MX2017015608A - Proceso de epoxidacion. - Google Patents
Proceso de epoxidacion.Info
- Publication number
- MX2017015608A MX2017015608A MX2017015608A MX2017015608A MX2017015608A MX 2017015608 A MX2017015608 A MX 2017015608A MX 2017015608 A MX2017015608 A MX 2017015608A MX 2017015608 A MX2017015608 A MX 2017015608A MX 2017015608 A MX2017015608 A MX 2017015608A
- Authority
- MX
- Mexico
- Prior art keywords
- silver
- carrier
- temperature
- less
- epoxidation catalyst
- Prior art date
Links
- 238000006735 epoxidation reaction Methods 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 3
- 229910052709 silver Inorganic materials 0.000 abstract 3
- 239000004332 silver Substances 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000011148 porous material Substances 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 230000000977 initiatory effect Effects 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
Classifications
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- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
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- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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- B01J37/082—Decomposition and pyrolysis
- B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
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- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
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- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
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Abstract
Se proporciona un método para mejorar el rendimiento de un catalizador de plata para la epoxidación que comprende un portador. El portador incluye al menos 80 por ciento de alúmina alfa y tiene un volumen de poro de 0.3 mL/g a 1.2 Ml/g, un área de la superficie de 0.3 m2/g a 3.0 m2/g, y una arquitectura de poro que proporciona al menos uno de una tortuosidad de 7 o menos, una constricción de 4 o menos y una permeabilidad de 30 mdarcys o mayor. Una cantidad catalítica de plata y una cantidad de promotor de uno o más promotores está dispuesta sobre y/o en dicho portador. El método además incluye los pasos de iniciar una reacción de epoxidación al hacer reaccionar una composición del gas alimentado que contiene etileno y oxígeno presente en una relación de aproximadamente 3.5:1 a aproximadamente 12:1, en la presencia del catalizador de plata para la epoxidación a una temperatura de aproximadamente 200°C a aproximadamente 230°C; y subsecuentemente aumentar la temperatura ya sea "paso a paso" o de manera continua.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201562169706P | 2015-06-02 | 2015-06-02 | |
US201562169766P | 2015-06-02 | 2015-06-02 | |
PCT/US2016/035478 WO2016196767A1 (en) | 2015-06-02 | 2016-06-02 | Epoxidation process |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2017015608A true MX2017015608A (es) | 2018-08-15 |
Family
ID=57441757
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2017015502A MX2017015502A (es) | 2015-06-02 | 2016-06-02 | Metodo para producir cuerpos porosos con propiedades mejoradas. |
MX2017015503A MX2017015503A (es) | 2015-06-02 | 2016-06-02 | Cuerpos porosos con arquitectura de poro mejorada. |
MX2017015608A MX2017015608A (es) | 2015-06-02 | 2016-06-02 | Proceso de epoxidacion. |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2017015502A MX2017015502A (es) | 2015-06-02 | 2016-06-02 | Metodo para producir cuerpos porosos con propiedades mejoradas. |
MX2017015503A MX2017015503A (es) | 2015-06-02 | 2016-06-02 | Cuerpos porosos con arquitectura de poro mejorada. |
Country Status (11)
Country | Link |
---|---|
US (6) | US9776169B2 (es) |
EP (3) | EP3302751B1 (es) |
JP (3) | JP6734301B2 (es) |
KR (1) | KR20180004792A (es) |
CN (3) | CN107847836A (es) |
BR (3) | BR112017025964A2 (es) |
CA (3) | CA2987423A1 (es) |
MX (3) | MX2017015502A (es) |
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- 2016-06-02 CA CA2987427A patent/CA2987427A1/en not_active Abandoned
- 2016-06-02 EP EP16804377.6A patent/EP3302752A4/en active Pending
- 2016-06-02 BR BR112017025945A patent/BR112017025945A2/pt not_active Application Discontinuation
- 2016-06-02 WO PCT/US2016/035478 patent/WO2016196767A1/en active Application Filing
- 2016-06-02 JP JP2017561881A patent/JP2018524153A/ja active Pending
- 2016-06-02 TW TW105117473A patent/TWI703108B/zh active
- 2016-06-02 JP JP2017561884A patent/JP6824909B2/ja active Active
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2017
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