JPS57123205A - Production of low-molecular weight copolymer - Google Patents
Production of low-molecular weight copolymerInfo
- Publication number
- JPS57123205A JPS57123205A JP260381A JP260381A JPS57123205A JP S57123205 A JPS57123205 A JP S57123205A JP 260381 A JP260381 A JP 260381A JP 260381 A JP260381 A JP 260381A JP S57123205 A JPS57123205 A JP S57123205A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- low
- molecular weight
- ethylene
- weight copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
PURPOSE: To produce the titled copolymer having a low heating loss and a high flash point, by copolymerizing in a liquid phase ethylene with a 3C or higher α-olefin in the presence of hydrogen under specified conditions including the use of a catalyst consisting of a soluble V compound and an organic Al compound.
CONSTITUTION: A low-molecular weight copolymer, ethylene content of 30W 90mol%, number-average MW of 300W30,000 is prepared by continuously polymerizing ethylene with a 3C higher α-olefin (e.g., propylene) in the presence of hydrogen in an inert solvent (e.g., butane) with the aid of a catalyst consisting of a soluble V compound of formulaI, where R is an aliphatic hydrocarbon group, X is a halogen and 0≤n≤3, and an organic Al compound of formula II, wherein R1 is R, X1 is X and 1≤m≤3, while feeding the V compound dissolved in an inert solvent in amounts to provide a concentration which is five- times or below that in the polymerization system so as to maintain the V compound concentration in the polymerization system at 0.3W30mmol/l of liquid phase.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP260381A JPS57123205A (en) | 1981-01-13 | 1981-01-13 | Production of low-molecular weight copolymer |
EP82300109A EP0060609B2 (en) | 1981-01-13 | 1982-01-08 | Process for producing an ethylene/alpha-olefin copolymer |
DE8282300109T DE3270823D1 (en) | 1981-01-13 | 1982-01-08 | Novel ethylene/alpha-olefin copolymer |
CA000393987A CA1169102A (en) | 1981-01-13 | 1982-01-12 | Ethylene/alpha-olefin copolymer |
US08/091,733 US6153807A (en) | 1981-01-13 | 1993-07-14 | Process for producing ethylene/alpha-olefin copolymer |
US08/098,236 US5955639A (en) | 1981-01-13 | 1993-07-29 | Ethylene/alpha-olefin copolymer |
US08/449,282 US5767331A (en) | 1981-01-13 | 1995-05-24 | Ethylene/alpha-olefin copolymer |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP260381A JPS57123205A (en) | 1981-01-13 | 1981-01-13 | Production of low-molecular weight copolymer |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS57123205A true JPS57123205A (en) | 1982-07-31 |
JPH021163B2 JPH021163B2 (en) | 1990-01-10 |
Family
ID=11533958
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP260381A Granted JPS57123205A (en) | 1981-01-13 | 1981-01-13 | Production of low-molecular weight copolymer |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57123205A (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6035009A (en) * | 1983-06-15 | 1985-02-22 | エクソン・リサ−チ・アンド・エンジニアリング・カンパニ− | Alpha-olefin copolymer of narrow mwd |
JPS6295304A (en) * | 1985-10-16 | 1987-05-01 | ユニロイヤル ケミカル カンパニ− インコ−ポレ−テツド | Low molecular weight ethylene-alpha-olefin copolymer |
JPS63196690A (en) * | 1987-02-12 | 1988-08-15 | Mitsui Petrochem Ind Ltd | Lubricating oil composition |
JPS63210198A (en) * | 1987-02-27 | 1988-08-31 | Idemitsu Kosan Co Ltd | Multigrade engine oil composition |
JPS63210197A (en) * | 1987-02-27 | 1988-08-31 | Idemitsu Kosan Co Ltd | Lubricating oil composition |
JPS63227697A (en) * | 1987-03-17 | 1988-09-21 | Shin Etsu Chem Co Ltd | Tacky grease composition |
US5942568A (en) * | 1994-10-24 | 1999-08-24 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyoxymethylene with polyolefin prepared from single site catalyst |
WO2022080396A1 (en) | 2020-10-15 | 2022-04-21 | 三井化学株式会社 | Organosilicon compound graft copolymer, and tire rubber composition containing said copolymer |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7795194B2 (en) | 2004-11-26 | 2010-09-14 | Mitsui Chemicals, Inc. | Synthetic lubricating oil and lubricating oil composition |
JP6618891B2 (en) | 2014-03-28 | 2019-12-11 | 三井化学株式会社 | Ethylene / α-olefin copolymer and lubricating oil |
KR101970078B1 (en) | 2014-09-10 | 2019-04-17 | 미쓰이 가가쿠 가부시키가이샤 | Lubricant composition |
JP6741790B2 (en) | 2017-01-16 | 2020-08-19 | 三井化学株式会社 | Lubricating oil composition for automobile gear |
US11767404B2 (en) | 2018-03-07 | 2023-09-26 | Mitsui Chemicals, Inc. | Resin composition for masterbatch |
JPWO2022154126A1 (en) | 2021-01-18 | 2022-07-21 | ||
JPWO2022186053A1 (en) | 2021-03-05 | 2022-09-09 |
-
1981
- 1981-01-13 JP JP260381A patent/JPS57123205A/en active Granted
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6035009A (en) * | 1983-06-15 | 1985-02-22 | エクソン・リサ−チ・アンド・エンジニアリング・カンパニ− | Alpha-olefin copolymer of narrow mwd |
JPS6295304A (en) * | 1985-10-16 | 1987-05-01 | ユニロイヤル ケミカル カンパニ− インコ−ポレ−テツド | Low molecular weight ethylene-alpha-olefin copolymer |
JPS63196690A (en) * | 1987-02-12 | 1988-08-15 | Mitsui Petrochem Ind Ltd | Lubricating oil composition |
JPS63210198A (en) * | 1987-02-27 | 1988-08-31 | Idemitsu Kosan Co Ltd | Multigrade engine oil composition |
JPS63210197A (en) * | 1987-02-27 | 1988-08-31 | Idemitsu Kosan Co Ltd | Lubricating oil composition |
JPS63227697A (en) * | 1987-03-17 | 1988-09-21 | Shin Etsu Chem Co Ltd | Tacky grease composition |
JPH0534394B2 (en) * | 1987-03-17 | 1993-05-21 | Shinetsu Chem Ind Co | |
US5942568A (en) * | 1994-10-24 | 1999-08-24 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyoxymethylene with polyolefin prepared from single site catalyst |
WO2022080396A1 (en) | 2020-10-15 | 2022-04-21 | 三井化学株式会社 | Organosilicon compound graft copolymer, and tire rubber composition containing said copolymer |
Also Published As
Publication number | Publication date |
---|---|
JPH021163B2 (en) | 1990-01-10 |
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