KR20010101232A - 감열성 기록 물질 - Google Patents
감열성 기록 물질 Download PDFInfo
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- KR20010101232A KR20010101232A KR1020017007474A KR20017007474A KR20010101232A KR 20010101232 A KR20010101232 A KR 20010101232A KR 1020017007474 A KR1020017007474 A KR 1020017007474A KR 20017007474 A KR20017007474 A KR 20017007474A KR 20010101232 A KR20010101232 A KR 20010101232A
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- substituted
- alkyl
- unsubstituted
- phenyl
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/44—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton
- C07C317/48—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton the carbon skeleton being further substituted by singly-bound nitrogen atoms, not being part of nitro or nitroso groups
- C07C317/50—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton the carbon skeleton being further substituted by singly-bound nitrogen atoms, not being part of nitro or nitroso groups at least one of the nitrogen atoms being part of any of the groups, X being a hetero atom, Y being any atom
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
- B41M5/333—Colour developing components therefor, e.g. acidic compounds
- B41M5/3333—Non-macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
- C07C311/50—Compounds containing any of the groups, X being a hetero atom, Y being any atom
- C07C311/51—Y being a hydrogen or a carbon atom
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
- C07C311/50—Compounds containing any of the groups, X being a hetero atom, Y being any atom
- C07C311/52—Y being a hetero atom
- C07C311/54—Y being a hetero atom either X or Y, but not both, being nitrogen atoms, e.g. N-sulfonylurea
- C07C311/57—Y being a hetero atom either X or Y, but not both, being nitrogen atoms, e.g. N-sulfonylurea having sulfur atoms of the sulfonylurea groups bound to carbon atoms of six-membered aromatic rings
- C07C311/60—Y being a hetero atom either X or Y, but not both, being nitrogen atoms, e.g. N-sulfonylurea having sulfur atoms of the sulfonylurea groups bound to carbon atoms of six-membered aromatic rings having nitrogen atoms of the sulfonylurea groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
- C07C311/50—Compounds containing any of the groups, X being a hetero atom, Y being any atom
- C07C311/52—Y being a hetero atom
- C07C311/54—Y being a hetero atom either X or Y, but not both, being nitrogen atoms, e.g. N-sulfonylurea
- C07C311/57—Y being a hetero atom either X or Y, but not both, being nitrogen atoms, e.g. N-sulfonylurea having sulfur atoms of the sulfonylurea groups bound to carbon atoms of six-membered aromatic rings
- C07C311/62—Y being a hetero atom either X or Y, but not both, being nitrogen atoms, e.g. N-sulfonylurea having sulfur atoms of the sulfonylurea groups bound to carbon atoms of six-membered aromatic rings having nitrogen atoms of the sulfonylurea groups further acylated
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Display Devices Of Pinball Game Machines (AREA)
Abstract
Description
Claims (22)
- 하나 이상의 색 형성 화합물 a)와하나 이상의 화학식 1의 현상제 b)를 포함하는 감열성 기록 물질.화학식 1위의 화학식 1에서,R1은 치환되지 않거나 치환된 페닐, 나프틸 또는 C1-C20알킬이고,X는 화학식의 그룹이며,A는 치환되지 않거나 치환된 페닐렌, 나프틸렌 또는 C1-C12알킬렌이거나, 치환되지 않거나 치환된 헤테로사이클릭 그룹이고,B는 화학식 -O-SO2-, -SO2-O-, -NH-SO2-, -SO2-NH-, -S-SO2-, -O-CO-, -O-CO-NH-, -NH-CO-, -NH-CO-O-, -S-CO-NH-, -S-CS-NH-, -CO-NH-SO2-, -O-CO-NH-SO2-, -NH=CH-, -CO-NH-CO-, -S-, -CO-, -O-, -SO2-NH-CO-, -O-CO-O- 및 -O-PO-(OR2)2의 결합 그룹이며,R2는 치환되지 않거나 치환된 아릴 또는 벤질이거나, C1-C20알킬이고,단, B가 화학식 -O-SO2-의 결합 그룹이 아닌 경우, R2는 치환되지 않거나 치환된 페닐, 나프틸 또는 C1-C6알킬이며,B가 -O-인 경우, R2는 알킬이 아니다.
- 제1항에 있어서, R1이 치환되지 않거나, C1-C8알킬, C1-C8알콕시 또는 할로겐에 의해 치환된 페닐인 기록 물질.
- 제1항 또는 제2항에 있어서, R1이, C1-C8알킬, C1-C8알콕시 또는 할로겐에 의해 치환된 페닐인 기록 물질.
- 제1항 내지 제3항 중의 어느 한 항에 있어서, R1이, C1-C4알킬, 바람직하게는 메틸에 의해 치환된 페닐인 기록 물질.
- 제1항 내지 제4항 중의 어느 한 항에 있어서, X가 화학식의 그룹인 기록 물질.
- 제1항 내지 제5항 중의 어느 한 항에 있어서, A가, 치환되지 않거나 C1-C8알킬, 할로겐 치환된 C1-C8알킬, C1-C8알콕시 치환된 C1-C8알킬, C1-C8알콕시, 할로겐 치환된 C1-C8알콕시, C1-C8알킬설포닐, 할로겐, 페닐, 페녹시 또는 페녹시카보닐에 의해 치환된 페닐렌; 나프틸렌; C1-C12알킬렌; 또는 치환되지 않거나 C1-C8알킬에 의해 치환된 피리미딜렌인 기록 물질.
- 제1항 내지 제6항 중의 어느 한 항에 있어서, A가, 치환되지 않거나 C1-C8알킬, 할로겐 치환된 C1-C8알킬, C1-C8알콕시 치환된 C1-C8알킬, C1-C8알콕시, 할로겐 치환된 C1-C8알콕시, C1-C8알킬설포닐, 할로겐, 페닐, 페녹시 또는 페녹시카보닐에 의해 치환된 페닐렌인 기록 물질.
- 제1항 내지 제7항 중의 어느 한 항에 있어서, A가, 치환되지 않거나 C1-C8알킬, 할로겐 치환된 C1-C8알킬, C1-C8알킬설포닐 또는 할로겐에 의해 치환된 페닐렌인 기록 물질.
- 제1항 내지 제8항 중의 어느 한 항에 있어서, A가, 치환되지 않거나 C1-C4알킬 또는 할로겐에 의해 치환된 페닐렌, 바람직하게는 치환되지 않은 페닐렌인 기록 물질.
- 제1항 내지 제9항 중의 어느 한 항에 있어서, B가 화학식 -O-SO2-, -SO2-O-, -SO2-NH-, -S-SO2-, -O-CO-, -O-, -O-CO-NH-, -SO2-NH-CO-, -O-CO-O- 또는 -O-PO-(OR2)2의 결합 그룹, 바람직하게는 화학식 -O-, -O-SO2-, -SO2-O- 또는 -SO2-NH-의 결합 그룹인 기록 물질.
- 제1항 내지 제10항 중의 어느 한 항에 있어서, B가 화학식 -O-SO2-의 결합 그룹인 기록 물질.
- 제1항 내지 제10항 중의 어느 한 항에 있어서,B가 화학식 -O-의 결합 그룹이고,R2가 치환되지 않거나 치환된 아릴 또는 벤질인 기록 물질.
- 제1항 내지 제12항 중의 어느 한 항에 있어서, R2가 C1-C6알킬, 할로겐 치환된 C1-C6알킬; 페닐 치환된 C1-C6알킬; 나프틸 치환된 C1-C6알킬; 치환되지 않거나 C1-C8알킬, 할로겐 치환된 C1-C8알킬, C1-C8알콕시 치환된 C1-C8알킬, C1-C8알콕시, 할로겐 치환된 C1-C8알콕시 또는 할로겐에 의해 치환된 페닐; 나프틸 및 C1-C4알킬 또는 할로겐에 의해 치환된 벤질인 기록 물질.
- 제1항 내지 제12항 중의 어느 한 항에 있어서, R2가 C1-C4알킬, 할로겐 치환된 C1-C4알킬; 치환되지 않거나 C1-C4알킬 또는 할로겐에 의해 치환된 페닐; 나프틸 또는 치환되지 않거나 C1-C4알킬 또는 할로겐에 의해 치환된 벤질인 기록 물질.
- 제1항 내지 제12항 중의 어느 한 항에 있어서, R2가 치환되지 않거나 C1-C4알킬에 의해 치환된 페닐인 기록 물질.
- 제1항 내지 제15항 중의 어느 한 항에 있어서,R1이 C1-C4알킬, 바람직하게는 메틸에 의해 치환된 페닐이고,X가 화학식의 그룹이며,A가 치환되지 않거나 C1-C4알킬 또는 할로겐에 의해 치환된 페닐렌, 바람직하게는 치환되지 않은 페닐렌이고,B가 화학식 -O-SO2- 또는 -O-의 결합 그룹이며,R2가 치환되지 않거나 C1-C4알킬에 의해 치환된 페닐 또는 벤질인 기록 물질.
- 제1항 내지 제16항 중의 어느 한 항에 있어서, 하나 이상의 감광제를 포함하는 기록 물질.
- 제17항에 있어서, 스테아르아미드, 메틸올 스테아르아미드, p-벤질비페닐, m-테르페닐, 2-벤질옥시나프탈렌, 4-메톡시비페닐, 디벤질 옥살레이트, 디(4-메틸벤질)옥살레이트, 디(4-클로로벤질)옥살레이트, 디메틸 프탈레이트, 디벤질 테레프탈레이트, 디벤질 이소프탈레이트, 1,2-디페녹시에탄, 1,2-비스(4-메틸페녹시)에탄, 1,2-비스(3-메틸페녹시)에탄, 4,4'-디메틸비페닐, 페닐-1-하이드록시-2-나프토에이트, 4-메틸페닐 비페닐 에테르, 1,2-비스(3,4-디메틸페닐)에탄, 2,3,5,6-4'-메틸디페닐 메탄, 1,4-디에톡시나프탈렌, 1,4-디아세톡시벤젠, 1,4-디프로프리온옥시벤젠, o-크실릴렌-비스(페닐 에테르), 4-(m-메틸페녹시메틸)비페닐, p-하이드록시아세트아닐리드, p-하이드록시부티르아닐리드, p-하이드록시노난아닐리드, p-하이드록시라우르아닐리드, p-하이드록시옥타데칸아닐리드, N-페닐-페닐설폰아미드 및 화학식 3의 감광제로 이루어진 그룹으로부터 선택된 하나 이상의 감광제를 포함하는 기록 물질.화학식 3위의 화학식 3에서,R 및 R'는 서로 동일하거나 상이하고, 각각 C1-C6알킬이다.
- 제1항 내지 제18항 중의 어느 한 항에 있어서, 하나 이상의 안정화제를 포함하는 기록 물질.
- 제18항에 있어서, 2,2'-메틸렌-비스(4-메틸-6-3급-부틸페놀), 2,2'-메틸렌-비스(4-에틸-6-3급-부틸페놀), 4,4'-부틸리덴-비스(3-메틸-6-3급-부틸페놀), 4,4'-티오-비스(2-3급-부틸-5-메틸페놀), 1,1,3-트리스(2-메틸-4-하이드록시-5-3급-부틸페닐)부탄, 1,1,3-트리스(2-메틸-4-하이드록시-5-사이클로헥실페닐)부탄, 비스(3-3급-부틸-4-하이드록시-6-메틸페닐)설폰, 비스(3,5-디브로모-4-하이드록시페닐)설폰, 4,4'-설피닐 비스(2-3급-부틸-5-메틸페놀), 2,2'-메틸렌 비스(4,6-디-3급-부틸페닐)포스페이트, 이들의 알칼리 금속염, 이들의 암모늄염, 이들의 다가 금속염, 4-벤질옥시-4'-(2-메틸글리시딜옥시)디페닐 설폰, 4,4'-디글리시딜옥시디페닐 설폰, 1,4-디글리시딜옥시벤젠, 4-[α-(하이드록시메틸)벤질옥시]-4-하이드록시디페닐 설폰, p-니트로벤조산의 금속염, 프탈산 모노벤질 에스테르의 금속염, 신남산의 금속염 및 이들의 혼합물로 이루어진 그룹으로부터 선택된 하나 이상의 안정화제를 포함하는 기록 물질.
- 화학식 2의 화합물.화학식 2위의 화학식 2에서,R1은 치환되지 않거나 치환된 페닐, 나프틸 또는 C1-C20알킬이고,R3및 R4는 서로 독립적으로 수소, C1-C8알킬, 할로겐 치환된 C1-C8알킬, C1-C8알콕시 치환된 C1-C8알킬, C1-C8알콕시, 할로겐 치환된 C1-C8알콕시, C1-C8알킬설포닐, 할로겐, 페닐, 페녹시 또는 페녹시카보닐이며,X는 화학식의 그룹이고,B는 화학식 -O-SO2-, -SO2-O-, -SO2-NH-, -O-CO- 또는 -CO-NH-SO2-의 결합 그룹이며,R2는 치환되지 않거나 치환된 페닐, 나프틸 또는 C1-C20알킬이고,단, B가 화학식 -O-SO2-의 결합 그룹이 아닌 경우, R2는 치환되지 않거나 치환된 페닐, 나프틸 또는 C1-C8알킬이다.
- 제21항에 있어서,R1이 C1-C4알킬, 바람직하게는 메틸에 의해 치환된 페닐이고,X가 화학식의 그룹이며,R3및 R4가 서로 독립적으로 수소, C1-C4알킬 또는 할로겐, 바람직하게는 수소이고,B가 화학식 -O-SO2-의 결합 그룹이며,R2가 치환되지 않거나 C1-C4알킬에 의해 치환된 페닐인 화합물.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9827569.6 | 1998-12-16 | ||
GBGB9827569.6A GB9827569D0 (en) | 1998-12-16 | 1998-12-16 | Heat sensitive recording material |
Publications (2)
Publication Number | Publication Date |
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KR20010101232A true KR20010101232A (ko) | 2001-11-14 |
KR100640676B1 KR100640676B1 (ko) | 2006-11-02 |
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Application Number | Title | Priority Date | Filing Date |
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KR1020017007474A KR100640676B1 (ko) | 1998-12-16 | 1999-12-03 | 감열성 기록 재료 |
Country Status (14)
Country | Link |
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US (1) | US6624117B1 (ko) |
EP (1) | EP1140515B1 (ko) |
JP (1) | JP4601174B2 (ko) |
KR (1) | KR100640676B1 (ko) |
CN (1) | CN1185108C (ko) |
AT (1) | ATE276111T1 (ko) |
AU (1) | AU769040B2 (ko) |
BR (1) | BR9916316B1 (ko) |
DE (1) | DE69920265T2 (ko) |
ES (1) | ES2228155T3 (ko) |
GB (1) | GB9827569D0 (ko) |
ID (1) | ID30230A (ko) |
WO (1) | WO2000035679A1 (ko) |
ZA (1) | ZA200104863B (ko) |
Families Citing this family (62)
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- 1999-12-03 EP EP99965436A patent/EP1140515B1/en not_active Expired - Lifetime
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JP4601174B2 (ja) | 2010-12-22 |
ATE276111T1 (de) | 2004-10-15 |
ZA200104863B (en) | 2002-06-14 |
CN1330593A (zh) | 2002-01-09 |
AU2095200A (en) | 2000-07-03 |
AU769040B2 (en) | 2004-01-15 |
EP1140515B1 (en) | 2004-09-15 |
KR100640676B1 (ko) | 2006-11-02 |
JP2002532441A (ja) | 2002-10-02 |
DE69920265T2 (de) | 2005-12-22 |
GB9827569D0 (en) | 1999-02-10 |
ES2228155T3 (es) | 2005-04-01 |
DE69920265D1 (de) | 2004-10-21 |
CN1185108C (zh) | 2005-01-19 |
ID30230A (id) | 2001-11-15 |
BR9916316A (pt) | 2001-08-14 |
WO2000035679A1 (en) | 2000-06-22 |
EP1140515A1 (en) | 2001-10-10 |
US6624117B1 (en) | 2003-09-23 |
BR9916316B1 (pt) | 2011-02-08 |
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