HUP0004538A2 - Nikkel-diimin katalizátorok metil-alumoxán kokatalizátorral, eljárás ezen katalizátorokkal történő olefin polimerizációra és az előállított polimerek - Google Patents

Nikkel-diimin katalizátorok metil-alumoxán kokatalizátorral, eljárás ezen katalizátorokkal történő olefin polimerizációra és az előállított polimerek

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Publication number
HUP0004538A2
HUP0004538A2 HU0004538A HUP0004538A HUP0004538A2 HU P0004538 A2 HUP0004538 A2 HU P0004538A2 HU 0004538 A HU0004538 A HU 0004538A HU P0004538 A HUP0004538 A HU P0004538A HU P0004538 A2 HUP0004538 A2 HU P0004538A2
Authority
HU
Hungary
Prior art keywords
different
same
carbon atoms
atom
aromatic
Prior art date
Application number
HU0004538A
Other languages
English (en)
Inventor
Nancy W. Eilerts
Gil R. Hawley
Original Assignee
Phillips Petroleum Co.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co. filed Critical Phillips Petroleum Co.
Publication of HUP0004538A2 publication Critical patent/HUP0004538A2/hu

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

Abstract

A találmány tárgya a következőket tartalmazó heterogénkatalizátorkészítmény: a) (I) vagy (II) általános képletű diimin-nikkel komplex: ahol R azonos vagy egymástól eltérő, és elágazó vagy lineáris alkil- vagyaromás csoport, amely 1-10 szénatomot tartalmaz alkilcsoportonként ésaz aromás gyűrűn bármely helyzetben lehet; R' azonos vagy egymástól eltérő, és jelentése hidrogénatom vagylineáris, elágazó, ciklusos, áthidaló, aromás és/vagy alifásszénhidrogéncsoport, amely 1-70 szénatomot tartalmaz csoportonként; R''CYCXCYR''azonos vagy egymástól eltérő, és jelentése a-deprotonált-b-diketon vagy annak kén- vagy szelénanalógja, a-deprotonált-b-ketoészter vagy annak kén- vagy szelénanalógja, halogénatom vagy azelőbbiekben említett csoportok közül bármely kettőnek vagy többnek akeveréke, és amelyben R'' és X azonos vagy egymástól eltérő, ésjelentése egyedileg hidrogénatom vagy adott esetben szubsztituáltlineáris, elágazó, ciklusos, áthidaló, aromás vagy alifásszénhidrogéncsoport vagy az említett csoportok közül bármely kettőnekvagy többnek a keveréke, amelyek 1-70 szénatomot tartalmaznakcsoportonként; Y azonos vagy egymástól eltérő, és jelentése oxigénatom, kénatom vagyszelénatom; és Z jelentése halogénatom; és b) metil-aluminoxán. A találmány tárgyatovábbá a fenti katalizátorokkal történő olefinpolimerizációs eljárásés az eljárással előállított etilén polimer készítmény, amely vázában20-3000 rövid szénláncú elágazást tartalmaz 10000 szénatomra és szélesmolekulatömeg-eloszlással jellemezhető. Ó
HU0004538A 1997-12-19 1998-12-08 Nikkel-diimin katalizátorok metil-alumoxán kokatalizátorral, eljárás ezen katalizátorokkal történő olefin polimerizációra és az előállított polimerek HUP0004538A2 (hu)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US99449097A 1997-12-19 1997-12-19
PCT/US1998/025889 WO1999032226A1 (en) 1997-12-19 1998-12-08 Nickel diimine catalysts with methylalumoxane as cocatalyst, method of polymerization of olefins therewith and polymers produced

Publications (1)

Publication Number Publication Date
HUP0004538A2 true HUP0004538A2 (hu) 2001-04-28

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
HU0004538A HUP0004538A2 (hu) 1997-12-19 1998-12-08 Nikkel-diimin katalizátorok metil-alumoxán kokatalizátorral, eljárás ezen katalizátorokkal történő olefin polimerizációra és az előállított polimerek

Country Status (13)

Country Link
US (3) US6479422B1 (hu)
EP (1) EP1056539A4 (hu)
JP (1) JP2001526311A (hu)
KR (1) KR20010033302A (hu)
CN (2) CN1138597C (hu)
AU (1) AU740452B2 (hu)
BR (1) BR9814295A (hu)
CA (1) CA2311624A1 (hu)
HU (1) HUP0004538A2 (hu)
MX (1) MXPA00006074A (hu)
NO (1) NO20003160L (hu)
RU (1) RU2000119136A (hu)
WO (1) WO1999032226A1 (hu)

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Also Published As

Publication number Publication date
CN1138597C (zh) 2004-02-18
CA2311624A1 (en) 1999-07-01
MXPA00006074A (es) 2003-08-01
BR9814295A (pt) 2000-10-10
US20020016426A1 (en) 2002-02-07
AU740452B2 (en) 2001-11-01
CN1282274A (zh) 2001-01-31
NO20003160L (no) 2000-08-18
KR20010033302A (ko) 2001-04-25
EP1056539A4 (en) 2005-01-26
US6821920B2 (en) 2004-11-23
EP1056539A1 (en) 2000-12-06
CN1482168A (zh) 2004-03-17
RU2000119136A (ru) 2002-08-10
US6521727B2 (en) 2003-02-18
US6479422B1 (en) 2002-11-12
JP2001526311A (ja) 2001-12-18
AU1904499A (en) 1999-07-12
NO20003160D0 (no) 2000-06-16
US20030134996A1 (en) 2003-07-17
WO1999032226A1 (en) 1999-07-01

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