RU2177948C2 - Металлоцены, способ их получения, катализатор полимеризации, способ полимеризации олефинов, гомополимеры и сополимер пропилена - Google Patents

Металлоцены, способ их получения, катализатор полимеризации, способ полимеризации олефинов, гомополимеры и сополимер пропилена Download PDF

Info

Publication number
RU2177948C2
RU2177948C2 RU96121252/04A RU96121252A RU2177948C2 RU 2177948 C2 RU2177948 C2 RU 2177948C2 RU 96121252/04 A RU96121252/04 A RU 96121252/04A RU 96121252 A RU96121252 A RU 96121252A RU 2177948 C2 RU2177948 C2 RU 2177948C2
Authority
RU
Russia
Prior art keywords
substituents
formula
hydrogen atoms
atoms
bis
Prior art date
Application number
RU96121252/04A
Other languages
English (en)
Russian (ru)
Other versions
RU96121252A (ru
Inventor
Луиджи Рескони
Фабрицио Пьемонтези
И.Е. Нифантьев
П.В. Ивченко
Original Assignee
Монтелл Текнолоджи Компани Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=11370281&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=RU2177948(C2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Монтелл Текнолоджи Компани Б.В. filed Critical Монтелл Текнолоджи Компани Б.В.
Publication of RU96121252A publication Critical patent/RU96121252A/ru
Application granted granted Critical
Publication of RU2177948C2 publication Critical patent/RU2177948C2/ru

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
RU96121252/04A 1995-01-23 1996-01-17 Металлоцены, способ их получения, катализатор полимеризации, способ полимеризации олефинов, гомополимеры и сополимер пропилена RU2177948C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITMI95A0000099 1995-01-23
ITMI95A000099 1995-01-23
ITMI950099A IT1272923B (it) 1995-01-23 1995-01-23 Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine

Publications (2)

Publication Number Publication Date
RU96121252A RU96121252A (ru) 1999-01-20
RU2177948C2 true RU2177948C2 (ru) 2002-01-10

Family

ID=11370281

Family Applications (1)

Application Number Title Priority Date Filing Date
RU96121252/04A RU2177948C2 (ru) 1995-01-23 1996-01-17 Металлоцены, способ их получения, катализатор полимеризации, способ полимеризации олефинов, гомополимеры и сополимер пропилена

Country Status (24)

Country Link
US (3) US6051728A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
EP (1) EP0751946B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
JP (1) JP3838662B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
KR (2) KR100414759B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CN (2) CN1075076C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
AR (1) AR000776A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
AU (1) AU700256B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
BG (1) BG100904A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
BR (1) BR9606373A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CA (1) CA2186232A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CZ (1) CZ309596A3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DE (1) DE69617543T3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
ES (1) ES2167539T5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
FI (1) FI963759A0 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
HU (1) HUP9602907A3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
IL (1) IL116853A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
IT (1) IT1272923B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
MX (1) MX9604229A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
PL (1) PL185055B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
RU (1) RU2177948C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
TR (1) TR199600720T1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
TW (1) TW319777B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
WO (1) WO1996022995A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
ZA (1) ZA96485B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2214415C1 (ru) * 2002-05-13 2003-10-20 Общество с ограниченной ответственностью "Научно-исследовательская лаборатория "Синор" Способ получения галогенидов металлоценов (варианты)

Families Citing this family (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19533336A1 (de) * 1995-09-11 1997-03-13 Basf Ag Verfahren zur Herstellung von Propen/But-1-en-Copolymeren
DE19533337A1 (de) * 1995-09-11 1997-03-13 Basf Ag Propen/But-1-en-Copolymere
JP3566819B2 (ja) * 1996-10-04 2004-09-15 関東化学株式会社 新規な有機遷移金属化合物
DE19644039A1 (de) * 1996-10-31 1998-05-07 Hoechst Ag Metallocene
ID22443A (id) * 1996-11-15 1999-10-14 Montelll Technology Co Bv Metallosena heterosiklik dan polimerisasi katalis
US5900497A (en) * 1996-12-20 1999-05-04 Union Carbide Chemicals & Plsatics Technology Corporation Process for preparing metallocene procatalysts
EP0914323B1 (en) 1997-03-29 2003-08-06 Basell Polyolefine GmbH Metallocenes and catalysts for polymerization of olefins
AT405834B (de) 1997-10-09 1999-11-25 Borealis Ag Metallocene mit ferrocenyl-substituierten brücken und deren einsatz für die olefinpolymerisation
DE19748388A1 (de) * 1997-11-03 1999-05-06 Borealis Polymere Holding Gmbh Metallocene mit ferrocenyl-substituierten Brücken und deren Einsatz für die Olefinpolymerisation
JP2002505713A (ja) 1998-04-21 2002-02-19 モンテル テクノロジー カンパニー ビーブイ α−オレフィンとのエチレンコポリマーの製造方法
DE69927234T2 (de) * 1998-07-02 2006-06-29 Basell Polyolefine Gmbh Verfahren zur herstellung von amorphen alpha-olefinpolymeren, diese enthaltende zusammensetzungen und verfahren zur herstellung von verbrückten liganden
DE19922020A1 (de) * 1999-05-12 2000-11-16 Targor Gmbh Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
CN1203076C (zh) 2000-02-24 2005-05-25 巴塞尔技术有限公司 可用作烯烃聚合的助催化剂的有机金属化合物
CN1162454C (zh) 2000-03-22 2004-08-18 巴塞尔技术有限公司 全同立构丙烯聚合物和全同立构规整度降低的软丙烯聚合物的热塑性组合物及其制备方法
JP2003534415A (ja) * 2000-05-24 2003-11-18 バセル テクノロジー カンパニー ビー．ブイ． プロピレンポリマーとその製造法
US6673869B2 (en) 2000-07-27 2004-01-06 Basell Poliolefine Italia S.P.A. Transparent elastomeric thermoplastic polyolefin compositions
DE60135311D1 (de) 2000-12-22 2008-09-25 Basell Polyolefine Gmbh Katalysatorkomponente fur die polymerisation von olefinen
WO2002051887A2 (en) 2000-12-22 2002-07-04 Basell Poliolefine Italia S.P.A. Process for the preparation of porous polymers and polymers obtainable thereof
DE60202524T2 (de) 2001-05-21 2005-06-30 Basell Polyolefine Gmbh Katalysatorsystem für die polymerisierung von olefinen
DE60239615D1 (de) 2001-07-19 2011-05-12 Univation Tech Llc Polyethylenfilme mit verbesserten physikalischen eigenschaften
EP1412394A2 (en) 2001-07-19 2004-04-28 Univation Technologies LLC Low comonomer incorporating metallocene catalyst compounds
AR034829A1 (es) 2001-07-19 2004-03-17 Univation Tech Llc Sistemas catalizadores de metaloceno mezclados que contienen un incorporador pobre de comonomeros y un buen incorporador de comonomeros
US6936675B2 (en) 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
US7022793B2 (en) 2001-11-27 2006-04-04 Basell Polyolefine Gmbh Process for the treatment of polymer compositions
US7572859B2 (en) 2002-06-26 2009-08-11 Basell Polyolefine Italia S.R.L. Impact-resistant polyolefin compositions
CN100354356C (zh) * 2002-06-26 2007-12-12 巴塞尔聚烯烃意大利有限公司 抗冲击聚烯烃组合物
US7449246B2 (en) * 2004-06-30 2008-11-11 General Electric Company Barrier coatings
JP2006502260A (ja) * 2002-10-10 2006-01-19 バセル ポリオレフィン ジーエムビーエイチ エチレンの共重合方法
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
AU2003302033A1 (en) * 2002-10-15 2004-06-15 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
EP1613668B1 (en) 2003-04-17 2012-08-08 Basell Poliolefine Italia S.r.l. Gas-phase olefin polymerization process
EP1648946B1 (en) 2003-07-04 2015-07-15 Basell Polyolefine GmbH Olefin polymerization process
EP1564226A1 (en) 2004-02-16 2005-08-17 Stichting Dutch Polymer Institute Titanocene-based catalyst system
US7943716B2 (en) 2004-03-12 2011-05-17 Basell Polyolefine Gmbh Process for polymerizing 1-hexene or higher alpha-olefins
JP2007528924A (ja) 2004-03-12 2007-10-18 バセル ポリオレフィン ジーエムビーエイチ オレフィンの重合用触媒システム
US7977444B2 (en) 2004-03-12 2011-07-12 Basell Polyolefine Gmbh Process for polymerizaing 1-hexene or higher alpha-olefins
EP1655314A1 (en) 2004-11-09 2006-05-10 Basell Polyolefine GmbH Process for the preparation of 1-butene/propylene copolymers
KR20070093058A (ko) 2004-11-22 2007-09-17 바젤 폴리올레핀 게엠베하 프로필렌 기재 삼중합체
US7300994B2 (en) * 2004-11-22 2007-11-27 Cornell Research Foundation, Inc. Isotactic polypropylene containing polymers
CN101076621A (zh) * 2004-12-13 2007-11-21 巴塞尔聚烯烃意大利有限责任公司 聚烯烃组合物、纤维以及非织造织物
EP1834015B1 (en) * 2004-12-23 2008-11-19 Basell Poliolefine Italia S.r.l. Fibres having elastic properties
US7026494B1 (en) 2005-01-10 2006-04-11 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high melt index polymers without the use of hydrogen
ATE519788T1 (de) 2007-12-18 2011-08-15 Basell Polyolefine Gmbh Gasphasenverfahren zur polymerisation von alpha- olefinen
EP2233506B1 (en) * 2008-01-11 2012-12-12 Mitsui Chemicals, Inc. Modified propylene resin
KR101580849B1 (ko) * 2008-02-29 2015-12-30 바셀 폴리올레핀 이탈리아 에스.알.엘 폴리올레핀 조성물
EP2350147B1 (en) * 2008-11-18 2013-05-01 Borealis AG Propylene-butene random copolymer produced in the presence of a mettalocene catalyst
EP2341086A1 (en) † 2009-12-30 2011-07-06 Borealis AG Bopp-film
US9834628B2 (en) 2013-07-17 2017-12-05 Exxonmobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
WO2015009470A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
ES2703344T3 (es) 2013-07-17 2019-03-08 Exxonmobil Chemical Patents Inc Metalocenos y composiciones catalíticas derivadas de ellos
ES2715831T3 (es) 2013-07-17 2019-06-06 Exxonmobil Chemical Patents Inc Catalizadores de metaloceno sustituidos
EP3848401A1 (en) * 2013-07-17 2021-07-14 ExxonMobil Chemical Patents Inc. Isotactic propylene polymers
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
KR101599978B1 (ko) * 2013-09-30 2016-03-04 주식회사 엘지화학 프로필렌-1-부텐 공중합체의 제조방법 및 이로부터 수득되는 프로필렌-1-부텐 공중합체
JP6440832B2 (ja) * 2014-12-15 2018-12-19 エルジー・ケム・リミテッド メタロセン化合物、メタロセン担持触媒およびこれを用いるポリオレフィンの製造方法
KR101826253B1 (ko) * 2015-07-15 2018-02-06 한화케미칼 주식회사 메탈로센 화합물 및 이의 제조방법
MY191910A (en) * 2016-12-05 2022-07-18 Exxonmobil Chemical Patents Inc Broad orthogonal distribution metallocene polyethylenes for films
WO2019072695A1 (en) 2017-10-11 2019-04-18 Basell Polyolefine Gmbh CATALYST SUPPORTED SYSTEM

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0416566A2 (de) * 1989-09-07 1991-03-13 Hoechst Aktiengesellschaft Verfahren zur Herstellung eines Polyolefinwachses
EP0485823A1 (de) * 1990-11-12 1992-05-20 Hoechst Aktiengesellschaft 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation
EP0485821A1 (de) * 1990-11-12 1992-05-20 Hoechst Aktiengesellschaft Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
WO1992012184A1 (en) * 1990-12-28 1992-07-23 Exxon Chemical Patents Inc. Syndiotactic polypropylene
EP0516018A2 (de) * 1991-05-27 1992-12-02 Hoechst Aktiengesellschaft Verfahren zur Herstellung von Polyolefinen mit breiter Molmassenverteilung
US5196496A (en) * 1990-06-27 1993-03-23 Himont Incorporated Syndiotactic crystalline copolymers of propylene and 1-butene
EP0588208A2 (de) * 1992-09-12 1994-03-23 Hoechst Aktiengesellschaft Polyolefin-Formmasse mit breitem Schmelzbereich, Verfahren zu ihrer Herstellung und ihre Verwendung
EP0629632A2 (en) * 1993-06-07 1994-12-21 Mitsui Petrochemical Industries, Ltd. Novel transition metal compound for use as a polymerization catalyst
RU2111219C1 (ru) * 1992-04-01 1998-05-20 Хехст АГ Катализатор полимеризации олефинов, способ его получения и способ получения олефинового полимера

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) * 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
US4668773A (en) * 1985-03-25 1987-05-26 Northwestern University Organolanthanide catalysts
DE3751694T2 (de) * 1987-04-03 1996-08-01 Fina Technology Metallocen-katalysatorsysteme für die Polymersation von Olefinen, mit einer Silizium-Hydrocarbyl-Brücke.
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
DE68929210T2 (de) * 1988-12-26 2001-01-04 Mitsui Chemicals, Inc. Olefincopolymere und Verfahren zur Herstellung davon
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
JPH04351638A (ja) * 1991-05-29 1992-12-07 Toray Dow Corning Silicone Co Ltd ヘキセニル基含有シリコーンレジンおよびその製造方法
TW300901B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * 1991-08-26 1997-03-21 Hoechst Ag
US5330948A (en) * 1992-03-31 1994-07-19 Northwestern University Homogeneous catalysts for stereoregular olefin polymerization
DE59309424D1 (de) * 1992-08-15 1999-04-15 Targor Gmbh Verfahren zur Herstellung von Polyolefinen
TW272985B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * 1992-09-11 1996-03-21 Hoechst Ag
JP3307704B2 (ja) * 1993-02-19 2002-07-24 三菱化学株式会社 α‐オレフィン重合体の製造法
EP0629631B1 (en) * 1993-06-07 2002-08-28 Mitsui Chemicals, Inc. Novel transition metal compound, and polymerization catalyst containing it
US5459117A (en) * 1993-08-27 1995-10-17 Ewen; John A. Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers
DE4333128A1 (de) * 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
US5504223A (en) * 1994-01-25 1996-04-02 The Dow Chemical Company Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0416566A2 (de) * 1989-09-07 1991-03-13 Hoechst Aktiengesellschaft Verfahren zur Herstellung eines Polyolefinwachses
US5196496A (en) * 1990-06-27 1993-03-23 Himont Incorporated Syndiotactic crystalline copolymers of propylene and 1-butene
EP0485823A1 (de) * 1990-11-12 1992-05-20 Hoechst Aktiengesellschaft 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation
EP0485821A1 (de) * 1990-11-12 1992-05-20 Hoechst Aktiengesellschaft Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
WO1992012184A1 (en) * 1990-12-28 1992-07-23 Exxon Chemical Patents Inc. Syndiotactic polypropylene
EP0516018A2 (de) * 1991-05-27 1992-12-02 Hoechst Aktiengesellschaft Verfahren zur Herstellung von Polyolefinen mit breiter Molmassenverteilung
RU2111219C1 (ru) * 1992-04-01 1998-05-20 Хехст АГ Катализатор полимеризации олефинов, способ его получения и способ получения олефинового полимера
EP0588208A2 (de) * 1992-09-12 1994-03-23 Hoechst Aktiengesellschaft Polyolefin-Formmasse mit breitem Schmelzbereich, Verfahren zu ihrer Herstellung und ihre Verwendung
EP0629632A2 (en) * 1993-06-07 1994-12-21 Mitsui Petrochemical Industries, Ltd. Novel transition metal compound for use as a polymerization catalyst

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Э.Фишер, Г.Вернер. Т - комплексы металлов. - М.: Мир, 1968, с.43-54. *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2214415C1 (ru) * 2002-05-13 2003-10-20 Общество с ограниченной ответственностью "Научно-исследовательская лаборатория "Синор" Способ получения галогенидов металлоценов (варианты)

Also Published As

Publication number Publication date
EP0751946B2 (en) 2006-08-09
ITMI950099A0 (it) 1995-01-23
KR100418106B1 (ko) 2004-04-30
US6051728A (en) 2000-04-18
EP0751946A1 (en) 1997-01-08
JPH09510994A (ja) 1997-11-04
ITMI950099A1 (it) 1996-07-23
DE69617543T2 (de) 2002-08-01
CA2186232A1 (en) 1996-08-01
IT1272923B (it) 1997-07-01
PL316387A1 (en) 1997-01-06
ES2167539T5 (es) 2007-04-01
FI963759A7 (fi) 1996-09-20
JP3838662B2 (ja) 2006-10-25
FI963759L (fi) 1996-09-20
FI963759A0 (fi) 1996-09-20
KR100414759B1 (ko) 2004-01-13
MX9604229A (es) 1997-12-31
US6518386B1 (en) 2003-02-11
US20030120015A1 (en) 2003-06-26
EP0751946B1 (en) 2001-12-05
TW319777B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1997-11-11
TR199600720T1 (tr) 1997-03-21
AU4536696A (en) 1996-08-14
CZ309596A3 (en) 1997-04-16
WO1996022995A1 (en) 1996-08-01
ZA96485B (en) 1996-08-13
DE69617543T3 (de) 2007-01-18
CN1355256A (zh) 2002-06-26
BG100904A (bg) 1997-07-31
AR000776A1 (es) 1997-08-06
HUP9602907A3 (en) 1997-12-29
ES2167539T3 (es) 2002-05-16
CN1150430A (zh) 1997-05-21
CN1196721C (zh) 2005-04-13
IL116853A0 (en) 1996-07-23
KR970701723A (ko) 1997-04-12
AU700256B2 (en) 1998-12-24
CN1075076C (zh) 2001-11-21
HUP9602907A2 (en) 1997-05-28
BR9606373A (pt) 2004-06-29
IL116853A (en) 2000-09-28
PL185055B1 (pl) 2003-02-28
DE69617543D1 (de) 2002-01-17

Similar Documents

Publication Publication Date Title
RU2177948C2 (ru) Металлоцены, способ их получения, катализатор полимеризации, способ полимеризации олефинов, гомополимеры и сополимер пропилена
JP3287617B2 (ja) アイソタクチツクポリオレフイン製造の方法及び触媒
USRE37208E1 (en) Polyolefins prepared with metallocene catalysts having 2-substituted indenyl type ligands
USRE37384E1 (en) 2-substituted disindenylmetallocenes, process for their preparation, and their use as catalysts in the polymerization of olefins
US6627764B1 (en) Transition metal compound, ligand system, catalyst system and its use for the polymerization of olefins
EP0628577A2 (en) Silyl bridged metallocenes and use thereof
JPH05345793A (ja) ブリッジのあるキラルなメタロセン、その製造方法およびそれの触媒としての用途
US6391991B1 (en) Process for the preparation of amorphous polymers of propylene
US6365764B1 (en) Bridged bis-fluorenyl metallocenes process for the preparation thereof and use thereof in catalysts for the polymerization of olefins
CZ434598A3 (cs) Metalocenové sloučeniny
JPH03193796A (ja) メタロセン化合物
CZ365489A3 (en) Syndiotactic polypropylene
JPH09136930A (ja) シンジオタクチツク／アイソタクチツクブロツクポリオレフインの製造方法
RU2168515C2 (ru) Способ получения мостикового металлоценового соединения, мостиковый бис-циклопентадиенильный лиганд
US6376418B1 (en) Process and catalyst for producing polyolefins having low molecular weight
KR20010024225A (ko) 라세미형 메탈로센 착물의 선택적 제조방법
JP4454225B2 (ja) ラセミメタロセン錯体の製造方法
US7635783B2 (en) Meso-selective synthesis of ansa-metallocenes
EP1742954B1 (en) Process for the racemoselective preparation of ansa-metallocenes
JP4131448B2 (ja) ヘテロ環式メタロセン類および重合触媒

Legal Events

Date Code Title Description
MM4A The patent is invalid due to non-payment of fees

Effective date: 20080118