KR870004062A - 저분자량의 에틸렌-알파올레핀 공중합체 중간물 - Google Patents

저분자량의 에틸렌-알파올레핀 공중합체 중간물 Download PDF

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KR870004062A
KR870004062A KR1019860008581A KR860008581A KR870004062A KR 870004062 A KR870004062 A KR 870004062A KR 1019860008581 A KR1019860008581 A KR 1019860008581A KR 860008581 A KR860008581 A KR 860008581A KR 870004062 A KR870004062 A KR 870004062A
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copolymer
composition
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에스·림 영
레오스 엔 · 메트 세우스 데메트
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더블유. 제이. 팔머
유니로열 케미칼 컴페니 인코퍼레이티드
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers

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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
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  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Insulating Materials (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
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Abstract

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Description

저분자량의 에틸렌-알파올레핀 공중합체 중간물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (44)

  1. 공중합체가 : (a) 약 250 ~ 약20,000의 수평균 분자량 및 ; (b) 최소한 약75의 점도지수를 가지며 상기 중합체가, 그 일단이 일반식 P-CR=CH2(여기서 P는 중합체 사슬을 나타내며 R은 1~10의 탄소 원선를 함유하는 알킬기이다)의 것인 비닐리덴형 불포화를 나타내는 ; 에틸렌 및 일반식 H2C=CHR(여기서 R은 위에서 정의된 바와 같다.)을 갖는 알파올레핀으로 구성된 공중합체.
  2. 제 1 항에 있어서, 공중합체가 비공역 폴리엔을 더 포함하여 구성된 공중합체.
  3. 제 1 항에 있어서, 공중합체가 약 500~약15,000의 수평균 분자량을 갖는 공중합체.
  4. 제 3 항에 있어서, 공중합체가 약 1,000~약10,000의 수평균 분자량을 갖는 공중합체.
  5. 제 1 항에 있어서, 공중합체가 최소한 약 100의 점도지수를 갖는 공중합체.
  6. 제 5 항에 있어서, 공중합체가 최소한 약 125의 점도지수를 갖는 공중합체.
  7. 제 1 항에 있어서, 공중합체가 약 20~약80%의 몰 에틸렌 함량을 갖는 공중합체.
  8. 제 1 항에 있어서, 공중합체 약 30~약70%의 몰 에틸렌 함량을 갖는 공중합체.
  9. 제 1 항에 있어서, 공중합체가 약35~약65%의 몰 에틸렌 함량을 갖는 공중합체.
  10. 제 1 항에 있어서, 알파올레핀이 프로필렌인 공중합체.
  11. 제 2 항에 있어서, 비공역 폴리엔이 5-에틸리덴-2-노르보르넨, 1,4-헥사디엔 또는 디시클로펜티디엔으로 구성된 군으로 부터 선택된 공중합체.
  12. 제 2 항에 있어서, 공중합체가 약 500~약15,000의 수평균 분자량을 갖는 공중합체.
  13. 제12항에 있어서, 공중합체가 약 1,000~약10,000의 수평균 분자량을 갖는 공중합체.
  14. 제 2 항에 있어서, 공중합체가 최소한 약 100의 점도지수를 갖는 공중합체.
  15. 제14항에 있어서, 공중합체가 최소한 약 125의 점도지수를 갖는 공중합체.
  16. 제 2 항에 있어서, 공중합체가 약 20~약80%의 몰 에틸렌 함량을 갖는 공중합체.
  17. 제 2 항에 있어서, 공중합체가 약 30~약70%의 몰 에틸렌 함량을 갖는 공중합체.
  18. 제 2 항에 있어서, 공중합체가 약 35~약65%의 몰 에틸렌 함량을 갖는 공중합체.
  19. 제 2 항에 있어서, 알파올레핀이 프로필렌인 공중합체.
  20. 공중합체가 : (a) 약250~약20,000의 수평균분자량 ; 및 (b) 최소한 약 75의 점도지수를 가지며 중합체 사슬의 최소한 약30%가 비닐리덴형 불포화를 나타내는 에틸렌 및 일반식 H2C=CHR(여기서 R은 1~10의 탄소원자를 함유하는 알킬기)을 갖는 알파올레핀의 공중합체 사슬로 구성된 조성물.
  21. 제20항에 있어서, 중합체 사슬의 최소한 약50%가 비닐리덴형 불포화를 나타내는 조성물.
  22. 제21항에 있어서, 중합체 사슬의 최소한 약60%가 비닐리덴형 불포화를 나타내는 조성물.
  23. 제22항에 있어서, 중합체 사슬의 최소한 약75%가 비닐리덴형 불포화를 나타내는 조성물.
  24. 제20항에 있어서, 중합체 사슬이 비공역 폴리엔을 더 포함하여 구성되는 조성물.
  25. 제20항에 있어서, 중합체 사슬이 약500~약15,000의 수평균 분자량을 갖는 조성물.
  26. 제25항에 있어서, 중합체 사슬이 약1,000~약10,000의 수평균 분자량을 갖는 조성물.
  27. 제20항에 있어서, 중합체 사슬이 최소한 약100의 점도지수를 갖는 조성물.
  28. 제27항에 있어서, 중합체 사슬이 최소한 약125의 점도지수를 갖는 조성물.
  29. 제20항에 있어서, 공중 합체가 약20~약80%의 몰 에틸렌 함량을 갖는 조성물.
  30. 제20항에 있어서, 공중 합체가 약30~약70%의 몰 에틸렌 함량을 갖는 조성물.
  31. 제20항에 있어서, 공중 합체가 약35~약65%의 몰 에틸렌 함량을 갖는 조성물.
  32. 제20항에 있어서, 알파올레핀이 프로필렌인 조성물.
  33. 제24항에 있어서, 공중합체 사슬이 약500~약15,000의 수평균 분자량을 갖는 조성물.
  34. 제33항에 있어서, 공중합체 사슬이 약1,000~약10,000의 수평균 분자량을 갖는 조성물.
  35. 제24항에 있어서, 공중합체 사슬이 최소한 약100의 점도지수를 갖는 조성물.
  36. 제35항에 있어서, 공중합체 사슬이 최소한 약125의 점도지수를 갖는 조성물.
  37. 제24항에 있어서, 공중합체가 약20~약80%의 몰 에틸렌 함량을 갖는 조성물.
  38. 제24항에 있어서, 공중합체가 약30~약70%의 몰 에틸렌 함량을 갖는 조성물.
  39. 제24항에 있어서, 공중합체가 약35~약65%의 몰 에틸렌 함량을 갖는 조성물.
  40. 제24항에 있어서, 알파올레핀이 프로필렌인 조성물.
  41. 제24항에 있어서, 비공역 폴리엔이 5-에틸리덴-2-노르보르넨, 1,4-헥사디엔 또는 디시클로펠타디엔으로 구성되어 있는 군으로부터 선택된 조성물.
  42. 제 1 항에 있어서, 공중합체가 에틸렌 및 일반식 H2C=CHR(여기서 R은 1~10의 탄소 원자를 함유하는 알킬기)을 갖는 알파올레핀으로 구성되는 공중합체.
  43. 제42항에 있어서, 알파올레핀이 프로필렌인 공중합체.
  44. (A) Q가 시클로펜타디엔, 5개 까지의 C1-C6알킬기로 치환된 시클로펜타디엔 또는 인덴이며 ; M은 지르코늄,티타늄 또는 하프늄 ; X는 C1-C4알킬, 할로겐, CH 2 AlR″2) CH2CH2AlR″2또는 CH2CH(AlR2″)2(여기서 R″는 C1-C6알킬 또는 OAl(C1-C6알킬) ; 및 n이 1,2 또는 3인 일반식 QnMX4~N을 갖는 촉매 : 및 (B)선상 구조식(a) R2′AlO-(AlR′O)n또는 환상구조식(b) (-AlR′0-)n+2(여기서 R′는 직쇄 또는 가지쇄 C1-C6알킬 및 n은 2~40의 정수)을 갖는 알루민옥산 조촉매에 있어서 Al/M몰비(여기서 M은 위에서 정의된 바와 같다)가 약10~약10,000인 것으로 구성된 촉매 조성물의 존재하에 약20~약100℃에서 에틸렌과 일반식 H2C=CHR(여기서 R은 1~10의 탄소 원자를 함유하는 알킬기)을 갖는 알파올레핀을 반응시키는 것으로 구성되는 공중합체.
    (a) 약250~약20,000의 수평균 분자량 및 ;
    (b) 최소한 약 75의 점도지수를 가지며 상기 중합체가, 그 일단이 일반식 P-CR=CH2(여기서 P는 중합체 사슬을 나타내며 R은 위에서 정의된 바와 같음)의 것인 비닐리덴형 불포화를 나타내는 ;
    에틸렌 및 일반식 H2C=CHR(여기서 R은 위에서 정의된 바와 같다)을 갖는 알파올레핀으로 구성되는 공중합체를 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860008581A 1985-10-16 1986-10-14 저분자량 에틸렌/알파올레핀 공중합체 중간물 KR910000200B1 (ko)

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US06787869 US4668834B1 (en) 1985-10-16 1985-10-16 Low molecular weight ethylene-alphaolefin copolymer intermediates
US787869 1985-10-16
US787,869 1991-11-05

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KR870004062A true KR870004062A (ko) 1987-05-07
KR910000200B1 KR910000200B1 (ko) 1991-01-23

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US (1) US4668834B1 (ko)
EP (1) EP0223394B1 (ko)
JP (3) JPS6295304A (ko)
KR (1) KR910000200B1 (ko)
CN (1) CN1018651B (ko)
AR (1) AR240330A1 (ko)
AU (1) AU597906B2 (ko)
BR (1) BR8604718A (ko)
CA (1) CA1281843C (ko)
DE (1) DE3684758D1 (ko)
IN (1) IN167916B (ko)
MX (1) MX168740B (ko)
ZA (1) ZA867249B (ko)

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US4668834A (en) 1987-05-26
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JPH07121969B2 (ja) 1995-12-25
MX168740B (es) 1993-06-07
CA1281843C (en) 1991-03-19
CN86106544A (zh) 1987-07-15
DE3684758D1 (de) 1992-05-14
BR8604718A (pt) 1987-06-23
ZA867249B (en) 1987-05-27
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CN1018651B (zh) 1992-10-14

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