KR950031959A - 유리 지지체위에 은 피막을 형성하는 방법 - Google Patents

유리 지지체위에 은 피막을 형성하는 방법 Download PDF

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KR950031959A
KR950031959A KR1019950011594A KR19950011594A KR950031959A KR 950031959 A KR950031959 A KR 950031959A KR 1019950011594 A KR1019950011594 A KR 1019950011594A KR 19950011594 A KR19950011594 A KR 19950011594A KR 950031959 A KR950031959 A KR 950031959A
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iii
silver coating
silver
solution
glass
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KR1019950011594A
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KR0173504B1 (ko
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라로쉐 피에르
불랑거 피에르
도뷔 크리스찬
Original Assignee
쟝 드 케르스매케르, 류시엔느 띠뜨가-반덴베르겐
글라베르벨
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Application filed by 쟝 드 케르스매케르, 류시엔느 띠뜨가-반덴베르겐, 글라베르벨 filed Critical 쟝 드 케르스매케르, 류시엔느 띠뜨가-반덴베르겐
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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/06—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/08—Mirrors
    • G02B5/0808—Mirrors having a single reflecting layer
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/06—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals
    • C03C17/10—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals by deposition from the liquid phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/23—Oxides
    • C03C17/25—Oxides by deposition from the liquid phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/38—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal at least one coating being a coating of an organic material
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/1851—Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material
    • C23C18/1872—Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material by chemical pretreatment
    • C23C18/1886—Multistep pretreatment
    • C23C18/1889—Multistep pretreatment with use of metal first

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Surface Treatment Of Glass (AREA)
  • Chemically Coating (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Catalysts (AREA)
  • Laminated Bodies (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

유리 지지체의 표면상에 은 피막을 형성하기 위한 방법이 기술된다. 본 방법은 유리 지지체의 표면의 활성용액과 접촉되는 활성화 단계, 상기 표면이 감응 용액과 접촉되는 감응 단계, 및 상기 표면이 은 공급원으로 이루어진 은 함유 용액과 접촉되어 은 피막을 형성하는 후속 은피복 단계로 구성된다. 본 방법은 상기 활성용액이 하나 이상의 비스무트(Ⅲ), 크롬(Ⅱ), 금(Ⅲ), 인듐(Ⅲ), 니켈(Ⅱ), 팔라듐(Ⅱ), 백금(Ⅱ), 로듐(Ⅲ), 루테늄(Ⅲ), 티탄(Ⅲ), 바나듐(Ⅲ) 및 아연(Ⅱ) 이온들로 구성됨을 특징으로 한다.

Description

유리 지지체위에 은 피막을 형성하는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (15)

  1. 유리 지지체의 표면을 활성 용액과 접촉시키는 활성화 단계, 상기 표면을 감응 용액과 접촉시키는 감응 단계, 및 상기 표면을 은 공급원으로 이루어진 은 함유 용액과 접촉시켜 은 피막을 형성하는 후속 은 피복 단계로 구성된 상기 표면상에 은 피막을 형성하는 방법으로서, 상기 활성 용액이 하나 이상의 비스무트(Ⅲ), 크롬(Ⅱ), 금(Ⅲ), 인듐(Ⅲ), 니켈(Ⅱ), 팔라듐(Ⅱ), 백금(Ⅱ), 로듐(Ⅲ), 루테늄(Ⅲ), 티탄(Ⅲ), 바나듐(Ⅲ) 및 아연(Ⅱ) 이온들로 구성됨을 특징으로 하는 방법.
  2. 제1항에 있어서, 상기 감응 단계에서, 상기 표면을 염화 주석(Ⅱ)으로 구성된 감응 용액과 접촉시키는 방법.
  3. 제1항 또는 제2항에 있어서, 상기 활성화 단계에 앞서 상기 감응 단계를 수행하는 방법.
  4. 제1 내지 제3항중 어느 한 항에 있어서, 상기 지지체가 편형한 유리 시이트인 방법.
  5. 제1 내지 제4항중 어느 한 항에 있어서, 상기 은 피복 단계에서 형성된 은층의 두께가 8nm 내지 30nm인 방법.
  6. 제1 내지 제5항중 어느 한 항에 있어서, 상기 은피복 단계에서 형성된 은층의 두께가 70nm 내지 100nm인 방법.
  7. 제1 내지 제6항중 어느 한 항에 있어서, 상기 활성 용액이 염화 팔라듐 수용액인 방법.
  8. 제7항에 있어서, 상기 염화 팔라듐 용액이 5 내지 135㎎/ℓ의 농도를 가지는 방법.
  9. 제7 또는 8항 있어서, 유리를 상기 지지체 표면의 제곱미터당 1 내지 23㎎ PdCl2와 접촉시키는 방법.
  10. 제7,8 또는 9항에 있어서, 유리를 상기 지지체 표면의 제곱미터당 5㎎ PdCl2와 접촉시키는 방법.
  11. 제1 내지 10항중 어느 한 항에 있어서, 상기 활성 용액의 pH가 3.0 내지 5.0인 방법.
  12. 제1 내지 11항중 어느 한 항에 있어서, 은 피막을 후속하여 Cr(Ⅱ), V(Ⅱ 또는 Ⅲ), Ti(Ⅱ 또는 Ⅲ), Fe(Ⅱ), In(Ⅰ또는 Ⅱ), Sn(Ⅱ), Cu(Ⅰ) 및 Al(Ⅲ)로 구성된 군중 하나 이상의 이온을 함유하는 용액과 접촉 시키는 방법.
  13. 제1 내지 12항 중 어느 한 항에 따른 방법에 의해 지지체 표면위에 형성된 은 피막을 갖는 유리 지지체.
  14. 구리 보호 층으로 덮지않은 은 피막을 포함하는 유리 지지체로 구성되고, 본원에 정의된 가속화된 노후 CASS 시험 및/또는 솔트 포그 시험에 적용시킨 후 d㎡당 10 이하의 흰색 반점의 평균수를 나타내는 거울.
  15. 제14항에 있어서, 본원에 정의된 가속화된 노후 CASS 시험 및/또는 솔트 포그 시험에 적용시킨 후, d㎡당 5 이하의 흰색 반점의 평균수를 나타내는 거울.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950011594A 1994-05-12 1995-05-11 유리 지지체상에 은 피막을 형성하는 방법 KR0173504B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9409538A GB9409538D0 (en) 1994-05-12 1994-05-12 Forming a silver coating on a vitreous substrate
GBN9409538.7 1994-05-12

Publications (2)

Publication Number Publication Date
KR950031959A true KR950031959A (ko) 1995-12-20
KR0173504B1 KR0173504B1 (ko) 1999-02-18

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KR1019950011594A KR0173504B1 (ko) 1994-05-12 1995-05-11 유리 지지체상에 은 피막을 형성하는 방법

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US (2) US6251482B1 (ko)
JP (1) JP3029187B2 (ko)
KR (1) KR0173504B1 (ko)
CN (1) CN1101351C (ko)
AT (1) AT405931B (ko)
AU (1) AU679621B2 (ko)
BE (1) BE1008678A3 (ko)
BR (1) BR9501696A (ko)
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DE (1) DE19516628A1 (ko)
DK (1) DK174699B1 (ko)
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Cited By (2)

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ZA953825B (en) 1996-01-17
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US6565217B2 (en) 2003-05-20
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NZ270981A (en) 1996-09-25
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NO951871L (no) 1995-11-13
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FR2719839B1 (fr) 1996-11-29
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