KR100418106B1 - 메탈로센화합물,이것의제조방법,및이것의올레핀중합용촉매로서의용도 - Google Patents

메탈로센화합물,이것의제조방법,및이것의올레핀중합용촉매로서의용도 Download PDF

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KR100418106B1
KR100418106B1 KR1019960705230A KR19960705230A KR100418106B1 KR 100418106 B1 KR100418106 B1 KR 100418106B1 KR 1019960705230 A KR1019960705230 A KR 1019960705230A KR 19960705230 A KR19960705230 A KR 19960705230A KR 100418106 B1 KR100418106 B1 KR 100418106B1
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substituent
metallocene compound
bis
formula
atom
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Expired - Fee Related
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KR1019960705230A
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Korean (ko)
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KR970701723A (ko
Inventor
뤼기 레스코니
파브리지오 피에몬테시
일리아 이. 나판테프
파벨 브이. 이프첸코
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바셀 테크놀로지 캄파니 비이브이
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
KR1019960705230A 1995-01-23 1996-01-17 메탈로센화합물,이것의제조방법,및이것의올레핀중합용촉매로서의용도 Expired - Fee Related KR100418106B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB9405192.1 1994-03-21
ITMI95A000099 1995-01-23
ITMI950099A IT1272923B (it) 1995-01-23 1995-01-23 Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
ITMI95A000039 1995-01-23

Related Child Applications (1)

Application Number Title Priority Date Filing Date
KR10-2003-7010028A Division KR100414759B1 (ko) 1995-01-23 1996-01-17 메탈로센 화합물, 이것의 제조 방법, 및 이것의 올레핀중합용 촉매로서의 용도

Publications (2)

Publication Number Publication Date
KR970701723A KR970701723A (ko) 1997-04-12
KR100418106B1 true KR100418106B1 (ko) 2004-04-30

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ID=11370281

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KR1019960705230A Expired - Fee Related KR100418106B1 (ko) 1995-01-23 1996-01-17 메탈로센화합물,이것의제조방법,및이것의올레핀중합용촉매로서의용도
KR10-2003-7010028A Expired - Fee Related KR100414759B1 (ko) 1995-01-23 1996-01-17 메탈로센 화합물, 이것의 제조 방법, 및 이것의 올레핀중합용 촉매로서의 용도

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Country Status (24)

Country Link
US (3) US6051728A (https=)
EP (1) EP0751946B2 (https=)
JP (1) JP3838662B2 (https=)
KR (2) KR100418106B1 (https=)
CN (2) CN1075076C (https=)
AR (1) AR000776A1 (https=)
AU (1) AU700256B2 (https=)
BG (1) BG100904A (https=)
BR (1) BR9606373A (https=)
CA (1) CA2186232A1 (https=)
CZ (1) CZ309596A3 (https=)
DE (1) DE69617543T3 (https=)
ES (1) ES2167539T5 (https=)
FI (1) FI963759A0 (https=)
HU (1) HUP9602907A3 (https=)
IL (1) IL116853A (https=)
IT (1) IT1272923B (https=)
MX (1) MX9604229A (https=)
PL (1) PL185055B1 (https=)
RU (1) RU2177948C2 (https=)
TR (1) TR199600720T1 (https=)
TW (1) TW319777B (https=)
WO (1) WO1996022995A1 (https=)
ZA (1) ZA96485B (https=)

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WO2017010648A1 (ko) * 2015-07-15 2017-01-19 한화케미칼 주식회사 메탈로센 화합물 및 이의 제조방법
KR20190078623A (ko) * 2016-12-05 2019-07-04 엑손모빌 케미칼 패턴츠 인코포레이티드 필름용의 브로드 오쏘고날 분포 메탈로센 폴리에틸렌

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DE19533337A1 (de) * 1995-09-11 1997-03-13 Basf Ag Propen/But-1-en-Copolymere
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KR20190078623A (ko) * 2016-12-05 2019-07-04 엑손모빌 케미칼 패턴츠 인코포레이티드 필름용의 브로드 오쏘고날 분포 메탈로센 폴리에틸렌
KR102212822B1 (ko) 2016-12-05 2021-02-08 엑손모빌 케미칼 패턴츠 인코포레이티드 필름용의 브로드 오쏘고날 분포 메탈로센 폴리에틸렌

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US6518386B1 (en) 2003-02-11
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