TW200728249A - Manufacture method of isobutene and tert-butanol - Google Patents

Manufacture method of isobutene and tert-butanol

Info

Publication number
TW200728249A
TW200728249A TW095140458A TW95140458A TW200728249A TW 200728249 A TW200728249 A TW 200728249A TW 095140458 A TW095140458 A TW 095140458A TW 95140458 A TW95140458 A TW 95140458A TW 200728249 A TW200728249 A TW 200728249A
Authority
TW
Taiwan
Prior art keywords
manufacture method
butanol
tert
isobutene
tba
Prior art date
Application number
TW095140458A
Other languages
English (en)
Other versions
TWI322797B (zh
Inventor
Tatsuo Yamaguchi
Hiroyuki Noda
Toru Watanabe
Toshiya Kirino
Original Assignee
Asahi Kasei Chemicals Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Kasei Chemicals Corp filed Critical Asahi Kasei Chemicals Corp
Publication of TW200728249A publication Critical patent/TW200728249A/zh
Application granted granted Critical
Publication of TWI322797B publication Critical patent/TWI322797B/zh

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/009—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in combination with chemical reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053—Details of the reactor
    • B01J19/0066—Stirrers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/08—Alkenes with four carbon atoms
    • C07C11/09—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18—Details relating to the spatial orientation of the reactor
    • B01J2219/185—Details relating to the spatial orientation of the reactor vertical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
TW095140458A 2005-11-01 2006-11-01 Manufacture method of isobutene and tert-butanol TW200728249A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2005317904 2005-11-01
JP2005373789 2005-12-27

Publications (2)

Publication Number Publication Date
TW200728249A true TW200728249A (en) 2007-08-01
TWI322797B TWI322797B (zh) 2010-04-01

Family

ID=38005657

Family Applications (3)

Application Number Title Priority Date Filing Date
TW098119272A TWI483922B (zh) 2005-11-01 2006-11-01 三級丁醇之製造方法及三級丁醇之連續製造裝置
TW095140458A TW200728249A (en) 2005-11-01 2006-11-01 Manufacture method of isobutene and tert-butanol
TW103144662A TWI537240B (zh) 2005-11-01 2006-11-01 三級丁醇之連續製造裝置

Family Applications Before (1)

Application Number Title Priority Date Filing Date
TW098119272A TWI483922B (zh) 2005-11-01 2006-11-01 三級丁醇之製造方法及三級丁醇之連續製造裝置

Family Applications After (1)

Application Number Title Priority Date Filing Date
TW103144662A TWI537240B (zh) 2005-11-01 2006-11-01 三級丁醇之連續製造裝置

Country Status (8)

Country Link
US (3) US8637716B2 (zh)
EP (2) EP2266939B1 (zh)
JP (2) JP5240988B2 (zh)
KR (1) KR100969616B1 (zh)
CN (2) CN101300211B (zh)
SG (1) SG158189A1 (zh)
TW (3) TWI483922B (zh)
WO (1) WO2007052505A1 (zh)

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JP5410052B2 (ja) * 2008-09-03 2014-02-05 東ソー株式会社 硫酸鉄の生成抑制方法
EP2394732B1 (en) * 2009-02-03 2021-03-31 Nippon Shokubai Co., Ltd. Method for regenerating filter
DE102009026585A1 (de) * 2009-05-29 2010-12-02 Evonik Oxeno Gmbh Herstellung von 3-Methylbut-1-en durch Dehydratisierung von 3-Methylbutan-1-ol
US9266792B2 (en) 2009-07-29 2016-02-23 The United States Of America As Represented By The Secretary Of The Navy Process and apparatus for the selective dimerization of terpenes and alpha-olefin oligomers with a single-stage reactor and a single-stage fractionation system
US8785702B2 (en) 2009-07-29 2014-07-22 The United States Of America As Represented By The Secretary Of The Navy Turbine and diesel fuels and methods for making the same
US9649626B2 (en) 2009-07-29 2017-05-16 The United States Of America As Represented By The Secretary Of The Navy Process for the dehydration of aqueous bio-derived terminal alcohols to terminal alkenes
US9242226B2 (en) 2009-07-29 2016-01-26 The Government Of The United States Of America As Represented By The Secretary Of The Navy Process for the dehydration of aqueous bio-derived terminal alcohols to terminal alkenes
US8912373B2 (en) 2009-07-29 2014-12-16 The United States Of America As Represented By The Secretary Of The Navy Process for the dehydration of aqueous bio-derived terminal alcohols to terminal alkenes
US20120209047A1 (en) 2009-07-29 2012-08-16 Wright Michael E Homogeneous metallocene ziegler-natta catalysts for the oligomerization of olefins in aliphatic-hydrocarbon solvents
WO2011054703A1 (de) * 2009-11-03 2011-05-12 Basf Se Verfahren zur handhabung von wässrigen methansulfonsäurelösungen
EP2578559A1 (en) 2011-10-07 2013-04-10 Metabolic Explorer Process for producing isobutene from isobutylamine
WO2014204509A1 (en) * 2013-06-18 2014-12-24 Washington State University Process and catalyst for conversion of acetic acid to isobutene and propylene
WO2014092849A1 (en) * 2012-12-14 2014-06-19 Washington State University Process and catalyst for conversion of acetic acid to isobutene
SG10201809230YA (en) * 2014-05-07 2018-11-29 Mitsubishi Chem Corp Method for producing isobutylene from isobutanol
SG11201704201VA (en) 2014-12-03 2017-06-29 China Petroleum & Chem Corp Catalyst and preparation method thereof, and method for preparing isobutylene by applying the same
KR20170035621A (ko) * 2015-09-23 2017-03-31 롯데케미칼 주식회사 터트-부탄올로부터 이소부틸렌의 제조 방법
CN105732326A (zh) * 2016-03-18 2016-07-06 安徽三联泵业股份有限公司 一种利用树脂处理正丁醇生产废液的方法
KR102080381B1 (ko) * 2018-01-09 2020-02-21 한화토탈 주식회사 알루미늄과 코발트를 중심원소로 하는 헤테로폴리산 촉매, 그 제조방법 및 상기 촉매를 이용하여 n-부텐의 수화반응으로부터 2-부탄올을 제조하는 방법
JP7020623B2 (ja) * 2018-03-27 2022-02-16 株式会社クラレ イソブテンの製造方法
FR3084267B1 (fr) 2018-07-25 2021-10-08 Axens Alumine a acidite et structure de porosite optimales
CN109096026B (zh) * 2018-08-28 2021-07-06 宁波昊德化学工业股份有限公司 一种异丁烯的生产方法

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Also Published As

Publication number Publication date
KR20080046735A (ko) 2008-05-27
EP2266939B1 (en) 2016-09-28
EP1944282A1 (en) 2008-07-16
US9919283B2 (en) 2018-03-20
TW200940486A (en) 2009-10-01
US8637716B2 (en) 2014-01-28
US20090124835A1 (en) 2009-05-14
TWI537240B (zh) 2016-06-11
CN102516030A (zh) 2012-06-27
TW201514139A (zh) 2015-04-16
CN101300211B (zh) 2012-10-17
TWI483922B (zh) 2015-05-11
KR100969616B1 (ko) 2010-07-14
US20150360198A1 (en) 2015-12-17
EP1944282B1 (en) 2016-06-29
JP5582621B2 (ja) 2014-09-03
JP5240988B2 (ja) 2013-07-17
TWI322797B (zh) 2010-04-01
JPWO2007052505A1 (ja) 2009-04-30
SG158189A1 (en) 2010-01-29
US20140107387A1 (en) 2014-04-17
EP2266939A1 (en) 2010-12-29
CN102516030B (zh) 2016-05-04
US9145342B2 (en) 2015-09-29
JP2013006864A (ja) 2013-01-10
WO2007052505A1 (ja) 2007-05-10
EP1944282A4 (en) 2009-05-06
CN101300211A (zh) 2008-11-05

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