee Related
- 1995-12-29 KR KR1019950067685A patent/KR100213955B1/ko not_active IP Right Cessation
-
1996
- 1996-01-10 SG SG1996000133A patent/SG34493A1/en unknown
- 1996-01-17 CZ CZ19972256A patent/CZ286385B6/cs not_active IP Right Cessation
- 1996-01-17 PL PL96321595A patent/PL179061B1/pl not_active IP Right Cessation
- 1996-01-17 WO PCT/EP1996/000180 patent/WO1996025763A2/en active IP Right Grant
- 1996-01-17 EP EP96901290A patent/EP0809862B1/en not_active Expired - Lifetime
- 1996-01-17 HU HU9702316A patent/HU216982B/hu not_active IP Right Cessation
- 1996-01-17 DE DE69605286T patent/DE69605286T2/de not_active Expired - Lifetime
- 1996-01-17 ES ES96901290T patent/ES2139330T3/es not_active Expired - Lifetime
- 1996-01-17 AT AT96901290T patent/ATE187014T1/de not_active IP Right Cessation
- 1996-01-17 RU RU97115245A patent/RU2146067C1/ru active
- 1996-01-31 MY MYPI96000367A patent/MY140232A/en unknown
- 1996-02-02 CN CN96102102A patent/CN1041470C/zh not_active Expired - Fee Related
- 1996-02-08 JP JP02231696A patent/JP3297287B2/ja not_active Expired - Fee Related
- 1996-05-21 US US08/655,323 patent/US5724232A/en not_active Expired - Fee Related
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- 1997-06-06 US US08/870,848 patent/US6038137A/en not_active Expired - Lifetime
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SG34493A1 (en) | 1996-12-06 |
PL321595A1 (en) | 1997-12-08 |
DE69605286D1 (de) | 1999-12-30 |
US5724232A (en) | 1998-03-03 |
JPH08241936A (ja) | 1996-09-17 |
WO1996025763A3 (en) | 1996-11-07 |
MY140232A (en) | 2009-12-31 |
US6038137A (en) | 2000-03-14 |
JP3297287B2 (ja) | 2002-07-02 |
WO1996025763A2 (en) | 1996-08-22 |
EP0809862B1 (en) | 1999-11-24 |
ATE187014T1 (de) | 1999-12-15 |
CA2164901C (en) | 2003-02-11 |
CN1205548A (zh) | 1999-01-20 |
HUP9702316A3 (en) | 1998-12-28 |
CN1134601A (zh) | 1996-10-30 |
CZ286385B6 (cs) | 2000-03-15 |
KR100213955B1 (ko) | 1999-08-02 |
PL179061B1 (pl) | 2000-07-31 |
TW297935B (zh) | 1997-02-11 |
EP0809862A2 (en) | 1997-12-03 |
HU216982B (hu) | 1999-10-28 |
ES2139330T3 (es) | 2000-02-01 |
DE69605286T2 (de) | 2000-05-25 |
KR960032659A (ko) | 1996-09-17 |
HUP9702316A2 (hu) | 1998-03-02 |
US5599747A (en) | 1997-02-04 |
CN1041470C (zh) | 1998-12-30 |
US5798909A (en) | 1998-08-25 |
RU2146067C1 (ru) | 2000-02-27 |
CZ225697A3 (cs) | 1998-01-14 |
CA2164901A1 (en) | 1996-08-16 |
CN1150613C (zh) | 2004-05-19 |
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