KR950000713A - 신규의 천이금속화합물, 이 화합물로 된 올레핀 중합용촉매성분, 이 촉매성분을 함유한 올레핀중합용촉매와 이 촉매를 사용한 올레핀 중합방법, 프로필렌 단독 중합체, 프로필렌공중합체 및 프로필렌 탄성중합체 - Google Patents

신규의 천이금속화합물, 이 화합물로 된 올레핀 중합용촉매성분, 이 촉매성분을 함유한 올레핀중합용촉매와 이 촉매를 사용한 올레핀 중합방법, 프로필렌 단독 중합체, 프로필렌공중합체 및 프로필렌 탄성중합체 Download PDF

Info

Publication number
KR950000713A
KR950000713A KR1019940012755A KR19940012755A KR950000713A KR 950000713 A KR950000713 A KR 950000713A KR 1019940012755 A KR1019940012755 A KR 1019940012755A KR 19940012755 A KR19940012755 A KR 19940012755A KR 950000713 A KR950000713 A KR 950000713A
Authority
KR
South Korea
Prior art keywords
propylene
transition metal
compound
olefin polymerization
group
Prior art date
Application number
KR1019940012755A
Other languages
English (en)
Other versions
KR100293970B1 (ko
Inventor
다이수께 후꾸오카
따까시 타시로
꼬지 카와아이
준지 사이또
따까시 우에다
요시히사 끼소
아끼라 미즈노
마사아끼 까와사끼
마시아끼 이또오
준이찌 이무따
떼루노리 후지타
마사토시 이타바루
마사야수 요시다
미끼오 하시모또
Original Assignee
고다 시게노리
미쓰이세끼유 가가꾸고오교오 가부시끼가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27549247&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=KR950000713(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by 고다 시게노리, 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 filed Critical 고다 시게노리
Publication of KR950000713A publication Critical patent/KR950000713A/ko
Application granted granted Critical
Publication of KR100293970B1 publication Critical patent/KR100293970B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
    • C07C45/46—Friedel-Crafts reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
    • C07C49/665—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system
    • C07C49/67—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system having two rings, e.g. tetralones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/687—Unsaturated compounds containing a keto groups being part of a ring containing halogen
    • C07C49/697—Unsaturated compounds containing a keto groups being part of a ring containing halogen containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6428—Component covered by group C08F4/64 with an organo-aluminium compound with an aluminoxane, i.e. a compound containing an Al-O-Al- group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

본 발명의 신규 천이금속화합물은 하기식(I)으로 나타낸다.
상기 식중 M은 천이금속, R1은 탄소원자 2-6의 탄화수소기, R2는 탄소원자 6-16의 아릴기, X1과 X2는 할로겐원자 등 ; Y는 2가 탄화수소기, 2가 규소함유기 등이다.
본 발명의 올레핀중합촉매성분은 전술한 천이금속화합물을 포함하며, 본 발명의 올레핀중합촉매는 전술한 올레핀 중합촉매성분을 포함하며, 본 발명의 프로필렌 단독 중합체, 프로필렌 공중합체 및 프로필렌 탄성중합체는 프로필렌 단위쇄의 트리아드탁티시티가 높고, 프로필렌 단량체의 2,1-삽입에 의한 위치불규칙의 비율이 특정범위 내이고, 135℃의 데카히드로나프탈렌 중에서 측정한 고유점도[

Description

신규의 천이금속화합물, 이 화합물로 된 올레핀 중합용촉매성분, 이 촉매성분을 함유한 올레핀중합용촉매와 이 촉매를 사용한 올레핀 중합방법, 프로필렌 단독 중합체, 프로필렌공중합체 및 프로필렌 탄성중합체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 의한 올레핀 중합용 촉매의 제조방법의 공정을 나타낸 도면이다.

Claims (16)

  1. 하기 일반식(I)으로 표시되는 천이금속화합물 ;
    식중의 M은 주기율표 제 Ⅳa, Ⅴa, Ⅵa족의 천이금속이고, R1은 탄소원자 2~6의 탄화수소기이고, R2는 할로겐원자로 치환될 수 있는 탄소원자 6-16의 아릴기, 수소원자, 탄소원자 1~20의 탄화수소기 또는 유기실릴기이고, X1및 X2는 각각 수소원자, 할로겐원자, 탄소원자 1~20인 2가의 탄화수소기, 탄소원자 1~20인 2가의 할로겐화 탄화수소기, 산소함유기 또는 황함유기이고, Y는 탄소 원자, 1~20인 2가의 탄화수소기, 탄소원자 1~20인 2가의 할로겐화 탄화수소기, 2가의 규소함유기, 2가의 게르마늄함유기, -O-, -CO-, -S-, -SO-, -SO2-, -NR3-, -P(R3)-, -P(O)(R|3)-, -BR3- 또는 -AlR5-(R3는 수소원자, 할로겐원자, 탄소원자 1~20의 탄화수소기 또는 탄소원자 1~20의 할로겐화이다)이다.
  2. 하기 일반식(I)으로 표시되는 천이금속화합물로 된 올레핀중합용촉매성분 ;
    식중의 M은 주기율표 제 Ⅳa, Ⅴa, Ⅵa족의 천이금속이고, R1은 탄소원자 2~6의 탄화수소기이고, R2는 할로겐원자로 치환될 수 있는 탄소원자 6-16의 아릴기, 수소원자, 탄소원자 1~20의 탄화수소기 또는 유기실릴기이고, X1및 X2는 각각 수소원자, 할로겐원자, 탄소원자 1~20인 2가의 탄화수소기, 탄소원자 1~20의 할로겐화 탄화수소기, 산소함유기 또는 황함유기이고, Y는 탄소 원자, 1~20인 2가의 탄화수소기, 탄소원자 1~20인 2가의 할로겐화 탄화수소기, 2가의 규소함유기, 2가의 게르마늄함유기, -O-, -CO-, -S-, -SO-, -SO2-, -NR3-, -P(R3)-, -P(O)(R3)-, -BR3- 또는 -AlR5-(R3는 수소원자, 할로겐원자, 탄소원자 1~20의 탄화수소기 또는 탄소원자 1~20의 할로겐화이다)이다.
  3. (A) 상기 제2항의 천이금속화합물촉매성분 및 (B) (B-1) 유기알루미늄옥시화합물 (B-2) 천이금속화합물과 반응하여 이온쌍을 형성하는 화합물로 된 군에서 선택되는 적어도 1종의 화합물로된 올레핀중합용촉매.
  4. (A) 상기 제2항의 천이금속화합물촉매성분 ; (B) (B-1) 유기알루미늄옥시화합물 (B-2) 천이금속화합물과 반응하여 이온쌍을 형성하는 화합물로 된 군에서 선택되는 적어도 1종의 화합물 및 (C) 유기알루미늄화합물로 된 올레핀중합용촉매.
  5. 미립자 상 담체 (A) 상기 제2항의 천이금속화합물촉매성분 ; (B) (B-1) 유기알루미늄옥시화합물 (B-2) 천이금속화합물과 반응하여 이온쌍을 형성하는 화합물로 된 군에서 선택되는 적어도 1종의 화합물로 되고 상기 천이금속화합물촉매성분(A) 및 상기 적어도 1종의 화합물(B)이 미립자 상 담체에 담지된 올레핀중합용촉매.
  6. 미립자 상 담체 (A) 상기 제2항의 천이금속화합물촉매성분 ; (B) (B-1) 유기알루미늄옥시화합물 (B-2) 천이금속화합물과 반응하여 이온쌍을 형성하는 화합물로 된 군에서 선택되는 적어도 1종의 화합물로 되고, 상기 천이금속화합물촉매성분(A) 및 상기 적어도 1종의 화합물(B)이 미립자 상 담체에 담지된 고체촉매성분과 (C) 유기알루미늄화합물로 된 올레핀중합용촉매.
  7. 미립자 상 담체 (A) 상기 제2항의 천이금속화합물촉매성분 ; (B) (B-1) 유기알루미늄옥시화합물 (B-2) 천이금속화합물과 반응하여 이온쌍을 형성하는 화합물로 된 군에서 선택되는 적어도 1종의 화합물 및 예비중합에 의해 제조된 예비중합올레핀중합체로 된 올레핀중합용촉매.
  8. 미립자 상 담체 (A) 상기 제2항의 천이금속화합물촉매성분 ; (B) (B-1) 유기알루미늄옥시화합물 (B-2) 천이금속화합물과 반응하여 이온쌍을 형성하는 화합물로 된 군에서 선택되는 적어도 1종의 화합물 (C) 유기 알루미늄 화합물 및 예비중합에 의해 제조된 예비중합올레핀중합체로 된 올레핀중합용촉매.
  9. 제3~제8항중의 어느 1항 기재의 올레핀중합용촉매의 존재하에서 올레핀을 중합 또는 공중합시키는 올레핀중합방법.
  10. 제7 또는 제8항에서 기재의 올레핀중합촉매 및 유기알루미늄화합물 존재하에 올레핀을 중합 또는 공중합시키는 올레핀중합방법.
  11. (A) 제2항에의 천이금속화합물촉매성분과, (B) (B-1) 유기알루미늄옥시화합물과 (B-2) 천이금속화합물과 반응하여 이온쌍을 형성하는 화합물로 된 군에서 선택된 1 이상의 화합물로 된 올레핀중합촉매의 존재하에서 프로필렌을 중합하여 얻은 프로필렌 단독 중합체.
  12. (A) 제2항의 천이금속화합물촉매성분과, (B) (B-1) 유기알루미늄옥시화합물과 (B-2) 천이금속화합물과 반응하여 이온쌍을 형성하는 화합물로 된 군에서 선택된 1 이상의 화합물로 된 올레핀중합촉매의 존재하에서 에틸렌과 탄소원자 4~20의 α-올레핀으로 된 군에서 선택된 α-올레핀과 프로필렌을 공중합하여 얻은 프로필렌단위를 50몰% 이상 함유하는 프로필렌 공중합체.
  13. 프로필렌중합체에 있어서, (i) 프로필렌단위쇄의 트리아드탁티시티가13C-NMR로 측정하여 99.0% 이상이고, (ⅱ) 전 프로필렌 삽입중의 프로필렌 단량체의 2,1삽입에 의거한 위치 불규칙단위의 비가13C-NMR로 측정하여 0.2% 이하이며, (ⅲ) 고유점도가 135℃ 데카히드로 나프탈렌 중에서 측정하여 0.1~20dl/g의 범위에 있는 특성을 갖는 프로필렌중합체.
  14. 프로필렌공중합체에 있어서, (i) 상기 공중합체는 50몰% 이하의 에틸렌 단위를 함유하고, (ⅱ) 두미결합으로 된 프로필렌단위쇄의 트리아드탁티시티가13C-NMR로 측정하여 98.0% 이상이고, (ⅱ) 전 프로필렌 삽입중의 프로필렌 단량체의 2,1-삽입에 의거한 위치 불규칙단위의 비가13C-NMR로 측정하여 0.2% 이하이고, (ⅳ) 고유점도가 135℃ 데카히드로 나프탈렌중에서 측정하여 0.1~20dl/g의 범위에 있는 특성을 갖는 프로필렌공중합체.
  15. 프로필렌공중합체에 있어서, (i) 상기 공중합체는 95~99.5몰%의 프로필렌 단위와 0.5~5몰%의 에틸렌 단위를 함유하고, (ⅱ) 두미결합으로 된 프로필렌단위쇄의 트리아드탁티시티가13C-NMR로 측정하여 95.0% 이상이고, (ⅲ) 전 프로필렌 삽입중의 프로필렌 단량체의 2,1-삽입에 의거한 위치 불규칙단위의 비가13C-NMR로 측정하여 0.05%~0.5%이고, (ⅳ) 고유점도가 135℃ 데카히드로 나프탈렌 중에서 측정하여 0.1~12dl/g의 범위에 있는 특성을 갖는 프로필렌공중합체.
  16. 프로필렌탄성중합체 있어서, (i) 상기 탄성중합체는 50~95몰%의 프로필렌 단위와 5~50몰%의 에틸렌 단위를 함유하고, (ⅱ) 두미결합으로 된 프로필렌단위쇄의 트리아드탁티시티가13C-NMR로 측정하여 90.0% 이상이고, (ⅲ) 전 프로필렌 삽입중의 프로필렌 단량체의 2,1-삽입에 의거한 위치 불규칙단위의 비가13C-NMR로 측정하여 0.05%~0.5%이고, (ⅳ) 고유점도가 135℃ 데카히드로 나프탈렌 중에서 측정하여 0.1~12dl/g의 범위에 있는 특성을 갖는 프로필렌탄성중합체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940012755A 1993-06-07 1994-06-07 신규의천이금속화합물,이화합물로된올레핀중합용촉매성분,이촉매성분을함유한올레핀중합용촉매와촉매를사용한올레핀중합방법,프로필렌단독중합체,프로필렌공중합체 KR100293970B1 (ko)

Applications Claiming Priority (12)

Application Number Priority Date Filing Date Title
JP13625393 1993-06-07
JP93-136253 1993-06-07
JP93-238561 1993-09-24
JP23856193 1993-09-24
JP93-250742 1993-10-06
JP25074293 1993-10-06
JP93-298745 1993-11-29
JP93-298744 1993-11-29
JP29874493 1993-11-29
JP29874593 1993-11-29
JP2554894 1994-02-23
JP94-25548 1994-02-23

Related Child Applications (3)

Application Number Title Priority Date Filing Date
KR1020000074566A Division KR100332503B1 (ko) 1993-10-06 2000-12-08 프로필렌 에라스토머
KR1020000074564A Division KR100327172B1 (ko) 1993-11-29 2000-12-08 프로필렌 중합체
KR1020000074565A Division KR100349730B1 (ko) 1993-09-24 2000-12-08 프로필렌 공중합체

Publications (2)

Publication Number Publication Date
KR950000713A true KR950000713A (ko) 1995-01-03
KR100293970B1 KR100293970B1 (ko) 2001-09-17

Family

ID=27549247

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019940012755A KR100293970B1 (ko) 1993-06-07 1994-06-07 신규의천이금속화합물,이화합물로된올레핀중합용촉매성분,이촉매성분을함유한올레핀중합용촉매와촉매를사용한올레핀중합방법,프로필렌단독중합체,프로필렌공중합체

Country Status (6)

Country Link
US (6) US5658997A (ko)
EP (3) EP1070729B1 (ko)
KR (1) KR100293970B1 (ko)
CN (2) CN1166702C (ko)
CA (1) CA2125247C (ko)
DE (2) DE69427999T3 (ko)

Families Citing this family (193)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW309523B (ko) * 1991-11-30 1997-07-01 Hoechst Ag
TW294669B (ko) 1992-06-27 1997-01-01 Hoechst Ag
DE69502851T2 (de) * 1994-02-25 1998-11-12 Sumitomo Chemical Co Statistisches Propylencopolymer und Filmlaminat davon
CA2157400C (en) * 1994-04-11 2003-07-29 Takashi Ueda Process for preparing propylene polymer composition, and propylene polymer composition
CA2157399C (en) * 1994-04-11 2003-04-08 Takashi Ueda Process for preparing propylene polymer composition and propylene polymer composition
JP3338190B2 (ja) * 1994-08-17 2002-10-28 三菱化学株式会社 α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法
CA2164461C (en) † 1994-12-06 2000-08-08 Tatsuya Tanizaki Polypropylene composition and uses thereof
IT1272923B (it) 1995-01-23 1997-07-01 Spherilene Srl Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
DE19516803A1 (de) * 1995-05-08 1996-11-14 Hoechst Ag Organometallverbindung
JPH08325327A (ja) * 1995-06-02 1996-12-10 Chisso Corp 高立体規則性ポリプロピレン
AT403376B (de) * 1995-07-03 1998-01-26 Danubia Petrochem Polymere Metallocene mit silylsubstituierten brücken und deren einsatz für die olefinpolymerisation
DE19527047A1 (de) * 1995-07-25 1997-01-30 Danubia Petrochem Deutschland Metallocene mit silylsubstituierten Brücken und deren Einsatz für die Olefinpolymerisation
JP3264148B2 (ja) * 1995-08-31 2002-03-11 住友化学工業株式会社 プロピレン−エチレンランダム共重合体、その製法及びフィルム
DE19533337A1 (de) * 1995-09-11 1997-03-13 Basf Ag Propen/But-1-en-Copolymere
DE19533336A1 (de) * 1995-09-11 1997-03-13 Basf Ag Verfahren zur Herstellung von Propen/But-1-en-Copolymeren
ATE245665T1 (de) * 1995-09-28 2003-08-15 Basell Polyolefine Gmbh Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen
ATE222936T1 (de) * 1995-10-18 2002-09-15 Chisso Corp Olefin(co)polymerzusammensetzung, verfahren zu dessen herstellung, katalysator for olefin(co)polymerisation und verfahren zu dessen herstellung
US6787618B1 (en) 1995-12-01 2004-09-07 Basell Polypropylen Gmbh Metallocene compound and high molecular weight copolymers of propylene and olefins having two or four to thirty-two carbon atoms
DE19544828A1 (de) * 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
JP3181920B2 (ja) * 1996-04-22 2001-07-03 日本ポリオレフィン株式会社 ポリオレフィン製造用触媒及びポリオレフィンの製造方法
IT1283630B1 (it) * 1996-05-09 1998-04-23 Enichem Spa Procedimento per la preparazione di copolimeri elastomerici ep(d)m
TW404956B (en) † 1996-05-21 2000-09-11 Mitsui Petrochemical Ind A method of diminishing the source of odor from polyolefin obtained by use of metallocene compound
SG67392A1 (en) * 1996-05-27 1999-09-21 Sumitomo Chemical Co Propylene/ethylene-alpha-olefin block copolymer and process for producing the same
TW452586B (en) 1996-08-09 2001-09-01 Chisso Corp Polypropylene composition, process for preparing the same and catalyst for polymerization
TW396215B (en) * 1996-11-29 2000-07-01 Chisso Corp Fiber and products made of such fiber
TW442528B (en) * 1996-12-02 2001-06-23 Chisso Corp Polypropylene composition
TW425414B (en) * 1997-02-18 2001-03-11 Chisso Corp Preactivated catalyst for olefin (co)polymerization, catalyst for olefin (co)polymerization and olefin (co)polymer composition and their manufacturing method
DE69831139T2 (de) * 1997-03-07 2006-06-01 Basell Polyolefine Gmbh Verfahren zur herstellung substituierter indanone, die substituierte indanone und daraus hergestelle metallocene
EP0972800A4 (en) 1997-04-02 2004-06-16 Chisso Corp MODIFIED OLEFIN (CO) POLYMER COMPOSITION, METHOD FOR THE PRODUCTION THEREOF AND MODIFIED OLEFIN (CO) POLYMER MOLD
SG67489A1 (en) * 1997-04-07 1999-09-21 Mitsui Chemicals Inc Laminating propylene/1-butene random copolymer composition and composite film using the same
US6303696B1 (en) 1997-04-11 2001-10-16 Chisso Corporation Propylene (co)polymer composition using metallocene catalyst
US6160072A (en) * 1997-05-02 2000-12-12 Ewen; John A. Process for polymerizing tactioselective polyolefins in condensed phase using titanocenes
US6252019B1 (en) * 1997-05-13 2001-06-26 Montell Technology Company Bv Process for polymerizing tactioselective polyolefins in condensed phase using hafnocenes
TW504515B (en) 1997-08-07 2002-10-01 Chisso Corp Olefin (co)polymer composition
US6921794B2 (en) * 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US6642316B1 (en) 1998-07-01 2003-11-04 Exxonmobil Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polym
US6525157B2 (en) * 1997-08-12 2003-02-25 Exxonmobile Chemical Patents Inc. Propylene ethylene polymers
US7232871B2 (en) * 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US7026404B2 (en) * 1997-08-12 2006-04-11 Exxonmobil Chemical Patents Inc. Articles made from blends made from propylene ethylene polymers
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
AU8997098A (en) * 1997-09-04 1999-03-22 Chisso Corporation Propylene copolymer and process for the production thereof
CA2314502A1 (en) * 1997-12-23 1999-07-01 Donna J. Crowther Slurry polymerization process with alkyl-substituted biscyclopentadienyl metallocenes
DE19806918A1 (de) * 1998-02-19 1999-08-26 Aventis Res & Tech Gmbh & Co Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
US6228951B1 (en) * 1998-08-24 2001-05-08 Japan Polychem Corporation Polypropylene molding material
WO2000012572A1 (en) * 1998-08-26 2000-03-09 Exxon Chemical Patents Inc. Branched polypropylene compositions
DE59914158D1 (de) 1998-11-25 2007-03-08 Basell Polyolefine Gmbh Metallocenmonohalogenide
US6291699B1 (en) * 1999-08-24 2001-09-18 Boulder Scientific Company 2-alkyl-4-(2,6-dialkylphenyl) indenes
US6194527B1 (en) * 1999-09-22 2001-02-27 Equistar Chemicals, L.P. Process for making polyolefins
CN100434433C (zh) * 1999-10-08 2008-11-19 三井化学株式会社 茂金属化合物及制备方法、烯烃聚合催化剂、聚烯烃及制备方法
US6395847B2 (en) 1999-11-19 2002-05-28 Exxonmobil Chemical Patents Inc. Supported organometallic catalysts and their use in olefin polymerization
US6582762B2 (en) 1999-12-22 2003-06-24 Exxonmobil Chemical Patents Inc. Sprayable hot melt adhesives
KR100718424B1 (ko) * 1999-12-22 2007-05-14 엑손모빌 케미칼 패턴츠 인코포레이티드 폴리프로필렌계 접착제 조성물
AU2001232855A1 (en) 2000-01-21 2001-07-31 U.S. Borax Inc. Nonaborate compositions and their preparation
US6384142B1 (en) 2000-02-08 2002-05-07 Exxonmobil Chemical Patents Inc. Propylene impact copolymers
JP2003522194A (ja) 2000-02-08 2003-07-22 エクソンモービル・ケミカル・パテンツ・インク 第１４族架橋ビスシクロペンタジエニル・リガンドの調製方法
US6846943B2 (en) 2000-05-23 2005-01-25 Chisso Corporation Metallocene compound, olefin polymerization catalyst containing the compound, and method for producing an olefin polymer by use of the catalyst
US6376627B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376410B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376408B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380121B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376409B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380123B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6870016B1 (en) 2000-06-30 2005-03-22 Exxonmobil Chemical Patents Inc. Polymerization process and polymer composition
US6414095B1 (en) 2000-06-30 2002-07-02 Exxon Mobil Chemical Patents Inc. Metallocene compositions
US6376413B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
EP1632506A1 (en) * 2000-06-30 2006-03-08 ExxonMobil Chemical Patents Inc. Propylene polymer
US6376412B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380334B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376407B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380330B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US7122498B2 (en) 2000-06-30 2006-10-17 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US6399723B1 (en) 2000-06-30 2002-06-04 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380124B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380120B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380331B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376411B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380122B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
DE60113701T2 (de) * 2000-07-24 2006-03-16 Idemitsu Kosan Co. Ltd. Propylen homo-und copolymer
US6673869B2 (en) 2000-07-27 2004-01-06 Basell Poliolefine Italia S.P.A. Transparent elastomeric thermoplastic polyolefin compositions
EP1328420A4 (en) * 2000-09-21 2009-03-04 American Calcar Inc TECHNIQUE FOR OPERATING A VEHICLE EFFECTIVELY AND SECURELY
ATE485319T1 (de) * 2001-04-12 2010-11-15 Exxonmobil Chem Patents Inc Verfahren zur polymerisation von propylen und ethylen in lösung
GB0111020D0 (en) * 2001-05-04 2001-06-27 Borealis Tech Oy Process
EP1421090B1 (en) 2001-06-29 2014-03-26 ExxonMobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
WO2003014166A1 (en) * 2001-08-07 2003-02-20 Denki Kagaku Kogyo Kabushiki Kaisha Process for producing polymer
US7157591B2 (en) * 2001-12-10 2007-01-02 Exxonmobie Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
JP4031656B2 (ja) * 2002-03-14 2008-01-09 バセル ポリオレフィン イタリア エス．アール．エル． ポリプロピレン系樹脂組成物およびそのフィルム
SG106681A1 (en) 2002-03-29 2004-10-29 Mitsui Chemicals Inc Olefinic polymer and process for producing the same
US6995279B2 (en) 2002-08-02 2006-02-07 Chisso Corporation Metallocene compounds, processes for the production of olefin polymers using catalysts containing the compounds, and olefin polymers produced by the processes
US7998579B2 (en) 2002-08-12 2011-08-16 Exxonmobil Chemical Patents Inc. Polypropylene based fibers and nonwovens
CA2492839C (en) 2002-08-12 2011-02-01 Exxonmobil Chemical Patents Inc. Plasticized polyolefin compositions
US8003725B2 (en) 2002-08-12 2011-08-23 Exxonmobil Chemical Patents Inc. Plasticized hetero-phase polyolefin blends
US7271209B2 (en) 2002-08-12 2007-09-18 Exxonmobil Chemical Patents Inc. Fibers and nonwovens from plasticized polyolefin compositions
US7531594B2 (en) 2002-08-12 2009-05-12 Exxonmobil Chemical Patents Inc. Articles from plasticized polyolefin compositions
US20080153997A1 (en) * 2006-12-20 2008-06-26 Exxonmobil Research And Engineering Polymer production at supercritical conditions
US8058371B2 (en) * 2002-09-20 2011-11-15 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization
US8008412B2 (en) * 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
EP1539841B1 (en) * 2002-09-20 2012-08-01 ExxonMobil Chemical Patents Inc. Polymer production at supercritical conditions
US7550528B2 (en) * 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7223822B2 (en) * 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
KR101113341B1 (ko) * 2002-10-15 2012-09-27 엑손모빌 케미칼 패턴츠 인코포레이티드 올레핀 중합용 다중 촉매 시스템 및 이로부터 제조된중합체
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7541402B2 (en) * 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
RU2323921C2 (ru) * 2002-10-22 2008-05-10 Базелль Полиолефине Гмбх Получение замещенных инденов
US7176158B2 (en) * 2002-10-25 2007-02-13 Exxonmobil Chemical Patents Inc. Polymerization catalyst composition
US7265193B2 (en) * 2003-01-31 2007-09-04 Exxonmobil Chemical Patents Inc. Polymerization process
US8192813B2 (en) 2003-08-12 2012-06-05 Exxonmobil Chemical Patents, Inc. Crosslinked polyethylene articles and processes to produce same
WO2005105864A1 (en) * 2004-04-16 2005-11-10 Exxonmobil Chemical Patents Inc. Heterocyclic substituted metallocene compounds for olefin polymerization
JP4897670B2 (ja) 2004-05-04 2012-03-14 バーゼル・ポリオレフィン・ゲーエムベーハー アタクチック１−ブテンポリマー類の製造方法
WO2006010139A2 (en) * 2004-07-08 2006-01-26 Exxonmobil Chemical Patents Inc. Olefin polymerization catalyst system and process for use thereof
RU2377256C2 (ru) 2004-08-09 2009-12-27 Юнион Карбайд Кемикалз Энд Пластикс Текнолоджи Ллс Твердый высушенный распылением прокатализатор циглера-натта и способ полимеризации, в котором он используется
US7169864B2 (en) * 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
WO2006065906A2 (en) * 2004-12-16 2006-06-22 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US8389615B2 (en) 2004-12-17 2013-03-05 Exxonmobil Chemical Patents Inc. Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin
EP1831304B1 (en) 2004-12-17 2010-05-12 ExxonMobil Chemical Patents Inc. Homogeneous polymer blend and articles therefrom
DE602005016304D1 (de) 2004-12-17 2009-10-08 Exxonmobil Chem Patents Inc Polymerblends und vliesstoffe daraus
EP1828303B1 (en) 2004-12-17 2009-08-26 ExxonMobil Chemical Patents, Inc., A Corporation of the State of Delaware Heterogeneous polymer blends and molded articles therefrom
ATE435887T1 (de) 2004-12-17 2009-07-15 Exxonmobil Chem Patents Inc Folien aus polymerblends
US7232869B2 (en) * 2005-05-17 2007-06-19 Novolen Technology Holdings, C.V. Catalyst composition for olefin polymerization
US7951872B2 (en) 2005-06-22 2011-05-31 Exxonmobil Chemical Patents Inc. Heterogeneous polymer blend with continuous elastomeric phase and process of making the same
US9745461B2 (en) 2005-06-22 2017-08-29 Exxonmobil Chemical Patents Inc. Vulcanized polymer blends
US9644092B2 (en) 2005-06-22 2017-05-09 Exxonmobil Chemical Patents Inc. Heterogeneous in-situ polymer blend
US7928164B2 (en) 2005-06-22 2011-04-19 Exxonmobil Chemical Patents Inc. Homogeneous polymer blend and process of making the same
CN101218296B (zh) 2005-07-15 2010-12-08 埃克森美孚化学专利公司 弹性体组合物
US7763562B2 (en) * 2005-12-14 2010-07-27 Exxonmobil Chemical Patents Inc. Heteroatom bridged metallocene compounds for olefin polymerization
US7667064B2 (en) * 2005-12-14 2010-02-23 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7910783B2 (en) 2005-12-14 2011-03-22 Exxonmobil Chemical Patents Inc. Preparation of substituted bridged indenyl and related ligands
US7550544B2 (en) 2005-12-14 2009-06-23 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7868197B2 (en) 2005-12-14 2011-01-11 Exxonmobil Chemical Patents Inc. Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization
EP1963347B1 (en) 2005-12-14 2011-10-19 ExxonMobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7538168B2 (en) 2005-12-14 2009-05-26 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
EP1847555A1 (en) * 2006-04-18 2007-10-24 Borealis Technology Oy Multi-branched Polypropylene
JP4714088B2 (ja) * 2006-06-16 2011-06-29 株式会社小糸製作所 車両用前照灯
US7713636B2 (en) 2006-12-15 2010-05-11 Exxonmobil Chemical Patents Inc. Multi-layer films comprising propylene-based polymers
US8143352B2 (en) * 2006-12-20 2012-03-27 Exxonmobil Research And Engineering Company Process for fluid phase in-line blending of polymers
US8242237B2 (en) 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
US8080610B2 (en) 2007-03-06 2011-12-20 Exxonmobil Research And Engineering Company Monomer recycle process for fluid phase in-line blending of polymers
CN101855250B (zh) * 2007-09-13 2013-01-02 埃克森美孚研究工程公司 增塑剂与基础聚合物的在线共混
US7928162B2 (en) * 2007-09-13 2011-04-19 Exxonmobil Research And Engineering Company In-line process for producing plasticized polymers and plasticized polymer blends
US7868104B2 (en) * 2007-10-26 2011-01-11 Exxonmobil Chemical Patents Inc. Crystallizable propylene copolymers
US7910679B2 (en) * 2007-12-20 2011-03-22 Exxonmobil Research And Engineering Company Bulk homogeneous polymerization process for ethylene propylene copolymers
CN101945940B (zh) * 2007-12-20 2014-04-09 埃克森美孚研究工程公司 聚丙烯乙烯-丙烯共聚物共混物和生产它的在线方法
WO2009082463A1 (en) * 2007-12-20 2009-07-02 Exxonmobil Research And Engineering Company In-line process to produce pellet-stable polyolefins
US7812104B2 (en) * 2008-01-18 2010-10-12 Exxonmobil Chemical Patents Inc. Production of propylene-based polymers
US8318875B2 (en) * 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
EP2103634A1 (en) 2008-03-20 2009-09-23 ExxonMobil Chemical Patents Inc. Production of propylene-based polymers
JP5315773B2 (ja) * 2008-04-24 2013-10-16 住友化学株式会社 プロピレン系樹脂組成物
SG174602A1 (en) 2009-03-30 2011-11-28 Mitsui Chemicals Inc Copolymer of olefin and conjugated diene, and process for producing same
EP2322568B1 (en) 2009-11-13 2013-05-15 Borealis AG Process for producing an olefin polymerization catalyst
US8501881B2 (en) 2009-11-13 2013-08-06 Borealis Ag Process for olefin polymerization
CN102686613B (zh) 2009-11-13 2014-08-13 博瑞立斯有限公司 用于回收过渡金属化合物的方法
WO2011058089A1 (en) 2009-11-13 2011-05-19 Borealis Ag Process for producing a polymerization catalyst
EP2325248B1 (en) 2009-11-16 2012-05-16 Borealis AG Melt blown fibers of polypropylene compositions
EP2330136B1 (en) 2009-12-07 2013-08-28 Borealis AG Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins
ES2474090T3 (es) 2010-01-28 2014-07-08 Borealis Ag Fibra soplada en fusión
CN102884117A (zh) 2010-05-12 2013-01-16 北欧化工公司 用于特殊电容器的具有特定硬脂酸钙含量的聚丙烯
DK2390092T4 (da) 2010-05-25 2019-01-02 Borealis Ag Åndbart ikke-vævet kompositmateriale
EP2495037B1 (en) 2011-03-02 2020-08-19 Borealis AG High throughput reactor assembly for polymerization of olefins
HUE052511T2 (hu) 2011-03-02 2021-05-28 Borealis Ag Eljárás polimerek elõállítására
ES2605429T3 (es) 2011-06-15 2017-03-14 Borealis Ag Mezcla del reactor in situ de un polipropileno nucleado catalizado por Ziegler-Natta y un polipropileno catalizado por metaloceno
EP2573091A1 (en) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Process for recycling of free ligand from their corresponding metallocene complexes
SG11201404422WA (en) 2012-03-09 2014-08-28 Exxonmobil Chem Patents Inc Polyolefin adhesive compositions and methods of preparing the same
EP2890490B1 (en) 2012-08-29 2020-05-06 Borealis AG Reactor assembly and method for polymerization of olefins
WO2014050816A1 (ja) 2012-09-25 2014-04-03 三井化学株式会社 遷移金属化合物、オレフィン重合用触媒およびオレフィン重合体の製造方法
US9598516B2 (en) 2012-12-21 2017-03-21 Borealis Ag Catalyst
EP2745927A1 (en) 2012-12-21 2014-06-25 Borealis AG Fluidized bed reactor with internal moving bed reaction unit
ES2674576T3 (es) 2012-12-21 2018-07-02 Borealis Ag Catalizador
ES2645256T3 (es) 2012-12-21 2017-12-04 Borealis Ag Catalizadores
EP2745926A1 (en) 2012-12-21 2014-06-25 Borealis AG Gas phase polymerization and reactor assembly comprising a fluidized bed reactor and an external moving bed reactor
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
US9464145B2 (en) 2013-07-17 2016-10-11 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
CN105358589B (zh) 2013-07-17 2018-07-03 埃克森美孚化学专利公司 金属茂和由其衍生的催化剂组合物
SG10201802959WA (en) 2013-07-17 2018-05-30 Exxonmobil Chemical Patents Inc Cyclopropyl substituted metallocene catalysts
EP3848401A1 (en) 2013-07-17 2021-07-14 ExxonMobil Chemical Patents Inc. Isotactic propylene polymers
KR101580591B1 (ko) * 2014-06-10 2015-12-28 주식회사 엘지화학 프로필렌계 엘라스토머
ES2635519T3 (es) 2014-11-21 2017-10-04 Borealis Ag Procedimiento para producir gránulos de copolímeros blandos
CN106715067A (zh) 2014-12-08 2017-05-24 博里利斯股份公司 丙烯共聚物粒料的制备方法
EP3124567A1 (en) 2015-07-30 2017-02-01 Borealis AG Polypropylene based hot-melt adhesive composition
CN106632781B (zh) * 2015-10-29 2020-05-12 中国石油化工股份有限公司 具有支化结构的乙烯/丙烯共聚物的制备方法和该共聚物
EP3178853B1 (en) 2015-12-07 2018-07-25 Borealis AG Process for polymerising alpha-olefin monomers
EP3243622B1 (en) 2016-05-13 2020-09-09 Borealis AG Process for hydraulic conveying of polyolefin pellets
US10926517B2 (en) * 2016-11-10 2021-02-23 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
CA3048550A1 (en) * 2017-01-13 2018-07-19 Total Research & Technology Feluy High purity polypropylenes and polypropylene compositions for molding
US20210277290A1 (en) 2018-08-06 2021-09-09 Borealis Ag Propylene random copolymer based hot melt adhesive composition
EP3608364A1 (en) 2018-08-06 2020-02-12 Borealis AG Multimodal propylene random copolymer based composition suitable as hot melt adhesive composition
US20220177613A1 (en) 2018-11-30 2022-06-09 Borealis Ag Washing process
US11859041B2 (en) * 2021-08-16 2024-01-02 Chevron Phillips Chemical Company Lp Modulating co-monomer selectivity using non-covalent dispersion interactions in group 4 olefin polymerization catalysts
EP4144435A1 (en) 2021-09-01 2023-03-08 Borealis AG Gas phase polymerization process with improved gas recycling
CN118434803A (zh) 2021-12-17 2024-08-02 埃克森美孚化学专利公司 基于丙烯的共混物组合物
EP4389776A1 (en) 2022-12-20 2024-06-26 Borealis AG Process
EP4389783A1 (en) 2022-12-20 2024-06-26 Borealis AG Catalyst transition process
WO2024133046A1 (en) 2022-12-23 2024-06-27 Borealis Ag Process for producing a polypropylene copolymer
WO2024133044A1 (en) 2022-12-23 2024-06-27 Borealis Ag Process for producing a polypropylene homo- or copolymer
WO2024133045A1 (en) 2022-12-23 2024-06-27 Borealis Ag Process for producing a high-flow polypropylene homopolymer

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US547718A (en) 1895-10-08 Joseph fletcher
JPS58152038A (ja) * 1982-03-04 1983-09-09 Mitsui Toatsu Chem Inc 射出成形用ポリプロピレン組成物
CA1216700A (en) * 1983-01-25 1987-01-13 Masaki Kohyama Film-forming propylene copolymer, film thereof and process for production of the film
JPS6088049A (ja) * 1983-10-20 1985-05-17 Toray Ind Inc 二軸延伸ポリプロピレンフイルム
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
JPS6445488A (en) * 1987-08-12 1989-02-17 Toray Industries Polypropylene film for adhesive tape
JP2587251B2 (ja) * 1987-11-09 1997-03-05 チッソ株式会社 立体規則性オレフィン重合体製造用触媒
DE3742934A1 (de) * 1987-12-18 1989-06-29 Hoechst Ag Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung
US5155080A (en) * 1988-07-15 1992-10-13 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
KR930002411B1 (ko) * 1988-09-14 1993-03-30 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 벤젠불용성 유기알루미늄 옥시화합물 및 그 제조방법
JP2693517B2 (ja) 1988-09-14 1997-12-24 三井石油化学工業株式会社 ベンゼン不溶性の有機アルミニウムオキシ化合物の製造方法
CA2027145C (en) * 1989-10-10 2002-12-10 Michael J. Elder Metallocene catalysts with lewis acids and aluminum alkyls
EP0426637B2 (en) * 1989-10-30 2001-09-26 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
ES2086397T5 (es) * 1989-10-30 2005-07-16 Fina Technology, Inc. Adicion de alkiloaluminio para un catalizador metaloceno mejorado.
JP2545006B2 (ja) * 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
IT1243188B (it) * 1990-08-01 1994-05-24 Himont Inc Composizioni poliolefiniche elastoplastiche
JPH04179006A (ja) 1990-11-09 1992-06-25 Furukawa Electric Co Ltd:The セラミックス超電導線材の製造方法
JPH04179005A (ja) 1990-11-09 1992-06-25 Furukawa Electric Co Ltd:The 撚線導体の素線絶縁処理レベル判定方法
US5243001A (en) * 1990-11-12 1993-09-07 Hoechst Aktiengesellschaft Process for the preparation of a high molecular weight olefin polymer
JPH04207703A (ja) 1990-11-30 1992-07-29 Inax Corp 平面アンテナ
JP2797709B2 (ja) 1990-11-30 1998-09-17 日本電気株式会社 逓倍装置
AU649872B2 (en) * 1991-06-27 1994-06-02 Idemitsu Petrochemical Co., Ltd. Polypropylene resin and its composition
TW300901B (ko) * 1991-08-26 1997-03-21 Hoechst Ag
TW318184B (ko) * 1991-11-30 1997-10-21 Hoechst Ag
TW294669B (ko) * 1992-06-27 1997-01-01 Hoechst Ag
JPH072936A (ja) * 1992-07-10 1995-01-06 Fina Technol Inc アイソタクチツクポリオレフイン製造のための方法及び触媒
WO1994016009A1 (en) † 1993-01-11 1994-07-21 Mitsui Petrochemical Industries, Ltd. Propylene polymer composition
DE4333128A1 (de) † 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
DE4333569A1 (de) † 1993-10-01 1995-04-06 Hoechst Ag Verfahren zur Olefinpolymerisation

Also Published As

Publication number Publication date
DE69427999T2 (de) 2002-04-04
CN1103405A (zh) 1995-06-07
EP0629632B1 (en) 2000-10-04
DE69426043D1 (de) 2000-11-09
US5936053A (en) 1999-08-10
EP0812854A2 (en) 1997-12-17
EP0629632A3 (en) 1995-03-08
EP1070729B1 (en) 2011-09-28
EP0629632A2 (en) 1994-12-21
CA2125247C (en) 2001-02-20
EP0812854A3 (en) 1998-04-29
CN1048501C (zh) 2000-01-19
EP0812854B1 (en) 2001-08-16
DE69426043T2 (de) 2001-05-10
EP1070729A2 (en) 2001-01-24
KR100293970B1 (ko) 2001-09-17
EP1070729A3 (en) 2002-01-23
US5723640A (en) 1998-03-03
US5705584A (en) 1998-01-06
EP0629632B2 (en) 2015-01-21
CN1166702C (zh) 2004-09-15
US5658997A (en) 1997-08-19
US5710223A (en) 1998-01-20
DE69427999D1 (de) 2001-09-20
CN1249312A (zh) 2000-04-05
US5629254A (en) 1997-05-13
DE69427999T3 (de) 2012-09-27
EP0812854B2 (en) 2011-04-20
DE69426043T3 (de) 2015-06-18
CA2125247A1 (en) 1994-12-08

Similar Documents

Publication Publication Date Title
KR950000713A (ko) 신규의 천이금속화합물, 이 화합물로 된 올레핀 중합용촉매성분, 이 촉매성분을 함유한 올레핀중합용촉매와 이 촉매를 사용한 올레핀 중합방법, 프로필렌 단독 중합체, 프로필렌공중합체 및 프로필렌 탄성중합체
KR950000715A (ko) 신규의 천이금속화합물, 이 화합물로 된 올레핀 중합용촉매성분, 이 촉매성분을 함유한 올레핀 중합용촉매, 이 촉매를 사용한 올레핀 중합방법, 프로필렌단독중합체, 프로필렌공중합체 및 프로필렌탄성중합체
KR960701943A (ko) 프로필렌 중합체조성물의 제조방법 및 프로필렌 중합체조성물
KR950014149A (ko) 신규의 천이 금속화합물, 이 화합물로 된 올레핀중합용촉매성분, 이 촉매성분을 함유한 올레핀중합용촉매 및 올레핀중합방법
KR950700357A (ko) 프로필렌중합체 조성물
CA2018666C (en) Polypropylene resin compositions of high syndiotacticity and preparation process thereof
KR970006328A (ko) 올레핀중합촉매, 올레핀중합체의 제조방법 및 올레핀중합체
US5412046A (en) Polyethylene and method of production thereof
KR960703137A (ko) 프로필렌 엘라스토머
KR960701942A (ko) 프로필렌 중합체조성물의 제조방법 및 프로필렌 중합체조성물
KR970706347A (ko) 에틸렌계 중합체 조성물
KR870004062A (ko) 저분자량의 에틸렌-알파올레핀 공중합체 중간물
KR940011493A (ko) α-올레핀 중합체의 제조방법
KR970001390A (ko) 에틸렌공중합체고무, 그를 함유하는 가황고무조성물 및 그 공중합체고무의 제조방법
KR920703661A (ko) 스티렌계 혼성중합체 및 그 제조방법
ATE38044T1 (de) Buten-1-polymer und seine verwendung.
EP0854156A3 (en) Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer
ATE283292T1 (de) Verfahren zur olefinpolymerisation, metallocenkatalysator dafür und cokatalysator um den prometallocenkatalysator zu aktivieren
WO1990011305A1 (en) Styrenic copolymer and production thereof
KR910018413A (ko) 올레핀 중합용 고체 티탄 촉매성분, 올레핀 중합용 촉매, 예비중합된 폴리올레핀-함유 촉매 및 올레핀 중합방법.
KR970061922A (ko) 분자량 분포가 넓은 고분자량 폴리프로필렌
KR910000814A (ko) 고강성 폴리프로필렌의 제조방법 및 고입체규칙성 폴리프로필렌
KR970010795A (ko) 올레핀 중합용 촉매 성분, 올레핀 중합용 촉매 및 올레핀 중합체의 제조방법
KR970707174A (ko) 말단에 관능기를 갖는 폴리올레핀 제조 방법
KR930023376A (ko) 올레핀 중합용 촉매계, 이의 중합법과 얻은 중합체

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
A107 Divisional application of patent
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment
FPAY Annual fee payment
EXPY Expiration of term