IT1272923B - Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine - Google Patents
Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefineInfo
- Publication number
- IT1272923B IT1272923B ITMI950099A ITMI950099A IT1272923B IT 1272923 B IT1272923 B IT 1272923B IT MI950099 A ITMI950099 A IT MI950099A IT MI950099 A ITMI950099 A IT MI950099A IT 1272923 B IT1272923 B IT 1272923B
- Authority
- IT
- Italy
- Prior art keywords
- olefins
- catalysts
- polymerization
- procedure
- preparation
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (30)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI950099A IT1272923B (it) | 1995-01-23 | 1995-01-23 | Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
EP96901285A EP0751946B2 (en) | 1995-01-23 | 1996-01-17 | Metallocene compounds, process for their preparation, and their use in catalysts for the polymerization of olefins |
RU96121252/04A RU2177948C2 (ru) | 1995-01-23 | 1996-01-17 | Металлоцены, способ их получения, катализатор полимеризации, способ полимеризации олефинов, гомополимеры и сополимер пропилена |
TR96/00720T TR199600720T1 (tr) | 1995-01-23 | 1996-01-17 | Metalosen bilesikleri, bunlarin hazirlanmasi icin islemler ve olefinlerin polimerizasyonu icin katalizörde kullanimlari. |
BR9606373-4A BR9606373A (pt) | 1995-01-23 | 1996-01-17 | Composto metaloceno, processo de preparação, e uso em catalizadores para a polimerização de olefinas |
HU9602907A HUP9602907A3 (en) | 1995-01-23 | 1996-01-17 | Metallocene compounds, process for their preparation, their use in catalysts for the polymerization of olefins, process for polymerization of olefins and propylene (co)polymer |
PL96316387A PL185055B1 (pl) | 1995-01-23 | 1996-01-17 | Związki matalocenowe oraz homopolimery i kopolimery propylenowe |
ES96901285T ES2167539T5 (es) | 1995-01-23 | 1996-01-17 | Compuestos de metaloceno, procedimiento para su preparacion y su empleo en catalizadores para la polimerizacion de olefinas. |
AU45366/96A AU700256B2 (en) | 1995-01-23 | 1996-01-17 | Metallocene compounds, process for their prepration, and their use in catalysts for the polymerization of olefins |
PCT/EP1996/000171 WO1996022995A1 (en) | 1995-01-23 | 1996-01-17 | Metallocene compounds, process for their prepration, and their use in catalysts for the polymerization of olefins |
MX9604229A MX9604229A (es) | 1995-01-23 | 1996-01-17 | Compuesto de metaloceno, procedimiento para su preparacion y su uso en catalizadores para la polimerizacion de olefinas. |
DE69617543T DE69617543T3 (de) | 1995-01-23 | 1996-01-17 | Metallocenverbindungen, verfahren zu ihrer herstellung und ihre verwendung in katalysatoren für die olefinpolymerisierung |
CN96190226A CN1075076C (zh) | 1995-01-23 | 1996-01-17 | 金属茂化合物及其制法和在烯烃聚合催化剂中的应用 |
KR1019960705230A KR100418106B1 (ko) | 1995-01-23 | 1996-01-17 | 메탈로센화합물,이것의제조방법,및이것의올레핀중합용촉매로서의용도 |
KR10-2003-7010028A KR100414759B1 (ko) | 1995-01-23 | 1996-01-17 | 메탈로센 화합물, 이것의 제조 방법, 및 이것의 올레핀중합용 촉매로서의 용도 |
CZ963095A CZ309596A3 (en) | 1995-01-23 | 1996-01-17 | Metallocene compounds, process of their preparation and their use in catalysts for olefin polymerization |
CA002186232A CA2186232A1 (en) | 1995-01-23 | 1996-01-17 | Metallocene compounds, process for their prepration, and their use in catalysts for the polymerization of olefins |
FI963759A FI963759A0 (fi) | 1995-01-23 | 1996-01-17 | Metalloseeniyhdisteitä, menetelmä niiden valmistamiseksi ja niiden käyttö olefiinien polymerointiin tarkoitetuissa katalyyteissä |
JP52259496A JP3838662B2 (ja) | 1995-01-23 | 1996-01-17 | メタロセン化合物、その製造法及びオレフィン重合用触媒におけるその使用 |
IL11685396A IL116853A (en) | 1995-01-23 | 1996-01-22 | Metallocene compounds their preparation and use |
ZA96485A ZA96485B (en) | 1995-01-23 | 1996-01-22 | Metallocene compounds process for the preparation and their use in catalysts for the polymerization of olefins |
US08/599,483 US6051728A (en) | 1995-01-23 | 1996-01-23 | Metallocene compounds, process for their preparation, and their use in catalysts for the polymerization of olefins |
ARP960101110A AR000776A1 (es) | 1995-01-23 | 1996-01-23 | Un compuesto metalocénico, proceso para prepararlo, un catalizador para la polimerización de olefinas obtenido mediante el mismo y un proceso de polimerización de olefinas, en particular propileno, mediante dicho catalizador. |
TW085102169A TW319777B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1995-01-23 | 1996-02-26 | |
NO963954A NO963954D0 (no) | 1995-01-23 | 1996-09-20 | Metallocen-forbindelser, fremgangsmåter for fremstilling, og anvendelse av disse ved polymerisering av olefiner |
BG100904A BG100904A (bg) | 1995-01-23 | 1996-10-11 | Металоцени, метод за тяхното получаване, приложението им в катализатори за полимеризация на олефини |
IL13392100A IL133921A0 (en) | 1995-01-23 | 2000-01-07 | A process for polymerization of olefins in the presence of metallocenes |
US09/481,047 US6518386B1 (en) | 1995-01-23 | 2000-01-11 | Metallocene compounds, process for their preparation thereof, and their use in catalysts for the polymerization of olefins |
CNB011208953A CN1196721C (zh) | 1995-01-23 | 2001-06-07 | 金属茂化合物及其制法和在烯烃聚合催化剂中的应用 |
US10/269,699 US20030120015A1 (en) | 1995-01-23 | 2002-10-11 | Metallocene compounds, process for their preparation, and their use in catalysts for the polymerization of olefins |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI950099A IT1272923B (it) | 1995-01-23 | 1995-01-23 | Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
Publications (3)
Publication Number | Publication Date |
---|---|
ITMI950099A0 ITMI950099A0 (it) | 1995-01-23 |
ITMI950099A1 ITMI950099A1 (it) | 1996-07-23 |
IT1272923B true IT1272923B (it) | 1997-07-01 |
Family
ID=11370281
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ITMI950099A IT1272923B (it) | 1995-01-23 | 1995-01-23 | Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
Country Status (24)
Families Citing this family (61)
Publication number | Priority date | Publication date | Assignee | Title |
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DE19533336A1 (de) * | 1995-09-11 | 1997-03-13 | Basf Ag | Verfahren zur Herstellung von Propen/But-1-en-Copolymeren |
DE19533337A1 (de) * | 1995-09-11 | 1997-03-13 | Basf Ag | Propen/But-1-en-Copolymere |
JP3566819B2 (ja) * | 1996-10-04 | 2004-09-15 | 関東化学株式会社 | 新規な有機遷移金属化合物 |
DE19644039A1 (de) * | 1996-10-31 | 1998-05-07 | Hoechst Ag | Metallocene |
ID22443A (id) * | 1996-11-15 | 1999-10-14 | Montelll Technology Co Bv | Metallosena heterosiklik dan polimerisasi katalis |
US5900497A (en) * | 1996-12-20 | 1999-05-04 | Union Carbide Chemicals & Plsatics Technology Corporation | Process for preparing metallocene procatalysts |
EP0914323B1 (en) | 1997-03-29 | 2003-08-06 | Basell Polyolefine GmbH | Metallocenes and catalysts for polymerization of olefins |
AT405834B (de) | 1997-10-09 | 1999-11-25 | Borealis Ag | Metallocene mit ferrocenyl-substituierten brücken und deren einsatz für die olefinpolymerisation |
DE19748388A1 (de) * | 1997-11-03 | 1999-05-06 | Borealis Polymere Holding Gmbh | Metallocene mit ferrocenyl-substituierten Brücken und deren Einsatz für die Olefinpolymerisation |
JP2002505713A (ja) | 1998-04-21 | 2002-02-19 | モンテル テクノロジー カンパニー ビーブイ | α−オレフィンとのエチレンコポリマーの製造方法 |
DE69927234T2 (de) * | 1998-07-02 | 2006-06-29 | Basell Polyolefine Gmbh | Verfahren zur herstellung von amorphen alpha-olefinpolymeren, diese enthaltende zusammensetzungen und verfahren zur herstellung von verbrückten liganden |
DE19922020A1 (de) * | 1999-05-12 | 2000-11-16 | Targor Gmbh | Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
CN1203076C (zh) | 2000-02-24 | 2005-05-25 | 巴塞尔技术有限公司 | 可用作烯烃聚合的助催化剂的有机金属化合物 |
CN1162454C (zh) | 2000-03-22 | 2004-08-18 | 巴塞尔技术有限公司 | 全同立构丙烯聚合物和全同立构规整度降低的软丙烯聚合物的热塑性组合物及其制备方法 |
JP2003534415A (ja) * | 2000-05-24 | 2003-11-18 | バセル テクノロジー カンパニー ビー.ブイ. | プロピレンポリマーとその製造法 |
US6673869B2 (en) | 2000-07-27 | 2004-01-06 | Basell Poliolefine Italia S.P.A. | Transparent elastomeric thermoplastic polyolefin compositions |
DE60135311D1 (de) | 2000-12-22 | 2008-09-25 | Basell Polyolefine Gmbh | Katalysatorkomponente fur die polymerisation von olefinen |
WO2002051887A2 (en) | 2000-12-22 | 2002-07-04 | Basell Poliolefine Italia S.P.A. | Process for the preparation of porous polymers and polymers obtainable thereof |
DE60202524T2 (de) | 2001-05-21 | 2005-06-30 | Basell Polyolefine Gmbh | Katalysatorsystem für die polymerisierung von olefinen |
DE60239615D1 (de) | 2001-07-19 | 2011-05-12 | Univation Tech Llc | Polyethylenfilme mit verbesserten physikalischen eigenschaften |
EP1412394A2 (en) | 2001-07-19 | 2004-04-28 | Univation Technologies LLC | Low comonomer incorporating metallocene catalyst compounds |
AR034829A1 (es) | 2001-07-19 | 2004-03-17 | Univation Tech Llc | Sistemas catalizadores de metaloceno mezclados que contienen un incorporador pobre de comonomeros y un buen incorporador de comonomeros |
US6936675B2 (en) | 2001-07-19 | 2005-08-30 | Univation Technologies, Llc | High tear films from hafnocene catalyzed polyethylenes |
US7022793B2 (en) | 2001-11-27 | 2006-04-04 | Basell Polyolefine Gmbh | Process for the treatment of polymer compositions |
RU2214415C1 (ru) * | 2002-05-13 | 2003-10-20 | Общество с ограниченной ответственностью "Научно-исследовательская лаборатория "Синор" | Способ получения галогенидов металлоценов (варианты) |
US7572859B2 (en) | 2002-06-26 | 2009-08-11 | Basell Polyolefine Italia S.R.L. | Impact-resistant polyolefin compositions |
CN100354356C (zh) * | 2002-06-26 | 2007-12-12 | 巴塞尔聚烯烃意大利有限公司 | 抗冲击聚烯烃组合物 |
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JP2006502260A (ja) * | 2002-10-10 | 2006-01-19 | バセル ポリオレフィン ジーエムビーエイチ | エチレンの共重合方法 |
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EP1648946B1 (en) | 2003-07-04 | 2015-07-15 | Basell Polyolefine GmbH | Olefin polymerization process |
EP1564226A1 (en) | 2004-02-16 | 2005-08-17 | Stichting Dutch Polymer Institute | Titanocene-based catalyst system |
US7943716B2 (en) | 2004-03-12 | 2011-05-17 | Basell Polyolefine Gmbh | Process for polymerizing 1-hexene or higher alpha-olefins |
JP2007528924A (ja) | 2004-03-12 | 2007-10-18 | バセル ポリオレフィン ジーエムビーエイチ | オレフィンの重合用触媒システム |
US7977444B2 (en) | 2004-03-12 | 2011-07-12 | Basell Polyolefine Gmbh | Process for polymerizaing 1-hexene or higher alpha-olefins |
EP1655314A1 (en) | 2004-11-09 | 2006-05-10 | Basell Polyolefine GmbH | Process for the preparation of 1-butene/propylene copolymers |
KR20070093058A (ko) | 2004-11-22 | 2007-09-17 | 바젤 폴리올레핀 게엠베하 | 프로필렌 기재 삼중합체 |
US7300994B2 (en) * | 2004-11-22 | 2007-11-27 | Cornell Research Foundation, Inc. | Isotactic polypropylene containing polymers |
CN101076621A (zh) * | 2004-12-13 | 2007-11-21 | 巴塞尔聚烯烃意大利有限责任公司 | 聚烯烃组合物、纤维以及非织造织物 |
EP1834015B1 (en) * | 2004-12-23 | 2008-11-19 | Basell Poliolefine Italia S.r.l. | Fibres having elastic properties |
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ATE519788T1 (de) | 2007-12-18 | 2011-08-15 | Basell Polyolefine Gmbh | Gasphasenverfahren zur polymerisation von alpha- olefinen |
EP2233506B1 (en) * | 2008-01-11 | 2012-12-12 | Mitsui Chemicals, Inc. | Modified propylene resin |
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ES2703344T3 (es) | 2013-07-17 | 2019-03-08 | Exxonmobil Chemical Patents Inc | Metalocenos y composiciones catalíticas derivadas de ellos |
ES2715831T3 (es) | 2013-07-17 | 2019-06-06 | Exxonmobil Chemical Patents Inc | Catalizadores de metaloceno sustituidos |
EP3848401A1 (en) * | 2013-07-17 | 2021-07-14 | ExxonMobil Chemical Patents Inc. | Isotactic propylene polymers |
US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
KR101599978B1 (ko) * | 2013-09-30 | 2016-03-04 | 주식회사 엘지화학 | 프로필렌-1-부텐 공중합체의 제조방법 및 이로부터 수득되는 프로필렌-1-부텐 공중합체 |
JP6440832B2 (ja) * | 2014-12-15 | 2018-12-19 | エルジー・ケム・リミテッド | メタロセン化合物、メタロセン担持触媒およびこれを用いるポリオレフィンの製造方法 |
KR101826253B1 (ko) * | 2015-07-15 | 2018-02-06 | 한화케미칼 주식회사 | 메탈로센 화합물 및 이의 제조방법 |
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WO2019072695A1 (en) | 2017-10-11 | 2019-04-18 | Basell Polyolefine Gmbh | CATALYST SUPPORTED SYSTEM |
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1995
- 1995-01-23 IT ITMI950099A patent/IT1272923B/it active IP Right Grant
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1996
- 1996-01-17 EP EP96901285A patent/EP0751946B2/en not_active Expired - Lifetime
- 1996-01-17 DE DE69617543T patent/DE69617543T3/de not_active Expired - Lifetime
- 1996-01-17 PL PL96316387A patent/PL185055B1/pl not_active IP Right Cessation
- 1996-01-17 WO PCT/EP1996/000171 patent/WO1996022995A1/en active Application Filing
- 1996-01-17 KR KR10-2003-7010028A patent/KR100414759B1/ko not_active Expired - Fee Related
- 1996-01-17 CN CN96190226A patent/CN1075076C/zh not_active Expired - Fee Related
- 1996-01-17 BR BR9606373-4A patent/BR9606373A/pt not_active IP Right Cessation
- 1996-01-17 JP JP52259496A patent/JP3838662B2/ja not_active Expired - Lifetime
- 1996-01-17 MX MX9604229A patent/MX9604229A/es unknown
- 1996-01-17 KR KR1019960705230A patent/KR100418106B1/ko not_active Expired - Fee Related
- 1996-01-17 CA CA002186232A patent/CA2186232A1/en not_active Abandoned
- 1996-01-17 ES ES96901285T patent/ES2167539T5/es not_active Expired - Lifetime
- 1996-01-17 AU AU45366/96A patent/AU700256B2/en not_active Ceased
- 1996-01-17 RU RU96121252/04A patent/RU2177948C2/ru not_active IP Right Cessation
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- 1996-01-22 ZA ZA96485A patent/ZA96485B/xx unknown
- 1996-01-22 IL IL11685396A patent/IL116853A/xx not_active IP Right Cessation
- 1996-01-23 AR ARP960101110A patent/AR000776A1/es active IP Right Grant
- 1996-01-23 US US08/599,483 patent/US6051728A/en not_active Expired - Lifetime
- 1996-02-26 TW TW085102169A patent/TW319777B/zh active
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