BRPI0714701B1 - método de produção contínua de um policarbonato aromático - Google Patents
método de produção contínua de um policarbonato aromático Download PDFInfo
- Publication number
- BRPI0714701B1 BRPI0714701B1 BRPI0714701A BRPI0714701A BRPI0714701B1 BR PI0714701 B1 BRPI0714701 B1 BR PI0714701B1 BR PI0714701 A BRPI0714701 A BR PI0714701A BR PI0714701 A BRPI0714701 A BR PI0714701A BR PI0714701 B1 BRPI0714701 B1 BR PI0714701B1
- Authority
- BR
- Brazil
- Prior art keywords
- raw material
- aromatic polycarbonate
- polycondensation
- aromatic
- ester exchange
- Prior art date
Links
- 125000003118 aryl group Chemical group 0.000 title claims abstract description 160
- 229920000515 polycarbonate Polymers 0.000 title claims abstract description 127
- 239000004417 polycarbonate Substances 0.000 title claims abstract description 127
- 238000000034 method Methods 0.000 title claims abstract description 41
- 238000010924 continuous production Methods 0.000 title claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 130
- 238000006068 polycondensation reaction Methods 0.000 claims abstract description 91
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 75
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- 239000003054 catalyst Substances 0.000 claims abstract description 69
- 150000002148 esters Chemical group 0.000 claims abstract description 66
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 41
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 41
- 239000000203 mixture Substances 0.000 claims abstract description 40
- 238000002360 preparation method Methods 0.000 claims description 47
- 238000006243 chemical reaction Methods 0.000 claims description 33
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- 238000003723 Smelting Methods 0.000 description 2
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- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 159000000009 barium salts Chemical class 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- QSRFYFHZPSGRQX-UHFFFAOYSA-N benzyl(tributyl)azanium Chemical compound CCCC[N+](CCCC)(CCCC)CC1=CC=CC=C1 QSRFYFHZPSGRQX-UHFFFAOYSA-N 0.000 description 1
- QCRBMEFNXGBPLL-UHFFFAOYSA-M benzyl(triphenyl)azanium;hydroxide Chemical compound [OH-].C=1C=CC=CC=1[N+](C=1C=CC=CC=1)(C=1C=CC=CC=1)CC1=CC=CC=C1 QCRBMEFNXGBPLL-UHFFFAOYSA-M 0.000 description 1
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- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
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- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- SXVFRTBMWHHATP-UHFFFAOYSA-M butyl(triphenyl)azanium;hydroxide Chemical compound [OH-].C=1C=CC=CC=1[N+](C=1C=CC=CC=1)(CCCC)C1=CC=CC=C1 SXVFRTBMWHHATP-UHFFFAOYSA-M 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
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- 229930016911 cinnamic acid Natural products 0.000 description 1
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- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- FHESUNXRPBHDQM-UHFFFAOYSA-N diphenyl benzene-1,3-dicarboxylate Chemical compound C=1C=CC(C(=O)OC=2C=CC=CC=2)=CC=1C(=O)OC1=CC=CC=C1 FHESUNXRPBHDQM-UHFFFAOYSA-N 0.000 description 1
- HPGJOUYGWKFYQW-UHFFFAOYSA-N diphenyl benzene-1,4-dicarboxylate Chemical compound C=1C=C(C(=O)OC=2C=CC=CC=2)C=CC=1C(=O)OC1=CC=CC=C1 HPGJOUYGWKFYQW-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- ODCCJTMPMUFERV-UHFFFAOYSA-N ditert-butyl carbonate Chemical compound CC(C)(C)OC(=O)OC(C)(C)C ODCCJTMPMUFERV-UHFFFAOYSA-N 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- KVFVBPYVNUCWJX-UHFFFAOYSA-M ethyl(trimethyl)azanium;hydroxide Chemical compound [OH-].CC[N+](C)(C)C KVFVBPYVNUCWJX-UHFFFAOYSA-M 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 229960004979 fampridine Drugs 0.000 description 1
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- 235000019253 formic acid Nutrition 0.000 description 1
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- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 150000002440 hydroxy compounds Chemical class 0.000 description 1
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 1
- TVZISJTYELEYPI-UHFFFAOYSA-N hypodiphosphoric acid Chemical compound OP(O)(=O)P(O)(O)=O TVZISJTYELEYPI-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 235000011160 magnesium carbonates Nutrition 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical class [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 235000012254 magnesium hydroxide Nutrition 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- VUQUOGPMUUJORT-UHFFFAOYSA-N methyl 4-methylbenzenesulfonate Chemical compound COS(=O)(=O)C1=CC=C(C)C=C1 VUQUOGPMUUJORT-UHFFFAOYSA-N 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- KPTPYMHWVGAEGG-UHFFFAOYSA-M methyl(triphenyl)azanium;hydroxide Chemical compound [OH-].C=1C=CC=CC=1[N+](C=1C=CC=CC=1)(C)C1=CC=CC=C1 KPTPYMHWVGAEGG-UHFFFAOYSA-M 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
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- ODKLEQPZOCJQMT-UHFFFAOYSA-N n,n-diethylpyridin-4-amine Chemical compound CCN(CC)C1=CC=NC=C1 ODKLEQPZOCJQMT-UHFFFAOYSA-N 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
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- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
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- KJIFKLIQANRMOU-UHFFFAOYSA-N oxidanium;4-methylbenzenesulfonate Chemical compound O.CC1=CC=C(S(O)(=O)=O)C=C1 KJIFKLIQANRMOU-UHFFFAOYSA-N 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
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- 229940081066 picolinic acid Drugs 0.000 description 1
- OXNIZHLAWKMVMX-UHFFFAOYSA-N picric acid Chemical compound OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
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- 239000001294 propane Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
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- 235000002906 tartaric acid Nutrition 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 description 1
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 description 1
- LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 description 1
- IGNTWNVBGLNYDV-UHFFFAOYSA-N triisopropylphosphine Chemical compound CC(C)P(C(C)C)C(C)C IGNTWNVBGLNYDV-UHFFFAOYSA-N 0.000 description 1
- HADKRTWCOYPCPH-UHFFFAOYSA-M trimethylphenylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C1=CC=CC=C1 HADKRTWCOYPCPH-UHFFFAOYSA-M 0.000 description 1
- 229950002929 trinitrophenol Drugs 0.000 description 1
- KCTAHLRCZMOTKM-UHFFFAOYSA-N tripropylphosphane Chemical compound CCCP(CCC)CCC KCTAHLRCZMOTKM-UHFFFAOYSA-N 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/205—General preparatory processes characterised by the apparatus used
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/1856—Stationary reactors having moving elements inside placed in parallel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/1862—Stationary reactors having moving elements inside placed in series
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/20—Stationary reactors having moving elements inside in the form of helices, e.g. screw reactors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/30—General preparatory processes using carbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/30—General preparatory processes using carbonates
- C08G64/307—General preparatory processes using carbonates and phenols
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
- B01J2219/00083—Coils
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00094—Jackets
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polyesters Or Polycarbonates (AREA)
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| JP2006-203616 | 2006-07-26 | ||
| JP2006324382A JP5332100B2 (ja) | 2006-07-26 | 2006-11-30 | 芳香族ポリカーボネートの連続製造方法及び製造装置 |
| JP2006-324382 | 2006-11-30 | ||
| PCT/JP2007/060463 WO2008012987A1 (en) | 2006-07-26 | 2007-05-22 | Process and apparatus for continuously producing aromatic polycarbonate |
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| BRPI0714701A2 BRPI0714701A2 (pt) | 2012-12-25 |
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| JP5245272B2 (ja) * | 2007-03-29 | 2013-07-24 | 三菱化学株式会社 | 芳香族ポリカーボネートの製造方法 |
| SG183052A1 (en) | 2007-07-31 | 2012-08-30 | Mitsubishi Chem Corp | Polycarbonate resins and methods for preparing the same |
| JP6019667B2 (ja) * | 2011-03-31 | 2016-11-02 | 三菱化学株式会社 | ポリカーボネート樹脂の製造方法 |
| CN102558534B (zh) * | 2011-12-29 | 2013-11-27 | 中蓝晨光化工研究设计院有限公司 | 一种酯交换法连续生产聚碳酸酯的工艺 |
| JP6167570B2 (ja) * | 2012-03-30 | 2017-07-26 | 三菱ケミカル株式会社 | 芳香族ポリカーボネートの製造方法及び製造設備 |
| DE102012105296A1 (de) | 2012-06-19 | 2013-12-19 | Epc Engineering Consulting Gmbh | Verfahren und Anlage zur Herstellung von Polycarbonat |
| KR102292786B1 (ko) | 2013-07-16 | 2021-08-23 | 미츠비시 가스 가가쿠 가부시키가이샤 | α-하이드록시아이소뷰티르산 아마이드의 제조 방법 및 반응 장치 |
| EP3122819B1 (en) | 2014-03-27 | 2023-07-19 | SABIC Global Technologies B.V. | Melt polymerization polycarbonate quenching technical field |
| JP6646398B2 (ja) * | 2014-10-21 | 2020-02-14 | 旭化成株式会社 | 芳香族ポリカーボネートの製造方法 |
| US10106648B2 (en) * | 2014-11-19 | 2018-10-23 | Sabic Global Technologies B.V. | Method of polymerizing end-capped polycarbonate and end-capped polycarbonates derived therefrom |
| CA2996496C (en) | 2015-08-25 | 2021-01-12 | Exxonmobil Chemical Patents Inc. | Reactor system for multi-phase polymerization process |
| JP6668506B2 (ja) * | 2017-10-12 | 2020-03-18 | 株式会社クレハ | 重合体の連続製造装置および連続製造方法 |
| EP3581605A1 (de) | 2018-06-14 | 2019-12-18 | Covestro Deutschland AG | Schmelzeumesterungsverfahren zur gleichzeitigen herstellung mindestens zweier verschiedenartiger polycarbonate in einer produktionsanlage |
| CN108707224B (zh) * | 2018-06-26 | 2020-06-16 | 北京濮源新材料技术研究院(普通合伙) | 环境友好型聚碳酸酯及其制备方法 |
| KR102871455B1 (ko) | 2018-10-11 | 2025-10-14 | 사빅 글로벌 테크놀러지스 비.브이. | 폴리카보네이트 |
| WO2020074983A1 (en) | 2018-10-11 | 2020-04-16 | Sabic Global Technologies B.V. | Method for the manufacture of polycarbonate |
| CN110964190B (zh) * | 2019-11-06 | 2022-09-16 | 濮阳市盛通聚源新材料有限公司 | 一种用于聚碳酸酯合成工艺中的原料输送及调配装置 |
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| US6252034B1 (en) * | 1998-06-04 | 2001-06-26 | Teljin Limited | Process for producing a polycarbonate resin |
| JP3694434B2 (ja) * | 2000-02-15 | 2005-09-14 | 三菱化学株式会社 | 芳香族ポリカーボネートの製造方法 |
| CN1310997C (zh) * | 2000-02-18 | 2007-04-18 | 通用电气公司 | 制备聚碳酸酯的方法 |
| ES2177384A1 (es) | 2000-02-18 | 2002-12-01 | Ge Plastics De Espana S Com P | Procedimiento de preparacion de policarbonatos |
| JP2003012792A (ja) * | 2001-06-29 | 2003-01-15 | Teijin Ltd | ポリカーボネートの製造方法および装置 |
| JP2003138002A (ja) * | 2001-11-02 | 2003-05-14 | Teijin Ltd | 芳香族ポリカーボネートの製造方法 |
| JP4386609B2 (ja) * | 2001-12-25 | 2009-12-16 | 旭化成ケミカルズ株式会社 | ポリカーボネートの連続製造方法 |
| CN101817973B (zh) † | 2002-04-22 | 2012-09-05 | 三菱化学株式会社 | 芳香族聚碳酸酯、其制造方法、聚碳酸酯组合物及由该组合物得到的中空容器 |
| JP3958634B2 (ja) * | 2002-06-14 | 2007-08-15 | 帝人化成株式会社 | 芳香族ポリカーボネート樹脂の製造方法およびその製造装置 |
| JP2004026916A (ja) * | 2002-06-24 | 2004-01-29 | Asahi Kasei Chemicals Corp | 複数のポリカーボネートの連続製法 |
| CN1681886B (zh) * | 2002-09-30 | 2010-04-21 | 三菱工程塑料株式会社 | 使用精整模的挤出成形用聚碳酸酯系树脂组合物和成形体 |
| JP2006203616A (ja) | 2005-01-21 | 2006-08-03 | Rohm Co Ltd | イメージセンサモジュール |
| JP2006324382A (ja) | 2005-05-18 | 2006-11-30 | Seiko Epson Corp | 固体撮像装置 |
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- 2007-05-22 BR BRPI0714701A patent/BRPI0714701B1/pt active IP Right Grant
- 2007-05-22 ES ES07743897.6T patent/ES2390601T5/es active Active
- 2007-05-22 WO PCT/JP2007/060463 patent/WO2008012987A1/ja not_active Ceased
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- 2007-05-22 RU RU2009106679/05A patent/RU2413739C2/ru active
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- 2007-05-22 KR KR1020087028336A patent/KR20090034807A/ko not_active Ceased
- 2007-07-16 TW TW096125798A patent/TWI439488B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| WO2008012987A1 (en) | 2008-01-31 |
| KR20090034807A (ko) | 2009-04-08 |
| TW200806706A (en) | 2008-02-01 |
| CN101448872B (zh) | 2011-06-15 |
| US7999056B2 (en) | 2011-08-16 |
| BRPI0714701A2 (pt) | 2012-12-25 |
| EP2048181B2 (en) | 2016-04-13 |
| TWI439488B (zh) | 2014-06-01 |
| EP2048181A1 (en) | 2009-04-15 |
| RU2413739C2 (ru) | 2011-03-10 |
| ES2390601T3 (es) | 2012-11-14 |
| JP2008050558A (ja) | 2008-03-06 |
| JP5332100B2 (ja) | 2013-11-06 |
| RU2009106679A (ru) | 2010-09-10 |
| CN101448872A (zh) | 2009-06-03 |
| EP2048181B1 (en) | 2012-08-29 |
| EP2048181A4 (en) | 2010-03-31 |
| US20100273973A1 (en) | 2010-10-28 |
| ES2390601T5 (es) | 2016-04-29 |
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