PL170118B1 - Sposób polimeryzacji i kopolimeryzacji w fazie gazowej olefin PL PL PL PL PL PL PL PL - Google Patents
Sposób polimeryzacji i kopolimeryzacji w fazie gazowej olefin PL PL PL PL PL PL PL PLInfo
- Publication number
- PL170118B1 PL170118B1 PL92297841A PL29784192A PL170118B1 PL 170118 B1 PL170118 B1 PL 170118B1 PL 92297841 A PL92297841 A PL 92297841A PL 29784192 A PL29784192 A PL 29784192A PL 170118 B1 PL170118 B1 PL 170118B1
- Authority
- PL
- Poland
- Prior art keywords
- catalyst
- propylene
- reactor
- gas phase
- polymerization
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITRM910379A IT1246614B (it) | 1991-06-03 | 1991-06-03 | Procedimento per la polimerizzazione in fase gas delle olefine |
| PCT/EP1992/001231 WO1992021706A1 (en) | 1991-06-03 | 1992-06-03 | Process for the gas-phase polymerization of olefins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL297841A1 PL297841A1 (en) | 1993-12-13 |
| PL170118B1 true PL170118B1 (pl) | 1996-10-31 |
Family
ID=11400172
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL92297841A PL170118B1 (pl) | 1991-06-03 | 1992-06-03 | Sposób polimeryzacji i kopolimeryzacji w fazie gazowej olefin PL PL PL PL PL PL PL PL |
Country Status (26)
| Country | Link |
|---|---|
| US (1) | US6228956B1 (cs) |
| EP (2) | EP0541760B1 (cs) |
| JP (1) | JP3190041B2 (cs) |
| KR (1) | KR100218863B1 (cs) |
| CN (1) | CN1078216C (cs) |
| AR (1) | AR247408A1 (cs) |
| AT (1) | ATE141094T1 (cs) |
| AU (1) | AU653829B2 (cs) |
| BR (1) | BR9205273A (cs) |
| CA (1) | CA2088681C (cs) |
| CZ (1) | CZ289004B6 (cs) |
| DE (1) | DE69212633T2 (cs) |
| DK (1) | DK0541760T3 (cs) |
| ES (1) | ES2090646T3 (cs) |
| FI (1) | FI106308B (cs) |
| GR (1) | GR3020753T3 (cs) |
| HU (1) | HU212442B (cs) |
| IL (1) | IL102074A (cs) |
| IT (1) | IT1246614B (cs) |
| MX (1) | MX9202633A (cs) |
| NO (1) | NO180721C (cs) |
| PL (1) | PL170118B1 (cs) |
| RU (1) | RU2114125C1 (cs) |
| UA (1) | UA27785C2 (cs) |
| WO (1) | WO1992021706A1 (cs) |
| ZA (1) | ZA923985B (cs) |
Families Citing this family (87)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1254279B (it) * | 1992-03-13 | 1995-09-14 | Montecatini Tecnologie Srl | Procedimento per la polimerizzazione in fase gas delle olefine |
| KR100298102B1 (ko) * | 1992-12-22 | 2001-10-24 | 치어즈 엠. 노우드 | 프로필렌단량체를중합시켜폴리프로필렌을제조하는방법,이를위한촉매및프로필렌중합용촉매의제조방법 |
| PL308997A1 (en) * | 1993-09-16 | 1995-09-18 | Shell Oil Co | Method of obtaining a polymer |
| FI952098L (fi) * | 1995-05-02 | 1996-11-03 | Borealis As | LLDPE-polymeerien valmistusmenetelmä |
| FI952175A7 (fi) * | 1995-05-05 | 1996-11-06 | Borealis As | Menetelmä ja katalysaattorikomponentti olefiinien homo- tai kopolymeroimiseksi |
| IT1275573B (it) * | 1995-07-20 | 1997-08-07 | Spherilene Spa | Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine |
| EP0846134B1 (en) | 1996-06-24 | 2003-07-23 | Basell Poliolefine Italia S.p.A. | High transparency and high flexibility elastoplastic polyolefin compositions |
| ATE305943T1 (de) * | 1997-01-30 | 2005-10-15 | Fina Technology | Selektive wirkung von metallocen-katalysatoren für die herstellung von isotaktischen polyolefinen |
| US6303709B1 (en) | 1997-06-05 | 2001-10-16 | Solvay Polyolefins Europe-Belgium (Societe Anonyme) | Continuous process for obtaining propylene polymers |
| FI111845B (fi) * | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä propeenin homopolymeerien ja iskulujuudeltaan modifioitujen polymeerien valmistamiseksi |
| FI111847B (fi) * | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä propeenin kopolymeerien valmistamiseksi |
| FI111846B (fi) | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä ja laitteisto polypropeeniseosten valmistamiseksi |
| FI111848B (fi) * | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi |
| YU49330B (sh) | 1998-07-08 | 2005-07-19 | Montell Technology Company B.V. | Postupak i uređaj za polimerizaciju u gasovitoj fazi |
| FI991015A0 (fi) * | 1999-05-04 | 1999-05-04 | Borealis As | Menetelmä alfa-olefiinipolymeerien valmistamiseksi |
| BR0006832B1 (pt) | 1999-06-18 | 2009-08-11 | componentes catalìticos para a polimerização de olefinas, processo para a preparação de componentes catalìticos e catalisadores resultantes. | |
| ATE353344T1 (de) | 1999-09-10 | 2007-02-15 | Basell Poliolefine Srl | Katalysator für die polymerisation von olefinen |
| AU7540700A (en) | 1999-10-02 | 2001-05-10 | Borealis Technology Oy | Modified supported catalysts for the polymerization of olefins |
| CN1210319C (zh) * | 2000-05-12 | 2005-07-13 | 巴塞尔技术有限公司 | 用于烯烃聚合的预聚合的催化剂组分 |
| RU2176649C1 (ru) * | 2000-12-08 | 2001-12-10 | Институт катализа им. Г.К. Борескова СО РАН | Способ получения сверхвысокомолекулярного полиэтилена |
| EP1368392A1 (en) | 2001-03-15 | 2003-12-10 | Basell Poliolefine Italia S.p.A. | Process for the (co)polymerization of ethylene |
| CN1249098C (zh) | 2001-06-26 | 2006-04-05 | 巴塞尔聚烯烃意大利有限公司 | 烯烃聚合用组分和催化剂 |
| MY136330A (en) | 2001-12-12 | 2008-09-30 | Basell Poliolefine Spa | Process for the polymerization of olefins |
| MXPA04002355A (es) * | 2002-01-15 | 2004-06-29 | Advanced Elastomer Systems | Elastomeros termoplasticos y procedimiento para la elaboracion de los mismos. |
| ES2289295T3 (es) | 2002-06-13 | 2008-02-01 | Basell Poliolefine Italia S.R.L. | Componentes cataliticos ziegler natta para la polimerizacion de olefinas. |
| CN1659190A (zh) | 2002-06-13 | 2005-08-24 | 巴塞尔聚烯烃意大利有限公司 | 乙烯共聚物的制备方法 |
| CN100519600C (zh) * | 2002-06-25 | 2009-07-29 | 玻利阿黎斯技术有限公司 | 提高了抗刮性的聚烯烃及其制备方法 |
| BR0306195B1 (pt) * | 2002-08-01 | 2012-12-25 | processo para a preparaÇço de polÍmeros, polÍmeros obtidos pelo mesmo, filmes ou folhas e artigos laminados multicamadas. | |
| US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
| WO2004033505A1 (en) | 2002-10-09 | 2004-04-22 | Basell Poliolefine Italia S.P.A. | Polymerization process |
| CN100554287C (zh) | 2002-12-18 | 2009-10-28 | 巴塞尔聚烯烃意大利有限公司 | 烯烃聚合用催化剂组分 |
| MXPA05012830A (es) | 2003-05-29 | 2006-02-13 | Basell Poliolefine Srl | Procedimiento para la preparacion de un componente catalizador y componentes obtenidos a partir de este. |
| WO2005019280A1 (en) | 2003-08-20 | 2005-03-03 | Basell Poliolefine Italia S.R.L. | Process and apparatus for the polymerization of ethylene |
| EP1774485B1 (en) | 2004-07-08 | 2016-05-04 | ExxonMobil Chemical Patents Inc. | Polymer production at supercritical conditions |
| WO2006040240A1 (en) * | 2004-10-14 | 2006-04-20 | Basell Poliolefine Italia S.R.L. | Process for the gas-phase polymerization of olefins |
| ATE401123T1 (de) | 2004-12-17 | 2008-08-15 | Borealis Tech Oy | Verfahren zur polymerisation von olefinen in gegenwart eines olefin polymerisationskatalysators |
| DE102005005506A1 (de) * | 2005-02-04 | 2006-08-10 | Basell Polyolefine Gmbh | Verfahren und Vorrichtung zur Polymerisation von Ethylen |
| CN101146833B (zh) | 2005-03-30 | 2010-12-08 | 巴塞尔聚烯烃意大利有限责任公司 | 用于烯烃聚合的催化剂组分 |
| US7834117B2 (en) | 2005-03-30 | 2010-11-16 | Basell Poliolefine Italia S.R.L. | Process for preparing crystalline ethylene (co)polymers |
| WO2006103170A1 (en) * | 2005-03-30 | 2006-10-05 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| US7687588B2 (en) | 2005-05-13 | 2010-03-30 | Basel Poliolefine Italia S.R.L. | Process for the gas-phase polymerization of olefins |
| EP1926755A1 (en) * | 2005-09-19 | 2008-06-04 | Basell Poliolefine Italia S.R.L. | Gas-phase process for the polymerization of olefins |
| JP5092260B2 (ja) * | 2005-09-21 | 2012-12-05 | 住友化学株式会社 | オレフィン重合体の製造方法 |
| BRPI0714250B1 (pt) * | 2006-08-04 | 2018-04-17 | Basell Poliolefine Italia S.R.L. | Processo em fase gasosa para preparar copolímeros heterofásicos de propileno |
| EP2094737A1 (en) * | 2006-11-21 | 2009-09-02 | Basell Poliolefine Italia S.r.l. | Catalyst component for the polymerization of olefins |
| US8242237B2 (en) | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
| RU2444532C2 (ru) * | 2006-12-20 | 2012-03-10 | Базелль Полиолефин Италия С.Р.Л. | Компоненты катализатора для полимеризации олефинов и катализаторы, полученные из них |
| EP2121773B1 (en) | 2006-12-22 | 2016-11-23 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
| EP2160419B1 (en) | 2007-06-04 | 2013-11-13 | ExxonMobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization |
| CN101168576B (zh) * | 2007-11-30 | 2011-04-20 | 北京三聚环保新材料股份有限公司 | 一种聚烯烃催化剂制备工艺 |
| CN101903420B (zh) | 2007-12-18 | 2012-09-19 | 巴塞尔聚烯烃股份有限公司 | α-烯烃聚合的气相方法 |
| US20100261859A1 (en) * | 2007-12-20 | 2010-10-14 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| EP2225287B1 (en) * | 2007-12-28 | 2011-08-31 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
| WO2010020575A1 (en) | 2008-08-20 | 2010-02-25 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
| US10125200B2 (en) | 2008-09-26 | 2018-11-13 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| KR20120031175A (ko) | 2009-06-18 | 2012-03-30 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 올레핀 중합용 촉매 성분 및 그로부터 수득된 촉매 |
| CN102030841B (zh) * | 2009-09-29 | 2012-07-04 | 中国石油化工股份有限公司 | 一种丙烯气相聚合方法 |
| EP2330135B1 (en) | 2009-12-02 | 2012-11-07 | Borealis AG | Process for producing polyolefins |
| EP2609124B1 (en) | 2010-08-24 | 2017-09-20 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| US10138310B2 (en) | 2010-08-24 | 2018-11-27 | Equistar Chemicals, Lp | Preparation of LLDPE resins and films having low gels |
| EP2694209A1 (en) | 2011-04-01 | 2014-02-12 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
| EP2518090A1 (en) | 2011-04-28 | 2012-10-31 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
| CN103788257B (zh) * | 2012-10-30 | 2016-12-21 | 中国石油化工股份有限公司 | 一种调节聚丙烯立构规整度的方法 |
| CN103788259B (zh) | 2012-10-30 | 2017-05-31 | 中国石油化工股份有限公司 | 一种分子量窄分布聚丙烯 |
| DE102013221849B4 (de) | 2012-10-30 | 2021-07-29 | Beijing Research Institute Of Chemical Industry, China Petroleum & Chemical Corporation | Verfahren zur Herstellung eines Propylenpolymers |
| CN103788258B (zh) * | 2012-10-30 | 2019-02-19 | 中国石油化工股份有限公司 | 一种丙烯的聚合方法 |
| EP2740748B1 (en) | 2012-12-07 | 2015-06-10 | Borealis AG | Method of polymerizing olefins in slurry reactors |
| EP2818509A1 (en) * | 2013-06-25 | 2014-12-31 | Basell Polyolefine GmbH | Polyethylene composition for blow molding having high stress cracking resistance |
| CN104250326B (zh) * | 2013-06-28 | 2017-04-26 | 中国石油化工股份有限公司 | 一种聚丙烯发泡板材或片材的制备方法 |
| US9428598B2 (en) | 2014-02-07 | 2016-08-30 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
| US10723824B2 (en) | 2014-02-07 | 2020-07-28 | Eastman Chemical Company | Adhesives comprising amorphous propylene-ethylene copolymers |
| US10647795B2 (en) | 2014-02-07 | 2020-05-12 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
| US10696765B2 (en) | 2014-02-07 | 2020-06-30 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer |
| US11267916B2 (en) | 2014-02-07 | 2022-03-08 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
| US10308740B2 (en) | 2014-02-07 | 2019-06-04 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
| EP3241611B1 (en) | 2016-05-02 | 2020-03-04 | Borealis AG | A process for feeding a polymerisation catalyst |
| EP3484932A1 (en) | 2016-07-15 | 2019-05-22 | Basell Poliolefine Italia S.r.l. | Catalyst for the polymerization of olefins |
| EP3519447B1 (en) * | 2016-09-27 | 2020-12-02 | ExxonMobil Chemical Patents Inc. | Polymerization process |
| ES2963183T3 (es) | 2016-12-19 | 2024-03-25 | Basell Poliolefine Italia Srl | Componentes del catalizador para la polimerización de olefinas y catalizadores obtenidos a partir de estos |
| EP3483189A1 (en) | 2017-11-14 | 2019-05-15 | Borealis AG | Automated method for terminating an olefin polymerization reaction under emergency conditions |
| CN112175115B (zh) * | 2019-07-02 | 2023-07-21 | 中国石油化工股份有限公司 | 烯烃聚合催化剂的固体催化剂组分及其制备方法和烯烃聚合催化剂及烯烃聚合的方法 |
| CN112175117B (zh) * | 2019-07-02 | 2023-07-21 | 中国石油化工股份有限公司 | 用于烯烃聚合的固体催化剂组分及其制备方法和用于烯烃聚合的催化剂及烯烃聚合的方法 |
| CN112759684B (zh) * | 2019-11-01 | 2023-07-21 | 中国石油化工股份有限公司 | 一种聚丁烯-1的制备方法及装置 |
| WO2021099123A1 (en) | 2019-11-20 | 2021-05-27 | Basell Poliolefine Italia S.R.L. | Process for the preparation of a catalyst component and components therefrom obtained |
| US11254761B1 (en) * | 2020-10-15 | 2022-02-22 | Chevron Phillips Chemical Company Lp | Catalyst pretreatment and feeding system for polypropylene production |
| US20240001317A1 (en) | 2020-11-27 | 2024-01-04 | Borealis Ag | Catalyst Feed System |
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| FR2646426B2 (fr) * | 1988-09-13 | 1991-08-16 | Bp Chemicals Sa | Procede et appareillage de polymerisation d'alpha-olefine en phase gazeuse en presence d'un agent ralentisseur d'activite |
| KR930001064B1 (ko) * | 1988-09-13 | 1993-02-15 | 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 | 올레핀중합용 촉매성분 및 그 제조방법, 올레핀중합용 촉매 및 올레핀의 중합방법 |
| IT1227258B (it) | 1988-09-30 | 1991-03-28 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| FR2649708B1 (fr) | 1989-07-17 | 1991-10-25 | Bp Chem Int Ltd | Procede de fabrication en phase gazeuse de copolymeres du propylene a l'aide d'un systeme catalytique de haute activite |
| IL95097A0 (en) | 1989-08-23 | 1991-06-10 | Himont Inc | Thermoplastic olefin polymer and its preparation |
| FR2651234B1 (fr) * | 1989-08-29 | 1993-03-12 | Bp Chem Int Ltd | Procede de fabrication en phase gazeuse de copolymeres du propylene a l'aide d'un systeme catalytique de haute activite. |
| JP2940684B2 (ja) | 1989-12-29 | 1999-08-25 | 三井化学株式会社 | オレフィン重合用固体状触媒成分およびこの触媒成分を用いたオレフィンの重合方法 |
| IT1241093B (it) | 1990-03-30 | 1993-12-29 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| JP3000706B2 (ja) | 1991-04-15 | 2000-01-17 | セイコーエプソン株式会社 | 超音波モータ |
-
1991
- 1991-06-03 IT ITRM910379A patent/IT1246614B/it active IP Right Grant
-
1992
- 1992-06-01 ZA ZA923985A patent/ZA923985B/xx unknown
- 1992-06-02 MX MX9202633A patent/MX9202633A/es unknown
- 1992-06-02 AR AR92322449A patent/AR247408A1/es active
- 1992-06-02 IL IL10207492A patent/IL102074A/en not_active IP Right Cessation
- 1992-06-03 DK DK92911445.2T patent/DK0541760T3/da active
- 1992-06-03 AU AU19177/92A patent/AU653829B2/en not_active Ceased
- 1992-06-03 DE DE69212633T patent/DE69212633T2/de not_active Expired - Lifetime
- 1992-06-03 UA UA93004428A patent/UA27785C2/uk unknown
- 1992-06-03 CA CA002088681A patent/CA2088681C/en not_active Expired - Fee Related
- 1992-06-03 EP EP92911445A patent/EP0541760B1/en not_active Expired - Lifetime
- 1992-06-03 EP EP19920109376 patent/EP0517183A3/en active Pending
- 1992-06-03 WO PCT/EP1992/001231 patent/WO1992021706A1/en not_active Ceased
- 1992-06-03 ES ES92911445T patent/ES2090646T3/es not_active Expired - Lifetime
- 1992-06-03 CN CN92105616A patent/CN1078216C/zh not_active Expired - Lifetime
- 1992-06-03 AT AT92911445T patent/ATE141094T1/de not_active IP Right Cessation
- 1992-06-03 BR BR9205273A patent/BR9205273A/pt not_active IP Right Cessation
- 1992-06-03 JP JP51122892A patent/JP3190041B2/ja not_active Expired - Lifetime
- 1992-06-03 PL PL92297841A patent/PL170118B1/pl not_active IP Right Cessation
- 1992-06-03 RU RU93005275/04A patent/RU2114125C1/ru active
- 1992-06-03 KR KR1019920703325A patent/KR100218863B1/ko not_active Expired - Lifetime
- 1992-06-03 HU HU9300265A patent/HU212442B/hu not_active IP Right Cessation
- 1992-12-29 CZ CS19923960A patent/CZ289004B6/cs not_active IP Right Cessation
-
1993
- 1993-01-14 FI FI930151A patent/FI106308B/fi active
- 1993-02-02 NO NO930363A patent/NO180721C/no not_active IP Right Cessation
-
1995
- 1995-06-07 US US08/476,063 patent/US6228956B1/en not_active Expired - Fee Related
-
1996
- 1996-08-08 GR GR960401974T patent/GR3020753T3/el unknown
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