MX2015001492A - Catalizador que comprende un metal noble soportado para la epoxidacion o deshidrogenacion oxidativa. - Google Patents

Catalizador que comprende un metal noble soportado para la epoxidacion o deshidrogenacion oxidativa.

Info

Publication number
MX2015001492A
MX2015001492A MX2015001492A MX2015001492A MX2015001492A MX 2015001492 A MX2015001492 A MX 2015001492A MX 2015001492 A MX2015001492 A MX 2015001492A MX 2015001492 A MX2015001492 A MX 2015001492A MX 2015001492 A MX2015001492 A MX 2015001492A
Authority
MX
Mexico
Prior art keywords
noble metal
oxidative dehydrogenation
epoxidation
catalyst
supported noble
Prior art date
Application number
MX2015001492A
Other languages
English (en)
Inventor
Georg Seeber
Christian Baltes
Sabine Huber
Tobias Rosendahl
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of MX2015001492A publication Critical patent/MX2015001492A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/466—Osmium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0217—Pretreatment of the substrate before coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0219—Coating the coating containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0228—Coating in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/002—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by dehydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/39—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a secondary hydroxyl group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Los catalizadores que comprenden metal noble soportado que se pueden obtener mediante a1) aplicación de un compuesto de metal noble, opcionalmente en mezcla con aditivos actuando como promotores, a un material de apoyo, luego secar y a2) aplicación de un agente reductor a un material de apoyo, luego secar, donde los pasos a1) y a2) se repiten simultáneamente o en turnos alternados, o donde cualquiera de los compuestos se aplica totalmente y luego el otro se aplica en su totalidad, b) opcionalmente después del secado del producto resultante, y c) posterior calcinación, su uso, especialmente para la deshidrogenación oxidativa y un proceso para producirla.
MX2015001492A 2012-08-01 2013-07-31 Catalizador que comprende un metal noble soportado para la epoxidacion o deshidrogenacion oxidativa. MX2015001492A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261678143P 2012-08-01 2012-08-01
EP12178872 2012-08-01
PCT/EP2013/066063 WO2014020054A1 (en) 2012-08-01 2013-07-31 Supported noble metal-comprising catalyst for oxidative dehydrogenation or epoxidation

Publications (1)

Publication Number Publication Date
MX2015001492A true MX2015001492A (es) 2015-04-08

Family

ID=50027296

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015001492A MX2015001492A (es) 2012-08-01 2013-07-31 Catalizador que comprende un metal noble soportado para la epoxidacion o deshidrogenacion oxidativa.

Country Status (7)

Country Link
US (1) US9346035B2 (es)
EP (1) EP2879788A1 (es)
JP (1) JP6333249B2 (es)
CN (1) CN104507575A (es)
MX (1) MX2015001492A (es)
MY (1) MY171153A (es)
WO (1) WO2014020054A1 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112018075784B1 (pt) * 2016-06-29 2022-06-28 Basf Se Processo para preparação de aldeídos alfa, beta insaturados
CN109833909B (zh) * 2017-11-29 2022-01-07 中国科学院大连化学物理研究所 一种碱性交联共聚物负载纳米钯催化剂的制备及其应用
CN108014797B (zh) * 2017-12-08 2020-08-28 万华化学集团股份有限公司 一种用于不饱和多碳醇氧化的负载型银单原子催化剂及其制备方法
CN110064420B (zh) * 2018-01-23 2021-11-30 中国石油天然气股份有限公司 一种氧化态连续重整催化剂及其制备方法
DE102018109254A1 (de) * 2018-04-18 2019-10-24 Clariant lnternational Ltd Platin-Schalenkatalysator
CN109438197B (zh) * 2018-09-04 2021-09-07 万华化学集团股份有限公司 一种制备3-甲基-3-丁烯醛的方法
WO2021119899A1 (en) * 2019-12-16 2021-06-24 Rhodia Operations Process for producing a catalyst, catalyst and use thereof

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB941349A (en) 1962-01-15 1963-11-13 Wolfen Filmfab Veb Process for the production of catalysts
DE2020865C3 (de) 1970-04-29 1975-05-07 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von alpha, beta-ungesättigten Carbonylverbindungen
DE2715209C3 (de) 1977-04-05 1981-11-05 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von 3-Alkyl-buten-l-alen
DE3612213A1 (de) 1986-04-11 1987-10-15 Basf Ag Rohrbuendelreaktor, dessen verwendung bei exothermen organischen reaktionen und verfahren zur herstellung von ketonen und aldehyden mit hilfe des rohrbuendelreaktors
EP0357293B1 (en) 1988-08-30 1996-02-28 Union Carbide Corporation Catalysts for the production of ethylene oxide and their preparation processes
DE4311608A1 (de) 1993-04-08 1994-12-15 Huels Chemische Werke Ag Silberkatalysator zur Oxidation von Ethylen zu Ethylenoxid und Verfahren zur Herstellung von Ethylenoxid
US5488024A (en) * 1994-07-01 1996-01-30 Phillips Petroleum Company Selective acetylene hydrogenation
DE19722567A1 (de) 1997-05-28 1998-12-03 Basf Ag Verfahren zur kontinuierlichen technischen Herstellung ungesättigter aliphatischer Aldehyde in einem Rohrbündelreaktor
DE19734974A1 (de) * 1997-08-13 1999-02-25 Hoechst Ag Verfahren zur Herstellung von porös geträgerten Metall-Nanopartikel-haltigen Katalysatoren, insbesondere für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat
US6383273B1 (en) 1999-08-12 2002-05-07 Apyron Technologies, Incorporated Compositions containing a biocidal compound or an adsorbent and/or catalyst compound and methods of making and using therefor
DE102008014910A1 (de) * 2008-03-19 2009-09-24 Basf Se Verwendung eines geträgerten edelmetallhaltigen Katalysators zur oxidativen Dehydrierung
ES2675237T3 (es) * 2009-07-02 2018-07-09 Basf Se Catalizador soportado que contiene metal noble para deshidrogenación o epoxidación
JP5626161B2 (ja) * 2010-09-03 2014-11-19 三菱レイヨン株式会社 パラジウム含有触媒の製造方法、およびα，β−不飽和カルボン酸の製造方法

Also Published As

Publication number Publication date
US9346035B2 (en) 2016-05-24
JP6333249B2 (ja) 2018-05-30
CN104507575A (zh) 2015-04-08
US20150151278A1 (en) 2015-06-04
WO2014020054A1 (en) 2014-02-06
MY171153A (en) 2019-09-27
EP2879788A1 (en) 2015-06-10
JP2015529553A (ja) 2015-10-08

Similar Documents

Publication Publication Date Title
MX2015001492A (es) Catalizador que comprende un metal noble soportado para la epoxidacion o deshidrogenacion oxidativa.
GB2525486A (en) Treating of catalyst support
WO2017029572A3 (en) Improved oxidative dehydrogenation catalyst
MY171816A (en) Process for preparing fisher-tropsch catalyst
IN2012DE00662A (es)
HK1199223A1 (en) Catalytic composition and process for the dehydrogenation of butenes or mixtures of butanes and butenes to give 1,3-butadiene 13-
EP3222347A4 (en) Catalyst for oxidative dehydrogenation reaction and method for producing same
MX2015017870A (es) Procedimiento para producir 4-propargilado amino-benzoxazinonas.
SG11201406833PA (en) Catalyst for production of butadiene, process for producing the catalyst, and process for producing butadiene using the catalyst
MY164527A (en) Process for production of acrylic acid or its derivatives
WO2014199348A3 (en) Metal doped silicate catalysts for the selective conversion of ethanol to butadiene
MY180334A (en) Method for preparing fischer-tropsch catalyst having improved activity and lifespan properties
SG11201408066UA (en) Catalyst for methanol production, method of producing the same and process of methanol production
GB2525746B (en) Hydrogenation catalyst and process for production thereof by the use of uncalcined starting material
MX2015012182A (es) Proceso para la conversión de compuestos aromáticos metoxilados en compuestos aromáticos simples.
SG10201809287VA (en) Metathesis catalyst and process for producing olefin
GB2518525A (en) Treating of catalyst carrier, fischer - tropsch catalysts and method of preparation thereof
EP3056273A4 (en) Catalyst used for dehydrogenation of formic acid, method for dehydrogenating formic acid, and method for producing hydrogen
EP2664583A4 (en) Porous alumina material, process for producing same, and catalyst
DK2888042T3 (da) Katalysatorbærermaterialer, katalysatorer, fremgangsmåder til fremstilling deraf og anvendelser deraf
IN2014KN01659A (es)
PH12015501453A1 (en) Method for producing olefin
EA028190B9 (ru) Монооксид азота в качестве катализатора цис/транс-изомеризации ненасыщенных соединений
PL401631A1 (pl) Nowe kompleksy rutenu, sposób ich wytwarzania oraz ich zastosowanie
MY182458A (en) Hydrocarbon synthesis catalyst, its preparation process and its use