BR112017025964A2 - processo de epoxidação - Google Patents
processo de epoxidaçãoInfo
- Publication number
- BR112017025964A2 BR112017025964A2 BR112017025964A BR112017025964A BR112017025964A2 BR 112017025964 A2 BR112017025964 A2 BR 112017025964A2 BR 112017025964 A BR112017025964 A BR 112017025964A BR 112017025964 A BR112017025964 A BR 112017025964A BR 112017025964 A2 BR112017025964 A2 BR 112017025964A2
- Authority
- BR
- Brazil
- Prior art keywords
- silver
- less
- catalyst
- epoxidation
- temperature
- Prior art date
Links
- 238000006735 epoxidation reaction Methods 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 3
- 229910052709 silver Inorganic materials 0.000 abstract 3
- 239000004332 silver Substances 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000011148 porous material Substances 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 230000000977 initiatory effect Effects 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
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- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
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- B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
- B01D39/1638—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being particulate
- B01D39/1653—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being particulate of synthetic origin
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- B01D67/0079—Manufacture of membranes comprising organic and inorganic components
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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- B01J37/082—Decomposition and pyrolysis
- B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
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- C07D301/02—Synthesis of the oxirane ring
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Dispersion Chemistry (AREA)
- Wood Science & Technology (AREA)
- Geology (AREA)
- Catalysts (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
método para melhorar o desempenho de um catalisador de epoxidação à base de prata, compreendendo um veículo consistindo em pelo menos 80 por cento de alfa alumina e tendo um volume de poro de 0,3 ml/g a 1,2 ml/g, uma área superficial de 0,3 m²/g a 3,0 m²/g, e uma arquitetura de poros que fornece pelo menos uma tortuosidade de 7 ou menos, uma constrição de 4 ou menos e uma permeabilidade de 30 mdarcy ou maior. uma quantidade catalítica de prata e uma quantidade promotora de um ou mais promotores dispostos no referido veículo. o método inclui adicionalmente as etapa de início de uma reação de epoxidação por reação de uma composição de gás de alimentação contendo etileno e oxigênio presentes em uma proporção de cerca de 3,5: 1 a cerca de 12: 1, na presença do catalisador de epoxidação à base de prata a uma temperatura de cerca de 200°c a cerca de 230°c; e subsequentemente aumentando a temperatura, de forma gradual ou contínua.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201562169766P | 2015-06-02 | 2015-06-02 | |
US201562169706P | 2015-06-02 | 2015-06-02 | |
PCT/US2016/035478 WO2016196767A1 (en) | 2015-06-02 | 2016-06-02 | Epoxidation process |
Publications (1)
Publication Number | Publication Date |
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BR112017025964A2 true BR112017025964A2 (pt) | 2018-08-14 |
Family
ID=57441757
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112017025953A BR112017025953A2 (pt) | 2015-06-02 | 2016-06-02 | corpos porosos com arquitetura de poro realçada |
BR112017025964A BR112017025964A2 (pt) | 2015-06-02 | 2016-06-02 | processo de epoxidação |
BR112017025945A BR112017025945A2 (pt) | 2015-06-02 | 2016-06-02 | método para produção de corpos porosos com propriedades aperfeiçoadas. |
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