RU2282497C2 - Носитель катализатора для эпоксидирования олефина и способ его изготовления - Google Patents

Носитель катализатора для эпоксидирования олефина и способ его изготовления Download PDF

Info

Publication number
RU2282497C2
RU2282497C2 RU2004126091/04A RU2004126091A RU2282497C2 RU 2282497 C2 RU2282497 C2 RU 2282497C2 RU 2004126091/04 A RU2004126091/04 A RU 2004126091/04A RU 2004126091 A RU2004126091 A RU 2004126091A RU 2282497 C2 RU2282497 C2 RU 2282497C2
Authority
RU
Russia
Prior art keywords
carrier
pores
mixture
carrier according
alpha alumina
Prior art date
Application number
RU2004126091/04A
Other languages
English (en)
Russian (ru)
Other versions
RU2004126091A (ru
Inventor
Томас ЖИМАНСКИ (US)
Томас Жимански
Доналд Дж. РЕМУС (US)
Доналд Дж. РЕМУС
Джон Р. ЛОКЕМЕЙЕР (US)
Джон Р. Локемейер
Рэндалл Клэйтон ЙЕТС (US)
Рэндалл Клэйтон ЙЕТС
Уиль м Х. ГЕРДС (US)
Уильям Х. ГЕРДС
Original Assignee
Сент-Гобэн Керамикс Энд Пластикс, Инк.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Сент-Гобэн Керамикс Энд Пластикс, Инк. filed Critical Сент-Гобэн Керамикс Энд Пластикс, Инк.
Publication of RU2004126091A publication Critical patent/RU2004126091A/ru
Application granted granted Critical
Publication of RU2282497C2 publication Critical patent/RU2282497C2/ru

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/14—Pore volume
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter
    • C01P2006/17—Pore diameter distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/90—Other properties not specified above

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
RU2004126091/04A 2002-02-25 2003-02-25 Носитель катализатора для эпоксидирования олефина и способ его изготовления RU2282497C2 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/082,761 US6831037B2 (en) 2002-02-25 2002-02-25 Catalyst carriers
US10/082,761 2002-02-25

Publications (2)

Publication Number Publication Date
RU2004126091A RU2004126091A (ru) 2005-05-27
RU2282497C2 true RU2282497C2 (ru) 2006-08-27

Family

ID=27753171

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2004126091/04A RU2282497C2 (ru) 2002-02-25 2003-02-25 Носитель катализатора для эпоксидирования олефина и способ его изготовления

Country Status (15)

Country Link
US (3) US6831037B2 (enExample)
EP (2) EP1478458B1 (enExample)
JP (2) JP5139622B2 (enExample)
KR (1) KR100591031B1 (enExample)
CN (1) CN100531897C (enExample)
AU (1) AU2003216412A1 (enExample)
BR (1) BR0307963B1 (enExample)
CA (1) CA2477067C (enExample)
DK (1) DK1478458T3 (enExample)
IN (1) IN2004CH01883A (enExample)
MX (1) MXPA04008258A (enExample)
MY (1) MY130801A (enExample)
RU (1) RU2282497C2 (enExample)
TW (1) TWI228433B (enExample)
WO (1) WO2003072244A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2476266C2 (ru) * 2007-08-27 2013-02-27 Сд Лиценцфервертунгсгезелльшафт Мбх Унд Ко.Кг Способ получения олефиноксида
RU2623436C1 (ru) * 2016-06-02 2017-06-26 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук Носитель для катализаторов на основе оксида алюминия и способ его приготовления

Families Citing this family (70)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6831037B2 (en) * 2002-02-25 2004-12-14 Saint-Gobain Norpro Corporation Catalyst carriers
US7176160B2 (en) * 2002-10-16 2007-02-13 Conocophillips Company Method for forming a Fischer-Tropsch catalyst using a boehmite support
US7341976B2 (en) * 2002-10-16 2008-03-11 Conocophillips Company Stabilized boehmite-derived catalyst supports, catalysts, methods of making and using
EP1675678B1 (en) 2003-10-16 2011-09-28 Dow Technology Investments LLC Catalysts having enhanced stability, efficiency and/or activity for alkylene oxide production
US7566428B2 (en) * 2005-03-11 2009-07-28 Saint-Gobain Ceramics & Plastics, Inc. Bed support media
US20060204414A1 (en) * 2005-03-11 2006-09-14 Saint-Gobain Ceramics & Plastics, Inc. Bed support media
US7507844B2 (en) * 2005-05-09 2009-03-24 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Nanometer scale restructuring of alumina carrier surface and catalysts for the production of alkene oxides
US7825062B2 (en) 2005-06-07 2010-11-02 Saint-Gobain Ceramics & Plastics, Inc. Catalyst carrier and a process for preparing the catalyst carrier
BRPI0611676B1 (pt) 2005-06-07 2015-08-11 Shell Int Research Catalisador, processo para a preparação do catalisador, e processo para a produção de um óxido de olefina, um 1,2- diol, e um 1,2-diol éter e uma alcanolamina
AU2006278461A1 (en) 2005-08-03 2007-02-15 Ccmi Corporation Enhancement of surface-active solid-phase heterogeneous catalysts
US8791280B2 (en) * 2005-08-10 2014-07-29 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Process for preparation of catalyst carrier and its use in catalyst preparation
CN100577289C (zh) * 2006-01-28 2010-01-06 中国石油化工股份有限公司 环氧乙烷生产用银催化剂的载体、其制备方法及其应用
US20070280877A1 (en) * 2006-05-19 2007-12-06 Sawyer Technical Materials Llc Alpha alumina supports for ethylene oxide catalysts and method of preparing thereof
US7932408B2 (en) * 2006-09-29 2011-04-26 Scientific Design Company, Inc. Catalyst with bimodal pore size distribution and the use thereof
JP4267015B2 (ja) 2006-09-29 2009-05-27 株式会社日本触媒 エチレンオキシド製造用触媒およびエチレンオキシドの製造方法
US7977274B2 (en) * 2006-09-29 2011-07-12 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof
CN101573180A (zh) 2006-11-20 2009-11-04 国际壳牌研究有限公司 处理载体的方法、制备催化剂的方法、催化剂及催化剂的用途
US7714152B2 (en) * 2007-08-30 2010-05-11 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Carrier for olefin oxide catalyst
US7910518B2 (en) * 2008-03-10 2011-03-22 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Geometrically sized solid shaped carrier for olefin epoxidation catalyst
US8349765B2 (en) 2008-07-18 2013-01-08 Scientific Design Company, Inc. Mullite-containing carrier for ethylene oxide catalysts
CA2759390C (en) 2009-04-21 2017-08-22 Dow Technology Investments Llc Methods for enhancing the efficiency of rhenium-promoted epoxidation catalysts and epoxidation methods utilizing these
KR20120003942A (ko) * 2009-04-21 2012-01-11 다우 테크놀로지 인베스트먼츠 엘엘씨. 레늄-촉진된 에폭시화 촉매, 및 이의 제조 및 사용 방법
KR101745736B1 (ko) * 2009-04-21 2017-06-09 다우 테크놀로지 인베스트먼츠 엘엘씨. 에폭시화 반응 및 이의 조작 조건
CA2749938C (en) 2009-12-28 2018-10-16 Dow Technology Investments Llc Method of controlling the production of silver chloride on a silver catalyst in the production of alkylene oxides
CA2793500C (en) 2010-03-17 2019-01-15 Dow Technology Investments Llc Catalytic fixed bed reactor for producing ethylene oxide by partial oxidation of ethylene
US8586769B2 (en) * 2010-06-04 2013-11-19 Scientific Design Company, Inc. Carrier for ethylene oxide catalysts
US8884037B2 (en) 2010-12-10 2014-11-11 Dow Technology Investments Llc Method of reducing the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst
SG190901A1 (en) 2010-12-15 2013-07-31 Dow Technology Investments Llc Method of starting-up a process of producing an alkylene oxide using a high-efficiency catalyst
JP5957005B2 (ja) * 2010-12-29 2016-07-27 サン−ゴバン セラミックス アンド プラスティクス，インコーポレイティド マルチローブ多孔質セラミック体およびその製造方法
KR20120080361A (ko) * 2011-01-07 2012-07-17 에스케이이노베이션 주식회사 합성가스 전환용 촉매로 코팅된 여과 구조물 및 이를 이용한 여과방법
US9227174B2 (en) 2011-04-21 2016-01-05 Ceramtec Gmbh Porous aluminum oxide
US9134213B2 (en) 2011-05-30 2015-09-15 Dow Technology Investments Llc Methods for testing structures, and selection methods using these
CA2837864C (en) 2011-06-06 2019-07-23 Dow Technology Investments Llc Methods for producing epoxidation catalysts and epoxidation methods utilizing them
TWI590867B (zh) * 2011-10-14 2017-07-11 聖高拜陶器塑膠公司 催化劑及催化劑載體
US9073035B2 (en) * 2011-10-14 2015-07-07 Saint-Gobain Ceramics & Plastics, Inc. Catalyst and catalyst carrier
US9162215B2 (en) 2011-10-31 2015-10-20 Dow Technology Investments Llc Methods for producing epoxidation catalysts and epoxidation methods utilizing these
EP2788337B1 (en) 2011-12-09 2016-03-02 Dow Technology Investments LLC Method of maintaining the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst
CN104125858B (zh) 2011-12-19 2017-07-11 陶氏技术投资有限责任公司 根据催化剂参考性质配制环氧烷催化剂的方法
US9468906B2 (en) 2012-03-02 2016-10-18 Basf Se Porous inorganic body
CN104220160B (zh) 2012-03-27 2017-10-31 陶氏技术投资有限责任公司 制备含锰负载型银催化剂中间体的方法
US9079154B2 (en) 2012-05-04 2015-07-14 Basf Se Catalyst for the epoxidation of alkenes
BR112014026976A2 (pt) 2012-05-04 2017-06-27 Basf Se catalisador sem tungstênio para a epoxidação de alcenos, processo para a produção de catalisadores sem tungstênio para a epoxidação de alcenos e uso de um catalisador
CN103721696A (zh) * 2012-10-12 2014-04-16 中国石油化工股份有限公司 一种制备银催化剂用α-氧化铝载体的方法
WO2014105924A1 (en) 2012-12-31 2014-07-03 Scientific Design Company, Inc. Calcination process for producing an improved ethylene oxide catalyst
TW201442779A (zh) * 2013-02-07 2014-11-16 Scient Design Co 用於銀基環氧乙烷觸媒之經改質載體
TW201512180A (zh) 2013-05-16 2015-04-01 Scient Design Co 用於乙烯氧化物觸媒之載體
CN104437664B (zh) * 2013-09-16 2016-09-21 中国石油化工股份有限公司 一种制备α-氧化铝载体的方法
JP2017501864A (ja) 2013-12-09 2017-01-19 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ アルケンのエポキシ化用触媒
US8975424B1 (en) 2013-12-30 2015-03-10 Scientific Design Company, Inc. Zinc-promoted catalysts for epoxidation of ethylene
TWI697358B (zh) 2015-02-27 2020-07-01 美商科學設計有限公司 具有改進的銀顆粒大小和分佈密度的銀催化劑
TWI703108B (zh) * 2015-06-02 2020-09-01 美商科學設計有限公司 用於製造具有增強的性能的多孔體的方法
CN106552619A (zh) * 2015-09-28 2017-04-05 中国石油化工股份有限公司 一种α-氧化铝载体、由其制成的银催化剂及应用
CN106955745A (zh) * 2016-01-08 2017-07-18 中国石油化工股份有限公司 一种α-氧化铝载体、由其制备的银催化剂和应用
TWI772322B (zh) 2016-09-02 2022-08-01 美商陶氏科技投資有限公司 製備環氧化催化劑之方法
WO2018128639A1 (en) * 2017-01-05 2018-07-12 Scientific Design Company, Inc. Carrier, catalyst, methods for producing them and method for producing ethylene oxide
CN108499613A (zh) * 2017-02-28 2018-09-07 中国石油化工股份有限公司 氧化铝载体及其制备方法与应用
US10449520B2 (en) 2017-05-15 2019-10-22 Scientific Design Company, Inc. Porous bodies with enhanced crush strength
WO2019020793A1 (en) 2017-07-28 2019-01-31 Basf Se PROCESS FOR PRODUCING A MOLDED CATALYST BODY COMPRISING SILVER APPLIED TO AN ALUMINUM CARRIER
CN111556786A (zh) 2017-12-28 2020-08-18 陶氏技术投资有限责任公司 用于制备环氧化催化剂的方法
TWI808125B (zh) 2018-02-07 2023-07-11 德商巴斯夫歐洲公司 有效地將乙烯氧化轉化為環氧乙烷之催化劑
EP3749449B1 (en) 2018-02-07 2022-02-02 Basf Se Method for preparing a silver impregnation solution
US10676401B2 (en) 2018-04-23 2020-06-09 Scientific Design Company, Inc. Porous bodies with enhanced pore architecture prepared with oxalic acid
EP3639924A1 (en) 2018-10-15 2020-04-22 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation
EP3639923A1 (en) 2018-10-15 2020-04-22 Basf Se Process for producing ethylene oxide by gas-phase oxidation of ethylene
EP3659703A1 (en) 2018-11-28 2020-06-03 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation
JP7213198B2 (ja) * 2020-03-09 2023-01-26 日本碍子株式会社 焼成前又は焼成後の柱状ハニカム成形体を検査する方法
US20230256420A1 (en) 2020-06-26 2023-08-17 Basf Se Shaped catalyst body for the production of ethylene oxide
US20230256415A1 (en) 2020-06-26 2023-08-17 Basf Se Production of porous alpha-alumina supports from boehmitic derived aluminas
EP4171802A1 (de) 2020-06-26 2023-05-03 Basf Se Poröser katalysatorträger-formkörper
CN115475609A (zh) * 2021-06-15 2022-12-16 中国石油化工股份有限公司 一种具有高稳定性的α-氧化铝载体与银催化剂和烯烃环氧化方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0327356A1 (en) * 1988-02-03 1989-08-09 China Petrochemical Corporation High efficiency silver catalysts for the production of ethylene oxide via ethylene oxidation
US5057481A (en) * 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US5100859A (en) * 1991-01-22 1992-03-31 Norton Company Catalyst carrier
US5929259A (en) * 1996-06-05 1999-07-27 Shell Oil Company Preparation of ethylene oxide and catalyst
RU98121694A (ru) * 1996-04-30 2000-09-20 Нортон Кемикал Проусесс Продактс Корпорейшн Способ получения носителя для катализаторов
RU2157729C2 (ru) * 1996-04-30 2000-10-20 Нортон Кемикал Проусесс Продактс Корпорейшн Способ получения носителя для катализаторов
RU2225255C2 (ru) * 1998-09-14 2004-03-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Носитель катализатора эпоксидирования, его получение и применение

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2069060A (en) 1935-12-14 1937-01-26 Gen Motors Corp Alkali-free ceramic materials and method of making same
EP0003642B1 (en) 1978-02-10 1984-07-18 Imperial Chemical Industries Plc Production of olefine oxides
JPS5637050A (en) * 1979-09-04 1981-04-10 Ube Ind Ltd Preparation of catalyst for preparing unsaturated acid
US4455392A (en) 1981-10-05 1984-06-19 Union Carbide Corporation Process for preparing a supported silver catalyst
US4845296A (en) 1983-12-13 1989-07-04 Union Carbide Corporation Process for preparing alkanolamines
GB8423044D0 (en) 1984-09-12 1984-10-17 Ici Plc Production of ethylene oxide
US4551443A (en) * 1984-11-27 1985-11-05 Shell Oil Company Catalysts for the selective hydrogenation of acetylenes
US4577047A (en) * 1984-11-27 1986-03-18 Shell Oil Company Catalysts and process for the selective hydrogenation of acetylenes
JPH084745B2 (ja) 1986-05-09 1996-01-24 三菱化学株式会社 エチレンオキシド製造用銀触媒
IL84232A (en) 1986-10-31 1992-06-21 Shell Int Research Catalyst and process for the catalytic production of ethylene oxide
US4761394A (en) 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4908343A (en) 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
JP2561678B2 (ja) 1987-11-06 1996-12-11 三菱化学株式会社 エチレンオキシド製造用銀触媒
US5187140A (en) 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
ATE170425T1 (de) 1990-10-12 1998-09-15 Union Carbide Chem Plastic Alkylenoxid-katalysator mit verbesserter aktivität und/oder stabilität
US5145824A (en) 1991-01-22 1992-09-08 Shell Oil Company Ethylene oxide catalyst
CA2089510C (en) 1992-02-27 1998-09-01 Shinichi Nagase Silver catalyst for production of ethylene oxide and method for production of the catalyst
US5384302A (en) 1993-09-08 1995-01-24 Norton Chemical Process Products Corp. Catalyst carrier
US5380697A (en) 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
US5512530A (en) 1994-09-12 1996-04-30 Norton Chemical Process Products Corp. Catalyst carrier
US5739075A (en) 1995-10-06 1998-04-14 Shell Oil Company Process for preparing ethylene oxide catalysts
TW408034B (en) 1997-12-16 2000-10-11 Nippon Catalytic Chem Ind Silver catalyst for production of ethylene oxide, method for production thereof, and method for production of ethylene oxide
TW426545B (en) 1997-12-25 2001-03-21 Nippon Catalytic Chem Ind Silver catalyst for production of ethylene oxide, method for production thereof, and method for production of ethylene oxide
EP0937498B1 (en) 1998-02-20 2004-08-18 Nippon Shokubai Co., Ltd. Silver catalyst for production of ethylene Oxide, method for production thereof, and method for production of ethylene oxide
JPH11240777A (ja) 1998-02-27 1999-09-07 Sumitomo Chem Co Ltd α−アルミナ多孔質凝集焼結体、その製造方法および用途
JP2000044331A (ja) 1998-05-22 2000-02-15 Sumitomo Chem Co Ltd α―アルミナ触媒担体、その製造方法、該触媒担体を用いた触媒
AU750895B2 (en) 1998-09-14 2002-08-01 Shell Internationale Research Maatschappij B.V. Process for removing ionizable species from catalyst surface to improve catalytic properties
KR100572967B1 (ko) 1998-09-14 2006-04-24 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 개선된 촉매 성질을 지닌 촉매의 제조방법
DE60109704D1 (de) * 2000-10-25 2005-05-04 Mitsubishi Chem Corp Verfahren zur Oxidation von Olefinen unter Verwendung eines Silber und Alkalimetall(e) enthaltenden Katalysator
US6831037B2 (en) * 2002-02-25 2004-12-14 Saint-Gobain Norpro Corporation Catalyst carriers

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5057481A (en) * 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
EP0327356A1 (en) * 1988-02-03 1989-08-09 China Petrochemical Corporation High efficiency silver catalysts for the production of ethylene oxide via ethylene oxidation
US5100859A (en) * 1991-01-22 1992-03-31 Norton Company Catalyst carrier
RU98121694A (ru) * 1996-04-30 2000-09-20 Нортон Кемикал Проусесс Продактс Корпорейшн Способ получения носителя для катализаторов
RU2157729C2 (ru) * 1996-04-30 2000-10-20 Нортон Кемикал Проусесс Продактс Корпорейшн Способ получения носителя для катализаторов
US5929259A (en) * 1996-06-05 1999-07-27 Shell Oil Company Preparation of ethylene oxide and catalyst
RU2225255C2 (ru) * 1998-09-14 2004-03-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Носитель катализатора эпоксидирования, его получение и применение

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2476266C2 (ru) * 2007-08-27 2013-02-27 Сд Лиценцфервертунгсгезелльшафт Мбх Унд Ко.Кг Способ получения олефиноксида
RU2623436C1 (ru) * 2016-06-02 2017-06-26 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук Носитель для катализаторов на основе оксида алюминия и способ его приготовления

Also Published As

Publication number Publication date
WO2003072244A1 (en) 2003-09-04
CN1646219A (zh) 2005-07-27
US20040170556A1 (en) 2004-09-02
RU2004126091A (ru) 2005-05-27
EP1478458B1 (en) 2017-04-05
MXPA04008258A (es) 2005-07-13
JP5139622B2 (ja) 2013-02-06
TWI228433B (en) 2005-03-01
JP2009072787A (ja) 2009-04-09
BR0307963B1 (pt) 2013-07-09
CN100531897C (zh) 2009-08-26
KR20040095231A (ko) 2004-11-12
JP2005518275A (ja) 2005-06-23
KR100591031B1 (ko) 2006-06-22
TW200400083A (en) 2004-01-01
BR0307963A (pt) 2004-12-21
EP3254756A1 (en) 2017-12-13
EP1478458A1 (en) 2004-11-24
US20030162655A1 (en) 2003-08-28
AU2003216412A1 (en) 2003-09-09
DK1478458T3 (en) 2017-07-24
IN2004CH01883A (enExample) 2006-06-23
US20050096219A1 (en) 2005-05-05
CA2477067C (en) 2007-07-17
CA2477067A1 (en) 2003-09-04
US6831037B2 (en) 2004-12-14
MY130801A (en) 2007-07-31

Similar Documents

Publication Publication Date Title
RU2282497C2 (ru) Носитель катализатора для эпоксидирования олефина и способ его изготовления
RU2342190C2 (ru) Катализатор и способ его применения
KR100931517B1 (ko) 촉매 캐리어 및 촉매 캐리어의 제조방법
JP3727653B2 (ja) エポキシ化触媒及び方法
US8586769B2 (en) Carrier for ethylene oxide catalysts
KR20080096678A (ko) 올레핀 산화 촉매용 담체, 그 제조 방법 및 적용
US8883678B2 (en) Carrier for ethylene oxide catalysts
KR20140104446A (ko) 에틸렌 옥사이드 촉매를 위한 담체
CN115364833A (zh) 一种α-氧化铝载体及其制备方法、乙烯环氧化用银催化剂及乙烯氧化方法
JP6033124B2 (ja) エチレンオキシド製造用触媒およびエチレンオキシドの製造方法
CN114433044B (zh) 一种α-氧化铝载体及其制备方法

Legal Events

Date Code Title Description
MM4A The patent is invalid due to non-payment of fees

Effective date: 20110226