RU2413739C2 - Непрерывный способ получения и установка для получения ароматического поликарбоната - Google Patents
Непрерывный способ получения и установка для получения ароматического поликарбоната Download PDFInfo
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- RU2413739C2 RU2413739C2 RU2009106679/05A RU2009106679A RU2413739C2 RU 2413739 C2 RU2413739 C2 RU 2413739C2 RU 2009106679/05 A RU2009106679/05 A RU 2009106679/05A RU 2009106679 A RU2009106679 A RU 2009106679A RU 2413739 C2 RU2413739 C2 RU 2413739C2
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- Russia
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- starting materials
- polycondensation
- aromatic polycarbonate
- stage
- group
- Prior art date
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- 125000003118 aryl group Chemical group 0.000 title claims abstract description 163
- 229920000515 polycarbonate Polymers 0.000 title claims abstract description 126
- 239000004417 polycarbonate Substances 0.000 title claims abstract description 126
- 238000011437 continuous method Methods 0.000 title claims abstract description 13
- 238000006068 polycondensation reaction Methods 0.000 claims abstract description 97
- 239000003054 catalyst Substances 0.000 claims abstract description 76
- 239000000203 mixture Substances 0.000 claims abstract description 43
- 239000000155 melt Substances 0.000 claims abstract description 9
- 239000007858 starting material Substances 0.000 claims description 132
- 238000005809 transesterification reaction Methods 0.000 claims description 63
- 238000002360 preparation method Methods 0.000 claims description 44
- 238000002156 mixing Methods 0.000 claims description 42
- 150000004650 carbonic acid diesters Chemical class 0.000 claims description 36
- 150000001875 compounds Chemical class 0.000 claims description 28
- 239000000654 additive Substances 0.000 claims description 15
- 150000005690 diesters Chemical class 0.000 claims description 15
- -1 phosphorus compound Chemical class 0.000 claims description 13
- 238000012546 transfer Methods 0.000 claims description 12
- 238000009434 installation Methods 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 9
- 229920005992 thermoplastic resin Polymers 0.000 claims description 8
- 150000001339 alkali metal compounds Chemical class 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 150000001639 boron compounds Chemical class 0.000 claims description 5
- 125000004122 cyclic group Chemical group 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 3
- 150000003868 ammonium compounds Chemical class 0.000 claims description 3
- 150000002681 magnesium compounds Chemical class 0.000 claims description 3
- 125000003545 alkoxy group Chemical group 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000003368 amide group Chemical group 0.000 claims description 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
- 125000004185 ester group Chemical group 0.000 claims description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 3
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- 238000000034 method Methods 0.000 abstract description 29
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 abstract description 10
- 230000006866 deterioration Effects 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 6
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- 239000006227 byproduct Substances 0.000 description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 238000006243 chemical reaction Methods 0.000 description 18
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 13
- 238000011068 loading method Methods 0.000 description 13
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 11
- 239000008187 granular material Substances 0.000 description 11
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- FJDQFPXHSGXQBY-UHFFFAOYSA-L caesium carbonate Chemical compound [Cs+].[Cs+].[O-]C([O-])=O FJDQFPXHSGXQBY-UHFFFAOYSA-L 0.000 description 8
- 229910000024 caesium carbonate Inorganic materials 0.000 description 8
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- 230000000996 additive effect Effects 0.000 description 7
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- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 6
- QYJXDIUNDMRLAO-UHFFFAOYSA-N butyl 4-methylbenzenesulfonate Chemical compound CCCCOS(=O)(=O)C1=CC=C(C)C=C1 QYJXDIUNDMRLAO-UHFFFAOYSA-N 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
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- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
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- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 3
- 229910052790 beryllium Inorganic materials 0.000 description 3
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- 150000002148 esters Chemical class 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
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- ICSNLGPSRYBMBD-UHFFFAOYSA-N 2-aminopyridine Chemical compound NC1=CC=CC=N1 ICSNLGPSRYBMBD-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
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- 238000012695 Interfacial polymerization Methods 0.000 description 2
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 2
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- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
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- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
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- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
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- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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| JP5245272B2 (ja) * | 2007-03-29 | 2013-07-24 | 三菱化学株式会社 | 芳香族ポリカーボネートの製造方法 |
| KR101557709B1 (ko) | 2007-07-31 | 2015-10-06 | 미쓰비시 가가꾸 가부시키가이샤 | 폴리카보네이트 수지 및 그의 제조방법 |
| JP6019667B2 (ja) * | 2011-03-31 | 2016-11-02 | 三菱化学株式会社 | ポリカーボネート樹脂の製造方法 |
| CN102558534B (zh) * | 2011-12-29 | 2013-11-27 | 中蓝晨光化工研究设计院有限公司 | 一种酯交换法连续生产聚碳酸酯的工艺 |
| JP6167570B2 (ja) * | 2012-03-30 | 2017-07-26 | 三菱ケミカル株式会社 | 芳香族ポリカーボネートの製造方法及び製造設備 |
| DE102012105296A1 (de) | 2012-06-19 | 2013-12-19 | Epc Engineering Consulting Gmbh | Verfahren und Anlage zur Herstellung von Polycarbonat |
| KR102292786B1 (ko) | 2013-07-16 | 2021-08-23 | 미츠비시 가스 가가쿠 가부시키가이샤 | α-하이드록시아이소뷰티르산 아마이드의 제조 방법 및 반응 장치 |
| WO2015145381A1 (en) | 2014-03-27 | 2015-10-01 | Sabic Global Technologies B.V. | Melt polymerization polycarbonate quenching |
| JP6646398B2 (ja) * | 2014-10-21 | 2020-02-14 | 旭化成株式会社 | 芳香族ポリカーボネートの製造方法 |
| KR102272484B1 (ko) * | 2014-11-19 | 2021-07-05 | 사빅 글로벌 테크놀러지스 비.브이. | 말단 캡핑된 폴리카보네이트의 중합 방법 및 이로부터 제조된 말단 캡핑된 폴리카보네이트 |
| EP3341118B1 (en) | 2015-08-25 | 2021-12-29 | ExxonMobil Chemical Patents Inc. | Reactor system for multi-phase polymerization process |
| KR102184849B1 (ko) * | 2017-10-12 | 2020-12-01 | 가부시끼가이샤 구레하 | 중합체의 연속 제조 장치 및 연속 제조 방법 |
| EP3581605A1 (de) * | 2018-06-14 | 2019-12-18 | Covestro Deutschland AG | Schmelzeumesterungsverfahren zur gleichzeitigen herstellung mindestens zweier verschiedenartiger polycarbonate in einer produktionsanlage |
| CN108707224B (zh) * | 2018-06-26 | 2020-06-16 | 北京濮源新材料技术研究院(普通合伙) | 环境友好型聚碳酸酯及其制备方法 |
| CN112912419A (zh) | 2018-10-11 | 2021-06-04 | Sabic环球技术有限责任公司 | 制备聚碳酸酯的方法 |
| KR102871455B1 (ko) | 2018-10-11 | 2025-10-14 | 사빅 글로벌 테크놀러지스 비.브이. | 폴리카보네이트 |
| CN110964190B (zh) * | 2019-11-06 | 2022-09-16 | 濮阳市盛通聚源新材料有限公司 | 一种用于聚碳酸酯合成工艺中的原料输送及调配装置 |
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| RU2040532C1 (ru) * | 1988-12-27 | 1995-07-25 | Асахи Касеи Когио Кабусики Кайся | Способ получения кристаллического ароматического поликарбонатного форполимера и способ получения высокомолекулярного кристаллического ароматического поликарбоната |
| JP2001226478A (ja) * | 2000-02-15 | 2001-08-21 | Mitsubishi Chemicals Corp | 芳香族ポリカーボネートの製造方法 |
| WO2001060889A1 (en) * | 2000-02-18 | 2001-08-23 | General Electric Company | Method for preparation of polycarbonates |
| JP2003192782A (ja) * | 2001-12-25 | 2003-07-09 | Asahi Kasei Corp | ポリカーボネートの連続製造方法 |
| JP2004026916A (ja) * | 2002-06-24 | 2004-01-29 | Asahi Kasei Chemicals Corp | 複数のポリカーボネートの連続製法 |
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|---|---|---|---|---|
| US6252034B1 (en) * | 1998-06-04 | 2001-06-26 | Teljin Limited | Process for producing a polycarbonate resin |
| ES2177384A1 (es) * | 2000-02-18 | 2002-12-01 | Ge Plastics De Espana S Com P | Procedimiento de preparacion de policarbonatos |
| JP2003012792A (ja) * | 2001-06-29 | 2003-01-15 | Teijin Ltd | ポリカーボネートの製造方法および装置 |
| JP2003138002A (ja) * | 2001-11-02 | 2003-05-14 | Teijin Ltd | 芳香族ポリカーボネートの製造方法 |
| CN1564837B (zh) † | 2002-04-22 | 2010-05-26 | 三菱化学株式会社 | 芳香族聚碳酸酯、其制造方法、聚碳酸酯组合物及由该组合物得到的中空容器 |
| JP3958634B2 (ja) * | 2002-06-14 | 2007-08-15 | 帝人化成株式会社 | 芳香族ポリカーボネート樹脂の製造方法およびその製造装置 |
| EP1548064B1 (en) * | 2002-09-30 | 2015-08-12 | Mitsubishi Engineering-Plastics Corporation | Process for producing molded product of polycarbonate-based resin and use of polycarbonate-based resin composition for extrusion molding using sizing die |
| JP2006203616A (ja) | 2005-01-21 | 2006-08-03 | Rohm Co Ltd | イメージセンサモジュール |
| JP2006324382A (ja) | 2005-05-18 | 2006-11-30 | Seiko Epson Corp | 固体撮像装置 |
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2006
- 2006-11-30 JP JP2006324382A patent/JP5332100B2/ja active Active
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2007
- 2007-05-22 KR KR1020087028336A patent/KR20090034807A/ko not_active Ceased
- 2007-05-22 BR BRPI0714701-5A patent/BRPI0714701B1/pt not_active IP Right Cessation
- 2007-05-22 RU RU2009106679/05A patent/RU2413739C2/ru active
- 2007-05-22 US US12/375,136 patent/US7999056B2/en active Active
- 2007-05-22 EP EP07743897.6A patent/EP2048181B2/en active Active
- 2007-05-22 CN CN2007800184588A patent/CN101448872B/zh active Active
- 2007-05-22 WO PCT/JP2007/060463 patent/WO2008012987A1/ja not_active Ceased
- 2007-05-22 ES ES07743897.6T patent/ES2390601T5/es active Active
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2040532C1 (ru) * | 1988-12-27 | 1995-07-25 | Асахи Касеи Когио Кабусики Кайся | Способ получения кристаллического ароматического поликарбонатного форполимера и способ получения высокомолекулярного кристаллического ароматического поликарбоната |
| JP2001226478A (ja) * | 2000-02-15 | 2001-08-21 | Mitsubishi Chemicals Corp | 芳香族ポリカーボネートの製造方法 |
| WO2001060889A1 (en) * | 2000-02-18 | 2001-08-23 | General Electric Company | Method for preparation of polycarbonates |
| JP2003192782A (ja) * | 2001-12-25 | 2003-07-09 | Asahi Kasei Corp | ポリカーボネートの連続製造方法 |
| JP2004026916A (ja) * | 2002-06-24 | 2004-01-29 | Asahi Kasei Chemicals Corp | 複数のポリカーボネートの連続製法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101448872A (zh) | 2009-06-03 |
| TWI439488B (zh) | 2014-06-01 |
| EP2048181A1 (en) | 2009-04-15 |
| EP2048181B2 (en) | 2016-04-13 |
| US20100273973A1 (en) | 2010-10-28 |
| EP2048181A4 (en) | 2010-03-31 |
| WO2008012987A1 (en) | 2008-01-31 |
| TW200806706A (en) | 2008-02-01 |
| KR20090034807A (ko) | 2009-04-08 |
| CN101448872B (zh) | 2011-06-15 |
| US7999056B2 (en) | 2011-08-16 |
| EP2048181B1 (en) | 2012-08-29 |
| BRPI0714701B1 (pt) | 2018-09-25 |
| JP2008050558A (ja) | 2008-03-06 |
| ES2390601T5 (es) | 2016-04-29 |
| RU2009106679A (ru) | 2010-09-10 |
| BRPI0714701A2 (pt) | 2012-12-25 |
| JP5332100B2 (ja) | 2013-11-06 |
| ES2390601T3 (es) | 2012-11-14 |
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