KR950008473A - 부가적인 관능기를 갖는 비닐 에테르 화합물 - Google Patents

부가적인 관능기를 갖는 비닐 에테르 화합물 Download PDF

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KR950008473A
KR950008473A KR1019940023859A KR19940023859A KR950008473A KR 950008473 A KR950008473 A KR 950008473A KR 1019940023859 A KR1019940023859 A KR 1019940023859A KR 19940023859 A KR19940023859 A KR 19940023859A KR 950008473 A KR950008473 A KR 950008473A
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쉬타인만 베티나
슐테스 아드리안
훈지커 막스
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베르너 발데크
시바-가이기 아게
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Abstract

본 발명은 분자 내에 아크릴레이트, 메타크릴레이트, 에폭시, 알켄일, 시크로알켄일 및 비닐아릴기로부터 선정된 1이상의 관능기를 더 포함하는 1이상의 비닐 에테르기함유 화합물, 이들 비닐 에테르 화합물을 포함하는, 특히 스테레오리소그래피용 조성물, 및 이들 조성물을 사용하여 3차원 제품을 제조하는 방법에 관한 것이다.

Description

부가적인 관능기를 갖는 비닐 에테르 화합물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (21)

  1. 분자 내에 아크릴레이트, 메타크릴레이트, 에폭시, 알켄일, 시크로알켄일 및 비닐아릴기로부터 선정된 1이상의 관능기를 더 포함하는 1이상의 비닐 에테르기 함유 화합물.
  2. 제2항에 있어서, 하기식의 화합물:
    상기식에서, A는 하기 일반식(1)(2)(3) 및 (4)의 라디칼로부터 선정되는 z가 라디칼이고;
    [D]는 하기식(5)의 기이며;
    [E]는 C1-또는 C2-알킬렌기이고; R0는 수소원자 또는 메틸기이며; R1는 지방족, 지환족, 방향족, 지방방향족 및 지방-지환족 라디칼 및 폴리옥시알킬렌 라디칼로부터 선정된 z가 라디칼이고; R2는 일반식
    의 라디칼들로부터 선정된 라디칼이며; R4는 일반식
    의 기들로부터 선정된 기이고; R5는 하기식의 기들로부터 선정된 기이며;
    R6는 일반식(2) 라디칼에서 하기식(6)의 각 z기의 탄소원자 Cα및 Cβ와 함께 (2-z)가 유기기이며, 탄소 원자 5이상의 지환족 고리를 형성하고;
    R14및 R15는 각각 수소원자이거나 또는 [E]가 C2알킬렌기일 때, 각각 수소원자이거나 또는 함께 메틸렌기를 형성하며; i는 0내지20의 정수이고; m은 1 내지 20의 정수이며; s는 2내지 10의 정수이고; t은 0내지 10의 정수이며; 일반식(5)에서 일반식
    의 각 단위체의 u는 각각 0 독립적으로 1 내지 20의 정수이며; v는 0 내지 4의 정수이고; x 및 y는 각각 독립적으로 2내지 20의 정수이며; z는 1 또는 2의 숫자이다.
  3. 제2항에 있어서, 하기식 (7) 또는 (8)중 하나를 갖는 화합물;
    상기식에서, R1, R2, R6, x 및 z는 제2항에 정의한 바와 같다.
  4. 제2항에 있어서, R1이 a)탄소 원자 2 내지 20의 지방족 라디칼, b)각각 탄소 원자 6 내지 14의 지환족 및 방향족 라디칼 c)각각 탄소 원자 7 내지 25의 지방-방향족 및 지방-지환족 라디칼, 및 d)일반식 R7-[OCgH2g]n- 및-(CgH2g)-[OCgH2g]n-1-의 폴리옥시알킬렌 라디칼로부터 선정된 z가 라디칼이고; R7이 탄소 원자 1 내지 8의 알킬기이며, g는폴리옥시알킬렌 라디칼의 알킬렌 단위체 탄소 원자의 평균 개수에 따른 1내지 8의 숫자이며, n이 2내지 20의 정수이고, 라디칼R1이 비치환되거나 또는 1이상의 치환체를 가질 수 있는데, 이 지방족 라디칼 R1이 C1-C4알콕시 및 할로겐 치환체로부터 선정되는 경우, 및 기타 유형의 라디칼 R1이 C1-C4알킬, C1-C|4알콕시 및 할로겐 치환체로부터 선정되는 경우인 화합물.
  5. 제4항에 있어서, R1이 하기식의 라디칼로부터 선정된 라디칼이며;
    R 및 R3은 각각 독립적으로 수소원자 또는 데틸이며, f는 2내지 20의 정수인 화합물.
  6. 제5항에 있어서, R1이 하기식의 라디칼로부터 선정된 라디칼이며;
    R4는 하기식의 기들로부터 선정된 기이고;
    R5는 하기식의 기들로부터 선정된 기이며;
    R 및 R3은 모두 수소원자 또는 메틸이고; k은 2내지 10의 정수이며, 지수 m의 상한은 10인 화합물.
  7. 제6항에 있어서, R1이 탄소 원자 2내지 4의 알킬렌 라디칼로부터 선정된 라디칼, 페닐 라디칼 및 일반식의 라디칼이고, R4가 일반식의 기이며, R5가 하기식의 기들로부터 선정된 기인 화합물;
  8. 제2항에 있어서, R6이 탄소 운자 3내지 50의 유기기인 화합물.
  9. 제8항에 있어서, z가 1이고, R6가 일반식(6)기의 탄소 원자 Cα및 Cβ와 함께 5내지 7의 고리 탄소원자를 갖는 시클로알킬 라디칼을 형성하며 여기에 5내지 7의 고리 탄소원자를 갖는 시클로알킬 라디칼이 더 융합될 수 있는 화합물.
  10. 제9항에 있어서, R6이 일반식(6)기의 탄소 원자 Cα및 Cβ와 함께 시클로펜틸 또는 시클로헥실 라디칼을 형성하는 화합물.
  11. 제8항에 있어서, R6는 일반식 R8-[G]-R9의 기이며, R8은 상기한 바와 같은 일반식(6)기의 탄소 원자 Cα및 Cβ와 함께 5내지 7의 고리 탄소원자를 갖는 시클로알킬 라디칼을 형성하며 여기에 5내지 7의 고리 탄소원자의 시클로알킬 라디칼이 더 융합될 수 있고; R9은 일반식(6)의 다른 기의 탄소 원자 Cα및 Cβ와 함께 5내지 7의 고리 탄소원자를 갖는 시클로알킬 라디칼을 형성하며, 여기에 5내지 7원 고리 탄소원자의 시클로알킬 라디칼이 더 융합될 수 있고, 또는 5 내지 7의 고리 탄소원다의 시클로알킬 라디칼이며, 여기에 5내지 7원 고리탄소 원자의 시클로알킬 라디칼이 더 융합될 수 있고, [G]는 하기식의 기 및 단일 결합으로부터 선정된 구조적 단위체이며;
    h는 1내지 6, 특히 2내지 4의 정수인 화합물.
  12. 제11항에 있어서, 하기식을 갖는 화합물:
    상기식에서, 라디칼 R10및 R13중 하나는 일반식 H2C=CH-O-(CH2)|x-O-의 기이고 또 다른 하나는 일반식 R2O-의 기이며, 이와 유사하게 R11및 R12중 하나는 일반식H2C=CH-O-(CH2)x-O-의 기이고 또 다른 하나는 일반식 R2O-의 기이며 x 및 h는 각각 독립적으로 2내지 4의 정수인 화합물.
  13. 제2항에 있어서, R2가인 화합물.
  14. 제2항에 있어서, A가 일반식(3) 또는 (4)의 라디칼이며, s는 2내지 4의 정수이고, t는 0내지 2의 정수이며, u는 숫자 1이고, v는 0 또는 1이며, x 및 y는 각각 2내지 10의 정수인 화합물.
  15. 제2항에 있어서, A가 일반식(4)의 라디칼이고, R14및 R15가 각각 수소 원자이며 z가 숫자 1인 화합물.
  16. 제2항에 있어서, 하기식을 갖는 화합물:
  17. 방사선에 의해 경화가능한 조성물의 중합성 성분으로서의 제1항에 따른 비닐 에테르 화합물의 용도.
  18. 서로 다른 중합성 화합물 1이상, 및 화합물 가교용 광개시제 1이상을 포함하는, 제1항에 따른 비닐 에테르화합물 1이상을 포함하는 조성물.
  19. 제18항에 있어서, 제1항에 따른 1이상의 비닐 에테르 화합물 5내지 60중량%; 단일, 이중 또는 다관능성 아크릴레이트 또는 메타크릴레이트 0내지 40중량%; 이중 또는 다기능성 에폭시 화합물 30 내지 80중량%; 라디칼 광개시제 0내지 5중량%; 히드록시-말단 폴리에테르 또는 폴리에스테르 0 내지 40중량%; 및 1이상의 부가제 0 내지 10중량%를 포함하는 조성물.
  20. 제18항에 따른 조성물이 화학 방사선으로 처리된 경화 제품 제조방법.
  21. UV/VIS 광원으로 조성물의 층표면 전체에 걸쳐 또는 소정 패턴에 조사하여 조사영역에서 원하는 층 두께로 층을 고형화하고, 조성물의 새로운 층을 고형화된 층 위에 형성시킨 다음 새로운 층의 표면 전체에 걸쳐 또는 소정 패턴을 조사하고, 피복 및 조사를 반복함으로써 다수의 상호 접착된 고형 층으로 구성된 3차원 제품을 제조하는 단계를 포함하는, 리소그래피에 의해 제18항에 따른 조성물로부터 3차원 제품을 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940023859A 1993-09-16 1994-09-15 부가적인관능기를갖는비닐에테르화합물 KR100355313B1 (ko)

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US5783615A (en) 1998-07-21
EP0646580B1 (de) 2000-05-31
EP0646580A2 (de) 1995-04-05
CA2132064A1 (en) 1995-03-17
AU7300394A (en) 1995-03-30
US5705316A (en) 1998-01-06
ES2147777T3 (es) 2000-10-01
US5783712A (en) 1998-07-21
ATE193532T1 (de) 2000-06-15
AU685824B2 (en) 1998-01-29
KR100355313B1 (ko) 2003-03-04
US5605941A (en) 1997-02-25
EP0646580A3 (de) 1995-10-11
DE59409385D1 (de) 2000-07-06
CA2132064C (en) 1999-12-28

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